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Effect of Flow Directions on Multiphase Flow Boiling Heat Transfer Enhanced by Suspending Particles in a Circulating Evaporation System 被引量:4
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作者 Feng Jiang Teng Jiang +1 位作者 Guopeng Qi Xiulun Li 《Transactions of Tianjin University》 EI CAS 2019年第3期201-213,共13页
A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental invest... A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental investigations were carried out by varying amount of added particles(0-2%), circulation flow rate(2.15-5.16 m^3/h) and heat flux(8-16 kW/m^2). The comparison of heat transfer performance in different vertical heights of the horizontal bed was also discussed. Results reveal that the glass bead particle can enhance heat transfer compared with vapor-liquid two-phase flow for all beds. At a low heat flux(q = 8 kW/m), the heat-transfer-enhancing factor of the horizontal bed is obviously greater than those of the up-flow and down-flow beds. With the increase in the amount of added particles, the heat-transfer-enhancing factors of the up-flow and down-flow beds increase, whereas that of the horizontal bed initially increases and then decreases. However, at a high heat flux(q=16 kW/m), the heat-transfer-enhancing factors of the three beds show an increasing tendency with the increase in the amount of added particles and become closer than those at a low heat flux. For all beds, the heat-transfer-enhancing factor generally increases with the circulation flow rate but decreases with the increase in heat flux. 展开更多
关键词 Heat transfer enhancement CIRCULATING fluidized BED EVAPORATOR FLOW direction DOWN-FLOW BED UP-FLOW BED Horizontal BED
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Case Studies of Heat Integration of Evaporation Systems
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作者 冯霄 RobinSmith 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2001年第2期224-227,共4页
In this paper, through two case studies, evaporation systems are considered in the context of overall process, and then are optimized to obtain energy-saving effect. The possible evaporation schemes are given when int... In this paper, through two case studies, evaporation systems are considered in the context of overall process, and then are optimized to obtain energy-saving effect. The possible evaporation schemes are given when integrated with the background process and how to optimize the evaporator is shown. From the case studies, it can be seen that sometimes incomplete integration and heat pump evaporation are better than complete integration so should be considered as candidate retrofit schemes. 展开更多
关键词 evaporation heat integration grand composite curve multi-effect evaporation vapour recompression evaporator
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Polymer Modified Banana Pseudo Stem-based Interfacial Solar-driven Evaporation System
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作者 Vivek Chandran Sujith Lal Sudip K.Batabyal 《Journal of Bionic Engineering》 SCIE EI CSCD 2022年第3期752-760,共9页
Interfacial solar-driven evaporation technique is an environmental friendly and cost-effective advanced approach for water purification using solar energy.Free energy sources are effectively utilized using the structu... Interfacial solar-driven evaporation technique is an environmental friendly and cost-effective advanced approach for water purification using solar energy.Free energy sources are effectively utilized using the structural design of evaporators and functional materials.In this work,we have fabricated a solar-driven interfacial evaporation device with Banana Pseudo Stem(BPS)and a photothermal layer made up of PVA PDMS Carbon(PPC)is attached to it.High evaporation rate of 2.03 kg m^(−2) h^(−1) is achieved by the system under 1 sun illumination.Heat localization on interfacial surface,reflectance of photothermal layer,presence of micro-fluidic channels in BPS were studied using IR imaging,UV-DRS and SEM characterization techniques,respectively.Effective localization of interfacial temperature around 53℃ and very low reflectance of photothermal layer substantiates high photothermal conversion efficiency of the device.The complete purification of water containing high concentration of Rhodamine-B dye using BPS is a novel and simple approach for water purification.This is an eco-friendly,cost-efficient novel approach in fabrication of interfacial solar-driven evaporation system with high evaporation rate for purification of water containing high concentration of organic dye. 展开更多
关键词 Banana pseudo stem POLYMERS Interfacial evaporator Biomaterial Water purification High efficiency
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High Efficient Synthesis of Enzymatic 2-Ethylhexyl Ferulate at Solvent-Free and Reduced Pressure Evaporation System
