We investigate the segregation behavior of alloying atoms （Sr, Th, In, Cd, Ag, Sc, Au, Zn, Cu, Mn, Cr, and Ti） near Z3 （ 111 ） [1]-0] tilt symmetric grain boundary （GB） in tungsten and their effects on the inter...We investigate the segregation behavior of alloying atoms （Sr, Th, In, Cd, Ag, Sc, Au, Zn, Cu, Mn, Cr, and Ti） near Z3 （ 111 ） [1]-0] tilt symmetric grain boundary （GB） in tungsten and their effects on the intergranular embrittlement by performing first-principles calculations. The calculated segregation energies suggest that Ag, Au, Cd, In, Sc, Sr, Th, and Ti prefer to occupy the site in the mirror plane of the GB, while Cu, Cr, Mn, and Zn intend to locate at the first layer nearby the GB core. The calculated strengthening energies predict Sr, Th, In, Cd, Ag, Sc, Au, Ti, and Zn act as embrittlers while Cu, Cr, and Mn act as cohesion enhancers. The correlation of the alloying atom＇s metal radius with strengthening energy is strong enough to predict the strengthening and embrittling behavior of alloying atoms; that is, the alloying atom with larger metal radius than W acts as an embrittler and the one with smaller metal radius acts as a cohesion enhancer.展开更多
Effects of alloying elements Ni,Co,Mn,Cr,and H on the stacking fault energy(SFE)ofγ-Fe and its microscopic mechanisms were systematically investigated.Generalized SFE calculations show that individual alloying elemen...Effects of alloying elements Ni,Co,Mn,Cr,and H on the stacking fault energy(SFE)ofγ-Fe and its microscopic mechanisms were systematically investigated.Generalized SFE calculations show that individual alloying elements Ni,Co,and H increase SFE ofγ-Fe,whereas Mn and Cr decrease SFE.The influence of alloying elements on SFE exhibits short-range characteristics.The effect of synergistic interaction of alloying elements and H on SFE was further investigated.Results show that the co-alloying of Ni/Co with H exacerbates the effect of H on the increase in SFE.In contrast,the synergistic effect of Mn/Cr with H tends to inhibit H from the increasing SFE.Finally,the electronic structure analysis elucidated the microscopic mechanism of the change in SFE.Alloying elements modulate SFE by changing the interatomic charge density at the stacking fault plane and the density of states of the stacking fault structure at the Fermi level.The present results add to the knowledge of alloying related influence on the mechanical property and hydrogen embrittlement ofγ-Fe.展开更多
Joining magnesium(Mg)alloys to steel is difficult due to metallurgical incompatibility.Applying a zinc(Zn)coating to steel enables formation of a thin Mg-Zn eutectic phase layer during welding,which promotes strong bo...Joining magnesium(Mg)alloys to steel is difficult due to metallurgical incompatibility.Applying a zinc(Zn)coating to steel enables formation of a thin Mg-Zn eutectic phase layer during welding,which promotes strong bonding.However,in joints created with Friction-stir assisted scribe technology(FAST),this Mg-Zn eutectic phase layer occasionally extends from the interface to the surface of the Mg sheet.This phenomenon is attributed to the formation of a liquid-state Mg-Zn eutectic phase,coupled with the distinctive material flow induced by the FAST tool.Microstructural analysis confirmed that the Mg-Zn eutectic phase comprisesα-Mg and the Mg_(21)Zn_(25)intermetallic compound.Lap shear tensile tests revealed that when the Mg-Zn eutectic phase migration pathway aligned with the stir zone boundary,it led to reduced joint strength and premature fracture along the eutectic phase pathway.This indicates that liquid metal embrittlement(LME)occurred during FAST joining of Mg alloy and galvanized steel.These findings highlight the critical importance of controlling tool features and process parameters in FAST welding to prevent LME-related failures in dissimilar Mg/steel assemblies.展开更多
In order to overcome the embrittlement of metastable titanium alloys caused by the precipitation ofωiso phase during aging,regulation of isothermalωprecipitation was investigated in Ti−15Mo alloy.The results show th...In order to overcome the embrittlement of metastable titanium alloys caused by the precipitation ofωiso phase during aging,regulation of isothermalωprecipitation was investigated in Ti−15Mo alloy.The results show that the sample is brittle when direct aging(A)is applied at 350℃for 1 h after solution treatment(ST).If pre-deformation(D)is performed on the ST sample to induce{332}twins and secondaryα″phase,subsequent aging at 350℃(STDA350)improves the strength to 931 MPa with a good ductility of about 20%maintained.However,when aging is performed at 400℃or 450℃(STDA400/450),the strength can be further improved,but the ductility is dramatically reduced.Atomic-scale characterizations show that the partial collapse ofωphase in the STDA350 sample effectively eliminates aging-induced embrittlement,but complete collapse leads to poor ductility in the STDA400/450 sample.展开更多
Micropillar compression tests were used to investigate the influence of hydrogen on the deformation behavior and hydrogen embrittlement(HE)of nitrogen-alloyed austenitic stainless steel QN_(2)109.Results indicate that...Micropillar compression tests were used to investigate the influence of hydrogen on the deformation behavior and hydrogen embrittlement(HE)of nitrogen-alloyed austenitic stainless steel QN_(2)109.Results indicate that the hydrogen increases the dislocation density,reduces the yield stress,and accelerates the formation and intersection of slip bands,with hydrogen-induced cracks initiating at slip band intersections.X-ray diffraction confirms the absence of martensitic transformation,ruling out the role of martensitic transformation in HE.The micropillar compression technique is highly sensitive for characterizing hydrogen-material interactions,owing to the material’s low hydrogen diffusivity and the small size of its hydrogen-affected zone.These findings align with the hydrogen-enhanced localized plasticity mechanism.展开更多
This study investigates the influence of hydrogen concentration at grain boundaries on the sensitivity of polycrystalline iron to hydrogen embrittlement using molecular dynamics simulations.These simulations reveal th...This study investigates the influence of hydrogen concentration at grain boundaries on the sensitivity of polycrystalline iron to hydrogen embrittlement using molecular dynamics simulations.These simulations reveal the diffusion behavior of hydrogen atoms at grain boundaries and their consequential impact on the hydrogen embrittlement sensitivity of iron alloys.The findings indicate that as the hydrogen concentration increases,both the yield strength and ultimate tensile strength of Fe-H alloys exhibit a declining trend.Moreover,the capture of hydrogen atoms at the grain boundaries significantly influences the fracture toughness of the material and promotes the formation and propagation of cracks.This study provides a novel theoretical basis for understanding and predicting the hydrogen embrittlement behavior of iron-based materials in hydrogen-rich environments,offering valuable insights for the design and development of Fe alloys with enhanced resistance to hydrogen embrittlement.展开更多
