This wok proposed the extraction distillation coupled pervaporation(ED+PV) technology process using two different solvents to separate isopropanol(IPA) and diisopropyl ether(DIPE) from DIPE/IPA/H_(2)O ternary heteroge...This wok proposed the extraction distillation coupled pervaporation(ED+PV) technology process using two different solvents to separate isopropanol(IPA) and diisopropyl ether(DIPE) from DIPE/IPA/H_(2)O ternary heterogeneous azeotropes in industrial wastewater from the synthesis of isopropanol in this study.Based on strict design specifications, simulation and sequential iteration methods are used for process design and optimization. Compared to the ethylene glycol(EG)-EG+H_(2)O process and the 1,3-propanediol(PDO)-IPA+H_(2)O process, the total annual cost(TAC) of the EG-IPA+H_(2)O process decreased by 20.76% and 7.86%(PDO). Compared to the EG-EG+H_(2)O process, the TAC of the PDO-IPA+H_(2)O process reduced 14%, but the global warming potential(GWP) and human toxicity of the PDO-IPA+H_(2)O process increased 11.3% and 4.07% respectively. Compared to the PDO-IPA+H_(2)O process, the EG-IPA+H_(2)O process saves 7.86%(TAC), 9.78%(GWP) and 9.85%(human toxicity). The ED+PV process with EG is superior to PDO in factors of TAC, energy consumption, human toxicity and environment. The EG-IPA+H_(2)O process changed the separation order of the products of the multi-azeotropic system, reduced the cost and energy conservation of the system, and enhanced the environmental protection evaluation of the process, is the best process through life cycle assessment for analyzing the economy, energy conservation, environmental assessment and human toxicity, designing cleaner products, controlling waste discharge, and promoting the chemical purification industry. This work provides a new process design and optimized separation ideas, will have a good guiding significance for the research and application separation of multi-azeotropic mixture with mixed solvents in organic wastewater from the cleaner chemical production, has been up to standard wastewater discharge process, and realized the development goal of carbon peak and carbon neutrality in the sustainable development of chemical clean industry.展开更多
Polybromodiphenyl ethers(PBDEs),the widely used flame retardants,are common contaminants in surface soils at e-waste recycling sites.The association of PBDEs with soil colloids has been observed,indicating the potenti...Polybromodiphenyl ethers(PBDEs),the widely used flame retardants,are common contaminants in surface soils at e-waste recycling sites.The association of PBDEs with soil colloids has been observed,indicating the potential risk to groundwater due to colloid-facilitated transport.However,the extent to which soil colloidsmay enhance the spreading of PBDEs in groundwater is largely unknown.Herein,we report the co-transport of decabromodiphenyl ester(BDE-209)and soil colloids in saturated porous media.The colloids released froma soil sample collected at an e-waste recycling site in Tianjin,China,contain high concentration of PBDEs,with BDE-209 being the most abundant conger(320±30 mg/kg).The colloids exhibit relatively high mobility in saturated sand columns,under conditions commonly observed in groundwater environments.Notably,under all the tested conditions(i.e.,varying flow velocity,pH,ionic species and ionic strength),the mass of eluted BDE-209 correlates linearly with that of eluted soil colloids,even though the mobility of the colloids varies markedly depending on the specific hydrodynamic and solution chemistry conditions involved.Additionally,the mass of BDE-209 retained in the columns also correlates strongly with themass of retained colloids.Apparently,the PBDEs remain bound to soil colloids during transport in porous media.Findings in this study indicate that soil colloidsmay significantly promote the transport of PBDEs in groundwater by serving as an effective carrier.This might be the reason why the highly insoluble and adsorptive PBDEs are found in groundwater at some PBDE-contaminated sites.展开更多
Gas wells often encounter blockages in gas recovery channels owing to fluid accumulation during the later stages of extraction,which adversely affects subsequent recovery efforts.These undesirable conditions(e.g.,high...Gas wells often encounter blockages in gas recovery channels owing to fluid accumulation during the later stages of extraction,which adversely affects subsequent recovery efforts.These undesirable conditions(e.g.,high condensate content,high temperature,and high salinity)often affect foaming agent performance.In this study,surfactants were screened using an airflow method that closely resembles field treatment method.Notably,alcohol ether sulfates(AE_(n)S)with various polyoxyethylene(EO)units demonstrated exceptional performance in terms of liquid unloading efficiency and foam stability.At 80℃,the unloading efficiency of AE_(n)S with two EO units(AE_(2)S)in a high NaCl mass concentration(up to 200 g/L)and high condensate volume fraction(up to 20%)reached 84%.The dynamic surface tension and interfacial tension measured at the same temperature were used to analyze the influence of the diffusion rate and interfacial characteristics on the AE_(n)S foam,while the viscosity and liquid film thickness measurements reflected the mechanical strength and liquid-carrying capacity.In addition,transmission electron microscopy(TEM)revealed that AE_(2)S formed“dendritic”micellar aggregates at a high NaCl mass concentration,which significantly enhanced the viscosity and stability of the foam.The interactions among AE_(n)S,NaCl,and H2O were analyzed using molecular dynamics,and it was confirmed from a molecular mechanics perspective that a stable structure can form among the three,contributing to the foam stability.These findings demonstrate the significant potential of the AE_(2)S foam for gas well deliquification.展开更多
Asplactones A-E(1-5),five unique diphenyl ether hybrids,along with two rare spiro-diphenyl ethers,aspviolaceols A(6)and B(7),were isolated and characterized from Aspergillus sp.F1-8A,an endophytic fungus associated wi...Asplactones A-E(1-5),five unique diphenyl ether hybrids,along with two rare spiro-diphenyl ethers,aspviolaceols A(6)and B(7),were isolated and characterized from Aspergillus sp.F1-8A,an endophytic fungus associated with the parotoid glands of Bufo gargarizans Cantor.Compounds 1-5 represent the first examples of diphenyl ether hybrids fused with unusual moieties,including conjugatedγ-butyrolactone and cyclopentenone.Compounds 6 and 7 are the first known natural spiro-diphenyl ethers,with 6 featuring an uncommon 6/6/6/6-membered carbon skeleton,and 7 possessing a distinct 6/6/6/6/6/6-membered diphenyl ether spiro-heterodimer carbon framework.Structural elucidation was performed using a combination of spectroscopic techniques,X-ray crystallography,and quantum-chemical calculations,and plausible biosynthetic pathways were proposed.Biologically,compounds 1,2,4,6,and 7 exhibited antioxidant activity comparable to or surpassing that of vitamin C in 1,1-diphenyl-2-picrylhydrazyl(DPPH)and 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonate)(ABTS),and ferric reducing power assays.They also significantly improved cell viability in H2O2-induced oxidative injury assays using A549 cells.展开更多
Electrochemical water splitting represents a sustainable technology for hydrogen(H_(2))production.However,its large-scale implementation is hindered by the high overpotentials required for both the cathodic hydrogen e...Electrochemical water splitting represents a sustainable technology for hydrogen(H_(2))production.However,its large-scale implementation is hindered by the high overpotentials required for both the cathodic hydrogen evolution reaction(HER)and the anodic oxygen evolution reaction(OER).Transition metal-based catalysts have garnered significant research interest as promising alternatives to noble-metal catalysts,owing to their low cost,tunable composition,and noble-metal-like catalytic activity.Nevertheless,systematic reviews on their application as bifunctional catalysts for overall water splitting(OWS)are still limited.This review comprehensively outlines the principal categories of bifunctional transition metal electrocatalysts derived from electrospun nanofibers(NFs),including metals,oxides,phosphides,sulfides,and carbides.Key strategies for enhancing their catalytic performance are systematically summarized,such as heterointerface engineering,heteroatom doping,metal-nonmetal-metal bridging architectures,and single-atom site design.Finally,current challenges and future research directions are discussed,aiming to provide insightful perspectives for the rational design of high-performance electrocatalysts for OWS.展开更多
