Using a transient thermoreflectance （TTR） technique, several Au films with different thicknesses on glass and SiC substrates are measured for thermal characterization of metMlic nano-films, including the electron ph...Using a transient thermoreflectance （TTR） technique, several Au films with different thicknesses on glass and SiC substrates are measured for thermal characterization of metMlic nano-films, including the electron phonon coupling factor G, interfazial thermal resistance R, and thermal conductivity Ks of the substrate. The rear heating-front detecting （RF） method is used to ensure the femtosecond temporal resolution. An intense laser beam is focused on the rear surface to heat the film, and another weak laser beam is focused on the very spot of the front surface to detect the change in the electron temperature. By varying the optical path delay between the two beams, a complete electron temperature profile can be scanned. Different from the normally used single-layer model, the double-layer model involving interfaciM thermal resistance is studied here. The electron temperature cooling profile can be affected by the electron energy transfer into the substrate or the electron-phonon interactions in the metallic films. For multiple-target optimization, the genetic algorithm （GA） is used to obtain both G and R. The experimental result gives a deep understanding of the mechanism of ultra-fast heat transfer in metals.展开更多
Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic str...Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic structure. In this work, Sb^(3+)/Te^(4+)ions doped Zn-based halide single crystals(SCs) with two STEs emissions have been synthesized and the possibility of its anti-counterfeiting application was explored.Further, the relationship between the strength of electron-phonon coupling and photoluminescence quantum yields(PLQYs) for STEs in a series of metal halides has been studied. And the semi-empirical range of the Huang-Rhys factors(S) for metal halides with excellent photoluminescence(PL) property has been summarized. This work provides ideas for further research into the relationship between luminescence performance and electron-phonon coupling of metal halides, and also provides a reference for designing the metal halides with high PLQYs.展开更多
Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoti...Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China.展开更多
Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these mat...Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these materials isfrequently constrained by heat generation during light absorption,resulting in significant thermal losses.Most offerroelectric films produce photocurrent and thermocurrent with opposite polarity,thus weakening the coupledphoto-thermoelectric output of the devices.Here we report on a LaNiO_(3)/BiMn_(2)O_(5)(BMO)/ITO ferroelectric film toproduce photocurrent and thermocurrent with the same polarity.The polarity of the photocurrent generated bythe BMO film is shown to be determined solely by the direction of spontaneous polarization,overcoming thedetrimental effect of Schottky barrier for energy harvesting in device.We propose a new strategy to enhance thecoupling factor,thereby offering valuable new insights for optimizing the utilization of ferroelectric materials inboth light and heat energy applications.展开更多
Both the complex geometrical morphology of rough-walled rock fractures and the nonlinearity of fluid flow contribute to resistance in fluid flow through rock fractures.The interactions of the shear-flow process furthe...Both the complex geometrical morphology of rough-walled rock fractures and the nonlinearity of fluid flow contribute to resistance in fluid flow through rock fractures.The interactions of the shear-flow process further complicate the characterisation of flow behaviours in rock fractures.In this study,an improved friction factor model involving both the effects of viscous and inertial forces is presented based on the Forchheimer equation.The model incorporates two key variables,i.e.Reynolds number and relative roughness,which reflect the effects of flow regimes and fracture roughness,respectively.The changes in geometrical parameters induced by shearing are considered,with the peak asperity height predicted through a correlation with post-peak roughness degradation.The hydraulic aperture during shearing is estimated using a suggested equation that accounts for the mobilised contact area ratio and variable aperture distribution.The parametric sensitivity analysis reveals that shear-induced changes in fracture geometry enhance the flow nonlinearity in rock fractures.The model performs well in predicting the friction factor based on two validation criteria.Then,the proposed friction factor model is incorporated into the three-dimensional distinct element code(3DEC)in the form of the Darcy-Weisbach equation.Coupled with the numerically implemented mechanical model and hydraulic aperture prediction model,numerical simulations of coupled shear-flow processes in single rock fractures are conducted.The simulation outcomes are validated through comparison with the experimental results,showing acceptable agreement and demonstrating that the numerical model is capable of accurately evaluating the hydro-mechanical coupling behaviour during the shearing of rock fractures.展开更多
Rural resilience,a core capability for addressing systemic risks and enabling sustainable development,is increasingly vital to promoting urban-rural integrated development and rural revitalization strategies.However,c...Rural resilience,a core capability for addressing systemic risks and enabling sustainable development,is increasingly vital to promoting urban-rural integrated development and rural revitalization strategies.However,current research lacks exploration of the collaborative mechanisms between rural economic resilience(RER)and rural social resilience(RSR)in ecologically vulnerable areas.Based on the practical context of rural sustainable development in such regions,this study investigates the interaction between RER and RSR from a resilience coordination perspective.In this paper,a rural resilience evaluation framework for collaborative development of economic and social resilience was established.By employing the coupling coordination degree model,obstacle degree model,and equilibrium entropy model,this paper examines the synergies,constraints,and potential of rural resilience subsystems in Jinchang City,Gansu Province,China,in 2020.The results reveal that:1)RER contributes to RSR by stabilizing the economy,enhancing community adaptability,and driving modernization.In turn,RSR strengthens RER by mitigating instability,building social capital,and fostering confidence—together forming a mutually reinforcing coupling mechanism.2)The rural economic and social resilience level in Jinchang City remains generally low with spatially clustered patterns,while the coupling coordination degree is at an intermediate level overall,with 62.59%of villages exhibiting unbalanced development between rural economic and social resilience.3)RER and RSR demonstrate synergistic degradation in ecologically vulnerable areas,where low-level rural economic and social resilience induce integrated systemic deterioration.4)Considering the unbalanced development of rural economic and social resilience in ecologically fragile areas,differentiated coordination pathways are proposed for three village typologies:RER-lagging villages,RSR-lagging villages,and villages where RER and RSR develop synchronously but lack effective coordination.These findings offer spatial governance strategies and practical guidance for enhancing rural resilience and advancing sustainable development in ecologically vulnerable regions.展开更多
