Accurate assessment of coal brittleness is crucial in the design of coal seam drilling and underground coal mining operations.This study proposes a method for evaluating the brittleness of gas-bearing coal based on a ...Accurate assessment of coal brittleness is crucial in the design of coal seam drilling and underground coal mining operations.This study proposes a method for evaluating the brittleness of gas-bearing coal based on a statistical damage constitutive model and energy evolution mechanisms.Initially,integrating the principle of effective stress and the Hoek-Brown criterion,a statistical damage constitutive model for gas-bearing coal is established and validated through triaxial compression tests under different gas pressures to verify its accuracy and applicability.Subsequently,employing energy evolution mechanism,two energy characteristic parameters(elastic energy proportion and dissipated energy proportion)are analyzed.Based on the damage stress thresholds,the damage evolution characteristics of gas bearing coal were explored.Finally,by integrating energy characteristic parameters with damage parameters,a novel brittleness index is proposed.The results demonstrate that the theoretical curves derived from the statistical damage constitutive model closely align with the test curves,accurately reflecting the stress−strain characteristics of gas-bearing coal and revealing the stress drop and softening characteristics of coal in the post-peak stage.The shape parameter and scale parameter represent the brittleness and macroscopic strength of the coal,respectively.As gas pressure increases from 1 to 5 MPa,the shape parameter and the scale parameter decrease by 22.18%and 60.45%,respectively,indicating a reduction in both brittleness and strength of the coal.Parameters such as maximum damage rate and peak elastic energy storage limit positively correlate with coal brittleness.The brittleness index effectively captures the brittleness characteristics and reveals a decrease in brittleness and an increase in sensitivity to plastic deformation under higher gas pressure conditions.展开更多
The Inner Mongolia mining area in western China are characterized by the development of numerous penetrating fissures,resulting in severe land damage.It is significant to reveal the underlying evolution mechanism and ...The Inner Mongolia mining area in western China are characterized by the development of numerous penetrating fissures,resulting in severe land damage.It is significant to reveal the underlying evolution mechanism and identify treatment timing for restoring the ecological environment.The Guanbanwusu mining subsidence area in Inner Mongolia,China was selected as the research case for this study.The evolution mechanism of different penetrating fissures was revealed by field measurement,physical simulation and theoretical analysis.The treatment timing prediction model for the mining subsidence area was established based on the enhanced Weibull time function.The results show that the ground fissures are mainly step-type and collapse-type fissures.The breaking form of overlying strata determines their vertical opening and horizontal dislocation.The high mining intensity in the western mining area results in a shortened period of dynamic fissure expansion and reduced closure degree.The damage extent of the overlying strata exhibits zoning characteristics both vertically and horizontally.The relative standard deviation of the prediction model is only 3.7%.Concurrently,the prediction model is employed to determine the optimal timing for treatment in the study area,estimated to be 259 days.Subsequently,once this threshold is reached,the study area undergoes treatment and restoration of its e cological environment.This study addresses the knowledge gap in this field by highlighting the interconnectedness between rock strata structure and evolution mechanism of penetrating fissures,thereby providing a method for determining the treatment timing in mining subsidence areas.展开更多
Explosion welding was carried out on the basis of vacuum hot melt W/CuCrZr composite plate.Metallurgical microscope,scanning electron microscope and energy dispersive X-ray spectroscope were used to observe the micros...Explosion welding was carried out on the basis of vacuum hot melt W/CuCrZr composite plate.Metallurgical microscope,scanning electron microscope and energy dispersive X-ray spectroscope were used to observe the microscopic morphology of the bonding interface.At the same time,combined with finite element calculations,the evolution mechanism of the interface of the hot melt explosion welded W/CuCrZr composite plate was explored.The results show that the interface bonding of the hot melt explosion welded W/CuCrZr composite plate is good and there is a cross-melting zone with 3–8μm in thickness,but cracks are developed on the W side.The numerical simulation reproduces the changes of pressure,stress,strain and internal energy at the bonding interface in the process of hot melt explosion welding.The location of the crack generated in the experiment coincides with the high stress position calculated by numerical simulation.The high pressure and high temperature near the hot melt explosion welding interface further promote the bonding of the interface.展开更多
This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing...This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing,logging calculation,and seismic inversion technology,we obtained the current insitu stress characteristics of a single well and rock mechanical parameters.Simultaneously,significant controlling factors of rock mechanical properties were analyzed.Subsequently,by coupling hydraulic fracturing physical experiments with finite element numerical simulation,three different fracturing models were configured:single-cluster,double-cluster,and triple-cluster perforations.Combined with acoustic emission technology,the fracture initiation mode and evolution characteristics during the loading process were determined.The results indicate the following findings:(1)The extension direction and length of the fracture are significantly controlled by the direction of the maximum horizontal principal stress.(2)Areas with poor cementation and compactness exhibit complex fracture morphology,prone to generating network fractures.(3)The interlayer development of fracturing fractures is controlled by the strata occurrence.(4)Increasing the displacement of fracturing fluid enlarges the fracturing fracture length and height.This research provides theoretical support and effective guidance for hydraulic fracturing design in tight oil and gas reservoirs.展开更多
The object of this article is to investigate the energy evolution mechanism and failure criteria of cross-jointed samples containing an opening during deformation and failure based on the uniaxial compression test and...The object of this article is to investigate the energy evolution mechanism and failure criteria of cross-jointed samples containing an opening during deformation and failure based on the uniaxial compression test and rock energy principle.The results show that the energy evolution characteristics of the samples correspond to a typical progressive damage mode.The peak total energy,peak elastic energy,and total input energy of the samples all first decrease and then increase with an increase of half of the included angle,reaching their minimum values when this angle is 45°,while the dissipated energy generally increases with this angle.The existence of the opening and cross joints can obviously weaken the energy storage capacity of the rock,and the change in the included angle of the cross joint has a great influence on the elastic energy ratio of the sample before the peak stress,which leads to some differences in the distribution laws of the input energy.The continuous change and the subsequent sharp change in the rate of change in the energy consumption ratio can be used as the criteria of the crack initiation and propagation and the unstable failure of the sample,respectively.展开更多
