The objective of this research is to quantify the EEC （embodied energy/CO2） of a building. The EEC represents the energy consumption and CO2 emissions at individual phases of a building＇s life-cycle, such as constr...The objective of this research is to quantify the EEC （embodied energy/CO2） of a building. The EEC represents the energy consumption and CO2 emissions at individual phases of a building＇s life-cycle, such as construction （including manufacture of materials and equipment）, renewal （including repair work） and demolition. Energy and CO2 emission intensities in terms of 401 sectors were calculated, using the 2005 I-O （input-output） table in Japan. According to our case study conducted from the construction phase to demolition, the EC （embodied CO2） of an office building used for 60 years is 12,044 t-CO2 and 1,093 kg-CO2/m^2 in total. CO2 equivalent emissions （CO2e） by Freon gases, contained in building materials, equipment and devices, were also calculated. As the results, CO2e by insulators was 2% of the building＇s EC and CO2e by refrigerants was 9%-12% of the building＇s EC. It is important to keep reducing emissions of Freon gases contained in refrigerators.展开更多
The rational design of high-performance CO_(2)adsorbents remains a critical challenge in addressing global carbon emissions,with metal-organic frameworks(MOFs)emerging as promising candidates due to their tunable pore...The rational design of high-performance CO_(2)adsorbents remains a critical challenge in addressing global carbon emissions,with metal-organic frameworks(MOFs)emerging as promising candidates due to their tunable pore environments.However,the lack of systematic guidelines for functional group selection has hindered their practical implementation in carbon capture applications.Here,this gap was addressed by developing a comprehensive design framework through high-throughput computational screening.Through construction of a topology-directed database of 4797,integrating 10 metal centers with 144 functionalized ligands(18 ligands modified by–NH_(2),–NO_(2),–CH_(3),–CF_(3),–SH_(2),–SO_(2),–OH,and–OLi)across 36 topologies,the fundamental structure–property relationships governing CO_(2)capture performance was established.Multi-metric evaluation reveals that–NO_(2),–SO_(2),and–OLi dramatically enhance CO_(2)selectivity over CH_4/N_(2)via selectivity(S_(ads)),working capacity(ΔN),adsorbent performance score(APS),sorbent selection parameter(S_(sp)),and renewability R.Specially,ΔN rises from 2.34(pristine)to 5.91–7.94 mmol g^(-1)and S_(ads)surges from 24.94/40.36 to 121.11/176.87(–NO_(2)),149.94/215.54(–SO_(2)),and 58.64/267.44(–OLi).Besides,the critical trade-off between adsorption strength and renewability demonstrates that enhanced performance comes at the cost of reduced renewability,where stronger CO_(2)affinity(isosteric heat of-29.15,-29.96,and-30.09 for–NO_(2),–SO_(2),and–OLi)compromises renewability(R reduced by -50%).To resolve this trade-off,a novel energy efficiency(η)metric was introduced,which holistically evaluates both adsorption performance(S_(ads),ΔN,APS,S_(sp),and R)and energy inputs(desorption heat,pressure-swing energy,net loss).This leads to the identification of–SO_(2)as the optimal functional group that balances exceptional CO_(2)capture(η=6.17/12.78 for CO_(2)over CH_4/N_(2)),surpassing the second higher of 4.74/8.80 in–CF_(3)and 0.99/2.18 in non-functionalized counterparts.Adopting high-throughput computational screening methods,this work provides both fundamental insights into host–vip interactions in functionalized MOFs and a practical framework for designing next-generation adsorbents,bridging the gap between materials discovery and process engineering considerations in carbon capture technologies.展开更多
The energy correlations of prompt fission neutrons have not yet been considered in the related coincidence and multiplication measurement techniques.To measure and verify the energy correlations,an experiment was perf...The energy correlations of prompt fission neutrons have not yet been considered in the related coincidence and multiplication measurement techniques.To measure and verify the energy correlations,an experiment was performed with a total measurement duration of approximately 1200 h.In the experiment,eight CLYC detectors and sixteen EJ309 liquid scintillation detectors were utilized,and the fission moment was tagged with the measured fissionγ-rays.The relative ratios of the energy spectra of the neutrons correlated with different energy neutrons to the^(252)Cf fission neutron energy spectra were obtained.The present results may be helpful for studying fission physics and nuclear technology applications.展开更多