Widespread use of green hydrogen is a critical route to achieving a carbon-neutral society,but it cannot be accomplished without extensive hydrogen distribution.Hydrogen pipelines are the most energy-efficient approac...Widespread use of green hydrogen is a critical route to achieving a carbon-neutral society,but it cannot be accomplished without extensive hydrogen distribution.Hydrogen pipelines are the most energy-efficient approach to transporting hydrogen in areas with high,long-term demand for hydrogen.A well-known fact is that the properties of hydrogen differ from those of natural gas,which leads to significant variations in the pipeline transportation process.In addition,hydrogen can degrade the mechanical properties of steels,thereby affecting pipeline integrity.This situation has led to two inevitable key challenges in the current development of hydrogen-pipeline technology:economic viability and safety.Based on a review of the current state of hydrogen pipelines,including material compatibility with hydrogen,design methods,process operations,safety monitoring,and standards,this paper highlights key knowledge gaps in gaseous hydrogen pipelines.These gaps include the utilisation of high-strength materials for hydrogen pipelines,design of high-quality hydrogen pipelines,determination of hydrogen velocity,and repurposing of existing natural-gas pipelines.This review aims to identify the challenges in current hydrogen pipelines development and provide valuable suggestions for future research.展开更多
Austenitic stainless steel(ASS)is a common material used in high-pressure hydrogen systems.Prolonged exposure to high-pressure hydrogen can cause hydrogen embrittlement(HE),raising significant safety concerns.Selectiv...Austenitic stainless steel(ASS)is a common material used in high-pressure hydrogen systems.Prolonged exposure to high-pressure hydrogen can cause hydrogen embrittlement(HE),raising significant safety concerns.Selective Laser Melting(SLM),known for its high precision,is a promising additive manufacturing technology that has been widely adopted across various industries.Studies have reported that under certain SLM manufacturing conditions and process parameters,the HE resistance of SLM ASS is significantly better than that of conventionally manufactured(CM)ASS,showing great potential for application in high-pressure hydrogen systems.Thus,studying the HE of SLM ASS is crucial for further improving the safety of high-pressure hydrogen systems.This paper provides an overview of the SLM process,reviews the mechanisms of HE and their synergistic effects,and analyzes the HE characteristics of SLM ASS.Additionally,it examines the influence of unique microstructures and SLM process variables on HE of SLM ASS and offers recommendations for future research to enhance the safety of high-pressure hydrogen systems.展开更多
In this study,we investigated the correlation between the pre-strain and hydrogen embrittlement(HE)mechanisms in medium-Mn steel.Intercritically annealed Fe-7Mn-0.2C-3Al(wt.%)steel,which showed a two-phase microstruct...In this study,we investigated the correlation between the pre-strain and hydrogen embrittlement(HE)mechanisms in medium-Mn steel.Intercritically annealed Fe-7Mn-0.2C-3Al(wt.%)steel,which showed a two-phase microstructure comprising α ferrite and γR retained austenite,was used as a model alloy.As the pre-strain level increased from 0%to 45%,the volume fraction of γR gradually decreased owing to the strain-inducedα′martensite transformation accompanied by an increase in dislocation density.The HE resistance decreased with increasing the pre-strain level because the sample with a higher pre-strain level revealed a higher amount of dissolved hydrogen,combined with a more extensive brittle fracture region owing to the enhanced diffusion and permeation of hydrogen from the reduced γR fraction.Ad-ditionally,the H-assisted crack in the sample without pre-strain was initiated and propagated from the γR grains when the strain-induced α′phase was formed,because most of the dissolved hydrogen was concentrated in the γR grains,and these grains were predominantly deformed compared to the other phases.However,the pre-strained sample showed more pronounced multiple H-assisted cracking at the constituent phases,such as α and α′,because it exhibited relatively well-dispersed hydrogen atoms and reduced microstrain localization at the γR grains,due to the reduced γR fraction.展开更多
The low-temperature embrittlement limits the service temperature of ferritic and duplex stainless steels.The effects of alloying elements added to Fe-Cr binary system on the low-temperature embrittlement have been rev...The low-temperature embrittlement limits the service temperature of ferritic and duplex stainless steels.The effects of alloying elements added to Fe-Cr binary system on the low-temperature embrittlement have been reviewed critically.Prior literature on the underlying phase transformation,i.e.,phase separation(PS)and changes of mechanical properties,is surveyed.The available literature indicates that the rate of PS is accelerated by Ni or Co in Fe-Cr binary system.The increased kinetics of PS also lead to an enhanced hardening rate during aging for Ni and Co alloyed Fe-Cr alloys.In low Cr(<17 wt.%)ferritic alloys,the additions of Al or Co can reduce embrittlement because these elements contribute to lowering the driving force for PS.The influence of other alloying elements such as Mo,Cu,Mn,Nb,and Ti is inconclusive but also discussed here.Thermodynamic and kinetic calculations were performed to evaluate current CALPHAD databases and to further investigate the thermodynamic and kinetic reasons for the effect of the additional alloying elements added to Fe-Cr alloy on PS.Some indications were provided for improving physically-based predictions of low-temperature embrittlement as well as opportunities to mitigate the phenomenon by alloying.展开更多
In this work,through performing microstructural characterization,tensile testing and failure analysis,the influence of electrochemical hydrogen charging on the microstructure and mechanical behavior of an as-cast Mg-8...In this work,through performing microstructural characterization,tensile testing and failure analysis,the influence of electrochemical hydrogen charging on the microstructure and mechanical behavior of an as-cast Mg-8wt.%Li alloy was investigated.It revealed that after being hydrogen charged at 50 mA/cm2 for respectively 3 h,6 h and 18 h in 0.1 M NaCl solution,obvious HID occurred and the damage degree was gradually increased with the hydrogen charging time.For the sample being hydrogen charged for 3 h,micro pores with the diameter ranging from 10~30µm were formed and preferentially present inα-Mg phase.Moreover,micro cracks with the length ranging from 10~50µm mainly initiated inα-Mg phase,atα-Mg/β-Li interfaces and the peripheries of pores.With the increase of hydrogen charging time,the numbers of pores and cracks were obviously increased.Tensile results revealed that the hydrogen charging can simultaneously decrease the tensile strength and ductility of the alloy.Compared with the uncharged sample,the tensile yield strength,ultimate tensile strength and the elongation ratio to failure were respectively reduced by 5.7%,7.3%,31.7%for the 3h-charged sample and 24.6%,24.8%,67.0%for the 18h-charged sample.Failure analysis indicated that hydrogen charging can induce the brittle cracking of the alloy and the size of brittle cracking region being composed of quasi-cleavage facets and interfacial cracks on the fracture surfaces was increased with the hydrogen charging time.展开更多
