High-temperature microwave absorbing materials(MAMs)and structures are increasingly appealing due to their critical role in stealth applications under harsh environments.However,the impedance mismatch caused by increa...High-temperature microwave absorbing materials(MAMs)and structures are increasingly appealing due to their critical role in stealth applications under harsh environments.However,the impedance mismatch caused by increased conduction loss often leads to a significant decline in electromagnetic wave absorp-tion(EMWA)performance at elevated temperatures,which severely restricts their practical application.In this study,we propose a novel approach for efficient electromagnetic wave absorption across a wide temperature range using reduced graphene oxide(RGO)/epoxy resin(EP)metacomposites that integrate both electromagnetic parameters and metamaterial design concepts.Due to the discrete distribution of the units,electromagnetic waves can more easily penetrate the interior of materials,thereby exhibiting stable microwave absorption(MA)performance and impedance-matching characteristics suitable across a wide temperature range.Consequently,exceptional MA properties can be achieved within the tem-perature range from 298 to 473 K.Furthermore,by carefully controlling the structural parameters in RGO metacomposites,both the resonant frequency and effective absorption bandwidth(EAB)can be optimized based on precise manipulation of equivalent electromagnetic parameters.This study not only provides an effective approach for the rational design of MA performance but also offers novel insights into achieving super metamaterials with outstanding performance across a wide temperature spectrum.展开更多
Rectangular explosive charges are usually used in military or civilian explosive transportation and storage.The effects of shape parameters and detonation positions on the peak overpressure and maximum impulse of blas...Rectangular explosive charges are usually used in military or civilian explosive transportation and storage.The effects of shape parameters and detonation positions on the peak overpressure and maximum impulse of blasts lack comprehensive investigation,which is significant for the design of blast-resistant structures.In this paper,the side-length ratio of the rectangle,orientation,and detonation position of the charge are chosen as controlling parameters to investigate their influence on blast loads in the scaled distances of the gauges ranging from 0.63 to 10.54 m/kg^(1/3) with well validated 3D numerical simulations.The results show that there is a large difference in the near-field spatial distribution of the blast load of the rectangular charge;if the blast load of the rectangular charge is simply evaluated with the spherical charge,the maximum peak overpressure(maximum impulse)will be underestimated by a factor of 7.46(4.84).This must be taken seriously by blast-resistant structure designers.With the increase in the scaled distance,when the critical scaled distance is greater than 6.32(7.38)m/kg^(1/3),the influence of the charge shape on the maximum peak overpressure(maximum impulse)of the spatial blast load can be ignored.In general,the impact of detonation of the charge at the end on the maximum peak overpressure is greater compared with central detonation,but for the impact of the maximum impulse,it is necessary to pay attention to the side-length ratio of the rectangular charge and the specific detonation position on the end face.Furthermore,the structural response of steel plates placed at different azimuths under the blast load of a rectangular charge is preliminarily analyzed,and the results show that the deformation and energy of the plates are consistent with the distribution of the blast load.These analysis results provide a reference for the explosion protection design in near-field air explosions.展开更多
As a kind of ionic artificial muscle material,Ionic Polymer-Metal Composites(IPMCs)have the advantages of a low drive current,light weight,and significant flexibility.IPMCs are widely used in the fields of biomedicine...As a kind of ionic artificial muscle material,Ionic Polymer-Metal Composites(IPMCs)have the advantages of a low drive current,light weight,and significant flexibility.IPMCs are widely used in the fields of biomedicine,soft robots,etc.However,the displacement and blocking force of the traditional sheet-type Nafion-IPMC need to be improved,and it has the limitation of unidirectional actuation.In this paper,a new type of short side chain Aquivion material is used as the polymer in the IPMC.The cylindrical IPMC is prepared by extrusion technology to improve its actuation performance and realize multi-degree-of-freedom motion.In comparison to the traditional Nafion-IPMC,the ion exchange capacity,specific capacitance,and conductivity of Aquivion-IPMC are improved by 28%,27%,and 32%,respectively,and the displacement and blocking force are improved by 57%and 25%,respectively.The cylindrical actuators can be deflected in eight directions.This indicates that Aquivion,as a polymer membrane for IPMC,holds significant application potential.By designing a cylindrical IPMC electrode distribution,the multi-degree-of-freedom deflection of IPMC can be realized.展开更多
The current artificial bone is unable to accurately replicate the inhomogeneity and anisotropy of human cancellous bone.To address this issue,we proposed a personalized approach based on clinical CT images to design m...The current artificial bone is unable to accurately replicate the inhomogeneity and anisotropy of human cancellous bone.To address this issue,we proposed a personalized approach based on clinical CT images to design mechanical equivalent porous structures for artificial femoral heads.Firstly,supported by Micro and clinical CT scans of 21 bone specimens,the anisotropic mechanical parameters of human cancellous bone in the femoral head were characterized using clinical CT values(Hounsfield unit).After that,the equivalent porous structure of cancellous bone was designed based on the gyroid surface,the influence of its degree of anisotropy and volume fraction on the macroscopic mechanical parameters was investigated by finite element analysis.Furthermore,a mapping relationship between CT values and the porous structure was established by jointly solving the mechanical parameters of the porous structure and human cancellous bone,allowing the design of personalized gradient porous structures based on clinical CT images.Finally,to verify the mechanical equivalence,implant press-in tests were conducted on 3D-printed artificial femoral heads and human femoral heads,the influence of the porous structure’s cell size in bone-implant interaction problems was also explored.Results showed that the minimum deviations of press-in stiffness(<15%)and peak load(<5%)both occurred when the cell size was 20%to 30%of the implant diameter.In conclusion,the designed porous structure can replicate the human cancellous bone-implant interaction at a high level,indicating its effectiveness in optimizing the mechanical performance of 3D-printed artificial femoral head.展开更多
The equivalent source(ES)method in the spherical coordinate system has been widely applied to processing,reduction,field modeling,and geophysical and geological interpretation of satellite magnetic anomaly data.Howeve...The equivalent source(ES)method in the spherical coordinate system has been widely applied to processing,reduction,field modeling,and geophysical and geological interpretation of satellite magnetic anomaly data.However,the inversion for the ES model suffers from nonuniqueness and instability,which remain unresolved.To mitigate these issues,we introduce both the minimum and flattest models into the model objective function as an alternative regularization approach in the spherical ES method.We first present the methods,then analyze the accuracy of forward calculation and test the proposed ES method in this study by using synthetic data.The experimental results from simulation data indicate that our proposed regularization effectively suppresses the Backus effect and mitigates inversion instability in the low-latitude region.Finally,we apply the proposed method to magnetic anomaly data from China Seismo-Electromagnetic Satellite-1(CSES-1)and Macao Science Satellite-1(MSS-1)magnetic measurements over Africa by constructing an ES model of the large-scale lithospheric magnetic field.Compared with existing global lithospheric magnetic field models,our ES model demonstrates good consistency at high altitudes and predicts more stable fields at low altitudes.Furthermore,we derive the reduction to the pole(RTP)magnetic anomaly fields and the apparent susceptibility contrast distribution based on the ES model.The latter correlates well with the regional tectonic framework in Africa and surroundings.展开更多