The utilization of solid wastes to prepare Li_(4)SiO_(4) based CO_(2) adsorbents and thermochemical energy storage(TES)materials has recently garnered significant interest.Considering practical application conditions,...The utilization of solid wastes to prepare Li_(4)SiO_(4) based CO_(2) adsorbents and thermochemical energy storage(TES)materials has recently garnered significant interest.Considering practical application conditions,the influence of CO_(2) concentration and temperature fluctuations on adsorbent performance remains a key research focus.Among various waste materials,waste clay bricks are particularly suitable for Li_(4)SiO_(4) synthesis due to their high SiO_(2) content(60% to 70%),while enabling waste valorization.Furthermore,it has been demonstrated that heteroatoms present in the waste materials positively in-fluence the CO_(2) adsorption performance of Li_(4)SiO_(4)-based adsorbents.In this study,Li_(4)SiO_(4) was syn thesized for the first time directly from waste clay bricks without pretreatment.Comprehensive characterization revealed that the resulting Li_(4)SiO_(4)-based adsorbent exhibits outstanding performance:a high CO_(2) capture capacity(27.9%(mass)),excellent cycling stability,and remarkable thermal energy storage capability(876.4 kJ·kg^(-1)).These superior properties position it as one of the most promising high-temperature adsorbents for simultaneous CO_(2) capture and thermal energy storage(TES)from fossil fuel flue gase.Moreover,the adsorbent maintained excellent stability under fluctuating temper-ature and CO_(2) concentration.Even at 20%(vol)CO_(2) and 500℃,it achieved a high capacity of 25.7%(mass),reaching equilibrium within 15 min.This CO_(2) capture performance is truly impressive.展开更多
The ultrasonic energy field(UEF)-induced grain refinement mechanisms in laser powder direct energy deposition-manufactured Ti5321G alloys were systematically investigated in this study.This study focused on the interp...The ultrasonic energy field(UEF)-induced grain refinement mechanisms in laser powder direct energy deposition-manufactured Ti5321G alloys were systematically investigated in this study.This study focused on the interplay between recrystallization in the high-temperature solid deposition layers and the ultrasonic cavitation-acoustic streaming effects during molten pool solidification.A novel experimental design was developed to decouple these mechanisms by creating four distinct UEF action zones(without UEF-N,withUEF-S,with UEF-L,and with UEF-S+L)within a single-pass multilayer sample.This approach enabled the dual effects of UEF(recrystallization in solidified layers and ultrasonic cavitation-acoustic streaming effects in liquid pools)to be directly compared.The UEF significantly refined the microstructures,reducing the average grain size by 64.2%(from(399.6±28.6)to(143.1±16.1)μm)in the with UEF-S+L zone,while promoting columnar-to-equiaxed transition,with the equiaxed grain probability increasing from 11.1%(without UEF) to 53.8%.The texture intensity was reduced by approximately 52.4%and the mechanical properties were enhanced,achieving a 6.2% increase in yield strength((702.0±10.6)MPa)and 31.7%improvement in elongation.Crucially,this study revealed the synergistic effect of the dual-action mechanisms of UEF,where recrystallization and cavitation-acoustic streaming collectively enabled non-linear grain refinement.This study provides a strategy for microstructural control in additive manufacturing,eliminating the need for complex post-processing and thereby advancing the industrial application of high-performance titanium components.展开更多
The high-order deformation effects in even-even^(246,248)No are investigated by means of pairing self-consistent WoodsSaxon-Strutinsky calculations using the potential-energy-surface(PES)approach in an extended deform...The high-order deformation effects in even-even^(246,248)No are investigated by means of pairing self-consistent WoodsSaxon-Strutinsky calculations using the potential-energy-surface(PES)approach in an extended deformation space(β_(2),β_(3),β_(4),β_(5),β_(6),β_(7),β_(8)).Based on the calculated two-dimensional projected energy maps and different potential energy curves,we found that the highly even-order deformations have an important impact on both the fission trajectory and energy minima,while the odd-order deformations,accompanying the even-order ones,primarily affect the fission path beyond the second barrier.Relative to the light actinide nuclei,the nuclear ground state changes to the superdeformed configuration,but the normally deformed minimum,as the low-energy shape isomer,may still be primarily responsible for enhancing nuclear stability and ensuring experimental accessibility in^(246,248)No.Our present investigation indicates the nonnegligible impact of high-order deformation effects along the fission valley and will be helpful for deepening the understanding of different deformation effects and deformation couplings in nuclei,especially in this neutron-deficient heavy-mass region.展开更多
Energy transfers among internal waves in the northern South China Sea are not well characterized,particularly during typhoons,owing to the lack of in situ observations.Based on high-resolution mooring data collected d...Energy transfers among internal waves in the northern South China Sea are not well characterized,particularly during typhoons,owing to the lack of in situ observations.Based on high-resolution mooring data collected during Typhoon Trami(2024),this study reveals the occurrence of robust vertical energy redistribution among diurnal internal tides(D1 ITs)and near-inertial waves(NIWs).Strikingly,the typhoon not only amplified the NIW energy but also triggered an unexpected surge in the D1 IT energy.The observed average net energy transfer rate of 1×10^(-7) W kg^(−1) from typhoon-forced NIWs to D1 ITs occurred at water depths of 120-170 m.Further bispectral analysis indicated that the energy transfer is driven by nonlinear wave—wave interaction.These results reveal the existence of a new energy transfer pathway—from atmospheric forcing to D1 ITs—and redefine the redistribution of the internal wave energy during extreme weather events.展开更多
