In this paper, we propose a mathe- matical model for long reach Passive Optical Networks （PON） planning. The model consid- ers the traffic demand, user requirements and physical constraints. It can support conven- t...In this paper, we propose a mathe- matical model for long reach Passive Optical Networks （PON） planning. The model consid- ers the traffic demand, user requirements and physical constraints. It can support conven- tional star-like topologies as well as cascade PON networks. Then a two-stage evolutional algorithm is described to solve this problem. The first stage was to find a proper splitter can- didate site set, composing the outer loop. The second stage aimed to get the optimal topology when the splitter locations were selected, com- posing the internal loop. In this algorithm, the Pr/ifer sequence is used to build up a one-to-one correspondence between a PON network configuration and a chromosome. Compared with the results obtained by the enumeration method, the proposed model and algorithm are shown to be effective and accu- rate.展开更多
With the help of an extended mapping approach and a linear variable separation method,new families ofvariable separation solutions with arbitrary functions for the(3+1)-dimensional Burgers system are derived.Based ont...With the help of an extended mapping approach and a linear variable separation method,new families ofvariable separation solutions with arbitrary functions for the(3+1)-dimensional Burgers system are derived.Based onthe derived exact solutions,some novel and interesting localized coherent excitations such as embed-solitons are revealedby selecting appropriate boundary conditions and/or initial qualifications.The time evolutional properties of the novellocalized excitation are also briefly investigated.展开更多
Tourism E-commerce in the tourism long-term development of tourism, plays an important industry, as the application function on its own for the role in E-commerce, and the E-commerce tourism site as a tourist carder a...Tourism E-commerce in the tourism long-term development of tourism, plays an important industry, as the application function on its own for the role in E-commerce, and the E-commerce tourism site as a tourist carder and its function determined the functions of tourism E-commerce. Moreover, the evolution of E-commerce and tourism are closely related to the evolution of tourism websites. The evolution of E-commerce can guide our future tourism development.展开更多
Based on the statistical mechanics and technology innovation network, this paper analyzed network evolutional mechanics, and constituted its evolutional model.
This paper is a part of series works for discussing the 'auto-destruction effects' of general nonlinear evolutional equations. The blown-up of Navier-Stokes equation is discussed in references [1, 2]. Some exp...This paper is a part of series works for discussing the 'auto-destruction effects' of general nonlinear evolutional equations. The blown-up of Navier-Stokes equation is discussed in references [1, 2]. Some expansion is made in this paper, and the blown-up of order-1 or 2 models and the 'rebel travelling' of complex model of poly-order are discussed. The results indicate that 'semi-rupture' appears for some models on specific condition: the blown-up appears during the whole evolution. For fluid, however, the weakly-nonlinear model is of more artificiality and there is much room for arguing about the smoothing scheme of the numerical integral on the basis of continuous thinking and so on.展开更多
We will study global properties of evolutional Lotka-Volterra system. We assume that the predatory efficiency is a function of a character of species whose evolution obeys a quantitative genetic model. We will show th...We will study global properties of evolutional Lotka-Volterra system. We assume that the predatory efficiency is a function of a character of species whose evolution obeys a quantitative genetic model. We will show that the structure of a solution is rather different from that of a non-evolutional system. We will analytically show new ecological features of the dynamics.展开更多
Acetolactate synthase(ALS)-targeting herbicides are among the most widely used weed-control chemicals globally.Mutations in the ALS gene can confer herbicide resistance in crops,thereby allowing selective elimination ...Acetolactate synthase(ALS)-targeting herbicides are among the most widely used weed-control chemicals globally.Mutations in the ALS gene can confer herbicide resistance in crops,thereby allowing selective elimination of weeds without harming crops.Herbicide-resistant ALS alleles were initially discovered in weeds and subsequently developed through artificial mutagenesis techniques.With the advancement of CRISPR/Cas technologies,various genome-editing tools are now available to introduce these resistant alleles,as well as novel variants,into diverse crop species.Moreover,emerging methodologies,such as directed evolution,enable the generation and screening of large populations of random ALS mutants.Consequently,ALS has become one of the most extensively targeted genes in plant gene evolution.This paper provides a comprehensive overview of both conventional and recently developed strategies for ALS evolution,with particular emphasis on CRISPR/Cas-based genome editing and directed evolution.Future perspectives on technological application are also discussed.By advancing our understanding of herbicide-resistant ALS allele development for crop improvement,these methodologies may also pave the way for their application to the evolution of other agronomically important genes.展开更多