A new calculation formula of THM coupling stress intensity factor was derived by the boundary collocation method, in which an additional constant stress function was successfully introduced for the cracked specimen wi...A new calculation formula of THM coupling stress intensity factor was derived by the boundary collocation method, in which an additional constant stress function was successfully introduced for the cracked specimen with hydraulic pressure applied on its crack surface. Based on the newly derived formula, THM coupling fracture modes （including tensile, shear and mixed fracture mode） can be predicted by a new fracture criterion of stress intensity factor ratio, where the maximum axial load was measured by self-designed THM coupling fracture test. SEM analyses of THM coupling fractured surface indicate that the higher the temperature and hydraulic pressure are and the lower the confining pressure is, the more easily the intergranular （tension） fracture occurs. The transgranular （shear） fracture occurs in the opposite case while the mixed-mode fracture occurs in the middle case. The tested THM coupling fracture mechanisms are in good agreement with the predicted THM coupling fracture modes, which can verify correction of the newly-derived THM coupling stress intensity factor formula.展开更多
The coupling model of major influence factors such state affecting the chloride diffusion process in concrete is as environmental relative humidity, load-induced crack and stress discussed. The probability distributio...The coupling model of major influence factors such state affecting the chloride diffusion process in concrete is as environmental relative humidity, load-induced crack and stress discussed. The probability distributions of the critical chloride concentration Cc, the chloride diffusion coefficient D, and the surface chloride concentration Cs were determined based on the collected natural exposure data. And the estimation of probability of corrosion initiation considering the coupling effects of influence factors is presented. It is found that the relative humidity and curing time are the most effective factors affecting the probability of corrosion initiation before and after 10 years of exposure time. At the same exposure time, the influence of load-induced crack and stress state on the probability of corrosion initiation is obvious, in which the effect of crack is the most one展开更多
This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker...This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker electron-phonon coupling in perovskite has been achieved by introducing the structurally soft cyclohexane methylamine(CMA^(+))cation,which could serve as a damper to alleviate the mechanical stress caused by lattice oscillations,compared to the rigid phenethyl methylamine(PEA^(+))analog.It demonstrates a significantly lower non-radiative recombination rate,even though the two types of bulky cations have similar chemical passivation effects on perovskite,which might be explained by the suppressed carrier capture process and improved lattice geometry relaxation.The resulting PSCs achieve an exceptional power conversion efficiency(PCE)of 25.5%with a record-high opencircuit voltage(V_(OC))of 1.20 V for narrow bandgap perovskite(FAPbI_(3)).The established correlations between electron-phonon coupling and non-radiative decay provide design and screening criteria for more effective passivators for highly efficient PSCs approaching the Shockley-Queisser limit.展开更多
The transmission of transverse vibrational energy of a vertically rigid beam plate coupled structure is analyzed to get the theoretical results of coupling loss factor(CLF), a very important parameter in statistical ...The transmission of transverse vibrational energy of a vertically rigid beam plate coupled structure is analyzed to get the theoretical results of coupling loss factor(CLF), a very important parameter in statistical energy analysis(SEA). The modal analysis method is used to discuss the vibration energy of the typical model, as well as the power flow between the two subsystems. Furthermore, the resolution to the coupling loss factor is also derived and compared with the measured values. The analytical results of the coupling loss factor agree with the measured ones fully, this new resolution is significant for the application of SEA.展开更多
Within the linear framework,the Modal Electromechanical Coupling Factor(MEMCF)is an important indicator to quantify the dynamic conversion of mechanical energy and electrical energy of piezoelectric structures.It is a...Within the linear framework,the Modal Electromechanical Coupling Factor(MEMCF)is an important indicator to quantify the dynamic conversion of mechanical energy and electrical energy of piezoelectric structures.It is also an important tool to guide the piezoelectric damping design of linear structures.Advanced aircraft often fly in maneuvers,and the variable working conditions induce drastic changes in the load level on structures.Geometric and contact nonlinearities of thin-walled structures and joint structures are often activated.To achieve a good vibration reduction effect covering all working conditions,one cannot directly use linear electromechanical coupling theory to instruct the piezoelectric damping design for nonlinear structures.Therefore,this paper defines the Nonlinear Modal Electromechanical Coupling Factor(NMEMCF)and proposes the corresponding numerical method for the first time to quantitatively evaluate the electromechanical coupling capability of nonlinear piezoelectric structures.Three candidate definitions of the NMEMCF are given,including two frequency definitions and one energy definition.The energy definition is the most promising one.It is not only applicable to both conservative and dissipative nonlinear structures but also compatible with the linear MEMCF.In addition,based on the energy formula,the NMEMCF can be obtained by only performing one nonlinear modal analysis in the open-circuit state.The analytical findings and the numerical tool are validated against two piezoelectric structures with different types of nonlinearities.A strong correlation among the NMEMCF,geometric parameters,and energy dissipation is observed.The results confirm that the proposed NMEMCF captures the physics of the electromechanical coupling phenomenon associated with nonlinear piezoelectric structures and can be used as an essential design indicator of piezoelectric damping,especially for variable working conditions.展开更多