The construction industry is a significant contributor to global CO_(2) emissions,and urgent innovation is needed to mitigate its environmental impact.This paper provides a comprehensive review of scalable approaches ...The construction industry is a significant contributor to global CO_(2) emissions,and urgent innovation is needed to mitigate its environmental impact.This paper provides a comprehensive review of scalable approaches for CO_(2) uptake in construction materials,including the injection of CO_(2) into fresh concrete,the CO_(2) curing of precast concrete,and the use of ceramics as CO_(2) sinks.Among these three approaches,CO_(2) curing methods for concrete represent the most advanced and widely adopted strategies within industrial practice,with substantial research supporting their effectiveness and scalability.The comparison of carbonation mineralisation across three distinct material groups reveals that the direct injection of CO_(2) into fresh concrete mixes results in CO_(2) uptake of less than 3 kg/m3.For the precast concrete elements,the CO_(2) uptake ranges from 30 to 350 kg/m3,while ceramics can achieve uptake efficiencies up to 23 wt.%under pilot-scale conditions.Achieving efficient CO_(2) uptake in fresh and precast concrete without compromising mechanical properties relies on precise control over the CO_(2) dose,a tailored mix design,and optimised curing conditions,while avoiding excessive carbonation that could reduce alkalinity or durability.Valorisation of carbonated materials as supplementary cementitious components or aggregates is identified as an important circular solution,though further research is needed to address regeneration,performance,and standardisation.The review highlights ongoing gaps in life-cycle assessment and industrial-scale validation,and recommends future work on durability and techno-economic optimisation for robust decarbonisation in the cement and concrete industries.展开更多
An integral part of the effort to reduce greenhouse gas emissions is carbon footprint accounting.EPA categorizes facility carbon footprints in three scopes.Scope-2 emissions include electricity,heat or steam purchased...An integral part of the effort to reduce greenhouse gas emissions is carbon footprint accounting.EPA categorizes facility carbon footprints in three scopes.Scope-2 emissions include electricity,heat or steam purchased from a utility provider.This paper evaluates the existing calculation methods for scope-2 CO2 emissions for purchased electricity.The electricity grid in US is complex and is divided spatially into states,eGRID regions,balancing authorities(BAs),and utilities.Up to hourly temporal granularity can be obtained from available datasets.A matrix is developed that categorizes different datasets based on the complexity to calculate the carbon emission factors.Spatial and temporal variations are evaluated.There are significant spatial overlap between regions in different categories and emission factors within a region show sub-regional variation.An area analysis is done using zip-code polygons to determine whether a state or balancing authority is smaller for all the overlapping cases.Temporal variations in emission factors are significant depending on the balancing authority considered.A single method to calculate scope-2 emission factors may not be accurate and efficient in every case and a nuanced assessment of emission factors is warranted.An implementation pathway for a“smart carbon calculator”—one that gives accurate carbon footprint that is the spatially and temporally most granular is suggested.展开更多
Supercapacitors are indispensable for next-generation energy storage,achieving high energy density and long-term durability remains a formidable challenge.Conventional CoS suffers from poor conductivity,while Ti_(3)C_...Supercapacitors are indispensable for next-generation energy storage,achieving high energy density and long-term durability remains a formidable challenge.Conventional CoS suffers from poor conductivity,while Ti_(3)C_(2)faces severe restacking.Herein,we report a novel synthesis strategy that integrates metal-organic framework(MOF)growth with electrostatic self-assembly to construct heterojunction of CoS nanotubes coated with ultrathin Ti_(3)C_(2)nanofilms.Material characterization via SEM,TEM,XRD,and XPS systematically confirms the heterostructure formation,and chemical composition.This rational design synergistically leverages CoS high pseudocapacitance and Ti_(3)C_(2)metallic conductivity while the heterostructure mitigates restacking,enhances charge transfer,and stabilizes interfacial interactions.Density functional theory(DFT)calculations reveal strengthened OH-adsorption at the Co-Ti interface(E_(ad)=1.106 eV).Consequently,the CoS/Ti_(3)C_(2)@CC delivers a remarkable specific capacitance of 1034.21 F g^(-1) at 1 A g^(-1).Assembled into a supercapacitor,CoS/Ti_(3)C_(2)@CC//AC achieves a high energy density of 74.22 Wh kg^(-1) at 800 W kg^(-1),maintaining 89.13%initial capacitance after 10,000 cycles.Significantly,it exhibits a remarkably low leakage current(0.23μA)and ultra-prolonged voltage retention(47.14%after 120 h),underscoring exceptional durability.This work pioneers a rational heterostructure engineering strategy by integrating MOF-derived architectures with conductive MXene nanofilms,offering critical insights for the development of ultra-durable supercapacitors.展开更多