A simplified data set with 8°×8° grid system in a region of 32°S--32°N from 1951 to 1979 for the elements of sea surface temperature (SST), zonal wind at sea level (U), sea level pressure (SLP...A simplified data set with 8°×8° grid system in a region of 32°S--32°N from 1951 to 1979 for the elements of sea surface temperature (SST), zonal wind at sea level (U), sea level pressure (SLP) and total cloud amount (CA) is made from the COADS. The oscillation components with periods of 2 years (QBO), 3.5 years (SO) and 5.5 years (FYO) in interannual low-frequency oscillations have been studied by using the methods of extended EOF (EEOF) and lag correlation analysis with the oscillational components of SST in the equator of eastern Pacific as the reference element. In our paper, the relationship between oscilla- tion components and occurrence of El Nino is also investigated.展开更多
NiFe-layered double hydroxides(NiFe-LDHs)are among the most promising earth-abundant electrocatalysts for the oxygen evolution reaction(OER)in alkaline media.However,their practical application is hindered by intrinsi...NiFe-layered double hydroxides(NiFe-LDHs)are among the most promising earth-abundant electrocatalysts for the oxygen evolution reaction(OER)in alkaline media.However,their practical application is hindered by intrinsic activity limitations and poor stability,primarily due to the asymmetric adsorption of oxygen intermediates.To overcome this,the binding strength must be synergistically tuned to a moderate level to optimize catalytic performance.Here,we engineered NiFeCoCr LDH through Co doping to enhance electrical conductivity and controlled Cr leaching to introduce cationic vacancies for modulating intermediate binding strength in NiFe LDH.X-ray absorption near-edge structure and extended X-ray absorption fine structure analyses reveal that NiFe-LDH with Co doping and Cr vacancies modulates the Ni oxidation state and local coordination environment,leading to a balanced electronic structure and enhanced structural complexity around the Ni sites.Additionally,these vacancies can trap OH^(-)/H_(2)O species,which can serve as a reservoir for OH^(-) transfer,facilitating the rapid formation of OER intermediates and enhancing catalytic performance at high current densities.As a result,V_(Cr)-NiFeCo LDH achieves 1.6 A cm^(-2)current density at 1.7 V vs.RHE while maintaining stable operation for over 1000 h at 500 mA cm^(-2).Density functional theory(DFT)calculations validate the synergistic effects of Co doping and Cr-induced vacancies on intermediate binding energies and improved OER kinetics.Overall,this work presents a rational design strategy to simultaneously enhance the activity and durability of NiFe-based OER catalysts for their application in high-performance alkaline water electrolysis.展开更多
Linsangs(Prionodon Horsfield,1822)are small,arboreal feliform carnivorans that live in the tropical and subtropical forests of Southeast Asia and southern China.Several lines of morphological evidence from the soft ti...Linsangs(Prionodon Horsfield,1822)are small,arboreal feliform carnivorans that live in the tropical and subtropical forests of Southeast Asia and southern China.Several lines of morphological evidence from the soft tissues,dentition,and basicranium support their placement in either Prionodontinae or Viverrinae of Viverridae.However,molecular evidence has not only excluded the linsangs from Viverridae but also established that they constitute a monogeneric family Prionodontidae sister to Felidae.For that reason,the examination of the skull osteology of linsangs and related taxa is necessary to better understand how morphological and molecular data-particularly morphology-have contributed to the reconstruction of the Feliformia phylogeny.During the summer field season in July of 2020,we stumbled across the carcass of a spotted linsang(P.pardicolor)in a karst cave on the outskirts of Chongzuo City.To contribute to the knowledge about the morphology of this enigmatic feliform carnivoran,we present a preliminary description of the exterior skull osteology of P.pardicolor.The craniodental morphology provides strong evidence for a closer phylogenetic relationship between P.pardicolor and Viverrinae.However,since both morphological and molecular approaches have inherent limitations,caution is urged when inferring feliform phylogeny based on either discipline alone.展开更多
A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and...A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and Mo2S3 nanoparticles were integrated at the edges of Co3O4 nanosheets,creating a rich,heterogeneous interface that enhances the synergistic effects of each component.In an alkaline electrolyte,the synthesized CoMoNiO-S/NF-110 exhibited superior electrocatalytic performance for oxygen evolution reaction(OER),achieving current densities of 100 and 200 mA·cm^(-2) with low overpotentials of 199.4 and 224.4 mV,respectively,outperforming RuO2 and several high-performance Mo and Ni-based catalysts.This excellent performance is attributed to the rich interface formed between the components and active sites exposed by the defect structure.展开更多
Combining the phase-field method and the moving boundary method,a three-dimensional phase-field simulation was conducted for the growth and grain evolution of Ti films deposited by physical vapor deposition under diff...Combining the phase-field method and the moving boundary method,a three-dimensional phase-field simulation was conducted for the growth and grain evolution of Ti films deposited by physical vapor deposition under different deposition rates and grain orientations.The evolution of grain morphology and grain orientation was also taken into consideration.Simulation results show that at lower deposition rates,the surface of the formed Ti film exhibits a distinct oriented texture structure.The surface roughness of the Ti film is positively correlated with the grain misorientation.Moreover,the surface roughness obtained from the simulation is in good agreement with the experiment results.展开更多
