Correction to:Nano-Micro Letters(2025)17:191 https://doi.org/10.1007/s40820-025-01702-7 Following the publication of the original article[1],the authors reported an error in Fig.3(b),and the figure legend was reversed...Correction to:Nano-Micro Letters(2025)17:191 https://doi.org/10.1007/s40820-025-01702-7 Following the publication of the original article[1],the authors reported an error in Fig.3(b),and the figure legend was reversed.The correct Fig.3 has been provided in this orrection.展开更多
A direct C–H amination reaction of N-Ts-2-Styrylaniline derivatives to realize the synthesis of indole derivatives was developed in the presence of copper salt. A variety of N-Ts-2-Styrylaniline derivatives were tran...A direct C–H amination reaction of N-Ts-2-Styrylaniline derivatives to realize the synthesis of indole derivatives was developed in the presence of copper salt. A variety of N-Ts-2-Styrylaniline derivatives were transformed into the corresponding indole products in good to excellent yield under mild conditions with the oxidation of potassium persulfate.展开更多
Chlorospermines A and B are biologically interesting acridone natural products and recently isolated from Glycosmis chlorosperma.We report here a convergent approach to construct the tetracyclic core of the natural pr...Chlorospermines A and B are biologically interesting acridone natural products and recently isolated from Glycosmis chlorosperma.We report here a convergent approach to construct the tetracyclic core of the natural products.The two fragments are assembled together through Sonogashira coupling,and a cis-triene intermediate was prepared by using hydrosilylation/desilylation.A 6p-electrocyclization/aromatization sequence served as the key step of the synthesis,which formed the tetrasubstituted arene motif in one pot.展开更多
A new colorimetric and fluorimetric chemosensor for F detection based on 1H-imidazo[4,5-b]phenazine derivative has been designed and synthesized.It shows excellent fluorescent specific selectivity and sensitivity for ...A new colorimetric and fluorimetric chemosensor for F detection based on 1H-imidazo[4,5-b]phenazine derivative has been designed and synthesized.It shows excellent fluorescent specific selectivity and sensitivity for F^- in DMSO solution.Upon addition of F^- to the solution of probe 1,a remarkable color change from yellow to red could be observed easily by the naked-eye.The detection limit of this probe toward F^- is 6.2× 10 ^-6mol/L.Analysis by^1 H NMR proved that the imidazolyl N–H could be hydrogen-bonded with added fluoride anions,and results in the difference of colors.展开更多
Over the past decades, the urgent need for high strength conductive hydrogels in diverse applications has motivated an unremitting effort to combine the improved mechanical properties of hydrogels with conductive perf...Over the past decades, the urgent need for high strength conductive hydrogels in diverse applications has motivated an unremitting effort to combine the improved mechanical properties of hydrogels with conductive performances. In this work, high strength conductive hydrogels intensified with intermolecular hydrogen bonding are fabricated by in situ mixing poly（2-vinyl-4,6-diamino-1,3,5-triazine-co-polyethylene glycol diacrylates）（PVDT-PEGDA） hydrogels with poly（3,4-ethylenedioxythiophene）-poly（styrenesulfonate）（PEDOT/PSS）. The conductive hydrogels in deionized water exhibit high mechanical performances with compressive strength and tensile strength in the range of 7.58-9.52 MPa and 0.48-1.20 MPa respectively, which are ascribed to the intermolecular hydrogen bonding interactions of diaminotriazinediaminotriazine（DAT-DAT） in the network. Meanwhile, adding PEDOT/PSS can significantly increase both the specific conductivities and equilibrium water contents of the hydrogels. These cytocompatible conductive hydrogels may have a great potential to be used as electrical stimuli responsive soft biomaterials.展开更多
An efficient method has been developed for the synthesis of a series of（20R）-panaxadiol derivatives（4a–w） using a continuous-flow microreactor.The antitumor activities of the newly synthesized compounds were eval...An efficient method has been developed for the synthesis of a series of（20R）-panaxadiol derivatives（4a–w） using a continuous-flow microreactor.The antitumor activities of the newly synthesized compounds were evaluated in vitro in two human prostate adenocarcinoma tumor cell lines（i.e.,PC-3and LNCa P cells）,and their cytotoxicities were evaluated using a standard MTT assay.Compounds 4c,4h,4p,4q and 4s exhibited higher antitumor activities toward PC-3 cell line than panaxadiol,which was used as a reference standard.展开更多
