INTRODUCTION Epoxy resins are reactive polymers which when cured with a variety of chemicals lead to a host of useful thermosets. Since the epoxide is a strained ring, it readily undergoes addition and homopolymerizat...INTRODUCTION Epoxy resins are reactive polymers which when cured with a variety of chemicals lead to a host of useful thermosets. Since the epoxide is a strained ring, it readily undergoes addition and homopolymerization. The homopolymerization is a process catalysed by acids, bases, Lewis acids, t-amines as well as by inorganic salts.展开更多
Epoxy resin is widely used in electronic packaging due to its exceptional performance,particularly the low-temperature curable thiol/epoxy system,which effectively minimizes thermal damage to sensitive electronic comp...Epoxy resin is widely used in electronic packaging due to its exceptional performance,particularly the low-temperature curable thiol/epoxy system,which effectively minimizes thermal damage to sensitive electronic components.However,the majority of commercial thiol curing agents contain hydrolysable ester bonds and lack rigid structures,which induces most of thiol/epoxy systems still suffering from unsatisfactory heat resistance and hygrothermal resistance,significantly hindering their application in electronic packaging.In this study,we synthesized a tetrafunctional thiol compound,bis[3-(3-sulfanylpropyl)-4-(3-sulfanylpropoxy)phenyl]sulfone(TMBPS)with rigid and ester-free structures to replace traditional commercial thiol curing agents,pentaerythritol tetra(3-mercaptopropionate)(PETMP).Compared to the PETMP/epoxy system,the TMBPS/epoxy system exhibited superior comprehensive properties.The rigid structures of bisphenol S-type tetrathiol enhanced the heat resistance and mechanical properties of TMBPS/epoxy resin cured products,outperforming those of PETMP/epoxy resin cured products.Notably,the glass transition temperature of TMBPS/epoxy resin cured products was 74.2℃which was 11.8°C higher than that of PETMP cured products.Moreover,the ester-free structure in TMBPS contributed to its enhanced resistance to chemicals and hygrothermal conditions.After undergoing 1000 h of hightemperature and high-humidity aging,the tensile strength and adhesion strength of TMBPS-cured products were 73.33 MPa and 3.39 MPa,respectively exceeding 100%and 40%of their initial values,while PETMP-cured products exhibited a complete loss of both tensile strength and adhesion strength.This study provides a strategy for obtaining thermosetting polymers that can be cured at low temperatures and exhibit excellent comprehensive properties.展开更多
The global energy landscape is undergoing a profound transformation,with wind energy,especially wind power,gaining increasing prominence due to its clean,renewable nature.However,as the installed capacity of wind powe...The global energy landscape is undergoing a profound transformation,with wind energy,especially wind power,gaining increasing prominence due to its clean,renewable nature.However,as the installed capacity of wind power continues to expand,the disposal of waste wind turbine blades(WWTB)has emerged as a significant challenge.These blades are predominantly composed of epoxy resin(EP)polymers,carbon fibers(CFs),and glass fibers(GFs).Improper disposal not only exacerbates environmental concerns but also leads to the loss of valuable resources,particularly carbon-based materials.Pyrolysis technology,a versatile and environmentally sustainable method for resource recovery,has garnered considerable attention in the context of WWTB disposal.This work presents a comprehensive review of the pyrolytic recycling of WWTB,focusing on the principles and classifications of pyrolysis technology,key factors influencing the pyrolysis process,as well as the pyrolysis methods,equipment,products,and their applications.Through an in-depth analysis of the current research on the pyrolytic recycling of WWTB,this review identifies critical unresolved issues in the field and provides a forward-looking perspective on emerging research trends.展开更多
This paper studies the effects of hygrothermal environment at different temperatures and ultraviolet(UV)radiation on the bending properties of epoxy polymer mortar(EPM).The microstructure changes of EPM during aging w...This paper studies the effects of hygrothermal environment at different temperatures and ultraviolet(UV)radiation on the bending properties of epoxy polymer mortar(EPM).The microstructure changes of EPM during aging were studied by scanning electron microscopy,and the bending properties of EPM were predicted by the Arrhenius law.The results showed that the bending properties of EPM were greatly affected by the temperature in the hygrothermal aging,but not evidently affected by ultraviolet radiation in UV aging.The prediction of Arrhenius model shows that the EPM will steadily retain 92.8%,89.1%and 79.4%of the original flexural strength after long-term hygrothermal aging at 40∘C,60∘C and 80∘C,respectively.展开更多
A compact, low-cost and high-output-power silicon-wafer solar strip-cells-array module （SCAM） wus experimentally demonstrated. The proposed SCAM consisted mainly of a silicon-wafer strip-cell sparse array and low-co...A compact, low-cost and high-output-power silicon-wafer solar strip-cells-array module （SCAM） wus experimentally demonstrated. The proposed SCAM consisted mainly of a silicon-wafer strip-cell sparse array and low-concentration- ratio array concentrator based on an epoxy resin polymer （ERP） cylindrical piano-convex lens. A polymer replication process based on a polydimethylsiloxane mold was used to fabricate the ERP lens array concentrator. The results show that 46.94% of the silicon-wafer cell was saved in the designed SCAM. Moreover, the output power of the SCAM with a low concentration ratio of 8 suns was improved by 8.6%, compared with a whole piece of a conventional silicon-wafer solar cell with the same area as the module. The proposed method encapsulating solar cells provides a means to reduce the usage of silicon cells in modules as well as improving the output power of modules.展开更多