The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the...The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the TiNb binary alloy system during spinodal decomposition,and then the formation mechanism of core-shell structure was revealed.In addition,the influences of initial temperature gradient,average temperature,and initial concentration distribution of the system on the core-shell structure were investigated.Results show that the initial concentration gradient is the key factor for forming the core-shell structure.Besides,larger initial temperature gradient and higher average temperature can promote the formation of core-shell structure,which can be stabilized by adjusting the initial concentration distribution of the Nb-rich region in TiNb binary alloy.As a theoretical basis,this research provides a novel and simple strategy for the preparation of TiNb-based alloys and other materials with peculiar core-shell structures and desirable mechanical and physical properties.展开更多
The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecul...The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecules and{[Co2(BINDI)(DMA)_(2)]·DMA}_(n)(Co-MOF,H4BINDI=N,N'-bis(5-isophthalic acid)naphthalenediimide,DMA=N,N-dimethylacetamide)was synthesized via a one-pot method,leveragingπ-πinteractions between pyrene and Co-MOF to modulate electrical conductivity.Results demonstrate that the Py@Co-MOF catalyst exhibited significantly enhanced OER performance compared to pure Co-MOF or pyrene-based electrodes,achieving an overpotential of 246 mV at a current density of 10 mA·cm^(-2) along with excellent stability.Density functional theory(DFT)calculations reveal that the formation of O*in the second step is the rate-determining step(RDS)during the OER process on Co-MOF,with an energy barrier of 0.85 eV due to the weak adsorption affinity of the OH*intermediate for Co sites.CCDC:2419276.展开更多
Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durabili...Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durability,and corrosion resistance.These metals have body-centered cubic crystal structure,characterized by limited slip systems and impeded dislocation motion,resulting in significant low-temperature brittleness,which poses challenges for the conventional processing.Additive manufacturing technique provides an innovative approach,enabling the production of intricate parts without molds,which significantly improves the efficiency of material usage.This review provides a comprehensive overview of the advancements in additive manufacturing techniques for the production of refractory metals,such as W,Ta,Mo,and Nb,particularly the laser powder bed fusion.In this review,the influence mechanisms of key process parameters(laser power,scan strategy,and powder characteristics)on the evolution of material microstructure,the formation of metallurgical defects,and mechanical properties were discussed.Generally,optimizing powder characteristics,such as sphericity,implementing substrate preheating,and formulating alloying strategies can significantly improve the densification and crack resistance of manufactured parts.Meanwhile,strictly controlling the oxygen impurity content and optimizing the energy density input are also the key factors to achieve the simultaneous improvement in strength and ductility of refractory metals.Although additive manufacturing technique provides an innovative solution for processing refractory metals,critical issues,such as residual stress control,microstructure and performance anisotropy,and process stability,still need to be addressed.This review not only provides a theoretical basis for the additive manufacturing of high-performance refractory metals,but also proposes forward-looking directions for their industrial application.展开更多
A multi-physics approach was used to quantify the effect of process parameters (laser power, scanning speed, hatch spacing, and scanning strategy) on the thermal history and corresponding microstructure evolution of T...A multi-physics approach was used to quantify the effect of process parameters (laser power, scanning speed, hatch spacing, and scanning strategy) on the thermal history and corresponding microstructure evolution of Ti-25Nb (at%) alloy during the dual-track selective laser melting (SLM) process. Simulation results reveal that during the dual-track SLM process, increasing laser power results in greater thermal accumulation, leading to a molten pool of larger volume and coarser grains. Reducing scanning speed enhances remelting and promotes cellular growth at the top of molten pool, whereas faster scanning speed leads to rougher melt tracks and finer grains. Notably, hatch spacing significantly influences the molten pool dimensions and microstructures, and smaller hatch spacing promotes remelting. Furthermore, the orientations of grains in the second track during zigzag scanning differ markedly from those in the first track. More importantly, compared with those after the first track, both the temperature gradient and cooling rate at the boundaries of remelting molten pool are reduced after the second track scanning, resulting in slower interface velocity and significant change in solidification microstructure. This research provides a theoretical foundation for controlling non-equilibrium microstructure and offering novel insights into the optimization of SLM process parameters of titanium alloys.展开更多
The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor ...The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.展开更多