Objectives:Philadelphia chromosome-positive B-cell acute lymphoblastic leukemia and Philadelphia-like B-cell acute lymphoblastic leukemia(Ph+/Ph-like ALL)constitute the majority of relapsed/refractory B-ALL(R/R B-ALL)...Objectives:Philadelphia chromosome-positive B-cell acute lymphoblastic leukemia and Philadelphia-like B-cell acute lymphoblastic leukemia(Ph+/Ph-like ALL)constitute the majority of relapsed/refractory B-ALL(R/R B-ALL)cases,highlighting an urgent need to discover new therapeutic targets.This study aims to elucidate the mechanisms underlying poor prognosis in Ph+/Ph-like ALL through transcriptome sequencing and functional cytological assays,with the goal of informing new clinical treatment strategies.Results:Transcriptomic analysis of Ph+/Ph-like ALL patients revealed that low expression of P2X Purinoceptor 1(P2RX1)was associated with unfavorable outcomes.Specifically,patients with poor prognosis and low P2RX1 expression exhibited downregulation of genes involved in energy and calcium metabolism pathways,along with upregulation of genes governing key cellular processes such as cell proliferation(e.g.,MYC),cell cycle progression(e.g.,CCND2),and apoptosis inhibition(e.g.,DASP6).Cellular experiments demonstrated that SUP-B15 cells overexpressing P2RX1 displayed elevated intracellular levels of ATP,calcium,and glucose,together with enhanced glycolytic capacity,compared to empty vector controls.Treatment of SUP-B15 cells with dexamethasone(Dex),Imatinib,or their combination significantly suppressed proliferation and promoted apoptosis,which was accompanied by increases in intracellular ATP,calcium,and glucose.Moreover,exogenous ATP administration(a P2RX1 agonist)enhanced apoptosis and inhibited proliferation in control cells.Conversely,treatment with NF449(a P2RX1 inhibitor)increased proliferation in both P2RX1-overexpressing and control SUP-B15 cells.Conclusion:Our findings indicate that P2RX1 may exert this function through modulating energy metabolism and calcium homeostasis,resulting in elevated intracellular calcium levels.Sustained elevation of calcium promotes apoptosis,whereas exogenous ATP activates P2RX1,enhances calcium influx,and attenuates the suppression of apoptosis associated with P2RX1 underexpression,ultimately correlating with improved treatment response.展开更多
NASICON-type Na_(3)V_(2)(PO_(4))_(3)(NVP)materials are seen as highly promising cathode materials in the field of sodium-ion batteries due to their low cost,a solid three-dimensional skeleton and good theoretical capa...NASICON-type Na_(3)V_(2)(PO_(4))_(3)(NVP)materials are seen as highly promising cathode materials in the field of sodium-ion batteries due to their low cost,a solid three-dimensional skeleton and good theoretical capacity,as well as high ionic conductivity.Nevertheless,the problem of low intrinsic electronic conductivity and energy density has limited the practical application of the materials.To address this issue,the relevant research team has successfully achieved remarkable research results through unremitting exploration and practical innovation.In this work,the crystal structure,ion migration mechanism and sodium storage mechanism of NVP cathode materials are systematically reviewed,with a focus on summarizing the latest progress of V-site doping modification research,classifying and exploring V-site doping from the perspectives of electronic structure,lattice strain and entropy,and briefly describing the optimization mechanism of V-site doping on electrochemical performance.In addition,the challenges and prospects for the future development of NVP cathode materials are presented,which are believed to provide new thinking for the design and development of high-performance NVP cathode materials and contribute to the large-scale application of sodium-ion batteries.展开更多
文摘The objective of this research is to quantify the EEC （embodied energy/CO2） of a building. The EEC represents the energy consumption and CO2 emissions at individual phases of a building＇s life-cycle, such as construction （including manufacture of materials and equipment）, renewal （including repair work） and demolition. Energy and CO2 emission intensities in terms of 401 sectors were calculated, using the 2005 I-O （input-output） table in Japan. According to our case study conducted from the construction phase to demolition, the EC （embodied CO2） of an office building used for 60 years is 12,044 t-CO2 and 1,093 kg-CO2/m^2 in total. CO2 equivalent emissions （CO2e） by Freon gases, contained in building materials, equipment and devices, were also calculated. As the results, CO2e by insulators was 2% of the building＇s EC and CO2e by refrigerants was 9%-12% of the building＇s EC. It is important to keep reducing emissions of Freon gases contained in refrigerators.
