Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and p...Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and poor heat resistance limit their application scope.Recent advances have highlighted that the combination of extensional flow and thermal fields can achieve toughness–stiffness balance,high transparency,and good heat resistance.However,the effect of extensional flow on the post-non-isothermal crystallization of PLLA during heating and the resulting crystalline texture remains unclear.In this study,PLLA with a heterogeneous amorphous structure and oriented polymorph was prepared by extensional flow.The effect of heterogeneous amorphous structures on non-isothermal crystallization kinetics during the heating process was studied by thermal analysis,polarized optical microscopy,infrared spectroscopy,and ex situ/in situ X-ray characterization.These results clearly illustrate that extensional flow enhances the formation of oriented crystalline structures,accelerates non-isothermal crystallization,and modulates the polymorphic composition of PLLA.Moreover,an unexpected dual cold-crystallization behavior is identified in ordered PLLA samples upon extensional flow,which is from the extensional flow-induced heterogeneous amorphous phase into α' phase(low-temperature peak)and the pristine amorphous phase intoαphase(high-temperature peak).The extensional flow primarily promotes the formation of the more perfectαandα'phases,but has a negative effect on the final content ofαphase formed after cold crystallization andα'-to-αphase transformation.The findings of this work advance the understanding of PLLA non-isothermal crystallization after extensional flow and offer valuable guidance for high-performance PLLA upon heat treatment in practical processing.展开更多
The tectonic setting of the Himalaya during the Early Paleozoic has been a subject of enduring debate within the scientific community.Newly discovered bimodal intrusive rocks from comprehensive field geological invest...The tectonic setting of the Himalaya during the Early Paleozoic has been a subject of enduring debate within the scientific community.Newly discovered bimodal intrusive rocks from comprehensive field geological investigation in the central mountain range were subjected to petrology,zircon U-Pb geochronology,zircon Hf isotopes and whole-rock geochemistry analyses.The Palie bimodal intrusive rocks,comprising amphibolite and granitic gneiss,were formed at~489 Ma.The amphibolite exhibits geochemical characteristics consistent with N-MORB,while the granitic gneiss is classified as high potassium calc-alkaline peraluminous S-type granite.Both igneous rocks exhibit negative zirconε_(Hf)(t)values and display ancient T_(DM)^(C)ages.In conjunction with regional geological survey findings,it can be inferred that the formation of the Palie bimodal intrusive rocks occurred within a post-collision extensional tectonic setting.The amphibolite genesis involved partial melting of an enriched lithospheric mantle with some crustal assimilation,whereas the origin of the granitic gneiss can be attributed to partial melting of pre-existing felsic crust.Our data indicate that during the Early Paleozoic,the Himalaya underwent a transition from a pan-African collisional setting to post-collisional extensional tectonics.展开更多
The fact that several half-grabens and normal faults developed in the Lower--Middle Cambrian of Tazhong （central Tarim Basin） and Bachu areas in Tarim Basin, northwest China, indicates that Tarim Basin was under ext...The fact that several half-grabens and normal faults developed in the Lower--Middle Cambrian of Tazhong （central Tarim Basin） and Bachu areas in Tarim Basin, northwest China, indicates that Tarim Basin was under extensional tectonic setting at this time. The half-grabens occur within a linear zone and the normal faults are arranged in en echelon patterns with gradually increasing displacement eastward. Extensional tectonics resulted in the formation of a passive continental margin in the southwest and a cratonic margin depression in the east, and most importantly, influenced the development of a three- pronged rift in the northeast margin of the Tarim Basin. The fault system controlled the development of platform -- slope -- bathyal facies sedimentation of mainly limestone-dolomite-gypsum rock-saline rock-red beds in the half-grabens. The NW-SE trending half-grabens reflect the distribution of buried basement faults.展开更多
Angular unconformity is one of the most direct and strongest evidences for approving the tectonic movements of the earth's crust. Its dynamic genesis process has been understood to be mainly related to the compres...Angular unconformity is one of the most direct and strongest evidences for approving the tectonic movements of the earth's crust. Its dynamic genesis process has been understood to be mainly related to the compressional setting for a long time. Especially, in a detailed structural analysis for a specific region, when an angular unconformity is discovered people would regard it as the result of orogenic movements of a certain period or a certain episode and neglect the extensional facts. Based on a dialectical point of view of extension-compression, this paper has proved that angular unconformities can be formed not only in compressional settings, but also in extensional ones. Further more, their geological features are compared and he possible genetic mechanisms for angular unconformity under different dynamic settings are studied.展开更多
Three series of sandbox modeling experiments were performed to study the fault-increment pattern in extensional basins. Experimental results showed that the tectonic action mode of boundaries and the shape of major bo...Three series of sandbox modeling experiments were performed to study the fault-increment pattern in extensional basins. Experimental results showed that the tectonic action mode of boundaries and the shape of major boundary faults control the formation and evolution of faults in extensional basins. In the process of extensional deformation, the increase in the number and length of faults was episodic, and every ＇episode＇ experienced three periods, strain-accumulation period, quick fault-increment period and strain-adjustment period. The more complex the shape of the boundary fault, the higher the strain increment each ＇episode＇ experienced. Different extensional modes resulted in different fault-increment patterns. The horizontal detachment extensional mode has the ＇linear＇ style of fault-increment pattern, while the extensional mode controlled by a listric fault has the ＇stepwise＇ style of fault-increment pattern, and the extensional mode controlled by a ramp-flat boundary fault has the ＇stepwise-linear＇ style of fault-increment pattern. These fault-increment patterns given above could provide a theoretical method of fault interpretation and fracture prediction in extensional basins.展开更多
The spatio-temporal characteristics of acoustic emission (AE) during the deformation of rock samples with compressional and extensional en-echelon faults have been studied. The results show that the pre-existing struc...The spatio-temporal characteristics of acoustic emission (AE) during the deformation of rock samples with compressional and extensional en-echelon faults have been studied. The results show that the pre-existing structure can significantly influence the patterns of AE spatial distribution. With increasing of differential stress, AE events firstly cluster around the two ends of pre-existing faults inside the jog and then along the line joining the two ends. The biggish AE events often occur around one end repeatedly. The image of AE clusters indicates the direction and the area of the fracture propagation. The direction of the macroscopic fracture in extensional and compressional jogs is perpendicular and parallel to the direction of axial stress, respectively. The weakening process before the fracturing of jog area is remarkable, and one of the typical precursors for the instability is that the cumulative frequency of AE events increases exponentially. After the fracturing of the jog the frequency and releasing strain energy of AE events decrease gradually. During the friction period, there is no precursory increasing of AE activity before the big stick-slip events. The change of b value in jog shows a typical change of decreasing tendentiously returning quickly before the instability. The decrease of b value occurs in the process of stress increasing and sometime goes down to the weakening stage, and the quick increase b values appears in a short time just before the instability. The comparative analysis shows that the difference in b value due to the different structures is larger than b value variation caused by increase of the differential stress. For the same sample, the temporal sequence of AE is strongly affected by the mechanical state, and the high loading velocity corresponds to the high release rate of strain energy and low b value. Due to its lower failure strength, the broken area is sensitive to small changes in differential stress. Therefore, it offers a potential explanation for the phenomena of precursory window or sensitive point and separation of seismic source and precursors.展开更多
