Low-dimensional physics provides profound insights into strongly correlated interactions,leading to enhancedquantum effects and the emergence of exotic quantum states.The Ln_(3)ScBi_(5)family stands out as a chemicall...Low-dimensional physics provides profound insights into strongly correlated interactions,leading to enhancedquantum effects and the emergence of exotic quantum states.The Ln_(3)ScBi_(5)family stands out as a chemicallyversatile kagome platform with mixed low-dimensional structural framework and tunable physical properties.Ourresearch initiates with a comprehensive evaluation of the currently known Ln_(3)ScBi_(5)(Ln=La-Nd,Sm)materials,providing a robust methodology for assessing their stability frontiers within this system.Focusing on Pr_(3)ScBi_(5),we investigate the influence of the zigzag chains of quasi-one-dimensional(Q1D)motifs and the distorted kagomelayers of quasi-two-dimensional(Q2D)networks in the mixed-dimensional structure on the intricate magneticground states and unique spin fluctuations.Our study reveals that the noncollinear antiferromagnetic(AFM)moments of Pr^(3+)ions are confined within the Q2D kagome planes,displaying minimal in-plane anisotropy.Incontrast,a strong AFM coupling is observed within the Q1D zigzag chains,significantly constraining spin motion.Notably,magnetic frustration is partially a consequence of coupling to conduction electrons via Ruderman-Kittel-Kasuya-Yosida interaction,highlighting a promising framework for future investigations into mixed-dimensional frustration in Ln_(3)ScBi_(5) systems.展开更多
基金supported by the National Key R&D Program of China(Grant Nos.2024YFA1408400 and 2021YFA1400401)the National Natural Science Foundation of China(Grant Nos.U22A6005 and 52271238)+2 种基金the China Postdoctoral Science Foundation(Grant No.2025M770186)the Center for Materials Genome,and the Synergetic Extreme Condition User Facility(SECUF)supported by the AI-driven experiments,simulations and model training on the robotic AI-Scientist platform from Chinese Academy of Sciences and the Research Funds for the Central Universities(Grant No.N25ZLE007).
文摘Low-dimensional physics provides profound insights into strongly correlated interactions,leading to enhancedquantum effects and the emergence of exotic quantum states.The Ln_(3)ScBi_(5)family stands out as a chemicallyversatile kagome platform with mixed low-dimensional structural framework and tunable physical properties.Ourresearch initiates with a comprehensive evaluation of the currently known Ln_(3)ScBi_(5)(Ln=La-Nd,Sm)materials,providing a robust methodology for assessing their stability frontiers within this system.Focusing on Pr_(3)ScBi_(5),we investigate the influence of the zigzag chains of quasi-one-dimensional(Q1D)motifs and the distorted kagomelayers of quasi-two-dimensional(Q2D)networks in the mixed-dimensional structure on the intricate magneticground states and unique spin fluctuations.Our study reveals that the noncollinear antiferromagnetic(AFM)moments of Pr^(3+)ions are confined within the Q2D kagome planes,displaying minimal in-plane anisotropy.Incontrast,a strong AFM coupling is observed within the Q1D zigzag chains,significantly constraining spin motion.Notably,magnetic frustration is partially a consequence of coupling to conduction electrons via Ruderman-Kittel-Kasuya-Yosida interaction,highlighting a promising framework for future investigations into mixed-dimensional frustration in Ln_(3)ScBi_(5) systems.
