The concept of emissivity has been with the scientific and engineering world since Planck formulated his blackbody radiation law more than a century ago.Nevertheless,emissivity is an elusive concept even for ex⁃perts....The concept of emissivity has been with the scientific and engineering world since Planck formulated his blackbody radiation law more than a century ago.Nevertheless,emissivity is an elusive concept even for ex⁃perts.It is a vague and fuzzy concept for the wider community of engineers.The importance of remote sensing of temperature by measuring IR radiation has been recognized in a wide range of industrial,medical,and environ⁃mental uses.One of the major sources of errors in IR radiometry is the emissivity of the surface being measured.In real experiments,emissivity may be influenced by many factors:surface texture,spectral properties,oxida⁃tion,and aging of surfaces.While commercial blackbodies are prevalent,the much-needed grey bodies with a known emissivity,are unavailable.This study describes how to achieve a calibrated and stable emissivity with a blackbody,a perforated screen,and a reliable and linear novel IR thermal sensor,18 dubbed TMOS.The Digital TMOS is now a low-cost commercial product,it requires low power,and it has a small form factor.The method⁃ology is based on two-color measurements,with two different optical filters,with selected wavelengths conform⁃ing to the grey body definition of the use case under study.With a photochemically etched perforated screen,the effective emissivity of the screen is simply the hole density area of the surface area that emits according to the blackbody temperature radiation.The concept is illustrated with ray tracing simulations,which demonstrate the approach.Measured results are reported.展开更多
Infrared radiation(IR)ceramics have been recognized as energy-saving materials for high-temperature industry due to excellent IR performance.However,for conventional IR ceramics,low emissivity in partial band and emis...Infrared radiation(IR)ceramics have been recognized as energy-saving materials for high-temperature industry due to excellent IR performance.However,for conventional IR ceramics,low emissivity in partial band and emissivity degradation during high-temperature service restricted the practical application.Herein,we integrated broad-band high emissivity and slow degradation rate in novel high-entropy perovskite ceramics:La(Al_(0.2)Co_(0.2)Fe_(0.2)Ni_(0.2)Cr_(0.2))O_(3−δ)(HE-1) and La(Al_(0.2)Co_(0.2)Fe_(0.2)Ni_(0.2)Mn_(0.2))O_(3−δ)(HE-2).Specifically,the high-energy ceramic HE-1&HE-2 displayed high emissivity of 0.94/0.90 and 0.90/0.95 in the broad-band of near/mid-infrared(0.76–14µm).This excellent IR performance can be attributed to impurity energy level absorption,free carrier absorption,and lattice vibration absorption.During high-temperature service,these high-entropy ceramics have much slower emissivity degradation rate than conventional IR ceramic,because of hysteresis diffusion effect.Additionally,energy-saving ratios of 17.70%and 10.77%were realized by heating water with porous burner containing HE-1 and HE-2 coating respectively,due to enhanced heat radiation in systems.Thus,these high-entropy IR ceramics have significant application potential for long-term energy-saving in high-temperature industry.展开更多
The rapid evolution of hypersonic vehicle technologies necessitates robust thermal protection systems capable of withstanding extreme oxidative ablation.This study introduces a novel gradient-architected ZrB_(2)-MoSi_...The rapid evolution of hypersonic vehicle technologies necessitates robust thermal protection systems capable of withstanding extreme oxidative ablation.This study introduces a novel gradient-architected ZrB_(2)-MoSi_(2)-SiC dense layer embedded within a lightweight three-dimensional(3D)needled carbon fiber composite.Utilizing the volatility of ethanol and polycarbosilane,the ceramic slurry is selectively infused into targeted regions of the fibrous structure,optimizing the ZrB_(2)to MoSi_(2)ratio to enhance performance.The resulting dense layer exhibits exceptional emissivity,surpassing 0.90 in the 1-3μm range and exceeding 0.87 in the 2-14μm range.Moreover,it demonstrates remarkable