Photothermal catalysis is a widely researched field in which the reaction mechanism is usually investigated based on the photochemical behavior of the catalytic material.Considering that the adsorption of reactants is...Photothermal catalysis is a widely researched field in which the reaction mechanism is usually investigated based on the photochemical behavior of the catalytic material.Considering that the adsorption of reactants is essential for catalytic reactions to occur,in this study,the synergistic effect of photothermal catalysis is innovatively elucidated in terms of the electron transfer behavior of reactant adsorption.For the H_(2)+O2 or CO+H_(2)reaction systems over a ZnO catalyst,UV irradiation at 25°C or heat without UV irradiation did not cause H_(2)oxidation or CO reduction;only photothermal conditions(100 or 150°C+UV light)initiated the two reactions.This result is related to the electron transfer behavior associated with the adsorption of CO or H_(2)on ZnO,in which H_(2)or CO that lost an electron could be oxidized by O2 or hydroxyls.However,the electron‐accepting CO could be reduced by the electron‐donating H_(2)into CH4 under photothermal conditions.Based on the in‐situ characterization and theoretical calculation results,it was established that the synergistic effect of the photothermal conditions acted on the(002)crystal surface of ZnO to stimulate the growth of zinc vacancies,which resulted in the formation of defect energy levels,adsorption sites,and an adjusted Fermi level.As a result,the electron transfer behavior between adsorbed CO or H_(2)and the crystal surface varied,which further affected the photocatalytic behavior.The results show that the effect of photothermal synergy may not only produce the expected kinetic energy,but more importantly,produce energy that can change the activation mode of the reactant gas.This study provides a new understanding of the CO catalytic oxidation and reduction processes over semiconductor materials.展开更多
The electronic structure of ferrite (tempered martensite phase) in high Co-Ni secondary hardened martensitic steel has been investigated. The local density of states (LOOS) of alloying elements in the steel displays t...The electronic structure of ferrite (tempered martensite phase) in high Co-Ni secondary hardened martensitic steel has been investigated. The local density of states (LOOS) of alloying elements in the steel displays the relationship between solid solubility and the shape of the LDOS. The bond order integral (BOI) between atoms in the steel shows that the directional bonding of the p orbital of Si or C leads to the brittleness of the steel. At last, ΣBOI between atoms demonstrate that C, Co, Mn, Cr, Mo, Si strengthen the alloyed steel through solid-solution effects.展开更多
A Monte Carlo simulation technique has been used to model the electron transport' behavior, especially the electron density and energy distributions under the influence of a mirror magnetic field and a uniform ele...A Monte Carlo simulation technique has been used to model the electron transport' behavior, especially the electron density and energy distributions under the influence of a mirror magnetic field and a uniform electric field in a positive column of helium direct current(DC) gas discharge Graphs showing the electron density and energy distributions, and the percentage of electrons that reach the wall and the end of the positive column are presented. The results indicate that the mirror magnetic field can control the electron transport behavior in the positive column which are in good agreement with experimental results.展开更多
Perovskite BiMnO_3 samples are successfully synthesized by the co-precipitation method at relatively low pressure and moderate temperature.The temperature dependences of resistivity are measured and systematically inv...Perovskite BiMnO_3 samples are successfully synthesized by the co-precipitation method at relatively low pressure and moderate temperature.The temperature dependences of resistivity are measured and systematically investigated.It is shown that the electrical resistivity increases sharply with the decrease of temperature above 210 K and the fitted results demonstrate that the thermally activated conduction model is the dominant conduction mechanism for the electron transport behaviors in this temperature region.A dual conducting mechanism,i.e.,the variable range hopping and thermal activated conduction,is suggested to be responsible for the transport behaviors of BiMnO_3 in the region of 180-200 K.Moreover,the resistivity increases slightly with the decrease of temperature below 180 K and the transport is governed by the variable range hopping mechanism.展开更多
Some nonlinear behavior in electron cyclotron resonance plasma was investigated using a two-dimension hybrid-mode with self-consistent microwave absorption. The saturation,oscillations of plasma parameters (plasma den...Some nonlinear behavior in electron cyclotron resonance plasma was investigated using a two-dimension hybrid-mode with self-consistent microwave absorption. The saturation,oscillations of plasma parameters (plasma density, potential, electron temperature) versus operating conditions (pressure, power) are discussed. Our simulation results are consistent qualitatively with many experimental measurements.展开更多