The Taihang Mountains in North China are an important carbon-water ecosystem service supply area.Understanding the coupling effect and influencing mechanisms of mountain carbon sequestration as well as water conservat...The Taihang Mountains in North China are an important carbon-water ecosystem service supply area.Understanding the coupling effect and influencing mechanisms of mountain carbon sequestration as well as water conservation is essential for regional eco-logical restoration and sustainable development.In this study,we utilized models such as the coupled coordination degree model,the random forest and Geodetector to analyze the spa-tio-temporal changes as well as driving factors of carbon sequestration-water conservation coupling coordination in the Taihang Mountains.The results show that:(1)From 1990 to 2020,the carbon sequestration and water conservation capacity of the Taihang Mountains exhibited a spatial pattern with higher values in the southeast and central regions,while lower values in the northwest region.(2)The average coupling coordination degree from 1990 to 2020 was O.23,which was overall low,with a fluctuating decreasing-rising-decreasing trend over time.The coupling coordination degree exhibited a pattern that is high in the middle and low in the periphery,with a fluctuating distribution that initially decreases and then increases with the increasing altitude.The overall trend of coupling coordination is degradation,with concen-trated degradation in the northwest mountainous regions.(3)Precipitation and soil texture were identified as the main driving factors influencing coupling coordination,with the interac-tion between precipitation and soil sand content showing the strongest explanatory power,while that among topography,vegetation and human activities had relatively low explanatory power.Therefore,enhanced protection and the continuous monitoring of vegetation and soil environments in the Taihang Mountains are essential,with particular emphasis on ecological restoration in areas experiencing a persistent degradation of carbon-water coupling.This study can provide assistance in monitoring and managing carbon sink and water resources in the mountains,meanwhile mitigating potential adverse impacts on human well-being.展开更多
Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. T...Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. The measured data proved that the simulated results are reliable. The effects of preheating time, thermal cycling times, and empty package time on steel temperature are calculated, an ideal preheating time is provided, besides, based on the analysis of a single factor and use the nonlinear analysis method, a steel temperature compensating model with di- versified coupling factors is proposed, with the largest error of the present coupling model at 1. 462 ~C, and the er- rors between actual and target steel temperature in tundish after the model is applied to practical production are basi- cally controlled within -4-6 ~C, which can meet the accuracy of the manufacturer and has a practical guiding significance for the production in steelmaking workshops.展开更多
We have investigated the transverse mode pattern and the optical field confinement factor of gallium nitride （GaN） laser diodes （LDs） theoretically. For the particular LD structure, composed of approximate 4 μm t...We have investigated the transverse mode pattern and the optical field confinement factor of gallium nitride （GaN） laser diodes （LDs） theoretically. For the particular LD structure, composed of approximate 4 μm thick n-GaN substrate layer, the maximum optical confinement factor was found to be corresponding to the 5^th order transverse mode, the so-called lasing mode. Moreover, the value of the maximum confinement factor varies periodically when increasing the n-side GaN layer thickness, which simultaneously changes and increases the oscillation mode order of the GaN LD caused by the effects of mode coupling. The effects of the thickness and the average composition of Al in the AlGaN/GaN superlat.tice on the optical confinement factor are also presented. Finally, the mode coupling and optimization of the layers in the GaN-based LD are discussed.展开更多
The electron-phonon interaction can reveal the microscopic mechanism of heat transfer in metals.The two-step heat conduction considering electron-phonon interaction has become an effective theoretical model for extrem...The electron-phonon interaction can reveal the microscopic mechanism of heat transfer in metals.The two-step heat conduction considering electron-phonon interaction has become an effective theoretical model for extreme environments,such as micro-scale and ultrafast processes.In this work,the two-step heat transfer model is further extended by considering the Burgers heat conduction model with the secondorder heat flux rate for electrons.Then,a novel generalized electron-phonon coupling thermoelasticity is proposed with the Burgers electronic heat transfer.Then,the problem of one-dimensional semi-infinite copper strip subject to a thermal shock at one side is studied by the Burgers two-step(BTS)model.The thermoelastic analytical solutions are systematically derived in the Laplace domain,and the numerical Laplace inversion method is adopted to obtain the transient responses.The new model is compared with the parabolic two-step(PTS)model and the hyperbolic two-step(HTS)model.The results show that in ultrafast heating,the BTS model has the same wave front jump as the HTS model.The present model has the faster wave speed,and predicts the bigger disturbed regions than the HTS model.More deeply,all two-step models also have the faster wave speeds than one-step models.This work may benefit the theoretical modeling of ultrafast heating of metals.展开更多
In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The p...In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.展开更多
Electron-phonon coupling （EPC） in cuprate and iron-based superconducting systems, as revealed by Raman scat- tering, is briefly reviewed. We introduce how to extract the coupling information through phonon lineshape...Electron-phonon coupling （EPC） in cuprate and iron-based superconducting systems, as revealed by Raman scat- tering, is briefly reviewed. We introduce how to extract the coupling information through phonon lineshape. Then we discuss the strength of EPC in different high-temperature superconductor （HTSC） systems and possible factors affecting the strength. A comparative study between Raman phonon theories and experiments allows us to gain insight into some crucial electronic properties, especially superconductivity. Finally, we summarize and compare EPC in the two existing HTSC systems, and discuss what role it may play in the HTSC.展开更多
Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation ...Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation of this system. The dynamic model of the heavy-equipment airdrop is based on the Lagrange analytical mechanics, which has all the degrees of freedom and can accurately pinpoint the real-time coordinates and attitude of the carrier with its cargo. Unfavorable conditions accounted in the factors＇ models, including aircraft malfunctions and adverse environments, are established from a man-machine-environment perspective. Subsequently, a virtual simulation system for the safety research of the multi-factor coupling heavy-equipment airdrop is developed through MATLAB/Simulink, C language and Flightgear software. To verify the veracity of the theory, the verification model is built based on dynamic software ADAMS. Finally, the emulation is put to the test with the input of realistic accident variables to ascertain its feasibility and validity of this method.展开更多
The construction of a livable environment for the elderly is an important measure to address the challenges of aging and improve their livelihood and well-being.Based on China’s national conditions and combined with ...The construction of a livable environment for the elderly is an important measure to address the challenges of aging and improve their livelihood and well-being.Based on China’s national conditions and combined with the actual development needs of the cities,it is of great significance to explore the coupling and coordination characteristics and influencing factors within the livable environment system for the elderly for the coordination and stable development.This article was based on the three subsystems of’living service environment,socioeconomic environment and ecological livable environment’,following the research framework of’process-pattern-trend-impact’,constructs an evaluation index system for the livable environment for the elderly.Entropy weight-TOPSIS evaluation model,coupling coordination degree model,center of gravity and standard deviation ellipse model and the geographic detector model were used starting from the evolution of coupling coordination types to study the spatial and temporal pattern and dynamic trend characteristics and influencing factors of internal coupling coordination types in the livable environment system for the elderly from2010 to 2019.The results showed that:1)The coordinated development of life service environment system and ecological livable environment system(LE)and socioeconomic environment system and ecological livable environment system(SE)in the livable environment for the elderly decreased from the intermediate coordination level coordination areas to the low-level quality improvement and optimization areas:coordinated transition type.The overall development level of life service environment system and socioeconomic environment system(LS)was low,and it was always at a low level.2)The coupling degree of livable environment system for the elderly was high,the coupling coordination type shown a gradually decreasing layer structure with Zhejiang,Beijing and Guangdong high-level leading demonstration areas as the axis belt.3)The coupling coordination center of the elderly livable environment system was located in Henan,and the standard deviation ellipse was distributed in the northeast-southwest direction.The development center and the ellipse of the high-level leading demonstration areas and the intermediate coordination level areas were concentrated in the central and eastern regions,while the low-level coordination areas for improving quality and efficiency are mainly located in the western region.4)Urban development,green facilities,infrastructure,government macroscopic regulation and control,economic stimulus,and housing construction were all important factors affecting the coordinated development of the livable environment system for the elderly,exerting a varying degree of effect on the level of coordinated development of various types of systems.展开更多
Wetland is a transition zone between terrestrial and aquatic ecosystems,and is the source and sink of various biogenic elements in the earth’s epipelagic zone.In order to investigate the driving force and coupling me...Wetland is a transition zone between terrestrial and aquatic ecosystems,and is the source and sink of various biogenic elements in the earth’s epipelagic zone.In order to investigate the driving force and coupling mechanism of carbon(C),nitrogen(N)and phosphorus(P)migration in the critical zone of lake wetland,this paper studies the natural wetland of Dongting Lake area,through measuring and analysing the C,N and P contents in the wetland soil and groundwater.Methods of Pearson correlation,non-linear regression and machine learning were employed to analyse the influencing factors,and to explore the coupling patterns of the C,N and P in both soils and groundwater,with data derived from soil and water samples collected from the wetland critical zone.The results show that the mean values of organic carbon(TOC),total nitrogen(TN)and total phosphorus(TP)in groundwater are 1.59 mg/L,4.19 mg/L and 0.5 mg/L,respectively,while the mean values of C,N and P in the soils are 18.05 g/kg,0.86 g/kg and 0.52 g/kg.The results also show that the TOC,TN and TP in the groundwater are driven by a variety of environmental factors.However,the concentrations of C,N and P in the soils are mainly related to vegetation abundance and species which influence each other.In addition,the fitted curves of wetland soil C-N and C-P appear to follow the power function and S-shaped curve,respectively.In order to establish a multivariate regression model,the soil N and P contents were used as the input parameters and the soil C content used as the output one.By comparing the prediction effects of machine learning and nonlinear regression modelling,the results show that coupled relationship equation for the C,N and P contents is highly reliable.Future modelling of the coupled soil and groundwater elemental cycles needs to consider the complexity of hydrogeological conditions and to explore the quantitative relationships among the influencing factors and chemical constituents.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 50730006,50976053,and 50906042)
文摘Using a transient thermoreflectance （TTR） technique, several Au films with different thicknesses on glass and SiC substrates are measured for thermal characterization of metMlic nano-films, including the electron phonon coupling factor G, interfazial thermal resistance R, and thermal conductivity Ks of the substrate. The rear heating-front detecting （RF） method is used to ensure the femtosecond temporal resolution. An intense laser beam is focused on the rear surface to heat the film, and another weak laser beam is focused on the very spot of the front surface to detect the change in the electron temperature. By varying the optical path delay between the two beams, a complete electron temperature profile can be scanned. Different from the normally used single-layer model, the double-layer model involving interfaciM thermal resistance is studied here. The electron temperature cooling profile can be affected by the electron energy transfer into the substrate or the electron-phonon interactions in the metallic films. For multiple-target optimization, the genetic algorithm （GA） is used to obtain both G and R. The experimental result gives a deep understanding of the mechanism of ultra-fast heat transfer in metals.