This paper constructs a dynamic conflict model that considers Decision Makers'(DMs)evolutional attitude using the option prioritization.The proposed evolutional attitude approach is based on the framework of the G...This paper constructs a dynamic conflict model that considers Decision Makers'(DMs)evolutional attitude using the option prioritization.The proposed evolutional attitude approach is based on the framework of the Graph Model for Conflict Resolution(GMCR).Compared with the existing state-based preference,the option prioritization is a more convenient and efficient approach to analyze larger models with consideration of the evolutional attitude,which exists broadly in the evolutional conflicts in reallife.This study reveals how the evolutional attitude of a DM succeeds in the overall evolution of conflict.The analysis unfolds that DMs change their attitude(s)consequent upon the changes in DMs and options available to them as conflict evolves from one level to the next.The changes in attitude of DMs during dynamic conflict situation have substantial effects on the equilibrium outcomes of a conflict.The proposed evaluation attitude-based approach is employed to analyze the conflict between the Punjab Government(G)and Heritage Campaigner and the Public(P)in Pakistan that appeared due to the inappropriate design,planning,and construction of an urban transport system project in Lahore,Pakistan.The present study demonstrates the modeling procedure of a two-level evolutional attitude-based conflict analysis.The results of the stability analysis reveal that improper(negative)attitude may result in undesirable and unexpected consequences,such as project temporalities and delays.This research provides a foundation for future research in urban project planning that employs strategic ways to avoid disputes caused by DMs'attitudes.展开更多
While methodology for determining the mode of evolution in coding sequences has been well established,evaluation of adaptation events in emerging types of phenotype data needs further development.Here,we propose an an...While methodology for determining the mode of evolution in coding sequences has been well established,evaluation of adaptation events in emerging types of phenotype data needs further development.Here,we propose an analysis framework(expression variance decomposition,EVaDe)for comparative single-cell expression data based on phenotypic evolution theory.After decomposing the gene expression variance into separate components,we use two strategies to identify genes exhibiting large between-taxon expression divergence and small within-cell-type expression noise in certain cell types,attributing this pattern to putative adaptive evolution.In a dataset of primate prefrontal cortex,we find that such humanspecific key genes enrich with neurodevelopment-related functions,while most other genes exhibit neutral evolution patterns.Specific neuron types are found to harbor more of these key genes than other cell types,thus likely to have experienced more extensive adaptation.Reassuringly,at the molecular sequence level,the key genes are significantly associated with the rapidly evolving conserved non-coding elements.An additional case analysis comparing the naked mole-rat(NMR)with the mouse suggests that innateimmunity-related genes and cell types have undergone putative expression adaptation in NMR.Overall,the EVaDe framework may effectively probe adaptive evolution mode in single-cell expression data.展开更多
The augmented evolution equation is established under the framework of the Variation Evolving Method(VEM)that seeks optimal solutions by solving the transformed Initial-Value Problems(IVPs).To improve the numerical pe...The augmented evolution equation is established under the framework of the Variation Evolving Method(VEM)that seeks optimal solutions by solving the transformed Initial-Value Problems(IVPs).To improve the numerical performance,its compact form is developed herein.Through replacing the states and costates variation evolution with that of the controls,the dimension-reduced Evolution Partial Differential Equation(EPDE)only solves the control variables along the variation time to get the optimal solution,and the initial conditions for the definite solution may be arbitrary.With this equation,the scale of the resulting IVPs,obtained via the semi-discrete method,is significantly reduced and they may be solved with common Ordinary Differential Equation(ODE)integration methods conveniently.Meanwhile,the state and the costate dynamics share consistent stability in the numerical computation and this avoids the intrinsic numerical difficulty as in the indirect methods.Numerical examples are solved and it is shown that the compact form evolution equation outperforms the primary form in the precision,and the efficiency may be higher for the dense discretization.Actually,it is uncovered that the compact form of the augmented evolution equation is a continuous realization of the Newton type iteration mechanism.展开更多
基金supported by National High Technology Research and Development Program of China under Grant No.2011AA01A104National 973 Program underGrant No. 2013CB329204National Natural Science Foundation of China under Grant No.61100206
文摘In this paper, we propose a mathe- matical model for long reach Passive Optical Networks （PON） planning. The model consid- ers the traffic demand, user requirements and physical constraints. It can support conven- tional star-like topologies as well as cascade PON networks. Then a two-stage evolutional algorithm is described to solve this problem. The first stage was to find a proper splitter can- didate site set, composing the outer loop. The second stage aimed to get the optimal topology when the splitter locations were selected, com- posing the internal loop. In this algorithm, the Pr/ifer sequence is used to build up a one-to-one correspondence between a PON network configuration and a chromosome. Compared with the results obtained by the enumeration method, the proposed model and algorithm are shown to be effective and accu- rate.
