The seismotectonic method is used to study the seismogenic structures and the maximum potential earthquake around an engineering site in order to determine the seismic risk at the site. Analysis of seismic risk from s...The seismotectonic method is used to study the seismogenic structures and the maximum potential earthquake around an engineering site in order to determine the seismic risk at the site. Analysis of seismic risk from site effect seismic intensity data, in combination with regional seismo_geological data, using the seismotectonic method can provide a more reliable result. In this paper, taking the area of six reservoir dam sites in western Anhui as an example, we analyze the seismic risk from site effect seismic intensity data in combination with the seismotectonic conditions and find that P (I≥i)=10% over 50 years. The result shows that the seismogenic structure and the maximum potential earthquake have a controlling effect on seismic risk from future earthquakes in the area around the site.展开更多
Long-line engineering sites usually have to pass through active tectonics, so the research of active tectonics is of great importance to seismic safety evaluation of this sort of site. In the paper, basing on the summ...Long-line engineering sites usually have to pass through active tectonics, so the research of active tectonics is of great importance to seismic safety evaluation of this sort of site. In the paper, basing on the summarization and analysis of the requirements for seismic safety evaluation of long-line engineering site and the status quo of active tectonics research, we propose the focal points of active tectonics research for seismic safety evaluation of long-line engineering sites, including the research contents, technical targets and routes, and the submission of the achievements, etc. Finally, we make a preliminary analysis and discussion about the problems existing in the present-day active tectonics research for seismic safety evaluation of long-line engineering sites.展开更多
In the design of building structures,joint efforts must be decided to resolve the depth of competent layers across the intended site to safeguard the durability of civil engineering structures and to avert the disastr...In the design of building structures,joint efforts must be decided to resolve the depth of competent layers across the intended site to safeguard the durability of civil engineering structures and to avert the disastrous consequences of structural failure and collapse.In this study,an integrated methodology that employed DC resistivity tomography involving 2-D and 3-D techniques and geotechnical-soil analysis was used to evaluate subsoil conditions for engineering site investigation at Okerenkoko primary school,in the Warri-southwest area of Delta State,to adduce the phenomena responsible for the visible cracks/structural failure observed in the buildings.The results obtained brought to light the geological structure beneath the subsurface,which consists of four geoelectric layers identified as topsoil,dry/lithified upper sandy layer,wet sand(water-saturated)and peat/clay/sandy clayey soil(highly water-saturated).The deeply-seated peat/clay materials(ρ≤20Ωm)were delineated in the study area to the depths of 17.1 m and 19.8 m from 2-D and 3-D tomography respectively.3-D images presented as horizontal depth slices revealed the dominance of very low resistivity materials i.e.peat/clay/sandy clay within the fourth,fifth and sixth layers at depths ranging from 8.68-12.5 m,12.5-16.9 m and 16.9-21.9 m respectively.The dominance of mechanically unstable peat/clay/sandy clay layers beneath the subsurface,which are highly mobile in response to volumetric changes,is responsible for the noticeable cracks/failure detected on structures within the study site.These observations were validated by a geotechnical test of soil samples in the study area.Atterberg’s limits of the samples revealed plasticity indices of zero.Thus,the soil samples within the depth analyzed were representatives of sandy soil that does not possess any plasticity.The methods justifiably provided relevant information on the subsurface geology beneath the study site and should be appropriated as major tools for engineering site assessment/geotechnical projects.展开更多