The Ni samples were electroformed from additive-free(AF) and saccharin-containing(SC) sulfamate solutions, respectively. In situ backscattered electron(BSE) imaging, electron backscatter diffraction(EBSD), and electro...The Ni samples were electroformed from additive-free(AF) and saccharin-containing(SC) sulfamate solutions, respectively. In situ backscattered electron(BSE) imaging, electron backscatter diffraction(EBSD), and electron-probe microanalysis(EPMA) were used to investigate the effect of annealing on the deformation behaviors of the AF and SC samples. The results indicate that columnar grains of the as-deposited AF sample had an approximated average width of 3 μm and an approximated aspect ratio of 8. The average width of columnar grains of the as-deposited SC sample was reduced to approximately 400 nm by the addition of saccharin to the electrolyte. A few very-large grains distributed in the matrix of the SC sample after annealing. No direct evidence indicated that S segregated at the grain boundaries before or after annealing. The average value of the total elongations of the SC samples decreased from 16% to 6% after annealing, whereas that of the AF samples increased from 18% to 50%. The dislocation recovery in grain-boundary areas of the annealed AF sample was reduced, which contributed to the appearance of microvoids at the triple junctions. The incompatibility deformation between very-large grains and fine grains contributed to the brittle fracture behavior of the annealed SC Ni.展开更多
TiNi-based shape memory alloys have been extensively investigated due to their significant applications,but a comprehensive understanding of the evolution of electronic structure and electrical transport in a system w...TiNi-based shape memory alloys have been extensively investigated due to their significant applications,but a comprehensive understanding of the evolution of electronic structure and electrical transport in a system with martensitic transformations(MT) is still lacking.In this work,we focused on the electronic transport behavior of three phases in Ni_(50-x)Fe_xTi_(50)across the MT.A phase diagram of Ni_(50-x)Fe_xTi_(50) was established based on x-ray diffraction,calorimetric,magnetic,and electrical measurements.To reveal the driving force of MT,phonon softening was revealed using first-principles calculations.Notably,the transverse and longitudinal transport behavior changed significantly across the phase transition,which can be attributed to the reconstruction of electronic structures.This work promotes the understanding of phase transitions and demonstrates the sensitivity of electron transport to phase transition.展开更多
In this study, shear tests have been performed on the as-reflowed Sn3.5Ag solder bumps and joints to investigate the deformation behavior of Sn3.5Ag lead-free solder samples. Scanning electron microscopy （SEM） was e...In this study, shear tests have been performed on the as-reflowed Sn3.5Ag solder bumps and joints to investigate the deformation behavior of Sn3.5Ag lead-free solder samples. Scanning electron microscopy （SEM） was employed to characterize the microstructures of the samples and orientation imaging microscopy （OIM） with electron backscattered diffraction （EBSD） in SEM was used to obtain crystallographic orientation of grains to provide a detailed characterization of the deformation behavior in Sn3.5Ag solder samples after shear tests. The deformation behavior in solder samples under shear stress was discussed. The experimental results suggest that the dynamic recrystallization could occur under shear stress at room temperature and recrystallized grains should evolve from subgrains by rotation. Compared with that of non-recrystallized and as-reflowed microstructures, the microhardness of the recrystallized microstructure decreased after shear tests.展开更多
The understanding of customer incidents and behaviour is crucial to the success of any organization. Evidence from literature shows a prediction pattern of products to customer. These studies predicted product charact...The understanding of customer incidents and behaviour is crucial to the success of any organization. Evidence from literature shows a prediction pattern of products to customer. These studies predicted product characteristics leaving out the customers characteristics. To address this gap, this study aims to design datamining system and implement it on an electronic commerce organization website. The customer information and history (clickstreams) from the electronic commerce website was used to predict the customers’ behaviour. This will give meaningful and usable data patterns to organizations. Python programming language was used to design the datamining system, while PHP, HTML, and JavaScript were used for the e-commerce website. A brief description of the background of e-commerce and data mining, previous work of researchers who have worked on data mining in e-commerce settings, was reviewed and the relationship between their findings and this work was established. The data mining system utilizes consensus clustering technique and the clustering algorithm with a graphical-based approach. Furthermore, the interaction between the data mining system and the customer’s dataset on an ecommerce website was defined. Quantitative evidence for determining the number and membership of possible customer behavioural clusters within the dataset was generated.展开更多