The present-day tectonic activities on the northeastern margin of the Pamir Plateau are mainly E-W oriented extensions, among which the Kongur Extensional System(KES) plays an important role in the internal expansion ...The present-day tectonic activities on the northeastern margin of the Pamir Plateau are mainly E-W oriented extensions, among which the Kongur Extensional System(KES) plays an important role in the internal expansion of the Pamir. As the largest earthquake since Taxkorgan earthquakes in 1895 and 1896, the Aketao earthquake occurred on the Muji fault on the northern portion of the KES in 2016. Since then, the trend of seismic activities along the KES has been paid much attention to. Based on the visco elastic layered lithosphere model, we calculate the co-seismic and post-seismic stress changes caused by five historical earthquakes on the KES and its adjacent areas since 1895, and analyze the interaction among strong earthquakes. The results show that all of the historical earthquakes after 1895 occurred in the areas where the co-seismic and post-seismic Coulomb stress increased. Coulomb stress loading at the hypocenters of the 1896 Taxkorgan earthquake, the 1974 Markansu earthquake and the 2016 Aketao earthquake were 0.251 MPa, 0.013 MPa and 0.563 MPa, respectively. The three earthquakes were catalyzed by such variations. The historical earthquakes increased the stress state on most segments of the Southern Kungai Mountain fault and Kongur fault along the KES. In particular, we can identify 2 visible earthquake gaps with increasing seismic hazard formed on the Qimugan segment and Bulunkou segment of the KES. The Qimugan section and the Bulunkou section are located at the fault transition zone with concentrated stress and high extension rate, so great attention should be paid to their seismic hazard at present day.展开更多
Multi-stage Mesozoic thrust-nappe and extensional structures are distributed in the east segment of the Southeast Yangtze Block situated in the junction region of Zhejiang-Jiangxi-Anhui provinces. The features and gen...Multi-stage Mesozoic thrust-nappe and extensional structures are distributed in the east segment of the Southeast Yangtze Block situated in the junction region of Zhejiang-Jiangxi-Anhui provinces. The features and genetic mechanism of the deformations were analyzed after a detailed field observation of their distribution, geometry, and kinematics. In addition, the time sequences of the thrust and extensional structures were determined by combining the results of the comparative analysis with the chronological evidence of strata and magmatic rocks cut by a fault or formed after a fault according to field facts. This study identified three stages of the nappe structures and at least two stages of the extensional structures during the Mesozoic. The geotectonic setting of the nappe and extensional structures was considered to be related to the different geodynamics in the study area including the Early Mesozoic geological event, i.e., N-S compression, forming Lantian fault, etc.;the Late Mesozoic flat-slab subduction, forming Xiaoxi thrust fault and tectonic window;and the roll-back of the paleoPacific Plate, forming extensional structures like basin marginal fault;the last compression, forming Wucheng-Shenxian fault. These findings provide additional evidence for remodeling the tectonic and geodynamic evolution of Southeast China.展开更多
During subduction, continental margins experience shortening along with inversion of extensional sedimentary basins. Here we explore a tectonic scenario for the inversion of two-phase extensional basin systems, where ...During subduction, continental margins experience shortening along with inversion of extensional sedimentary basins. Here we explore a tectonic scenario for the inversion of two-phase extensional basin systems, where the Early-Middle Jurassic intra-arc volcano-sedimentary Oseosan Volcanic Complex was developed on top of the Late Triassic-Early Jurassic post-collisional sequences, namely the Chungnam Basin. The basin shortening was accommodated mostly by contractional faults and related folds. In the basement, regional high-angle reverse faults as well as low-angle thrusts accommodate the overall shortening, and are compatible with those preserved in the cover. This suggests that their spatial and temporal development is strongly dependent on the initial basin geometry and inherited structures.Changes in transport direction observed along the basement-sedimentary cover interface is a characteristic structural feature, reflecting sequential kinematic evolution during basin inversion. Propagation of basement faults also enhanced shortening of the overlying sedimentary cover sequences. We constrain timing of the Late Jurassic-Early Cretaceous(ca. 158-110 Ma) inversion from altered K-feldspar 40 Ar/39 Ar ages in stacked thrust sheets and K-Ar illite ages of fault gouges, along with previously reported geochronological data from the area. This "non-magmatic phase" of the Daebo Orogeny is contemporaneous with the timing of magmatic quiescence across the Korean Peninsula. We propose the role of flat/low-angle subduction of the Paleo-Pacific Plate for the development of the "Laramide-style" basement-involved orogenic event along East Asian continental margin.展开更多
On the basis of exhaustive researches on the facies sequences and depositlonal evolutionary process of various depositional systems, the genetic stratigraphic framework of the extensional rifted oceanic basin, which h...On the basis of exhaustive researches on the facies sequences and depositlonal evolutionary process of various depositional systems, the genetic stratigraphic framework of the extensional rifted oceanic basin, which has undergone strong structural destruction, has been reconstructed by means of dynamic genetic stratigraphic analysis. Five depositional episodes have been distinguished from various isochronous stratigraphic boundaries and stratigraphic sequences with the three-dimensional structure of each depositional episode analysed in detail. The tectonic paleogeographic environment corresponding to different stages of each depositional episode has been reconstructed for individual depositional system tracts. And the evolution history of this rifted basin has been divided into four stages' initial rifting and oceanization of continental crust, stretching and spreading of the basin, subduction and basin differentiation, and convergence and collision. A NNE-trending intracontinental soft collision suture was left after the closing of the basin.展开更多