Ion-solvaing membranes(ISMs)have received extensive attention in recent years as a key component in electrochemical energy conversion and storage devices.This article provides an overview of structural composition,per...Ion-solvaing membranes(ISMs)have received extensive attention in recent years as a key component in electrochemical energy conversion and storage devices.This article provides an overview of structural composition,performance advan-tages,research progress,ion conduction mechanism and existing issues of ISMs,primarily classifying them according to the matrix structure.A detailed analysis of performance enhancement methods,key performance indicators of ISMs and performance influencing factors is also presented.The article contributes to further optimizing the design and application of ion-solvation membranes,providing theoretical support for the development of fields such as hydrogen production through electrolysis of water and electrochemical energy in the future.展开更多
The Arno River Basin(Central Italy)is affected by a considerable anthropogenic pressure due to the presence of large cities and widespread industrial and agricultural practices.In this work,26 water samples from the A...The Arno River Basin(Central Italy)is affected by a considerable anthropogenic pressure due to the presence of large cities and widespread industrial and agricultural practices.In this work,26 water samples from the Arno River and its main tributaries were analyzed to assess the water pollution status.The geochemical composition of the Arno River changes from the source(dominated by a Ca-HCO_(3) facies)to the mouth(where a Na-Cl(SO4)chemistry prevails)with an increasing quality deterioration,as suggested by the Chemical Water Quality Index,due to anthropogenic contributions and seawater intrusion before flowing into the Ligurian Sea.The Ombrone and Usciana tributaries introduce anthropogenic pollutants into the Arno River,whilst Elsa tributary supplies significant contents of geogenic sulfate.The concentrations of dissolved nitrate and nitrite(up to 63 and 9 mg/L,respectively)and the respective isotopic values of𝛿15N and𝛿18O were also determined to understand origin and fate of the N-species in the Arno River Basin surface waters.The combined application of𝛿15N-NO_(3) and𝛿18O-NO_(3) and N-source apportionment modelling allowed the identification of soil organic nitrogen and sewage and domestic wastes as primary sources for dissolved NO_(3)-.The𝛿15N-NO_(2) and𝛿18O-NO_(2) values suggest that the nitrification process affects the ARB waters,thus controlling the abundances and proportion of the N-species.Our work indicates that additional efforts are needed to improve management strategies to reduce the release of nitrogenated species to the surface waters of the Arno River Basin,since little progress has been made from the early 2000s.展开更多
Unequal virtual water transfer may aggravate local water scarcity risk.However,the quantitative confirmation of a clear geographic convergence between virtual water transfer and water scarcity risk remains undetermine...Unequal virtual water transfer may aggravate local water scarcity risk.However,the quantitative confirmation of a clear geographic convergence between virtual water transfer and water scarcity risk remains undetermined.We present an analytical framework that reveals the spatial matching between global water scarcity risk and virtual water trade inequality.This framework integrates a three-dimensional water scarcity risk assessment,hybrid input-output analysis,pollution trade term construction,and geographic convergence identification.The framework is applied to 123 countries for long-term validation from 1991 to 2021.We show that despite global improvements in water efficiency and security,countries exceeding the maximum water vulnerability threshold have increased by 50%.South Asia is the largest net exporter of virtual water.Central Asia exhibits the most pronounced virtual water trade inequality.To achieve the same economic growth,Central Asia needs to pay several times the local water consumption costs of developed regions(15.9−83.6 times,2021).In the past 30 years,the average geographic convergence index exceeded 0.8.Countries facing severe water scarcity also exhibit pronounced inequalities in virtual water trade,indicating that a significant geographic convergence relationship exists.Effectively responding to this unsustainable relationship necessitates balancing both domestic resource risk management and global virtual water trade regulation.展开更多
To maintain soil quality under long-term saline water irrigation,the influence of manure on soil physical properties was examined.Long-term saline irrigation has been conducted from 2015 to 2024 at the Nanpi Eco-Agric...To maintain soil quality under long-term saline water irrigation,the influence of manure on soil physical properties was examined.Long-term saline irrigation has been conducted from 2015 to 2024 at the Nanpi Eco-Agricultural Experimental Station of Chinese Academy Sciences in the Low Plain of the North China Plain,comprising four irrigation treatments:irrigation once at the jointing stage for winter wheat with irrigation water containing salt at fresh water,3,4 and 5 g·L^(–1),and maize irrigation at sowing using fresh water.Manure application was conducted under all irrigation treatments,with treatments without manure application used as controls.The results showed that under long-term irrigation with saline water,the application of manure increased the soil organic matter content,exchangeable potassium,available phosphorus,and total nitrogen content in the 0–20 cm soil layer by 46.8%,117.0%,75.7%,and 45.5%,respectively,compared to treatments without manure application.The application of manure reduced soil bulk density.It also increased the proportion of water-stable aggregates and the abundance of bacteria,fungi,and actinomycetes in the tillage soil layer compared to the controls.Because of the salt contained in the manure,the application of manure had dual effects on soil salt content.During the winter wheat season,manure application increased soil salt content.The salt content was significantly reduced during the summer maize season,owing to the strong salt-leaching effects under manure application,resulting in a smaller difference in salt content between the manure and non-manure treatments.During the summer rainfall season,improvements in soil structure under manure application increased the soil desalination rate for the 1 m top soil layer.The desalination rate for 0–40 cm and 40–100 cm was averagely by 39.1%and 18.9%higher,respectively,under manure application as compared with that under the nomanure treatments.The yield of winter wheat under manure application was 0.12%lower than that of the control,owing to the higher salt content during the winter wheat season.In contrast,the yield of summer maize improved by 3.9%under manure application,owing to the increased soil nutrient content and effective salt leaching.The results of this study indicated that manure application helped maintain the soil physical structure,which is important for the long-term use of saline water.In practice,using manure with a low salt content is suggested to reduce the adverse effects of saline water irrigation on soil properties and achieve sustainable saline water use.展开更多
In Bom Jesus Municipality,a cool breeze drifts in from the Kwanza River,softening the edges of a town marked by landmarks such as António Agostinho Neto International Airport.Yet beneath Luanda’s scenic faç...In Bom Jesus Municipality,a cool breeze drifts in from the Kwanza River,softening the edges of a town marked by landmarks such as António Agostinho Neto International Airport.Yet beneath Luanda’s scenic façade,daily life for many residents is defined by a persistent struggle for water.“We have to walk 5 to 15 km to access water.This perennial problem is so depressing.What’s more,the lack of clean water causes waterborne diseases in our community,”local resident Isabel Fernando told ChinAfrica.展开更多
