The concentrically layered thermal cloaks with isotropic materials could realize the equivalent thermal cloaking effect with Pendry＇s cloak, while the effectiveness is scarcely investigated quantitatively. Here we ex...The concentrically layered thermal cloaks with isotropic materials could realize the equivalent thermal cloaking effect with Pendry＇s cloak, while the effectiveness is scarcely investigated quantitatively. Here we examine the cloaking effectiveness quantitatively by evaluating the standard deviation of the temperature difference between the simulated plane with the layered thermal cloak and Pendry＇s thermal cloak. The design rules for the isotropic materials in terms of thermal conductivity and layer thickness are presented. The present method could quan- titatively evaluate the cloaking effectiveness, and could open avenues for analyzing the cloaking effect, detecting the （anti-） cloaks, etc.展开更多
Digital twins(DTs)are rapidly emerging as transformative tools in materials science and engineering,enabling real-time data integration,predictive modeling,and virtual testing.This study presents a systematic bibliome...Digital twins(DTs)are rapidly emerging as transformative tools in materials science and engineering,enabling real-time data integration,predictive modeling,and virtual testing.This study presents a systematic bibliometric review of 1106 peer-reviewed articles published in the last decade in Scopus and Web of Science.Using a five-stage methodology,the review examines publication trends,thematic areas,citation metrics,and keyword patterns.The results reveal exponential growth in scientific output,with Materials Theory,Computation,and Data Science as the most represented area.A thematic analysis of the most cited documents identifies four major research streams:foundational frameworks,DTs in additive manufacturing,sector-specific applications,and intelligent production systems.Keyword co-occurrence and strategic mapping show a strong foundation in modeling,simulation,and optimization,with growing links to machine learning and sustainability.The review highlights current challenges and proposes future research directions for advancing DTs in materials science.展开更多
Cancer remains a significant global health concern,necessitating the development of innovative therapeutic strategies.This research paper aims to investigate the role of pyroptosis induction in cancer treatment.Pyropt...Cancer remains a significant global health concern,necessitating the development of innovative therapeutic strategies.This research paper aims to investigate the role of pyroptosis induction in cancer treatment.Pyroptosis,a form of programmed cell death characterized by the release of pro-inflammatory cytokines and the formation of plasma membrane pores,has gained significant attention as a potential target for cancer therapy.The objective of this study is to provide a comprehensive overview of the current understanding of pyroptosis and its role in cancer treatment.The paper discusses the concept of pyroptosis and its relationship with other forms of cell death,such as apoptosis and necroptosis.It explores the role of pyroptosis in immune activation and its potential for combination therapy.The study also reviews the use of natural,biological,chemical,and multifunctional composite materials for pyroptosis induction in cancer cells.The molecular mechanisms underlying pyroptosis induction by these materials are discussed,along with their advantages and challenges in cancer treatment.The findings of this study highlight the potential of pyroptosis induction as a novel therapeutic strategy in cancer treatment and provide insights into the different materials and mechanisms involved in pyroptosis induction.展开更多
Nature continues to serve as inspiration for the design and fabrication of high-performance materials [1,2].The structural and compositional features responsible for e.g. the high hardness and fracture toughness of na...Nature continues to serve as inspiration for the design and fabrication of high-performance materials [1,2].The structural and compositional features responsible for e.g. the high hardness and fracture toughness of nacre,tooth enamel and other biominerals have served as a bench- mark for the structural design of hard and strong materials [3].Wood has been utilized by humankind for millennia for protection,construction,energy and for cultural and religious objects.The hierarchical and cellular structure of wood and the structure-property rela- tions of the constituents and their assemblies:e.g. cellulose,hemicellulose and lignin,has been the focus of intense research efforts and resulted in advances in the fabrication of wood-based functional and structural high- performance materials [4,5].展开更多
