In this paper a pH microprobe technique was developed to measure in-situ the pH value at the electrode/solution interface. Iridium oxide was used as a pH sensitive material with good response behavior in the measured ...In this paper a pH microprobe technique was developed to measure in-situ the pH value at the electrode/solution interface. Iridium oxide was used as a pH sensitive material with good response behavior in the measured solutions. The experimental results indicated that the interfacial pH increased with the applied potential, first jumped to a maximum, then slowly decreased at the controlled potential during the electrodeposition process of functional ceramics.展开更多
The low specific capacitances(SCs)of traditional carbonaceous negative electrodes significantly limit the enhancement in energy density of aqueous hybrid supercapacitors(AHCs).It is still hugely challengeable to explo...The low specific capacitances(SCs)of traditional carbonaceous negative electrodes significantly limit the enhancement in energy density of aqueous hybrid supercapacitors(AHCs).It is still hugely challengeable to explore a candidate with large SCs,which can stably operate in the negative potential region mean-while.For this propose,we design and fabricate solid-solution Ru_(x)Cu_(1-x)O_(2) nanocrystals(NCs),which exhibit competitive SCs and electrochemical stability within the potential range from-0.9 V to 0.0 V in the aqueous KOH electrolyte.The incorporation of Cu enhances the electrochemical utilization of RuO_(2),reaction kinetics,electronic conductivity,and hydrogen evolution overpotentials,which are all highly dependent upon the added contents of Cu species.The optimized Ru_(0.8)Cu_(0.2)O_(2)(RuCu82)electrode of a high mass loading of 5 mg cm^(-2) reveals the best electrochemical capacitances in terms of reversible SCs and capacitance degradation at room temperature and-20℃.Furthermore,the reversible K^(+)-(de)intercalation induced pseudocapacitance is proposed for electrochemical charge storage process of RuCu82.In particu-lar,remarkable specific energy of 59.1 Wh kg-1 at 400 W kg-1 and excellent cycling stability are achieved in the assembled NiCoO_(2)//RuCu82 AHCs.Our contribution here presents a new promising negative elec-trode platform with high SCs and electrochemical stability for next-generation AHCs.展开更多
Theoretical simulations on complex electrochemical processes have been developed on the basis of the understanding in electrochemistry,which has benefited from quantum mechanics calculations.This article reviews the r...Theoretical simulations on complex electrochemical processes have been developed on the basis of the understanding in electrochemistry,which has benefited from quantum mechanics calculations.This article reviews the recent progress on the theory and applications in electrocatalysis.Two representative reactions,namely water electrolysis and oxygen reduction,are selected to illustrate how the theoretical methods are applied to electrocatalytic reactions.The microscopic nature of these electrochemical reactions under the applied potentials is described and the understanding of the reactions is summarized.The thermodynamics and kinetics of the electrochemical reactions affected by the interplay of the electrochemical potential,the bonding strength and the local surface structure are addressed at the atomic level.展开更多
As-Sb alloy was electrodeposited from high arsenic-containing solutions. The influences of current density, Sb（3＋） concentration, reaction temperature and HCl concentration on the electrolyte composition, cell volt...As-Sb alloy was electrodeposited from high arsenic-containing solutions. The influences of current density, Sb（3＋） concentration, reaction temperature and HCl concentration on the electrolyte composition, cell voltage and current efficiency were investigated. The surface morphology, composition and structure of the deposits were analyzed by scanning electron microscopy（SEM）, inductively coupled plasma mass spectrometry（ICP-MS） and X-ray diffraction（XRD）, respectively. The results show that the prepared As-Sb alloy shows an amorphous structure under all conditions. Under the optimized condition, i.e., 10 g/L As（3＋）, 2 g/L Sb（3＋）, 4 mol/L HCl, current density of 4 mA/cm2 and temperature of 20 °C, desired As-Sb alloy with a composition of 70.26% As and 29.74% Sb（mass fraction） is obtained. What is more, the current efficiency is as high as 94.74% and high arsenic removal rate is achieved under this condition.展开更多
Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of va...Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of vanadium species on conventional carbon electrodes remains a major limitation to their performance.We investigated the deposition of carbon black,carbon nanotubes,and electrochemically exfoliated graphene(Exf-Gr)onto thermally-activated carbon paper(ACP)by spray coating to increase the electrode electrocatalytic activity.The modified electrodes were characterized using scanning electron microscopy,X-ray diffraction,Raman spectroscopy,X-ray photoelectron microscopy,and surface area analysis,while their electrochemical properties were evaluated by cyclic voltammetry,electrochemical impedance spectroscopy,and singlecell VRFB testing.Among the modified electrodes,Exf-Gr/ACP had the best performance,achieving a 2.9-fold reduction in charge transfer resistance compared to pristine ACP and delivering 2.5 times the discharge capacity in single-cell tests.This improvement is attributed to Exf-Gr’s high surface area,favorable catalytic activity,and excellent dispersion on the ACP substrate.Surface modification with electrochemically exfoliated graphene is a highly effective strategy for improving the electrode performance in VRFB systems,with significant implications for large-scale energy storage.展开更多
In this study,FeCr_(x)MnAlCu(x=0,0.5,1.0,1.5,2.0)high-entropy alloys were fabricated using vacuum arc melting,and the corrosion behavior of these alloys in 3.5wt%NaCl solution at room temperature was investigated by e...In this study,FeCr_(x)MnAlCu(x=0,0.5,1.0,1.5,2.0)high-entropy alloys were fabricated using vacuum arc melting,and the corrosion behavior of these alloys in 3.5wt%NaCl solution at room temperature was investigated by electrochemical dynamic potential polarization curves and immersion experiments.The microstructure results show that the high-entropy alloy with x=0 has a body-centered cubic phase structure,whereas the high-entropy alloys with x=0.5–2.0 have a mixed face-centered cubic+body-centered cubic dual-phase structure.The corrosion results show that the corrosion resistance of the high-entropy alloy is increased with the increase in Cr content.Among them,the high-entropy alloy with x=2.0 exhibits the optimal corrosion resistance:the highest self-corrosion potential(E_(corr)=−0.354 V vs.Ag/AgCl),the smallest self-corrosion current density(I_(corr)=1.991×10^(−6)A·cm^(−2)),and the smallest corrosion rate(0.0292 mm/a).The composite passivation film of oxides and hydroxides is formed on the surface of the corroded high-entropy alloys,and the Cr_(2)O_(3)content is increased with the increase in Cr content,which effectively improves the stability and protective properties of the passivation film.展开更多
The development of shape-customizable and bulk flexible electrochemical devices through processing technologies as versatile as those used for plastics promises to revolutionize the future of battery technology.Howeve...The development of shape-customizable and bulk flexible electrochemical devices through processing technologies as versatile as those used for plastics promises to revolutionize the future of battery technology.However,this pursuit has been fundamentally hindered by the absence of transformative battery materials capable of delivering the necessary electrochemical functions,robust interface adhesion,and,crucially,the suitable rheological properties required for on-demand shaping.In this work,we introduce a concept of a multifunctional plasticine electrode matrix(PEM)featuring nano-interpenetrating networks(nano-IPN)to address this challenge.Utilizing the nonflammable liquid-electrolyte hydration combined with conductive nanomaterials,we have realized a PEM in the form of a multifunctional nanocomposite that integrates ion and electron conduction,component binding,non-flammability,and plasticine-like moldability.With this PEM,we have successfully fabricated a variety of bulk-flexible electrodes with high mass loading of active material(AM)(>70 wt%)using industry-friendly extrusion and compression molding techniques.Moreover,these high AM-loading composite electrodes achieve an unparalleled bulk conformability and flexibility,remaining structurally intact even under severe mechanical stress.Ultimately,we have successfully produced shape-patternable and flexible batteries via extrusion molding.This study underscores the potential of the PEM to revolutionize battery microstructures,interfaces,manufacturing processes,and performance characteristics.展开更多
In this study,a straightforward one-step hydrothermal method was successfully utilized to synthesize the solid solution Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)(NNMTO-x),where x denotes the molar perce...In this study,a straightforward one-step hydrothermal method was successfully utilized to synthesize the solid solution Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)(NNMTO-x),where x denotes the molar percentage of Na_(2)Ni_(2)Ti_(6)O_(16)(NNTO)within Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)(NMTO),with x values of 10,20,30,40,and 50.Both XPS(X-ray Photoelectron Spectroscopy)and EDX(Energy Dispersive X-ray Spectroscopy)analyses unequivocally validated the formation of the NNMTO-x solid solutions.It was observed that when x is below 40,the NNMTO-x solid solution retains the structural characteristics of the original NMTO.However,beyond this threshold,significant alterations in crystal morphology were noted,accompanied by a noticeable decline in photocatalytic activity.Notably,the absorption edge of NNMTO-x(x<40)exhibited a shift towards the visible-light spectrum,thereby substantially broadening the absorption range.The findings highlight that NNMTO-30 possesses the most pronounced photocatalytic activity for the reduction of CO_(2).Specifically,after a 6 h irradiation period,the production rates of CO and CH_(4)were recorded at 42.38 and 1.47μmol/g,respectively.This investigation provides pivotal insights that are instrumental in the advancement of highly efficient and stable photocatalysts tailored for CO_(2)reduction processes.展开更多