Combined with the hydrogen pre-charging and tensile testing methods,the effect of charged hydrogen content on the microstructure and mechanical behavior of an as-forged Ti–6Al–4V alloy was investigated.After perform...Combined with the hydrogen pre-charging and tensile testing methods,the effect of charged hydrogen content on the microstructure and mechanical behavior of an as-forged Ti–6Al–4V alloy was investigated.After performing hydrogen charging for 2,4,6,8 and 10 h at a constant cathodic current density value of 75 mA/cm^(2) in a corrosion medium of 3.5 wt.%NaCl solution,the hydrogen contents in the charged samples increased gradually from 73×10^(−4) to 230×10^(−4) wt.%.When the hydrogen content was less than 190×10^(−4) wt.%,the charged hydrogen atoms were present as the solute atoms in the matrix,resulting in the enhanced tensile strength due to the solid solution strengthening of hydrogen atoms.Moreover,the reduced axial ratio c/a for α-Ti matrix due to the hydrogen dissolution was beneficial to improving the ductility of the hydrogenated samples.The critical hydrogen content for simultaneously improving the ductility and strength is determined to be 99×10^(−4)wt.%.When the hydrogen content was 230×10^(−4)wt.%,a small number of δ-TiHx hydrides and micro cracks formed in the localized areas of α-Ti matrix,resulting in the simultaneous decrease of ductility and strength.展开更多
Hydrogen embrittlement(HE)in 2 GPa-grade press-hardened steel(PHS)has posed a great risk to its lightweighting application in automotive crash-resistant components.While conventional slow strain rate tensile tests sho...Hydrogen embrittlement(HE)in 2 GPa-grade press-hardened steel(PHS)has posed a great risk to its lightweighting application in automotive crash-resistant components.While conventional slow strain rate tensile tests show that the precharged hydrogen concentration of 3.5 wppm induces a severe loss in strength and ductility,the high strain rate tests conducted at 1–103 s−1 that simulate the crash condition demonstrate no loss in strength and a minimal loss in ductility.Such strain rate dependency cannot be exclusively explained via hydrogen diffusion and redistribution to susceptible prior austenite grain boundaries,as the tensile testing of precharged samples with jumping strain rates offers a sufficient redistribution period at slow-strain-rate loading,but does not necessarily lead to a high level of HE afterwards.Detailed fractography analysis acknowledges that hydrogen-induced microcracks nucleated within early deformation stages are directly responsible for the high HE susceptibility of all test conditions.A phase-field simulation comprising 2 GPa-grade PHS's microstructure features and the hydrogen diffusion under tested loading conditions is applied.The calculation reveals that the hydrogen redistribution behavior is spatially confined to the crack tip areas but to a much greater extent.It thus facilitates continuous crack growth following the main crack with minimal plastic deformation and avoids branching to form secondary cracks.The combined experiments and modeling highlight the vital role of microcracks in the HE performance of 2 GPa-grade PHS,upon which the safety factor of HE in high-strength martensitic steels shall be established.展开更多
Direct evidence of hydrogen-assisted crack nucleation and propagation associated with the δ phase in the selective laser melted GH4169 superalloy was obtained.The analysis of hydrogen trapping sites using thermal des...Direct evidence of hydrogen-assisted crack nucleation and propagation associated with the δ phase in the selective laser melted GH4169 superalloy was obtained.The analysis of hydrogen trapping sites using thermal desorption spectroscopy revealed that the δ phase exhibits strong hydrogen capture capability,with a hydrogen desorption activation energy of 35.45±2.51 kJ/mol.In addition,spatially resolved hydrogen mapping conducted by scanning Kelvin probe force microscopy and hydrogen microprint technique provided further evidence for the δ phase as a deep hydrogen trapping site.The atomic-scale characterization sufficiently reveals the deformation mechanism of the δ phase induced by dislocation accumulation.Hydrogen-promoted dislocation slip localization facilitates the formation of microvoid defects in the δ phase,which is the main reason for the δ phase fracture,and induces intergranular and transgranular cracks.展开更多
The effects of the Laves-decorated dendrite structure on the hydrogen-assisted cracking behavior of the SLM-718 alloy were investigated.The Laves phase exhibits a hydrogen desorption activation energy of 47.67±7....The effects of the Laves-decorated dendrite structure on the hydrogen-assisted cracking behavior of the SLM-718 alloy were investigated.The Laves phase exhibits a hydrogen desorption activation energy of 47.67±7.85 kJ mol^(-1).The results of in situ scanning Kelvin probe force microscopy and hydrogen microprint technique provide direct evidence of the hydrogen trapping by the Laves phase.The high-density dendrite walls consisting of entangled dislocations exhibit an inhibitory effect on hydrogen diffusion.Atomic-scale characterization reveals that dislocation stacking at the Laves/γ-matrix interface induces the formation of dislocation defects and a high-stress concentration in the Laves phase.The presence of hydrogen further promotes the formation of micropore defects and the embrittlement of the Laves phase.Hydrogen-promoted dislocation slip localization and hydrogen-induced reduction of interatomic bonding are the primary reasons for the Laves phase fracture and debonding at the Laves/γ-matrix interface.The coalescence of micropore defects ultimately leads to hydrogen-induced crack formation.展开更多
Hydrogen dissolved from the moisture or the wire filler is formed on the surface of welded joint due to the driving of high-energy heat source.The diffused hydrogen in the welded joint could cause hydrogen embrittleme...Hydrogen dissolved from the moisture or the wire filler is formed on the surface of welded joint due to the driving of high-energy heat source.The diffused hydrogen in the welded joint could cause hydrogen embrittlement(HE).The important factors determining the HE resistance of welded joints are microstructure style,dislocation distribution,grains characteristics,precipitate particle,and residual stress.Different welding technologies show various heat sources and heat cycles,which result in different characteristics of fusion zone and heat-affected zone.Thus,the HE fracture behavior of welded joint produced by different welded technologies differs greatly.The current stage of HE behavior of welded joint was reviewed to provide fundamental reference for the scientists and engineers engaging in welding.The appearance of hydrogen atoms in the surface or interior of welded joint could weaken the bonding strength and change the fracture mode from ductile to sudden brittle fracture.Generally,the controlling of filler wire and heat input is a practical route to obtain the excellent welded joint with high HE resistance.The inhibition of hydrogen diffusion via the formation of fine coating and the aggregation of hydrogen atoms via the control of microstructure and precipitates are the effective routes to improve HE resistance.展开更多