The mining industry is frequently subjected to various disasters,one of the major concerns is water-related disasters,particularly seam floor water inrush.These disasters pose significant threats to the safety and pro...The mining industry is frequently subjected to various disasters,one of the major concerns is water-related disasters,particularly seam floor water inrush.These disasters pose significant threats to the safety and production of deep coal mines.The primary reason for this is that the fracturing of the rock mass induces the formation of a fluid(water)with both kinetic and potential energy.In this paper,a novel water inrush mechanism for deep floor failure due to water hammer effects is proposed based on the Xingdong coal mine in China.The water hammer pressure within rock pore channels has a different impact on the surrounding rock,leading to the degradation of the rock mass channel through repeated conduction and instantaneous cutoff.To further investigate this phenomenon,a progressive corrosion fracture mechanics(PCFM)model induced by a water hammer is established.The results show that the water hammer pressure caused by instantaneous channel truncation increases with increasing water flow velocity.The chemical damage factor(i.e.,stress corrosion fracture)is also incorporated into the Dugdale-Barenblatt(D-B)model to analyze the factors influencing the PCFM.These findings indicate that the greater the degree of damage is,the more likely the concealed fault is to experience water inrush.Finally,methods for controlling water inrush caused by the water hammer effects of deep floors are proposed.The failure mechanisms of the water hammer and the PCFM provide theoretical and practical guidance for controlling water inrush from the deep floor.展开更多
In permafrost regions of the QinghaiXizang Plateau,embankments of the Qinghai-Xizang Highway and Qinghai-Xizang Railway experiencing roadside water accumulation exhibit more pronounced engineering deteriorations.A wid...In permafrost regions of the QinghaiXizang Plateau,embankments of the Qinghai-Xizang Highway and Qinghai-Xizang Railway experiencing roadside water accumulation exhibit more pronounced engineering deteriorations.A widely accepted view is that the accumulated water adjacent to the embankment possesses substantial thermal energy,which accelerates the degradation-even disappearance-of the underlying permafrost.Moreover,the presence of roadside water keeps the embankment soil in a persistently high-moisture state,thereby making the frozen-soil embankment more susceptible to deformation under traffic loading.However,in the permafrost regions of the QinghaiXizang Plateau,deteriorations of embankments affected by roadside water are more commonly manifested as undulating pavement surfaces,and extensive crack networks appear on the embankment crest even where thermosyphons are installed.These manifestations are not fully consistent with the deterioration mechanisms proposed by existing viewpoints.We propose the hypothesis that temperature gradients,formed due to the freezing and thawing processes between the roadside wateraffected soil and the roadbed soil,lead to moisture migration under the influence of temperature gradients,resulting in frost heave and thaw settlement in the roadbed soil.To validate this hypothesis,we conducted the following investigations sequentially.Initially,we selected a roadbed with a thermosyphon(TPCT)system,which has a significant cooling effect,as the study object.By analyzing the temperature monitoring data of the roadbed section,the temperature variance was calculated to identify the time nodes where the temperature gradient of the roadbed soil was maximum and minimum.Subsequently,corresponding roadbed temperature distribution maps were drawn,illustrating the changes in the temperature and position of the lowtemperature core near the TPCT over time.Furthermore,using small-scale indoor model experiments,we qualitatively concluded that moisture in the soil migrates toward the TPCT due to the temperature gradient.Thereafter,combining borehole water content data and precipitation data from the sloped terrain construction site,the formation mechanisms and timing characteristics of roadside water accumulation were analyzed.Ultimately,by integrating the ground temperature data,air temperature data,roadside water formation mechanisms,and the operating characteristics of the TPCT,it was concluded that roadside water,while in a thawed state during TPCT operation,acts as a supplementary source for moisture migration in the roadbed soil.This migration leads to cracking in the TPCT roadbed.Therefore,this study reveals a novel damage mechanism:asynchronous freeze-thaw processes induce temperature gradients,which drive the migration of roadside water into the roadbed and are responsible for the cracking damage.展开更多
Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the i...Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the impacts of wildfire on hydrology have been widely assessed at the watershed scale,the underlying mechanisms of the responses of summer low flows remain poorly understood.In this study,we employed an integrated research framework that combines hydrometric monitoring with geochemical tracing to evaluate how the 2021 White Rock Lake Wildfire affected summer low flows,and to identify the underlying mechanisms governing these responses in the Okanagan Valley,British Columbia(BC),Canada.We found that(1)summer low flows,represented by Q90(flows exceeded at 90%of the time in summer)significantly increased following the wildfire(p<0.05);(2)summer low flows were primarily regulated by snow water in early summer(July),while dominated by groundwater in late summer(August and September);and(3)enhanced snow water contribution and reduced evapotranspiration(ET)were two primary contributors to the increased summer low flows.Our results provide insights for developing sustainable water management strategies for the region in the context of climate change and increasing forest disturbance.This study also demonstrates that the combination of hydrometric monitoring and geochemical tracing is an effective approach towards uncovering mechanisms that drive low-flow responses.展开更多
Water molecules can form hydrogen bonds.At the solid surfaces,the preferential alignment of water molecules due to the heterogeneous atomic distributions can induce ordered hydrogen bond networks of water molecules wi...Water molecules can form hydrogen bonds.At the solid surfaces,the preferential alignment of water molecules due to the heterogeneous atomic distributions can induce ordered hydrogen bond networks of water molecules with spatially heterogeneous patterns and slower dynamics compared to bulk water.Both the confinement and the surface atomic structures can induce the water phase transitions at low dimensional spaces.Here,we review how the phase transitions of interfacial water affect the surface physical behaviors,such as wetting,ice nucleation and the terahertz-wave-water interactions,from solid materials to the biological surfaces.These works help extend our knowledge of the physics properties of the interfacial water,particularly the multi-phase behaviors in materials and biology sciences.展开更多
Herein,we have developed a straightforward wet-chemical method to synthesize a series of Pd-based alloy nanowires(NWs),including Pd Pt NWs,Pd Au NWs,Pd Ir NWs,and Pd Ru NWs,which exhibits high mass activity and turnov...Herein,we have developed a straightforward wet-chemical method to synthesize a series of Pd-based alloy nanowires(NWs),including Pd Pt NWs,Pd Au NWs,Pd Ir NWs,and Pd Ru NWs,which exhibits high mass activity and turnover frequency(TOF) for HER,surpassing Pt/C by 4.6-fold and 1.5-fold in acidic and alkaline electrolytes,respectively.It also demonstrates high stability in alkaline electrolyte at a current density of 220 m A/cm^(2) for 280 h,highlighting its potential for practical applications under industrial current conditions.Pd Pt NWs exhibited ultrathin structures with head-to-tail kinks and inherent defects,significantly increasing the density of active sites and precisely tuning the electronic structure,which could accelerate reaction kinetics and boost water-splitting electrocatalytic performance.This study highlights the potential of Pd Pt NWs as highly efficient catalysts,offering outstanding catalytic performance and stability for practical applications.展开更多
Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to miti...Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to mitigate the freshwater,energy and food crises.However,the performance of solar-driven systems decreases significantly during operation due to uncontrollable weather.This study proposes an integrated water/electricity cogeneration-cultivation system with superior thermal management.The energy storage evaporator,consisting of energy storage microcapsules/hydrogel composites,is optimally designed for sustainable desalination,achieving an evaporation rate of around 1.91 kg m^(-2)h^(-1).In the dark,heat released from the phase-change layer supported an evaporation rate of around 0.54kg m^(-2)h^(-1).Reverse electrodialysis harnessed the salinity-gradient energy enhanced during desalination,enabling the long-running WEC system to achieve a power output of~0.3 W m^(-2),which was almost three times higher than that of conventional seawater/surface water mixing.Additionally,an integrated crop irrigation platform utilized system drainage for real-time,on-demand wheat cultivation without secondary contaminants,facilitating seamless WEF integration.This work presents a novel approach to all-day solar water production,electricity generation and crop irrigation,offering a solution and blueprint for the sustainable development of WEF.展开更多