基金supported by the financial aid from the National Natural Science Foundation of China (No. 22271273)International Partnership Program of Chinese Academy of Sciences (No. 121522KYSB20190022)。
文摘Self-trapping excitons(STEs) emission in metal halides has been a matter of interest, correlating with the strength of electron-phonon coupling in the lattice, which are usually caused by ions with ns~2 electronic structure. In this work, Sb^(3+)/Te^(4+)ions doped Zn-based halide single crystals(SCs) with two STEs emissions have been synthesized and the possibility of its anti-counterfeiting application was explored.Further, the relationship between the strength of electron-phonon coupling and photoluminescence quantum yields(PLQYs) for STEs in a series of metal halides has been studied. And the semi-empirical range of the Huang-Rhys factors(S) for metal halides with excellent photoluminescence(PL) property has been summarized. This work provides ideas for further research into the relationship between luminescence performance and electron-phonon coupling of metal halides, and also provides a reference for designing the metal halides with high PLQYs.
基金Supported by the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX24_0102)the China Scholarship Council Program(202406190114)。
文摘Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China.
基金supported by the National Natural Science Foundation of China(grant no.52072041)the Beijing Natural Science Foundation(grant no.JQ21007).
文摘Ferroelectric film materials have attracted significant interest due to their potential for harvesting various forms ofclean energy from natural environmental sources.However,the photoelectric performance of these materials isfrequently constrained by heat generation during light absorption,resulting in significant thermal losses.Most offerroelectric films produce photocurrent and thermocurrent with opposite polarity,thus weakening the coupledphoto-thermoelectric output of the devices.Here we report on a LaNiO_(3)/BiMn_(2)O_(5)(BMO)/ITO ferroelectric film toproduce photocurrent and thermocurrent with the same polarity.The polarity of the photocurrent generated bythe BMO film is shown to be determined solely by the direction of spontaneous polarization,overcoming thedetrimental effect of Schottky barrier for energy harvesting in device.We propose a new strategy to enhance thecoupling factor,thereby offering valuable new insights for optimizing the utilization of ferroelectric materials inboth light and heat energy applications.
基金supported by the China Scholarship Council(CSC)(Grant No.202006060033).
文摘Both the complex geometrical morphology of rough-walled rock fractures and the nonlinearity of fluid flow contribute to resistance in fluid flow through rock fractures.The interactions of the shear-flow process further complicate the characterisation of flow behaviours in rock fractures.In this study,an improved friction factor model involving both the effects of viscous and inertial forces is presented based on the Forchheimer equation.The model incorporates two key variables,i.e.Reynolds number and relative roughness,which reflect the effects of flow regimes and fracture roughness,respectively.The changes in geometrical parameters induced by shearing are considered,with the peak asperity height predicted through a correlation with post-peak roughness degradation.The hydraulic aperture during shearing is estimated using a suggested equation that accounts for the mobilised contact area ratio and variable aperture distribution.The parametric sensitivity analysis reveals that shear-induced changes in fracture geometry enhance the flow nonlinearity in rock fractures.The model performs well in predicting the friction factor based on two validation criteria.Then,the proposed friction factor model is incorporated into the three-dimensional distinct element code(3DEC)in the form of the Darcy-Weisbach equation.Coupled with the numerically implemented mechanical model and hydraulic aperture prediction model,numerical simulations of coupled shear-flow processes in single rock fractures are conducted.The simulation outcomes are validated through comparison with the experimental results,showing acceptable agreement and demonstrating that the numerical model is capable of accurately evaluating the hydro-mechanical coupling behaviour during the shearing of rock fractures.
基金Under the auspices of National Natural Science Foundation of China(No.42271222)Natural Science Foundation of Gansu Province(No.22JR5RA130)。
文摘Rural resilience,a core capability for addressing systemic risks and enabling sustainable development,is increasingly vital to promoting urban-rural integrated development and rural revitalization strategies.However,current research lacks exploration of the collaborative mechanisms between rural economic resilience(RER)and rural social resilience(RSR)in ecologically vulnerable areas.Based on the practical context of rural sustainable development in such regions,this study investigates the interaction between RER and RSR from a resilience coordination perspective.In this paper,a rural resilience evaluation framework for collaborative development of economic and social resilience was established.By employing the coupling coordination degree model,obstacle degree model,and equilibrium entropy model,this paper examines the synergies,constraints,and potential of rural resilience subsystems in Jinchang City,Gansu Province,China,in 2020.The results reveal that:1)RER contributes to RSR by stabilizing the economy,enhancing community adaptability,and driving modernization.In turn,RSR strengthens RER by mitigating instability,building social capital,and fostering confidence—together forming a mutually reinforcing coupling mechanism.2)The rural economic and social resilience level in Jinchang City remains generally low with spatially clustered patterns,while the coupling coordination degree is at an intermediate level overall,with 62.59%of villages exhibiting unbalanced development between rural economic and social resilience.3)RER and RSR demonstrate synergistic degradation in ecologically vulnerable areas,where low-level rural economic and social resilience induce integrated systemic deterioration.4)Considering the unbalanced development of rural economic and social resilience in ecologically fragile areas,differentiated coordination pathways are proposed for three village typologies:RER-lagging villages,RSR-lagging villages,and villages where RER and RSR develop synchronously but lack effective coordination.These findings offer spatial governance strategies and practical guidance for enhancing rural resilience and advancing sustainable development in ecologically vulnerable regions.