Hydrogen embrittlement(HE)remains a critical challenge for high-strength steels.This study comparatively investigates the HE behavior and hydrogen diffusion characteristics of a vanadium-micro-alloyed 42CrNiMoV steel ...Hydrogen embrittlement(HE)remains a critical challenge for high-strength steels.This study comparatively investigates the HE behavior and hydrogen diffusion characteristics of a vanadium-micro-alloyed 42CrNiMoV steel against conventional 40CrNiMo steel through slow strain rate testing(SSRT),hydrogen thermal desorption,and hydrogen permeation measurements.The 42CrNiMoV steel demonstrated better mechanical properties and improved HE resistance under SSRT with both hydrogen pre-charged and in situ charging conditions.Microstructural analysis revealed that vanadium micro-alloying leads to grain refinement and reduces hydrogen diffusivity through vanadium carbides.Fractographic investigations revealed the environment-dependent fracture mechanisms,transitioning from ductile-to brittle-dominated failure modes under different hydrogen-charging conditions.These findings validate that vanadium micro-alloying represents a promising,cost-effective strategy for developing hydrogen-resistant high-strength steels,while emphasizing the crucial need for rigorous hydrogen ingress control in practical applications.展开更多
In this study,an alternative modelling approach for absorbed hydrogen stress corrosion cracking(SCC)is proposed,with hydrogen-enhanced decohesion(HEDE)identified as the key failure mechanism.All analyses have been per...In this study,an alternative modelling approach for absorbed hydrogen stress corrosion cracking(SCC)is proposed,with hydrogen-enhanced decohesion(HEDE)identified as the key failure mechanism.All analyses have been performed by utilising only ABAQUS standard elements,COH2D4T and CPE4T,already available within the software and without the need to develop external subroutines.The study also tends to highlight the criticality of implementing a correct Traction Separation Law(TSL)curve to simulate the hydrogen diffusion within the specimen and using the concept of dynamic hydrogen penetration by continuously updating the hydrogen concentration boundary conditions as the crack propagates.In conclusion,this study successfully demonstrated that standard software elements(COH2D4T and CPE4T)can effectively model physical problems and crack velocity propagation without custom subroutines.It emphasized that while the specific shape of the Traction-Separation Law(TSL)is less critical,its correct implementation is vital for simulating dynamic hydrogen coverage.Crucially,excluding this dynamic coverage—a common practice—risks significantly underestimating crack propagation speed.Although results incorporating dynamic coverage aligned well with experimental data,minor discrepancies are likely due to unmodeled factors like material property variations,hydrogen trapping,temperature,and granular microstructure,which are proposed for future research.展开更多
Powder bed fusion-laser beam with metals(PBF-LB/M)can be used to manufacture intricate NiTi com-ponents.However,the ductility of NiTi alloys fabricated by PBF-LB/M is generally∼20%less than those made via conventiona...Powder bed fusion-laser beam with metals(PBF-LB/M)can be used to manufacture intricate NiTi com-ponents.However,the ductility of NiTi alloys fabricated by PBF-LB/M is generally∼20%less than those made via conventional processes.Although many heat treatment methods have been proposed,solving this issue has been proven difficult.An intractable problem is the brittleness of PBF-LB/M-fabricated NiTi after solid-solution treatment at 1000℃.By investigating the microstructural and fractography change after heat treatment in the range of 100-1000℃,this study found that this ductile-to-brittle transition stems from abnormal oxygen-containing Ti-rich precipitates being generated in the PBF-LB/M fabricated Ni-rich NiTi.We identified laser processing-induced local oxygen segregation and tiny TiO2(B)particles at the fusion and grain boundaries.During the heat treatment at temperatures above 700℃,these ox-ides decompose due to their low thermal stability.After this decomposition,most oxygen diffuses into the matrix,with titanium remaining in local regions.This process enriches titanium in the interfaces,forming a brittle oxygen-rich Ti_(2)Ni network that is known to hinder the recrystallization process in heat treatment.Furthermore,when subjected to external loading,these precipitates can induce high misfit levels and local distortion,resulting in brittle fractures along the interfaces.Based on these results,we also propose approaches to avoid high-temperature-induced embrittlement in Ni-rich NiTi.展开更多
The effect of rare-earth cerium on impurity P-induced embrittlement for an advanced SA508Gr.4N reactor pressure vessels steel is investigated by virtue of microstructural characterization,Auger electron spectroscopy(A...The effect of rare-earth cerium on impurity P-induced embrittlement for an advanced SA508Gr.4N reactor pressure vessels steel is investigated by virtue of microstructural characterization,Auger electron spectroscopy(AES),and spin-polarized density functional theory(DFT)calculations.The ductile-to-brittle transition temperatures(DBTTs)are evaluated by Charpy impact testing,and grain boundary segregation(GBS)of P is quantified by AES.Trace addition of Ce can effectively reduce GBS level of P,thereby substantially decreasing the embrittlement induced by P.A linear correlation between DBTT(℃)and GBS level of P(Cp,at.%)is observed for both undoped and Ce-doped samples,being expressed as DBTT=13.13C_(p)-335.70(undoped)and DBTT=12.67C_(p)-350.78(Ce-doped).In the absence of GBS of P,the incorporation of Ce appears to play a pivotal role in augmenting the intrinsic toughness.These results imply that the impact of Ce on impurity P-induced embrittlement may be attributed to a combination of increasing the intrinsic toughness and lowering GBS of P.DFT calculations indicate that there is a negligible interaction between Ce and P in the ternary alloy,and thus GBS of P and Ce is mainly site-competitive.展开更多
基金Project supported by the National Magnetic Confinement Fusion Program(Grant No.2011GB108004)the National Natural Science Foundation of China(Grant Nos.91026002 and 91126002)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.KJCX2-YW-N35 andXDA03010303)the Center for Computation Science,Hefei Institutes of Physical Sciences
文摘We investigate the segregation behavior of alloying atoms （Sr, Th, In, Cd, Ag, Sc, Au, Zn, Cu, Mn, Cr, and Ti） near Z3 （ 111 ） [1]-0] tilt symmetric grain boundary （GB） in tungsten and their effects on the intergranular embrittlement by performing first-principles calculations. The calculated segregation energies suggest that Ag, Au, Cd, In, Sc, Sr, Th, and Ti prefer to occupy the site in the mirror plane of the GB, while Cu, Cr, Mn, and Zn intend to locate at the first layer nearby the GB core. The calculated strengthening energies predict Sr, Th, In, Cd, Ag, Sc, Au, Ti, and Zn act as embrittlers while Cu, Cr, and Mn act as cohesion enhancers. The correlation of the alloying atom＇s metal radius with strengthening energy is strong enough to predict the strengthening and embrittling behavior of alloying atoms; that is, the alloying atom with larger metal radius than W acts as an embrittler and the one with smaller metal radius acts as a cohesion enhancer.
