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主链含电子传输型基团的可溶性PPV发光特性研究 被引量:6
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作者 印寿根 杨晓辉 +4 位作者 徐征 华玉林 张福强 黄文强 徐叙瑢 《功能高分子学报》 CAS CSCD 1999年第2期129-131,共3页
经由Witig-Horner反应合成了一种可溶的PPV主链含有电子传输基团的新型结构电子聚合物。该低聚物的Mw=1000、Td=270℃,可溶于氯仿和四氢呋喃。构造了最简单的三明治式电致发光器件ITO/O-PPV(8... 经由Witig-Horner反应合成了一种可溶的PPV主链含有电子传输基团的新型结构电子聚合物。该低聚物的Mw=1000、Td=270℃,可溶于氯仿和四氢呋喃。构造了最简单的三明治式电致发光器件ITO/O-PPV(80nm)/Al,其电致发光和光致发光光谱基本一致。该器件与同样结构的PPV相比其EL表现出在509nm处单一的宽峰,而PPV的器件为520nm和550nm的双峰。另外由于主链上含有电子传输特性的二唑基团及聚合物材料的分子量较小,器件的量子效率达到0.13%。 展开更多
关键词 PPV 低聚物 聚对苯撑乙烯 电致发光材料
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三苯基膦氧基团在合成高性能有机电致发光材料中的应用
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作者 姜鸿基 张庆维 《化学进展》 SCIE CAS CSCD 北大核心 2016年第10期1515-1527,共13页
有机电致发光技术在通讯、信息、显示和照明等领域显现出巨大的商业应用前景,十几年来一直是光电信息领域的研究热点之一。相对于无机电致发光材料,有机电致发光材料具有许多优点。近年来,三苯基膦氧基团在合成高性能有机电致发光材料... 有机电致发光技术在通讯、信息、显示和照明等领域显现出巨大的商业应用前景,十几年来一直是光电信息领域的研究热点之一。相对于无机电致发光材料,有机电致发光材料具有许多优点。近年来,三苯基膦氧基团在合成高性能有机电致发光材料方面的研究吸引了大批研究者的关注。由于磷原子自身性质,可以形成5个共价键,所以膦氧基团极易和其他基团连接形成以其为核的衍生物。由于氧原子具有很强的电负性,这就使膦氧结构高度极化并具有强的吸电子性。吸电子的膦氧基团连接苯环形成的三苯基膦氧单元也具有较强的吸电子性,其对所形成的化合物的能级结构也会产生明显影响。本文从材料合成的角度综述了三苯基膦氧基团在合成高性能有机电致发光材料中的应用方面所取得的最新研究进展,重点介绍了三苯基膦氧基团在合成高性能磷光二极管主体材料、电子传输材料和单分子电致发光材料等方面的应用。最后讨论了三苯基膦氧基团在上述领域应用过程中所存在的问题和功能拓展方向,并对下一步需要研究的热点问题作了展望。 展开更多
关键词 三苯基膦氧基团 电致发光 主体材料 白光 电子传输材料
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1,4-二[5-(4-羟基苯基)-1,3,4-噁二唑-2-基]苯的合成及其光谱特征
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作者 陈多谋 胡海强 《琼州学院学报》 2009年第5期46-48,共3页
通过酰氯化、二酰肼化和脱水关环反应,合成1,4-二[5-(4-羟基苯基)-1,3,4-噁二唑-2-基]苯,关环反应产率达到78.9%,产物结构经核磁氢谱得到了表征.探讨了反应条件对合成噁二唑衍生物的影响,研究了它们的紫外吸收和光致发光性能.研究结果表... 通过酰氯化、二酰肼化和脱水关环反应,合成1,4-二[5-(4-羟基苯基)-1,3,4-噁二唑-2-基]苯,关环反应产率达到78.9%,产物结构经核磁氢谱得到了表征.探讨了反应条件对合成噁二唑衍生物的影响,研究了它们的紫外吸收和光致发光性能.研究结果表明:目标化合物具有强烈的紫外吸收和光致发光性能,其最大紫外吸收波长在286.8nm,最大荧光发射波长在375nm.作为电致磷光中间体的对称2,5-二苯基-1,3,4-噁二唑中引入羟基对,进一步连接其它功能基合成新型的有机环金属电致磷光材料具有重要的意义. 展开更多
关键词 1 3 4-噁二唑 电子传输材料 合成
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固氮酶中的电子传递 被引量:2
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作者 黄静伟 张鸿图 +1 位作者 万惠霖 蔡启瑞 《生物化学与生物物理进展》 SCIE CAS CSCD 北大核心 1996年第1期18-20,共3页
提出改进的二步ATP驱动的电子传递机理,对还原剂和MgATP都充足或其中有一种不充足的情况下固氮酶体系的EPR信号变化作了合理的解释.