基金Project(11072269)supported by the National Natural Science Foundation of ChinaProject(20090162110066)supported by the Research Fund for the Doctoral Program of Higher Education of China
文摘A new calculation formula of THM coupling stress intensity factor was derived by the boundary collocation method, in which an additional constant stress function was successfully introduced for the cracked specimen with hydraulic pressure applied on its crack surface. Based on the newly derived formula, THM coupling fracture modes （including tensile, shear and mixed fracture mode） can be predicted by a new fracture criterion of stress intensity factor ratio, where the maximum axial load was measured by self-designed THM coupling fracture test. SEM analyses of THM coupling fractured surface indicate that the higher the temperature and hydraulic pressure are and the lower the confining pressure is, the more easily the intergranular （tension） fracture occurs. The transgranular （shear） fracture occurs in the opposite case while the mixed-mode fracture occurs in the middle case. The tested THM coupling fracture mechanisms are in good agreement with the predicted THM coupling fracture modes, which can verify correction of the newly-derived THM coupling stress intensity factor formula.
基金Project(50925829) supported by the National Science Fund for Distinguished Young Scholars of ChinaProject(50908148) supported by the National Natural Science Foundation of ChinaProjects(2009-K4-23,2010-11-33) supported by the Research of Ministry of Housing and Urban Rural Development of China
文摘The coupling model of major influence factors such state affecting the chloride diffusion process in concrete is as environmental relative humidity, load-induced crack and stress discussed. The probability distributions of the critical chloride concentration Cc, the chloride diffusion coefficient D, and the surface chloride concentration Cs were determined based on the collected natural exposure data. And the estimation of probability of corrosion initiation considering the coupling effects of influence factors is presented. It is found that the relative humidity and curing time are the most effective factors affecting the probability of corrosion initiation before and after 10 years of exposure time. At the same exposure time, the influence of load-induced crack and stress state on the probability of corrosion initiation is obvious, in which the effect of crack is the most one
基金supported by the National Natural Science Foundation of China(U21A20331,81903743,22005322,22279151,and 22275004)National Science Fund for Distinguished Young Scholars(21925506).
文摘This study presents experimental evidence of the dependence of non-radiative recombination processes on the electron-phonon coupling of perovskite in perovskite solar cells(PSCs).Via A-site cation engineering,a weaker electron-phonon coupling in perovskite has been achieved by introducing the structurally soft cyclohexane methylamine(CMA^(+))cation,which could serve as a damper to alleviate the mechanical stress caused by lattice oscillations,compared to the rigid phenethyl methylamine(PEA^(+))analog.It demonstrates a significantly lower non-radiative recombination rate,even though the two types of bulky cations have similar chemical passivation effects on perovskite,which might be explained by the suppressed carrier capture process and improved lattice geometry relaxation.The resulting PSCs achieve an exceptional power conversion efficiency(PCE)of 25.5%with a record-high opencircuit voltage(V_(OC))of 1.20 V for narrow bandgap perovskite(FAPbI_(3)).The established correlations between electron-phonon coupling and non-radiative decay provide design and screening criteria for more effective passivators for highly efficient PSCs approaching the Shockley-Queisser limit.
文摘The transmission of transverse vibrational energy of a vertically rigid beam plate coupled structure is analyzed to get the theoretical results of coupling loss factor(CLF), a very important parameter in statistical energy analysis(SEA). The modal analysis method is used to discuss the vibration energy of the typical model, as well as the power flow between the two subsystems. Furthermore, the resolution to the coupling loss factor is also derived and compared with the measured values. The analytical results of the coupling loss factor agree with the measured ones fully, this new resolution is significant for the application of SEA.
基金funded by Major Projects of Aero-Engines and Gas Turbines(J2019-Ⅳ-0023-0091 and J2019-Ⅳ-0005-0073)Aeronautical Science Foundation of China(2019ZB051002)+1 种基金China Postdoctoral Science Foundation(2021M700326)Advanced Jet Propulsion Creativity Center(Projects HKCX2020-02-013,HKCX2020-02-016 and HKCX2022-01009)。
文摘Within the linear framework,the Modal Electromechanical Coupling Factor(MEMCF)is an important indicator to quantify the dynamic conversion of mechanical energy and electrical energy of piezoelectric structures.It is also an important tool to guide the piezoelectric damping design of linear structures.Advanced aircraft often fly in maneuvers,and the variable working conditions induce drastic changes in the load level on structures.Geometric and contact nonlinearities of thin-walled structures and joint structures are often activated.To achieve a good vibration reduction effect covering all working conditions,one cannot directly use linear electromechanical coupling theory to instruct the piezoelectric damping design for nonlinear structures.Therefore,this paper defines the Nonlinear Modal Electromechanical Coupling Factor(NMEMCF)and proposes the corresponding numerical method for the first time to quantitatively evaluate the electromechanical coupling capability of nonlinear piezoelectric structures.Three candidate definitions of the NMEMCF are given,including two frequency definitions and one energy definition.The energy definition is the most promising one.It is not only applicable to both conservative and dissipative nonlinear structures but also compatible with the linear MEMCF.In addition,based on the energy formula,the NMEMCF can be obtained by only performing one nonlinear modal analysis in the open-circuit state.The analytical findings and the numerical tool are validated against two piezoelectric structures with different types of nonlinearities.A strong correlation among the NMEMCF,geometric parameters,and energy dissipation is observed.The results confirm that the proposed NMEMCF captures the physics of the electromechanical coupling phenomenon associated with nonlinear piezoelectric structures and can be used as an essential design indicator of piezoelectric damping,especially for variable working conditions.