Prognostics and health management （PHM） significantly improves system availability and reliability, and reduces the cost of system operations. Design for testability （DFT） developed concurrently with system design...Prognostics and health management （PHM） significantly improves system availability and reliability, and reduces the cost of system operations. Design for testability （DFT） developed concurrently with system design is an important way to improve PHM capability. Testability modeling and analysis are the foundation of DFT. This paper proposes a novel approach of testability modeling and analysis based on failure evolution mechanisms. At the component level, the fault progression-related information of each unit under test （UUT） in a system is obtained by means of failure modes, evolution mechanisms, effects and criticality analysis （FMEMECA）, and then the failure-symptom dependency can be generated. At the system level, the dynamic attributes of UUTs are assigned by using the bond graph methodology, and then the symptom-test dependency can be obtained by means of the functional flow method. Based on the failure-symptom and symptom-test dependencies, testability analysis for PHM systems can be realized. A shunt motor is used to verify the application of the approach proposed in this paper. Experimental results show that this approach is able to be applied to testability modeling and analysis for PHM systems very well, and the analysis results can provide a guide for engineers to design for testability in order to improve PHM performance.展开更多
The test selection and optimization （TSO） can improve the abilities of fault diagnosis, prognosis and health-state evalua- tion for prognostics and health management （PHM） systems. Traditionally, TSO mainly focuse...The test selection and optimization （TSO） can improve the abilities of fault diagnosis, prognosis and health-state evalua- tion for prognostics and health management （PHM） systems. Traditionally, TSO mainly focuses on fault detection and isolation, but they cannot provide an effective guide for the design for testability （DFT） to improve the PHM performance level. To solve the problem, a model of TSO for PHM systems is proposed. Firstly, through integrating the characteristics of fault severity and propa- gation time, and analyzing the test timing and sensitivity, a testability model based on failure evolution mechanism model （FEMM） for PHM systems is built up. This model describes the fault evolution- test dependency using the fault-symptom parameter matrix and symptom parameter-test matrix. Secondly, a novel method of in- herent testability analysis for PHM systems is developed based on the above information. Having completed the analysis, a TSO model, whose objective is to maximize fault trackability and mini- mize the test cost, is proposed through inherent testability analysis results, and an adaptive simulated annealing genetic algorithm （ASAGA） is introduced to solve the TSO problem. Finally, a case of a centrifugal pump system is used to verify the feasibility and effectiveness of the proposed models and methods. The results show that the proposed technology is important for PHM systems to select and optimize the test set in order to improve their performance level.展开更多
The problem of rural development arises from the evolution of rural regional system.It is urgent to deepen the research on the evolution process and mechanism of rural regional system.However,there are relatively few ...The problem of rural development arises from the evolution of rural regional system.It is urgent to deepen the research on the evolution process and mechanism of rural regional system.However,there are relatively few studies on rural development from the perspective of the evolution process,driving mechanism and evolution mechanism of rural regional system.Therefore,this study took Huang-Huai-Hai Area for example,started with the systematicness of the rural regional system,the spatio-temporal pattern and driving mechanism of rural regional system evolution,and further summarized and refined the evolution mechanism of the rural regional system.The methods of spatial pattern analysis,gray correlation degree and geographical detection were adopted.The results showed that the problems in rural areas were often dominated by one factor and produced by the joint action of many factors.Factors such as county urbanization,county economy,county public service,agricultural mechanization,surrounding cities and convenient transportation will affect the evolution of rural regional systems.Based on the evolution of the elements in the rural regional system,the evolution types of rural regional system can be divided into decline type,equilibrium type and growth type.This study can provide a reference for understanding the process of rural rise and fall and can also guide rural revitalization and rural sustainable development.展开更多
Low-frequency vibrations can effectively improve natural sandstone permeability,and higher vibration frequency is associated with larger permeability.However,the optimum permeability and permeability evolution mechani...Low-frequency vibrations can effectively improve natural sandstone permeability,and higher vibration frequency is associated with larger permeability.However,the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined.To solve the above problems,in this study,identical homogeneous sandstone samples were selected to simulate lowpermeability sandstone;a permeability evolution model considering the combined action of vibration stress,pore water pressure,water flow impact force,and chemical erosion was established;and vibration leaching experiments were performed to test the model accuracy.Both the permeability and chemical reactions were found to simultaneously restrict U6þleaching,and the vibration treatment increased the permeability,causing the U6þleaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate.Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion,to prove the correctness of the mechanism according to the experimental results,and to develop a new method for determining the optimum permeability in uranium leaching.The uranium leaching was found to primarily follow a process consisting of(1)a permeability control stage,(2)achieving the optimum permeability,(3)a chemical reactive rate control stage,and(4)a channel flow stage.The resolution of these problems is of great significance for facilitating the application and promotion of lowfrequency vibration in the CO_(2)+O_(2) leaching process.展开更多
A new method has been proposed to prepare Mg-A1-Si master alloys by utilizing scrap AI-Si-Fe alloys with higher Fe levels, which aims to segregate Fe from AI-Si-Fe alloys by Mg melt. The segregation be- haviors, micro...A new method has been proposed to prepare Mg-A1-Si master alloys by utilizing scrap AI-Si-Fe alloys with higher Fe levels, which aims to segregate Fe from AI-Si-Fe alloys by Mg melt. The segregation be- haviors, microstructure morphology and evolution mechanism of iron-rich phases in Mg-A1-Si alloy melts were studied, after AI-14Si-4Fe （wt%） alloys were added and dissolved completely. In the Mg-A1-Si alloys, iron has very little solubility and tends to combine with other elements to form intermetallic phases, which grow into a deposition layer due to the higher density. During the cooling and solidifying process of Mg-A1-Si melts, the needle-like AlsSiFe phase in AI-14Si-4Fe alloy evolved into blocky AI5Fe2 and Al0.7Fe3Si0.3 phases. Besides, the Fe levels of the Mg-AI-Si master alloys were reduced to 0.017 wt% from nominal content of 0.164 wt%. Based on the above results, this work carried out a semi-quantitative phase- compositions analysis for the deposition layer by relative intensity ratio （RIR） method, and evolution mechanism of the iron-rich phases had also been discussed. This study has paved a new way to regen- erate the scrap AI-Si-Fe alloys, which has a great significance of promoting the recycling of aluminum resources.展开更多