Deciphering the atomic‐level properties and mechanism of electrocatalysts for water splitting is vital for the development of highly active non‐noble‐metal catalysts.Herein,we conduct a detailed study of layered cr...Deciphering the atomic‐level properties and mechanism of electrocatalysts for water splitting is vital for the development of highly active non‐noble‐metal catalysts.Herein,we conduct a detailed study of layered crystalline CoMoO_(4)using density functional theory(DFT)calculations.The layered arrangement of CoMoO_(4)along the[110]lattice direction is observed,and the two thermodynamically stable and most exposed(110)A and(001)A crystal facets are selected among all low‐index facets by surface energy calculations and Wulff construction to study the electrocatalytic activity for alkaline water splitting and corresponding mechanism.CoMoO_(4)with an exposed(110)A facet(i.e.,CMO(110)A)exhibited a high hydrogen evolution reaction(HER)activity,with aΔGH*of 0.22 eV,which is similar to that of Pt because the adsorbed H is allowed to interact with two oxygen atoms(O_(3)and Oadj).The(110)A facet also possesses better H_(2)O adsorption and dissociation abilities than the(001)A facet,benefiting the HER performance in alkaline solutions.Moreover,the overpotential of the(110)A facet for the electrocatalytic oxygen evolution reaction(OER)is only 0.74 V according to the Gibbs free‐energy calculation,this overpotential is lower than that of the(001)A facet(0.84 V)owing to the stronger binding and more stable adsorption states between Co and O for the intermediate*O.By allowing us to identify highly active facets and sites,this approach guided the selective synthesis of CoMoO_(4)and its isostructural substances,such as Mn(Ni,Fe)MoO4 nanocatalysts,for alkaline water splitting.展开更多
The development of single-activator-doped,single-component full-spectrum white light emission materials is essential for human-centric lighting.Here,full-spectrum white light emission(350-800 nm)was achieved in a sing...The development of single-activator-doped,single-component full-spectrum white light emission materials is essential for human-centric lighting.Here,full-spectrum white light emission(350-800 nm)was achieved in a single-Bi^(3+)-doped single-component phosphor Ca_(5)Ga_(6)O_(14):xBi^(3+)via crystallographic site engineering.The ultra-broadband emission comprises three distinct emission bands centred at 374,515 and 620 nm,arising from Bi^(3+)activators occupying Ca_(3),Ca_(2),and Ca1 sites in Ca_(5)Ga_(6)O_(14):xBi^(3+),respectively.These spectral components produce high-quality white light with a superior colour rendering index of 91.0 and a correlated colour temperature of 4820 K for the prototype pc-WLED devices fabricated by coating the optimised phosphors onto a UV LED chip.Notably,the 347 and 515 nm emissions exhibit typical thermal quenching(TQ)upon heating,whereas the 620 nm emission shows an unusual excitation wavelength-dependent transition from anti-TQ to normal TQ due to preferential energy compensation from the defect energy levels.This unique thermal response endows Ca_(5)Ga_(6)O_(14):xBi^(3+)with an outstanding maximum relative sensitivity of 5.12%K^(-1) in fluorescence intensity ratio(FIR)-based thermometry,outperforming hitherto reported single Bi^(3+)-doped ratiometric thermometers.The rational design of Ca_(5)Ga_(6)O_(14):xBi^(3+)marks a significant advance toward single-component,multi-functional phosphors capable of simultaneous full-spectrum white light generation and temperature sensing,highlighting crystallographic site engineering as a powerful strategy for smart luminescent materials in advanced lighting and sensing applications.展开更多
Dielectric ceramics have attracted extensive attention for high-power energy storage applications due to their fast charge-discharge capabilities and high power density.Bi_(0.5)Na_(0.5)TiO_(3)(BNT)-based lead-free cer...Dielectric ceramics have attracted extensive attention for high-power energy storage applications due to their fast charge-discharge capabilities and high power density.Bi_(0.5)Na_(0.5)TiO_(3)(BNT)-based lead-free ceramics are notable for their high saturation polarization and moderate breakdown electric field(Eb),but they still suffer from a low breakdown field,large hysteresis losses and insufficient efficiency.Here,we propose a strategy of dual-site ion-pair engineering by introducing Ba(Sr_(0.5)W_(0.5))O_(3)(BSW)into the BNT matrix.In this design,Ba^(2+)-Ba^(2+)pairs at the A-site and Sr^(2+)-W^(6+)pairs at the B-site induce local lattice distortion and generate strong random fields,which effectively promote the formation of multiple relaxor phases with polymorphic nanodomains.The features of electrical properties and phase-field simulations indicate that BSW doping facilitates greater compositional disorder and disruption of long-range FE order,integrating the short-range ordered antiferroelectric(AFE)nanodomains with highly disordered relaxor ferroelectric(RFE)regions to reduce the electric field-induced AFE-FE phase transition barrier.Additionally,the incorporation of BSW refines the grain size and increases microstructural homogeneity,enhancing the breakdown strength and delaying the polarization saturation.Accordingly,the 0.90BNT-0.10BSW ceramic exhibited an outstanding energy storage performance with a high W_(rec) of 6.57 J cm^(-3) and anηof 72%under an electric field of 450 kV cm^(-1).In addition,the ceramic synchronously possesses an excellent transient discharge rate t0.9 of 90 ns and a high power density PD of 121.9 MW cm^(-3).This work suggests that dual-site ion-pair engineering is an effective approach for regulating structure-property relationships in BNT-based ceramics and provides a viable pathway for the development of high-performance lead-free dielectric materials for advanced energy storage applications.展开更多