To share and utilize data effectively for collaborative work,a common understanding of the knowledge behind the data,including its context and meaning,is a fundamental requirement.This paper focuses on the gaps that h...To share and utilize data effectively for collaborative work,a common understanding of the knowledge behind the data,including its context and meaning,is a fundamental requirement.This paper focuses on the gaps that hinder common understanding between the real world and the data space,acting as barriers between systems,organizations,data spaces,and disciplines.To understand the core reasons and devise strategies for bridging the gap,the author has endeavored to synthesize a case study of material data activities from two perspectives:diachronic and synchronic,which is framed into a two-step process,involving the establishment of intersubjectivity among experts and interobjectivity among materials/substances data.As a result,the author has formulated an action plan for the digitization of engineering materials,encompassing tacit knowledge,know-how,and intellectual property rights to establish a foundation for their use with traceability,interoperability,and reusability.In order to create a conceptual framework that enhances a productive ecosystem facilitated by networked materials and substance databases,this plan is conclusively based on two key steps:fostering interactions among experts rooted in substances and materials and standardizing digitized data related to substances/materials based on their geospatial structural information.展开更多
Chongqing University is located inChongqing City,Sichuan Province.Foundedoriginally in 1929,the university has sincethen greatly expanded in its scope ofeducation and organization.Now it becomesone of China’s key uni...Chongqing University is located inChongqing City,Sichuan Province.Foundedoriginally in 1929,the university has sincethen greatly expanded in its scope ofeducation and organization.Now it becomesone of China’s key universities of scienceand engineering with 18 departments and38 specialities.In addition it has 20 researchinstitutes and about one hundred laboratories.The department of metallurgy and ma-terials engineering of Chongqing University展开更多
Integrated computational materials engineering(ICME)is to integrate multi-scale computational simulations and key experimental methods such as macroscopic,mesoscopic,and microscopic into the whole process of Al alloys...Integrated computational materials engineering(ICME)is to integrate multi-scale computational simulations and key experimental methods such as macroscopic,mesoscopic,and microscopic into the whole process of Al alloys design and development,which enables the design and development of Al alloys to upgrade from traditional empirical to the integration of compositionprocess-structure-mechanical property,thus greatly accelerating its development speed and reducing its development cost.This study combines calculation of phase diagram(CALPHAD),Finite element calculations,first principle calculations,and microstructure characterization methods to predict and regulate the formation and structure of composite precipitates from the design of highmodulus Al alloy compositions and optimize the casting process parameters to inhibit the formation of micropore defects in the casting process,and the final tensile strength of Al alloys reaches420 MPa and Young's modulus reaches more than 88 GPa,which achieves the design goal of the high strength and modulus Al alloys,and establishes a new mode of the design and development of the strength/modulus Al alloys.展开更多
New materials are fundamental to the growth,security,and quality of life of human being sand open doors to technologies in civil,chemical,nuclear,aeronautical,mechanical,biomedical,and electrical engineering.Creative ...New materials are fundamental to the growth,security,and quality of life of human being sand open doors to technologies in civil,chemical,nuclear,aeronautical,mechanical,biomedical,and electrical engineering.Creative companies use multiple materials in the development of their activities,such as solid stone,fiber glass,concrete,and glass reinforced concrete,for example.Based on bibliographic research,the article examines the synergy between materials science&engineering and creative economy.The main argument indicates that this synergy creates solutions and functionalities that add value to existing products and allow the development of new products with competitive advantages.It may also contribute to the preservation of cultural values and promote sustainability.展开更多
This paper analyses the peculiar acting mechanism of artificial neural network (ANN) tech, and explores the great immediate significence for the intelligent sci-tech (IST) to research and develop the nano-tech.