oxidative ablation resistance.Specifically,at an optimized ZrB_(2)to MoSi_(2)ratio of 6:4,the dense layer achieves a minimal linear ablation rate of 0.015μm·s^(-1) under a 1.5 MW·m^(-2)oxyacetylene flame for 1000 s.Even after exposure to oxyacetylene ablation at surface temperatures of approximately 1750℃for 1000 s,the dense layer retains its structural integrity,highlighting its enduring oxidation resistance.The incorporation of MoSi_(2)not only enhances emissivity but also fortifies the ZrO_(2)and SiO_(2)oxide layers,crucial for environments with elevated oxygen levels,thereby mitigating the active oxidation of SiC.This combination of high emissivity and long-term oxidation resistance at ultra-high temperatures positions the ZrB_(2)-MoSi_(2)-SiC dense layer as an exceptionally promising candidate for advanced thermal protection in hypersonic vehicles.展开更多
We present in this paper a numerical study of the validity limit of the geometrical optics approximation compared with a differential method which is established according to rigorous formalisms based on the electroma...We present in this paper a numerical study of the validity limit of the geometrical optics approximation compared with a differential method which is established according to rigorous formalisms based on the electromagnetic theory. The precedent studies show that this method is adapted to the study of diffraction by periodic rough surfaces. We determine by two methods the emissivity of gold and tungsten for surfaces with a rectangular or sinusoidal profile, for a wavelength equal to 0.55 microns. The monochromatic directional emissivity of these surfaces clearly depends on the angle of incidence, the surface profile, height, period and the nature of the material. We perform our calculations by a method of coupled wave analysis (CWA) and a geometric optics method (GOA). The latter method is theoretically valid only when the dimensions of the cavities are very large compared to the wavelength, while the CWA is theoretically correct whatever these dimensions. The main purpose of this work is to investigate the validity limit of GOA compared with CWA. The obtained results for a fixed height of the grating, allowed us to delimit the validity domain of the optic geometrical approximation for the treated cases. Finally, the agreement between the emissivity calculated by the differential method and that given on the basis of the homogenization theory is satisfactory when the period is much smaller than the wavelength.展开更多
Luminescent metal-organic frameworks(MOFs)have garnered significant attention due to their structural tunability and potential applications in solid-state lighting,bioimaging,sensing,anticounterfeiting,and other field...Luminescent metal-organic frameworks(MOFs)have garnered significant attention due to their structural tunability and potential applications in solid-state lighting,bioimaging,sensing,anticounterfeiting,and other fields.Nevertheless,due to the tendency of1,4-benzenedicarboxylic acid(BDC)to rotate within the framework,MOFs composed of it exhibit significant non-radiative energy dissipation and thus impair the emissive properties.In this study,efficient luminescence of MIL-140A nanocrystals(NCs)with BDC rotors as ligands is achieved by pressure treatment strategy.Pressure treatment effectively modulates the pore structure of the framework,enhancing the interactions between the N,N-dimethylformamide vip molecules and the BDC ligands.The enhanced host-vip interaction contributes to the structural rigidity of the MOF,thereby suppressing the rotation-induced excited-state energy loss.As a result,the pressure-treated MIL-140A NCs displayed bright blue-light emission,with the photoluminescence quantum yield increasing from an initial 6.8%to 69.2%.This study developed an effective strategy to improve the luminescence performance of rotor ligand MOFs,offers a new avenue for the rational design and synthesis of MOFs with superior luminescent properties.展开更多