Processing schedules for grain boundary engineering involving different types of cold deformation（tension, compression, and rolling） and annealing were designed and carried out for 18Mn18Cr0.6N high nitrogen austeni...Processing schedules for grain boundary engineering involving different types of cold deformation（tension, compression, and rolling） and annealing were designed and carried out for 18Mn18Cr0.6N high nitrogen austenitic stainless steel. The grain boundary characteristic distribution was obtained and characterized by electron backscatter diffraction（EBSD） analysis. The corrosion resistance of the specimens with different grain boundary characteristic distribution was examined by using potentiodynamic polarization test. The corrosion behavior of different types of boundaries after sensitization was also studied.The fraction of low-∑ boundaries decreased with increasing strain, and it was insensitive to the type of cold deformation when the engineering strain was lower than 20%. At the strain of 30%, the largest and smallest fractions of low-∑ boundaries were achieved in cold-tensioned and rolled specimens, respectively. The fraction of low-∑ boundaries increased exponentially with the increase of grain size. The proportion of low-∑ angle grain boundaries increased with decreasing grain size. Increasing the fraction of low-∑ boundaries could improve the pitting corrosion resistance for the steels with the same grain size.After sensitization, the relative corrosion resistances of low-∑ angle grain boundaries, ∑3 boundaries, and ∑9 boundaries were 100%, 95%, and 25%, respectively, while ∑27 boundaries, other low-∑ boundaries and random high-angle grain boundaries had no resistance to corrosion.展开更多
Semiconductor based photocatalysis that harvests renewable solar energy to produce green hydrogen has attracted widespread attention[1],known for its environmental friendliness,low opera-tional costs,and scalability.E...Semiconductor based photocatalysis that harvests renewable solar energy to produce green hydrogen has attracted widespread attention[1],known for its environmental friendliness,low opera-tional costs,and scalability.Extensive experimental and theoretical explorations have significantly advanced the development of pho-tocatalysts for overall water splitting at laboratory scale[2],by band structure engineering[3],heterostructure construction[4],active site design[5],and even micro-/macro-texture modulation[6,7].Preliminary demonstration and verification of its large-scale application have been accomplished using SrTiO_(3) as photocatalyst[8].However,this technology yet faces the great challenges in practical application,with solar-to-hydrogen conversion efficiency still lower than 2%,suffering from the thermodynamically and kinetically constrained water splitting reactions[9].Although some well documented strategies(e.g.,light concentration,exter-nal heat,and concentrated electrolytes)could overcome these pho-tocatalytic limitations to some extent[10],the introduced harsh reaction conditions would significantly compromise the durability of photocatalysts[11].For example,to realize the practical applica-tion of photocatalytic recycling and upgrading of plastic wastes into solar hydrogen,strong alkaline solutions containing mono-meric constituents should serve as feedstocks for photo-reforming[12],with photocatalysts exposed to the harsh alkaline condition and then suffering from degradation and inactivation.展开更多
文摘The seismotectonic method is used to study the seismogenic structures and the maximum potential earthquake around an engineering site in order to determine the seismic risk at the site. Analysis of seismic risk from site effect seismic intensity data, in combination with regional seismo_geological data, using the seismotectonic method can provide a more reliable result. In this paper, taking the area of six reservoir dam sites in western Anhui as an example, we analyze the seismic risk from site effect seismic intensity data in combination with the seismotectonic conditions and find that P (I≥i)=10% over 50 years. The result shows that the seismogenic structure and the maximum potential earthquake have a controlling effect on seismic risk from future earthquakes in the area around the site.