A cryogenic scanning electron microscopy（cryo-SEM） technique was used to explore the shear-thickening behavior of Fe-ZSM5 zeolite pastes and to discover its underlying mechanism. Bare Fe-ZSM5 zeolite samples were fo...A cryogenic scanning electron microscopy（cryo-SEM） technique was used to explore the shear-thickening behavior of Fe-ZSM5 zeolite pastes and to discover its underlying mechanism. Bare Fe-ZSM5 zeolite samples were found to contain agglomerations, which may break the flow of the pastes and cause shear-thickening behaviors. However, the shear-thickening behaviors can be eliminated by the addition of halloysite and various boehmites because of improved particle packing. Furthermore, compared with pure Fe-ZSM5 zeolite samples and its composite samples with halloysite, the samples with boehmite（Pural SB or Disperal） additions exhibited network structures in their cryo-SEM images; these structures could facilitate the storage and release of flow water, smooth paste flow, and avoid shear-thickening. By contrast, another boehmite（Versal 250） formed agglomerations rather than network structures after being added to the Fe-ZSM5 zeolite paste and resulted in shear-thickening behavior. Consequently, the results suggest that these network structures play key roles in eliminating the shear-thickening behavior.展开更多
A method based on electronic structure calculation is proposed to predict the substitution behavior of elements in ordered intermetallics. The electronic structure of 20 alloying elements in TiAl is calculated using ...A method based on electronic structure calculation is proposed to predict the substitution behavior of elements in ordered intermetallics. The electronic structure of 20 alloying elements in TiAl is calculated using the DV-Xα cluster method The bond orders between alloying elements and surrounding atoms, Bo_Ti,Bo_Al, are used as parameters. Two lines on the Bo_Ti-Bo_Al diagram separate the elements into three groups. The elements located outside of the two lines substitute either Ti or Al atom regardless of the composition of TiAl. The substitution behavior of elements between the two lines will be affected by the Ti/Al ratio and the amount of alloying elements added Substituting sequence in multi-element alloy is discussed The prediction based on this method agrees well with the experimental results.展开更多
In this paper, we report the ground state properties i.e. electron momentum density and X-ray structure factors of fcc-copper are presented. The Am241 Compton spectrometer, which uses 59.54 keV gamma-rays, has been us...In this paper, we report the ground state properties i.e. electron momentum density and X-ray structure factors of fcc-copper are presented. The Am241 Compton spectrometer, which uses 59.54 keV gamma-rays, has been used for the Compton profile measurement. To compare the experimental data, the Compton profiles within the framework of linear combination of atomic orbitals (LCAO) method using Hartree–Fock (HF), density functional (DF) and hybrid B3PW schemes embodied in the CRYSTAL06 code have been computed. Among the various theoretical calculations, it is found that the present experimental data is in very good agreement with the hybrid B3PW scheme. A real-space analysis of the experimental Compton profile shows the metal-like behavior of copper The structure factors for copper are computed using hybrid B3PW scheme and compared with available experimental and theoretical data.展开更多
The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematica...The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematically investigate the influence of interlayer sliding on the electronic behavior of PtSe_(2) using density functional theory(DFT) calculations. Our results demonstrate that interlayer sliding induces a pronounced photocurrent spanning the short-wavelength infrared to visible spectral ranges. Remarkably, under an applied gate voltage, the sliding ferroelectric PtSe_(2) exhibits anomalously enhanced photovoltaic performance and an ultrahigh extinction ratio.Transmission spectral analysis reveals that this phenomenon originates from band structure modifications driven by energy-level transitions. Furthermore, the observed photocurrent enhancement via sliding ferroelectricity demonstrates universality across diverse platinum-based optoelectronic devices. This study introduces a novel paradigm for tailoring the intrinsic characteristics of 2D vdW semiconductors, expanding the design space for next-generation ferroelectric materials in advanced optoelectronic applications.展开更多
Dielectric barrier discharges(DBDs)are primarily utilized as efficient sources of large-volume diffuse plasmas.However,the synergistic interaction of certain key plasma factors limits their broader application.In the ...Dielectric barrier discharges(DBDs)are primarily utilized as efficient sources of large-volume diffuse plasmas.However,the synergistic interaction of certain key plasma factors limits their broader application.In the present paper,we report numerical investigations of the effects of voltage amplitude in dual-frequency excitation on atmospheric DBDs using a 50 kHz/5 MHz frequency combination.Our results indicate that varying the voltages for low frequency(LF)and radio frequency(RF)significantly influences the electron dynamics during discharge,resulting in distinct spatio-temporal distributions of electron and metastable particle densities.These findings contribute to the regulation of discharges under atmospheric pressure conditions and facilitate the attainment of non-equilibrium and nonlinear plasma parameters.展开更多