Developing highly active and robust oxygen evolution reaction(OER)electrocatalysts is still a critical challenge for water electrolyzers and metal-air batteries.Realizing the dynamic evolution of the intermediate and ...Developing highly active and robust oxygen evolution reaction(OER)electrocatalysts is still a critical challenge for water electrolyzers and metal-air batteries.Realizing the dynamic evolution of the intermediate and charge transfer during OER and developing a clear OER mechanism is crucial to design high-performance OER catalysts.Recently in Nature,Xue and colleagues revealed a new OER mechanism,coupled oxygen evolution mechanism(COM),which involves a switchable metal and oxygen redox under light irradiation in nickel oxyhydroxide-based materials.This newly developed mechanism requires a reversible geometric conversion between octahedron(NiO_(6))and square planar(NiO_(4))to achieve electronic states with both“metal redox”and“oxygen redox”during OER.The asymmetric structure endows NR-NiOOH with a nonoverlapping region between the dz^(2) orbitals and a_(1g)^(*)bands,which facilitate the geometric conversion and enact the COM pathway.As a result,NR-NiOOH exhibited better OER activity and stability than the traditional NiOOH.展开更多
In this paper, we conduct research on the development and evolution mechanism of Chongqing rural tourism activities. Rural tourism industry cluster development is the important direction is to promote and enhance the ...In this paper, we conduct research on the development and evolution mechanism of Chongqing rural tourism activities. Rural tourism industry cluster development is the important direction is to promote and enhance the rural tourism the important measures to get long-term vitality. To upgrade the development of rural tourism to the height of the industrial cluster will make the rural tourism development onto a new level. In the future, we will combine more related literature review to polish and modify the proposed methodology which will be meaningful.展开更多
The study of the oxygen evolution reaction(OER)mechanism is vital for advancing our understanding of this pivotal energy conversion process.This review synthesizes recent advancements in OER mechanism,emphasizing the ...The study of the oxygen evolution reaction(OER)mechanism is vital for advancing our understanding of this pivotal energy conversion process.This review synthesizes recent advancements in OER mechanism,emphasizing the intricate relationship between catalytic mechanisms and catalyst design.This review discusses the connotation and cutting-edge progress of traditional mechanisms such as adsorbate evolution mechanism(AEM)and lattice oxygen mechanism(LOM)as well as emerging pathways including oxide path mechanism(OPM),oxo-oxo coupling mechanism(OCM),and intramolecular oxygen coupling mechanism(IMOC)etc.Innovative research progress on the coexistence and transformation of multiple mechanisms is highlighted,and the intrinsic factors that influence these dynamic processes are summarized.Advanced characterization techniques and theoretical modeling are underscored as indispensable tools for revealing these complex interactions.This review provides guiding principles for mechanism-based catalyst design.Finally,in view of the multidimensional challenges currently faced by OER mechanisms,prospects for future research are given to bridge the gap between mechanism innovation and experimental verification and application.This comprehensive review provides valuable perspectives for advancing clean energy technologies and achieving sustainable development.展开更多
Activating both metal and lattice oxygen sites for efficient oxygen evolution reactions(OER)is a critical challenge.This study pioneers a novel approach,employing cobalt-nickel glycerate solid spheres(CoNi-G SSs)as se...Activating both metal and lattice oxygen sites for efficient oxygen evolution reactions(OER)is a critical challenge.This study pioneers a novel approach,employing cobalt-nickel glycerate solid spheres(CoNi-G SSs)as self-sacrificial templates to synthesize yolk-shell structured CoNi-G SSs@ZIF-67 nanospheres.The derived NiCo2S4@CoS2/MoS2 double-shelled hollow nanospheres integrate the adsorbate evolution mechanism(AEM)and lattice oxygen mechanism(LOM),enabling synergistic dual catalytic pathways.Nickel modulation facilitates active species reconstruction in NiCo_(2)S_(4),enhancing lattice oxygen activity and optimizing the LOM pathway.Characterization results indicate that anode activation triggered the redox processes of metal and lattice oxygen sites,involving the formation and re-filling of oxygen vacancies.Additionally,the CoS_(2)/MoS_(2) heterostructure enhances the AEM pathway,as supported by density functional theory calculations,which demonstrate optimized adsorption of intermediates for both hydrogen evolution reaction and OER.The assembled anion exchange membrane water splitting device can deliver a catalytic current of 500 mA cm^(-2) at 1.74 V under commercial catalytic operating conditions(1 mol L^(-1) KOH)for 150 h,with negligible degradation.This work provides important insights into the understanding of OER mechanisms and the design of high-performance water-splitting electrocatalysts,while also opening new avenues for developing multifunctional materials with multi-shell structures.展开更多
The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the...The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are unclear.Therefore,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock failure.Based on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on monzogabbro.The results show that increasing amplitude or decreasing frequency diminishes the failure strength of monzogabbro.Deformation modulus gradually decreases during disturbance failure.As frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial stress.Before disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at failure.With the increase of amplitude and frequency,the micro-shear crack mechanism increases.When approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at failure.Finally,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated.展开更多
The rotating stall mechanism is of high importance for the stability of centrifugal compressors and thermal power cycles.The majority of research concerning this topic has concentrated on the initial stall phase.Howev...The rotating stall mechanism is of high importance for the stability of centrifugal compressors and thermal power cycles.The majority of research concerning this topic has concentrated on the initial stall phase.However,the evolution of stall cells in wide-long diffusers has not been comprehensively studied.In this paper,the causes of rotating stall in the wide-long diffuser and the three-dimensional evolution mechanism of stall cells during the stall process were thoroughly analyzed.During the stall induction phase,an annulus vortex structure was found in the reverse-flow zone near the hub side of the diffuser outlet,which was the initial form of stall cells.The whole evolution process of stall cells was divided into three phases as the flow rate decreased.During the initial stall phase,the dynamic equilibrium was built under effects of the impeller wake and the adverse pressure gradient.As a result,the number of stall cells was kept at seven and the size of stall cells remained constant.During the transition phase,the flow in the diffuser became unstable.Stall cells extended to the impeller outlet,and the effect of the wake flow was strengthened significantly.Stall cells started integrating and separating regularly.As a result,the number and propagation speed of stall cells varied periodically at a constant mass flow rate.During the deep stall phase,the size of stall cells remained unchanged,and the number of stall cells kept at one.This study has important practical guidance and engineering value for the high-efficiency design and safe operation of centrifugal compressors.展开更多