关键词 固氮酶 电子传递
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High-performance carbon-based perovskite solar cells through the dual role of PC_(61)BM
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作者 Weili Fan Zhe Wei +5 位作者 Zhenyun Zhang Fazheng Qiu Chaosheng Hu Zhichao Li Minxuan Xu Junjie Qi 《Inorganic Chemistry Frontiers》 2019年第10期2767-2775,共9页
Carbon-based HTM-free perovskite solar cells(C-PSCs)have received extensive attention due to their low cost and high stability.However,some issues with regard to their relatively low efficiency and toxicity still need... Carbon-based HTM-free perovskite solar cells(C-PSCs)have received extensive attention due to their low cost and high stability.However,some issues with regard to their relatively low efficiency and toxicity still need to be addressed before their commercialization.For the first time,a high-efficiency carbonbased planar perovskite solar cell was prepared based on TiO_(2)combined with PC_(61)BM as the electrontransport layer.PC_(61)BM could passivate the interface between the perovskite film layer and the TiO_(2)film layer;at the same time,it also exhibited the function of an additive to improve the crystal quality of the perovskite.Planar C-PSC was successfully fabricated with an open voltage(Voc)of 1.005 V,which represented~2.6%enhancement compared to that of the device with a mesoporous structure,and power conversion efficiency(PCE)of 14.37%.Moreover,stability was also investigated;3%degradation appeared in the PCE of the planar C-PSC after being stored for 1900 h in the dark.This methodology of introducing PC_(61)BM to reduce the recombination probability of electrons and holes and improve the crystal quality of perovskites has universal significance for the further development of planar C-PSCs. 展开更多
关键词 perovskite film layer electron transport layer planar perovskite solar cell crystal quality improvement electrontransport layerpc bm interface passivation high performance carbon based perovskite solar cells pc bm
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Influence of Electroacupuncture on COX Activity of Hippocampal Mitochondria in Senescence-accelerated Mouse Prone 8 Mice
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作者 Peng Jing Zeng Fang +4 位作者 He Yu-heng Tang Yong Yin Hai-yan Yu Shu-guang Feng Xiao-ming 《Journal of Acupuncture and Tuina Science》 2014年第4期199-202,共4页
Objective: To observe the effect of electroacupuncture(EA) on cytochrome c oxidase(COX) activity of hippocampal mitochondria in senescence-accelerated mouse prone 8(SAMP8) mice, and to explore the EA mechanism on Alzh... Objective: To observe the effect of electroacupuncture(EA) on cytochrome c oxidase(COX) activity of hippocampal mitochondria in senescence-accelerated mouse prone 8(SAMP8) mice, and to explore the EA mechanism on Alzheimer disease(AD) in improving energy metabolic disorder. Methods: Twelve SAMP8 mice were randomly divided into a model group and an EA group, with six in each group. Six senescence-accelerated mouse resistance 1(SAMR1) mice were prepared as blank group. Mice in the EA group received EA on Baihui(GV 20) and Yongquan(KI 1), once a day for 7 d as a course, altogether 3 courses with one day interval between two courses. Mice in the model group and the blank group were manipulated and fixed as those in the EA group. After interventions, Morris water maze was employed to test spatial learning and memory ability to evaluate EA effect; spectrophotometry was used to detect the activity of hippocampal mitochondria COX. Results: Compared with the blank group, mean escape latencies of the EA group and model group were prolonged significantly in Morris water maze tests(P<0.01), the residue duration in the former platform quadrant significantly decreased(P<0.01). Compared with the model group, mean escape latencies on 1 d, 2 d and 3 d of the EA group were significantly reduced(P<0.05), and those on 4 d and 5 d continued the decreasing tendency(P<0.01), the residue duration on the former platform quadrant was significantly prolonged(P<0.05). The COX activity tests showed that, compared with the blank group, COX activities of the model group and the EA group were significantly decreased(P<0.01); compared with the model group, COX activity of the EA group was significantly elevated(P<0.01). Conclusion: It's plausible that EA improves AD learning and memory ability by increasing mitochondria COX activity, protecting the structure and function, and improving energy metabolism. 展开更多
关键词 ELECTROACUPUNCTURE Acupuncture Therapy AIzheimer Disease electrontransport Complex IV MICE
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