A microwave-assisted general method for the synthesis of 2-aminovinyl benzimidazoles has been developed.Treatment of the 1,2-phenylenediamines and N-arylated/N,N-dialkylated 3-aminoacroleins with bis（cyclopentadienyl...A microwave-assisted general method for the synthesis of 2-aminovinyl benzimidazoles has been developed.Treatment of the 1,2-phenylenediamines and N-arylated/N,N-dialkylated 3-aminoacroleins with bis（cyclopentadienyl）zirconium（IV） dichloride（Cp2Zr Cl2） as the catalyst under microwave irradiation for 3–5 min followed by in situ Mn O2 oxidation afforded thirteen 2-aminovinyl benzimidazoles in good yields.展开更多
An efficient methodology for the synthesis of 2,3-disubstituted 3H-quinazolin-4-ones is described via one-pot three component reaction from anthranilic acid using T3 P as catalyst. Mild reaction conditions,short react...An efficient methodology for the synthesis of 2,3-disubstituted 3H-quinazolin-4-ones is described via one-pot three component reaction from anthranilic acid using T3 P as catalyst. Mild reaction conditions,short reaction time, broad functional group tolerance, easy isolation of products and good yields are main advantages of this protocol.展开更多
A novel method for achieving a copper（II）-catalyzed domino reaction for the construction of 2-aryl quinazolinones,without the addition of any ligand and additive,has been developed.The domino reaction achieved N-（a...A novel method for achieving a copper（II）-catalyzed domino reaction for the construction of 2-aryl quinazolinones,without the addition of any ligand and additive,has been developed.The domino reaction achieved N-（a-substituted）benzylation,benzylic C–H amidation,and C–C（or C–H） bond cleavage.展开更多
This paper discusses about how to use the theory of thematic progression in translation. Some linguists have talked about thematic progression in their works, but most of them are related to stylistics. This paper wil...This paper discusses about how to use the theory of thematic progression in translation. Some linguists have talked about thematic progression in their works, but most of them are related to stylistics. This paper will pay much attention to the relationship between the patterns of thematic progression and the translation between English and Chinese, and how to use thematic progression in understanding and translating between English and Chinese.展开更多
As we all know that exquisite subtitle translation of foreign film and television series is the fatal elements for them to spread among Chinese audiences. This article is based on Eugene·Nida's"the Funct...As we all know that exquisite subtitle translation of foreign film and television series is the fatal elements for them to spread among Chinese audiences. This article is based on Eugene·Nida's"the Functional Equivalence"principle with three char acteristics of sitcoms'subtitle to study the type, form and features of the Big Bang Theory, which lead to the conclusion of sitcom subtitle's characteristics. It helps us to analyze its subtitle from six aspects. As the result, the author of the paper makes the conclusion of translation tactic about Big Bang Theory, which could help the subtitle translation of similar sitcoms.展开更多
Transliteration aims to adapt loanwords to perfect sound patterns and structures. With the guidance of Optimality Theory, this paper elaborates on the constraints that must be observed in transliteration to achieve Ch...Transliteration aims to adapt loanwords to perfect sound patterns and structures. With the guidance of Optimality Theory, this paper elaborates on the constraints that must be observed in transliteration to achieve Chinese phonological harmony from phonemic equivalents. It analyzes the ranking of constraints for structural acceptability of the loanwords.展开更多
Certain molecules such as ethane and acetone possess moiety capable of internal rotation in addition to the rigid structure.When energy is large enough,the methyl group of ethane and acetone can freely rotate along th...Certain molecules such as ethane and acetone possess moiety capable of internal rotation in addition to the rigid structure.When energy is large enough,the methyl group of ethane and acetone can freely rotate along the C—C bond.If not,the methyl group can then only oscillate within certain angles similar to the simple harmonic motion due to the restriction of potential barrier.This is the so-called torsion.展开更多