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作者 Kuo-Chuan Huang Ying Li +1 位作者 Yawo-Kuo Twu Chwen-Jen Shieh 《Journal of Materials Science and Chemical Engineering》 2015年第6期33-40,共8页
The use of immobilized lipase from Candida antarctica (Novozymò 435) to catalyze ferulic acid of esterification was investigated in this study. The synthesis product was analyzed using HPLC. The results revealed ... The use of immobilized lipase from Candida antarctica (Novozymò 435) to catalyze ferulic acid of esterification was investigated in this study. The synthesis product was analyzed using HPLC. The results revealed that the major product was 2-ethylhexyl ferulate. Response surface methodology and 3-level-3-factor central composite rotatable design were adopted to evaluate the effects of synthesis variables, including reaction temperature (60℃- 80℃), enzyme amount (500 - 1500 PLU) and reaction time (8 - 24 h) on the percentage molar conversion of 2-ethylhexyl ferulate. The results showed that reaction temperature and reaction time were the most important parameters on percentage molar conversion. Based on ridge max analysis, the optimum conditions for synthesis were: reaction time 23 h, reaction temperature 71℃?and enzyme amount 1422 PLU. The molar conversion of actual experimental values was 98% under optimal conditions. 展开更多
关键词 Ferulic Acid Green Chemistry Novozym 435 Rotary Evaporator ESTERIFICATION
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Energy, exergy, economic, and environmental compromising performance of dual-stage evaporation-ammonia hybrid compression-absorption refrigeration system for the cooling supply of keto-benzene dewaxing process
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作者 Shuaishuai Zhang Yuanbo Liu +4 位作者 Tong Zheng Da Ruan Zhong Lan Tingting Hao Xuehu Ma 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第11期274-289,共16页
Absorption refrigeration systems driven by low-temperature waste heat is one way to achieve“carbon neutrality.”Meanwhile,the keto-benzene dewaxing equipment needs a cooling capacity of 5 MW,with refrigeration temper... Absorption refrigeration systems driven by low-temperature waste heat is one way to achieve“carbon neutrality.”Meanwhile,the keto-benzene dewaxing equipment needs a cooling capacity of 5 MW,with refrigeration temperature of-10℃and-25℃.This paper researches the feasibility of dual-stage evaporation-ammonia hybrid compressioneabsorption refrigeration system(DSE-AHCARS)replacing the vapor compression refrigeration system for keto-benzene dewaxing process based on energy,exergy,economic,and environmental(4E)analysis.At the primary-and secondary-stage evaporation temperature of 0 and-23℃,respectively,the coefficient of performance(COP)reaches the maximum value of 0.85;however,COP-electricity reaches the minimum value of 8.1.When the secondary-stage refrigeration temperature is-23℃,CO_(2)emission increases from 1150 t·a^(-1)to 3600 t·a^(-1),and life cycle climate performance increases from 3.29×10^(4) to 7.7×10^(4) t,with the primary-stage refrigeration temperature being-15-0℃,as well as matching three parameters to ensure the 4E compromising performance by the multi-objective optimization.To guarantee that the life cycle climate performance is less than 5.5×10^(4)t,the payback period is<2 a,and COP is>0.6 at the optimal operation ranges,such that the refrigeration temperature difference between primary stage and secondary stage is within 20℃.The power of DSE-AHCARS was reduced by 77%compared with the vapor-compression refrigeration system.Therefore,the DSE-AHCARS can reduce CO_(2)emissions by about 6250 t·a^(-1)and save 1.2×10^(5)t of CO_(2)in the life cycle climate performance term.This result shows that the DSE-AHCARS can completely replace the vapor-compression refrigeration system. 展开更多
关键词 evaporation Optimal design Thermodynamic process Multi-objective optimization Ammonia hybrid refrigeration
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Continuous high-efficient water-electricity cogeneration over a hybrid solar-driven water evaporation system and the working mechanism
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作者 Dewei Chu 《Science China Materials》 SCIE EI CAS CSCD 2024年第7期2371-2372,共2页
With the escalation of industrialization and population growth,energy and clean water shortages pose an unprecedented threat to sustainable development.Therefore,it is imperative to develop green and effective strateg... With the escalation of industrialization and population growth,energy and clean water shortages pose an unprecedented threat to sustainable development.Therefore,it is imperative to develop green and effective strategies to address these challenges.In this context,solar-driven interfacial water evaporation(SIWE)has emerged as a highly promising low-carbon solution to the water-energy nexus[1].By locating the evaporator at airwater interfaces,heat localization can be achieved,leading to high-efficient water evaporation and freshwater production.More significantly,taking advantage of the special conditions during SIWE has opened numerous opportunities for generation of extra electrical power[2,3].Throughout the processes of SIWE,various elements such as photons,waves,capillary flow,evaporation,vapor motions,condensation,and droplet sliding can all be harnessed to produce electricity through photovoltaic,thermoelectric,thermogalvanic,pyroelectric,piezoelectric,triboelectricity and hydrovoltaic effects[3].Extensive research efforts have provided valuable insights for the development of water-electricity cogeneration(WEG)hybrid systems. 展开更多