基金supported by National Science and Technology Major Project(2025ZD0618901)National Natural Science Foundation of China(U2241245 and 52321001)+2 种基金Aeronautical Science Foundation of China(2022Z053092001)Natural Science Foundation of Shenyang(23-503-6-05)Science and Technology Major Project of Liaoning Province(2024JH1/11700028).
文摘Effects of alloying elements Ni,Co,Mn,Cr,and H on the stacking fault energy(SFE)ofγ-Fe and its microscopic mechanisms were systematically investigated.Generalized SFE calculations show that individual alloying elements Ni,Co,and H increase SFE ofγ-Fe,whereas Mn and Cr decrease SFE.The influence of alloying elements on SFE exhibits short-range characteristics.The effect of synergistic interaction of alloying elements and H on SFE was further investigated.Results show that the co-alloying of Ni/Co with H exacerbates the effect of H on the increase in SFE.In contrast,the synergistic effect of Mn/Cr with H tends to inhibit H from the increasing SFE.Finally,the electronic structure analysis elucidated the microscopic mechanism of the change in SFE.Alloying elements modulate SFE by changing the interatomic charge density at the stacking fault plane and the density of states of the stacking fault structure at the Fermi level.The present results add to the knowledge of alloying related influence on the mechanical property and hydrogen embrittlement ofγ-Fe.
基金PNNL is operated by Battelle Memorial Institute for the U.S.Department of Energy under contract DE-AC05-76RL01830sponsored by the DOEEERE,Vehicle Technology Office,through the Joining Core Program.
文摘Joining magnesium(Mg)alloys to steel is difficult due to metallurgical incompatibility.Applying a zinc(Zn)coating to steel enables formation of a thin Mg-Zn eutectic phase layer during welding,which promotes strong bonding.However,in joints created with Friction-stir assisted scribe technology(FAST),this Mg-Zn eutectic phase layer occasionally extends from the interface to the surface of the Mg sheet.This phenomenon is attributed to the formation of a liquid-state Mg-Zn eutectic phase,coupled with the distinctive material flow induced by the FAST tool.Microstructural analysis confirmed that the Mg-Zn eutectic phase comprisesα-Mg and the Mg_(21)Zn_(25)intermetallic compound.Lap shear tensile tests revealed that when the Mg-Zn eutectic phase migration pathway aligned with the stir zone boundary,it led to reduced joint strength and premature fracture along the eutectic phase pathway.This indicates that liquid metal embrittlement(LME)occurred during FAST joining of Mg alloy and galvanized steel.These findings highlight the critical importance of controlling tool features and process parameters in FAST welding to prevent LME-related failures in dissimilar Mg/steel assemblies.
基金the financial support from the National Natural Science Foundation of China (No. 52374380)the China Postdoctoral Science Foundation (Nos. 2023M730234, 2024T171126)。
文摘In order to overcome the embrittlement of metastable titanium alloys caused by the precipitation ofωiso phase during aging,regulation of isothermalωprecipitation was investigated in Ti−15Mo alloy.The results show that the sample is brittle when direct aging(A)is applied at 350℃for 1 h after solution treatment(ST).If pre-deformation(D)is performed on the ST sample to induce{332}twins and secondaryα″phase,subsequent aging at 350℃(STDA350)improves the strength to 931 MPa with a good ductility of about 20%maintained.However,when aging is performed at 400℃or 450℃(STDA400/450),the strength can be further improved,but the ductility is dramatically reduced.Atomic-scale characterizations show that the partial collapse ofωphase in the STDA350 sample effectively eliminates aging-induced embrittlement,but complete collapse leads to poor ductility in the STDA400/450 sample.
基金support from the National Natural Science Foundation of China(Grant No.U24A20105 and 52071209)the Major Scientific and Technological Innovation Project of CITIC Group(Grant No.2022ZXKYA06100,with Hongzhou Lu as the principal grant recipient)the Program of Shanghai Academic and Technology Research Leader(Grant No.18XD1402200).
文摘Micropillar compression tests were used to investigate the influence of hydrogen on the deformation behavior and hydrogen embrittlement(HE)of nitrogen-alloyed austenitic stainless steel QN_(2)109.Results indicate that the hydrogen increases the dislocation density,reduces the yield stress,and accelerates the formation and intersection of slip bands,with hydrogen-induced cracks initiating at slip band intersections.X-ray diffraction confirms the absence of martensitic transformation,ruling out the role of martensitic transformation in HE.The micropillar compression technique is highly sensitive for characterizing hydrogen-material interactions,owing to the material’s low hydrogen diffusivity and the small size of its hydrogen-affected zone.These findings align with the hydrogen-enhanced localized plasticity mechanism.
基金supported by the National Science Fund for Distinguished Young Scholars(No.52425404).
文摘This study investigates the influence of hydrogen concentration at grain boundaries on the sensitivity of polycrystalline iron to hydrogen embrittlement using molecular dynamics simulations.These simulations reveal the diffusion behavior of hydrogen atoms at grain boundaries and their consequential impact on the hydrogen embrittlement sensitivity of iron alloys.The findings indicate that as the hydrogen concentration increases,both the yield strength and ultimate tensile strength of Fe-H alloys exhibit a declining trend.Moreover,the capture of hydrogen atoms at the grain boundaries significantly influences the fracture toughness of the material and promotes the formation and propagation of cracks.This study provides a novel theoretical basis for understanding and predicting the hydrogen embrittlement behavior of iron-based materials in hydrogen-rich environments,offering valuable insights for the design and development of Fe alloys with enhanced resistance to hydrogen embrittlement.
基金supported by the National Key Research and Development Program of China(No.2022YFB4003400)the Key Research and Development Program of Zhejiang Province of China(No.2023C01225)the State Key Laboratory of Clean Energy Utilization,China。
文摘Widespread use of green hydrogen is a critical route to achieving a carbon-neutral society,but it cannot be accomplished without extensive hydrogen distribution.Hydrogen pipelines are the most energy-efficient approach to transporting hydrogen in areas with high,long-term demand for hydrogen.A well-known fact is that the properties of hydrogen differ from those of natural gas,which leads to significant variations in the pipeline transportation process.In addition,hydrogen can degrade the mechanical properties of steels,thereby affecting pipeline integrity.This situation has led to two inevitable key challenges in the current development of hydrogen-pipeline technology:economic viability and safety.Based on a review of the current state of hydrogen pipelines,including material compatibility with hydrogen,design methods,process operations,safety monitoring,and standards,this paper highlights key knowledge gaps in gaseous hydrogen pipelines.These gaps include the utilisation of high-strength materials for hydrogen pipelines,design of high-quality hydrogen pipelines,determination of hydrogen velocity,and repurposing of existing natural-gas pipelines.This review aims to identify the challenges in current hydrogen pipelines development and provide valuable suggestions for future research.