文摘Long-line engineering sites usually have to pass through active tectonics, so the research of active tectonics is of great importance to seismic safety evaluation of this sort of site. In the paper, basing on the summarization and analysis of the requirements for seismic safety evaluation of long-line engineering site and the status quo of active tectonics research, we propose the focal points of active tectonics research for seismic safety evaluation of long-line engineering sites, including the research contents, technical targets and routes, and the submission of the achievements, etc. Finally, we make a preliminary analysis and discussion about the problems existing in the present-day active tectonics research for seismic safety evaluation of long-line engineering sites.
文摘In the design of building structures,joint efforts must be decided to resolve the depth of competent layers across the intended site to safeguard the durability of civil engineering structures and to avert the disastrous consequences of structural failure and collapse.In this study,an integrated methodology that employed DC resistivity tomography involving 2-D and 3-D techniques and geotechnical-soil analysis was used to evaluate subsoil conditions for engineering site investigation at Okerenkoko primary school,in the Warri-southwest area of Delta State,to adduce the phenomena responsible for the visible cracks/structural failure observed in the buildings.The results obtained brought to light the geological structure beneath the subsurface,which consists of four geoelectric layers identified as topsoil,dry/lithified upper sandy layer,wet sand(water-saturated)and peat/clay/sandy clayey soil(highly water-saturated).The deeply-seated peat/clay materials(ρ≤20Ωm)were delineated in the study area to the depths of 17.1 m and 19.8 m from 2-D and 3-D tomography respectively.3-D images presented as horizontal depth slices revealed the dominance of very low resistivity materials i.e.peat/clay/sandy clay within the fourth,fifth and sixth layers at depths ranging from 8.68-12.5 m,12.5-16.9 m and 16.9-21.9 m respectively.The dominance of mechanically unstable peat/clay/sandy clay layers beneath the subsurface,which are highly mobile in response to volumetric changes,is responsible for the noticeable cracks/failure detected on structures within the study site.These observations were validated by a geotechnical test of soil samples in the study area.Atterberg’s limits of the samples revealed plasticity indices of zero.Thus,the soil samples within the depth analyzed were representatives of sandy soil that does not possess any plasticity.The methods justifiably provided relevant information on the subsurface geology beneath the study site and should be appropriated as major tools for engineering site assessment/geotechnical projects.