All-solid-state lithium batteries(ASSLBs)are strongly considered as the next-generation energy storage devices for their high energy density and intrinsic safety.The solid-solid contact between lithium metal and solid...All-solid-state lithium batteries(ASSLBs)are strongly considered as the next-generation energy storage devices for their high energy density and intrinsic safety.The solid-solid contact between lithium metal and solid electrolyte plays a vital role in the performance of working ASSLBs,which is challenging to investigate quantitatively by experimental approach.This work proposed a quantitative model based on the finite element method for electrochemical impedance spectroscopy simulation of different solid-solid contact states in ASSLBs.With the assistance of an equivalent circuit model and distribution of relaxation times,it is discovered that as the number of voids and the sharpness of cracks increase,the contact resistance Rcgrows and ultimately dominates the battery impedance.Through accurate fitting,inverse proportional relations between contact resistance Rcand(1-porosity)as well as crack angle was disclosed.This contribution affords a fresh insight into clarifying solid-solid contact states in ASSLBs.展开更多
The scientific assessment of ecosystem ser-vice value(ESV)plays a critical role in regional ecologi-cal protection and management,rational land use planning,and the establishment of ecological security barriers.The ec...The scientific assessment of ecosystem ser-vice value(ESV)plays a critical role in regional ecologi-cal protection and management,rational land use planning,and the establishment of ecological security barriers.The ecosystem service value of the Northeast Forest Belt from 2005 to 2020 was assessed,focusing on spatial–temporal changes and the driving forces behind these dynamics.Using multi-source data,the equivalent factor method,and geo-graphic detectors,we analyzed natural and socio-economic factors affecting the region.which was crucial for effective ecological conservation and land-use planning.Enhanced the effectiveness of policy formulation and land use plan-ning.The results show that the ESV of the Northeast Forest Belt exhibits an overall increasing trend from 2005 to 2020,with forests and wetlands contributing the most.However,there are significant differences between forest belts.Driven by natural and socio-economic factors,the ESV of forest belts in Heilongjiang and Jilin provinces showed significant growth.In contrast,the ESV of Forest Belts in Liaoning and Inner Mongolia of China remains relatively stable,but the spatial differentiation within these regions is characterized by significant clustering of high-value and low-value areas.Furthermore,climate regulation and hydrological regulation services were identified as the most important ecological functions in the Northeast Forest Belt,contributing greatly to regional ecological stability and human well-being.The ESV in the Northeast Forest Belt is improved during the study period,but the stability of the ecosystem is still chal-lenged by the dual impacts of natural and socio-economic factors.To further optimize regional land use planning and ecological protection policies,it is recommended to prior-itize the conservation of high-ESV areas,enhance ecological restoration efforts for wetlands and forests,and reasonably control the spatial layout of urban expansion and agricul-tural development.Additionally,this study highlights the importance of tailored ecological compensation policies and strategic land-use planning to balance environmental protec-tion and economic growth.展开更多
The constant amplitude loading fatigue tests were carried out on the 6061/7075 aluminum alloy TIG fillet welded lap specimens in this study,and the weld seam cross-section hardness was measured.The experimental result...The constant amplitude loading fatigue tests were carried out on the 6061/7075 aluminum alloy TIG fillet welded lap specimens in this study,and the weld seam cross-section hardness was measured.The experimental results show that most specimens mainly failed at the 7075 side weld toes even though the base material tensile strength of 7075 is higher than that of 6061.The maximum stress-strain concentration in the two finite element models is located at the 7075 side weld toe,which is basically consistent with the actual fracture location.The weld zone on the 7075 side experiences severe material softening,with a large gradient.However,the Vickers hardness value on the 6061 side negligibly changes and fluctuates around 70 HV.No obvious defects are found on the fatigue fracture,but a large number of secondary cracks appear.Cracks germinate from the weld toe and propagate in the direction of the plate thickness.Weld reinforcement has a serious impact on fatigue life.Fatigue life will decrease exponentially as the weld reinforcement increases under low stress.It is found that the notch stress method can give a better fatigue life prediction for TIG weldments,and the errors of the predicted results are within the range of two factors,while the prediction accuracy decreases under low stress.The equivalent structural stress method can also be used for fatigue life prediction of TIG weldments,but the errors of prediction results are within the range of three factors,and the accuracy decreases under high stress.展开更多
To further understand the performance of the energy harvesters under the influence of the wind force and the random excitation,this paper investigates the stochastic response of the bio-inspired energy harvesters subj...To further understand the performance of the energy harvesters under the influence of the wind force and the random excitation,this paper investigates the stochastic response of the bio-inspired energy harvesters subjected to Gaussian white noise and galloping excitation,simulating the flapping pattern of a seagull and its interaction with wind force.The equivalent linearization method is utilized to convert the original nonlinear model into the Itôstochastic differential equation by minimizing the mean squared error.Then,the second-order steady-state moments about the displacement,velocity,and voltage are derived by combining the moment analysis theory.The theoretical results are simulated numerically to analyze the stochastic response performance under different noise intensities,wind speeds,stiffness coefficients,and electromechanical coupling coefficients,time domain analysis is also conducted to study the performance of the harvester with different parameters.The results reveal that the mean square displacement and voltage increase with increasing the noise intensity and wind speed,larger absolute values of stiffness coefficient correspond to smaller mean square displacement and voltage,and larger electromechanical coupling coefficients can enhance the mean square voltage.Finally,the influence of wind speed and electromechanical coupling coefficient on the stationary probability density function(SPDF)is investigated,revealing the existence of a bimodal distribution under varying environmental conditions.展开更多