基金the Natural Science Foundation of Zhejiang Province under Grant Nos.Y604106 and Y606181the Foundation of New Century"151 Talent Engineering"of Zhejiang Province+1 种基金the Scientific Research Foundation of Key Discipline of Zhejiang Provincethe Natural Science Foundation of Zhejiang Lishui University under Grant No KZ06006
文摘With the help of an extended mapping approach and a linear variable separation method,new families ofvariable separation solutions with arbitrary functions for the(3+1)-dimensional Burgers system are derived.Based onthe derived exact solutions,some novel and interesting localized coherent excitations such as embed-solitons are revealedby selecting appropriate boundary conditions and/or initial qualifications.The time evolutional properties of the novellocalized excitation are also briefly investigated.
文摘Tourism E-commerce in the tourism long-term development of tourism, plays an important industry, as the application function on its own for the role in E-commerce, and the E-commerce tourism site as a tourist carder and its function determined the functions of tourism E-commerce. Moreover, the evolution of E-commerce and tourism are closely related to the evolution of tourism websites. The evolution of E-commerce can guide our future tourism development.
文摘Based on the statistical mechanics and technology innovation network, this paper analyzed network evolutional mechanics, and constituted its evolutional model.
文摘This paper is a part of series works for discussing the 'auto-destruction effects' of general nonlinear evolutional equations. The blown-up of Navier-Stokes equation is discussed in references [1, 2]. Some expansion is made in this paper, and the blown-up of order-1 or 2 models and the 'rebel travelling' of complex model of poly-order are discussed. The results indicate that 'semi-rupture' appears for some models on specific condition: the blown-up appears during the whole evolution. For fluid, however, the weakly-nonlinear model is of more artificiality and there is much room for arguing about the smoothing scheme of the numerical integral on the basis of continuous thinking and so on.
文摘We will study global properties of evolutional Lotka-Volterra system. We assume that the predatory efficiency is a function of a character of species whose evolution obeys a quantitative genetic model. We will show that the structure of a solution is rather different from that of a non-evolutional system. We will analytically show new ecological features of the dynamics.
基金Guangdong Basic and Applied Basic Research Foundation(2023B1515120050,2023A1515110529 and 2024A1515012454)Shenzhen Science and Technology Program(JCYJ20230807145759008 and KJZD20240903100206009).
文摘Acetolactate synthase(ALS)-targeting herbicides are among the most widely used weed-control chemicals globally.Mutations in the ALS gene can confer herbicide resistance in crops,thereby allowing selective elimination of weeds without harming crops.Herbicide-resistant ALS alleles were initially discovered in weeds and subsequently developed through artificial mutagenesis techniques.With the advancement of CRISPR/Cas technologies,various genome-editing tools are now available to introduce these resistant alleles,as well as novel variants,into diverse crop species.Moreover,emerging methodologies,such as directed evolution,enable the generation and screening of large populations of random ALS mutants.Consequently,ALS has become one of the most extensively targeted genes in plant gene evolution.This paper provides a comprehensive overview of both conventional and recently developed strategies for ALS evolution,with particular emphasis on CRISPR/Cas-based genome editing and directed evolution.Future perspectives on technological application are also discussed.By advancing our understanding of herbicide-resistant ALS allele development for crop improvement,these methodologies may also pave the way for their application to the evolution of other agronomically important genes.
