The interfacial oxygen transfer rate is one of the main factors to control the composition of alloys.The commonly employed method of studying the interfacial oxygen transfer rate is the chemical composition analysis;h...The interfacial oxygen transfer rate is one of the main factors to control the composition of alloys.The commonly employed method of studying the interfacial oxygen transfer rate is the chemical composition analysis;however,it is difficult to be studied in situ.Here,a new method of measuring the oxygen transfer rate at the gas-slag and slag-metal interfaces was reported based on electrochemical analyses.The interfacial oxygen transfer rate in the smelting process of Inconel 718 superalloy was investigated at 1723,1773,1823,and 1873 K.The experimental results show that the electrochemical method can measure the real-time oxygen content;hence,this method is promising in controlling the oxygen content in alloys.As the temperature increased,both the equilibrium oxygen content and the rate of oxygen absorption increased significantly,and the increase was the most obvious when the temperature was 1873 K.The possible reason is that the increase in temperature weakens the mass transfer resistance of the electric double layer at the interface,thus accelerating the oxygen transfer rate.展开更多
通过对转炉终点碳氧积及RH深脱碳的热力学分析,结合实际生产数据,探讨了炼钢过程铁碳氧平衡问题。得出转炉终点碳氧积并非固定,而是随外界条件变化而变化;其他组元活度相互作用系数及温度对碳氧积影响很小,但CO平衡分压影响显著,当CO平...通过对转炉终点碳氧积及RH深脱碳的热力学分析,结合实际生产数据,探讨了炼钢过程铁碳氧平衡问题。得出转炉终点碳氧积并非固定,而是随外界条件变化而变化;其他组元活度相互作用系数及温度对碳氧积影响很小,但CO平衡分压影响显著,当CO平衡分压达1 k Pa时即可实现平衡碳含量10×10-6;在正常转炉出钢温度范围,碳含量处于0.034%时,钢液出现"脱铁保碳"转折点,与之相平衡的渣中氧化铁含量仅需11%。展开更多
基金gratefully express their appreciation to National Natural Science Foundation of China(Nos.51974153 and U1960203)the Joint Fund of State Key Laboratory of Marine Engineering and University of Science and Technology Liaoning(SKLMEA-USTL-201707)the China Scholarship Council(201908210457).
文摘The interfacial oxygen transfer rate is one of the main factors to control the composition of alloys.The commonly employed method of studying the interfacial oxygen transfer rate is the chemical composition analysis;however,it is difficult to be studied in situ.Here,a new method of measuring the oxygen transfer rate at the gas-slag and slag-metal interfaces was reported based on electrochemical analyses.The interfacial oxygen transfer rate in the smelting process of Inconel 718 superalloy was investigated at 1723,1773,1823,and 1873 K.The experimental results show that the electrochemical method can measure the real-time oxygen content;hence,this method is promising in controlling the oxygen content in alloys.As the temperature increased,both the equilibrium oxygen content and the rate of oxygen absorption increased significantly,and the increase was the most obvious when the temperature was 1873 K.The possible reason is that the increase in temperature weakens the mass transfer resistance of the electric double layer at the interface,thus accelerating the oxygen transfer rate.
文摘通过对转炉终点碳氧积及RH深脱碳的热力学分析,结合实际生产数据,探讨了炼钢过程铁碳氧平衡问题。得出转炉终点碳氧积并非固定,而是随外界条件变化而变化;其他组元活度相互作用系数及温度对碳氧积影响很小,但CO平衡分压影响显著,当CO平衡分压达1 k Pa时即可实现平衡碳含量10×10-6;在正常转炉出钢温度范围,碳含量处于0.034%时,钢液出现"脱铁保碳"转折点,与之相平衡的渣中氧化铁含量仅需11%。