Molecular dynamics (MD) is a computer simulation technique that helps to explore the behavior and properties of molecules and atoms. MD has been used in research and development in many spaces, including materials sci...Molecular dynamics (MD) is a computer simulation technique that helps to explore the behavior and properties of molecules and atoms. MD has been used in research and development in many spaces, including materials science and engineering and nanotechnology. MD has been proven useful in topics like the nano-engineering of construction materials, correcting graphene planar defects, studying self-assembling bio-materials, and the densification, consolidation, and sintering of nanocrystalline materials.展开更多
The construction of centralized and standardized material databases is essential to support both scientific innovation and industrial application.However,for rare and precious metal materials,existing data resources a...The construction of centralized and standardized material databases is essential to support both scientific innovation and industrial application.However,for rare and precious metal materials,existing data resources are often decentralized.This results in persistent issues such as data silos and fragmentation,which significantly hinder efficient data utilization and collaboration.In response to these challenges,this study investigates the development of an integrated platform for sharing genetic data of rare and precious metal materials.The research begins by analyzing current trends in material data platforms,both domestically and internationally.These insights help inform the architectural design.The core of the platform consists of several key modules.Data resource integration is designed to aggregate and harmonize heterogeneous data from diverse sources.A structured data management system supports efficient storage and retrieval.A computational environment enables data analysis and modeling.A trusted sharing mechanism ensures security and access control.By integrating these functionalities,the platform aims to provide a unified ecosystem.This system facilitates open yet secure data exchange,promotes reproducibility,and enhances research efficiency.Finally,the article summarizes the initial implementation of the platform.It discusses its potential limitations and outlines future directions for development,including the integration of artificial intelligence tools and the expansion of data coverage.展开更多
Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for...Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for mitigating the energy crisis.A comprehensive review connecting the advancements in engineered radiative cooling systems(ERCSs),encompassing material and structural design as well as thermal and energy-related applications,is currently absent.Herein,this review begins with a concise summary of the essential concepts of ERCSs,followed by an introduction to engineered materials and structures,containing nature-inspired designs,chromatic materials,meta-structural configurations,and multilayered constructions.It subsequently encapsulates the primary applications,including thermal-regulating textiles and energy-saving devices.Next,it highlights the challenges of ERCSs,including maximized thermoregulatory effects,environmental adaptability,scalability and sustainability,and interdisciplinary integration.It seeks to offer direction for forthcoming fundamental research and industrial advancement of radiative cooling systems in real-world applications.展开更多
Analysis is given to energy sources home and abroad, the employed and customer market in oceanographic engineering and necessity of its development. Risk out of system is put forward just after marine industry into oc...Analysis is given to energy sources home and abroad, the employed and customer market in oceanographic engineering and necessity of its development. Risk out of system is put forward just after marine industry into oceanographic engineering market. It also metions several influencing factors including politics, finance and ocean engineering materials.展开更多
Landscape architecture engineering materials change rapidly. Glass is a kind of isotropic amorphous homogeneous non-crystal materials which are of diverse types, complex composition, plasticity, mirror property, abras...Landscape architecture engineering materials change rapidly. Glass is a kind of isotropic amorphous homogeneous non-crystal materials which are of diverse types, complex composition, plasticity, mirror property, abrasion resistance, durability and texture. Therefore, more attention should be paid on the application of land- scape materials.展开更多
Closing the carbon loop,through CO_(2)capture and utilization,is a promising route to mitigate climate change.Solar energy is a sustainable energy source which can be exploited to drive catalytic reactions for utilizi...Closing the carbon loop,through CO_(2)capture and utilization,is a promising route to mitigate climate change.Solar energy is a sustainable energy source which can be exploited to drive catalytic reactions for utilizing CO_(2),including converting the CO_(2)into useful products.Solar energy can be harnessed through a range of different pathways to valorize CO_(2).Whilst using solar energy to drive CO_(2)reduction has vast potential to promote catalytic CO_(2)conversions,the progress is limited due to the lack of understanding of property-performance relations as well as feasible material engineering approaches.Herein,we outline the various driving forces involved in photothermal CO_(2)catalysis.The heat from solar energy can be utilized to induce CO_(2)catalytic reduction reactions via the photothermal effect.Further,solar energy can act to modify reaction pathways through light-matter interactions.Light-induced chemical functions have demonstrated the ability to regulate intermediary reaction steps,and thus control the reaction selectivity.Photothermal catalyst structures and specific catalyst design strategies are discussed in this context.This review provides a comprehensive understanding of the heat-light synergy and guidance for rational photothermal catalyst design for CO_(2)utilization.展开更多