关键词 mechanism evaporation PIEZOELECTRIC
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Systematic study of the synthesis of heavy and superheavy nuclei in 48Ca-induced fusion-evaporation reactions
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作者 Shi-Hao Zhu Tian-Liang Zhao Xiao-Jun Bao 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第7期157-172,共16页
We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applic... We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applicability of the model.To produce new proton-rich Fl and Lv isotopes through hot fusion reactions in the superheavy element region with Z≥104,we utilized the reactions ^(48)Ca+^(236,238,239) Pu and ^(48)Ca+^(242,243,244,250) Cm.However,owing to the detection limit of available equipment(0.1 pb),only 283Fl and 287−289Lv,which have the maximum evaporation residue cross section values of 0.149,0.130,9.522,and 0.309 pb,respectively,can be produced.Furthermore,to produce neutron-deficient isotopes of actinides near the proton drip line with Z=93−100,we attempted to generate the new isotopes(224−227Pu,228−232,237Cm)using the reactions ^(48)Ca+180,182,183 W and ^(48)Ca+^(184,186,187,192) Os.The maximum evaporation residue cross section values are 0.07,0.06,0.26,and 0.30 nb for the former set of reactions,and 1.96 pb,5.73 pb,12.16 pb,19.39 pb,54.79 pb,and 6.45 nb for the latter,respectively.These results are expected to provide new information for the future synthesis of unknown neutron-deficient isotopes. 展开更多
关键词 Dinuclear system(DNS)model evaporation residue cross section Neutron-deficient isotopes
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An overview of photothermal materials for solar-driven interfacial evaporation 被引量:1
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作者 Yiming Fang Huimin Gao +4 位作者 Kaiting Cheng Liang Bai Zhengtong Li Yadong Zhao Xingtao Xu 《Chinese Chemical Letters》 2025年第3期6-15,共10页
The utilization of solar-driven interfacial evaporation technology is highly important in addressing the energy crisis and water scarcity,primarily because of its affordability and minimal energy usage.Enhancing the p... The utilization of solar-driven interfacial evaporation technology is highly important in addressing the energy crisis and water scarcity,primarily because of its affordability and minimal energy usage.Enhancing the performance of solar energy evaporation and minimizing material degradation during application can be achieved through the design of novel photothermal materials.In solar interfacial evaporation,photothermal materials exhibit a wide range of additional characteristics,but a systematic overview is lacking.This paper encompasses an examination of various categories and principles pertaining to photothermal materials,as well as the structural design considerations for salt-resistant materials.Additionally,we discuss the versatile uses of this appealing technology in different sectors related to energy and the environment.Furthermore,potential solutions to enhance the durability of photothermal materials are also highlighted,such as the rational design of micro/nano-structures,the use of adhesives,the addition of anti-corrosion coatings,and the preparation of self-healing surfaces.The objective of this review is to offer a viable resolution for the logical creation of high-performance photothermal substances,presenting a guide for the forthcoming advancement of solar evaporation technology. 展开更多
关键词 Solar-driven interfacial evaporation Desalination Wastewater treatment Photothermal material SALT-RESISTANCE Durability
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Laser melting,evaporation,and fragmentation of nanoparticles:Experiments,modeling,and applications
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作者 Victor K.Pustovalov 《Nanotechnology and Precision Engineering》 2025年第2期146-191,共46页