The mechanical properties of secondary cells are crucial to the safety and reliability of battery packs,which can fail due to extrusion and vibration in a vehicle crash.To analyze the structural response of the second...The mechanical properties of secondary cells are crucial to the safety and reliability of battery packs,which can fail due to extrusion and vibration in a vehicle crash.To analyze the structural response of the secondary cell and its other dynamic behaviors,the experiment and some numerical simulations were carried out based on single reference impact testing.Then,an equivalent constitutive relationship of the secondary cell was proposed to reveal the dynamic properties and used to guide the safety estimation of the battery pack.As the input parameter to the finite element model,the equivalent constitutive relationship,including but not limited to the elastic modulus and stain-stress curve,determines the simulation precision of the battery packs.Compared to the experimental results of the natural frequency of the battery pack,the simulation error is below 2%when the elastic modulus of the secondary cell in the battery pack has been verified.展开更多
Evaluation of a Commercially Available Radiochromic Film for Use as a Complementary Dosimeter for Rapid In-field Low Photon Equivalent Radiation Dose (≤50 mSv) Monitoring Nicky Nivi1, Helen Moise1,2, Ana Pejovic'...Evaluation of a Commercially Available Radiochromic Film for Use as a Complementary Dosimeter for Rapid In-field Low Photon Equivalent Radiation Dose (≤50 mSv) Monitoring Nicky Nivi1, Helen Moise1,2, Ana Pejovic'-Milic'1(1. Department of Physics, Toronto Metropolitan University, 350 Victoria Street, Toronto, Ontario, M5B 2K3;2. Autonomous and Radiological Technologies Section, Defense Research and Development Canada, PO Box 4000 Stn Main,Medicine Hat, Alberta, T1A 8K6).展开更多
The zero coprime system equivalence is one of important research in the theory of multidimensional system equivalence,and is closely related to zero coprime equivalence of multivariate polynomial matrices.We first dis...The zero coprime system equivalence is one of important research in the theory of multidimensional system equivalence,and is closely related to zero coprime equivalence of multivariate polynomial matrices.We first discuss the relation between zero coprime equivalence and unimodular equivalence for polynomial matrices.Then,we investigate the zero coprime equivalence problem for several classes of polynomial matrices,some novel findings and criteria on reducing these matrices to their Smith normal forms are obtained.Finally,an example is provided to illustrate the main results.展开更多
Although variant selection during the phase transformation of zirconium(Zr)alloys has been studied extensively,studies on the formation mechanism of microstructural characteristics related to a variant selection remai...Although variant selection during the phase transformation of zirconium(Zr)alloys has been studied extensively,studies on the formation mechanism of microstructural characteristics related to a variant selection remain limited.The formation mechanisms of the self-accommodation morphology and inter-variant boundary characteristics of a variants in homogenized Zr-2.5Nb alloy cooled by water quenching(WQ),furnace cooling(FC),and air cooling(AC)were systematically investigated from the perspective of local strain during phase transformation.The a variants exhibited triangular morphologies in both the WQ and AC samples,and a colony morphology in the FC sample.Further,there were five types of inter-variant boundaries:TypeI<0001>/10.53°,Typell<1120>/60°,Type Ill<1.377 I 2.3770.359>/60.83°,Type IV<10553>/63.26°,and Type V<12.381.380>/90°.The proportion of Type ll is up to 98%in the AC sample and 57.9%in the WQ sample;the Type I was very low in all three samples;and a high proportion of the Type V was observed in the FC sample(23.6%).The self-accommodation morphology of a variants is closely related to the equivalent strain(Evm)during the variant selection.Theoretical calculations indicated that,for a specific 2-variant combinations,there were always one or more 3-variant combinations with a lower Evm than the 2-variant combinations.A lower eym contributes to the presence of 3-variant combinations,which forms a triangle morphology.The formation of inter-variant boundaries is determined by the type and frequency of variants as well as the eym of the 2-variant combinations.The order of the mean values of evm for the five types of boundaries was Type II(0.0757),Type III(0.0859),Type IV(0.1012),Type V(0.1112),and Type I(0.1307).That is,Type II is the easiest and Type I is the most difficult,which resulted in a very high fraction of Type ll and a very low fraction of Type I in the WQ,AC,and FC samples.The presence of a high fraction of Type V in the FC sample was related to the type and fraction of each variant.展开更多
Storm surge events(SSEs)involve multiple hazard-causing factors,such as surges,extreme rainfall,strong winds,waves,and ocean currents,which have destructive impacts on coastal regions.For a quantitative multi-hazard a...Storm surge events(SSEs)involve multiple hazard-causing factors,such as surges,extreme rainfall,strong winds,waves,and ocean currents,which have destructive impacts on coastal regions.For a quantitative multi-hazard assessment of SSEs,this study introduced the concept of the storm surge event seawater-atmosphere system(SSE-SAS)and proposed the system energy equivalence(SEE)model from a systemic energy perspective.SEE was obtained by employing a parameterization approach,and the hazard index(HI)and the concept of most significant hazard(MSH)were adopted to evaluate the severity of SSE-SAS.SEE at five stations in the Shandong Peninsula was calculated from 2005 to 2019,and probability analysis and hazard assessment were further conducted.Results show that the SEE of SSE-SAS ranges from 0.029×10^(3) to 30.418×10^(3) J/m^(2),and it exhibits an insignificant decreasing trend from 2005 to 2019.The SEE of SSE-SAS in the west of the Shandong Peninsula is greater than that in the east.Moreover,storm waves,storm surges,and storm rainfall are the major contributors to SEE,which exhibit different spatial patterns and characters in different SSE-SAS types.The HI of SSE-SAS at five stations is no more than medium hazard level,with MSH at return periods of 2-to 4-year level.This study provides a new approach for quantifying multi-hazard SSEs,which offers scientific insights for regional multi-hazard risk reduction and mitigation efforts.展开更多
The high cost and low efficiency of full-scale vehicle experiments and numerical simulations limit the efficient development of armored vehicle occupant protection systems.The floor-occupant-seat local simulation mode...The high cost and low efficiency of full-scale vehicle experiments and numerical simulations limit the efficient development of armored vehicle occupant protection systems.The floor-occupant-seat local simulation model provides an alternative solution for quickly evaluating the performance of occupant protection systems.However,the error and rationality of the loading of the thin-walled floor in the local model cannot be ignored.This study proposed an equivalent loading method for the local model,which includes two parts:the dimensionality reduction method for acceleration matrix and the joint optimization framework for equivalent node coordinates.In the dimensionality reduction method,the dimension of the acceleration matrix was reduced based on the improved kernel principal component analysis(KPCA),and a dynamic variable bandwidth was introduced to address the limitation of failing to effectively measure the similarity between acceleration data in conventional KPCA.In addition,a least squares problem with forced displacement constraints was constructed to solve the correction matrix,thereby achieving the scale restoration process of the principal component acceleration matrix.The joint optimization framework for coordinates consists of the error assessment of response time histories(EARTH)and Bayesian optimization.In this framework,the local loading error of the equivalent acceleration matrix is taken as the Bayesian optimization objective,which is quantified and scored by EARTH.The expected improvement acquisition function was used to select the new set of the equivalent acceleration node coordinates for the self-updating optimization of the observation dataset and Gaussian process surrogate model.We reduced the dimension of the acceleration matrix from 2256 to 7,while retaining 91%of the information features.The comprehensive error score of occupant's lower limb response in the local model increased from 58.5%to 80.4%.The proposed equivalent loading method provides a solution for the rapid and reliable development of occupant protection systems.展开更多