基金supported by The National Natural Science Foundation of China(22471289 and 22478430)Shandong Natural Science Foundation(ZR2022ME105 and ZR2023ME004)+4 种基金Qingdao Natural Science Foundation(23-2-1-232-zyyd-jch)Geological body description and key technologies of reservoir engineering of CCUS oil displacement(2021ZZ01-03)Science and Technology Major Project on New Oil and Gas Exploration and Development:Research on Comprehensive Control Technology for CO_(2)-Enhanced Miscible and Immiscible Displacement(2024ZD1406601)State Key Laboratory of Enhanced Oil Recovery of Open Fund Funded Project(2024-KFKT-19)the Fundamental Research Funds for the Central Universities(24CX06042A and 24CX06070A)。
文摘The rational design of high-performance CO_(2)adsorbents remains a critical challenge in addressing global carbon emissions,with metal-organic frameworks(MOFs)emerging as promising candidates due to their tunable pore environments.However,the lack of systematic guidelines for functional group selection has hindered their practical implementation in carbon capture applications.Here,this gap was addressed by developing a comprehensive design framework through high-throughput computational screening.Through construction of a topology-directed database of 4797,integrating 10 metal centers with 144 functionalized ligands(18 ligands modified by–NH_(2),–NO_(2),–CH_(3),–CF_(3),–SH_(2),–SO_(2),–OH,and–OLi)across 36 topologies,the fundamental structure–property relationships governing CO_(2)capture performance was established.Multi-metric evaluation reveals that–NO_(2),–SO_(2),and–OLi dramatically enhance CO_(2)selectivity over CH_4/N_(2)via selectivity(S_(ads)),working capacity(ΔN),adsorbent performance score(APS),sorbent selection parameter(S_(sp)),and renewability R.Specially,ΔN rises from 2.34(pristine)to 5.91–7.94 mmol g^(-1)and S_(ads)surges from 24.94/40.36 to 121.11/176.87(–NO_(2)),149.94/215.54(–SO_(2)),and 58.64/267.44(–OLi).Besides,the critical trade-off between adsorption strength and renewability demonstrates that enhanced performance comes at the cost of reduced renewability,where stronger CO_(2)affinity(isosteric heat of-29.15,-29.96,and-30.09 for–NO_(2),–SO_(2),and–OLi)compromises renewability(R reduced by -50%).To resolve this trade-off,a novel energy efficiency(η)metric was introduced,which holistically evaluates both adsorption performance(S_(ads),ΔN,APS,S_(sp),and R)and energy inputs(desorption heat,pressure-swing energy,net loss).This leads to the identification of–SO_(2)as the optimal functional group that balances exceptional CO_(2)capture(η=6.17/12.78 for CO_(2)over CH_4/N_(2)),surpassing the second higher of 4.74/8.80 in–CF_(3)and 0.99/2.18 in non-functionalized counterparts.Adopting high-throughput computational screening methods,this work provides both fundamental insights into host–vip interactions in functionalized MOFs and a practical framework for designing next-generation adsorbents,bridging the gap between materials discovery and process engineering considerations in carbon capture technologies.
基金supported by the National Natural Science Foundation of China(No.12105257)the Research and Development Fund(No.JMJJ202401)。
文摘The energy correlations of prompt fission neutrons have not yet been considered in the related coincidence and multiplication measurement techniques.To measure and verify the energy correlations,an experiment was performed with a total measurement duration of approximately 1200 h.In the experiment,eight CLYC detectors and sixteen EJ309 liquid scintillation detectors were utilized,and the fission moment was tagged with the measured fissionγ-rays.The relative ratios of the energy spectra of the neutrons correlated with different energy neutrons to the^(252)Cf fission neutron energy spectra were obtained.The present results may be helpful for studying fission physics and nuclear technology applications.