This review examines the processes of laser heating,melting,evaporation,fragmentation,and breakdown of metal nanoparticles,as well as the dependences and values of the threshold laser parameters that initiate these pr... This review examines the processes of laser heating,melting,evaporation,fragmentation,and breakdown of metal nanoparticles,as well as the dependences and values of the threshold laser parameters that initiate these processes.Literature results are analyzed from experimental studies of these processes with gold,silver,and other nanoparticles,including laser surface melting and evaporation of nanoparticles and Coulomb fragmentation of nanoparticles by ultrashort laser pulses.A theoretical model and description of the thermal mechanisms of mentioned processes with metal(solid)nanoparticles in a liquid(solid)medium,initiated by the action of laser pulses with the threshold fluences,are presented.Comparison of the obtained results with experimental data confirms the accuracy of the model and makes it possible to use them to evaluate the parameters of laser thermal processing of nanoparticles.Applications of the processes include the laser melting,reshaping,and fragmentation of nanoparticles,the formation of nanostructures and nanonetworks,the laser processing of nanoparticles located on substrates,and their cladding on surfaces in various laser nanotechnologies.The use of laser ignition,combustion,and incandescence of nanoparticles is discussed,as is the use of nanoparticle-triggered laser breakdown for spectroscopy.These laser processes are used in photothermal nanotechnologies,nanoenergy,laser processing of nanoparticles,nonlinear optical devices,high-temperature material science,etc.In general,this review presents a modern picture of the state of laser technology and high-temperature processes with nanoparticles and their applications,being focused on the latest publications with an emphasis on recent results from 2021-2024. 展开更多
关键词 Laser HEATING MELTING evaporation FRAGMENTATION NANOPARTICLE MODELING
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Experimental and model research on the evaporation of loess-like sulfate saline soil considering the influence of initial salt content
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作者 ZHANG Yabin CHOU Yaling +2 位作者 ZHAO Dong WANG Lijie ZHANG Peng 《Journal of Arid Land》 2025年第7期912-932,共21页
Intense evaporation in areas with loess-like sulfate saline soils has resulted in significant ecological challenges that include water shortages and soil salinization.Investigating evaporation rate in loess-like sulfa... Intense evaporation in areas with loess-like sulfate saline soils has resulted in significant ecological challenges that include water shortages and soil salinization.Investigating evaporation rate in loess-like sulfate saline soils under varying salt contents carries crucial implications for understanding regional water loss processes,predicting soil salinization advancement,and formulating effective ecological management strategies.Therefore,this study sampled the loess-like sulfate saline soil that is widely distributed in western China as experimental materials and investigated the impact of different initial salt contents(0.00%,0.50%,1.50%,3.00%,and 5.00%)on the evaporation rate,water content,and temperature of soil.The results showed that the evaporation rate decreased with increasing initial salt content.After a salt accumulation layer formed on the soil surface,the water content of the surface soil fluctuated.An increase in the initial salt content resulted in a corresponding increase in the surface temperature.Considering the evaporation characteristics of loess-like sulfate saline soil and the impact of an anomalous increase in surface soil water content on soil surface resistance,this study proposed a modified evaporation model on the basis of Fujimaki's evaporation model of saline soil by introducing a correction coefficientβto modify the soil surface resistance.A comparison of the calculated evaporation rates before and after the modification with the measured evaporation rates revealed a significant improvement in the calculation accuracy of the modified model,indicating that the modified model is capable of more accurately simulating the evaporation rate of sulfate saline soil with different initial salt contents.This paper proposes an effective method for calculating the evaporation rate of loess-like sulfate saline soils,providing a theoretical basis for evaporation research in saline soil. 展开更多
关键词 loess-like sulfate saline soil evaporation rate salt accumulation layer salt crystallization evaporation model soil surface resistance air resistance
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Smoothed Particle Hydrodynamics(SPH)Simulations of Drop Evaporation:A Comprehensive Overview of Methods and Applications
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作者 Leonardo Di G.Sigalotti Carlos A.Vargas 《Computer Modeling in Engineering & Sciences》 2025年第3期2281-2337,共57页