The south-western Ordos Basin is rich in low-middle rank coalbed methane(CBM)resources;while the geochemical characteristics and genetic mechanism of CBM are not clear.Herein,according to geological and geochemical te...The south-western Ordos Basin is rich in low-middle rank coalbed methane(CBM)resources;while the geochemical characteristics and genetic mechanism of CBM are not clear.Herein,according to geological and geochemical test data from gas and coal seam water from CBM wells in Bingchang,Jiaoxun,Huangling,Yonglong,and Longdong minging areas,we systematically studied the geochemical characteristics,generation,and evolution mechanism of CBM in Jurassic Yan’an Formation in the south-western Ordos Basin.The results show that the CH4 content of whole gas is in the range of 42.01%-94.72%.The distribution ranges of theδ^(13)C-CH_(4)value is−87.2‰to−32.5‰,indicating diverse sources of thermogenic gas and biogenic gas.The microbial methane is mainly generated by a CO_(2)reduction pathway,with certain methyl-type fermentation spots.Theδ^(13)C-CH_(4)has a positive correlation with burial depth,indicating the obvious fractionation of CBM.The relationship between the genetic types and burial depth of the CBM reservoir indicates that the favorable depth of secondary biogenic gas is less than 660 m.The Late Cretaceous Yanshanian Movement led to the uplift of the Ordos Basin,and a large amount of thermogenic gas escaped from the edge of the basin.Since the Paleogene Period,the coal reservoir in the basin margin has received recharge from atmospheric precipitation,which is favorable for the formation of secondary biogenic methane.The deep area,generally under 1000 m,mainly contains residual thermogenic gas.The intermediate transition zone is mixed gas.Constrained by the tectonic background,the genetic types of CBM in different mining areas are controlled by the coupling of burial depth,coal rank,and hydrogeological conditions.The Binchang mining area contains biogenic gas,and the development of CBM has achieved initial success,indicating that similar blocks with biogenic gas formation conditions is key to the efficient development of CBM.The research results provide a scientific basis for searching for favorable exploration areas of CBM in the south-western Ordos Basin.展开更多
The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase preci...The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase precipitation on strength and toughness of a self-developed 32Si_(2)CrNi_(2)MoVNb steel during the quenching and tempering process.Research outputs indicated that the steel microstructure under the quenching state could be composed of martensite with a high dislocation density,a small amount of residual austenite,and many dispersed spherical MC carbides.In details,after tempering at 200℃,fine needle-shapedε-carbides would precipitate,which may improve yield strength and toughness of the steel.However,as compared to that after tempering at 200℃,the average length of needle-shapedε-carbides was found to increase to 144.1±4 from 134.1±3 nm after tempering at 340℃.As a result,the yield strength may increase to 1505±40 MPa,and the impact absorption energy(V-notch)may also decrease.Moreover,after tempering at 450℃,thoseε-carbides in the steel may transform into coarse rod-shaped cementite,and dislocation recoveries at such high tempering temperature may lead to decrease of strength and toughness of the steel.Finally,the following properties could be obtained:a yield strength of 1440±35 MPa,an ultimate tensile strength of 1864±50 MPa and an impact absorption energy of 45.9±4 J,by means of rational composition design and microstructural control.展开更多
Two batches of Bi‐2212 precursor powder with Sr/Ca=2.24,2.33 were prepared by the spray pyrolysis tech-nology.Then two Bi‐2212 superconducting wires marked as Line4 and Line8‐2 were prepared by the above powders.Li...Two batches of Bi‐2212 precursor powder with Sr/Ca=2.24,2.33 were prepared by the spray pyrolysis tech-nology.Then two Bi‐2212 superconducting wires marked as Line4 and Line8‐2 were prepared by the above powders.Line4 with Sr/Ca=2.24 showed much higher phase purity,higher texture and its critical current density(J_(c))was 1.5 times that of Line8‐2 with Sr/Ca=2.33.Their micro‐structure evolution was scrutinized by quenching each wire at 7 instantaneous moments during the partial melting process(PMP).Bi‐2212 was found to decompose into(Sr,Ca)_(14)Cu_(24)O_(x)(14:24AEC),Bi_(9)Sr_(11)Ca_(5)O_(x)(9:16CF),Bi‐rich liquid Bi‐2212 and Bi‐rich solid Bi‐2212 at the initial stage of PMP.When Bi‐2212 began to solidify,the above four phases reacted to generate Bi‐2212.By analyzing the particle size,the content and the composition variation for 14:24AEC,9:16CF as well as the composition variation for Bi‐2212 matrix in above 7 moments of PMP,the phase evolu-tion’s difference between two wires was finally confirmed.The formation energy of 14:24AEC was smaller compared with 9:16CF,while 9:16CF was faster on dynamics.14:24AEC determined the whole synthetic reac-tion’s rate of Bi‐2212,and Sr/Ca as well as its value fluctuation in Bi‐2212 precursor powder can decide both the timeline and the driving force of PMP.A larger Sr/Ca in Line8‐2 made it melt earlier compared with Line4,which led to its earlier timeline during the melting stage of PMP.While the more consistent phase evolution’s pace between 14:24AEC and 9:16CF in Line4 finally contributed a larger Sr/Ca after solidification.Both the larger Sr/Ca and its larger fluctuation in Line4 finally contributed to its faster phase evolution’s pace,higher phase purity,better texture and higher J_(c).The deep logic driving the phase evolution mechanism in Bi‐2212 wires was disclosed for the first time,which will be very helpful to the future improvement of J_(c)for Bi‐2212 wires.展开更多
The transition to renewable energy sources has elevated the importance of SIBs(SIBs)as cost-effective alternatives to lithium-ion batteries(LIBs)for large-scale energy storage.This review examines the mechanisms of ga...The transition to renewable energy sources has elevated the importance of SIBs(SIBs)as cost-effective alternatives to lithium-ion batteries(LIBs)for large-scale energy storage.This review examines the mechanisms of gas generation in SIBs,identifying sources from cathode materials,anode materials,and electrolytes,which pose safety risks like swelling,leakage,and explosions.Gases such as CO_(2),H_(2),and O_(2) primarily arise from the instability of cathode materials,side reactions between electrode and electrolyte,and electrolyte decomposition under high temperatures or voltages.Enhanced mitigation strategies,encompassing electrolyte design,buffer layer construction,and electrode material optimization,are deliberated upon.Accordingly,subsequent research endeavors should prioritize long-term high-precision gas detection to bolster the safety and performance of SIBs,thereby fortifying their commercial viability and furnishing dependable solutions for large-scale energy storage and electric vehicles.展开更多
基金Project(52274096)supported by the National Natural Science Foundation of ChinaProject(WS2023A03)supported by the State Key Laboratory Cultivation Base for Gas Geology and Gas Control,China。
文摘Accurate assessment of coal brittleness is crucial in the design of coal seam drilling and underground coal mining operations.This study proposes a method for evaluating the brittleness of gas-bearing coal based on a statistical damage constitutive model and energy evolution mechanisms.Initially,integrating the principle of effective stress and the Hoek-Brown criterion,a statistical damage constitutive model for gas-bearing coal is established and validated through triaxial compression tests under different gas pressures to verify its accuracy and applicability.Subsequently,employing energy evolution mechanism,two energy characteristic parameters(elastic energy proportion and dissipated energy proportion)are analyzed.Based on the damage stress thresholds,the damage evolution characteristics of gas bearing coal were explored.Finally,by integrating energy characteristic parameters with damage parameters,a novel brittleness index is proposed.The results demonstrate that the theoretical curves derived from the statistical damage constitutive model closely align with the test curves,accurately reflecting the stress−strain characteristics of gas-bearing coal and revealing the stress drop and softening characteristics of coal in the post-peak stage.The shape parameter and scale parameter represent the brittleness and macroscopic strength of the coal,respectively.As gas pressure increases from 1 to 5 MPa,the shape parameter and the scale parameter decrease by 22.18%and 60.45%,respectively,indicating a reduction in both brittleness and strength of the coal.Parameters such as maximum damage rate and peak elastic energy storage limit positively correlate with coal brittleness.The brittleness index effectively captures the brittleness characteristics and reveals a decrease in brittleness and an increase in sensitivity to plastic deformation under higher gas pressure conditions.