文摘Photothermal catalysis is a widely researched field in which the reaction mechanism is usually investigated based on the photochemical behavior of the catalytic material.Considering that the adsorption of reactants is essential for catalytic reactions to occur,in this study,the synergistic effect of photothermal catalysis is innovatively elucidated in terms of the electron transfer behavior of reactant adsorption.For the H_(2)+O2 or CO+H_(2)reaction systems over a ZnO catalyst,UV irradiation at 25°C or heat without UV irradiation did not cause H_(2)oxidation or CO reduction;only photothermal conditions(100 or 150°C+UV light)initiated the two reactions.This result is related to the electron transfer behavior associated with the adsorption of CO or H_(2)on ZnO,in which H_(2)or CO that lost an electron could be oxidized by O2 or hydroxyls.However,the electron‐accepting CO could be reduced by the electron‐donating H_(2)into CH4 under photothermal conditions.Based on the in‐situ characterization and theoretical calculation results,it was established that the synergistic effect of the photothermal conditions acted on the(002)crystal surface of ZnO to stimulate the growth of zinc vacancies,which resulted in the formation of defect energy levels,adsorption sites,and an adjusted Fermi level.As a result,the electron transfer behavior between adsorbed CO or H_(2)and the crystal surface varied,which further affected the photocatalytic behavior.The results show that the effect of photothermal synergy may not only produce the expected kinetic energy,but more importantly,produce energy that can change the activation mode of the reactant gas.This study provides a new understanding of the CO catalytic oxidation and reduction processes over semiconductor materials.
文摘The electronic structure of ferrite (tempered martensite phase) in high Co-Ni secondary hardened martensitic steel has been investigated. The local density of states (LOOS) of alloying elements in the steel displays the relationship between solid solubility and the shape of the LDOS. The bond order integral (BOI) between atoms in the steel shows that the directional bonding of the p orbital of Si or C leads to the brittleness of the steel. At last, ΣBOI between atoms demonstrate that C, Co, Mn, Cr, Mo, Si strengthen the alloyed steel through solid-solution effects.
文摘A Monte Carlo simulation technique has been used to model the electron transport' behavior, especially the electron density and energy distributions under the influence of a mirror magnetic field and a uniform electric field in a positive column of helium direct current(DC) gas discharge Graphs showing the electron density and energy distributions, and the percentage of electrons that reach the wall and the end of the positive column are presented. The results indicate that the mirror magnetic field can control the electron transport behavior in the positive column which are in good agreement with experimental results.
基金Supported by the Key Research Project of Shaanxi University of Science and Technology under Grant Nos 2016GBJ-12 and2016BJ-59
文摘Perovskite BiMnO_3 samples are successfully synthesized by the co-precipitation method at relatively low pressure and moderate temperature.The temperature dependences of resistivity are measured and systematically investigated.It is shown that the electrical resistivity increases sharply with the decrease of temperature above 210 K and the fitted results demonstrate that the thermally activated conduction model is the dominant conduction mechanism for the electron transport behaviors in this temperature region.A dual conducting mechanism,i.e.,the variable range hopping and thermal activated conduction,is suggested to be responsible for the transport behaviors of BiMnO_3 in the region of 180-200 K.Moreover,the resistivity increases slightly with the decrease of temperature below 180 K and the transport is governed by the variable range hopping mechanism.
文摘Some nonlinear behavior in electron cyclotron resonance plasma was investigated using a two-dimension hybrid-mode with self-consistent microwave absorption. The saturation,oscillations of plasma parameters (plasma density, potential, electron temperature) versus operating conditions (pressure, power) are discussed. Our simulation results are consistent qualitatively with many experimental measurements.
基金financially supported by the China Scholarship Council(No.201606460015)the support of the H.Nakano laboratory of Kyushu University for the study
文摘The Ni samples were electroformed from additive-free(AF) and saccharin-containing(SC) sulfamate solutions, respectively. In situ backscattered electron(BSE) imaging, electron backscatter diffraction(EBSD), and electron-probe microanalysis(EPMA) were used to investigate the effect of annealing on the deformation behaviors of the AF and SC samples. The results indicate that columnar grains of the as-deposited AF sample had an approximated average width of 3 μm and an approximated aspect ratio of 8. The average width of columnar grains of the as-deposited SC sample was reduced to approximately 400 nm by the addition of saccharin to the electrolyte. A few very-large grains distributed in the matrix of the SC sample after annealing. No direct evidence indicated that S segregated at the grain boundaries before or after annealing. The average value of the total elongations of the SC samples decreased from 16% to 6% after annealing, whereas that of the AF samples increased from 18% to 50%. The dislocation recovery in grain-boundary areas of the annealed AF sample was reduced, which contributed to the appearance of microvoids at the triple junctions. The incompatibility deformation between very-large grains and fine grains contributed to the brittle fracture behavior of the annealed SC Ni.