为探究稻茬小麦深施肥“一基一追”机艺融合技术的增产增效减排机制,2021—2024年在长江下游南通稻茬麦区开展大田试验。试验采用缓释掺混肥料(SRF,N∶P_(2)O_(5)∶K_(2)O=26∶12∶12)和普通尿素(U,46%N),结合自主研发的2BFGK-12(6)260...为探究稻茬小麦深施肥“一基一追”机艺融合技术的增产增效减排机制,2021—2024年在长江下游南通稻茬麦区开展大田试验。试验采用缓释掺混肥料(SRF,N∶P_(2)O_(5)∶K_(2)O=26∶12∶12)和普通尿素(U,46%N),结合自主研发的2BFGK-12(6)260全秸秆茬地洁区旋耕智能施肥播种机和3ZF-4(200)中耕追肥机,设置7种施肥模式(30 cm+15 cm宽窄行种植):以尿素4次分施(N 240 kg hm^(-2),基肥∶分蘖肥∶拔节肥∶孕穗肥=5∶1∶2∶2,窄行基施,追肥全田撒施)为对照(CK);减氮15%(N 204 kg hm^(-2))条件下设置6种处理:M_(1)(100%SRF窄行基施);M_(2)(60%SRF窄行基施+40%U拔节期窄行撒施);M_(3)(60%SRF窄行基施+40%U返青期宽行条施);M_(4)(60%SRF窄行基施+40%SRF返青期窄行撒施);M_(5)(60%SRF窄行基施+40%SRF返青期宽行条施);M_(4+5)(60%SRF窄行基施+20%SRF返青期宽行条施+20%SRF返青期窄行撒施)。研究比较不同施肥模式对小麦产量效益、根系形态生理、氮素利用效率及N_(2)O排放的影响。结果表明,与CK相比,M_(2)~M_(5)处理提高了小麦产量(4.0%~19.0%)和经济效益(13.7%~35.7%),其中M_(4)和M_(5)处理表现最优,分别增产14.1%和19.0%,经济效益提升34.5%和35.7%。这些处理明显改善了根系特性(根干重密度增加9.7%~111.8%,根系活力和氧化力分别提高6.8%~52.0%和4.2%~44.2%),降低N_(2)O累积排放量22.6%~34.5%,提高0~20 cm土层硝态氮含量11.2%~40.0%。在氮素利用方面,M_(2)~M_(5)处理均提高了籽粒氮素积累量、花后氮素积累量及其对籽粒氮素的贡献率,氮肥利用效率指标(包括偏生产力、农学效率和表观利用率)分别显著提升了22.4%~40.0%、29.7%~74.3%和9.41~18.77个百分点。值得注意的是,M_(4)和M_(5)处理表现出最优的综合效益:N_(2)O累积排放量降幅最大(分别达27.0%和34.5%),氮肥表观利用率2季均维持在43.0%以上(均值分别为43.5%和46.8%),同时在生育后期保持较高的根系活性和耕层无机氮含量。相比之下,M_(1)处理虽然实现了最大的N_(2)O减排效果(降幅35.9%),但导致减产10.4%和经济效益下降10.8%,且氮肥利用效率呈现不稳定的年际变化特征。而优化处理M_(4+5)进一步改善了根系形态生理特性,并提高氮肥表观利用率和籽粒氮素积累量。综上,减氮15%条件下(N 204 kg hm^(-2)),缓混肥2次施用处理(M_(4)和M_(5))能实现产量、经济效益、氮肥利用效率和N_(2)O减排的协同提高,并以追肥深施处理(M_(5))效应更强。本研究为稻茬小麦缓释肥减氮优化高效应用提供重要理论依据。展开更多
文摘The concept of emissivity has been with the scientific and engineering world since Planck formulated his blackbody radiation law more than a century ago.Nevertheless,emissivity is an elusive concept even for ex⁃perts.It is a vague and fuzzy concept for the wider community of engineers.The importance of remote sensing of temperature by measuring IR radiation has been recognized in a wide range of industrial,medical,and environ⁃mental uses.One of the major sources of errors in IR radiometry is the emissivity of the surface being measured.In real experiments,emissivity may be influenced by many factors:surface texture,spectral properties,oxida⁃tion,and aging of surfaces.While commercial blackbodies are prevalent,the much-needed grey bodies with a known emissivity,are unavailable.This study describes how to achieve a calibrated and stable emissivity with a blackbody,a perforated screen,and a reliable and linear novel IR thermal sensor,18 dubbed TMOS.The Digital TMOS is now a low-cost commercial product,it requires low power,and it has a small form factor.The method⁃ology is based on two-color measurements,with two different optical filters,with selected wavelengths conform⁃ing to the grey body definition of the use case under study.With a photochemically etched perforated screen,the effective emissivity of the screen is simply the hole density area of the surface area that emits according to the blackbody temperature radiation.The concept is illustrated with ray tracing simulations,which demonstrate the approach.Measured results are reported.
基金financially supported by the National Natural Science Foundation of China(Nos.52372029,U22A20127,52304356,and 92263205)the Key R&D Plan Project in Hubei Province(No.2023BCB100).
文摘Infrared radiation(IR)ceramics have been recognized as energy-saving materials for high-temperature industry due to excellent IR performance.However,for conventional IR ceramics,low emissivity in partial band and emissivity degradation during high-temperature service restricted the practical application.Herein,we integrated broad-band high emissivity and slow degradation rate in novel high-entropy perovskite ceramics:La(Al_(0.2)Co_(0.2)Fe_(0.2)Ni_(0.2)Cr_(0.2))O_(3−δ)(HE-1) and La(Al_(0.2)Co_(0.2)Fe_(0.2)Ni_(0.2)Mn_(0.2))O_(3−δ)(HE-2).Specifically,the high-energy ceramic HE-1&HE-2 displayed high emissivity of 0.94/0.90 and 0.90/0.95 in the broad-band of near/mid-infrared(0.76–14µm).This excellent IR performance can be attributed to impurity energy level absorption,free carrier absorption,and lattice vibration absorption.During high-temperature service,these high-entropy ceramics have much slower emissivity degradation rate than conventional IR ceramic,because of hysteresis diffusion effect.Additionally,energy-saving ratios of 17.70%and 10.77%were realized by heating water with porous burner containing HE-1 and HE-2 coating respectively,due to enhanced heat radiation in systems.Thus,these high-entropy IR ceramics have significant application potential for long-term energy-saving in high-temperature industry.