Primary challenges with a forest inventory program are surveyors with various levels of experience and the turnover of inexperienced surveyors.Few studies have looked at the consistency of an instrument’s results amo...Primary challenges with a forest inventory program are surveyors with various levels of experience and the turnover of inexperienced surveyors.Few studies have looked at the consistency of an instrument’s results among inexperienced surveyors.Most studies have assessed whether instruments were significantly different.These tests do not indicate whether instruments were statistically equivalent,i.e.,that choosing either one would be acceptable under a certain level of tolerance.This study evaluated the consistency and statistical equivalence among instruments for measuring diameter at breast height(DBH)and for total tree height(HT)among inexperienced surveyors.The study was conducted as a randomized experiment with students from an introductory tree measurement course,using four types of DBH and HT instruments,and with different tree attributes.For DBH,the results show that D-tape was the most consistent across tree attributes and teams of inexperienced surveyors and was only statistically interchangeable with Caliper with a tolerance≥3 cm.For HT,Ultrasound was the most consistent but only statistically interchangeable with Laser with a tolerance≥8 m.A single type of instrument for measuring DBH and for HT is recommended,especially when field crews may be a mixture of experienced and inexperienced surveyors.Our study provides initial recommendations on the choice of instruments when either purchasing new ones or replacing old ones in forest inventories.展开更多
To investigate the problem of ethylene jet mixing and combustion in the scramjet at high Mach number(Ma = 8), numerical simulations were carried out for different equivalent ratios at cold and combustion conditions, i...To investigate the problem of ethylene jet mixing and combustion in the scramjet at high Mach number(Ma = 8), numerical simulations were carried out for different equivalent ratios at cold and combustion conditions, in which three-dimensional steady compressible RANS and k-ω SST turbulence model were adopted. It demonstrates that as the equivalence ratio increases from 0.42 to 1.08, the combustion becomes more intensified, and the higher backpressure pushes flame to propagate upstream. The supersonic combustion region in the combustor decreases from 92% to 85% with the increase of equivalence ratio from 0.42 to 1.08, resulting in the transition of the combustor from scram-mode to dual-mode. Both mixing and combustion efficiencies decrease by 35% and 16% respectively when the equivalence ratio increases from 0.42 to 1.08, indicating that the high equivalence ratio is unfavorable to the mixing and combustion processes. Combustion mode analysis reveals that the flame in the cavity under the high Mach number is dominated by non-premixed flames, i.e., more than 95% behaves as non-premixed mode, and the heat release is also mainly contributed by non-premixed flame. Increasing the equivalence ratio is beneficial to the thrust performance. Although the viscous force hardly changes with equivalence ratio, the percentage of pressure force used to balance the viscous force increases gradually,which limits the engine performance.展开更多
The penetration of ogival-nosed projectiles into ship plates represents a complex impact dynamics issue essential for analyzing structural failuremechanisms.Although stiffenedplates are vital in ship construction,fews...The penetration of ogival-nosed projectiles into ship plates represents a complex impact dynamics issue essential for analyzing structural failuremechanisms.Although stiffenedplates are vital in ship construction,fewstudies have addressed the issue of model equivalence under penetration loading.This study employs numerical simulation to validate an experiment with an ogival-nosed projectile penetrating a Q345 steel plate.Four equivalent stiffened plate methods are proposed based on the area,flexural modulus,moment of inertia,and thickness.The results indicate that thickness equivalence(DM4)is unsuitable for penetration-loaded stiffened plates,except under low-speed,nonpenetrating through impacts,and yields less accuracy than DM1/DM3.DM1,DM2,and DM3 each perform optimally with specific velocity ranges:DM1 at very low(critical)and high velocities,DM3 at low velocities,and DM2 at high speeds.Furthermore,in penetration scenarios,T-shaped stiffeners can be replacedwith rectangular ones,as both exhibit similar failure behaviors and deflection trends,simplifying the design while preserving key structural characteristics.These findings provide valuable insights into the design of protective ship structures.展开更多
The absence of humic vitrinite complicates the determination of thermal maturity in pre-Devonian sediments.Lower Paleozoic shales contain structured zooclasts,solid bitumen,and vitrinite-like materials,and their refle...The absence of humic vitrinite complicates the determination of thermal maturity in pre-Devonian sediments.Lower Paleozoic shales contain structured zooclasts,solid bitumen,and vitrinite-like materials,and their reflectances have been found to be valid maturity proxies.Yet there remains much controversy as to the degree of evolution of reflectances.The current work aims to investigate the reflectance of dispersed organic matter(DOM),as well as their transformation degree and organic pore development.To this end,this study evaluated an Upper Ordovician zooclasts-bearing shale and a Middle Jurassic coal sample via anhydrous-pyrolysis to compare differences in the maturation pathways between marine-derived DOM and terrigenous vitrinite.These two original samples were cut into small blocks and placed in an identical vacuum stainless vessel simultaneously.The pyrolysis was carried out at isothermal temperatures ranging from 250 to 550℃ for 48 h.The morphologic and reflectance changes of DOM in pyrolysis residues were studied and compared with previous pyrolysis results.Adopting the combined use of optical reflectance and scanning electron microscope(SEM)techniques,the study shows that DOM in the shale components consists of solid bitumen(SB),bituminite,chitinozoans,a few graptolites,vitrinite-like particles(VLP),alginate and liptodetrinite.The reflectance sequence,from high to low,is zooclasts,VLP and SB.Their reflectances gradually increases as the pyrolysis temperature rises,although the rate of growth is slower than that of co-heating coal vitrinite.Notably,zooclasts yield significantly higher reflectance values than those of VLP and SB at each pyrolysis temperature.However,the VLP undergoes two distinct phases in reflectance development,despite gradual morphology changes similar to vitrinite.Based on evidence of the optical texture and organic pore evolution,we argue that a fair amount of VLP in studied Upper Ordovician shale does not consist of graptolite-type fragments.Consequently,the VLPRo serves as a reliable indicator for assessing organic matter maturity in Ordovician shales with a reflectance value of less than 2.0%.This investigation enhances scholarly understandings of marine-derived DOM evolution issues,providing clearer correlations among reflectances of different DOM and reducing uncertainties in thermal maturity determination.展开更多
基金supported by the National Nature Science Foundation of China(Nos.22305066 and 52372041).