Extensional fault-bend folds,also called rollovers,are one of the most common structures in extensional settings.Numerous studies have shown that oblique simple shear is the most appropriate mechanism for quantitative...Extensional fault-bend folds,also called rollovers,are one of the most common structures in extensional settings.Numerous studies have shown that oblique simple shear is the most appropriate mechanism for quantitative modeling of geometric relations between normal faults and the strata in their hanging walls.However,the oblique simple shear has a rather serious issue derived from the shear direction,particularly above convex bends.We use geometric and experimental methods to study the deformation of extensional fault-bend folds on convex bends.The results indicate that whether the fault bends are concave or convex,the shear direction of the hanging wall dips toward the main fault.On this basis,we improve the previous geometric model by changing the shear direction above the convex bends.To illustrate basin history,our model highlights the importance of the outer limit of folding instead of the growth axial.Moreover,we propose a new expression for the expansion index that is applicable to the condition of no deposition on the footwall.This model is validated by modeling a natural structure of the East China Sea Basin.展开更多
Objective Previous studies indicate that the North China Craton（NCC）had undergone the loss of thickened lithosphere and fundamental change of physical and chemical property of lithospheric mantle（the destruction of...Objective Previous studies indicate that the North China Craton（NCC）had undergone the loss of thickened lithosphere and fundamental change of physical and chemical property of lithospheric mantle（the destruction of NCC）during the Mesozoic.The peak period of the destruction of NCC is estimated to be 130 Ma,accompanied by widespread metamorphic core complex,rift basins,A-type granites and mafic dykes. However, it remains greatly controversial on the tectonic setting of NCC in the pre- 130Ma.展开更多
The estimation of contemporary tectonic stress field and deformation in active fold-and-thrust belts are imperative in identifying active geodynamics and resulting faulting phenomenon. In this paper, we focus on conte...The estimation of contemporary tectonic stress field and deformation in active fold-and-thrust belts are imperative in identifying active geodynamics and resulting faulting phenomenon. In this paper, we focus on contemporary extensional tectonics in the overall compressive setting of the Himalayan orogen. Here we examine the regional tectonic stress field and upper crustal deformation in the Himalayan thrust wedge using a 2D finite element technique, incorporating elastic rheology under plain strain condition. The elastic models demonstrate that the extensional tectonic stress and related nor- mal faulting is extensively developed in the southern front of the Himalaya at shallow crustal level (<10 km in depth). Our modelling shows a good consistency with the geological field evidences of active faulting, focal mechanism solutions of medium size earthquakes in the several sectors of the Himalaya. Results based on numerical simulation, tectonic analysis and taking geological and geophysical data into account, we interpret that the present-day extensional tectonic activity is not restricted in the southern Tibet but distributed in the different sectors of the Himalayan fold-and-thrust belt co-exist with compressional structures. Modelling results also indicate that the nature, distribution and orientation of the maximum compressive stress (?1) of the Himalaya are mainly controlled by the intra crustal Main Himalayan décollement (MHT). The significant amount of shear stress/strain concentration along the MHT in the western Nepal predict that the region is prone to moderate and great future earthquakes.展开更多
Based on the study of the location of extensional action in the tectonic background and the state of regional tectonic stress, the extensional action can be distinguished into active and passive types. The active exte...Based on the study of the location of extensional action in the tectonic background and the state of regional tectonic stress, the extensional action can be distinguished into active and passive types. The active extensional movement is mainly composed of a set of deposition formed under extensional stress and syntectonic and syndepositional deformational structure. The passive extentional movement is expressed as regional extensional action induced under the compressional elevation. Extensional movement and action are well\|developed in the Tibet\|Tethys domain. By the analysis of tectonic deformation, extensional unconformity, depositional facies and paleogeographical rebuilding in the South Tibet, it is recognized that the extensional movement consists of active extension of Hercynian, Indo\|China and Early Yanshan epochs, and the passive extension of Late Yanshan and Himalayan epochs. Some of the characteristics of extensional movement and structures are discussed in this paper(Table.1).展开更多
The Mesoproterozoic Baoban Group is the oldest basement in Hainan Island and has played an important role in Columbia(Nuna)supercontinent reconstructions.The Mesoproterozoic granitic intrusions in the Baoban Group are...The Mesoproterozoic Baoban Group is the oldest basement in Hainan Island and has played an important role in Columbia(Nuna)supercontinent reconstructions.The Mesoproterozoic granitic intrusions in the Baoban Group are the most widely-exposed Precambrian magmatic rocks and are the key to understanding the tectonic settings of Hainan Island and its relationship with the South China Block and the Columbia supercontinent.New LA-ICP-MS zircon U-Pb dating on three mylonitic granite samples from the Tuwaishan and Baoban areas yield ages ranging from 1447 Ma to 1437 Ma,representing the absolute timing of the emplacement of the granitic intrusions.Combined with previously published geochronological data for rocks from the Baoban Group and regional mafic intrusions,it is concluded that the Baoban Group formed at 1460-1430 Ma,coeval with the emplacement of the granitic and mafic intrusions.New in-situ zircon LuHf isotope analyses for the three mylonitic granite samples yielded positiveε(t)values,ranging from+0.49 to+8.27,with model ages(T~C)ranging from 2181 Ma to 1687 Ma,suggesting that the granitic intrusions originated from a mixed source of Paleoproterozoic crust with juvenile crust.New zircon trace element data show characteristics of high Th/U values of 0.24-1.50,steep slopes from LREE to HREE and negative Pr,Eu anomalies with positive Ce,Sm anomalies,representing typical magmatic zircons formed in continental crust.Compared with available magmatic and detrital zircon ages from Precambrian rocks in the Cathaysia Block,Yangtze Block and western Laurentia,it is inferred that Hainan Island was separated from both the Cathaysia Block and the Yangtze Block,instead being connected with western Laurentia in the Columbia supercontinent.Considering the decreasing tendency of basin deposition time along the western margin of Laurentia,it is proposed that Hainan Island was located to the north or northwest of the Belt-Purcell Supergroup,along the western margin of Laurentia,during the breakup of the Columbia supercontinent.展开更多
Due to the multiformity and complexity of chain conformation under external flow and the challenge of systematically investigating the transient conformation and dynamic evolution process of polymer chains at the mole...Due to the multiformity and complexity of chain conformation under external flow and the challenge of systematically investigating the transient conformation and dynamic evolution process of polymer chains at the molecular level by means of present experimental techniques,a universal description of both chain conformation and dynamics with respect to continuous volume extensional flow(CVEF)is still absent.Taking into account the temperature effect,we performed dissipative particle dynamics(DPD)simulations with the particles corresponding to the repeat units of polymers over a wide temperature range and analyzed the correlation with the conformational properties of ultra-high molecular weight polyethylene/polypropylene(UHMWPE/PP)blend in response to the CVEF.With time evolution,the polymer chains become highly oriented parallel to the flow direction instead of the initial random coiling and self-aggregation.It is found that a high temperature is necessary for more substantial compactness to take place than low temperature.The low-k plateau and low-k peak in structure factor S(k)curves suggest a low degree of conformational diversity and a high degree of chain stretching.It is also concluded that the intra-molecular C-C bond interaction is the main driving force for the dynamics process of the chain conformations undergoing CVEF,where the motion of the alkyl chains is seriously restricted owing to the increase in bond interaction potential,resulting in a reduction of the difference in diffusion rates among alkyl chains.展开更多