Biology is a rich source of great ideas that can inspire us to find successful ways to solve the challenging problems in engineering practices including those in the chemical industry. Bio-inspired chemical engineerin...Biology is a rich source of great ideas that can inspire us to find successful ways to solve the challenging problems in engineering practices including those in the chemical industry. Bio-inspired chemical engineering(Bio Ch E)may be recognized as a significant branch of chemical engineering. It may consist of, but not limited to, the following three aspects: 1) Chemical engineering principles and unit operations in biological systems; 2) Process engineering principles for producing existing or developing new chemical products through living ‘devices';and 3) Chemical engineering processes and equipment that are designed and constructed through mimicking(does not have to reproduce one hundred percent) the biological systems including their physical–chemical and mechanical structures to deliver uniquely beneficial performances. This may also include the bio-inspired sensors for process monitoring. In this paper, the above aspects are defined and discussed which establishes the scope of BioChE.展开更多
In order to effectively solve the problem of copyright protection of materials genome engineering data,this paper proposes a method for copyright protection of materials genome engineering data based on zero-watermark...In order to effectively solve the problem of copyright protection of materials genome engineering data,this paper proposes a method for copyright protection of materials genome engineering data based on zero-watermarking technology.First,the important attribute values are selected from the materials genome engineering database;then,use the method of remainder to group the selected attribute values and extract eigenvalues;then,the eigenvalues sequence is obtained by the majority election method;finally,XOR the sequence with the actual copyright information to obtain the watermarking information and store it in the third-party authentication center.When a copyright dispute requires copyright authentication for the database to be detected.First,the zero-watermarking construction algorithm is used to obtain an eigenvalues sequence;then,this sequence is XORed with the watermarking information stored in the third-party authentication center to obtain copyright information to-be-detected.Finally,the ownership is determined by calculating the similarity between copyright information to-be-detected and copyright information that has practical significance.The experimental result shows that the zero-watermarking method proposed in this paper can effectively resist various common attacks,and can well achieve the copyright protection of material genome engineering database.展开更多
Owning various crystal structures and high theoretical capacity,metal tellurides are emerging as promising electrode materials for high-performance metal-ion batteries(MBs).Since metal telluride-based MBs are quite ne...Owning various crystal structures and high theoretical capacity,metal tellurides are emerging as promising electrode materials for high-performance metal-ion batteries(MBs).Since metal telluride-based MBs are quite new,fundamental issues raise regarding the energy storage mechanism and other aspects affecting electrochemical performance.Severe volume expansion,low intrinsic conductivity and slow ion diffusion kinetics jeopardize the performance of metal tellurides,so that rational design and engineering are crucial to circumvent these disadvantages.Herein,this review provides an in-depth discussion of recent investigations and progresses of metal tellurides,beginning with a critical discussion on the energy storage mechanisms of metal tellurides in various MBs.In the following,recent design and engineering strategies of metal tellurides,including morphology engineering,compositing,defect engineering and heterostructure construction,for high-performance MBs are summarized.The primary focus is to present a comprehensive understanding of the structural evolution based on the mechanism and corresponding effects of dimension control,composition,electron configuration and structural complexity on the electrochemical performance.In closing,outlooks and prospects for future development of metal tellurides are proposed.This work also highlights the promising directions of design and engineering strategies of metal tellurides with high performance and low cost.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 51576078 and 51376070
文摘The concentrically layered thermal cloaks with isotropic materials could realize the equivalent thermal cloaking effect with Pendry＇s cloak, while the effectiveness is scarcely investigated quantitatively. Here we examine the cloaking effectiveness quantitatively by evaluating the standard deviation of the temperature difference between the simulated plane with the layered thermal cloak and Pendry＇s thermal cloak. The design rules for the isotropic materials in terms of thermal conductivity and layer thickness are presented. The present method could quan- titatively evaluate the cloaking effectiveness, and could open avenues for analyzing the cloaking effect, detecting the （anti-） cloaks, etc.
文摘Digital twins(DTs)are rapidly emerging as transformative tools in materials science and engineering,enabling real-time data integration,predictive modeling,and virtual testing.This study presents a systematic bibliometric review of 1106 peer-reviewed articles published in the last decade in Scopus and Web of Science.Using a five-stage methodology,the review examines publication trends,thematic areas,citation metrics,and keyword patterns.The results reveal exponential growth in scientific output,with Materials Theory,Computation,and Data Science as the most represented area.A thematic analysis of the most cited documents identifies four major research streams:foundational frameworks,DTs in additive manufacturing,sector-specific applications,and intelligent production systems.Keyword co-occurrence and strategic mapping show a strong foundation in modeling,simulation,and optimization,with growing links to machine learning and sustainability.The review highlights current challenges and proposes future research directions for advancing DTs in materials science.