文摘High-temperature microwave absorbing materials(MAMs)and structures are increasingly appealing due to their critical role in stealth applications under harsh environments.However,the impedance mismatch caused by increased conduction loss often leads to a significant decline in electromagnetic wave absorp-tion(EMWA)performance at elevated temperatures,which severely restricts their practical application.In this study,we propose a novel approach for efficient electromagnetic wave absorption across a wide temperature range using reduced graphene oxide(RGO)/epoxy resin(EP)metacomposites that integrate both electromagnetic parameters and metamaterial design concepts.Due to the discrete distribution of the units,electromagnetic waves can more easily penetrate the interior of materials,thereby exhibiting stable microwave absorption(MA)performance and impedance-matching characteristics suitable across a wide temperature range.Consequently,exceptional MA properties can be achieved within the tem-perature range from 298 to 473 K.Furthermore,by carefully controlling the structural parameters in RGO metacomposites,both the resonant frequency and effective absorption bandwidth(EAB)can be optimized based on precise manipulation of equivalent electromagnetic parameters.This study not only provides an effective approach for the rational design of MA performance but also offers novel insights into achieving super metamaterials with outstanding performance across a wide temperature spectrum.
基金supported by the National Science Foundation of China(Grant No.14102428)the Fundamental Research Funds for the Central Universities(Grant Nos.WK2090000019 and YD2480002002)the Open Research Fund of Anhui Province Key Laboratory of Green Building and Assembly Construction,Anhui Institute of Building Research&Design(Grant No.2021-JKYL-005).
文摘Rectangular explosive charges are usually used in military or civilian explosive transportation and storage.The effects of shape parameters and detonation positions on the peak overpressure and maximum impulse of blasts lack comprehensive investigation,which is significant for the design of blast-resistant structures.In this paper,the side-length ratio of the rectangle,orientation,and detonation position of the charge are chosen as controlling parameters to investigate their influence on blast loads in the scaled distances of the gauges ranging from 0.63 to 10.54 m/kg^(1/3) with well validated 3D numerical simulations.The results show that there is a large difference in the near-field spatial distribution of the blast load of the rectangular charge;if the blast load of the rectangular charge is simply evaluated with the spherical charge,the maximum peak overpressure(maximum impulse)will be underestimated by a factor of 7.46(4.84).This must be taken seriously by blast-resistant structure designers.With the increase in the scaled distance,when the critical scaled distance is greater than 6.32(7.38)m/kg^(1/3),the influence of the charge shape on the maximum peak overpressure(maximum impulse)of the spatial blast load can be ignored.In general,the impact of detonation of the charge at the end on the maximum peak overpressure is greater compared with central detonation,but for the impact of the maximum impulse,it is necessary to pay attention to the side-length ratio of the rectangular charge and the specific detonation position on the end face.Furthermore,the structural response of steel plates placed at different azimuths under the blast load of a rectangular charge is preliminarily analyzed,and the results show that the deformation and energy of the plates are consistent with the distribution of the blast load.These analysis results provide a reference for the explosion protection design in near-field air explosions.
基金financial support from the National Natural Science Foundation of China(Grant No.U1637101)The Research Fund of State Key Laboratory of Mechanics and Control for Aerospace Structures(1005-ZAG23011).
文摘As a kind of ionic artificial muscle material,Ionic Polymer-Metal Composites(IPMCs)have the advantages of a low drive current,light weight,and significant flexibility.IPMCs are widely used in the fields of biomedicine,soft robots,etc.However,the displacement and blocking force of the traditional sheet-type Nafion-IPMC need to be improved,and it has the limitation of unidirectional actuation.In this paper,a new type of short side chain Aquivion material is used as the polymer in the IPMC.The cylindrical IPMC is prepared by extrusion technology to improve its actuation performance and realize multi-degree-of-freedom motion.In comparison to the traditional Nafion-IPMC,the ion exchange capacity,specific capacitance,and conductivity of Aquivion-IPMC are improved by 28%,27%,and 32%,respectively,and the displacement and blocking force are improved by 57%and 25%,respectively.The cylindrical actuators can be deflected in eight directions.This indicates that Aquivion,as a polymer membrane for IPMC,holds significant application potential.By designing a cylindrical IPMC electrode distribution,the multi-degree-of-freedom deflection of IPMC can be realized.
基金supported by the National Key R&D Program of China(Grant No.2021YFC2501700).
文摘The current artificial bone is unable to accurately replicate the inhomogeneity and anisotropy of human cancellous bone.To address this issue,we proposed a personalized approach based on clinical CT images to design mechanical equivalent porous structures for artificial femoral heads.Firstly,supported by Micro and clinical CT scans of 21 bone specimens,the anisotropic mechanical parameters of human cancellous bone in the femoral head were characterized using clinical CT values(Hounsfield unit).After that,the equivalent porous structure of cancellous bone was designed based on the gyroid surface,the influence of its degree of anisotropy and volume fraction on the macroscopic mechanical parameters was investigated by finite element analysis.Furthermore,a mapping relationship between CT values and the porous structure was established by jointly solving the mechanical parameters of the porous structure and human cancellous bone,allowing the design of personalized gradient porous structures based on clinical CT images.Finally,to verify the mechanical equivalence,implant press-in tests were conducted on 3D-printed artificial femoral heads and human femoral heads,the influence of the porous structure’s cell size in bone-implant interaction problems was also explored.Results showed that the minimum deviations of press-in stiffness(<15%)and peak load(<5%)both occurred when the cell size was 20%to 30%of the implant diameter.In conclusion,the designed porous structure can replicate the human cancellous bone-implant interaction at a high level,indicating its effectiveness in optimizing the mechanical performance of 3D-printed artificial femoral head.
基金supported by the National Natural Science Foundation of China(Grant Nos.42250103 and 42174090)the Opening Fund of Key Laboratory of Geological Survey and Evaluation of Ministry of Education(Grant No.GLAB2023ZR02)the MOST Special Fund from the State Key Laboratory of Geological Processes and Mineral Resources(Grant No.MSFGPMR2022-4).