To investigate the effect of solution treatment and aging process parameters on the microstructure and mechanical properties of TB18 titanium alloy,process optimization research was conducted based on the mixed-level ...To investigate the effect of solution treatment and aging process parameters on the microstructure and mechanical properties of TB18 titanium alloy,process optimization research was conducted based on the mixed-level orthogonal experiment design of factor levels.Results show that through range analysis,the significance order of process parameters is determined as follows:solution cooling method>solution temperature>aging time>aging temperature>solution time.Considering the strength-ductility matching and engineering application requirements,the benchmark parameters are selected as solution time of 1 h,solution cooling method of air cooling(AC),aging temperature of 525℃,and aging time of 4 h.Furthermore,the effects of solution temperature in the range of 790–870℃ on the impact toughness and micro-fracture characteristics of the alloy were studied.The results reveal that the larger the area of shear lip and fibrous zone,and the smaller the area of radiation zone,the better the toughness of the alloy.With the increase in solution temperature,the length of secondary cracks on the fracture surface increases,the number of dimples increases,and the toughness is enhanced.Based on the collaborative optimization of strength and toughness,the optimal heat treatment process for TB18 alloy is determined as 870℃/1 h,AC+525℃/4 h,AC.展开更多
In this paper,we consider a Schr¨odinger-Poisson system with sublinear nonlinearity.The growth of nonlinearity depends on potential function and a bounded function.We first obtain the existence of nontrivial solu...In this paper,we consider a Schr¨odinger-Poisson system with sublinear nonlinearity.The growth of nonlinearity depends on potential function and a bounded function.We first obtain the existence of nontrivial solution sequence with negative energy for the system via a variant Clark’s theorem.Then we get the asymptotical property of the solution sequence by L∞norm.展开更多
Metals,indispensable since the Bronze Age,remain pivotal in modern technologies due to their exceptional properties and versatility.Beyond traditional machining,advanced nano/micro-machining techniques enable the fabr...Metals,indispensable since the Bronze Age,remain pivotal in modern technologies due to their exceptional properties and versatility.Beyond traditional machining,advanced nano/micro-machining techniques enable the fabrication of metallic nano/micro structures with high precision in shape,size,and pattern.These structures endow flexible electrodes with outstanding electrical,mechanical,optical,and electrochemical performance,enabling growing applications in flexible optoelectronics,epidermal electronics,energy harvesting,and biochemical sensing.This review provides a comprehensive overview of the fabrication strategies for flexible electrodes made from metal meshes,metal nanowires,and liquid metals.The current advancements,existing challenges,and emerging technologies are systematically discussed.Furthermore,the progression toward ultra-thin,soft epidermal electrodes is explored,with an emphasis on novel in situ and transfer fabrication methods.We examine the underlying mechanisms,performance indicators,and their integration for on-skin applications,including bioelectric sensing,electrical stimulation,and energy harvesting.Finally,we highlight the remaining challenges in performance improvement and industrialization of flexible and epidermal electrodes,along with future opportunities for integrating multimodal systems and leveraging artificial intelligence to enhance their functionalities.展开更多
This study investigates the dimensionless quasi-geostrophic potential vorticity(QG-PV)equation with external sources.Employing the Gardner-Morikawa transformation and weakly nonlinear perturbation expansion,we derive ...This study investigates the dimensionless quasi-geostrophic potential vorticity(QG-PV)equation with external sources.Employing the Gardner-Morikawa transformation and weakly nonlinear perturbation expansion,we derive the nonlinear Boussinesq equation with external sources.We demonstrate the existence of explicit zero-order and first-order Wronskian solutions for the model equation whenα_4=0.Furthermore,using a modified Jacobi elliptic function method,we obtain soliton-like solutions for bothα_4=0 andα_4≠0.Analysis of these solutions reveals that the generalizedβ-plane approximation and shear flow are significant factors in inducing nonlinear Rossby waves,and that external sources play a crucial role in influencing Rossby wave behavior.展开更多