This work presents a novel radio frequency(RF)narrowband Si micro-electro-mechanical systems(MEMS)filter based on capacitively transduced slotted width extensional mode(WEM)resonators.The flexibility of the plate lead...This work presents a novel radio frequency(RF)narrowband Si micro-electro-mechanical systems(MEMS)filter based on capacitively transduced slotted width extensional mode(WEM)resonators.The flexibility of the plate leads to multiple modes near the target frequency.The high Q-factor resonators of around 100000 enable narrow bandwidth filters with small size and simplified design.The 1-wavelength and 2-wavelength WEMs were first developed as a pair of coupled modes to form a passband.To reduce bandwidth,two plates are coupled with aλ-length coupling beam.The 79.69 MHz coupled plate filter(CPF)achieved a narrow bandwidth of 8.8 kHz,corresponding to a tiny 0.011%.The CPF exhibits an impressive 34.84 dB stopband rejection and 7.82 dB insertion loss with near-zero passband ripple.In summary,the RF MEMS filter presented in this work shows promising potential for application in RF transceiver front-ends.展开更多
Horsetailing is an important feature to identify the strike-slip structure and indicates the movement mode of the fault.However,the formation mechanism of horsetailing in the extensional regime remains unclear.In this...Horsetailing is an important feature to identify the strike-slip structure and indicates the movement mode of the fault.However,the formation mechanism of horsetailing in the extensional regime remains unclear.In this study,the formation process of horsetailing is reproduced through physical experiment,simulating the Linnan sag in the extensional regime.The results of the physical experiment demonstrates that the formation of the horsetailing in the extensional regime requires two phases of non-coaxial stretching plus the segment of the principal fault.The stretching distance in the early phase is slightly smaller than that in the middle-late phase.The segment point of the principal fault is only the intersection of the horsetailing structure and the principal fault.The horsetailing formed in the extensional regime is different from that in the strike-slip regime.For the formation of structure,the principal fault is dip-slip in the early phase and then becomes an oblique-slip in the middle-late phase,and the horsetailing is composed of the middle-late new tensile faults.The fault properties of the horsetailing in the extensional regime has important guiding significance for the longitudinal fluid migration along the fault in petroliferous basins.展开更多
The Aegean area of the western Anatolian region of Turkey,controlled by the low-angle detachment normal fault system,forms an extensional province,the West Anatolian Extensional Province(WAEP).The tectonic deformation...The Aegean area of the western Anatolian region of Turkey,controlled by the low-angle detachment normal fault system,forms an extensional province,the West Anatolian Extensional Province(WAEP).The tectonic deformation which occurred in the Miocene Period,including the Plio–Quaternary Period has created different structures in both the basement rocks and intra-basin deposits of the crust.One of these structures,high-angle normal faults,controls the supradetachment Soke-Kusadasi Basin(SKB).Within this basin,there are folds with different axes and thrust faults with a north-northwestnortheast(N,NW,NE)trend.These folds and thrust faults in the SKB deformed the sedimentary structures of intra-basin deposits.The folds and thrust faults,which caused the rotation of beddings and imbrications in the SKB,are mainly associated with the tectonic process of the low angle detachment normal fault,which affected the SKB and the Aegean part of western Anatolia.In the SKB,during the process of extensional deformation associated with primary low angle detachment normal faulting,the ramp-flat and inversion geometry observed in the basement rocks and basin deposits of the crust caused folds and thrust faults in only intra-basin deposits.In the WAEP,it is determined for the first time that the folds and thrust faults causing limited shortening deformed the Plio–Quaternary sediments.展开更多
This work systematically simulates the external mass transfer from/to a spherical drop and solid particle suspended in a nonlinear uniaxial extensional creeping flow.The mass transfer problem is governed by three dime...This work systematically simulates the external mass transfer from/to a spherical drop and solid particle suspended in a nonlinear uniaxial extensional creeping flow.The mass transfer problem is governed by three dimensionless parameters:the viscosity ratio(λ),the Peclet number(Pe),and the nonlinear intensity of the flow(E).The existing mass transfer theory,valid for very large Peclet numbers only,is expanded,by numerical simulations,to include a much larger range of Peclet numbers(1≤Pe≤105).The simulation results show that the dimensionless mass transfer rate,expressed as the Sherwood number(5 h),agrees well with the theoretical results at the convection-dominated regime(Pe>103).Only when E>5/4,the simulated Sh for a solid sphere in the nonlinear uniaxial extensional flow is larger than theoretical results because the theory neglects the effect of the vortex formed outside the particle on the rate of mass transfer.Empirical correlations are proposed to predict the influence of the dimensionless governing parameters(λ,Pe,E)on the Sherwood number(Sh).The maximum deviations of all empirical correlations are less than 15%when compared to the numerical simulated results.展开更多
基金supported by the National Natural Science Foundation of China(Nos.U23A20583,52033005,U21A2090,and 52173040)Department of Science and Technology of Sichuan Province(No.2024NSFTD0003)。
文摘Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and poor heat resistance limit their application scope.Recent advances have highlighted that the combination of extensional flow and thermal fields can achieve toughness–stiffness balance,high transparency,and good heat resistance.However,the effect of extensional flow on the post-non-isothermal crystallization of PLLA during heating and the resulting crystalline texture remains unclear.In this study,PLLA with a heterogeneous amorphous structure and oriented polymorph was prepared by extensional flow.The effect of heterogeneous amorphous structures on non-isothermal crystallization kinetics during the heating process was studied by thermal analysis,polarized optical microscopy,infrared spectroscopy,and ex situ/in situ X-ray characterization.These results clearly illustrate that extensional flow enhances the formation of oriented crystalline structures,accelerates non-isothermal crystallization,and modulates the polymorphic composition of PLLA.Moreover,an unexpected dual cold-crystallization behavior is identified in ordered PLLA samples upon extensional flow,which is from the extensional flow-induced heterogeneous amorphous phase into α' phase(low-temperature peak)and the pristine amorphous phase intoαphase(high-temperature peak).The extensional flow primarily promotes the formation of the more perfectαandα'phases,but has a negative effect on the final content ofαphase formed after cold crystallization andα'-to-αphase transformation.The findings of this work advance the understanding of PLLA non-isothermal crystallization after extensional flow and offer valuable guidance for high-performance PLLA upon heat treatment in practical processing.