文摘The equivalent source(ES)method in the spherical coordinate system has been widely applied to processing,reduction,field modeling,and geophysical and geological interpretation of satellite magnetic anomaly data.However,the inversion for the ES model suffers from nonuniqueness and instability,which remain unresolved.To mitigate these issues,we introduce both the minimum and flattest models into the model objective function as an alternative regularization approach in the spherical ES method.We first present the methods,then analyze the accuracy of forward calculation and test the proposed ES method in this study by using synthetic data.The experimental results from simulation data indicate that our proposed regularization effectively suppresses the Backus effect and mitigates inversion instability in the low-latitude region.Finally,we apply the proposed method to magnetic anomaly data from China Seismo-Electromagnetic Satellite-1(CSES-1)and Macao Science Satellite-1(MSS-1)magnetic measurements over Africa by constructing an ES model of the large-scale lithospheric magnetic field.Compared with existing global lithospheric magnetic field models,our ES model demonstrates good consistency at high altitudes and predicts more stable fields at low altitudes.Furthermore,we derive the reduction to the pole(RTP)magnetic anomaly fields and the apparent susceptibility contrast distribution based on the ES model.The latter correlates well with the regional tectonic framework in Africa and surroundings.
基金supported by the Beijing Natural Science Foundation(Z200011,L233004)the National Key Research and Development Program(2021YFB2500300)+3 种基金the National Natural Science Foundation of China(52394170,52394171,22109011,22393900,and 22108151)the Tsinghua-Jiangyin Innovation Special Fund(TJISF)(2022JYTH0101)the S&T Program of Hebei(22344402D)the Tsinghua University Initiative Scientific Research Program.
文摘All-solid-state lithium batteries(ASSLBs)are strongly considered as the next-generation energy storage devices for their high energy density and intrinsic safety.The solid-solid contact between lithium metal and solid electrolyte plays a vital role in the performance of working ASSLBs,which is challenging to investigate quantitatively by experimental approach.This work proposed a quantitative model based on the finite element method for electrochemical impedance spectroscopy simulation of different solid-solid contact states in ASSLBs.With the assistance of an equivalent circuit model and distribution of relaxation times,it is discovered that as the number of voids and the sharpness of cracks increase,the contact resistance Rcgrows and ultimately dominates the battery impedance.Through accurate fitting,inverse proportional relations between contact resistance Rcand(1-porosity)as well as crack angle was disclosed.This contribution affords a fresh insight into clarifying solid-solid contact states in ASSLBs.
基金funded by the Central University D Project(HFW230600022)National Natural Science Foundation of China(71973021)+1 种基金National Natural Science Foundation Youth Funding Project(72003022)Heilongjiang Province University Think Tank Open Topic(ZKKF2022173).
文摘The scientific assessment of ecosystem ser-vice value(ESV)plays a critical role in regional ecologi-cal protection and management,rational land use planning,and the establishment of ecological security barriers.The ecosystem service value of the Northeast Forest Belt from 2005 to 2020 was assessed,focusing on spatial–temporal changes and the driving forces behind these dynamics.Using multi-source data,the equivalent factor method,and geo-graphic detectors,we analyzed natural and socio-economic factors affecting the region.which was crucial for effective ecological conservation and land-use planning.Enhanced the effectiveness of policy formulation and land use plan-ning.The results show that the ESV of the Northeast Forest Belt exhibits an overall increasing trend from 2005 to 2020,with forests and wetlands contributing the most.However,there are significant differences between forest belts.Driven by natural and socio-economic factors,the ESV of forest belts in Heilongjiang and Jilin provinces showed significant growth.In contrast,the ESV of Forest Belts in Liaoning and Inner Mongolia of China remains relatively stable,but the spatial differentiation within these regions is characterized by significant clustering of high-value and low-value areas.Furthermore,climate regulation and hydrological regulation services were identified as the most important ecological functions in the Northeast Forest Belt,contributing greatly to regional ecological stability and human well-being.The ESV in the Northeast Forest Belt is improved during the study period,but the stability of the ecosystem is still chal-lenged by the dual impacts of natural and socio-economic factors.To further optimize regional land use planning and ecological protection policies,it is recommended to prior-itize the conservation of high-ESV areas,enhance ecological restoration efforts for wetlands and forests,and reasonably control the spatial layout of urban expansion and agricul-tural development.Additionally,this study highlights the importance of tailored ecological compensation policies and strategic land-use planning to balance environmental protec-tion and economic growth.
基金Partially funded by the National Natural Science Foundation of China(No.51065012)。
文摘The constant amplitude loading fatigue tests were carried out on the 6061/7075 aluminum alloy TIG fillet welded lap specimens in this study,and the weld seam cross-section hardness was measured.The experimental results show that most specimens mainly failed at the 7075 side weld toes even though the base material tensile strength of 7075 is higher than that of 6061.The maximum stress-strain concentration in the two finite element models is located at the 7075 side weld toe,which is basically consistent with the actual fracture location.The weld zone on the 7075 side experiences severe material softening,with a large gradient.However,the Vickers hardness value on the 6061 side negligibly changes and fluctuates around 70 HV.No obvious defects are found on the fatigue fracture,but a large number of secondary cracks appear.Cracks germinate from the weld toe and propagate in the direction of the plate thickness.Weld reinforcement has a serious impact on fatigue life.Fatigue life will decrease exponentially as the weld reinforcement increases under low stress.It is found that the notch stress method can give a better fatigue life prediction for TIG weldments,and the errors of the predicted results are within the range of two factors,while the prediction accuracy decreases under low stress.The equivalent structural stress method can also be used for fatigue life prediction of TIG weldments,but the errors of prediction results are within the range of three factors,and the accuracy decreases under high stress.
文摘To further understand the performance of the energy harvesters under the influence of the wind force and the random excitation,this paper investigates the stochastic response of the bio-inspired energy harvesters subjected to Gaussian white noise and galloping excitation,simulating the flapping pattern of a seagull and its interaction with wind force.The equivalent linearization method is utilized to convert the original nonlinear model into the Itôstochastic differential equation by minimizing the mean squared error.Then,the second-order steady-state moments about the displacement,velocity,and voltage are derived by combining the moment analysis theory.The theoretical results are simulated numerically to analyze the stochastic response performance under different noise intensities,wind speeds,stiffness coefficients,and electromechanical coupling coefficients,time domain analysis is also conducted to study the performance of the harvester with different parameters.The results reveal that the mean square displacement and voltage increase with increasing the noise intensity and wind speed,larger absolute values of stiffness coefficient correspond to smaller mean square displacement and voltage,and larger electromechanical coupling coefficients can enhance the mean square voltage.Finally,the influence of wind speed and electromechanical coupling coefficient on the stationary probability density function(SPDF)is investigated,revealing the existence of a bimodal distribution under varying environmental conditions.
基金supported by the 2019 Postdoctoral Research Project funded by Hefei Municipal Bureau of Human Resources and Social Security and the National key R&D Program of China(2017YFB0102101).