基金Special Program for Survey of National Basic Scientific and Technological Resources,No.2021FY00802。
文摘The Taihang Mountains in North China are an important carbon-water ecosystem service supply area.Understanding the coupling effect and influencing mechanisms of mountain carbon sequestration as well as water conservation is essential for regional eco-logical restoration and sustainable development.In this study,we utilized models such as the coupled coordination degree model,the random forest and Geodetector to analyze the spa-tio-temporal changes as well as driving factors of carbon sequestration-water conservation coupling coordination in the Taihang Mountains.The results show that:(1)From 1990 to 2020,the carbon sequestration and water conservation capacity of the Taihang Mountains exhibited a spatial pattern with higher values in the southeast and central regions,while lower values in the northwest region.(2)The average coupling coordination degree from 1990 to 2020 was O.23,which was overall low,with a fluctuating decreasing-rising-decreasing trend over time.The coupling coordination degree exhibited a pattern that is high in the middle and low in the periphery,with a fluctuating distribution that initially decreases and then increases with the increasing altitude.The overall trend of coupling coordination is degradation,with concen-trated degradation in the northwest mountainous regions.(3)Precipitation and soil texture were identified as the main driving factors influencing coupling coordination,with the interac-tion between precipitation and soil sand content showing the strongest explanatory power,while that among topography,vegetation and human activities had relatively low explanatory power.Therefore,enhanced protection and the continuous monitoring of vegetation and soil environments in the Taihang Mountains are essential,with particular emphasis on ecological restoration in areas experiencing a persistent degradation of carbon-water coupling.This study can provide assistance in monitoring and managing carbon sink and water resources in the mountains,meanwhile mitigating potential adverse impacts on human well-being.
基金Item Sponsored by Technology Supporting Program During the 11th Five-Year Plan Period(BAE03A07)
文摘Combined with the parameters of the production process of a steel factory, numerical simulations for a new ladle from preheating to turnover are conducted using the finite element analysis system software （ANSYS）. The measured data proved that the simulated results are reliable. The effects of preheating time, thermal cycling times, and empty package time on steel temperature are calculated, an ideal preheating time is provided, besides, based on the analysis of a single factor and use the nonlinear analysis method, a steel temperature compensating model with di- versified coupling factors is proposed, with the largest error of the present coupling model at 1. 462 ~C, and the er- rors between actual and target steel temperature in tundish after the model is applied to practical production are basi- cally controlled within -4-6 ~C, which can meet the accuracy of the manufacturer and has a practical guiding significance for the production in steelmaking workshops.
基金Project supported by the Wang Faculty Fellowship at Peking University,Beijing,China,2006-2007 through California State University (CSU) International Programs USAthe National Basic Research Program of China (Grant No 2007CB307004)+1 种基金the National High Technology Research and Development Program of China (Grant No 2006AA03A113)the National Natural Science Foundation of China (Grant Nos 60276034,60577030 and 60607003)
文摘We have investigated the transverse mode pattern and the optical field confinement factor of gallium nitride （GaN） laser diodes （LDs） theoretically. For the particular LD structure, composed of approximate 4 μm thick n-GaN substrate layer, the maximum optical confinement factor was found to be corresponding to the 5^th order transverse mode, the so-called lasing mode. Moreover, the value of the maximum confinement factor varies periodically when increasing the n-side GaN layer thickness, which simultaneously changes and increases the oscillation mode order of the GaN LD caused by the effects of mode coupling. The effects of the thickness and the average composition of Al in the AlGaN/GaN superlat.tice on the optical confinement factor are also presented. Finally, the mode coupling and optimization of the layers in the GaN-based LD are discussed.
基金Project supported by the Fundamental Research Funds for the Central Universities of China(Nos.D5000230066 and D5000210117)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2022JQ-358)。
文摘The electron-phonon interaction can reveal the microscopic mechanism of heat transfer in metals.The two-step heat conduction considering electron-phonon interaction has become an effective theoretical model for extreme environments,such as micro-scale and ultrafast processes.In this work,the two-step heat transfer model is further extended by considering the Burgers heat conduction model with the secondorder heat flux rate for electrons.Then,a novel generalized electron-phonon coupling thermoelasticity is proposed with the Burgers electronic heat transfer.Then,the problem of one-dimensional semi-infinite copper strip subject to a thermal shock at one side is studied by the Burgers two-step(BTS)model.The thermoelastic analytical solutions are systematically derived in the Laplace domain,and the numerical Laplace inversion method is adopted to obtain the transient responses.The new model is compared with the parabolic two-step(PTS)model and the hyperbolic two-step(HTS)model.The results show that in ultrafast heating,the BTS model has the same wave front jump as the HTS model.The present model has the faster wave speed,and predicts the bigger disturbed regions than the HTS model.More deeply,all two-step models also have the faster wave speeds than one-step models.This work may benefit the theoretical modeling of ultrafast heating of metals.
基金the National Natural Science Foundation of China (No.51178305)Key Projects in the Science & Technology Pillar Program of Tianjin (No.11ZCKFSF00300)
文摘In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.