文摘Deciphering the atomic‐level properties and mechanism of electrocatalysts for water splitting is vital for the development of highly active non‐noble‐metal catalysts.Herein,we conduct a detailed study of layered crystalline CoMoO_(4)using density functional theory(DFT)calculations.The layered arrangement of CoMoO_(4)along the[110]lattice direction is observed,and the two thermodynamically stable and most exposed(110)A and(001)A crystal facets are selected among all low‐index facets by surface energy calculations and Wulff construction to study the electrocatalytic activity for alkaline water splitting and corresponding mechanism.CoMoO_(4)with an exposed(110)A facet(i.e.,CMO(110)A)exhibited a high hydrogen evolution reaction(HER)activity,with aΔGH*of 0.22 eV,which is similar to that of Pt because the adsorbed H is allowed to interact with two oxygen atoms(O_(3)and Oadj).The(110)A facet also possesses better H_(2)O adsorption and dissociation abilities than the(001)A facet,benefiting the HER performance in alkaline solutions.Moreover,the overpotential of the(110)A facet for the electrocatalytic oxygen evolution reaction(OER)is only 0.74 V according to the Gibbs free‐energy calculation,this overpotential is lower than that of the(001)A facet(0.84 V)owing to the stronger binding and more stable adsorption states between Co and O for the intermediate*O.By allowing us to identify highly active facets and sites,this approach guided the selective synthesis of CoMoO_(4)and its isostructural substances,such as Mn(Ni,Fe)MoO4 nanocatalysts,for alkaline water splitting.
基金supported by the National Natural Science Foundation of China(no.22271030,22171031,and 22171032)the Chongqing Science and Technology Commission(2024NSCQ-MSX0913).
文摘The development of single-activator-doped,single-component full-spectrum white light emission materials is essential for human-centric lighting.Here,full-spectrum white light emission(350-800 nm)was achieved in a single-Bi^(3+)-doped single-component phosphor Ca_(5)Ga_(6)O_(14):xBi^(3+)via crystallographic site engineering.The ultra-broadband emission comprises three distinct emission bands centred at 374,515 and 620 nm,arising from Bi^(3+)activators occupying Ca_(3),Ca_(2),and Ca1 sites in Ca_(5)Ga_(6)O_(14):xBi^(3+),respectively.These spectral components produce high-quality white light with a superior colour rendering index of 91.0 and a correlated colour temperature of 4820 K for the prototype pc-WLED devices fabricated by coating the optimised phosphors onto a UV LED chip.Notably,the 347 and 515 nm emissions exhibit typical thermal quenching(TQ)upon heating,whereas the 620 nm emission shows an unusual excitation wavelength-dependent transition from anti-TQ to normal TQ due to preferential energy compensation from the defect energy levels.This unique thermal response endows Ca_(5)Ga_(6)O_(14):xBi^(3+)with an outstanding maximum relative sensitivity of 5.12%K^(-1) in fluorescence intensity ratio(FIR)-based thermometry,outperforming hitherto reported single Bi^(3+)-doped ratiometric thermometers.The rational design of Ca_(5)Ga_(6)O_(14):xBi^(3+)marks a significant advance toward single-component,multi-functional phosphors capable of simultaneous full-spectrum white light generation and temperature sensing,highlighting crystallographic site engineering as a powerful strategy for smart luminescent materials in advanced lighting and sensing applications.
基金supported by the National Natural Science Foundation of China(Grant No.52202142)the Science and Technology Serving Enterprise Project in Universities and Colleges of Xi’an Science and Technology Bureau(Grant No.24GXFW0002)the Natural Science Basic Research Program of Shaanxi Province(Grants No.2025JC-YBMS-133 and 2023-JC-QN-0066).
文摘Dielectric ceramics have attracted extensive attention for high-power energy storage applications due to their fast charge-discharge capabilities and high power density.Bi_(0.5)Na_(0.5)TiO_(3)(BNT)-based lead-free ceramics are notable for their high saturation polarization and moderate breakdown electric field(Eb),but they still suffer from a low breakdown field,large hysteresis losses and insufficient efficiency.Here,we propose a strategy of dual-site ion-pair engineering by introducing Ba(Sr_(0.5)W_(0.5))O_(3)(BSW)into the BNT matrix.In this design,Ba^(2+)-Ba^(2+)pairs at the A-site and Sr^(2+)-W^(6+)pairs at the B-site induce local lattice distortion and generate strong random fields,which effectively promote the formation of multiple relaxor phases with polymorphic nanodomains.The features of electrical properties and phase-field simulations indicate that BSW doping facilitates greater compositional disorder and disruption of long-range FE order,integrating the short-range ordered antiferroelectric(AFE)nanodomains with highly disordered relaxor ferroelectric(RFE)regions to reduce the electric field-induced AFE-FE phase transition barrier.Additionally,the incorporation of BSW refines the grain size and increases microstructural homogeneity,enhancing the breakdown strength and delaying the polarization saturation.Accordingly,the 0.90BNT-0.10BSW ceramic exhibited an outstanding energy storage performance with a high W_(rec) of 6.57 J cm^(-3) and anηof 72%under an electric field of 450 kV cm^(-1).In addition,the ceramic synchronously possesses an excellent transient discharge rate t0.9 of 90 ns and a high power density PD of 121.9 MW cm^(-3).This work suggests that dual-site ion-pair engineering is an effective approach for regulating structure-property relationships in BNT-based ceramics and provides a viable pathway for the development of high-performance lead-free dielectric materials for advanced energy storage applications.