基金the National Natural Science Foundation of China(5240101142)Yunnan Province basic research project(202401CF070252)+1 种基金the Key R&D plan of Yunnan Province(202303AC100008)the Scientific Researching Fund Projects of Yunnan Provincial Department of Education(2025J0077),which funded this study。
文摘The utilization of solid wastes to prepare Li_(4)SiO_(4) based CO_(2) adsorbents and thermochemical energy storage(TES)materials has recently garnered significant interest.Considering practical application conditions,the influence of CO_(2) concentration and temperature fluctuations on adsorbent performance remains a key research focus.Among various waste materials,waste clay bricks are particularly suitable for Li_(4)SiO_(4) synthesis due to their high SiO_(2) content(60% to 70%),while enabling waste valorization.Furthermore,it has been demonstrated that heteroatoms present in the waste materials positively in-fluence the CO_(2) adsorption performance of Li_(4)SiO_(4)-based adsorbents.In this study,Li_(4)SiO_(4) was syn thesized for the first time directly from waste clay bricks without pretreatment.Comprehensive characterization revealed that the resulting Li_(4)SiO_(4)-based adsorbent exhibits outstanding performance:a high CO_(2) capture capacity(27.9%(mass)),excellent cycling stability,and remarkable thermal energy storage capability(876.4 kJ·kg^(-1)).These superior properties position it as one of the most promising high-temperature adsorbents for simultaneous CO_(2) capture and thermal energy storage(TES)from fossil fuel flue gase.Moreover,the adsorbent maintained excellent stability under fluctuating temper-ature and CO_(2) concentration.Even at 20%(vol)CO_(2) and 500℃,it achieved a high capacity of 25.7%(mass),reaching equilibrium within 15 min.This CO_(2) capture performance is truly impressive.
基金supported by the National Key Researchand Development Program of China(No.2021YFC2801904)the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai,China(No.AMGM2024F11).
文摘The ultrasonic energy field(UEF)-induced grain refinement mechanisms in laser powder direct energy deposition-manufactured Ti5321G alloys were systematically investigated in this study.This study focused on the interplay between recrystallization in the high-temperature solid deposition layers and the ultrasonic cavitation-acoustic streaming effects during molten pool solidification.A novel experimental design was developed to decouple these mechanisms by creating four distinct UEF action zones(without UEF-N,withUEF-S,with UEF-L,and with UEF-S+L)within a single-pass multilayer sample.This approach enabled the dual effects of UEF(recrystallization in solidified layers and ultrasonic cavitation-acoustic streaming effects in liquid pools)to be directly compared.The UEF significantly refined the microstructures,reducing the average grain size by 64.2%(from(399.6±28.6)to(143.1±16.1)μm)in the with UEF-S+L zone,while promoting columnar-to-equiaxed transition,with the equiaxed grain probability increasing from 11.1%(without UEF) to 53.8%.The texture intensity was reduced by approximately 52.4%and the mechanical properties were enhanced,achieving a 6.2% increase in yield strength((702.0±10.6)MPa)and 31.7%improvement in elongation.Crucially,this study revealed the synergistic effect of the dual-action mechanisms of UEF,where recrystallization and cavitation-acoustic streaming collectively enabled non-linear grain refinement.This study provides a strategy for microstructural control in additive manufacturing,eliminating the need for complex post-processing and thereby advancing the industrial application of high-performance titanium components.
基金supported by the Natural Science Foundation of Henan Province(No.252300421478)the National Natural Science Foundation of China(Nos.11975209,U2032211,12075287)。
文摘The high-order deformation effects in even-even^(246,248)No are investigated by means of pairing self-consistent WoodsSaxon-Strutinsky calculations using the potential-energy-surface(PES)approach in an extended deformation space(β_(2),β_(3),β_(4),β_(5),β_(6),β_(7),β_(8)).Based on the calculated two-dimensional projected energy maps and different potential energy curves,we found that the highly even-order deformations have an important impact on both the fission trajectory and energy minima,while the odd-order deformations,accompanying the even-order ones,primarily affect the fission path beyond the second barrier.Relative to the light actinide nuclei,the nuclear ground state changes to the superdeformed configuration,but the normally deformed minimum,as the low-energy shape isomer,may still be primarily responsible for enhancing nuclear stability and ensuring experimental accessibility in^(246,248)No.Our present investigation indicates the nonnegligible impact of high-order deformation effects along the fission valley and will be helpful for deepening the understanding of different deformation effects and deformation couplings in nuclei,especially in this neutron-deficient heavy-mass region.