文摘Cancer remains a significant global health concern,necessitating the development of innovative therapeutic strategies.This research paper aims to investigate the role of pyroptosis induction in cancer treatment.Pyroptosis,a form of programmed cell death characterized by the release of pro-inflammatory cytokines and the formation of plasma membrane pores,has gained significant attention as a potential target for cancer therapy.The objective of this study is to provide a comprehensive overview of the current understanding of pyroptosis and its role in cancer treatment.The paper discusses the concept of pyroptosis and its relationship with other forms of cell death,such as apoptosis and necroptosis.It explores the role of pyroptosis in immune activation and its potential for combination therapy.The study also reviews the use of natural,biological,chemical,and multifunctional composite materials for pyroptosis induction in cancer cells.The molecular mechanisms underlying pyroptosis induction by these materials are discussed,along with their advantages and challenges in cancer treatment.The findings of this study highlight the potential of pyroptosis induction as a novel therapeutic strategy in cancer treatment and provide insights into the different materials and mechanisms involved in pyroptosis induction.
文摘Nature continues to serve as inspiration for the design and fabrication of high-performance materials [1,2].The structural and compositional features responsible for e.g. the high hardness and fracture toughness of nacre,tooth enamel and other biominerals have served as a bench- mark for the structural design of hard and strong materials [3].Wood has been utilized by humankind for millennia for protection,construction,energy and for cultural and religious objects.The hierarchical and cellular structure of wood and the structure-property rela- tions of the constituents and their assemblies:e.g. cellulose,hemicellulose and lignin,has been the focus of intense research efforts and resulted in advances in the fabrication of wood-based functional and structural high- performance materials [4,5].
文摘To share and utilize data effectively for collaborative work,a common understanding of the knowledge behind the data,including its context and meaning,is a fundamental requirement.This paper focuses on the gaps that hinder common understanding between the real world and the data space,acting as barriers between systems,organizations,data spaces,and disciplines.To understand the core reasons and devise strategies for bridging the gap,the author has endeavored to synthesize a case study of material data activities from two perspectives:diachronic and synchronic,which is framed into a two-step process,involving the establishment of intersubjectivity among experts and interobjectivity among materials/substances data.As a result,the author has formulated an action plan for the digitization of engineering materials,encompassing tacit knowledge,know-how,and intellectual property rights to establish a foundation for their use with traceability,interoperability,and reusability.In order to create a conceptual framework that enhances a productive ecosystem facilitated by networked materials and substance databases,this plan is conclusively based on two key steps:fostering interactions among experts rooted in substances and materials and standardizing digitized data related to substances/materials based on their geospatial structural information.
文摘Chongqing University is located inChongqing City,Sichuan Province.Foundedoriginally in 1929,the university has sincethen greatly expanded in its scope ofeducation and organization.Now it becomesone of China’s key universities of scienceand engineering with 18 departments and38 specialities.In addition it has 20 researchinstitutes and about one hundred laboratories.The department of metallurgy and ma-terials engineering of Chongqing University
基金supported by the National Natural Science Foundation of China(No.52073030)。
文摘Integrated computational materials engineering(ICME)is to integrate multi-scale computational simulations and key experimental methods such as macroscopic,mesoscopic,and microscopic into the whole process of Al alloys design and development,which enables the design and development of Al alloys to upgrade from traditional empirical to the integration of compositionprocess-structure-mechanical property,thus greatly accelerating its development speed and reducing its development cost.This study combines calculation of phase diagram(CALPHAD),Finite element calculations,first principle calculations,and microstructure characterization methods to predict and regulate the formation and structure of composite precipitates from the design of highmodulus Al alloy compositions and optimize the casting process parameters to inhibit the formation of micropore defects in the casting process,and the final tensile strength of Al alloys reaches420 MPa and Young's modulus reaches more than 88 GPa,which achieves the design goal of the high strength and modulus Al alloys,and establishes a new mode of the design and development of the strength/modulus Al alloys.
文摘New materials are fundamental to the growth,security,and quality of life of human being sand open doors to technologies in civil,chemical,nuclear,aeronautical,mechanical,biomedical,and electrical engineering.Creative companies use multiple materials in the development of their activities,such as solid stone,fiber glass,concrete,and glass reinforced concrete,for example.Based on bibliographic research,the article examines the synergy between materials science&engineering and creative economy.The main argument indicates that this synergy creates solutions and functionalities that add value to existing products and allow the development of new products with competitive advantages.It may also contribute to the preservation of cultural values and promote sustainability.