基金supported by the Major Program of the National Natural Science Foundation of China(No.52394191)the Fundamental Research Funds for China University of Mining and Technology(Beijing):Doctoral Top-notch Innovative Talents Cultivation Fund(No.BBJ2023018,BBJ2023023)the Open Fund of State Key Laboratory of Water Resource Protection and Utilization in Coal Mining(No.GJNY-20-113-20).
文摘The Inner Mongolia mining area in western China are characterized by the development of numerous penetrating fissures,resulting in severe land damage.It is significant to reveal the underlying evolution mechanism and identify treatment timing for restoring the ecological environment.The Guanbanwusu mining subsidence area in Inner Mongolia,China was selected as the research case for this study.The evolution mechanism of different penetrating fissures was revealed by field measurement,physical simulation and theoretical analysis.The treatment timing prediction model for the mining subsidence area was established based on the enhanced Weibull time function.The results show that the ground fissures are mainly step-type and collapse-type fissures.The breaking form of overlying strata determines their vertical opening and horizontal dislocation.The high mining intensity in the western mining area results in a shortened period of dynamic fissure expansion and reduced closure degree.The damage extent of the overlying strata exhibits zoning characteristics both vertically and horizontally.The relative standard deviation of the prediction model is only 3.7%.Concurrently,the prediction model is employed to determine the optimal timing for treatment in the study area,estimated to be 259 days.Subsequently,once this threshold is reached,the study area undergoes treatment and restoration of its e cological environment.This study addresses the knowledge gap in this field by highlighting the interconnectedness between rock strata structure and evolution mechanism of penetrating fissures,thereby providing a method for determining the treatment timing in mining subsidence areas.
基金National Natural Science Foundation of China(12072363,12272374,12372373)Special Fund for Fundamental Research of the Central Universities(WK2480000008,WK2480000007,WK2320000049)Anhui Provincial Science and Technology Major Project(202003A05020035)。
文摘Explosion welding was carried out on the basis of vacuum hot melt W/CuCrZr composite plate.Metallurgical microscope,scanning electron microscope and energy dispersive X-ray spectroscope were used to observe the microscopic morphology of the bonding interface.At the same time,combined with finite element calculations,the evolution mechanism of the interface of the hot melt explosion welded W/CuCrZr composite plate was explored.The results show that the interface bonding of the hot melt explosion welded W/CuCrZr composite plate is good and there is a cross-melting zone with 3–8μm in thickness,but cracks are developed on the W side.The numerical simulation reproduces the changes of pressure,stress,strain and internal energy at the bonding interface in the process of hot melt explosion welding.The location of the crack generated in the experiment coincides with the high stress position calculated by numerical simulation.The high pressure and high temperature near the hot melt explosion welding interface further promote the bonding of the interface.
基金supported by the Major Scientific and Technological Projects of CNPC under grant ZD2019-183-006the National Science and Technology Major Project of China(2016ZX05014002-006)the National Natural Science Foundation of China(42072234)。
文摘This study aims to elucidate the dynamic evolution mechanism of the fracturing fracture system during the exploration and development of complex oil and gas reservoirs.By integrating methods of rock mechanical testing,logging calculation,and seismic inversion technology,we obtained the current insitu stress characteristics of a single well and rock mechanical parameters.Simultaneously,significant controlling factors of rock mechanical properties were analyzed.Subsequently,by coupling hydraulic fracturing physical experiments with finite element numerical simulation,three different fracturing models were configured:single-cluster,double-cluster,and triple-cluster perforations.Combined with acoustic emission technology,the fracture initiation mode and evolution characteristics during the loading process were determined.The results indicate the following findings:(1)The extension direction and length of the fracture are significantly controlled by the direction of the maximum horizontal principal stress.(2)Areas with poor cementation and compactness exhibit complex fracture morphology,prone to generating network fractures.(3)The interlayer development of fracturing fractures is controlled by the strata occurrence.(4)Increasing the displacement of fracturing fluid enlarges the fracturing fracture length and height.This research provides theoretical support and effective guidance for hydraulic fracturing design in tight oil and gas reservoirs.
基金Project(FRF-TP-20-041A1)supported by the Fundamental Research Funds for the Central Universities,ChinaProjects(2016YFC0600801,2017YFC0804103)supported by the State Key Research Development Program of ChinaProjects(51774022,52074020)supported by the National Natural Science Foundation of China.
文摘The object of this article is to investigate the energy evolution mechanism and failure criteria of cross-jointed samples containing an opening during deformation and failure based on the uniaxial compression test and rock energy principle.The results show that the energy evolution characteristics of the samples correspond to a typical progressive damage mode.The peak total energy,peak elastic energy,and total input energy of the samples all first decrease and then increase with an increase of half of the included angle,reaching their minimum values when this angle is 45°,while the dissipated energy generally increases with this angle.The existence of the opening and cross joints can obviously weaken the energy storage capacity of the rock,and the change in the included angle of the cross joint has a great influence on the elastic energy ratio of the sample before the peak stress,which leads to some differences in the distribution laws of the input energy.The continuous change and the subsequent sharp change in the rate of change in the energy consumption ratio can be used as the criteria of the crack initiation and propagation and the unstable failure of the sample,respectively.
