The ionic conductivity in high-performance solid-state electrolytes can reach 10^(-2) S cm^(-1) that is equivalent to the conductivity of liquid electrolytes,which has greatly promoted the vigorous development of quas...The ionic conductivity in high-performance solid-state electrolytes can reach 10^(-2) S cm^(-1) that is equivalent to the conductivity of liquid electrolytes,which has greatly promoted the vigorous development of quasi-solid-state batteries and all-solid-state batteries.Whether in polymer electrolytes,inorganic crystal electrolytes or composite solid electrolytes,the rapid transport mechanism of lithium-ion is the essential criterion used to guide high-performance solid electrolyte design.A comprehensive understanding of the rapid lithium-ion transport mechanism requires to focus on the structural characteristics of the material and developing relevant simulation methods to reveal the structure-activity relationship in rapid ion transport.展开更多
基金supported by the National Natural Science Foundation of China(Nos.22308096,22278127,and 22378112)Shanghai Pilot Program for Basic Research(22T01400100-18)the National Key Research and Development Program of China(No.2022YFB4602101).
文摘The ionic conductivity in high-performance solid-state electrolytes can reach 10^(-2) S cm^(-1) that is equivalent to the conductivity of liquid electrolytes,which has greatly promoted the vigorous development of quasi-solid-state batteries and all-solid-state batteries.Whether in polymer electrolytes,inorganic crystal electrolytes or composite solid electrolytes,the rapid transport mechanism of lithium-ion is the essential criterion used to guide high-performance solid electrolyte design.A comprehensive understanding of the rapid lithium-ion transport mechanism requires to focus on the structural characteristics of the material and developing relevant simulation methods to reveal the structure-activity relationship in rapid ion transport.