基金the financial supports from the National Natural Science Foundation of China (No.51505416)the Natural Science Foundation-Steel and Iron Foundation of Hebei Province (No.E2017203041)+1 种基金the Post-Doctoral Research Project of Hebei Province (No.B2016003029)the Foundation for Young Scholars in Yanshan University(No.14LGA004)
文摘Processing schedules for grain boundary engineering involving different types of cold deformation（tension, compression, and rolling） and annealing were designed and carried out for 18Mn18Cr0.6N high nitrogen austenitic stainless steel. The grain boundary characteristic distribution was obtained and characterized by electron backscatter diffraction（EBSD） analysis. The corrosion resistance of the specimens with different grain boundary characteristic distribution was examined by using potentiodynamic polarization test. The corrosion behavior of different types of boundaries after sensitization was also studied.The fraction of low-∑ boundaries decreased with increasing strain, and it was insensitive to the type of cold deformation when the engineering strain was lower than 20%. At the strain of 30%, the largest and smallest fractions of low-∑ boundaries were achieved in cold-tensioned and rolled specimens, respectively. The fraction of low-∑ boundaries increased exponentially with the increase of grain size. The proportion of low-∑ angle grain boundaries increased with decreasing grain size. Increasing the fraction of low-∑ boundaries could improve the pitting corrosion resistance for the steels with the same grain size.After sensitization, the relative corrosion resistances of low-∑ angle grain boundaries, ∑3 boundaries, and ∑9 boundaries were 100%, 95%, and 25%, respectively, while ∑27 boundaries, other low-∑ boundaries and random high-angle grain boundaries had no resistance to corrosion.
基金supported by the National Natural Science Foun-dation of China(22432003,52225606,and 523B2070).
文摘Semiconductor based photocatalysis that harvests renewable solar energy to produce green hydrogen has attracted widespread attention[1],known for its environmental friendliness,low opera-tional costs,and scalability.Extensive experimental and theoretical explorations have significantly advanced the development of pho-tocatalysts for overall water splitting at laboratory scale[2],by band structure engineering[3],heterostructure construction[4],active site design[5],and even micro-/macro-texture modulation[6,7].Preliminary demonstration and verification of its large-scale application have been accomplished using SrTiO_(3) as photocatalyst[8].However,this technology yet faces the great challenges in practical application,with solar-to-hydrogen conversion efficiency still lower than 2%,suffering from the thermodynamically and kinetically constrained water splitting reactions[9].Although some well documented strategies(e.g.,light concentration,exter-nal heat,and concentrated electrolytes)could overcome these pho-tocatalytic limitations to some extent[10],the introduced harsh reaction conditions would significantly compromise the durability of photocatalysts[11].For example,to realize the practical applica-tion of photocatalytic recycling and upgrading of plastic wastes into solar hydrogen,strong alkaline solutions containing mono-meric constituents should serve as feedstocks for photo-reforming[12],with photocatalysts exposed to the harsh alkaline condition and then suffering from degradation and inactivation.