基金the National Natural Science Foundation of China(No.51175502)
文摘Prognostics and health management （PHM） significantly improves system availability and reliability, and reduces the cost of system operations. Design for testability （DFT） developed concurrently with system design is an important way to improve PHM capability. Testability modeling and analysis are the foundation of DFT. This paper proposes a novel approach of testability modeling and analysis based on failure evolution mechanisms. At the component level, the fault progression-related information of each unit under test （UUT） in a system is obtained by means of failure modes, evolution mechanisms, effects and criticality analysis （FMEMECA）, and then the failure-symptom dependency can be generated. At the system level, the dynamic attributes of UUTs are assigned by using the bond graph methodology, and then the symptom-test dependency can be obtained by means of the functional flow method. Based on the failure-symptom and symptom-test dependencies, testability analysis for PHM systems can be realized. A shunt motor is used to verify the application of the approach proposed in this paper. Experimental results show that this approach is able to be applied to testability modeling and analysis for PHM systems very well, and the analysis results can provide a guide for engineers to design for testability in order to improve PHM performance.
基金supported by the National Natural Science Foundation of China(51175502)
文摘The test selection and optimization （TSO） can improve the abilities of fault diagnosis, prognosis and health-state evalua- tion for prognostics and health management （PHM） systems. Traditionally, TSO mainly focuses on fault detection and isolation, but they cannot provide an effective guide for the design for testability （DFT） to improve the PHM performance level. To solve the problem, a model of TSO for PHM systems is proposed. Firstly, through integrating the characteristics of fault severity and propa- gation time, and analyzing the test timing and sensitivity, a testability model based on failure evolution mechanism model （FEMM） for PHM systems is built up. This model describes the fault evolution- test dependency using the fault-symptom parameter matrix and symptom parameter-test matrix. Secondly, a novel method of in- herent testability analysis for PHM systems is developed based on the above information. Having completed the analysis, a TSO model, whose objective is to maximize fault trackability and mini- mize the test cost, is proposed through inherent testability analysis results, and an adaptive simulated annealing genetic algorithm （ASAGA） is introduced to solve the TSO problem. Finally, a case of a centrifugal pump system is used to verify the feasibility and effectiveness of the proposed models and methods. The results show that the proposed technology is important for PHM systems to select and optimize the test set in order to improve their performance level.
基金Under the auspices of Key projects of National Natural Science Foundation of China(No.41931293)。
文摘The problem of rural development arises from the evolution of rural regional system.It is urgent to deepen the research on the evolution process and mechanism of rural regional system.However,there are relatively few studies on rural development from the perspective of the evolution process,driving mechanism and evolution mechanism of rural regional system.Therefore,this study took Huang-Huai-Hai Area for example,started with the systematicness of the rural regional system,the spatio-temporal pattern and driving mechanism of rural regional system evolution,and further summarized and refined the evolution mechanism of the rural regional system.The methods of spatial pattern analysis,gray correlation degree and geographical detection were adopted.The results showed that the problems in rural areas were often dominated by one factor and produced by the joint action of many factors.Factors such as county urbanization,county economy,county public service,agricultural mechanization,surrounding cities and convenient transportation will affect the evolution of rural regional systems.Based on the evolution of the elements in the rural regional system,the evolution types of rural regional system can be divided into decline type,equilibrium type and growth type.This study can provide a reference for understanding the process of rural rise and fall and can also guide rural revitalization and rural sustainable development.
基金supported by the National Natural Science Foundation of China(Grant No.11705086)the National Science Foundation of Hunan Province,China(Grant No.2018JJ3424)the Foundation of Hunan Educational Committee(Grant No.16C1387).
文摘Low-frequency vibrations can effectively improve natural sandstone permeability,and higher vibration frequency is associated with larger permeability.However,the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined.To solve the above problems,in this study,identical homogeneous sandstone samples were selected to simulate lowpermeability sandstone;a permeability evolution model considering the combined action of vibration stress,pore water pressure,water flow impact force,and chemical erosion was established;and vibration leaching experiments were performed to test the model accuracy.Both the permeability and chemical reactions were found to simultaneously restrict U6þleaching,and the vibration treatment increased the permeability,causing the U6þleaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate.Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion,to prove the correctness of the mechanism according to the experimental results,and to develop a new method for determining the optimum permeability in uranium leaching.The uranium leaching was found to primarily follow a process consisting of(1)a permeability control stage,(2)achieving the optimum permeability,(3)a chemical reactive rate control stage,and(4)a channel flow stage.The resolution of these problems is of great significance for facilitating the application and promotion of lowfrequency vibration in the CO_(2)+O_(2) leaching process.
基金supported by the National Natural Science Foundation of China(No.512711101)the National Basic Research Program of China (No.2012CB825702)
文摘A new method has been proposed to prepare Mg-A1-Si master alloys by utilizing scrap AI-Si-Fe alloys with higher Fe levels, which aims to segregate Fe from AI-Si-Fe alloys by Mg melt. The segregation be- haviors, microstructure morphology and evolution mechanism of iron-rich phases in Mg-A1-Si alloy melts were studied, after AI-14Si-4Fe （wt%） alloys were added and dissolved completely. In the Mg-A1-Si alloys, iron has very little solubility and tends to combine with other elements to form intermetallic phases, which grow into a deposition layer due to the higher density. During the cooling and solidifying process of Mg-A1-Si melts, the needle-like AlsSiFe phase in AI-14Si-4Fe alloy evolved into blocky AI5Fe2 and Al0.7Fe3Si0.3 phases. Besides, the Fe levels of the Mg-AI-Si master alloys were reduced to 0.017 wt% from nominal content of 0.164 wt%. Based on the above results, this work carried out a semi-quantitative phase- compositions analysis for the deposition layer by relative intensity ratio （RIR） method, and evolution mechanism of the iron-rich phases had also been discussed. This study has paved a new way to regen- erate the scrap AI-Si-Fe alloys, which has a great significance of promoting the recycling of aluminum resources.
基金supported by the National Natural Science Foundation of China(52122308,21905253,51973200).
文摘Developing highly active and robust oxygen evolution reaction(OER)electrocatalysts is still a critical challenge for water electrolyzers and metal-air batteries.Realizing the dynamic evolution of the intermediate and charge transfer during OER and developing a clear OER mechanism is crucial to design high-performance OER catalysts.Recently in Nature,Xue and colleagues revealed a new OER mechanism,coupled oxygen evolution mechanism(COM),which involves a switchable metal and oxygen redox under light irradiation in nickel oxyhydroxide-based materials.This newly developed mechanism requires a reversible geometric conversion between octahedron(NiO_(6))and square planar(NiO_(4))to achieve electronic states with both“metal redox”and“oxygen redox”during OER.The asymmetric structure endows NR-NiOOH with a nonoverlapping region between the dz^(2) orbitals and a_(1g)^(*)bands,which facilitate the geometric conversion and enact the COM pathway.As a result,NR-NiOOH exhibited better OER activity and stability than the traditional NiOOH.