基金supported by the National Basic Research Program of China(Grant Nos.2011CBA00112 and 2012CB921701)
文摘Electron-phonon coupling （EPC） in cuprate and iron-based superconducting systems, as revealed by Raman scat- tering, is briefly reviewed. We introduce how to extract the coupling information through phonon lineshape. Then we discuss the strength of EPC in different high-temperature superconductor （HTSC） systems and possible factors affecting the strength. A comparative study between Raman phonon theories and experiments allows us to gain insight into some crucial electronic properties, especially superconductivity. Finally, we summarize and compare EPC in the two existing HTSC systems, and discuss what role it may play in the HTSC.
基金co-supported by the National Natural Science Foundation of China (Nos. 61374145 and U1333131)
文摘Heavy-equipment airdrop is a highly risky procedure that has a complicated system due to the secluded and complex nature of factors＇ coupling. As a result, it is difficult to study the modeling and safety simulation of this system. The dynamic model of the heavy-equipment airdrop is based on the Lagrange analytical mechanics, which has all the degrees of freedom and can accurately pinpoint the real-time coordinates and attitude of the carrier with its cargo. Unfavorable conditions accounted in the factors＇ models, including aircraft malfunctions and adverse environments, are established from a man-machine-environment perspective. Subsequently, a virtual simulation system for the safety research of the multi-factor coupling heavy-equipment airdrop is developed through MATLAB/Simulink, C language and Flightgear software. To verify the veracity of the theory, the verification model is built based on dynamic software ADAMS. Finally, the emulation is put to the test with the input of realistic accident variables to ascertain its feasibility and validity of this method.
基金Under the auspices of Natural Science Foundation of Heilongjiang Province(No.LH2019D008)Youth Fund for Humanities and Social Sciences of the Ministry of Education(No.19YJC630177)+1 种基金Innovative Youth Talent Cultivation Plan of Heilongjiang Provincial Universities(No.UNPYSCT-2018194)Human Civilization and Social Science Supportive Program for Excellent Young Scholars of Harbin Normal University(No.SYQ2014-06)。
文摘The construction of a livable environment for the elderly is an important measure to address the challenges of aging and improve their livelihood and well-being.Based on China’s national conditions and combined with the actual development needs of the cities,it is of great significance to explore the coupling and coordination characteristics and influencing factors within the livable environment system for the elderly for the coordination and stable development.This article was based on the three subsystems of’living service environment,socioeconomic environment and ecological livable environment’,following the research framework of’process-pattern-trend-impact’,constructs an evaluation index system for the livable environment for the elderly.Entropy weight-TOPSIS evaluation model,coupling coordination degree model,center of gravity and standard deviation ellipse model and the geographic detector model were used starting from the evolution of coupling coordination types to study the spatial and temporal pattern and dynamic trend characteristics and influencing factors of internal coupling coordination types in the livable environment system for the elderly from2010 to 2019.The results showed that:1)The coordinated development of life service environment system and ecological livable environment system(LE)and socioeconomic environment system and ecological livable environment system(SE)in the livable environment for the elderly decreased from the intermediate coordination level coordination areas to the low-level quality improvement and optimization areas:coordinated transition type.The overall development level of life service environment system and socioeconomic environment system(LS)was low,and it was always at a low level.2)The coupling degree of livable environment system for the elderly was high,the coupling coordination type shown a gradually decreasing layer structure with Zhejiang,Beijing and Guangdong high-level leading demonstration areas as the axis belt.3)The coupling coordination center of the elderly livable environment system was located in Henan,and the standard deviation ellipse was distributed in the northeast-southwest direction.The development center and the ellipse of the high-level leading demonstration areas and the intermediate coordination level areas were concentrated in the central and eastern regions,while the low-level coordination areas for improving quality and efficiency are mainly located in the western region.4)Urban development,green facilities,infrastructure,government macroscopic regulation and control,economic stimulus,and housing construction were all important factors affecting the coordinated development of the livable environment system for the elderly,exerting a varying degree of effect on the level of coordinated development of various types of systems.
基金supported by National Natural Science Foundation of China(No.42077176,No.41976057)Natural Science Foundation of Shanghai(No.20ZR1459700).
文摘Wetland is a transition zone between terrestrial and aquatic ecosystems,and is the source and sink of various biogenic elements in the earth’s epipelagic zone.In order to investigate the driving force and coupling mechanism of carbon(C),nitrogen(N)and phosphorus(P)migration in the critical zone of lake wetland,this paper studies the natural wetland of Dongting Lake area,through measuring and analysing the C,N and P contents in the wetland soil and groundwater.Methods of Pearson correlation,non-linear regression and machine learning were employed to analyse the influencing factors,and to explore the coupling patterns of the C,N and P in both soils and groundwater,with data derived from soil and water samples collected from the wetland critical zone.The results show that the mean values of organic carbon(TOC),total nitrogen(TN)and total phosphorus(TP)in groundwater are 1.59 mg/L,4.19 mg/L and 0.5 mg/L,respectively,while the mean values of C,N and P in the soils are 18.05 g/kg,0.86 g/kg and 0.52 g/kg.The results also show that the TOC,TN and TP in the groundwater are driven by a variety of environmental factors.However,the concentrations of C,N and P in the soils are mainly related to vegetation abundance and species which influence each other.In addition,the fitted curves of wetland soil C-N and C-P appear to follow the power function and S-shaped curve,respectively.In order to establish a multivariate regression model,the soil N and P contents were used as the input parameters and the soil C content used as the output one.By comparing the prediction effects of machine learning and nonlinear regression modelling,the results show that coupled relationship equation for the C,N and P contents is highly reliable.Future modelling of the coupled soil and groundwater elemental cycles needs to consider the complexity of hydrogeological conditions and to explore the quantitative relationships among the influencing factors and chemical constituents.