Distributions of nuclear magnetic resonance(NMR)relaxation times provide detailed information about the water in wood.This study documents the water dynamics analysis of T_(2)and T_(1)distributions for saturated delig...Distributions of nuclear magnetic resonance(NMR)relaxation times provide detailed information about the water in wood.This study documents the water dynamics analysis of T_(2)and T_(1)distributions for saturated delignified sapwood(DSW),delignified heartwood(DHW)and lignocellulose(LC)samples at different temperatures.Results indicate that below the freezing point of bulk water,free water freezes,causing its signal to disappear from the distribution.Then,the low temperature distributions of the unfrozen bound water contain more information about its components,with DSW,DHW and LC containing two distinct states of bound water(OH bound water(B-water)and more freely bound water(C-water)).Furthermore,it was observed that within the temperature range of−3°C to−60°C,B-water in DSW,DHW and LC maintained a higher unfrozen water content(UWC)value than C-water,and the T_(1)/T_(2)ratios for B-water were consistently higher than that for C-water,indicating that B-water has a greater antifreeze capacity.T_(2)and T_(1)distributions offer different kinds of information about water components,and all peaks within the distribution have been assigned.展开更多
Boron(B)doping serves as a promising strategy to enhance the quantum yield,photostability and environmental robustness of graphene quantum dots(GQDs).In this study,we reported a light-driven strategy for the facile sy...Boron(B)doping serves as a promising strategy to enhance the quantum yield,photostability and environmental robustness of graphene quantum dots(GQDs).In this study,we reported a light-driven strategy for the facile synthesis of boron-doped graphene quantum dots(B-GQDs).Specifically,under continuous stirring at room temperature,ultraviolet irradiation induces the progressive polymerization of o-phenylenediamine(o-PDA)precursors,resulting in the formation of GQDs;meanwhile,2-hydroxyphenylboronic acid(2-HPBA),acting as the B source,participates in the polymerization reaction with o-PDA intermediates,ultimately yielding B-GQDs.This approach significantly improves the technology of preparing QDs,yielding B-GQDs with a remarkably high fluorescence quantum yield of 71.2%.Detailed investigations reveal that the abundant surface functional groups on B-GQDs facilitate hydrogen-bonding interactions with water molecules,enabling their application as fluorescent probes for the quantitative detection of water content in various organic solvents.By integrating B-GQDs,a paper-based fluorescent sensor was successfully designed,achieving ultra-portable water content detection with excellent performance(0%-100%).展开更多
Human health is seriously jeopardized by infections caused by pathogenic microorganisms.The current traditional disinfection technologies have many defects,such as producing harmful by-products,being affected by water...Human health is seriously jeopardized by infections caused by pathogenic microorganisms.The current traditional disinfection technologies have many defects,such as producing harmful by-products,being affected by water turbidity,and high energy consumption.The growing concern for microbial safety has brought non-thermal plasma(NTP)disinfection technology into the spotlight.NTP is a promising disinfection technology with advantages such as environmental protection,safety,room temperature disinfection,short disinfection cycle,and wide applicability.Researchers are continuously optimizing NTP reactions to improve disinfection efficiency.This paper provides an integrated analysis of both plasma disinfection in water and plasma-activated water(PAW)disinfection on object surfaces.NTP can directly treat bacterial contaminated water,and can also be employed to produce PAW as a disinfectant for treating bacteria on surfaces.This review introduces the fundamental concepts and commonly used equipment related to NTP technology,analyzes the influencing factors and mechanisms of disinfection,and concludes by outlining the future directions of NTP technology in the field of disinfection.We hope to provide a reference for the research and practice of bacterial pollution issues.展开更多
Accurate water budget closure is critical for sustainable water resource management facing increased pressures from climate change and human activities.Although error reduction methods for individual water balance com...Accurate water budget closure is critical for sustainable water resource management facing increased pressures from climate change and human activities.Although error reduction methods for individual water balance components have advanced,persistent biases remain due to the independent development of datasets,impacting basin scale water budget balance.In this research,we analyzed the mathematical origin of the bias between water budget components and developed a new basin-scale water balance calibration method that redistributes errors across components while enforcing water balance constraints.Validation confirms systematic improvements,with reduced RMSE(Precipitation:-2.29 mm/month;ET:-1.34 mm/month)and increased R2 against in situ observations.Applied to the Jinghe River Basin(2000−2019),the calibrated data reveal declining precipitation(-1.70 mm/year)and evapotranspiration(-1.84 mm/year)alongside slightly increasing runoff(0.20 mm/year in basin depth),signaling a drying trend.Land cover changes—marked by cropland loss(-3,497 km^(2))and forest(+720 km^(2))and grassland(+2,776 km^(2))expansion—reflect improved water consumption requirements by ecosystem,raising concerns for water retention and ecosystem stability.The method is particularly effective for ungauged basins with sparse ground data and underscores the need for integrated land-water management to enhance long-term resilience.展开更多
基金supported by the National Natural Science Foundation of China (21776145 and 21808117)。
文摘This wok proposed the extraction distillation coupled pervaporation(ED+PV) technology process using two different solvents to separate isopropanol(IPA) and diisopropyl ether(DIPE) from DIPE/IPA/H_(2)O ternary heterogeneous azeotropes in industrial wastewater from the synthesis of isopropanol in this study.Based on strict design specifications, simulation and sequential iteration methods are used for process design and optimization. Compared to the ethylene glycol(EG)-EG+H_(2)O process and the 1,3-propanediol(PDO)-IPA+H_(2)O process, the total annual cost(TAC) of the EG-IPA+H_(2)O process decreased by 20.76% and 7.86%(PDO). Compared to the EG-EG+H_(2)O process, the TAC of the PDO-IPA+H_(2)O process reduced 14%, but the global warming potential(GWP) and human toxicity of the PDO-IPA+H_(2)O process increased 11.3% and 4.07% respectively. Compared to the PDO-IPA+H_(2)O process, the EG-IPA+H_(2)O process saves 7.86%(TAC), 9.78%(GWP) and 9.85%(human toxicity). The ED+PV process with EG is superior to PDO in factors of TAC, energy consumption, human toxicity and environment. The EG-IPA+H_(2)O process changed the separation order of the products of the multi-azeotropic system, reduced the cost and energy conservation of the system, and enhanced the environmental protection evaluation of the process, is the best process through life cycle assessment for analyzing the economy, energy conservation, environmental assessment and human toxicity, designing cleaner products, controlling waste discharge, and promoting the chemical purification industry. This work provides a new process design and optimized separation ideas, will have a good guiding significance for the research and application separation of multi-azeotropic mixture with mixed solvents in organic wastewater from the cleaner chemical production, has been up to standard wastewater discharge process, and realized the development goal of carbon peak and carbon neutrality in the sustainable development of chemical clean industry.