文摘In this paper, we conduct research on the development and evolution mechanism of Chongqing rural tourism activities. Rural tourism industry cluster development is the important direction is to promote and enhance the rural tourism the important measures to get long-term vitality. To upgrade the development of rural tourism to the height of the industrial cluster will make the rural tourism development onto a new level. In the future, we will combine more related literature review to polish and modify the proposed methodology which will be meaningful.
文摘The study of the oxygen evolution reaction(OER)mechanism is vital for advancing our understanding of this pivotal energy conversion process.This review synthesizes recent advancements in OER mechanism,emphasizing the intricate relationship between catalytic mechanisms and catalyst design.This review discusses the connotation and cutting-edge progress of traditional mechanisms such as adsorbate evolution mechanism(AEM)and lattice oxygen mechanism(LOM)as well as emerging pathways including oxide path mechanism(OPM),oxo-oxo coupling mechanism(OCM),and intramolecular oxygen coupling mechanism(IMOC)etc.Innovative research progress on the coexistence and transformation of multiple mechanisms is highlighted,and the intrinsic factors that influence these dynamic processes are summarized.Advanced characterization techniques and theoretical modeling are underscored as indispensable tools for revealing these complex interactions.This review provides guiding principles for mechanism-based catalyst design.Finally,in view of the multidimensional challenges currently faced by OER mechanisms,prospects for future research are given to bridge the gap between mechanism innovation and experimental verification and application.This comprehensive review provides valuable perspectives for advancing clean energy technologies and achieving sustainable development.
文摘Activating both metal and lattice oxygen sites for efficient oxygen evolution reactions(OER)is a critical challenge.This study pioneers a novel approach,employing cobalt-nickel glycerate solid spheres(CoNi-G SSs)as self-sacrificial templates to synthesize yolk-shell structured CoNi-G SSs@ZIF-67 nanospheres.The derived NiCo2S4@CoS2/MoS2 double-shelled hollow nanospheres integrate the adsorbate evolution mechanism(AEM)and lattice oxygen mechanism(LOM),enabling synergistic dual catalytic pathways.Nickel modulation facilitates active species reconstruction in NiCo_(2)S_(4),enhancing lattice oxygen activity and optimizing the LOM pathway.Characterization results indicate that anode activation triggered the redox processes of metal and lattice oxygen sites,involving the formation and re-filling of oxygen vacancies.Additionally,the CoS_(2)/MoS_(2) heterostructure enhances the AEM pathway,as supported by density functional theory calculations,which demonstrate optimized adsorption of intermediates for both hydrogen evolution reaction and OER.The assembled anion exchange membrane water splitting device can deliver a catalytic current of 500 mA cm^(-2) at 1.74 V under commercial catalytic operating conditions(1 mol L^(-1) KOH)for 150 h,with negligible degradation.This work provides important insights into the understanding of OER mechanisms and the design of high-performance water-splitting electrocatalysts,while also opening new avenues for developing multifunctional materials with multi-shell structures.
基金the financial support from the National Natural Science Foundation of China(No.52109119)the Guangxi Natural Science Foundation(No.2021GXNSFBA075030)+2 种基金the Guangxi Science and Technology Project(No.Guike AD20325002)the Chinese Postdoctoral Science Fund Project(No.2022M723408)the Open Research Fund of State Key Laboratory of Simulation and Regulation of Water Cycle in River Basin(China Institute of Water Resources and Hydropower Research)(No.IWHR-SKL-202202)。
文摘The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are unclear.Therefore,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock failure.Based on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on monzogabbro.The results show that increasing amplitude or decreasing frequency diminishes the failure strength of monzogabbro.Deformation modulus gradually decreases during disturbance failure.As frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial stress.Before disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at failure.With the increase of amplitude and frequency,the micro-shear crack mechanism increases.When approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at failure.Finally,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated.
基金supports of National Natural Science Foundation of China(No.52076079)Natural Science Foundation of Hebei Province(E2022502048,E2020502013)+1 种基金Fundamental Research Funds for the Central Universities(No.2022MS085,2023MS121)Post-graduate's Innovation Fund Project of Hebei Province(No.CXZZSS2024162,No.CXZZBS2024165)。
文摘The rotating stall mechanism is of high importance for the stability of centrifugal compressors and thermal power cycles.The majority of research concerning this topic has concentrated on the initial stall phase.However,the evolution of stall cells in wide-long diffusers has not been comprehensively studied.In this paper,the causes of rotating stall in the wide-long diffuser and the three-dimensional evolution mechanism of stall cells during the stall process were thoroughly analyzed.During the stall induction phase,an annulus vortex structure was found in the reverse-flow zone near the hub side of the diffuser outlet,which was the initial form of stall cells.The whole evolution process of stall cells was divided into three phases as the flow rate decreased.During the initial stall phase,the dynamic equilibrium was built under effects of the impeller wake and the adverse pressure gradient.As a result,the number of stall cells was kept at seven and the size of stall cells remained constant.During the transition phase,the flow in the diffuser became unstable.Stall cells extended to the impeller outlet,and the effect of the wake flow was strengthened significantly.Stall cells started integrating and separating regularly.As a result,the number and propagation speed of stall cells varied periodically at a constant mass flow rate.During the deep stall phase,the size of stall cells remained unchanged,and the number of stall cells kept at one.This study has important practical guidance and engineering value for the high-efficiency design and safe operation of centrifugal compressors.
基金supported by the National Natural Science Foundation of China(Grant Nos.42130802 and 42372200)China Postdoctoral Science Foundation(No.2022M713792)+1 种基金Key Science and Technology Program of Shaanxi Province(No.2023YBGY-083)Open Fund of Key Laboratory of Coalbed Methane Resources and Reservoir Formation Process of the Ministry of Education(China University of Mining and Technology)(No.2022-007).