基金supported by the National Key R&D Plan Program of China [Grant number 2021YFC3101500]the National Natural Science Foundation of China [Grant number 42305014,42506024]。
文摘Energy transfers among internal waves in the northern South China Sea are not well characterized,particularly during typhoons,owing to the lack of in situ observations.Based on high-resolution mooring data collected during Typhoon Trami(2024),this study reveals the occurrence of robust vertical energy redistribution among diurnal internal tides(D1 ITs)and near-inertial waves(NIWs).Strikingly,the typhoon not only amplified the NIW energy but also triggered an unexpected surge in the D1 IT energy.The observed average net energy transfer rate of 1×10^(-7) W kg^(−1) from typhoon-forced NIWs to D1 ITs occurred at water depths of 120-170 m.Further bispectral analysis indicated that the energy transfer is driven by nonlinear wave—wave interaction.These results reveal the existence of a new energy transfer pathway—from atmospheric forcing to D1 ITs—and redefine the redistribution of the internal wave energy during extreme weather events.
基金funded by the Recovery and Resilience Plan(PRR)to support Collaborative Laboratories(CoLABs),Interface Mission[Notice No.01/C05-i02/2022].
文摘The construction industry is a significant contributor to global CO_(2) emissions,and urgent innovation is needed to mitigate its environmental impact.This paper provides a comprehensive review of scalable approaches for CO_(2) uptake in construction materials,including the injection of CO_(2) into fresh concrete,the CO_(2) curing of precast concrete,and the use of ceramics as CO_(2) sinks.Among these three approaches,CO_(2) curing methods for concrete represent the most advanced and widely adopted strategies within industrial practice,with substantial research supporting their effectiveness and scalability.The comparison of carbonation mineralisation across three distinct material groups reveals that the direct injection of CO_(2) into fresh concrete mixes results in CO_(2) uptake of less than 3 kg/m3.For the precast concrete elements,the CO_(2) uptake ranges from 30 to 350 kg/m3,while ceramics can achieve uptake efficiencies up to 23 wt.%under pilot-scale conditions.Achieving efficient CO_(2) uptake in fresh and precast concrete without compromising mechanical properties relies on precise control over the CO_(2) dose,a tailored mix design,and optimised curing conditions,while avoiding excessive carbonation that could reduce alkalinity or durability.Valorisation of carbonated materials as supplementary cementitious components or aggregates is identified as an important circular solution,though further research is needed to address regeneration,performance,and standardisation.The review highlights ongoing gaps in life-cycle assessment and industrial-scale validation,and recommends future work on durability and techno-economic optimisation for robust decarbonisation in the cement and concrete industries.
文摘An integral part of the effort to reduce greenhouse gas emissions is carbon footprint accounting.EPA categorizes facility carbon footprints in three scopes.Scope-2 emissions include electricity,heat or steam purchased from a utility provider.This paper evaluates the existing calculation methods for scope-2 CO2 emissions for purchased electricity.The electricity grid in US is complex and is divided spatially into states,eGRID regions,balancing authorities(BAs),and utilities.Up to hourly temporal granularity can be obtained from available datasets.A matrix is developed that categorizes different datasets based on the complexity to calculate the carbon emission factors.Spatial and temporal variations are evaluated.There are significant spatial overlap between regions in different categories and emission factors within a region show sub-regional variation.An area analysis is done using zip-code polygons to determine whether a state or balancing authority is smaller for all the overlapping cases.Temporal variations in emission factors are significant depending on the balancing authority considered.A single method to calculate scope-2 emission factors may not be accurate and efficient in every case and a nuanced assessment of emission factors is warranted.An implementation pathway for a“smart carbon calculator”—one that gives accurate carbon footprint that is the spatially and temporally most granular is suggested.
基金supported by the National Natural Science Foundation of China(22201107,52203147)Zhejiang Provincial Natural Science Foundation of China(MS25B040011)significant science and technology projects of LongMen Laboratory in Henan Province(231100220100).