基金supported by the National Key Research and Development Program of China(No.2019YFC1804202)the National Natural Science Foundation of China(No.22020102004)+1 种基金the Tianjin Municipal Science and Technology Bureau(No.21JCZDJC00280)the Fundamental Research Funds for the Central Universities by the Ministry of Education of China(No.T2017002).
文摘Polybromodiphenyl ethers(PBDEs),the widely used flame retardants,are common contaminants in surface soils at e-waste recycling sites.The association of PBDEs with soil colloids has been observed,indicating the potential risk to groundwater due to colloid-facilitated transport.However,the extent to which soil colloidsmay enhance the spreading of PBDEs in groundwater is largely unknown.Herein,we report the co-transport of decabromodiphenyl ester(BDE-209)and soil colloids in saturated porous media.The colloids released froma soil sample collected at an e-waste recycling site in Tianjin,China,contain high concentration of PBDEs,with BDE-209 being the most abundant conger(320±30 mg/kg).The colloids exhibit relatively high mobility in saturated sand columns,under conditions commonly observed in groundwater environments.Notably,under all the tested conditions(i.e.,varying flow velocity,pH,ionic species and ionic strength),the mass of eluted BDE-209 correlates linearly with that of eluted soil colloids,even though the mobility of the colloids varies markedly depending on the specific hydrodynamic and solution chemistry conditions involved.Additionally,the mass of BDE-209 retained in the columns also correlates strongly with themass of retained colloids.Apparently,the PBDEs remain bound to soil colloids during transport in porous media.Findings in this study indicate that soil colloidsmay significantly promote the transport of PBDEs in groundwater by serving as an effective carrier.This might be the reason why the highly insoluble and adsorptive PBDEs are found in groundwater at some PBDE-contaminated sites.
文摘Gas wells often encounter blockages in gas recovery channels owing to fluid accumulation during the later stages of extraction,which adversely affects subsequent recovery efforts.These undesirable conditions(e.g.,high condensate content,high temperature,and high salinity)often affect foaming agent performance.In this study,surfactants were screened using an airflow method that closely resembles field treatment method.Notably,alcohol ether sulfates(AE_(n)S)with various polyoxyethylene(EO)units demonstrated exceptional performance in terms of liquid unloading efficiency and foam stability.At 80℃,the unloading efficiency of AE_(n)S with two EO units(AE_(2)S)in a high NaCl mass concentration(up to 200 g/L)and high condensate volume fraction(up to 20%)reached 84%.The dynamic surface tension and interfacial tension measured at the same temperature were used to analyze the influence of the diffusion rate and interfacial characteristics on the AE_(n)S foam,while the viscosity and liquid film thickness measurements reflected the mechanical strength and liquid-carrying capacity.In addition,transmission electron microscopy(TEM)revealed that AE_(2)S formed“dendritic”micellar aggregates at a high NaCl mass concentration,which significantly enhanced the viscosity and stability of the foam.The interactions among AE_(n)S,NaCl,and H2O were analyzed using molecular dynamics,and it was confirmed from a molecular mechanics perspective that a stable structure can form among the three,contributing to the foam stability.These findings demonstrate the significant potential of the AE_(2)S foam for gas well deliquification.
基金supported by the National Natural Science Foundation of China(No.82073721)Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.23KJA310003).
文摘Asplactones A-E(1-5),five unique diphenyl ether hybrids,along with two rare spiro-diphenyl ethers,aspviolaceols A(6)and B(7),were isolated and characterized from Aspergillus sp.F1-8A,an endophytic fungus associated with the parotoid glands of Bufo gargarizans Cantor.Compounds 1-5 represent the first examples of diphenyl ether hybrids fused with unusual moieties,including conjugatedγ-butyrolactone and cyclopentenone.Compounds 6 and 7 are the first known natural spiro-diphenyl ethers,with 6 featuring an uncommon 6/6/6/6-membered carbon skeleton,and 7 possessing a distinct 6/6/6/6/6/6-membered diphenyl ether spiro-heterodimer carbon framework.Structural elucidation was performed using a combination of spectroscopic techniques,X-ray crystallography,and quantum-chemical calculations,and plausible biosynthetic pathways were proposed.Biologically,compounds 1,2,4,6,and 7 exhibited antioxidant activity comparable to or surpassing that of vitamin C in 1,1-diphenyl-2-picrylhydrazyl(DPPH)and 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonate)(ABTS),and ferric reducing power assays.They also significantly improved cell viability in H2O2-induced oxidative injury assays using A549 cells.
基金Supported by the National Natural Science Foundation of China(No.52273056)the Science and Technology Development Program of Jilin Province,China(No.YDZJ202501ZYTS305)。
文摘Electrochemical water splitting represents a sustainable technology for hydrogen(H_(2))production.However,its large-scale implementation is hindered by the high overpotentials required for both the cathodic hydrogen evolution reaction(HER)and the anodic oxygen evolution reaction(OER).Transition metal-based catalysts have garnered significant research interest as promising alternatives to noble-metal catalysts,owing to their low cost,tunable composition,and noble-metal-like catalytic activity.Nevertheless,systematic reviews on their application as bifunctional catalysts for overall water splitting(OWS)are still limited.This review comprehensively outlines the principal categories of bifunctional transition metal electrocatalysts derived from electrospun nanofibers(NFs),including metals,oxides,phosphides,sulfides,and carbides.Key strategies for enhancing their catalytic performance are systematically summarized,such as heterointerface engineering,heteroatom doping,metal-nonmetal-metal bridging architectures,and single-atom site design.Finally,current challenges and future research directions are discussed,aiming to provide insightful perspectives for the rational design of high-performance electrocatalysts for OWS.