文摘The south-western Ordos Basin is rich in low-middle rank coalbed methane(CBM)resources;while the geochemical characteristics and genetic mechanism of CBM are not clear.Herein,according to geological and geochemical test data from gas and coal seam water from CBM wells in Bingchang,Jiaoxun,Huangling,Yonglong,and Longdong minging areas,we systematically studied the geochemical characteristics,generation,and evolution mechanism of CBM in Jurassic Yan’an Formation in the south-western Ordos Basin.The results show that the CH4 content of whole gas is in the range of 42.01%-94.72%.The distribution ranges of theδ^(13)C-CH_(4)value is−87.2‰to−32.5‰,indicating diverse sources of thermogenic gas and biogenic gas.The microbial methane is mainly generated by a CO_(2)reduction pathway,with certain methyl-type fermentation spots.Theδ^(13)C-CH_(4)has a positive correlation with burial depth,indicating the obvious fractionation of CBM.The relationship between the genetic types and burial depth of the CBM reservoir indicates that the favorable depth of secondary biogenic gas is less than 660 m.The Late Cretaceous Yanshanian Movement led to the uplift of the Ordos Basin,and a large amount of thermogenic gas escaped from the edge of the basin.Since the Paleogene Period,the coal reservoir in the basin margin has received recharge from atmospheric precipitation,which is favorable for the formation of secondary biogenic methane.The deep area,generally under 1000 m,mainly contains residual thermogenic gas.The intermediate transition zone is mixed gas.Constrained by the tectonic background,the genetic types of CBM in different mining areas are controlled by the coupling of burial depth,coal rank,and hydrogeological conditions.The Binchang mining area contains biogenic gas,and the development of CBM has achieved initial success,indicating that similar blocks with biogenic gas formation conditions is key to the efficient development of CBM.The research results provide a scientific basis for searching for favorable exploration areas of CBM in the south-western Ordos Basin.
基金the National Natural Science Foundation of China(Key Program)(52031004).
文摘The characterization techniques were employed like transmission electron microscope,X-ray diffraction and microstructural characterization to investigate microstructural evolution and impact of precipitate-phase precipitation on strength and toughness of a self-developed 32Si_(2)CrNi_(2)MoVNb steel during the quenching and tempering process.Research outputs indicated that the steel microstructure under the quenching state could be composed of martensite with a high dislocation density,a small amount of residual austenite,and many dispersed spherical MC carbides.In details,after tempering at 200℃,fine needle-shapedε-carbides would precipitate,which may improve yield strength and toughness of the steel.However,as compared to that after tempering at 200℃,the average length of needle-shapedε-carbides was found to increase to 144.1±4 from 134.1±3 nm after tempering at 340℃.As a result,the yield strength may increase to 1505±40 MPa,and the impact absorption energy(V-notch)may also decrease.Moreover,after tempering at 450℃,thoseε-carbides in the steel may transform into coarse rod-shaped cementite,and dislocation recoveries at such high tempering temperature may lead to decrease of strength and toughness of the steel.Finally,the following properties could be obtained:a yield strength of 1440±35 MPa,an ultimate tensile strength of 1864±50 MPa and an impact absorption energy of 45.9±4 J,by means of rational composition design and microstructural control.
基金financially supported by the Key Research and Development Program of Shaanxi(Program No.2023‐YBGY‐428)the National natural Science foundation of China(No.52002333)+2 种基金the Science and Technology Planning Project in Weiyang District of Xi’an(No.202107)the National Key R&D Program of China(Grant No.2021YFB3800201)the National natural Science foundation of China(No.52277029).
文摘Two batches of Bi‐2212 precursor powder with Sr/Ca=2.24,2.33 were prepared by the spray pyrolysis tech-nology.Then two Bi‐2212 superconducting wires marked as Line4 and Line8‐2 were prepared by the above powders.Line4 with Sr/Ca=2.24 showed much higher phase purity,higher texture and its critical current density(J_(c))was 1.5 times that of Line8‐2 with Sr/Ca=2.33.Their micro‐structure evolution was scrutinized by quenching each wire at 7 instantaneous moments during the partial melting process(PMP).Bi‐2212 was found to decompose into(Sr,Ca)_(14)Cu_(24)O_(x)(14:24AEC),Bi_(9)Sr_(11)Ca_(5)O_(x)(9:16CF),Bi‐rich liquid Bi‐2212 and Bi‐rich solid Bi‐2212 at the initial stage of PMP.When Bi‐2212 began to solidify,the above four phases reacted to generate Bi‐2212.By analyzing the particle size,the content and the composition variation for 14:24AEC,9:16CF as well as the composition variation for Bi‐2212 matrix in above 7 moments of PMP,the phase evolu-tion’s difference between two wires was finally confirmed.The formation energy of 14:24AEC was smaller compared with 9:16CF,while 9:16CF was faster on dynamics.14:24AEC determined the whole synthetic reac-tion’s rate of Bi‐2212,and Sr/Ca as well as its value fluctuation in Bi‐2212 precursor powder can decide both the timeline and the driving force of PMP.A larger Sr/Ca in Line8‐2 made it melt earlier compared with Line4,which led to its earlier timeline during the melting stage of PMP.While the more consistent phase evolution’s pace between 14:24AEC and 9:16CF in Line4 finally contributed a larger Sr/Ca after solidification.Both the larger Sr/Ca and its larger fluctuation in Line4 finally contributed to its faster phase evolution’s pace,higher phase purity,better texture and higher J_(c).The deep logic driving the phase evolution mechanism in Bi‐2212 wires was disclosed for the first time,which will be very helpful to the future improvement of J_(c)for Bi‐2212 wires.
基金financial support of Shenzhen Science and Technology Program(No.KJZD20230923115005009)Xiangjiang Lab(22XJ01007)+3 种基金National Natural Science Foundation(NNSF)of China(No.52202269)Shenzhen Science and Technology program(No.20220810155330003)Shenzhen Science and Technology Program(NO.KJZD20230923115005009)Project of Department of Education of Guangdong Province(No.2022ZDZX3018).
文摘The transition to renewable energy sources has elevated the importance of SIBs(SIBs)as cost-effective alternatives to lithium-ion batteries(LIBs)for large-scale energy storage.This review examines the mechanisms of gas generation in SIBs,identifying sources from cathode materials,anode materials,and electrolytes,which pose safety risks like swelling,leakage,and explosions.Gases such as CO_(2),H_(2),and O_(2) primarily arise from the instability of cathode materials,side reactions between electrode and electrolyte,and electrolyte decomposition under high temperatures or voltages.Enhanced mitigation strategies,encompassing electrolyte design,buffer layer construction,and electrode material optimization,are deliberated upon.Accordingly,subsequent research endeavors should prioritize long-term high-precision gas detection to bolster the safety and performance of SIBs,thereby fortifying their commercial viability and furnishing dependable solutions for large-scale energy storage and electric vehicles.