基金finncially supported by the National Natural Science Foundation of China(No.52075183)the Guangdong Basic and Applied Research Fundamental(No.2023A1515010692)the Key-Area Research and Development Program of Guangdong Province(Nos.2024B1111080002 and 2020B0404020004).
文摘Austenitic stainless steel(ASS)is a common material used in high-pressure hydrogen systems.Prolonged exposure to high-pressure hydrogen can cause hydrogen embrittlement(HE),raising significant safety concerns.Selective Laser Melting(SLM),known for its high precision,is a promising additive manufacturing technology that has been widely adopted across various industries.Studies have reported that under certain SLM manufacturing conditions and process parameters,the HE resistance of SLM ASS is significantly better than that of conventionally manufactured(CM)ASS,showing great potential for application in high-pressure hydrogen systems.Thus,studying the HE of SLM ASS is crucial for further improving the safety of high-pressure hydrogen systems.This paper provides an overview of the SLM process,reviews the mechanisms of HE and their synergistic effects,and analyzes the HE characteristics of SLM ASS.Additionally,it examines the influence of unique microstructures and SLM process variables on HE of SLM ASS and offers recommendations for future research to enhance the safety of high-pressure hydrogen systems.
基金supported by the Korea Institute for Advancement of Technology(KIAT)grant funded by the Korean Government(MOTIE)(P0023676,HRD Program for Industrial Innovation)the National Research Foundation of Korea(NRF)(No.2021R1A6A3A13045008).
文摘In this study,we investigated the correlation between the pre-strain and hydrogen embrittlement(HE)mechanisms in medium-Mn steel.Intercritically annealed Fe-7Mn-0.2C-3Al(wt.%)steel,which showed a two-phase microstructure comprising α ferrite and γR retained austenite,was used as a model alloy.As the pre-strain level increased from 0%to 45%,the volume fraction of γR gradually decreased owing to the strain-inducedα′martensite transformation accompanied by an increase in dislocation density.The HE resistance decreased with increasing the pre-strain level because the sample with a higher pre-strain level revealed a higher amount of dissolved hydrogen,combined with a more extensive brittle fracture region owing to the enhanced diffusion and permeation of hydrogen from the reduced γR fraction.Ad-ditionally,the H-assisted crack in the sample without pre-strain was initiated and propagated from the γR grains when the strain-induced α′phase was formed,because most of the dissolved hydrogen was concentrated in the γR grains,and these grains were predominantly deformed compared to the other phases.However,the pre-strained sample showed more pronounced multiple H-assisted cracking at the constituent phases,such as α and α′,because it exhibited relatively well-dispersed hydrogen atoms and reduced microstrain localization at the γR grains,due to the reduced γR fraction.
基金support from the China Scholarship Council(CSC No.201700260207)Swedish Iron and Steel Research Office(Jernkontoret)The EIT RawMaterials Upscaling project EndureIT(No.18317)is acknowledged by PH and WM for financial support.
文摘The low-temperature embrittlement limits the service temperature of ferritic and duplex stainless steels.The effects of alloying elements added to Fe-Cr binary system on the low-temperature embrittlement have been reviewed critically.Prior literature on the underlying phase transformation,i.e.,phase separation(PS)and changes of mechanical properties,is surveyed.The available literature indicates that the rate of PS is accelerated by Ni or Co in Fe-Cr binary system.The increased kinetics of PS also lead to an enhanced hardening rate during aging for Ni and Co alloyed Fe-Cr alloys.In low Cr(<17 wt.%)ferritic alloys,the additions of Al or Co can reduce embrittlement because these elements contribute to lowering the driving force for PS.The influence of other alloying elements such as Mo,Cu,Mn,Nb,and Ti is inconclusive but also discussed here.Thermodynamic and kinetic calculations were performed to evaluate current CALPHAD databases and to further investigate the thermodynamic and kinetic reasons for the effect of the additional alloying elements added to Fe-Cr alloy on PS.Some indications were provided for improving physically-based predictions of low-temperature embrittlement as well as opportunities to mitigate the phenomenon by alloying.
基金supported by the National Natural Science Foundation of China Projects under grant[nos.U21A2049,52071220,51871211,51701129 and 51971054]Liaoning Province's project of“Revitalizing Liaoning Talents”(XLYC1907062)+6 种基金the Doctor Startup Fund of Natural Science Foundation Program of Liaoning Province(no.2019-BS-200)the Strategic New Industry Development Special Foundation of Shenzhen(JCYJ20170306141749970)the funds of International Joint Laboratory for Light Alloys,Liaoning BaiQianWan Talents Program,the Domain Foundation of Equipment Advance Research of 13th Five-year Plan(61409220118)National Key Research and Development Program of China under grant[nos.2017YFB0702001 and 2016YFB0301105]the Innovation Fund of Institute of Metal Research(IMR),Chinese Academy of Sciences(CAS),the National Basic Research Program of China(973 Program)project under grant no.2013CB632205the Fundamental Research Fund for the Central Universities under grant[no.N2009006]Bintech-IMR R&D Program[no.GYY-JSBU-2022-009].
文摘In this work,through performing microstructural characterization,tensile testing and failure analysis,the influence of electrochemical hydrogen charging on the microstructure and mechanical behavior of an as-cast Mg-8wt.%Li alloy was investigated.It revealed that after being hydrogen charged at 50 mA/cm2 for respectively 3 h,6 h and 18 h in 0.1 M NaCl solution,obvious HID occurred and the damage degree was gradually increased with the hydrogen charging time.For the sample being hydrogen charged for 3 h,micro pores with the diameter ranging from 10~30µm were formed and preferentially present inα-Mg phase.Moreover,micro cracks with the length ranging from 10~50µm mainly initiated inα-Mg phase,atα-Mg/β-Li interfaces and the peripheries of pores.With the increase of hydrogen charging time,the numbers of pores and cracks were obviously increased.Tensile results revealed that the hydrogen charging can simultaneously decrease the tensile strength and ductility of the alloy.Compared with the uncharged sample,the tensile yield strength,ultimate tensile strength and the elongation ratio to failure were respectively reduced by 5.7%,7.3%,31.7%for the 3h-charged sample and 24.6%,24.8%,67.0%for the 18h-charged sample.Failure analysis indicated that hydrogen charging can induce the brittle cracking of the alloy and the size of brittle cracking region being composed of quasi-cleavage facets and interfacial cracks on the fracture surfaces was increased with the hydrogen charging time.