基金supported by the China Geological Survey Program(Grant No.DD20220989)the National Natural Science Foundation of China(Grant No.41972118)。
文摘The tectonic setting of the Himalaya during the Early Paleozoic has been a subject of enduring debate within the scientific community.Newly discovered bimodal intrusive rocks from comprehensive field geological investigation in the central mountain range were subjected to petrology,zircon U-Pb geochronology,zircon Hf isotopes and whole-rock geochemistry analyses.The Palie bimodal intrusive rocks,comprising amphibolite and granitic gneiss,were formed at~489 Ma.The amphibolite exhibits geochemical characteristics consistent with N-MORB,while the granitic gneiss is classified as high potassium calc-alkaline peraluminous S-type granite.Both igneous rocks exhibit negative zirconε_(Hf)(t)values and display ancient T_(DM)^(C)ages.In conjunction with regional geological survey findings,it can be inferred that the formation of the Palie bimodal intrusive rocks occurred within a post-collision extensional tectonic setting.The amphibolite genesis involved partial melting of an enriched lithospheric mantle with some crustal assimilation,whereas the origin of the granitic gneiss can be attributed to partial melting of pre-existing felsic crust.Our data indicate that during the Early Paleozoic,the Himalaya underwent a transition from a pan-African collisional setting to post-collisional extensional tectonics.
基金sponsored jointly by the National Natural Science Foundation of China(Grant No.41102087)the National Key Basic Research Program of China(No.2005CB422103)+1 种基金National"973"program(Grant No.2012CB214802)Major National Sci-Tech Projects(Grant Nos.2011ZX05005-002-010HZ. 2011ZX05009-002)
文摘The fact that several half-grabens and normal faults developed in the Lower--Middle Cambrian of Tazhong （central Tarim Basin） and Bachu areas in Tarim Basin, northwest China, indicates that Tarim Basin was under extensional tectonic setting at this time. The half-grabens occur within a linear zone and the normal faults are arranged in en echelon patterns with gradually increasing displacement eastward. Extensional tectonics resulted in the formation of a passive continental margin in the southwest and a cratonic margin depression in the east, and most importantly, influenced the development of a three- pronged rift in the northeast margin of the Tarim Basin. The fault system controlled the development of platform -- slope -- bathyal facies sedimentation of mainly limestone-dolomite-gypsum rock-saline rock-red beds in the half-grabens. The NW-SE trending half-grabens reflect the distribution of buried basement faults.
基金the National Natural Science Foundation(grant 40373005)the Foundation of Sichuan Province for Training Outstanding Young Leaders of V arious Disciplines(No.02ZQ026-046)the Foundation of Sichuan Province for Training Scientific and Technological Leaders in the Year 2003(No.2200336)
文摘Angular unconformity is one of the most direct and strongest evidences for approving the tectonic movements of the earth's crust. Its dynamic genesis process has been understood to be mainly related to the compressional setting for a long time. Especially, in a detailed structural analysis for a specific region, when an angular unconformity is discovered people would regard it as the result of orogenic movements of a certain period or a certain episode and neglect the extensional facts. Based on a dialectical point of view of extension-compression, this paper has proved that angular unconformities can be formed not only in compressional settings, but also in extensional ones. Further more, their geological features are compared and he possible genetic mechanisms for angular unconformity under different dynamic settings are studied.
文摘Three series of sandbox modeling experiments were performed to study the fault-increment pattern in extensional basins. Experimental results showed that the tectonic action mode of boundaries and the shape of major boundary faults control the formation and evolution of faults in extensional basins. In the process of extensional deformation, the increase in the number and length of faults was episodic, and every ＇episode＇ experienced three periods, strain-accumulation period, quick fault-increment period and strain-adjustment period. The more complex the shape of the boundary fault, the higher the strain increment each ＇episode＇ experienced. Different extensional modes resulted in different fault-increment patterns. The horizontal detachment extensional mode has the ＇linear＇ style of fault-increment pattern, while the extensional mode controlled by a listric fault has the ＇stepwise＇ style of fault-increment pattern, and the extensional mode controlled by a ramp-flat boundary fault has the ＇stepwise-linear＇ style of fault-increment pattern. These fault-increment patterns given above could provide a theoretical method of fault interpretation and fracture prediction in extensional basins.
基金Project Study on the Short-term Forecasting Technique of Strong Earthquake (01-04-01) during the Tenth Five-Year Plan from Ministry of Science and Technology of China and Joint Seismological Science Foundation of China (102037).