文摘Supercapacitors are indispensable for next-generation energy storage,achieving high energy density and long-term durability remains a formidable challenge.Conventional CoS suffers from poor conductivity,while Ti_(3)C_(2)faces severe restacking.Herein,we report a novel synthesis strategy that integrates metal-organic framework(MOF)growth with electrostatic self-assembly to construct heterojunction of CoS nanotubes coated with ultrathin Ti_(3)C_(2)nanofilms.Material characterization via SEM,TEM,XRD,and XPS systematically confirms the heterostructure formation,and chemical composition.This rational design synergistically leverages CoS high pseudocapacitance and Ti_(3)C_(2)metallic conductivity while the heterostructure mitigates restacking,enhances charge transfer,and stabilizes interfacial interactions.Density functional theory(DFT)calculations reveal strengthened OH-adsorption at the Co-Ti interface(E_(ad)=1.106 eV).Consequently,the CoS/Ti_(3)C_(2)@CC delivers a remarkable specific capacitance of 1034.21 F g^(-1) at 1 A g^(-1).Assembled into a supercapacitor,CoS/Ti_(3)C_(2)@CC//AC achieves a high energy density of 74.22 Wh kg^(-1) at 800 W kg^(-1),maintaining 89.13%initial capacitance after 10,000 cycles.Significantly,it exhibits a remarkably low leakage current(0.23μA)and ultra-prolonged voltage retention(47.14%after 120 h),underscoring exceptional durability.This work pioneers a rational heterostructure engineering strategy by integrating MOF-derived architectures with conductive MXene nanofilms,offering critical insights for the development of ultra-durable supercapacitors.
基金supported by Guangdong Province Basic and Applied Basic Research Fund Project(2023A1515220104)Open Fund of Key Laboratory of Hepatoaplenic Surgery,Ministry of Education(Award Number:GPKF202407).
文摘Objectives:Philadelphia chromosome-positive B-cell acute lymphoblastic leukemia and Philadelphia-like B-cell acute lymphoblastic leukemia(Ph+/Ph-like ALL)constitute the majority of relapsed/refractory B-ALL(R/R B-ALL)cases,highlighting an urgent need to discover new therapeutic targets.This study aims to elucidate the mechanisms underlying poor prognosis in Ph+/Ph-like ALL through transcriptome sequencing and functional cytological assays,with the goal of informing new clinical treatment strategies.Results:Transcriptomic analysis of Ph+/Ph-like ALL patients revealed that low expression of P2X Purinoceptor 1(P2RX1)was associated with unfavorable outcomes.Specifically,patients with poor prognosis and low P2RX1 expression exhibited downregulation of genes involved in energy and calcium metabolism pathways,along with upregulation of genes governing key cellular processes such as cell proliferation(e.g.,MYC),cell cycle progression(e.g.,CCND2),and apoptosis inhibition(e.g.,DASP6).Cellular experiments demonstrated that SUP-B15 cells overexpressing P2RX1 displayed elevated intracellular levels of ATP,calcium,and glucose,together with enhanced glycolytic capacity,compared to empty vector controls.Treatment of SUP-B15 cells with dexamethasone(Dex),Imatinib,or their combination significantly suppressed proliferation and promoted apoptosis,which was accompanied by increases in intracellular ATP,calcium,and glucose.Moreover,exogenous ATP administration(a P2RX1 agonist)enhanced apoptosis and inhibited proliferation in control cells.Conversely,treatment with NF449(a P2RX1 inhibitor)increased proliferation in both P2RX1-overexpressing and control SUP-B15 cells.Conclusion:Our findings indicate that P2RX1 may exert this function through modulating energy metabolism and calcium homeostasis,resulting in elevated intracellular calcium levels.Sustained elevation of calcium promotes apoptosis,whereas exogenous ATP activates P2RX1,enhances calcium influx,and attenuates the suppression of apoptosis associated with P2RX1 underexpression,ultimately correlating with improved treatment response.
基金supported by the National Natural Science Foundation of China(no.52574348)the Natural Science Foundation of Hebei Province(no.B2024501004)+2 种基金the Fundamental Research Funds for the Central Universities(no.N2423013)the Shijiazhuang Basic Research Project(no.241790667A)the Performance Subsidy Fund for Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province(no.22567627H).
文摘NASICON-type Na_(3)V_(2)(PO_(4))_(3)(NVP)materials are seen as highly promising cathode materials in the field of sodium-ion batteries due to their low cost,a solid three-dimensional skeleton and good theoretical capacity,as well as high ionic conductivity.Nevertheless,the problem of low intrinsic electronic conductivity and energy density has limited the practical application of the materials.To address this issue,the relevant research team has successfully achieved remarkable research results through unremitting exploration and practical innovation.In this work,the crystal structure,ion migration mechanism and sodium storage mechanism of NVP cathode materials are systematically reviewed,with a focus on summarizing the latest progress of V-site doping modification research,classifying and exploring V-site doping from the perspectives of electronic structure,lattice strain and entropy,and briefly describing the optimization mechanism of V-site doping on electrochemical performance.In addition,the challenges and prospects for the future development of NVP cathode materials are presented,which are believed to provide new thinking for the design and development of high-performance NVP cathode materials and contribute to the large-scale application of sodium-ion batteries.