基金supported by the National Key Research and Development Program of China (2022YFE0138900)the “Scientific and Technical Innovation Action Plan” Basic Research Field of Shanghai Science and Technology Committee (19JC1410500)。
文摘Ion-solvaing membranes(ISMs)have received extensive attention in recent years as a key component in electrochemical energy conversion and storage devices.This article provides an overview of structural composition,performance advan-tages,research progress,ion conduction mechanism and existing issues of ISMs,primarily classifying them according to the matrix structure.A detailed analysis of performance enhancement methods,key performance indicators of ISMs and performance influencing factors is also presented.The article contributes to further optimizing the design and application of ion-solvation membranes,providing theoretical support for the development of fields such as hydrogen production through electrolysis of water and electrochemical energy in the future.
文摘The Arno River Basin(Central Italy)is affected by a considerable anthropogenic pressure due to the presence of large cities and widespread industrial and agricultural practices.In this work,26 water samples from the Arno River and its main tributaries were analyzed to assess the water pollution status.The geochemical composition of the Arno River changes from the source(dominated by a Ca-HCO_(3) facies)to the mouth(where a Na-Cl(SO4)chemistry prevails)with an increasing quality deterioration,as suggested by the Chemical Water Quality Index,due to anthropogenic contributions and seawater intrusion before flowing into the Ligurian Sea.The Ombrone and Usciana tributaries introduce anthropogenic pollutants into the Arno River,whilst Elsa tributary supplies significant contents of geogenic sulfate.The concentrations of dissolved nitrate and nitrite(up to 63 and 9 mg/L,respectively)and the respective isotopic values of𝛿15N and𝛿18O were also determined to understand origin and fate of the N-species in the Arno River Basin surface waters.The combined application of𝛿15N-NO_(3) and𝛿18O-NO_(3) and N-source apportionment modelling allowed the identification of soil organic nitrogen and sewage and domestic wastes as primary sources for dissolved NO_(3)-.The𝛿15N-NO_(2) and𝛿18O-NO_(2) values suggest that the nitrification process affects the ARB waters,thus controlling the abundances and proportion of the N-species.Our work indicates that additional efforts are needed to improve management strategies to reduce the release of nitrogenated species to the surface waters of the Arno River Basin,since little progress has been made from the early 2000s.
基金supported by National Natural Science Foundation of China(Grant No.52279027)National Key R&D Program of China(Grant No.2021YFC3200201)+1 种基金Key Research Project on Decision Consultation of the Strategic Development Department of China Association for Science and Technology(Grant No.2023070615CG111504)China Engineering Science and Technology Development Strategy Henan Research Institute Strategic Consulting Research Project(Grant No.2024HENYB01).
文摘Unequal virtual water transfer may aggravate local water scarcity risk.However,the quantitative confirmation of a clear geographic convergence between virtual water transfer and water scarcity risk remains undetermined.We present an analytical framework that reveals the spatial matching between global water scarcity risk and virtual water trade inequality.This framework integrates a three-dimensional water scarcity risk assessment,hybrid input-output analysis,pollution trade term construction,and geographic convergence identification.The framework is applied to 123 countries for long-term validation from 1991 to 2021.We show that despite global improvements in water efficiency and security,countries exceeding the maximum water vulnerability threshold have increased by 50%.South Asia is the largest net exporter of virtual water.Central Asia exhibits the most pronounced virtual water trade inequality.To achieve the same economic growth,Central Asia needs to pay several times the local water consumption costs of developed regions(15.9−83.6 times,2021).In the past 30 years,the average geographic convergence index exceeded 0.8.Countries facing severe water scarcity also exhibit pronounced inequalities in virtual water trade,indicating that a significant geographic convergence relationship exists.Effectively responding to this unsustainable relationship necessitates balancing both domestic resource risk management and global virtual water trade regulation.
基金supported by National Key R&D Program of China (2022YFD1900104)。
文摘To maintain soil quality under long-term saline water irrigation,the influence of manure on soil physical properties was examined.Long-term saline irrigation has been conducted from 2015 to 2024 at the Nanpi Eco-Agricultural Experimental Station of Chinese Academy Sciences in the Low Plain of the North China Plain,comprising four irrigation treatments:irrigation once at the jointing stage for winter wheat with irrigation water containing salt at fresh water,3,4 and 5 g·L^(–1),and maize irrigation at sowing using fresh water.Manure application was conducted under all irrigation treatments,with treatments without manure application used as controls.The results showed that under long-term irrigation with saline water,the application of manure increased the soil organic matter content,exchangeable potassium,available phosphorus,and total nitrogen content in the 0–20 cm soil layer by 46.8%,117.0%,75.7%,and 45.5%,respectively,compared to treatments without manure application.The application of manure reduced soil bulk density.It also increased the proportion of water-stable aggregates and the abundance of bacteria,fungi,and actinomycetes in the tillage soil layer compared to the controls.Because of the salt contained in the manure,the application of manure had dual effects on soil salt content.During the winter wheat season,manure application increased soil salt content.The salt content was significantly reduced during the summer maize season,owing to the strong salt-leaching effects under manure application,resulting in a smaller difference in salt content between the manure and non-manure treatments.During the summer rainfall season,improvements in soil structure under manure application increased the soil desalination rate for the 1 m top soil layer.The desalination rate for 0–40 cm and 40–100 cm was averagely by 39.1%and 18.9%higher,respectively,under manure application as compared with that under the nomanure treatments.The yield of winter wheat under manure application was 0.12%lower than that of the control,owing to the higher salt content during the winter wheat season.In contrast,the yield of summer maize improved by 3.9%under manure application,owing to the increased soil nutrient content and effective salt leaching.The results of this study indicated that manure application helped maintain the soil physical structure,which is important for the long-term use of saline water.In practice,using manure with a low salt content is suggested to reduce the adverse effects of saline water irrigation on soil properties and achieve sustainable saline water use.
文摘In Bom Jesus Municipality,a cool breeze drifts in from the Kwanza River,softening the edges of a town marked by landmarks such as António Agostinho Neto International Airport.Yet beneath Luanda’s scenic façade,daily life for many residents is defined by a persistent struggle for water.“We have to walk 5 to 15 km to access water.This perennial problem is so depressing.What’s more,the lack of clean water causes waterborne diseases in our community,”local resident Isabel Fernando told ChinAfrica.