The evaporation ofmicrometer and millimeter liquid drops,involving a liquid-to-vapor phase transition accompanied by mass and energy transfer through the liquid-vapor interface,is encountered in many natural and indus... The evaporation ofmicrometer and millimeter liquid drops,involving a liquid-to-vapor phase transition accompanied by mass and energy transfer through the liquid-vapor interface,is encountered in many natural and industrial processes as well as in numerous engineering applications.Therefore,understanding and predicting the dynamics of evaporating flows have become of primary importance.Recent efforts have been addressed using the method of Smoothed Particle Hydrodynamics(SPH),which has proven to be very efficient in correctly handling the intrinsic complexity introduced by the multiscale nature of the evaporation process.This paper aims to provide an overview of published work on SPH-based simulations related to the evaporation of drops suspended in static and convective environments and impacting on heated solid surfaces.After a brief theoretical account of the main ingredients necessary for the modeling of drop evaporation,the fundamental aspects of SPH are revisited along with the various existing formulations that have been implemented to address the challenges imposed by the physics of evaporating flows.In the following sections,the paper summarizes the results of SPH-based simulations of drop evaporation and ends with a few comments on the limitations of the current state-of-the-art SPHsimulations and future lines of research. 展开更多
关键词 Drop evaporation surface tension heat and mass transfer phase separation smoothed particle hydrodynamics(SPH) boiling evaporation explosive vaporization droplet/wall interaction
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Development of a capillary bundle evaporation advanced mathematical modeling for 1,2-propylene glycol-glycerin mixtures in porous media
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作者 Bingbing Li Jiantong Li +3 位作者 Side Ren Shuo Gu Zhanjian Liu Liyan Liu 《Chinese Journal of Chemical Engineering》 2025年第4期261-273,共13页
Porous liquid-conducting micro-heat exchangers have garnered considerable attention for their role in efficient heat dissipation in small electronic devices.This demand highlights the need for advanced mathematical mo... Porous liquid-conducting micro-heat exchangers have garnered considerable attention for their role in efficient heat dissipation in small electronic devices.This demand highlights the need for advanced mathematical models to optimize the selection of mixed heat exchange media and equipment design.A capillary bundle evaporation model for porous liquid-conducting media was developed based on the conjugate mass transfer evaporation rate prediction model of a single capillary tube,supplemented by mercury injection experimental data.Theoretical and experimental comparisons were conducted using 1,2-propanediol-glycerol(PG-VG)mixtures at molar ratios of 1:9,3:7,5:5,and 7:3 at 120,150,and 180℃.The Jouyban-Acree model was implemented to enhance the evaporation rate predictions.For the 7:3 PG-VG mixture at 180℃under the experimental conditions of the thermal medium,the model's error reduced from 16.75%to 10.84%post-correction.Overall,the mean relative error decreased from 11.76%to 5.98%after correction. 展开更多
关键词 evaporation in porous media Capillary bundle model 1 2-propylene glycol-glycerin evaporation rate
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Drainage-induced arch hydrogel-based interfacial evaporator drives long-term stable solar evaporation
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作者 Zexiang Zhao Junqi Li +7 位作者 Fan Wang Puxin Tan Lu Wang Bo Wang Jingjing Jin Xiaoxue Wang Wenhe Zhang Chengbing Wang 《Journal of Energy Chemistry》 2025年第5期540-550,共11页
Hydrogel has developed into a very important platform in solar interface evaporator.However,the current hydrogel evaporators are usually three-dimensional evaporators,which will consume a lot of raw materials.Thus,a n... Hydrogel has developed into a very important platform in solar interface evaporator.However,the current hydrogel evaporators are usually three-dimensional evaporators,which will consume a lot of raw materials.Thus,a new two-dimensional hydrogel evaporator is urgently needed to alleviate this problem.Here,a double layer hydrogel evaporator was designed by twice vacuum filtration.Furthermore,through the arched design and the introduction of concentrated brine drainage system,the hydrogel evaporator has enhanced water transportation and tailored water transportation path.Such a unique drainage evaporation system greatly improves the stability of the evaporator.Thereby,a good balance is established between photothermal conversion and water supply,and solar energy is utilized efficiently.It can remain stable in continuous evaporation for up to 12 h with an excellent evaporation rate of 2.70 kg m^(-2)h^(-1)under 1 sun irradiation.Meanwhile,the drainage system realized the 1.8×10^(-10)mol m^(-2)s^(-1)diffusion flux of concentrated brine.Through one-time freeze-drying preparation,an arch-shaped drainage evaporator was used to prepare an evaporation area of more than 20 cm^(2).With the self-made condensate collecting device in outdoor environment,the fresh water yield reaches 7.5 L m^(-2)d^(-1).This provides a new scheme for building a new hydrogel evaporator and solving the fresh water crisis. 展开更多