文摘The mechanical properties of secondary cells are crucial to the safety and reliability of battery packs,which can fail due to extrusion and vibration in a vehicle crash.To analyze the structural response of the secondary cell and its other dynamic behaviors,the experiment and some numerical simulations were carried out based on single reference impact testing.Then,an equivalent constitutive relationship of the secondary cell was proposed to reveal the dynamic properties and used to guide the safety estimation of the battery pack.As the input parameter to the finite element model,the equivalent constitutive relationship,including but not limited to the elastic modulus and stain-stress curve,determines the simulation precision of the battery packs.Compared to the experimental results of the natural frequency of the battery pack,the simulation error is below 2%when the elastic modulus of the secondary cell in the battery pack has been verified.
文摘Evaluation of a Commercially Available Radiochromic Film for Use as a Complementary Dosimeter for Rapid In-field Low Photon Equivalent Radiation Dose (≤50 mSv) Monitoring Nicky Nivi1, Helen Moise1,2, Ana Pejovic'-Milic'1(1. Department of Physics, Toronto Metropolitan University, 350 Victoria Street, Toronto, Ontario, M5B 2K3;2. Autonomous and Radiological Technologies Section, Defense Research and Development Canada, PO Box 4000 Stn Main,Medicine Hat, Alberta, T1A 8K6).
基金Supported by the National Natural Science Foundation of China(12271154)the Natural Science Foundation of Hunan Province(2022JJ30234)the Postgraduate Scientific Research Innovation Project of Hunan Province(CX20231032)。
文摘The zero coprime system equivalence is one of important research in the theory of multidimensional system equivalence,and is closely related to zero coprime equivalence of multivariate polynomial matrices.We first discuss the relation between zero coprime equivalence and unimodular equivalence for polynomial matrices.Then,we investigate the zero coprime equivalence problem for several classes of polynomial matrices,some novel findings and criteria on reducing these matrices to their Smith normal forms are obtained.Finally,an example is provided to illustrate the main results.
基金financially supported by the National Natural Science Foundation of China(No.52275161)the Key Projects of International Science and Technology Cooperation in Shaanxi Province(No.2024GH-ZDXM-01)+2 种基金the Shaanxi Science and Technology Innovation Team(No.2023-CX-TD-50)the Shaanxi Qin Chuangyuan Scientists and Engineers(No.2022KXJ-145)the National Natural Science Foundation of Jiangsu Province of China(No.BK20241873),and Shaanxi Province Science and Technology Department-Shaanxi International Science and Technology Cooperation Base(No.2020GHJD-10).
文摘Although variant selection during the phase transformation of zirconium(Zr)alloys has been studied extensively,studies on the formation mechanism of microstructural characteristics related to a variant selection remain limited.The formation mechanisms of the self-accommodation morphology and inter-variant boundary characteristics of a variants in homogenized Zr-2.5Nb alloy cooled by water quenching(WQ),furnace cooling(FC),and air cooling(AC)were systematically investigated from the perspective of local strain during phase transformation.The a variants exhibited triangular morphologies in both the WQ and AC samples,and a colony morphology in the FC sample.Further,there were five types of inter-variant boundaries:TypeI<0001>/10.53°,Typell<1120>/60°,Type Ill<1.377 I 2.3770.359>/60.83°,Type IV<10553>/63.26°,and Type V<12.381.380>/90°.The proportion of Type ll is up to 98%in the AC sample and 57.9%in the WQ sample;the Type I was very low in all three samples;and a high proportion of the Type V was observed in the FC sample(23.6%).The self-accommodation morphology of a variants is closely related to the equivalent strain(Evm)during the variant selection.Theoretical calculations indicated that,for a specific 2-variant combinations,there were always one or more 3-variant combinations with a lower Evm than the 2-variant combinations.A lower eym contributes to the presence of 3-variant combinations,which forms a triangle morphology.The formation of inter-variant boundaries is determined by the type and frequency of variants as well as the eym of the 2-variant combinations.The order of the mean values of evm for the five types of boundaries was Type II(0.0757),Type III(0.0859),Type IV(0.1012),Type V(0.1112),and Type I(0.1307).That is,Type II is the easiest and Type I is the most difficult,which resulted in a very high fraction of Type ll and a very low fraction of Type I in the WQ,AC,and FC samples.The presence of a high fraction of Type V in the FC sample was related to the type and fraction of each variant.
基金supported by the Key Laboratory of Coastal Science and Integrated Management,Ministry of Natural Resources(No.2022COSIMQ002)the Shandong Provincial Social Science Planning Research Project(No.22CXSXJ15)+1 种基金the Guangxi Key Laboratory of Marine Environmental Science,Guangxi Academy of Sciences(No.GXKLHY21-04)the Hainan Province Marxism Project General Program(No.2023HNMGC03).
文摘Storm surge events(SSEs)involve multiple hazard-causing factors,such as surges,extreme rainfall,strong winds,waves,and ocean currents,which have destructive impacts on coastal regions.For a quantitative multi-hazard assessment of SSEs,this study introduced the concept of the storm surge event seawater-atmosphere system(SSE-SAS)and proposed the system energy equivalence(SEE)model from a systemic energy perspective.SEE was obtained by employing a parameterization approach,and the hazard index(HI)and the concept of most significant hazard(MSH)were adopted to evaluate the severity of SSE-SAS.SEE at five stations in the Shandong Peninsula was calculated from 2005 to 2019,and probability analysis and hazard assessment were further conducted.Results show that the SEE of SSE-SAS ranges from 0.029×10^(3) to 30.418×10^(3) J/m^(2),and it exhibits an insignificant decreasing trend from 2005 to 2019.The SEE of SSE-SAS in the west of the Shandong Peninsula is greater than that in the east.Moreover,storm waves,storm surges,and storm rainfall are the major contributors to SEE,which exhibit different spatial patterns and characters in different SSE-SAS types.The HI of SSE-SAS at five stations is no more than medium hazard level,with MSH at return periods of 2-to 4-year level.This study provides a new approach for quantifying multi-hazard SSEs,which offers scientific insights for regional multi-hazard risk reduction and mitigation efforts.
