The oxygen evolution reaction with its high energy barrier on the anode during water electrolysis is the main factor limiting its large-scale application.A viable strategy is to explore anode substitution reactions to...The oxygen evolution reaction with its high energy barrier on the anode during water electrolysis is the main factor limiting its large-scale application.A viable strategy is to explore anode substitution reactions to replace the oxygen evolution reaction in water electrolysis.In this study,the selective electrooxidation of tetrahydroisoquinoline(THIQ)was demonstrated on a specially designed and prepared Cu2S electrode,which was coupled with the hydrogen evolution reaction.展开更多
Highly active,ultra-long duration and cost-effective catalysts are imminently required for the development of electrolytic appliances for H2 generation.Herein,we propose a novel and facile strategy to fabricate P dope...Highly active,ultra-long duration and cost-effective catalysts are imminently required for the development of electrolytic appliances for H2 generation.Herein,we propose a novel and facile strategy to fabricate P doped CoS2 nanosheet arrays on carbon cloth(Co-S-P/CC)as bifunctional electrocatalysts toward hybrid water electrolysis,in which the tardy anodic oxygen evolution reaction(OER)is substituted by a more favorable kinetic and thermodynamic ethanol oxidation reaction(EOR).展开更多
基金the National Natural Science Foundation of China(No.21776115)for the project supported by the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing(Wuhan University of Technology)the project from the Key Laboratory of Advanced Electrode Materials for Novel Solar Cells for the Petroleum and Chemical Industry of China,School of Chemistry and Life Sciences(Suzhou University of Science and Technology).
文摘The oxygen evolution reaction with its high energy barrier on the anode during water electrolysis is the main factor limiting its large-scale application.A viable strategy is to explore anode substitution reactions to replace the oxygen evolution reaction in water electrolysis.In this study,the selective electrooxidation of tetrahydroisoquinoline(THIQ)was demonstrated on a specially designed and prepared Cu2S electrode,which was coupled with the hydrogen evolution reaction.
基金supported by the National Natural Science Foundation of China(51672056)the Excellent Youth Project of the Natural Science Foundation of Heilongjiang Province of China(YQ2019B002)the Fundamental Research Funds for the Central Universities(3072020CF1018).
文摘Highly active,ultra-long duration and cost-effective catalysts are imminently required for the development of electrolytic appliances for H2 generation.Herein,we propose a novel and facile strategy to fabricate P doped CoS2 nanosheet arrays on carbon cloth(Co-S-P/CC)as bifunctional electrocatalysts toward hybrid water electrolysis,in which the tardy anodic oxygen evolution reaction(OER)is substituted by a more favorable kinetic and thermodynamic ethanol oxidation reaction(EOR).