关键词 Solar evaporation Drainage system Arch hydrogel SALT-TOLERANT ALGINATE
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Effect of Photoresist Biomimetic Surface Roughness on Droplet Evaporation Dynamics
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作者 Zhihao Zhang Xiangcheng Gao Yuying Yan 《Journal of Bionic Engineering》 2025年第3期1338-1351,共14页
Control of the wetting properties of biomimetic functional surfaces is a desired functionality in many applications.In this paper,the photoresist SU-8 was used as fabrication material.A silicon wafer was used as a sub... Control of the wetting properties of biomimetic functional surfaces is a desired functionality in many applications.In this paper,the photoresist SU-8 was used as fabrication material.A silicon wafer was used as a substrate to prepare a biomimetic surface with different surface roughness and micro-pillars arranged in array morphology.The evaporation dynamics and interfacial heat transfer processes of deionised water droplets on the bioinspired microstructure surface were experimentally studied.The study not only proves the feasibility of preparing hydrophilic biomimetic functional surfaces directly through photoresist materials and photolithography technology but also shows that by adjusting the structural parameters and arrangement of the surface micro-pillar structure,the wettability of the biomimetic surface can be significantly linearly regulated,thereby effectively affecting the heat and mass transfer process at the droplet liquid-vapour interface.Analysis of the results shows that by controlling the biomimetic surface microstructure,the wettability can be enhanced by about 22%at most,the uniformity of the temperature distribution at the liquid-vapour interface can be improved by about 34%,and the average evaporation rate can be increased by about 28%.This study aims to provide some guidance for the research on bionic surface design based on photoresist materials. 展开更多
关键词 Biomimetics Droplet evaporation Surface roughness WETTABILITY Interfacial phenomenon
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Efficient fabrication of fabric-based Janus interfacial evaporator via melt centrifugal spinning for simultaneous solar evaporation,pollutant degradation,antibacterial action,and thermoelectric output
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作者 Yingying Chen Rong Zhou +5 位作者 Hao Wang Xiaowei Ning Yu Du Heng Xie Ting Wu Jinping Qu 《Journal of Energy Chemistry》 2025年第6期385-394,I0009,共11页
Fiber fabrics have been wildly utilized for solar interracial evaporators to address freshwater scarcity.However,the complex and expensive manufacturing processes remain limited to their scalable development.Herein,a ... Fiber fabrics have been wildly utilized for solar interracial evaporators to address freshwater scarcity.However,the complex and expensive manufacturing processes remain limited to their scalable development.Herein,a fabric-based Janus interracial evaporator is efficiently fabricated on a large scale by integrating an extremely innovative self-designed melt-centrifugal spinning technology with spray coating technology.The prepared fabric-based Janus interfacial evaporator has differential hydrophilicity,uneven surfaces,and channels that allow moisture escape.Benefiting from the excellent photothermai conversion of graphene oxide and the charge transfer actions of titanium dioxide,such a multifunction evaporator can reach a high evaporation rate of 1.72 kg m^(-2)h^(-1)under 1 sun irradiation,a superior antibacterial rate of 99%,excellent photocatalytic degradation,and effective thermoelectric ability simultaneously.Moreover,it also shows fantastic performance in salt resistance,recyclable evaporation,and real desalination,This work demonstrates a high-efficiency,cost-effective,multifunctional,and scalable strategy for high-performance fiber fabrics solar interfacial evaporation. 展开更多
关键词 Melt-centrifugal spinning Solar interfacial evaporation Thermoelectric ANTIBACTERIAL Photocatalytic degradation
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Experimental Method for Studying the Effect of Dissolved Substances on the Evaporation Rate of Watwer Droplets Suspended in Air
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作者 Alexander A.Fedorets Eduard E.Kolmakov +4 位作者 Anna V.Nasyrova Dmitry N.Medvedev Vyacheslav O.Mayorov Vladimir Yu.Levashov Leonid A.Dombrovsky 《Frontiers in Heat and Mass Transfer》 2025年第4期1091-1102,共12页