文摘The spatio-temporal characteristics of acoustic emission (AE) during the deformation of rock samples with compressional and extensional en-echelon faults have been studied. The results show that the pre-existing structure can significantly influence the patterns of AE spatial distribution. With increasing of differential stress, AE events firstly cluster around the two ends of pre-existing faults inside the jog and then along the line joining the two ends. The biggish AE events often occur around one end repeatedly. The image of AE clusters indicates the direction and the area of the fracture propagation. The direction of the macroscopic fracture in extensional and compressional jogs is perpendicular and parallel to the direction of axial stress, respectively. The weakening process before the fracturing of jog area is remarkable, and one of the typical precursors for the instability is that the cumulative frequency of AE events increases exponentially. After the fracturing of the jog the frequency and releasing strain energy of AE events decrease gradually. During the friction period, there is no precursory increasing of AE activity before the big stick-slip events. The change of b value in jog shows a typical change of decreasing tendentiously returning quickly before the instability. The decrease of b value occurs in the process of stress increasing and sometime goes down to the weakening stage, and the quick increase b values appears in a short time just before the instability. The comparative analysis shows that the difference in b value due to the different structures is larger than b value variation caused by increase of the differential stress. For the same sample, the temporal sequence of AE is strongly affected by the mechanical state, and the high loading velocity corresponds to the high release rate of strain energy and low b value. Due to its lower failure strength, the broken area is sensitive to small changes in differential stress. Therefore, it offers a potential explanation for the phenomena of precursory window or sensitive point and separation of seismic source and precursors.
基金funded by the Spark Program of Earthquake Technology of CEA(XH17023Y)The National Natural Science Foundation of China(41604079,41504011,41574017,41541029)the Science and Technology Partnership Program of Shanghai Cooperation Organization(2017E01030)
文摘The present-day tectonic activities on the northeastern margin of the Pamir Plateau are mainly E-W oriented extensions, among which the Kongur Extensional System(KES) plays an important role in the internal expansion of the Pamir. As the largest earthquake since Taxkorgan earthquakes in 1895 and 1896, the Aketao earthquake occurred on the Muji fault on the northern portion of the KES in 2016. Since then, the trend of seismic activities along the KES has been paid much attention to. Based on the visco elastic layered lithosphere model, we calculate the co-seismic and post-seismic stress changes caused by five historical earthquakes on the KES and its adjacent areas since 1895, and analyze the interaction among strong earthquakes. The results show that all of the historical earthquakes after 1895 occurred in the areas where the co-seismic and post-seismic Coulomb stress increased. Coulomb stress loading at the hypocenters of the 1896 Taxkorgan earthquake, the 1974 Markansu earthquake and the 2016 Aketao earthquake were 0.251 MPa, 0.013 MPa and 0.563 MPa, respectively. The three earthquakes were catalyzed by such variations. The historical earthquakes increased the stress state on most segments of the Southern Kungai Mountain fault and Kongur fault along the KES. In particular, we can identify 2 visible earthquake gaps with increasing seismic hazard formed on the Qimugan segment and Bulunkou segment of the KES. The Qimugan section and the Bulunkou section are located at the fault transition zone with concentrated stress and high extension rate, so great attention should be paid to their seismic hazard at present day.
文摘Multi-stage Mesozoic thrust-nappe and extensional structures are distributed in the east segment of the Southeast Yangtze Block situated in the junction region of Zhejiang-Jiangxi-Anhui provinces. The features and genetic mechanism of the deformations were analyzed after a detailed field observation of their distribution, geometry, and kinematics. In addition, the time sequences of the thrust and extensional structures were determined by combining the results of the comparative analysis with the chronological evidence of strata and magmatic rocks cut by a fault or formed after a fault according to field facts. This study identified three stages of the nappe structures and at least two stages of the extensional structures during the Mesozoic. The geotectonic setting of the nappe and extensional structures was considered to be related to the different geodynamics in the study area including the Early Mesozoic geological event, i.e., N-S compression, forming Lantian fault, etc.;the Late Mesozoic flat-slab subduction, forming Xiaoxi thrust fault and tectonic window;and the roll-back of the paleoPacific Plate, forming extensional structures like basin marginal fault;the last compression, forming Wucheng-Shenxian fault. These findings provide additional evidence for remodeling the tectonic and geodynamic evolution of Southeast China.
基金supported by Basic Science Research Program through National Research Foundation of Korea funded by the Ministry of Education, Science and Technology (2018R1C 186003851)to S.-I. Park and 2015RIDlAIA09058914 and NRF2019R1A2C1002211 to S. Kwonsupported by the 2017RlA6A1A07015374(Multidisciplinary study forassessment of large earthquake potentials in the Korean Peninsula) through the National Research Foundation of Korea(NRF)funded by the Ministry of Science and ICT, Korea to S.K
文摘During subduction, continental margins experience shortening along with inversion of extensional sedimentary basins. Here we explore a tectonic scenario for the inversion of two-phase extensional basin systems, where the Early-Middle Jurassic intra-arc volcano-sedimentary Oseosan Volcanic Complex was developed on top of the Late Triassic-Early Jurassic post-collisional sequences, namely the Chungnam Basin. The basin shortening was accommodated mostly by contractional faults and related folds. In the basement, regional high-angle reverse faults as well as low-angle thrusts accommodate the overall shortening, and are compatible with those preserved in the cover. This suggests that their spatial and temporal development is strongly dependent on the initial basin geometry and inherited structures.Changes in transport direction observed along the basement-sedimentary cover interface is a characteristic structural feature, reflecting sequential kinematic evolution during basin inversion. Propagation of basement faults also enhanced shortening of the overlying sedimentary cover sequences. We constrain timing of the Late Jurassic-Early Cretaceous(ca. 158-110 Ma) inversion from altered K-feldspar 40 Ar/39 Ar ages in stacked thrust sheets and K-Ar illite ages of fault gouges, along with previously reported geochronological data from the area. This "non-magmatic phase" of the Daebo Orogeny is contemporaneous with the timing of magmatic quiescence across the Korean Peninsula. We propose the role of flat/low-angle subduction of the Paleo-Pacific Plate for the development of the "Laramide-style" basement-involved orogenic event along East Asian continental margin.