Throughout this letter, G is a finite group. We fix a splitting modular system (K, R, F), where Char K=0 and Char F=p. A p-block means a block of the group algebra FG. S_p(G) denotes the set of Sylow p-subgroups of fi...Throughout this letter, G is a finite group. We fix a splitting modular system (K, R, F), where Char K=0 and Char F=p. A p-block means a block of the group algebra FG. S_p(G) denotes the set of Sylow p-subgroups of finite group G.展开更多
It was reported in the literature that the main products from the reaction of LnCl3 and C5Me5M were anionic complexes of the type （ML2）(（C5Me5）n LnCl4-n), where L is Lewis base. During our study on the reaction of...It was reported in the literature that the main products from the reaction of LnCl3 and C5Me5M were anionic complexes of the type （ML2）(（C5Me5）n LnCl4-n), where L is Lewis base. During our study on the reaction of （HP（C2H5）3）2CeCl6 with 4 molar equiv, of C5Me5Na, we have recently succeeded in isolating a neutral species （C5Me5）2Ce Cl （Ⅰ）. （Ⅰ） was identified by elemental analysis, IR and 1H-NMR.展开更多
To give the geometrical meanings of some coefficient inequalities in classical function theory is the purpose of this note. It also offers some possibilities to extend these inequalities into a new point of view. We o...To give the geometrical meanings of some coefficient inequalities in classical function theory is the purpose of this note. It also offers some possibilities to extend these inequalities into a new point of view. We only consider the class S, for it can be done without any difficulties for the other function classes. The S is the class of functions f(z)展开更多
The phenyl derivatives of lanthanides Sc（C<sub>6</sub>H<sub>5</sub>）<sub>3</sub>, Y（C<sub>6</sub>H<sub>5</sub>）<sub>3</sub>, LiLa （C<sub&...The phenyl derivatives of lanthanides Sc（C<sub>6</sub>H<sub>5</sub>）<sub>3</sub>, Y（C<sub>6</sub>H<sub>5</sub>）<sub>3</sub>, LiLa （C<sub>6</sub>H<sub>5</sub>）<sub>4</sub> and LiPr（C<sub>6</sub>H<sub>5</sub>）<sub>4</sub> were prepared by Hart et al. in 1970, and dis（cyclopentadienyl） phenyl complexes of lanthanides have been isolated recently. We reported here the synthesis and crystallography parameters of a new type of phenyl derivative of neodymium:展开更多
The right question is actually not,"Do you lie?"The right question is,"How often do you lie?"And unfortunately,because we are all such good self-deceivers,we really do not know the answer to ...The right question is actually not,"Do you lie?"The right question is,"How often do you lie?"And unfortunately,because we are all such good self-deceivers,we really do not know the answer to this question,so the best response may be,"Of course I lie a lot,why do you ask?"We deceive,misrepresent,obfuscate,misdirect,equivocate,confuse the issue,conveniently forget,withhold,lose track,exaggerate,argue for positions we do not even agree with,save face,change the topic,etc.-and blame others if we are caught at it!We all lie,often,everyday,and throughout our lives.展开更多
基金supported in part by STI 2030-Major Projects under Grant 2022ZD0209200in part by Beijing Natural Science Foundation-Xiaomi Innovation Joint Fund (L233009)+4 种基金in part by National Natural Science Foundation of China under Grant No. 62374099in part by the Tsinghua-Toyota Joint Research Fundin part by the Daikin Tsinghua Union Programin part by Independent Research Program of School of Integrated Circuits,Tsinghua Universitysponsored by CIE-Tencent Robotics X Rhino-Bird Focused Research Program
文摘Correction to:Nano-Micro Letters(2025)17:191 https://doi.org/10.1007/s40820-025-01702-7 Following the publication of the original article[1],the authors reported an error in Fig.3(b),and the figure legend was reversed.The correct Fig.3 has been provided in this orrection.
基金financially supported by the National Natural Science Foundation of China(Nos.21272169,21302135)the Key Innovation Team of Science & Technology in Zhejiang Province(No.2010R50018-10)+1 种基金the Science and Technology Bureau of Taizhou(No.08KY10)the Key Disciplines of Applied Chemistry of Zhejiang Province,Taizhou University
文摘A direct C–H amination reaction of N-Ts-2-Styrylaniline derivatives to realize the synthesis of indole derivatives was developed in the presence of copper salt. A variety of N-Ts-2-Styrylaniline derivatives were transformed into the corresponding indole products in good to excellent yield under mild conditions with the oxidation of potassium persulfate.
基金Ministry of Science & Technology (No.2013CB836900)National Natural Science Foundation of China (Nos.21290180,21172235 and 21222202)China Postdoctoral Science Foundation (No.2014M561537,M.Y.)