基金supported by the State Key Development Program for Basic Research of China(Grant Nos.2019YFA0704900 and 2022YFA1403800)the Fundamental Science Center of the National Natural Science Foundation of China(Grant No.52088101)+2 种基金the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(CAS)(Grant No.XDB33000000)the Synergetic Extreme Condition User Facility(SECUF)the Scientific Instrument Developing Project of CAS(Grant No.ZDKYYQ20210003)。
文摘TiNi-based shape memory alloys have been extensively investigated due to their significant applications,but a comprehensive understanding of the evolution of electronic structure and electrical transport in a system with martensitic transformations(MT) is still lacking.In this work,we focused on the electronic transport behavior of three phases in Ni_(50-x)Fe_xTi_(50)across the MT.A phase diagram of Ni_(50-x)Fe_xTi_(50) was established based on x-ray diffraction,calorimetric,magnetic,and electrical measurements.To reveal the driving force of MT,phonon softening was revealed using first-principles calculations.Notably,the transverse and longitudinal transport behavior changed significantly across the phase transition,which can be attributed to the reconstruction of electronic structures.This work promotes the understanding of phase transitions and demonstrates the sensitivity of electron transport to phase transition.
基金supported by the National Natural Science Foundation of China under Grant No.50905042the Shenzhen Special Funds for Overseas High-level Talents(No. KQC201109020053A)+1 种基金Shenzhen Technological Innovation Project (No.CXZZ20120829103358067)the Shenzhen Special Funds for Strategic Emerging Industries(No.JCYJ20120613140542764)
文摘In this study, shear tests have been performed on the as-reflowed Sn3.5Ag solder bumps and joints to investigate the deformation behavior of Sn3.5Ag lead-free solder samples. Scanning electron microscopy （SEM） was employed to characterize the microstructures of the samples and orientation imaging microscopy （OIM） with electron backscattered diffraction （EBSD） in SEM was used to obtain crystallographic orientation of grains to provide a detailed characterization of the deformation behavior in Sn3.5Ag solder samples after shear tests. The deformation behavior in solder samples under shear stress was discussed. The experimental results suggest that the dynamic recrystallization could occur under shear stress at room temperature and recrystallized grains should evolve from subgrains by rotation. Compared with that of non-recrystallized and as-reflowed microstructures, the microhardness of the recrystallized microstructure decreased after shear tests.
文摘The understanding of customer incidents and behaviour is crucial to the success of any organization. Evidence from literature shows a prediction pattern of products to customer. These studies predicted product characteristics leaving out the customers characteristics. To address this gap, this study aims to design datamining system and implement it on an electronic commerce organization website. The customer information and history (clickstreams) from the electronic commerce website was used to predict the customers’ behaviour. This will give meaningful and usable data patterns to organizations. Python programming language was used to design the datamining system, while PHP, HTML, and JavaScript were used for the e-commerce website. A brief description of the background of e-commerce and data mining, previous work of researchers who have worked on data mining in e-commerce settings, was reviewed and the relationship between their findings and this work was established. The data mining system utilizes consensus clustering technique and the clustering algorithm with a graphical-based approach. Furthermore, the interaction between the data mining system and the customer’s dataset on an ecommerce website was defined. Quantitative evidence for determining the number and membership of possible customer behavioural clusters within the dataset was generated.