基金supported by the National Natural Science Foundation of China(Grant Nos.52272437 and 52272370)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX24_0635)。
文摘The high cost and low efficiency of full-scale vehicle experiments and numerical simulations limit the efficient development of armored vehicle occupant protection systems.The floor-occupant-seat local simulation model provides an alternative solution for quickly evaluating the performance of occupant protection systems.However,the error and rationality of the loading of the thin-walled floor in the local model cannot be ignored.This study proposed an equivalent loading method for the local model,which includes two parts:the dimensionality reduction method for acceleration matrix and the joint optimization framework for equivalent node coordinates.In the dimensionality reduction method,the dimension of the acceleration matrix was reduced based on the improved kernel principal component analysis(KPCA),and a dynamic variable bandwidth was introduced to address the limitation of failing to effectively measure the similarity between acceleration data in conventional KPCA.In addition,a least squares problem with forced displacement constraints was constructed to solve the correction matrix,thereby achieving the scale restoration process of the principal component acceleration matrix.The joint optimization framework for coordinates consists of the error assessment of response time histories(EARTH)and Bayesian optimization.In this framework,the local loading error of the equivalent acceleration matrix is taken as the Bayesian optimization objective,which is quantified and scored by EARTH.The expected improvement acquisition function was used to select the new set of the equivalent acceleration node coordinates for the self-updating optimization of the observation dataset and Gaussian process surrogate model.We reduced the dimension of the acceleration matrix from 2256 to 7,while retaining 91%of the information features.The comprehensive error score of occupant's lower limb response in the local model increased from 58.5%to 80.4%.The proposed equivalent loading method provides a solution for the rapid and reliable development of occupant protection systems.
文摘Primary challenges with a forest inventory program are surveyors with various levels of experience and the turnover of inexperienced surveyors.Few studies have looked at the consistency of an instrument’s results among inexperienced surveyors.Most studies have assessed whether instruments were significantly different.These tests do not indicate whether instruments were statistically equivalent,i.e.,that choosing either one would be acceptable under a certain level of tolerance.This study evaluated the consistency and statistical equivalence among instruments for measuring diameter at breast height(DBH)and for total tree height(HT)among inexperienced surveyors.The study was conducted as a randomized experiment with students from an introductory tree measurement course,using four types of DBH and HT instruments,and with different tree attributes.For DBH,the results show that D-tape was the most consistent across tree attributes and teams of inexperienced surveyors and was only statistically interchangeable with Caliper with a tolerance≥3 cm.For HT,Ultrasound was the most consistent but only statistically interchangeable with Laser with a tolerance≥8 m.A single type of instrument for measuring DBH and for HT is recommended,especially when field crews may be a mixture of experienced and inexperienced surveyors.Our study provides initial recommendations on the choice of instruments when either purchasing new ones or replacing old ones in forest inventories.
文摘To investigate the problem of ethylene jet mixing and combustion in the scramjet at high Mach number(Ma = 8), numerical simulations were carried out for different equivalent ratios at cold and combustion conditions, in which three-dimensional steady compressible RANS and k-ω SST turbulence model were adopted. It demonstrates that as the equivalence ratio increases from 0.42 to 1.08, the combustion becomes more intensified, and the higher backpressure pushes flame to propagate upstream. The supersonic combustion region in the combustor decreases from 92% to 85% with the increase of equivalence ratio from 0.42 to 1.08, resulting in the transition of the combustor from scram-mode to dual-mode. Both mixing and combustion efficiencies decrease by 35% and 16% respectively when the equivalence ratio increases from 0.42 to 1.08, indicating that the high equivalence ratio is unfavorable to the mixing and combustion processes. Combustion mode analysis reveals that the flame in the cavity under the high Mach number is dominated by non-premixed flames, i.e., more than 95% behaves as non-premixed mode, and the heat release is also mainly contributed by non-premixed flame. Increasing the equivalence ratio is beneficial to the thrust performance. Although the viscous force hardly changes with equivalence ratio, the percentage of pressure force used to balance the viscous force increases gradually,which limits the engine performance.
基金supported by Natural Science Foundation of Fujian Province(2022I0019)Scientific Research Foundation for Jimei University(ZQ2024041,ZQ2024042).
文摘The penetration of ogival-nosed projectiles into ship plates represents a complex impact dynamics issue essential for analyzing structural failuremechanisms.Although stiffenedplates are vital in ship construction,fewstudies have addressed the issue of model equivalence under penetration loading.This study employs numerical simulation to validate an experiment with an ogival-nosed projectile penetrating a Q345 steel plate.Four equivalent stiffened plate methods are proposed based on the area,flexural modulus,moment of inertia,and thickness.The results indicate that thickness equivalence(DM4)is unsuitable for penetration-loaded stiffened plates,except under low-speed,nonpenetrating through impacts,and yields less accuracy than DM1/DM3.DM1,DM2,and DM3 each perform optimally with specific velocity ranges:DM1 at very low(critical)and high velocities,DM3 at low velocities,and DM2 at high speeds.Furthermore,in penetration scenarios,T-shaped stiffeners can be replacedwith rectangular ones,as both exhibit similar failure behaviors and deflection trends,simplifying the design while preserving key structural characteristics.These findings provide valuable insights into the design of protective ship structures.
基金supported by National Natural Science Foundation of China(Nos.42202172,U24B6001,41830424)the Fundamental Research Funds for the Central Universities,CHD(300102274202).
文摘The absence of humic vitrinite complicates the determination of thermal maturity in pre-Devonian sediments.Lower Paleozoic shales contain structured zooclasts,solid bitumen,and vitrinite-like materials,and their reflectances have been found to be valid maturity proxies.Yet there remains much controversy as to the degree of evolution of reflectances.The current work aims to investigate the reflectance of dispersed organic matter(DOM),as well as their transformation degree and organic pore development.To this end,this study evaluated an Upper Ordovician zooclasts-bearing shale and a Middle Jurassic coal sample via anhydrous-pyrolysis to compare differences in the maturation pathways between marine-derived DOM and terrigenous vitrinite.These two original samples were cut into small blocks and placed in an identical vacuum stainless vessel simultaneously.The pyrolysis was carried out at isothermal temperatures ranging from 250 to 550℃ for 48 h.The morphologic and reflectance changes of DOM in pyrolysis residues were studied and compared with previous pyrolysis results.Adopting the combined use of optical reflectance and scanning electron microscope(SEM)techniques,the study shows that DOM in the shale components consists of solid bitumen(SB),bituminite,chitinozoans,a few graptolites,vitrinite-like particles(VLP),alginate and liptodetrinite.The reflectance sequence,from high to low,is zooclasts,VLP and SB.Their reflectances gradually increases as the pyrolysis temperature rises,although the rate of growth is slower than that of co-heating coal vitrinite.Notably,zooclasts yield significantly higher reflectance values than those of VLP and SB at each pyrolysis temperature.However,the VLP undergoes two distinct phases in reflectance development,despite gradual morphology changes similar to vitrinite.Based on evidence of the optical texture and organic pore evolution,we argue that a fair amount of VLP in studied Upper Ordovician shale does not consist of graptolite-type fragments.Consequently,the VLPRo serves as a reliable indicator for assessing organic matter maturity in Ordovician shales with a reflectance value of less than 2.0%.This investigation enhances scholarly understandings of marine-derived DOM evolution issues,providing clearer correlations among reflectances of different DOM and reducing uncertainties in thermal maturity determination.