文摘On the basis of exhaustive researches on the facies sequences and depositlonal evolutionary process of various depositional systems, the genetic stratigraphic framework of the extensional rifted oceanic basin, which has undergone strong structural destruction, has been reconstructed by means of dynamic genetic stratigraphic analysis. Five depositional episodes have been distinguished from various isochronous stratigraphic boundaries and stratigraphic sequences with the three-dimensional structure of each depositional episode analysed in detail. The tectonic paleogeographic environment corresponding to different stages of each depositional episode has been reconstructed for individual depositional system tracts. And the evolution history of this rifted basin has been divided into four stages' initial rifting and oceanization of continental crust, stretching and spreading of the basin, subduction and basin differentiation, and convergence and collision. A NNE-trending intracontinental soft collision suture was left after the closing of the basin.
文摘Extensional fault-bend folds,also called rollovers,are one of the most common structures in extensional settings.Numerous studies have shown that oblique simple shear is the most appropriate mechanism for quantitative modeling of geometric relations between normal faults and the strata in their hanging walls.However,the oblique simple shear has a rather serious issue derived from the shear direction,particularly above convex bends.We use geometric and experimental methods to study the deformation of extensional fault-bend folds on convex bends.The results indicate that whether the fault bends are concave or convex,the shear direction of the hanging wall dips toward the main fault.On this basis,we improve the previous geometric model by changing the shear direction above the convex bends.To illustrate basin history,our model highlights the importance of the outer limit of folding instead of the growth axial.Moreover,we propose a new expression for the expansion index that is applicable to the condition of no deposition on the footwall.This model is validated by modeling a natural structure of the East China Sea Basin.
基金financially supported by the Nature Science Foundation of China (grants No.41372109,90914003 and 41672111)China Geological Survey (grants No.12120115068901,1212011120142 and 12120114064301)the National Science and Technology Works Special Project (grant No.2015FY310100)
文摘Objective Previous studies indicate that the North China Craton（NCC）had undergone the loss of thickened lithosphere and fundamental change of physical and chemical property of lithospheric mantle（the destruction of NCC）during the Mesozoic.The peak period of the destruction of NCC is estimated to be 130 Ma,accompanied by widespread metamorphic core complex,rift basins,A-type granites and mafic dykes. However, it remains greatly controversial on the tectonic setting of NCC in the pre- 130Ma.
文摘The estimation of contemporary tectonic stress field and deformation in active fold-and-thrust belts are imperative in identifying active geodynamics and resulting faulting phenomenon. In this paper, we focus on contemporary extensional tectonics in the overall compressive setting of the Himalayan orogen. Here we examine the regional tectonic stress field and upper crustal deformation in the Himalayan thrust wedge using a 2D finite element technique, incorporating elastic rheology under plain strain condition. The elastic models demonstrate that the extensional tectonic stress and related nor- mal faulting is extensively developed in the southern front of the Himalaya at shallow crustal level (<10 km in depth). Our modelling shows a good consistency with the geological field evidences of active faulting, focal mechanism solutions of medium size earthquakes in the several sectors of the Himalaya. Results based on numerical simulation, tectonic analysis and taking geological and geophysical data into account, we interpret that the present-day extensional tectonic activity is not restricted in the southern Tibet but distributed in the different sectors of the Himalayan fold-and-thrust belt co-exist with compressional structures. Modelling results also indicate that the nature, distribution and orientation of the maximum compressive stress (?1) of the Himalaya are mainly controlled by the intra crustal Main Himalayan décollement (MHT). The significant amount of shear stress/strain concentration along the MHT in the western Nepal predict that the region is prone to moderate and great future earthquakes.
文摘Based on the study of the location of extensional action in the tectonic background and the state of regional tectonic stress, the extensional action can be distinguished into active and passive types. The active extensional movement is mainly composed of a set of deposition formed under extensional stress and syntectonic and syndepositional deformational structure. The passive extentional movement is expressed as regional extensional action induced under the compressional elevation. Extensional movement and action are well\|developed in the Tibet\|Tethys domain. By the analysis of tectonic deformation, extensional unconformity, depositional facies and paleogeographical rebuilding in the South Tibet, it is recognized that the extensional movement consists of active extension of Hercynian, Indo\|China and Early Yanshan epochs, and the passive extension of Late Yanshan and Himalayan epochs. Some of the characteristics of extensional movement and structures are discussed in this paper(Table.1).
基金funded by the Chinese Geological Survey Program(Grant Nos.DD20160035,DD20190047)the National Nonprofit Institute Research Grant of IGGE(AS2022P03)the Chinese Scholarship Council(File No.201606400032)Scholarship to Liu Yuheng。
文摘The Mesoproterozoic Baoban Group is the oldest basement in Hainan Island and has played an important role in Columbia(Nuna)supercontinent reconstructions.The Mesoproterozoic granitic intrusions in the Baoban Group are the most widely-exposed Precambrian magmatic rocks and are the key to understanding the tectonic settings of Hainan Island and its relationship with the South China Block and the Columbia supercontinent.New LA-ICP-MS zircon U-Pb dating on three mylonitic granite samples from the Tuwaishan and Baoban areas yield ages ranging from 1447 Ma to 1437 Ma,representing the absolute timing of the emplacement of the granitic intrusions.Combined with previously published geochronological data for rocks from the Baoban Group and regional mafic intrusions,it is concluded that the Baoban Group formed at 1460-1430 Ma,coeval with the emplacement of the granitic and mafic intrusions.New in-situ zircon LuHf isotope analyses for the three mylonitic granite samples yielded positiveε(t)values,ranging from+0.49 to+8.27,with model ages(T~C)ranging from 2181 Ma to 1687 Ma,suggesting that the granitic intrusions originated from a mixed source of Paleoproterozoic crust with juvenile crust.New zircon trace element data show characteristics of high Th/U values of 0.24-1.50,steep slopes from LREE to HREE and negative Pr,Eu anomalies with positive Ce,Sm anomalies,representing typical magmatic zircons formed in continental crust.Compared with available magmatic and detrital zircon ages from Precambrian rocks in the Cathaysia Block,Yangtze Block and western Laurentia,it is inferred that Hainan Island was separated from both the Cathaysia Block and the Yangtze Block,instead being connected with western Laurentia in the Columbia supercontinent.Considering the decreasing tendency of basin deposition time along the western margin of Laurentia,it is proposed that Hainan Island was located to the north or northwest of the Belt-Purcell Supergroup,along the western margin of Laurentia,during the breakup of the Columbia supercontinent.