文摘This paper analyses the peculiar acting mechanism of artificial neural network (ANN) tech, and explores the great immediate significence for the intelligent sci-tech (IST) to research and develop the nano-tech.
文摘Molecular dynamics (MD) is a computer simulation technique that helps to explore the behavior and properties of molecules and atoms. MD has been used in research and development in many spaces, including materials science and engineering and nanotechnology. MD has been proven useful in topics like the nano-engineering of construction materials, correcting graphene planar defects, studying self-assembling bio-materials, and the densification, consolidation, and sintering of nanocrystalline materials.
基金funded by the Major Science and Technology Projects in Yunnan Province(202502AD080002)Yunnan Fundamental Research Projects(202201AT070161)Yunnan Province High-Level Talent Introduction Program(C619300A023).
文摘The construction of centralized and standardized material databases is essential to support both scientific innovation and industrial application.However,for rare and precious metal materials,existing data resources are often decentralized.This results in persistent issues such as data silos and fragmentation,which significantly hinder efficient data utilization and collaboration.In response to these challenges,this study investigates the development of an integrated platform for sharing genetic data of rare and precious metal materials.The research begins by analyzing current trends in material data platforms,both domestically and internationally.These insights help inform the architectural design.The core of the platform consists of several key modules.Data resource integration is designed to aggregate and harmonize heterogeneous data from diverse sources.A structured data management system supports efficient storage and retrieval.A computational environment enables data analysis and modeling.A trusted sharing mechanism ensures security and access control.By integrating these functionalities,the platform aims to provide a unified ecosystem.This system facilitates open yet secure data exchange,promotes reproducibility,and enhances research efficiency.Finally,the article summarizes the initial implementation of the platform.It discusses its potential limitations and outlines future directions for development,including the integration of artificial intelligence tools and the expansion of data coverage.
基金support from the Contract Research(“Development of Breathable Fabrics with Nano-Electrospun Membrane”,CityU ref.:9231419“Research and application of antibacterial and healing-promoting smart nanofiber dressing for children’s burn wounds”,CityU ref:PJ9240111)+1 种基金the National Natural Science Foundation of China(“Study of Multi-Responsive Shape Memory Polyurethane Nanocomposites Inspired by Natural Fibers”,Grant No.51673162)Startup Grant of CityU(“Laboratory of Wearable Materials for Healthcare”,Grant No.9380116).
文摘Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for mitigating the energy crisis.A comprehensive review connecting the advancements in engineered radiative cooling systems(ERCSs),encompassing material and structural design as well as thermal and energy-related applications,is currently absent.Herein,this review begins with a concise summary of the essential concepts of ERCSs,followed by an introduction to engineered materials and structures,containing nature-inspired designs,chromatic materials,meta-structural configurations,and multilayered constructions.It subsequently encapsulates the primary applications,including thermal-regulating textiles and energy-saving devices.Next,it highlights the challenges of ERCSs,including maximized thermoregulatory effects,environmental adaptability,scalability and sustainability,and interdisciplinary integration.It seeks to offer direction for forthcoming fundamental research and industrial advancement of radiative cooling systems in real-world applications.
文摘Analysis is given to energy sources home and abroad, the employed and customer market in oceanographic engineering and necessity of its development. Risk out of system is put forward just after marine industry into oceanographic engineering market. It also metions several influencing factors including politics, finance and ocean engineering materials.
文摘Landscape architecture engineering materials change rapidly. Glass is a kind of isotropic amorphous homogeneous non-crystal materials which are of diverse types, complex composition, plasticity, mirror property, abrasion resistance, durability and texture. Therefore, more attention should be paid on the application of land- scape materials.