文摘Chlorospermines A and B are biologically interesting acridone natural products and recently isolated from Glycosmis chlorosperma.We report here a convergent approach to construct the tetracyclic core of the natural products.The two fragments are assembled together through Sonogashira coupling,and a cis-triene intermediate was prepared by using hydrosilylation/desilylation.A 6p-electrocyclization/aromatization sequence served as the key step of the synthesis,which formed the tetrasubstituted arene motif in one pot.
基金support in part by Natural Science Foundation of the Jiangsu Higher Education Institutions of China (No.13KJB150018)Natural Science Foundation of Jiangsu Province (No.BK20130926)+1 种基金Innovation program of Shanghai institute of technical physics of the Chinese Academy of Sciences (No.2013,Q-DX-36,Q-DX-37)Postgraduate Innovation Fund of Jiangsu Province (No.2013,CXZZ13_0459)
文摘A new colorimetric and fluorimetric chemosensor for F detection based on 1H-imidazo[4,5-b]phenazine derivative has been designed and synthesized.It shows excellent fluorescent specific selectivity and sensitivity for F^- in DMSO solution.Upon addition of F^- to the solution of probe 1,a remarkable color change from yellow to red could be observed easily by the naked-eye.The detection limit of this probe toward F^- is 6.2× 10 ^-6mol/L.Analysis by^1 H NMR proved that the imidazolyl N–H could be hydrogen-bonded with added fluoride anions,and results in the difference of colors.
基金financially supported by the National Natural Science Foundation of China(Nos.51325305,51473117 and 21274105)National Key Research and Development Program(No.2016YFC1101301)
文摘Over the past decades, the urgent need for high strength conductive hydrogels in diverse applications has motivated an unremitting effort to combine the improved mechanical properties of hydrogels with conductive performances. In this work, high strength conductive hydrogels intensified with intermolecular hydrogen bonding are fabricated by in situ mixing poly（2-vinyl-4,6-diamino-1,3,5-triazine-co-polyethylene glycol diacrylates）（PVDT-PEGDA） hydrogels with poly（3,4-ethylenedioxythiophene）-poly（styrenesulfonate）（PEDOT/PSS）. The conductive hydrogels in deionized water exhibit high mechanical performances with compressive strength and tensile strength in the range of 7.58-9.52 MPa and 0.48-1.20 MPa respectively, which are ascribed to the intermolecular hydrogen bonding interactions of diaminotriazinediaminotriazine（DAT-DAT） in the network. Meanwhile, adding PEDOT/PSS can significantly increase both the specific conductivities and equilibrium water contents of the hydrogels. These cytocompatible conductive hydrogels may have a great potential to be used as electrical stimuli responsive soft biomaterials.
基金supported by the National Natural Science Foundation of China (Nos.81160381 and 81260468)the Natural Science Foundation of Jilin Province (No.201115235)
文摘An efficient method has been developed for the synthesis of a series of（20R）-panaxadiol derivatives（4a–w） using a continuous-flow microreactor.The antitumor activities of the newly synthesized compounds were evaluated in vitro in two human prostate adenocarcinoma tumor cell lines（i.e.,PC-3and LNCa P cells）,and their cytotoxicities were evaluated using a standard MTT assay.Compounds 4c,4h,4p,4q and 4s exhibited higher antitumor activities toward PC-3 cell line than panaxadiol,which was used as a reference standard.
基金the National Natural Science Foundation of China (Nos.21262014 to Q.Sun and 21003018 to H.-B.Sun)Key Project of Chinese Ministry of Education (No.212092)Research Funds (Nos.ky2012zy08 and 2013QNBJRC001) from JXSTNU for financial support
文摘A microwave-assisted general method for the synthesis of 2-aminovinyl benzimidazoles has been developed.Treatment of the 1,2-phenylenediamines and N-arylated/N,N-dialkylated 3-aminoacroleins with bis（cyclopentadienyl）zirconium（IV） dichloride（Cp2Zr Cl2） as the catalyst under microwave irradiation for 3–5 min followed by in situ Mn O2 oxidation afforded thirteen 2-aminovinyl benzimidazoles in good yields.