基金supported by the National Natural Science Foundation of China(Nos.52272060,51902067,51872066 and 52172041)the Key Program of National Natural Science Foundation of China(No.52032003)+5 种基金the Young Elite Scientists Sponsorship Program by CAST(No.2020QNRC001)China Postdoctoral Science Foundation(Nos.2019M651282 and 2022T150157)Heilongjiang Provincial Postdoctoral Science Foundation(Nos.LBH-Z19022 and LBH-TZ2207)Heilongjiang Touyan Innovation Team Program,Shanghai Aerospace Science and Technology Innovation Fund(No.SAST2019-012)the Fundamental Research Funds for the Central Universities(No.FRFCU5710051022)the Science Foundation of National Key Laboratory of Science and Technology on Advanced Composites in Special Environments(No.JCKYS2022603C011).
文摘The rapid evolution of hypersonic vehicle technologies necessitates robust thermal protection systems capable of withstanding extreme oxidative ablation.This study introduces a novel gradient-architected ZrB_(2)-MoSi_(2)-SiC dense layer embedded within a lightweight three-dimensional(3D)needled carbon fiber composite.Utilizing the volatility of ethanol and polycarbosilane,the ceramic slurry is selectively infused into targeted regions of the fibrous structure,optimizing the ZrB_(2)to MoSi_(2)ratio to enhance performance.The resulting dense layer exhibits exceptional emissivity,surpassing 0.90 in the 1-3μm range and exceeding 0.87 in the 2-14μm range.Moreover,it demonstrates remarkable oxidative ablation resistance.Specifically,at an optimized ZrB_(2)to MoSi_(2)ratio of 6:4,the dense layer achieves a minimal linear ablation rate of 0.015μm·s^(-1) under a 1.5 MW·m^(-2)oxyacetylene flame for 1000 s.Even after exposure to oxyacetylene ablation at surface temperatures of approximately 1750℃for 1000 s,the dense layer retains its structural integrity,highlighting its enduring oxidation resistance.The incorporation of MoSi_(2)not only enhances emissivity but also fortifies the ZrO_(2)and SiO_(2)oxide layers,crucial for environments with elevated oxygen levels,thereby mitigating the active oxidation of SiC.This combination of high emissivity and long-term oxidation resistance at ultra-high temperatures positions the ZrB_(2)-MoSi_(2)-SiC dense layer as an exceptionally promising candidate for advanced thermal protection in hypersonic vehicles.
文摘We present in this paper a numerical study of the validity limit of the geometrical optics approximation compared with a differential method which is established according to rigorous formalisms based on the electromagnetic theory. The precedent studies show that this method is adapted to the study of diffraction by periodic rough surfaces. We determine by two methods the emissivity of gold and tungsten for surfaces with a rectangular or sinusoidal profile, for a wavelength equal to 0.55 microns. The monochromatic directional emissivity of these surfaces clearly depends on the angle of incidence, the surface profile, height, period and the nature of the material. We perform our calculations by a method of coupled wave analysis (CWA) and a geometric optics method (GOA). The latter method is theoretically valid only when the dimensions of the cavities are very large compared to the wavelength, while the CWA is theoretically correct whatever these dimensions. The main purpose of this work is to investigate the validity limit of GOA compared with CWA. The obtained results for a fixed height of the grating, allowed us to delimit the validity domain of the optic geometrical approximation for the treated cases. Finally, the agreement between the emissivity calculated by the differential method and that given on the basis of the homogenization theory is satisfactory when the period is much smaller than the wavelength.