文摘A simplified data set with 8°×8° grid system in a region of 32°S--32°N from 1951 to 1979 for the elements of sea surface temperature (SST), zonal wind at sea level (U), sea level pressure (SLP) and total cloud amount (CA) is made from the COADS. The oscillation components with periods of 2 years (QBO), 3.5 years (SO) and 5.5 years (FYO) in interannual low-frequency oscillations have been studied by using the methods of extended EOF (EEOF) and lag correlation analysis with the oscillational components of SST in the equator of eastern Pacific as the reference element. In our paper, the relationship between oscilla- tion components and occurrence of El Nino is also investigated.
基金supported by the Natural Science Foundation of China Grant No.52272289 and 5240223,and JSPS(Japan Society for the Promotion of Science)of Grant No.22K19088,23H00313,24H02202,and 24H02205。
文摘NiFe-layered double hydroxides(NiFe-LDHs)are among the most promising earth-abundant electrocatalysts for the oxygen evolution reaction(OER)in alkaline media.However,their practical application is hindered by intrinsic activity limitations and poor stability,primarily due to the asymmetric adsorption of oxygen intermediates.To overcome this,the binding strength must be synergistically tuned to a moderate level to optimize catalytic performance.Here,we engineered NiFeCoCr LDH through Co doping to enhance electrical conductivity and controlled Cr leaching to introduce cationic vacancies for modulating intermediate binding strength in NiFe LDH.X-ray absorption near-edge structure and extended X-ray absorption fine structure analyses reveal that NiFe-LDH with Co doping and Cr vacancies modulates the Ni oxidation state and local coordination environment,leading to a balanced electronic structure and enhanced structural complexity around the Ni sites.Additionally,these vacancies can trap OH^(-)/H_(2)O species,which can serve as a reservoir for OH^(-) transfer,facilitating the rapid formation of OER intermediates and enhancing catalytic performance at high current densities.As a result,V_(Cr)-NiFeCo LDH achieves 1.6 A cm^(-2)current density at 1.7 V vs.RHE while maintaining stable operation for over 1000 h at 500 mA cm^(-2).Density functional theory(DFT)calculations validate the synergistic effects of Co doping and Cr-induced vacancies on intermediate binding energies and improved OER kinetics.Overall,this work presents a rational design strategy to simultaneously enhance the activity and durability of NiFe-based OER catalysts for their application in high-performance alkaline water electrolysis.
文摘Linsangs(Prionodon Horsfield,1822)are small,arboreal feliform carnivorans that live in the tropical and subtropical forests of Southeast Asia and southern China.Several lines of morphological evidence from the soft tissues,dentition,and basicranium support their placement in either Prionodontinae or Viverrinae of Viverridae.However,molecular evidence has not only excluded the linsangs from Viverridae but also established that they constitute a monogeneric family Prionodontidae sister to Felidae.For that reason,the examination of the skull osteology of linsangs and related taxa is necessary to better understand how morphological and molecular data-particularly morphology-have contributed to the reconstruction of the Feliformia phylogeny.During the summer field season in July of 2020,we stumbled across the carcass of a spotted linsang(P.pardicolor)in a karst cave on the outskirts of Chongzuo City.To contribute to the knowledge about the morphology of this enigmatic feliform carnivoran,we present a preliminary description of the exterior skull osteology of P.pardicolor.The craniodental morphology provides strong evidence for a closer phylogenetic relationship between P.pardicolor and Viverrinae.However,since both morphological and molecular approaches have inherent limitations,caution is urged when inferring feliform phylogeny based on either discipline alone.
文摘A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and Mo2S3 nanoparticles were integrated at the edges of Co3O4 nanosheets,creating a rich,heterogeneous interface that enhances the synergistic effects of each component.In an alkaline electrolyte,the synthesized CoMoNiO-S/NF-110 exhibited superior electrocatalytic performance for oxygen evolution reaction(OER),achieving current densities of 100 and 200 mA·cm^(-2) with low overpotentials of 199.4 and 224.4 mV,respectively,outperforming RuO2 and several high-performance Mo and Ni-based catalysts.This excellent performance is attributed to the rich interface formed between the components and active sites exposed by the defect structure.