A new experimental method is developed to investigate the effect of dissolved substances on the evaporation rate of small water droplets suspended in the atmosphere.The laboratory setup is based on converting a genera... A new experimental method is developed to investigate the effect of dissolved substances on the evaporation rate of small water droplets suspended in the atmosphere.The laboratory setup is based on converting a generated droplet jet of complex structure into a directed flow of evaporating droplets falling in a vertical tube.Images of falling droplets captured by a high-speed camera through a window in the vertical channel wall are used to determine the sizes and velocities of individual droplets.The computational modeling of droplet motion and evaporation proved useful at all stages of the experimental work:from selecting the position of the vertical channel to processing the experimental data.It was found that even a 0.1%mass concentration of the dissolved ionic salt KCl has a considerable effect on decreasing the evaporation rate of the droplets.In contrast,a typical fungicide with a mass concentration of 2.5%has only a slight impact on the evaporation rate.The laboratory results enabled the authors to refine the evaporation model of water droplets to account for the presence of dissolved substances.Modified models of this type are expected to be useful in controling crop spraying and also in other potential applications. 展开更多
关键词 Droplets evaporation crop spraying experimental method physical model
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Evaporation of sub-millimeter flying dinitrogen tetroxide droplet under high temperature and pressure:Experimental measurement and theoretical modeling
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作者 Lihan FEI Wu ZHU +3 位作者 Yuyuan ZHANG Peng ZHANG Zuohua HUANG Chenglong TANG 《Chinese Journal of Aeronautics》 2025年第5期80-91,共12页
The evaporation behaviors are crucial for the flame location estimation in liquid rocketengines.This work,for the first time,experimentally reports the sub-millimeter droplet evaporationcharacteristics of the corrosiv... The evaporation behaviors are crucial for the flame location estimation in liquid rocketengines.This work,for the first time,experimentally reports the sub-millimeter droplet evaporationcharacteristics of the corrosive dinitrogen tetroxide(NTO,one prevailing hypergolic oxidizer)athigh ambient pressure up to 4.5 MPa.An in-house corrosion-resistant droplet generator is usedto generate isolated flying droplets of sub-millimeter size,which are then exposed in a gas environ-ment with temperatures between 1010 K and 1210 K and pressures in the range between 2.0 MPaand 4.5 MPa,provided by an optical rapid compression machine.Parallelly,a theoretical modelconsidering both the droplet ambient convection and the NTO dissociation is developed.Resultsindicate that firstly,the present theoretical model that considers the transient droplet-ambient con-vection as well as the temperature and pressure dependent rate of dissociation shows good agree-ment with the experimentally observed droplet lifetime.In addition,the flying droplets velocityregress gradually due to momentum exchange with the ambient,which is more prominent at higherpressure.The evaporation caused droplet size reduction is consistent with the classical D^(2)-law pre-diction,in the present temperature and pressure range.Finally,higher temperature and pressureaccelerate the evaporation and an empirical correlation for the temperature and pressure dependentevaporation rate constant is proposed,which shows good agreement with experiment and simula-tion results. 展开更多
关键词 DROPS evaporation Flying isolated droplets Dinitrogen tetroxide High pressure effect
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Pickering Emulsion-Driven MXene/Silk Fibroin Hydrogels with Programmable Functional Networks for EMI Shielding and Solar Evaporation
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作者 Guang Yin Jing Wu +3 位作者 Chengzhang Qi Xinfeng Zhou Zhong-Zhen Yu Hao-Bin Zhang 《Nano-Micro Letters》 2025年第12期369-382,共14页
Flexible and conformable nanomaterial-based functional hydrogels find promising applications in various fields.However,the controllable manipulation of functional electron/mass transport networks in hydrogels remains ... Flexible and conformable nanomaterial-based functional hydrogels find promising applications in various fields.However,the controllable manipulation of functional electron/mass transport networks in hydrogels remains rather challenging to realize.We describe a general and versatile surfactant-free emulsion construction strategy to customize robust functional hydrogels with programmable hierarchical structures.Significantly,the amphipathy of silk fibroin(SF)and the reinforcement effect of MXene nanosheets produce sable Pickering emulsion without any surfactant.The followed microphase separation and self-cross-linking of the SF chains induced by the solvent exchange convert the composite emulsions into high-performance hydrogels with tunable microstructures and functionalities.As a proof-of-concept,the controllable regulation of the ordered conductive network and the water polarization effect confer the hydrogels with an intriguing electromagnetic interference shielding efficiency(~64 dB).Also,the microstructures of functional hydrogels are modulated to promote mass/heat transfer properties.The amino acids of SF and the surface terminations of MXene help reduce the enthalpy of water evaporation and the hierarchical structures of the hydrogels accelerate evaporation process,expecting far superior evaporation performance(~3.5 kg m^(-2)h^(-1))and salt tolerance capability compared to other hydrogel evaporators.Our findings open a wealth of opportunities for producing functional hydrogel devices with integrated structure-dependent properties. 展开更多