基金supported by the National Natural Science Foundation of China(Grant Nos.52225404 and 52404121)the Key Research and Development Program Projects of Xinjiang Uygur Autonomous Region(Grant No.2024B03017).
文摘The mining industry is frequently subjected to various disasters,one of the major concerns is water-related disasters,particularly seam floor water inrush.These disasters pose significant threats to the safety and production of deep coal mines.The primary reason for this is that the fracturing of the rock mass induces the formation of a fluid(water)with both kinetic and potential energy.In this paper,a novel water inrush mechanism for deep floor failure due to water hammer effects is proposed based on the Xingdong coal mine in China.The water hammer pressure within rock pore channels has a different impact on the surrounding rock,leading to the degradation of the rock mass channel through repeated conduction and instantaneous cutoff.To further investigate this phenomenon,a progressive corrosion fracture mechanics(PCFM)model induced by a water hammer is established.The results show that the water hammer pressure caused by instantaneous channel truncation increases with increasing water flow velocity.The chemical damage factor(i.e.,stress corrosion fracture)is also incorporated into the Dugdale-Barenblatt(D-B)model to analyze the factors influencing the PCFM.These findings indicate that the greater the degree of damage is,the more likely the concealed fault is to experience water inrush.Finally,methods for controlling water inrush caused by the water hammer effects of deep floors are proposed.The failure mechanisms of the water hammer and the PCFM provide theoretical and practical guidance for controlling water inrush from the deep floor.
基金supported by the Major Science and Technology Project of Gansu Province(Grant No.24ZD13FA003 and 23ZDWA005)National Natural Science Foundation of China(Grant No.42371140,42301163,41971087 and 42272332)the program of the State Key Laboratory of Cryospheric Science and Frozen Soil Engineering,CAS(No.CSFSEZZ-2411)。
文摘In permafrost regions of the QinghaiXizang Plateau,embankments of the Qinghai-Xizang Highway and Qinghai-Xizang Railway experiencing roadside water accumulation exhibit more pronounced engineering deteriorations.A widely accepted view is that the accumulated water adjacent to the embankment possesses substantial thermal energy,which accelerates the degradation-even disappearance-of the underlying permafrost.Moreover,the presence of roadside water keeps the embankment soil in a persistently high-moisture state,thereby making the frozen-soil embankment more susceptible to deformation under traffic loading.However,in the permafrost regions of the QinghaiXizang Plateau,deteriorations of embankments affected by roadside water are more commonly manifested as undulating pavement surfaces,and extensive crack networks appear on the embankment crest even where thermosyphons are installed.These manifestations are not fully consistent with the deterioration mechanisms proposed by existing viewpoints.We propose the hypothesis that temperature gradients,formed due to the freezing and thawing processes between the roadside wateraffected soil and the roadbed soil,lead to moisture migration under the influence of temperature gradients,resulting in frost heave and thaw settlement in the roadbed soil.To validate this hypothesis,we conducted the following investigations sequentially.Initially,we selected a roadbed with a thermosyphon(TPCT)system,which has a significant cooling effect,as the study object.By analyzing the temperature monitoring data of the roadbed section,the temperature variance was calculated to identify the time nodes where the temperature gradient of the roadbed soil was maximum and minimum.Subsequently,corresponding roadbed temperature distribution maps were drawn,illustrating the changes in the temperature and position of the lowtemperature core near the TPCT over time.Furthermore,using small-scale indoor model experiments,we qualitatively concluded that moisture in the soil migrates toward the TPCT due to the temperature gradient.Thereafter,combining borehole water content data and precipitation data from the sloped terrain construction site,the formation mechanisms and timing characteristics of roadside water accumulation were analyzed.Ultimately,by integrating the ground temperature data,air temperature data,roadside water formation mechanisms,and the operating characteristics of the TPCT,it was concluded that roadside water,while in a thawed state during TPCT operation,acts as a supplementary source for moisture migration in the roadbed soil.This migration leads to cracking in the TPCT roadbed.Therefore,this study reveals a novel damage mechanism:asynchronous freeze-thaw processes induce temperature gradients,which drive the migration of roadside water into the roadbed and are responsible for the cracking damage.
基金the China Scholarship Council(CSC)the Uplifting Reciprocal Research Scholarship Program for sponsoring Shixuan Lyu+1 种基金supported by MITACS Accelerate(No.IT39116)the Okanagan Basin Water Board water conservation and quality improvement grant program。
文摘Forests are experiencing more frequent and intense wildfires in Canada,which pose considerable threats to water quantity and quality,particularly during the summer low-flow period when water demand is high.While the impacts of wildfire on hydrology have been widely assessed at the watershed scale,the underlying mechanisms of the responses of summer low flows remain poorly understood.In this study,we employed an integrated research framework that combines hydrometric monitoring with geochemical tracing to evaluate how the 2021 White Rock Lake Wildfire affected summer low flows,and to identify the underlying mechanisms governing these responses in the Okanagan Valley,British Columbia(BC),Canada.We found that(1)summer low flows,represented by Q90(flows exceeded at 90%of the time in summer)significantly increased following the wildfire(p<0.05);(2)summer low flows were primarily regulated by snow water in early summer(July),while dominated by groundwater in late summer(August and September);and(3)enhanced snow water contribution and reduced evapotranspiration(ET)were two primary contributors to the increased summer low flows.Our results provide insights for developing sustainable water management strategies for the region in the context of climate change and increasing forest disturbance.This study also demonstrates that the combination of hydrometric monitoring and geochemical tracing is an effective approach towards uncovering mechanisms that drive low-flow responses.
基金supported by the National Natural Science Foundation of China(Grant Nos.22576126,12074394,12022508).
文摘Water molecules can form hydrogen bonds.At the solid surfaces,the preferential alignment of water molecules due to the heterogeneous atomic distributions can induce ordered hydrogen bond networks of water molecules with spatially heterogeneous patterns and slower dynamics compared to bulk water.Both the confinement and the surface atomic structures can induce the water phase transitions at low dimensional spaces.Here,we review how the phase transitions of interfacial water affect the surface physical behaviors,such as wetting,ice nucleation and the terahertz-wave-water interactions,from solid materials to the biological surfaces.These works help extend our knowledge of the physics properties of the interfacial water,particularly the multi-phase behaviors in materials and biology sciences.
基金the financial support from the National Natural Science Foundation of China (Nos.21805170,22172093)Natural Science Foundation of Shandong Province (Nos.ZR2023QB219,ZR2021QB161)Qingdao Postdoctoral Innovation Project (No.QDBSH20220202031)。
文摘Herein,we have developed a straightforward wet-chemical method to synthesize a series of Pd-based alloy nanowires(NWs),including Pd Pt NWs,Pd Au NWs,Pd Ir NWs,and Pd Ru NWs,which exhibits high mass activity and turnover frequency(TOF) for HER,surpassing Pt/C by 4.6-fold and 1.5-fold in acidic and alkaline electrolytes,respectively.It also demonstrates high stability in alkaline electrolyte at a current density of 220 m A/cm^(2) for 280 h,highlighting its potential for practical applications under industrial current conditions.Pd Pt NWs exhibited ultrathin structures with head-to-tail kinks and inherent defects,significantly increasing the density of active sites and precisely tuning the electronic structure,which could accelerate reaction kinetics and boost water-splitting electrocatalytic performance.This study highlights the potential of Pd Pt NWs as highly efficient catalysts,offering outstanding catalytic performance and stability for practical applications.