Epoxy polymer concrete(EPC) has found various applications in civil engineering. To enhance the flexural performance of EPC,two kinds of short natural fibers with high specific strength(sisal fibers and ramie fibers) ...Epoxy polymer concrete(EPC) has found various applications in civil engineering. To enhance the flexural performance of EPC,two kinds of short natural fibers with high specific strength(sisal fibers and ramie fibers) have been incorporated into EPC. The results of mechanical tests show that a small loading of natural fibers(0.36 vol%) can significantly increase the flexural strength of EPC by 25.3%(ramie fibers) or 10.4%(sisal fibers). This enhancement is achieved without any sacrifice of compressive strength of EPC. The reinforcing effects of short natural fibers on the flexural properties and compressive properties of EPC decrease with further increase in fiber content, due to the insufficient wetting of fibers by epoxy resin which results in poor interfacial bonding. The reinforcing mechanisms of short natural fibers are explored according to the observation of fracture surfaces and micromechanical modelling. It is found that the parallel model based on the rule of mixture can be a good approximation to describe the improvement in flexural strength of the short natural fiber reinforced EPC at low fiber volume fractions.展开更多
The epoxy shape memory polymer(SMP)with adjustable phase transition temperature is a kind of high-performance shape mem-ory polymer,which can change its phase transition temperature and improve its mechanical properti...The epoxy shape memory polymer(SMP)with adjustable phase transition temperature is a kind of high-performance shape mem-ory polymer,which can change its phase transition temperature and improve its mechanical properties through the process of photo curing.An epoxy SMP constitutive model combining phase transition and viscoelasticity is established by discretizing the epoxy SMP into several glass phase units and rubbery phase units in this paper.The model includes the viscoelastic constitutive equa-tions of glass phase units and rubber phase units,the parameter expression during shape memory process,and material parameter equation during photocuring process.And the stress relaxation behavior of epoxy SMP at different temperatures and the change of material parameters during the photo-curing process are simu-lated numerically,and the simulation results perform consistency with the experimental data.The model can not only relate shape memory effect and phase transformation in physics but also better characterize the viscoelastic properties of SMP and predict the shape memory response of SMP.展开更多
文摘INTRODUCTION Epoxy resins are reactive polymers which when cured with a variety of chemicals lead to a host of useful thermosets. Since the epoxide is a strained ring, it readily undergoes addition and homopolymerization. The homopolymerization is a process catalysed by acids, bases, Lewis acids, t-amines as well as by inorganic salts.
基金the support of the Science and Technology Commission of Shanghai Municipality(STCSM,No.20dz1203600)the Experimental Center of Materials Science and Engineering in Tongji University。
文摘Epoxy resin is widely used in electronic packaging due to its exceptional performance,particularly the low-temperature curable thiol/epoxy system,which effectively minimizes thermal damage to sensitive electronic components.However,the majority of commercial thiol curing agents contain hydrolysable ester bonds and lack rigid structures,which induces most of thiol/epoxy systems still suffering from unsatisfactory heat resistance and hygrothermal resistance,significantly hindering their application in electronic packaging.In this study,we synthesized a tetrafunctional thiol compound,bis[3-(3-sulfanylpropyl)-4-(3-sulfanylpropoxy)phenyl]sulfone(TMBPS)with rigid and ester-free structures to replace traditional commercial thiol curing agents,pentaerythritol tetra(3-mercaptopropionate)(PETMP).Compared to the PETMP/epoxy system,the TMBPS/epoxy system exhibited superior comprehensive properties.The rigid structures of bisphenol S-type tetrathiol enhanced the heat resistance and mechanical properties of TMBPS/epoxy resin cured products,outperforming those of PETMP/epoxy resin cured products.Notably,the glass transition temperature of TMBPS/epoxy resin cured products was 74.2℃which was 11.8°C higher than that of PETMP cured products.Moreover,the ester-free structure in TMBPS contributed to its enhanced resistance to chemicals and hygrothermal conditions.After undergoing 1000 h of hightemperature and high-humidity aging,the tensile strength and adhesion strength of TMBPS-cured products were 73.33 MPa and 3.39 MPa,respectively exceeding 100%and 40%of their initial values,while PETMP-cured products exhibited a complete loss of both tensile strength and adhesion strength.This study provides a strategy for obtaining thermosetting polymers that can be cured at low temperatures and exhibit excellent comprehensive properties.
