The microstructure evolution and its effect on the impact toughness of a new Ni-Fe based alloy GH984 G,used in 700℃ ultra-super critical coal-fired power plant,were investigated during thermal exposure at 650℃-750℃...The microstructure evolution and its effect on the impact toughness of a new Ni-Fe based alloy GH984 G,used in 700℃ ultra-super critical coal-fired power plant,were investigated during thermal exposure at 650℃-750℃ for up to 10,000 h.The results show that the impact toughness at room tempe rature drops rapidly at the early stage during thermal exposure at 700℃ and then has no significant change even if after exposure for 10,000 h.The significant decline of the impact toughness is attributed to the coarsening of M_(23)C_(6) carbides at grain boundaries,which weakens the grain boundary strength and leads to the aging-induced grain boundary embrittlement.The M_(23)C_(6) carbides have almost no change with further thermal exposure and the impact toughness also remains stable.Additionally,the impact toughness rises with the increase of thermal exposure temperature.The size of γ' after thermal exposure at 750℃ for10,000 h is much bigger than that at 650℃ and 700℃ for 10,000 h.There fore,the intragranular strength decreases significantly due to the transformation of the interaction between γ' and dislocation from stro ngly coupled dislocation shearing to Orowan bowing.More plastic deformation occurs within grains after thermal exposure at 750℃ for 10,000 h,which increases the impact toughness.展开更多
In this paper, we give an overview of the evolution of wireless mobiles starting from the first generation which is the analogue system started in 1980’s, and passing through the 2G technologies which are all digital...In this paper, we give an overview of the evolution of wireless mobiles starting from the first generation which is the analogue system started in 1980’s, and passing through the 2G technologies which are all digital networks and GSM is the most popular network. 2.5G networks will introduce the packet notion on the existing 2G networks and 3G will bring the quality of service as new perspective for the 3G partnership projet 3GPP and 3GPP2. However, high demand on data speed has pushed the operators to looking for 3.5G system. 3.99G networks are defined as long-term evolution for the existing 3G network and it will be based on OFDM and MIMO technologies. 4G networks was not yet defined, but requirement is to support heterogeneous networks at 100 Mbps mobility data speed.展开更多
随着4G/5G网络的快速发展,4G/5G网络覆盖的深度和广度有待完善,部分区域存在弱覆盖或盲区,针对网络覆盖建设周期长、成本高的问题。本文首先分析快速解决4G/5G网络弱覆盖存在的问题,其次围绕怎样实现弱覆盖或盲点区域快速覆盖4G/5G网络...随着4G/5G网络的快速发展,4G/5G网络覆盖的深度和广度有待完善,部分区域存在弱覆盖或盲区,针对网络覆盖建设周期长、成本高的问题。本文首先分析快速解决4G/5G网络弱覆盖存在的问题,其次围绕怎样实现弱覆盖或盲点区域快速覆盖4G/5G网络开展研究,提出利旧小区宽带空闲的传输网络资源连接微功率射频拉远单元(pico remote radio unit,PRRU)的方案,该方案可实现4G/5G网络弱覆盖快速处理。最后对方案的实用性及有效性进行了阐述。本研究为快速解决4G/5G网络弱覆盖问题提供了新思路和新方法。展开更多
Doping engineering is an effective strategy for graphitic carbon nitride(g-C_(3)N_(4))to improve its photocat-alytic hydrogen evolution reaction(HER)performance.In this work,a novel nitrogen and sulfur co-doped g-C_(3...Doping engineering is an effective strategy for graphitic carbon nitride(g-C_(3)N_(4))to improve its photocat-alytic hydrogen evolution reaction(HER)performance.In this work,a novel nitrogen and sulfur co-doped g-C_(3)N_(4)(N,S-g-C_(3)N_(4))is elaborately designed on the basis of theoretical predictions of first-principle density functional theory(DFT).The calculated Gibbs free energy of adsorbed hydrogen(ΔGH∗)for N,S-g-C_(3)N_(4) at the N-doping active sites is extremely close to zero(0.01 eV).Inspired by the theoretical predictions,the N,S-g-C_(3)N_(4) is successfully fabricated through ammonia-rich pyrolysis synthesis strategy,in which ammonia is in-situ obtained by pyrolyzing melamine.Subsequent characterizations indicate that the N,S-g-C_(3)N_(4) possesses high specific surface area,outstanding light utilization,good hydrophilicity,and efficient carrier transfer efficiency.Consequently,the N,S-g-C_(3)N_(4) displays an extremely high H2 evolution rate of 8269.9μmol g−1 h−1,achieves an apparent quantum efficiency(AQE)of 3.24%,and also possesses outsatnding durability.Theoretical calculations further demonstrate that N and S dopants can not only introduce doping energy level to reduce the band gap,but also induce charge redistribution to facilitate hydrogen adsorption,thus promoting the photocatalytic HER process.Moreover,femtosecond transient absorption(fs-TA)spectroscopy further corroborates the efficient photogenerated carrier transport of N,S-g-C_(3)N_(4).This research highlights a promising and reliable strategy to achieve superior photocatalytic activity,and exhibits significant guidance for precise designing high-efficiency photocatalysts.展开更多
