A few derivatives of calixarenes have been synthesized and characterized by IR, ^1H NNtR, thermal and elemental analysis. The transport of potassium or calcium ion through the liquid membrane, in which the derivatives...A few derivatives of calixarenes have been synthesized and characterized by IR, ^1H NNtR, thermal and elemental analysis. The transport of potassium or calcium ion through the liquid membrane, in which the derivatives act as carriers, has been studied. The electron-effect of the substituent on the upper rim of calixarene possesses important effect on the net transport of metal ions. The p- tert-butylcalix[4]arene is the best carrier of calcium ion, compared with p-tert-calix[4]arene（n = 4, 6, 8）. The ptert-butylcalix[4]arene acid is better than p-tert-butylcalix [4]arene. The calixr43crown is the best carrier of calcium ions of all the carriers. The pH gradient between the source and receiving phase, and the concentration of K^＋ , Ca^2＋ ions in the source phase affect mainly transport. After the transport, the pH value of the source phase is found to be decreased, once the calix [n ] arene derivatives act as carrier. But it is not the case for the calix[n] crowns. It might be interpreted as the result of their different mechanisms.展开更多
文摘A few derivatives of calixarenes have been synthesized and characterized by IR, ^1H NNtR, thermal and elemental analysis. The transport of potassium or calcium ion through the liquid membrane, in which the derivatives act as carriers, has been studied. The electron-effect of the substituent on the upper rim of calixarene possesses important effect on the net transport of metal ions. The p- tert-butylcalix[4]arene is the best carrier of calcium ion, compared with p-tert-calix[4]arene（n = 4, 6, 8）. The ptert-butylcalix[4]arene acid is better than p-tert-butylcalix [4]arene. The calixr43crown is the best carrier of calcium ions of all the carriers. The pH gradient between the source and receiving phase, and the concentration of K^＋ , Ca^2＋ ions in the source phase affect mainly transport. After the transport, the pH value of the source phase is found to be decreased, once the calix [n ] arene derivatives act as carrier. But it is not the case for the calix[n] crowns. It might be interpreted as the result of their different mechanisms.