基金Supported by the National Natural Science Foundation of China(22468035,22468036,22368038,22308048)the Natural Science Foundation of Inner Mongolia(2024QN02018,2025MS02030)+2 种基金First-class Discipline Research Special Project of Inner Mongolia(YLXKZX-NGD-045)Inner Mongolia Autonomous Region Postgraduate Research Innovation Project(KC2024047B)Research Foundation for Introducing High-level Talents in Inner Mongolia Autonomous Region。
文摘The global energy landscape is undergoing a profound transformation,with wind energy,especially wind power,gaining increasing prominence due to its clean,renewable nature.However,as the installed capacity of wind power continues to expand,the disposal of waste wind turbine blades(WWTB)has emerged as a significant challenge.These blades are predominantly composed of epoxy resin(EP)polymers,carbon fibers(CFs),and glass fibers(GFs).Improper disposal not only exacerbates environmental concerns but also leads to the loss of valuable resources,particularly carbon-based materials.Pyrolysis technology,a versatile and environmentally sustainable method for resource recovery,has garnered considerable attention in the context of WWTB disposal.This work presents a comprehensive review of the pyrolytic recycling of WWTB,focusing on the principles and classifications of pyrolysis technology,key factors influencing the pyrolysis process,as well as the pyrolysis methods,equipment,products,and their applications.Through an in-depth analysis of the current research on the pyrolytic recycling of WWTB,this review identifies critical unresolved issues in the field and provides a forward-looking perspective on emerging research trends.
基金The study is financially supported by the National Natural Science Foundation of China(Grant Nos.12072116,11772132,12072115,11772131,11772134,11972162 and 11932007).
文摘This paper studies the effects of hygrothermal environment at different temperatures and ultraviolet(UV)radiation on the bending properties of epoxy polymer mortar(EPM).The microstructure changes of EPM during aging were studied by scanning electron microscopy,and the bending properties of EPM were predicted by the Arrhenius law.The results showed that the bending properties of EPM were greatly affected by the temperature in the hygrothermal aging,but not evidently affected by ultraviolet radiation in UV aging.The prediction of Arrhenius model shows that the EPM will steadily retain 92.8%,89.1%and 79.4%of the original flexural strength after long-term hygrothermal aging at 40∘C,60∘C and 80∘C,respectively.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61377021 and 61671329)
文摘A compact, low-cost and high-output-power silicon-wafer solar strip-cells-array module （SCAM） wus experimentally demonstrated. The proposed SCAM consisted mainly of a silicon-wafer strip-cell sparse array and low-concentration- ratio array concentrator based on an epoxy resin polymer （ERP） cylindrical piano-convex lens. A polymer replication process based on a polydimethylsiloxane mold was used to fabricate the ERP lens array concentrator. The results show that 46.94% of the silicon-wafer cell was saved in the designed SCAM. Moreover, the output power of the SCAM with a low concentration ratio of 8 suns was improved by 8.6%, compared with a whole piece of a conventional silicon-wafer solar cell with the same area as the module. The proposed method encapsulating solar cells provides a means to reduce the usage of silicon cells in modules as well as improving the output power of modules.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11772131 & 11772132)the Natural Science Foundation of Guangdong Province, China (Grant Nos. 2015A030311046 & 2015B010131009)+1 种基金the Opening Fund of State Key Laboratory of Nonlinear Mechanics (LNM), CASSouth China University of Technology (Grant No. 2017ZD096)
文摘Epoxy polymer concrete(EPC) has found various applications in civil engineering. To enhance the flexural performance of EPC,two kinds of short natural fibers with high specific strength(sisal fibers and ramie fibers) have been incorporated into EPC. The results of mechanical tests show that a small loading of natural fibers(0.36 vol%) can significantly increase the flexural strength of EPC by 25.3%(ramie fibers) or 10.4%(sisal fibers). This enhancement is achieved without any sacrifice of compressive strength of EPC. The reinforcing effects of short natural fibers on the flexural properties and compressive properties of EPC decrease with further increase in fiber content, due to the insufficient wetting of fibers by epoxy resin which results in poor interfacial bonding. The reinforcing mechanisms of short natural fibers are explored according to the observation of fracture surfaces and micromechanical modelling. It is found that the parallel model based on the rule of mixture can be a good approximation to describe the improvement in flexural strength of the short natural fiber reinforced EPC at low fiber volume fractions.
基金This work was supported by the National Key Research and Development Program of China[2017YFC0307604].
文摘The epoxy shape memory polymer(SMP)with adjustable phase transition temperature is a kind of high-performance shape mem-ory polymer,which can change its phase transition temperature and improve its mechanical properties through the process of photo curing.An epoxy SMP constitutive model combining phase transition and viscoelasticity is established by discretizing the epoxy SMP into several glass phase units and rubbery phase units in this paper.The model includes the viscoelastic constitutive equa-tions of glass phase units and rubber phase units,the parameter expression during shape memory process,and material parameter equation during photocuring process.And the stress relaxation behavior of epoxy SMP at different temperatures and the change of material parameters during the photo-curing process are simu-lated numerically,and the simulation results perform consistency with the experimental data.The model can not only relate shape memory effect and phase transformation in physics but also better characterize the viscoelastic properties of SMP and predict the shape memory response of SMP.