基金Financial support from DST-Fast track,New Delhi(No.SERB/F/2013-14)
文摘An efficient methodology for the synthesis of 2,3-disubstituted 3H-quinazolin-4-ones is described via one-pot three component reaction from anthranilic acid using T3 P as catalyst. Mild reaction conditions,short reaction time, broad functional group tolerance, easy isolation of products and good yields are main advantages of this protocol.
基金the National Natural Science Foundation of China (Nos.21302188,81072576,91027033)Chinese Academy of Sciences (Nos.KJCX2-EW-N06-01 and XDA09030307) for financial support
文摘A novel method for achieving a copper（II）-catalyzed domino reaction for the construction of 2-aryl quinazolinones,without the addition of any ligand and additive,has been developed.The domino reaction achieved N-（a-substituted）benzylation,benzylic C–H amidation,and C–C（or C–H） bond cleavage.
文摘This paper discusses about how to use the theory of thematic progression in translation. Some linguists have talked about thematic progression in their works, but most of them are related to stylistics. This paper will pay much attention to the relationship between the patterns of thematic progression and the translation between English and Chinese, and how to use thematic progression in understanding and translating between English and Chinese.
文摘As we all know that exquisite subtitle translation of foreign film and television series is the fatal elements for them to spread among Chinese audiences. This article is based on Eugene·Nida's"the Functional Equivalence"principle with three char acteristics of sitcoms'subtitle to study the type, form and features of the Big Bang Theory, which lead to the conclusion of sitcom subtitle's characteristics. It helps us to analyze its subtitle from six aspects. As the result, the author of the paper makes the conclusion of translation tactic about Big Bang Theory, which could help the subtitle translation of similar sitcoms.
文摘Transliteration aims to adapt loanwords to perfect sound patterns and structures. With the guidance of Optimality Theory, this paper elaborates on the constraints that must be observed in transliteration to achieve Chinese phonological harmony from phonemic equivalents. It analyzes the ranking of constraints for structural acceptability of the loanwords.
文摘Certain molecules such as ethane and acetone possess moiety capable of internal rotation in addition to the rigid structure.When energy is large enough,the methyl group of ethane and acetone can freely rotate along the C—C bond.If not,the methyl group can then only oscillate within certain angles similar to the simple harmonic motion due to the restriction of potential barrier.This is the so-called torsion.
文摘Throughout this letter, G is a finite group. We fix a splitting modular system (K, R, F), where Char K=0 and Char F=p. A p-block means a block of the group algebra FG. S_p(G) denotes the set of Sylow p-subgroups of finite group G.
文摘It was reported in the literature that the main products from the reaction of LnCl3 and C5Me5M were anionic complexes of the type （ML2）(（C5Me5）n LnCl4-n), where L is Lewis base. During our study on the reaction of （HP（C2H5）3）2CeCl6 with 4 molar equiv, of C5Me5Na, we have recently succeeded in isolating a neutral species （C5Me5）2Ce Cl （Ⅰ）. （Ⅰ） was identified by elemental analysis, IR and 1H-NMR.
文摘To give the geometrical meanings of some coefficient inequalities in classical function theory is the purpose of this note. It also offers some possibilities to extend these inequalities into a new point of view. We only consider the class S, for it can be done without any difficulties for the other function classes. The S is the class of functions f(z)
文摘The phenyl derivatives of lanthanides Sc（C<sub>6</sub>H<sub>5</sub>）<sub>3</sub>, Y（C<sub>6</sub>H<sub>5</sub>）<sub>3</sub>, LiLa （C<sub>6</sub>H<sub>5</sub>）<sub>4</sub> and LiPr（C<sub>6</sub>H<sub>5</sub>）<sub>4</sub> were prepared by Hart et al. in 1970, and dis（cyclopentadienyl） phenyl complexes of lanthanides have been isolated recently. We reported here the synthesis and crystallography parameters of a new type of phenyl derivative of neodymium:
文摘The right question is actually not,"Do you lie?"The right question is,"How often do you lie?"And unfortunately,because we are all such good self-deceivers,we really do not know the answer to this question,so the best response may be,"Of course I lie a lot,why do you ask?"We deceive,misrepresent,obfuscate,misdirect,equivocate,confuse the issue,conveniently forget,withhold,lose track,exaggerate,argue for positions we do not even agree with,save face,change the topic,etc.-and blame others if we are caught at it!We all lie,often,everyday,and throughout our lives.