基金the National Key R&D Program of China(No.2016YFB0302301)the Guangdong YangFan Innovative&Ente preneurial Research TeamProgram(No.2016YT03C077)+1 种基金the Science and Technology Planning Project of Guangzhou(No.201704020008)the Open Foundation of Hubei Key Laboratory of Theory and Application of Advanced Materials Mechanics(Wuhan University of Technology)(No.TAM202001)。
文摘Due to the multiformity and complexity of chain conformation under external flow and the challenge of systematically investigating the transient conformation and dynamic evolution process of polymer chains at the molecular level by means of present experimental techniques,a universal description of both chain conformation and dynamics with respect to continuous volume extensional flow(CVEF)is still absent.Taking into account the temperature effect,we performed dissipative particle dynamics(DPD)simulations with the particles corresponding to the repeat units of polymers over a wide temperature range and analyzed the correlation with the conformational properties of ultra-high molecular weight polyethylene/polypropylene(UHMWPE/PP)blend in response to the CVEF.With time evolution,the polymer chains become highly oriented parallel to the flow direction instead of the initial random coiling and self-aggregation.It is found that a high temperature is necessary for more substantial compactness to take place than low temperature.The low-k plateau and low-k peak in structure factor S(k)curves suggest a low degree of conformational diversity and a high degree of chain stretching.It is also concluded that the intra-molecular C-C bond interaction is the main driving force for the dynamics process of the chain conformations undergoing CVEF,where the motion of the alkyl chains is seriously restricted owing to the increase in bond interaction potential,resulting in a reduction of the difference in diffusion rates among alkyl chains.
基金supported by the National Natural Science Foundation of China(61734007)National Key Research and Development Program of China(2022YFF0706100).
文摘This work presents a novel radio frequency(RF)narrowband Si micro-electro-mechanical systems(MEMS)filter based on capacitively transduced slotted width extensional mode(WEM)resonators.The flexibility of the plate leads to multiple modes near the target frequency.The high Q-factor resonators of around 100000 enable narrow bandwidth filters with small size and simplified design.The 1-wavelength and 2-wavelength WEMs were first developed as a pair of coupled modes to form a passband.To reduce bandwidth,two plates are coupled with aλ-length coupling beam.The 79.69 MHz coupled plate filter(CPF)achieved a narrow bandwidth of 8.8 kHz,corresponding to a tiny 0.011%.The CPF exhibits an impressive 34.84 dB stopband rejection and 7.82 dB insertion loss with near-zero passband ripple.In summary,the RF MEMS filter presented in this work shows promising potential for application in RF transceiver front-ends.
文摘Horsetailing is an important feature to identify the strike-slip structure and indicates the movement mode of the fault.However,the formation mechanism of horsetailing in the extensional regime remains unclear.In this study,the formation process of horsetailing is reproduced through physical experiment,simulating the Linnan sag in the extensional regime.The results of the physical experiment demonstrates that the formation of the horsetailing in the extensional regime requires two phases of non-coaxial stretching plus the segment of the principal fault.The stretching distance in the early phase is slightly smaller than that in the middle-late phase.The segment point of the principal fault is only the intersection of the horsetailing structure and the principal fault.The horsetailing formed in the extensional regime is different from that in the strike-slip regime.For the formation of structure,the principal fault is dip-slip in the early phase and then becomes an oblique-slip in the middle-late phase,and the horsetailing is composed of the middle-late new tensile faults.The fault properties of the horsetailing in the extensional regime has important guiding significance for the longitudinal fluid migration along the fault in petroliferous basins.
文摘The Aegean area of the western Anatolian region of Turkey,controlled by the low-angle detachment normal fault system,forms an extensional province,the West Anatolian Extensional Province(WAEP).The tectonic deformation which occurred in the Miocene Period,including the Plio–Quaternary Period has created different structures in both the basement rocks and intra-basin deposits of the crust.One of these structures,high-angle normal faults,controls the supradetachment Soke-Kusadasi Basin(SKB).Within this basin,there are folds with different axes and thrust faults with a north-northwestnortheast(N,NW,NE)trend.These folds and thrust faults in the SKB deformed the sedimentary structures of intra-basin deposits.The folds and thrust faults,which caused the rotation of beddings and imbrications in the SKB,are mainly associated with the tectonic process of the low angle detachment normal fault,which affected the SKB and the Aegean part of western Anatolia.In the SKB,during the process of extensional deformation associated with primary low angle detachment normal faulting,the ramp-flat and inversion geometry observed in the basement rocks and basin deposits of the crust caused folds and thrust faults in only intra-basin deposits.In the WAEP,it is determined for the first time that the folds and thrust faults causing limited shortening deformed the Plio–Quaternary sediments.
基金support and helpful insight.This work was supported by the National Key Research and Development Program(2021YFC2902502)the National Natu-ral Science Foundation of China(21938009,91934301,22078320)+5 种基金the Major Scientific and Technological Innovation Projects in Shan-dong Province(2019JZZY010302)the Shandong Key Research and Development Program(International Cooperation Office)(2019GHZ018)the Shandong Province Postdoctoral Innovative Talents Support Plan(SDBX2020018)the External Cooperation Program of BIC,Chinese Academy of Sciences(122111KYSB20190032)Chemistry and Chemical Engineering Guangdong Laboratory(1922006)GHfund B(202107021062).
文摘This work systematically simulates the external mass transfer from/to a spherical drop and solid particle suspended in a nonlinear uniaxial extensional creeping flow.The mass transfer problem is governed by three dimensionless parameters:the viscosity ratio(λ),the Peclet number(Pe),and the nonlinear intensity of the flow(E).The existing mass transfer theory,valid for very large Peclet numbers only,is expanded,by numerical simulations,to include a much larger range of Peclet numbers(1≤Pe≤105).The simulation results show that the dimensionless mass transfer rate,expressed as the Sherwood number(5 h),agrees well with the theoretical results at the convection-dominated regime(Pe>103).Only when E>5/4,the simulated Sh for a solid sphere in the nonlinear uniaxial extensional flow is larger than theoretical results because the theory neglects the effect of the vortex formed outside the particle on the rate of mass transfer.Empirical correlations are proposed to predict the influence of the dimensionless governing parameters(λ,Pe,E)on the Sherwood number(Sh).The maximum deviations of all empirical correlations are less than 15%when compared to the numerical simulated results.