基金supported by the Australian Research Council(ARC)under the Laureate Fellowship Scheme-FL140100081 and ARC Discovery Project DP170102410the support of Scientia Ph D Scholarship from UNSW Sydneythe support of Australia Government Research Training Program(RTP)Scholarship。
文摘Closing the carbon loop,through CO_(2)capture and utilization,is a promising route to mitigate climate change.Solar energy is a sustainable energy source which can be exploited to drive catalytic reactions for utilizing CO_(2),including converting the CO_(2)into useful products.Solar energy can be harnessed through a range of different pathways to valorize CO_(2).Whilst using solar energy to drive CO_(2)reduction has vast potential to promote catalytic CO_(2)conversions,the progress is limited due to the lack of understanding of property-performance relations as well as feasible material engineering approaches.Herein,we outline the various driving forces involved in photothermal CO_(2)catalysis.The heat from solar energy can be utilized to induce CO_(2)catalytic reduction reactions via the photothermal effect.Further,solar energy can act to modify reaction pathways through light-matter interactions.Light-induced chemical functions have demonstrated the ability to regulate intermediary reaction steps,and thus control the reaction selectivity.Photothermal catalyst structures and specific catalyst design strategies are discussed in this context.This review provides a comprehensive understanding of the heat-light synergy and guidance for rational photothermal catalyst design for CO_(2)utilization.
文摘Biology is a rich source of great ideas that can inspire us to find successful ways to solve the challenging problems in engineering practices including those in the chemical industry. Bio-inspired chemical engineering(Bio Ch E)may be recognized as a significant branch of chemical engineering. It may consist of, but not limited to, the following three aspects: 1) Chemical engineering principles and unit operations in biological systems; 2) Process engineering principles for producing existing or developing new chemical products through living ‘devices';and 3) Chemical engineering processes and equipment that are designed and constructed through mimicking(does not have to reproduce one hundred percent) the biological systems including their physical–chemical and mechanical structures to deliver uniquely beneficial performances. This may also include the bio-inspired sensors for process monitoring. In this paper, the above aspects are defined and discussed which establishes the scope of BioChE.
基金This work is supported by Foundation of Beijing Key Laboratory of Internet Culture and Digital Dissemination Research No.ICDDXN004Foundation of Beijing Advanced Innovation Center for Materials Genome Engineering.
文摘In order to effectively solve the problem of copyright protection of materials genome engineering data,this paper proposes a method for copyright protection of materials genome engineering data based on zero-watermarking technology.First,the important attribute values are selected from the materials genome engineering database;then,use the method of remainder to group the selected attribute values and extract eigenvalues;then,the eigenvalues sequence is obtained by the majority election method;finally,XOR the sequence with the actual copyright information to obtain the watermarking information and store it in the third-party authentication center.When a copyright dispute requires copyright authentication for the database to be detected.First,the zero-watermarking construction algorithm is used to obtain an eigenvalues sequence;then,this sequence is XORed with the watermarking information stored in the third-party authentication center to obtain copyright information to-be-detected.Finally,the ownership is determined by calculating the similarity between copyright information to-be-detected and copyright information that has practical significance.The experimental result shows that the zero-watermarking method proposed in this paper can effectively resist various common attacks,and can well achieve the copyright protection of material genome engineering database.
基金supported by the International Collaboration Program of Jilin Provincial Department of Science and Technology,China(20230402051GH)the National Natural Science Foundation of China(51932003,51902050)+2 种基金the Open Project Program of Key Laboratory of Preparation and Application of Environmental friendly Materials(Jilin Normal University)of Ministry of China(2021006)the Fundamental Research Funds for the Central Universities JLU“Double-First Class”Discipline for Materials Science&Engineering。
文摘Owning various crystal structures and high theoretical capacity,metal tellurides are emerging as promising electrode materials for high-performance metal-ion batteries(MBs).Since metal telluride-based MBs are quite new,fundamental issues raise regarding the energy storage mechanism and other aspects affecting electrochemical performance.Severe volume expansion,low intrinsic conductivity and slow ion diffusion kinetics jeopardize the performance of metal tellurides,so that rational design and engineering are crucial to circumvent these disadvantages.Herein,this review provides an in-depth discussion of recent investigations and progresses of metal tellurides,beginning with a critical discussion on the energy storage mechanisms of metal tellurides in various MBs.In the following,recent design and engineering strategies of metal tellurides,including morphology engineering,compositing,defect engineering and heterostructure construction,for high-performance MBs are summarized.The primary focus is to present a comprehensive understanding of the structural evolution based on the mechanism and corresponding effects of dimension control,composition,electron configuration and structural complexity on the electrochemical performance.In closing,outlooks and prospects for future development of metal tellurides are proposed.This work also highlights the promising directions of design and engineering strategies of metal tellurides with high performance and low cost.