基金National MCF Energy R&D Program of China(2018YFE0306100)Natural Science Foundation of Hunan Province for Distinguished Young Scholars(2021JJ10062)+1 种基金National Natural Science Foundation of China(52101028)China Postdoctoral Science Foundation(2021M703628)。
文摘Combining the phase-field method and the moving boundary method,a three-dimensional phase-field simulation was conducted for the growth and grain evolution of Ti films deposited by physical vapor deposition under different deposition rates and grain orientations.The evolution of grain morphology and grain orientation was also taken into consideration.Simulation results show that at lower deposition rates,the surface of the formed Ti film exhibits a distinct oriented texture structure.The surface roughness of the Ti film is positively correlated with the grain misorientation.Moreover,the surface roughness obtained from the simulation is in good agreement with the experiment results.
基金National Natural Science Foundation of China(12372152)Guangdong Basic and Applied Basic Research Foundation(2023A1515011819,2024A1515012469)Shandong Provincial Natural Science Foundation(ZR2023MA058)。
文摘The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the TiNb binary alloy system during spinodal decomposition,and then the formation mechanism of core-shell structure was revealed.In addition,the influences of initial temperature gradient,average temperature,and initial concentration distribution of the system on the core-shell structure were investigated.Results show that the initial concentration gradient is the key factor for forming the core-shell structure.Besides,larger initial temperature gradient and higher average temperature can promote the formation of core-shell structure,which can be stabilized by adjusting the initial concentration distribution of the Nb-rich region in TiNb binary alloy.As a theoretical basis,this research provides a novel and simple strategy for the preparation of TiNb-based alloys and other materials with peculiar core-shell structures and desirable mechanical and physical properties.
文摘The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecules and{[Co2(BINDI)(DMA)_(2)]·DMA}_(n)(Co-MOF,H4BINDI=N,N'-bis(5-isophthalic acid)naphthalenediimide,DMA=N,N-dimethylacetamide)was synthesized via a one-pot method,leveragingπ-πinteractions between pyrene and Co-MOF to modulate electrical conductivity.Results demonstrate that the Py@Co-MOF catalyst exhibited significantly enhanced OER performance compared to pure Co-MOF or pyrene-based electrodes,achieving an overpotential of 246 mV at a current density of 10 mA·cm^(-2) along with excellent stability.Density functional theory(DFT)calculations reveal that the formation of O*in the second step is the rate-determining step(RDS)during the OER process on Co-MOF,with an energy barrier of 0.85 eV due to the weak adsorption affinity of the OH*intermediate for Co sites.CCDC:2419276.
基金National MCF Energy R&D Program(2024YFE03260300)。
文摘Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durability,and corrosion resistance.These metals have body-centered cubic crystal structure,characterized by limited slip systems and impeded dislocation motion,resulting in significant low-temperature brittleness,which poses challenges for the conventional processing.Additive manufacturing technique provides an innovative approach,enabling the production of intricate parts without molds,which significantly improves the efficiency of material usage.This review provides a comprehensive overview of the advancements in additive manufacturing techniques for the production of refractory metals,such as W,Ta,Mo,and Nb,particularly the laser powder bed fusion.In this review,the influence mechanisms of key process parameters(laser power,scan strategy,and powder characteristics)on the evolution of material microstructure,the formation of metallurgical defects,and mechanical properties were discussed.Generally,optimizing powder characteristics,such as sphericity,implementing substrate preheating,and formulating alloying strategies can significantly improve the densification and crack resistance of manufactured parts.Meanwhile,strictly controlling the oxygen impurity content and optimizing the energy density input are also the key factors to achieve the simultaneous improvement in strength and ductility of refractory metals.Although additive manufacturing technique provides an innovative solution for processing refractory metals,critical issues,such as residual stress control,microstructure and performance anisotropy,and process stability,still need to be addressed.This review not only provides a theoretical basis for the additive manufacturing of high-performance refractory metals,but also proposes forward-looking directions for their industrial application.