基金supported by the National Natural Science Foundation of China(No.52070057)China Postdoctoral Science Foundation(No.2023M730855)Heilongjiang Postdoctoral Fund(No.LBH-Z22183)for financial support。
文摘Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to mitigate the freshwater,energy and food crises.However,the performance of solar-driven systems decreases significantly during operation due to uncontrollable weather.This study proposes an integrated water/electricity cogeneration-cultivation system with superior thermal management.The energy storage evaporator,consisting of energy storage microcapsules/hydrogel composites,is optimally designed for sustainable desalination,achieving an evaporation rate of around 1.91 kg m^(-2)h^(-1).In the dark,heat released from the phase-change layer supported an evaporation rate of around 0.54kg m^(-2)h^(-1).Reverse electrodialysis harnessed the salinity-gradient energy enhanced during desalination,enabling the long-running WEC system to achieve a power output of~0.3 W m^(-2),which was almost three times higher than that of conventional seawater/surface water mixing.Additionally,an integrated crop irrigation platform utilized system drainage for real-time,on-demand wheat cultivation without secondary contaminants,facilitating seamless WEF integration.This work presents a novel approach to all-day solar water production,electricity generation and crop irrigation,offering a solution and blueprint for the sustainable development of WEF.
基金supported by Natural Science Foundation of Inner Mongolia Autonomous Region of China (2023MS03027)the National Natural Science Foundation of China (31860185 and 31160141)
文摘Distributions of nuclear magnetic resonance(NMR)relaxation times provide detailed information about the water in wood.This study documents the water dynamics analysis of T_(2)and T_(1)distributions for saturated delignified sapwood(DSW),delignified heartwood(DHW)and lignocellulose(LC)samples at different temperatures.Results indicate that below the freezing point of bulk water,free water freezes,causing its signal to disappear from the distribution.Then,the low temperature distributions of the unfrozen bound water contain more information about its components,with DSW,DHW and LC containing two distinct states of bound water(OH bound water(B-water)and more freely bound water(C-water)).Furthermore,it was observed that within the temperature range of−3°C to−60°C,B-water in DSW,DHW and LC maintained a higher unfrozen water content(UWC)value than C-water,and the T_(1)/T_(2)ratios for B-water were consistently higher than that for C-water,indicating that B-water has a greater antifreeze capacity.T_(2)and T_(1)distributions offer different kinds of information about water components,and all peaks within the distribution have been assigned.
基金support from Sichuan Science and Technology Project(Nos.2023zYD0034 and 2024NSFJQ0061)the State Key Lab of Geohazard Prevention&Geoenvironment Protection Independent Research Project(No.SKLGP 2023Z009).
文摘Boron(B)doping serves as a promising strategy to enhance the quantum yield,photostability and environmental robustness of graphene quantum dots(GQDs).In this study,we reported a light-driven strategy for the facile synthesis of boron-doped graphene quantum dots(B-GQDs).Specifically,under continuous stirring at room temperature,ultraviolet irradiation induces the progressive polymerization of o-phenylenediamine(o-PDA)precursors,resulting in the formation of GQDs;meanwhile,2-hydroxyphenylboronic acid(2-HPBA),acting as the B source,participates in the polymerization reaction with o-PDA intermediates,ultimately yielding B-GQDs.This approach significantly improves the technology of preparing QDs,yielding B-GQDs with a remarkably high fluorescence quantum yield of 71.2%.Detailed investigations reveal that the abundant surface functional groups on B-GQDs facilitate hydrogen-bonding interactions with water molecules,enabling their application as fluorescent probes for the quantitative detection of water content in various organic solvents.By integrating B-GQDs,a paper-based fluorescent sensor was successfully designed,achieving ultra-portable water content detection with excellent performance(0%-100%).
基金support by National Natural Science Foundation of China(No.22006069)Natural Science Foundation of Jiangsu Province in China(No.BK20200801)Jiangsu Special Foundation on Technology Innovation of Carbon Dioxide Peaking and Carbon Neutrality(No.BK20220016).
文摘Human health is seriously jeopardized by infections caused by pathogenic microorganisms.The current traditional disinfection technologies have many defects,such as producing harmful by-products,being affected by water turbidity,and high energy consumption.The growing concern for microbial safety has brought non-thermal plasma(NTP)disinfection technology into the spotlight.NTP is a promising disinfection technology with advantages such as environmental protection,safety,room temperature disinfection,short disinfection cycle,and wide applicability.Researchers are continuously optimizing NTP reactions to improve disinfection efficiency.This paper provides an integrated analysis of both plasma disinfection in water and plasma-activated water(PAW)disinfection on object surfaces.NTP can directly treat bacterial contaminated water,and can also be employed to produce PAW as a disinfectant for treating bacteria on surfaces.This review introduces the fundamental concepts and commonly used equipment related to NTP technology,analyzes the influencing factors and mechanisms of disinfection,and concludes by outlining the future directions of NTP technology in the field of disinfection.We hope to provide a reference for the research and practice of bacterial pollution issues.
基金supported by the National Key Research and Development Program of China(Grants No.2024YFF0810500 and 2022YFD1900802)the National Natural Scientific Foundations of China(Grants No.41991232,42301016 and 42571034)the Hainan Provincial Natural Science Foundation of China(Grant No.424QN354).
文摘Accurate water budget closure is critical for sustainable water resource management facing increased pressures from climate change and human activities.Although error reduction methods for individual water balance components have advanced,persistent biases remain due to the independent development of datasets,impacting basin scale water budget balance.In this research,we analyzed the mathematical origin of the bias between water budget components and developed a new basin-scale water balance calibration method that redistributes errors across components while enforcing water balance constraints.Validation confirms systematic improvements,with reduced RMSE(Precipitation:-2.29 mm/month;ET:-1.34 mm/month)and increased R2 against in situ observations.Applied to the Jinghe River Basin(2000−2019),the calibrated data reveal declining precipitation(-1.70 mm/year)and evapotranspiration(-1.84 mm/year)alongside slightly increasing runoff(0.20 mm/year in basin depth),signaling a drying trend.Land cover changes—marked by cropland loss(-3,497 km^(2))and forest(+720 km^(2))and grassland(+2,776 km^(2))expansion—reflect improved water consumption requirements by ecosystem,raising concerns for water retention and ecosystem stability.The method is particularly effective for ungauged basins with sparse ground data and underscores the need for integrated land-water management to enhance long-term resilience.