关键词 MXene Silk fibroin Pickering emulsion Electromagnetic interference shielding Solar-driven evaporation
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Bimetallic composite carbon fiber with persulfate mediation for intercepting volatile organic compounds during solar interfacial evaporation
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作者 Yuling Ma Dongqing Liu +4 位作者 Tao Zhang Chengjie Song Dongmei Liu Peizhi Wang Wei Wang 《Chinese Chemical Letters》 2025年第3期151-155,共5页
Solar interfacial evaporation(SIE),is currently one of the most potential water supply technologies in the remote,insular,and disaster-stricken areas.However,the existence of volatile organic compounds(VOCs)in water d... Solar interfacial evaporation(SIE),is currently one of the most potential water supply technologies in the remote,insular,and disaster-stricken areas.However,the existence of volatile organic compounds(VOCs)in water deteriorates the distillate quality,threatening human health.Herein,we constructed a carbonbased bimetallic(C/FeCo)photothermal membrane by electrospinning technique.Results illustrated that the membrane can catalytically degrade VOCs during SIE with persulfate(PDS)mediation.PDS,as well as phenol,was mainly reacted on the interface of the photothermal membrane instead of in the bulk solution.The interception efficiency of phenol achieved nearly 100%using the C/FeCo membrane during SIE.Hydroxyl radical(•OH),sulfate radical(SO_(4)•−),superoxide radical(O_(2)•−),and singlet oxygen(^(1)O_(2))were identified as the main active substances to degrade VOCs.We also conducted SIE experiments using actual river water to evaluate the practical performance of the C/FeCo membrane.This work holds the promise of VOCs interception during SIE and enlarges the application of solar distillation in water/wastewater treatment. 展开更多
关键词 Solar distillation Interfacial evaporation Volatile organic compounds Bimetallic composite carbon fiber Persulfate mediation
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Incorporating Co_(3)O_(4)/C modified MnO_(x)/SiO_(2) into tailored sponge for bifunctional photothermal water evaporation and pollutant degradation
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作者 Ya-Rao Gao Hong-Yao Zhao +6 位作者 Meng-Ting Liu Qian-Nan Liu Yan-Yun Wang Lu-Lu Li Jian-Wei Yuan Yi-Yan Song Fu Yang 《Rare Metals》 2025年第2期1122-1138,共17页
In this study,cobalt-incorporated polydopamine coating onto Mn-modified mesoporous silica and successive graphitization treatment make the resulting composite afford abundant porosity,multiple metal active species,pol... In this study,cobalt-incorporated polydopamine coating onto Mn-modified mesoporous silica and successive graphitization treatment make the resulting composite afford abundant porosity,multiple metal active species,polar N sites,and excellent light-to-heat conversion ability.The controlled graphitization temperature was optimized to improve the activity state of metal species.The results reveal that Co_(3)O_(4) nanoparticles incorporated thin-layer carbon formed onto the Mn-confined mesoporous silica,and more Co(Ⅱ)and Mn(Ⅲ)were generated in the MS-Co-500N_(2) compared to MS-Co-500Air,which could cause the accelerated reaction cycles in the potassium peroxymonosulfate complex salt(PMS)activation.The degradation experiments demonstrated that the catalyst almost completely degraded biphenol A within 10 min with the reaction rate constant of 0.56 min−1,nearly 205 times enhancement compared to the MS-Co-500Air.The free radicals trapping and quenching control demonstrated the dominant role of ^(1)O_(2) and·O_(2) in the degradation process.Due to the efficient incorporation of Co_(3)O_(4) nanoparticles and thin-layer carbon,the photothermal conversion properties were explored and utilized for solar-driving interface water evaporation and cleanwater recovery.To explore the practical application possibility in treating complicated polluted wastewater,the MS-Co-500N_(2) materials were fixed on the melamine sponge by Ca ions-trigger alginate crosslinking strategy,and the integrated monolith evaporator shows an excellent water evaporation performance(1.52 kg·m^(−2)·h^(−1))and synchronous pollutant removal in biphenol A(94%,10 min),carbamazepine(92%,10 min),oxytetracycline(84%,20 min)and norfloxacin(84%,20 min). 展开更多
关键词 Bimetallic synergy Advanced oxidation processes(AOPs) Photothermal conversion Solar water evaporation
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