基金Guangdong Basic and Applied Basic Research Foundation (2024A1515011873)Shenzhen Basic Research Project (JCYJ20241202123504007)Shenzhen Science and Technology Innovation Commission (KJZD20240903101400001, KJZD20240903102006009)。
文摘A multi-physics approach was used to quantify the effect of process parameters (laser power, scanning speed, hatch spacing, and scanning strategy) on the thermal history and corresponding microstructure evolution of Ti-25Nb (at%) alloy during the dual-track selective laser melting (SLM) process. Simulation results reveal that during the dual-track SLM process, increasing laser power results in greater thermal accumulation, leading to a molten pool of larger volume and coarser grains. Reducing scanning speed enhances remelting and promotes cellular growth at the top of molten pool, whereas faster scanning speed leads to rougher melt tracks and finer grains. Notably, hatch spacing significantly influences the molten pool dimensions and microstructures, and smaller hatch spacing promotes remelting. Furthermore, the orientations of grains in the second track during zigzag scanning differ markedly from those in the first track. More importantly, compared with those after the first track, both the temperature gradient and cooling rate at the boundaries of remelting molten pool are reduced after the second track scanning, resulting in slower interface velocity and significant change in solidification microstructure. This research provides a theoretical foundation for controlling non-equilibrium microstructure and offering novel insights into the optimization of SLM process parameters of titanium alloys.
文摘The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.
基金the National Natural Science Foundation of China(71471087,71071076,and 61673209).
文摘This paper constructs a dynamic conflict model that considers Decision Makers'(DMs)evolutional attitude using the option prioritization.The proposed evolutional attitude approach is based on the framework of the Graph Model for Conflict Resolution(GMCR).Compared with the existing state-based preference,the option prioritization is a more convenient and efficient approach to analyze larger models with consideration of the evolutional attitude,which exists broadly in the evolutional conflicts in reallife.This study reveals how the evolutional attitude of a DM succeeds in the overall evolution of conflict.The analysis unfolds that DMs change their attitude(s)consequent upon the changes in DMs and options available to them as conflict evolves from one level to the next.The changes in attitude of DMs during dynamic conflict situation have substantial effects on the equilibrium outcomes of a conflict.The proposed evaluation attitude-based approach is employed to analyze the conflict between the Punjab Government(G)and Heritage Campaigner and the Public(P)in Pakistan that appeared due to the inappropriate design,planning,and construction of an urban transport system project in Lahore,Pakistan.The present study demonstrates the modeling procedure of a two-level evolutional attitude-based conflict analysis.The results of the stability analysis reveal that improper(negative)attitude may result in undesirable and unexpected consequences,such as project temporalities and delays.This research provides a foundation for future research in urban project planning that employs strategic ways to avoid disputes caused by DMs'attitudes.
文摘While methodology for determining the mode of evolution in coding sequences has been well established,evaluation of adaptation events in emerging types of phenotype data needs further development.Here,we propose an analysis framework(expression variance decomposition,EVaDe)for comparative single-cell expression data based on phenotypic evolution theory.After decomposing the gene expression variance into separate components,we use two strategies to identify genes exhibiting large between-taxon expression divergence and small within-cell-type expression noise in certain cell types,attributing this pattern to putative adaptive evolution.In a dataset of primate prefrontal cortex,we find that such humanspecific key genes enrich with neurodevelopment-related functions,while most other genes exhibit neutral evolution patterns.Specific neuron types are found to harbor more of these key genes than other cell types,thus likely to have experienced more extensive adaptation.Reassuringly,at the molecular sequence level,the key genes are significantly associated with the rapidly evolving conserved non-coding elements.An additional case analysis comparing the naked mole-rat(NMR)with the mouse suggests that innateimmunity-related genes and cell types have undergone putative expression adaptation in NMR.Overall,the EVaDe framework may effectively probe adaptive evolution mode in single-cell expression data.
基金supported by the National Nature Science Foundation of China under Grant No.11902332。
文摘The augmented evolution equation is established under the framework of the Variation Evolving Method(VEM)that seeks optimal solutions by solving the transformed Initial-Value Problems(IVPs).To improve the numerical performance,its compact form is developed herein.Through replacing the states and costates variation evolution with that of the controls,the dimension-reduced Evolution Partial Differential Equation(EPDE)only solves the control variables along the variation time to get the optimal solution,and the initial conditions for the definite solution may be arbitrary.With this equation,the scale of the resulting IVPs,obtained via the semi-discrete method,is significantly reduced and they may be solved with common Ordinary Differential Equation(ODE)integration methods conveniently.Meanwhile,the state and the costate dynamics share consistent stability in the numerical computation and this avoids the intrinsic numerical difficulty as in the indirect methods.Numerical examples are solved and it is shown that the compact form evolution equation outperforms the primary form in the precision,and the efficiency may be higher for the dense discretization.Actually,it is uncovered that the compact form of the augmented evolution equation is a continuous realization of the Newton type iteration mechanism.