基金supported by the National Natural Science Foundation of China(Grant Nos.51871211,U21A2049,52071220,51701129 and 51971054)Liaoning Province’s project of“Revitalizing Liaoning Talents”(XLYC1907062)+5 种基金the Doctor Startup Fund of Natural Science Foundation Program of Liaoning Province(No.2019-BS-200)Liaoning BaiQianWan Talents Program,the Domain Foundation of Equipment Advance Research of 13th Five-Year Plan(61409220118)National Key Research and Development Program of China(Grant Nos.2017YFB0702001 and 2016YFB0301105)the Innovation Fund of Institute of Metal Research(IMR),Chinese Academy of Sciences(CAS)the National Basic Research Program of China(973 Program)(Grant No.2013CB632205)the Fundamental Research Fund for the Central Universities(Grant No.N2009006).
文摘Combined with the hydrogen pre-charging and tensile testing methods,the effect of charged hydrogen content on the microstructure and mechanical behavior of an as-forged Ti–6Al–4V alloy was investigated.After performing hydrogen charging for 2,4,6,8 and 10 h at a constant cathodic current density value of 75 mA/cm^(2) in a corrosion medium of 3.5 wt.%NaCl solution,the hydrogen contents in the charged samples increased gradually from 73×10^(−4) to 230×10^(−4) wt.%.When the hydrogen content was less than 190×10^(−4) wt.%,the charged hydrogen atoms were present as the solute atoms in the matrix,resulting in the enhanced tensile strength due to the solid solution strengthening of hydrogen atoms.Moreover,the reduced axial ratio c/a for α-Ti matrix due to the hydrogen dissolution was beneficial to improving the ductility of the hydrogenated samples.The critical hydrogen content for simultaneously improving the ductility and strength is determined to be 99×10^(−4)wt.%.When the hydrogen content was 230×10^(−4)wt.%,a small number of δ-TiHx hydrides and micro cracks formed in the localized areas of α-Ti matrix,resulting in the simultaneous decrease of ductility and strength.
基金support from the National Natural Science Foundation of China(No.52130102)the National Key Research and Development Program of China(No.2019YFA0209900)+5 种基金the Research Grants Council of Hong Kong(No.R7066–18)the Guangzhou Municipal Science and Technology Project(No.202007020007)the Guangdong Basic and Applied Basic Research Foundation of China(No.2020B1515130007)Lunhua He and Mingxin Huang acknowledge the support from the International Partnership Program of the Chinese Academy of Sciences(No.113111KYSB20190029)the key program of the Chinese Academy of Sciences(CAS)China Spallation Neutron Source(CSNS)is acknowledged for supporting neutron diffraction experiments using the General Purpose Powder Diffractometer(GPPD).
文摘Hydrogen embrittlement(HE)in 2 GPa-grade press-hardened steel(PHS)has posed a great risk to its lightweighting application in automotive crash-resistant components.While conventional slow strain rate tensile tests show that the precharged hydrogen concentration of 3.5 wppm induces a severe loss in strength and ductility,the high strain rate tests conducted at 1–103 s−1 that simulate the crash condition demonstrate no loss in strength and a minimal loss in ductility.Such strain rate dependency cannot be exclusively explained via hydrogen diffusion and redistribution to susceptible prior austenite grain boundaries,as the tensile testing of precharged samples with jumping strain rates offers a sufficient redistribution period at slow-strain-rate loading,but does not necessarily lead to a high level of HE afterwards.Detailed fractography analysis acknowledges that hydrogen-induced microcracks nucleated within early deformation stages are directly responsible for the high HE susceptibility of all test conditions.A phase-field simulation comprising 2 GPa-grade PHS's microstructure features and the hydrogen diffusion under tested loading conditions is applied.The calculation reveals that the hydrogen redistribution behavior is spatially confined to the crack tip areas but to a much greater extent.It thus facilitates continuous crack growth following the main crack with minimal plastic deformation and avoids branching to form secondary cracks.The combined experiments and modeling highlight the vital role of microcracks in the HE performance of 2 GPa-grade PHS,upon which the safety factor of HE in high-strength martensitic steels shall be established.
基金financially supported by the National Natural Science Foundation of China(Nos.U21A2044 and 52201060)Science Center for Gas Turbine Project(No.P2022-B-Ⅳ-008-001)China Postdoctoral Science Foundation(Nos.BX20220035 and 2022M710347).
文摘Direct evidence of hydrogen-assisted crack nucleation and propagation associated with the δ phase in the selective laser melted GH4169 superalloy was obtained.The analysis of hydrogen trapping sites using thermal desorption spectroscopy revealed that the δ phase exhibits strong hydrogen capture capability,with a hydrogen desorption activation energy of 35.45±2.51 kJ/mol.In addition,spatially resolved hydrogen mapping conducted by scanning Kelvin probe force microscopy and hydrogen microprint technique provided further evidence for the δ phase as a deep hydrogen trapping site.The atomic-scale characterization sufficiently reveals the deformation mechanism of the δ phase induced by dislocation accumulation.Hydrogen-promoted dislocation slip localization facilitates the formation of microvoid defects in the δ phase,which is the main reason for the δ phase fracture,and induces intergranular and transgranular cracks.
基金financially supported by the National Natural Science Foundation of China(Nos.U21A2044 and 52201060)CGN-USTB Joint Research and Development Center for Advanced Energy Materials and Service Safet.
文摘The effects of the Laves-decorated dendrite structure on the hydrogen-assisted cracking behavior of the SLM-718 alloy were investigated.The Laves phase exhibits a hydrogen desorption activation energy of 47.67±7.85 kJ mol^(-1).The results of in situ scanning Kelvin probe force microscopy and hydrogen microprint technique provide direct evidence of the hydrogen trapping by the Laves phase.The high-density dendrite walls consisting of entangled dislocations exhibit an inhibitory effect on hydrogen diffusion.Atomic-scale characterization reveals that dislocation stacking at the Laves/γ-matrix interface induces the formation of dislocation defects and a high-stress concentration in the Laves phase.The presence of hydrogen further promotes the formation of micropore defects and the embrittlement of the Laves phase.Hydrogen-promoted dislocation slip localization and hydrogen-induced reduction of interatomic bonding are the primary reasons for the Laves phase fracture and debonding at the Laves/γ-matrix interface.The coalescence of micropore defects ultimately leads to hydrogen-induced crack formation.
基金supported by Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.SJCX24_2524)National Natural Science Foundation of China(No.52005228).