基金supported by the National Key Research and Development Program of China(No.2017YFB0305204)the National Natural Science Foundation of China(No.51971216 and No.51871213)LiaoNing Revitalization Talents Program(No.XLYC1807038)。
文摘The microstructure evolution and its effect on the impact toughness of a new Ni-Fe based alloy GH984 G,used in 700℃ ultra-super critical coal-fired power plant,were investigated during thermal exposure at 650℃-750℃ for up to 10,000 h.The results show that the impact toughness at room tempe rature drops rapidly at the early stage during thermal exposure at 700℃ and then has no significant change even if after exposure for 10,000 h.The significant decline of the impact toughness is attributed to the coarsening of M_(23)C_(6) carbides at grain boundaries,which weakens the grain boundary strength and leads to the aging-induced grain boundary embrittlement.The M_(23)C_(6) carbides have almost no change with further thermal exposure and the impact toughness also remains stable.Additionally,the impact toughness rises with the increase of thermal exposure temperature.The size of γ' after thermal exposure at 750℃ for10,000 h is much bigger than that at 650℃ and 700℃ for 10,000 h.There fore,the intragranular strength decreases significantly due to the transformation of the interaction between γ' and dislocation from stro ngly coupled dislocation shearing to Orowan bowing.More plastic deformation occurs within grains after thermal exposure at 750℃ for 10,000 h,which increases the impact toughness.
文摘In this paper, we give an overview of the evolution of wireless mobiles starting from the first generation which is the analogue system started in 1980’s, and passing through the 2G technologies which are all digital networks and GSM is the most popular network. 2.5G networks will introduce the packet notion on the existing 2G networks and 3G will bring the quality of service as new perspective for the 3G partnership projet 3GPP and 3GPP2. However, high demand on data speed has pushed the operators to looking for 3.5G system. 3.99G networks are defined as long-term evolution for the existing 3G network and it will be based on OFDM and MIMO technologies. 4G networks was not yet defined, but requirement is to support heterogeneous networks at 100 Mbps mobility data speed.
文摘随着4G/5G网络的快速发展,4G/5G网络覆盖的深度和广度有待完善,部分区域存在弱覆盖或盲区,针对网络覆盖建设周期长、成本高的问题。本文首先分析快速解决4G/5G网络弱覆盖存在的问题,其次围绕怎样实现弱覆盖或盲点区域快速覆盖4G/5G网络开展研究,提出利旧小区宽带空闲的传输网络资源连接微功率射频拉远单元(pico remote radio unit,PRRU)的方案,该方案可实现4G/5G网络弱覆盖快速处理。最后对方案的实用性及有效性进行了阐述。本研究为快速解决4G/5G网络弱覆盖问题提供了新思路和新方法。
基金supported by the National Natural Science Foun-dation of China(No.62004143)the Key R&D Program of Hubei Province(No.2022BAA084)the Natural Science Foundation of Hubei Province(No.2021CFB133).
文摘Doping engineering is an effective strategy for graphitic carbon nitride(g-C_(3)N_(4))to improve its photocat-alytic hydrogen evolution reaction(HER)performance.In this work,a novel nitrogen and sulfur co-doped g-C_(3)N_(4)(N,S-g-C_(3)N_(4))is elaborately designed on the basis of theoretical predictions of first-principle density functional theory(DFT).The calculated Gibbs free energy of adsorbed hydrogen(ΔGH∗)for N,S-g-C_(3)N_(4) at the N-doping active sites is extremely close to zero(0.01 eV).Inspired by the theoretical predictions,the N,S-g-C_(3)N_(4) is successfully fabricated through ammonia-rich pyrolysis synthesis strategy,in which ammonia is in-situ obtained by pyrolyzing melamine.Subsequent characterizations indicate that the N,S-g-C_(3)N_(4) possesses high specific surface area,outstanding light utilization,good hydrophilicity,and efficient carrier transfer efficiency.Consequently,the N,S-g-C_(3)N_(4) displays an extremely high H2 evolution rate of 8269.9μmol g−1 h−1,achieves an apparent quantum efficiency(AQE)of 3.24%,and also possesses outsatnding durability.Theoretical calculations further demonstrate that N and S dopants can not only introduce doping energy level to reduce the band gap,but also induce charge redistribution to facilitate hydrogen adsorption,thus promoting the photocatalytic HER process.Moreover,femtosecond transient absorption(fs-TA)spectroscopy further corroborates the efficient photogenerated carrier transport of N,S-g-C_(3)N_(4).This research highlights a promising and reliable strategy to achieve superior photocatalytic activity,and exhibits significant guidance for precise designing high-efficiency photocatalysts.