基金financially supported by the National Natural Science Foundation of China (No. 51602018)Beijing Natural Science Foundation (No. 2154052)+2 种基金China Postdoctoral Science Foundation Funded Project (No. 2014M560044)the Fundamental Research Funds for the Central Universities (FRF-GF-17-B7)National Key Technologies Research and Development Program of China:Key International Science and Technology Cooperation Projects (2016YFE0111500)
文摘A cryogenic scanning electron microscopy（cryo-SEM） technique was used to explore the shear-thickening behavior of Fe-ZSM5 zeolite pastes and to discover its underlying mechanism. Bare Fe-ZSM5 zeolite samples were found to contain agglomerations, which may break the flow of the pastes and cause shear-thickening behaviors. However, the shear-thickening behaviors can be eliminated by the addition of halloysite and various boehmites because of improved particle packing. Furthermore, compared with pure Fe-ZSM5 zeolite samples and its composite samples with halloysite, the samples with boehmite（Pural SB or Disperal） additions exhibited network structures in their cryo-SEM images; these structures could facilitate the storage and release of flow water, smooth paste flow, and avoid shear-thickening. By contrast, another boehmite（Versal 250） formed agglomerations rather than network structures after being added to the Fe-ZSM5 zeolite paste and resulted in shear-thickening behavior. Consequently, the results suggest that these network structures play key roles in eliminating the shear-thickening behavior.
文摘A method based on electronic structure calculation is proposed to predict the substitution behavior of elements in ordered intermetallics. The electronic structure of 20 alloying elements in TiAl is calculated using the DV-Xα cluster method The bond orders between alloying elements and surrounding atoms, Bo_Ti,Bo_Al, are used as parameters. Two lines on the Bo_Ti-Bo_Al diagram separate the elements into three groups. The elements located outside of the two lines substitute either Ti or Al atom regardless of the composition of TiAl. The substitution behavior of elements between the two lines will be affected by the Ti/Al ratio and the amount of alloying elements added Substituting sequence in multi-element alloy is discussed The prediction based on this method agrees well with the experimental results.
文摘In this paper, we report the ground state properties i.e. electron momentum density and X-ray structure factors of fcc-copper are presented. The Am241 Compton spectrometer, which uses 59.54 keV gamma-rays, has been used for the Compton profile measurement. To compare the experimental data, the Compton profiles within the framework of linear combination of atomic orbitals (LCAO) method using Hartree–Fock (HF), density functional (DF) and hybrid B3PW schemes embodied in the CRYSTAL06 code have been computed. Among the various theoretical calculations, it is found that the present experimental data is in very good agreement with the hybrid B3PW scheme. A real-space analysis of the experimental Compton profile shows the metal-like behavior of copper The structure factors for copper are computed using hybrid B3PW scheme and compared with available experimental and theoretical data.
基金supported by the National Key Research and Development Program of China (Grant No. 2024YFB3211701)the National Natural Science Foundation of China (Grant Nos. T2222011, 62174026, and 12274234)+1 种基金the National Key Research and Development Program of China (Grant Nos. 2023YFB3611400 and 2019YFA0308000)the Fundamental Research Funds for the Central Universities (Grant No. 242023k30027)。
文摘The weak interlayer van der Waals(vdW) interactions in two-dimensional(2D) vdW materials enable sliding ferroelectricity as an effective strategy for modulating their intrinsic properties. In this work, we systematically investigate the influence of interlayer sliding on the electronic behavior of PtSe_(2) using density functional theory(DFT) calculations. Our results demonstrate that interlayer sliding induces a pronounced photocurrent spanning the short-wavelength infrared to visible spectral ranges. Remarkably, under an applied gate voltage, the sliding ferroelectric PtSe_(2) exhibits anomalously enhanced photovoltaic performance and an ultrahigh extinction ratio.Transmission spectral analysis reveals that this phenomenon originates from band structure modifications driven by energy-level transitions. Furthermore, the observed photocurrent enhancement via sliding ferroelectricity demonstrates universality across diverse platinum-based optoelectronic devices. This study introduces a novel paradigm for tailoring the intrinsic characteristics of 2D vdW semiconductors, expanding the design space for next-generation ferroelectric materials in advanced optoelectronic applications.
基金supported by National Natural Science Foundation of China (Nos.52377141 and 92371105)。
文摘Dielectric barrier discharges(DBDs)are primarily utilized as efficient sources of large-volume diffuse plasmas.However,the synergistic interaction of certain key plasma factors limits their broader application.In the present paper,we report numerical investigations of the effects of voltage amplitude in dual-frequency excitation on atmospheric DBDs using a 50 kHz/5 MHz frequency combination.Our results indicate that varying the voltages for low frequency(LF)and radio frequency(RF)significantly influences the electron dynamics during discharge,resulting in distinct spatio-temporal distributions of electron and metastable particle densities.These findings contribute to the regulation of discharges under atmospheric pressure conditions and facilitate the attainment of non-equilibrium and nonlinear plasma parameters.