基金supported by the National Key R&D Program of China(Grant No.2023YFA1406200)the National Natural Science Foundation of China(No.12274177 and 12304261)the China Postdoctoral Science Foundation(No.2024M751076)。
文摘Luminescent metal-organic frameworks(MOFs)have garnered significant attention due to their structural tunability and potential applications in solid-state lighting,bioimaging,sensing,anticounterfeiting,and other fields.Nevertheless,due to the tendency of1,4-benzenedicarboxylic acid(BDC)to rotate within the framework,MOFs composed of it exhibit significant non-radiative energy dissipation and thus impair the emissive properties.In this study,efficient luminescence of MIL-140A nanocrystals(NCs)with BDC rotors as ligands is achieved by pressure treatment strategy.Pressure treatment effectively modulates the pore structure of the framework,enhancing the interactions between the N,N-dimethylformamide vip molecules and the BDC ligands.The enhanced host-vip interaction contributes to the structural rigidity of the MOF,thereby suppressing the rotation-induced excited-state energy loss.As a result,the pressure-treated MIL-140A NCs displayed bright blue-light emission,with the photoluminescence quantum yield increasing from an initial 6.8%to 69.2%.This study developed an effective strategy to improve the luminescence performance of rotor ligand MOFs,offers a new avenue for the rational design and synthesis of MOFs with superior luminescent properties.
文摘为探究稻茬小麦深施肥“一基一追”机艺融合技术的增产增效减排机制,2021—2024年在长江下游南通稻茬麦区开展大田试验。试验采用缓释掺混肥料(SRF,N∶P_(2)O_(5)∶K_(2)O=26∶12∶12)和普通尿素(U,46%N),结合自主研发的2BFGK-12(6)260全秸秆茬地洁区旋耕智能施肥播种机和3ZF-4(200)中耕追肥机,设置7种施肥模式(30 cm+15 cm宽窄行种植):以尿素4次分施(N 240 kg hm^(-2),基肥∶分蘖肥∶拔节肥∶孕穗肥=5∶1∶2∶2,窄行基施,追肥全田撒施)为对照(CK);减氮15%(N 204 kg hm^(-2))条件下设置6种处理:M_(1)(100%SRF窄行基施);M_(2)(60%SRF窄行基施+40%U拔节期窄行撒施);M_(3)(60%SRF窄行基施+40%U返青期宽行条施);M_(4)(60%SRF窄行基施+40%SRF返青期窄行撒施);M_(5)(60%SRF窄行基施+40%SRF返青期宽行条施);M_(4+5)(60%SRF窄行基施+20%SRF返青期宽行条施+20%SRF返青期窄行撒施)。研究比较不同施肥模式对小麦产量效益、根系形态生理、氮素利用效率及N_(2)O排放的影响。结果表明,与CK相比,M_(2)~M_(5)处理提高了小麦产量(4.0%~19.0%)和经济效益(13.7%~35.7%),其中M_(4)和M_(5)处理表现最优,分别增产14.1%和19.0%,经济效益提升34.5%和35.7%。这些处理明显改善了根系特性(根干重密度增加9.7%~111.8%,根系活力和氧化力分别提高6.8%~52.0%和4.2%~44.2%),降低N_(2)O累积排放量22.6%~34.5%,提高0~20 cm土层硝态氮含量11.2%~40.0%。在氮素利用方面,M_(2)~M_(5)处理均提高了籽粒氮素积累量、花后氮素积累量及其对籽粒氮素的贡献率,氮肥利用效率指标(包括偏生产力、农学效率和表观利用率)分别显著提升了22.4%~40.0%、29.7%~74.3%和9.41~18.77个百分点。值得注意的是,M_(4)和M_(5)处理表现出最优的综合效益:N_(2)O累积排放量降幅最大(分别达27.0%和34.5%),氮肥表观利用率2季均维持在43.0%以上(均值分别为43.5%和46.8%),同时在生育后期保持较高的根系活性和耕层无机氮含量。相比之下,M_(1)处理虽然实现了最大的N_(2)O减排效果(降幅35.9%),但导致减产10.4%和经济效益下降10.8%,且氮肥利用效率呈现不稳定的年际变化特征。而优化处理M_(4+5)进一步改善了根系形态生理特性,并提高氮肥表观利用率和籽粒氮素积累量。综上,减氮15%条件下(N 204 kg hm^(-2)),缓混肥2次施用处理(M_(4)和M_(5))能实现产量、经济效益、氮肥利用效率和N_(2)O减排的协同提高,并以追肥深施处理(M_(5))效应更强。本研究为稻茬小麦缓释肥减氮优化高效应用提供重要理论依据。