文摘Hydrogen dissolved from the moisture or the wire filler is formed on the surface of welded joint due to the driving of high-energy heat source.The diffused hydrogen in the welded joint could cause hydrogen embrittlement(HE).The important factors determining the HE resistance of welded joints are microstructure style,dislocation distribution,grains characteristics,precipitate particle,and residual stress.Different welding technologies show various heat sources and heat cycles,which result in different characteristics of fusion zone and heat-affected zone.Thus,the HE fracture behavior of welded joint produced by different welded technologies differs greatly.The current stage of HE behavior of welded joint was reviewed to provide fundamental reference for the scientists and engineers engaging in welding.The appearance of hydrogen atoms in the surface or interior of welded joint could weaken the bonding strength and change the fracture mode from ductile to sudden brittle fracture.Generally,the controlling of filler wire and heat input is a practical route to obtain the excellent welded joint with high HE resistance.The inhibition of hydrogen diffusion via the formation of fine coating and the aggregation of hydrogen atoms via the control of microstructure and precipitates are the effective routes to improve HE resistance.
基金supported by the Natural Science Foundation of Shanghai(No.23ZR1421700).
文摘Hydrogen embrittlement(HE)remains a critical challenge for high-strength steels.This study comparatively investigates the HE behavior and hydrogen diffusion characteristics of a vanadium-micro-alloyed 42CrNiMoV steel against conventional 40CrNiMo steel through slow strain rate testing(SSRT),hydrogen thermal desorption,and hydrogen permeation measurements.The 42CrNiMoV steel demonstrated better mechanical properties and improved HE resistance under SSRT with both hydrogen pre-charged and in situ charging conditions.Microstructural analysis revealed that vanadium micro-alloying leads to grain refinement and reduces hydrogen diffusivity through vanadium carbides.Fractographic investigations revealed the environment-dependent fracture mechanisms,transitioning from ductile-to brittle-dominated failure modes under different hydrogen-charging conditions.These findings validate that vanadium micro-alloying represents a promising,cost-effective strategy for developing hydrogen-resistant high-strength steels,while emphasizing the crucial need for rigorous hydrogen ingress control in practical applications.
文摘In this study,an alternative modelling approach for absorbed hydrogen stress corrosion cracking(SCC)is proposed,with hydrogen-enhanced decohesion(HEDE)identified as the key failure mechanism.All analyses have been performed by utilising only ABAQUS standard elements,COH2D4T and CPE4T,already available within the software and without the need to develop external subroutines.The study also tends to highlight the criticality of implementing a correct Traction Separation Law(TSL)curve to simulate the hydrogen diffusion within the specimen and using the concept of dynamic hydrogen penetration by continuously updating the hydrogen concentration boundary conditions as the crack propagates.In conclusion,this study successfully demonstrated that standard software elements(COH2D4T and CPE4T)can effectively model physical problems and crack velocity propagation without custom subroutines.It emphasized that while the specific shape of the Traction-Separation Law(TSL)is less critical,its correct implementation is vital for simulating dynamic hydrogen coverage.Crucially,excluding this dynamic coverage—a common practice—risks significantly underestimating crack propagation speed.Although results incorporating dynamic coverage aligned well with experimental data,minor discrepancies are likely due to unmodeled factors like material property variations,hydrogen trapping,temperature,and granular microstructure,which are proposed for future research.
基金supported by the National Key R&D Program of China(No.2022YFB4600700)The authors gratefully acknowledge the support from the Shenzhen Science and Technology Innovation Commission through awards(Nos.JCYJ20210324104414040,20220530114400001,and 20220815150609002)+2 种基金Shuai Wang acknowledges support from the Key-Area Research Project of the Guangdong Province Department of Education(No.2022ZDZX3021)the High Level of Special Funds(Nos.G03034K001 and G03034K003)Jiang Yi acknowledges the support from the Guangdong Basic and Applied Basic Research Foundation through awards(No.2024A1515010358).
文摘Powder bed fusion-laser beam with metals(PBF-LB/M)can be used to manufacture intricate NiTi com-ponents.However,the ductility of NiTi alloys fabricated by PBF-LB/M is generally∼20%less than those made via conventional processes.Although many heat treatment methods have been proposed,solving this issue has been proven difficult.An intractable problem is the brittleness of PBF-LB/M-fabricated NiTi after solid-solution treatment at 1000℃.By investigating the microstructural and fractography change after heat treatment in the range of 100-1000℃,this study found that this ductile-to-brittle transition stems from abnormal oxygen-containing Ti-rich precipitates being generated in the PBF-LB/M fabricated Ni-rich NiTi.We identified laser processing-induced local oxygen segregation and tiny TiO2(B)particles at the fusion and grain boundaries.During the heat treatment at temperatures above 700℃,these ox-ides decompose due to their low thermal stability.After this decomposition,most oxygen diffuses into the matrix,with titanium remaining in local regions.This process enriches titanium in the interfaces,forming a brittle oxygen-rich Ti_(2)Ni network that is known to hinder the recrystallization process in heat treatment.Furthermore,when subjected to external loading,these precipitates can induce high misfit levels and local distortion,resulting in brittle fractures along the interfaces.Based on these results,we also propose approaches to avoid high-temperature-induced embrittlement in Ni-rich NiTi.
基金supported by the China Postdoctoral Science Foundation(No.2023M740973)the Shenzhen Polytechnic University Research Fund,China(No.6023310017K)the National Natural Science Foundation of China(Nos.52071088 and 51871064).
文摘The effect of rare-earth cerium on impurity P-induced embrittlement for an advanced SA508Gr.4N reactor pressure vessels steel is investigated by virtue of microstructural characterization,Auger electron spectroscopy(AES),and spin-polarized density functional theory(DFT)calculations.The ductile-to-brittle transition temperatures(DBTTs)are evaluated by Charpy impact testing,and grain boundary segregation(GBS)of P is quantified by AES.Trace addition of Ce can effectively reduce GBS level of P,thereby substantially decreasing the embrittlement induced by P.A linear correlation between DBTT(℃)and GBS level of P(Cp,at.%)is observed for both undoped and Ce-doped samples,being expressed as DBTT=13.13C_(p)-335.70(undoped)and DBTT=12.67C_(p)-350.78(Ce-doped).In the absence of GBS of P,the incorporation of Ce appears to play a pivotal role in augmenting the intrinsic toughness.These results imply that the impact of Ce on impurity P-induced embrittlement may be attributed to a combination of increasing the intrinsic toughness and lowering GBS of P.DFT calculations indicate that there is a negligible interaction between Ce and P in the ternary alloy,and thus GBS of P and Ce is mainly site-competitive.