As the carrier of charge storage,the electrode determines the efficiency of the energy conversion reaction between the battery and the substance.However,with the continuous development of scientific research,electrode...As the carrier of charge storage,the electrode determines the efficiency of the energy conversion reaction between the battery and the substance.However,with the continuous development of scientific research,electrode preparation is still facing complex technical problems,and it is difficult to achieve a balance in performance,cost,and technology.Based on the ion dissolution and deposition behavior of Mn^(2+)/MnO_(2) and Al^(3+)/Al,a novel cathode-free aqueous ion dissolution/deposition battery is designed,which can contribute 15 mAh at 16 cm^(2) in a voltage window of 0.5-1.8 V.The charge storage and the attenuation mechanism are systematically investigated.The battery model with compensable electrolyte was constructed,and the cycle characteristics of the cathode-free aqueous ion dissolution/deposition battery were optimized,which could achieve 1000 h continuous operation.This system provides a low-cost and high-safety solution for future high-energy density and large-scale energy storage.Future research will focus on optimizing electrolytes,controlling deposition morphology,and improving interface stability to further promote the commercialization of cathode-free batteries.展开更多
Hydrothermal carbonization(HTC)is a promising techno-economic method for biomass waste valorization owing to its advantages over other thermochemical processes.This study focused on carbon sequestration from sugarcane...Hydrothermal carbonization(HTC)is a promising techno-economic method for biomass waste valorization owing to its advantages over other thermochemical processes.This study focused on carbon sequestration from sugarcane bioethanol distillery wastewater via HTC and chemical activation to produce activated carbon(AC).The resulting AC was then applied as an active material for supercapacitor electrodes.The introduction of redox molecules,such as 1,4-anthraquinone(AQ)and 9,10-phenanthrenequinone(PQ),on AC increased charge storage capability via redox transformation and enhanced the electrochemical performance of the supercapacitor elec-trode.Electrochemical testing showed that AC loaded with 16 wt%PQ achieved the highest specific capacitance of 488.21 F g^(-1) with remarkable capacitance retention of 95.3% after 1000 charge-discharge cycles.N-doped AC obtained from the HTC of wastewater and melamine presented a slightly enhanced specific capacitance.Various commercial LEDs with a voltage range of 1.8-3.0 V were illuminated simultaneously by connecting them to two series of symmetric supercapacitors,demonstrating the potential application of our proposed strategy in energy storage systems.This study proposes a simple and efficient strategy to utilize wastewater and achieve net-zero emission goals in a Bio-Circular-Green Economy model.展开更多
Let A be a 3×3 singular or diagonalizable matrix,all solutions to the Yang-Baxter-like matrix equation have been determined.However,finding all solutions for full rank,non-diagonalizable matrices remains challeng...Let A be a 3×3 singular or diagonalizable matrix,all solutions to the Yang-Baxter-like matrix equation have been determined.However,finding all solutions for full rank,non-diagonalizable matrices remains challenging.By utilizing classification techniques,we establish all solutions of the Yang-Baxter-like matrix equation in this paper when the coefficient matrix A is similar to non-diagonalizable matrix diag(λ,J_(2)(λ))withλ̸=0.More specifically,we divide the non-diagonal elements of the solution into 10 different cases.By discussing each situation,we establish all solutions of the Yang-Baxter-like matrix equation.The results of this work enrich the existing ones.展开更多
Strategies for achieving high-energy-density lithium-ion batteries include using high-capacity materials such as high-nickel NCM,increasing the active material content in the electrode by utilizing high-conductivity c...Strategies for achieving high-energy-density lithium-ion batteries include using high-capacity materials such as high-nickel NCM,increasing the active material content in the electrode by utilizing high-conductivity carbon nanotubes(CNT)conductive materials,and electrode thickening.However,these methods are still limited due to the limitation in the capacity of high-nickel NCM,aggregation of CNT conductive materials,and nonuniform material distribution of thick-film electrodes,which ultimately damage the mechanical and electrical integrity of the electrode,leading to a decrease in electrochemical performance.Here,we present an integrated binder-CNT composite dispersion solution to realize a high-solids-content(>77 wt%)slurry for high-mass-loading electrodes and to mitigate the migration of binder and conductive additives.Indeed,the approach reduces solvent usage by approximately 30%and ensures uniform conductive additive-binder domain distribution during electrode manufacturing,resulting in improved coating quality and adhesive strength for high-mass-loading electrodes(>12 mAh cm^(−2)).In terms of various electrode properties,the presented electrode showed low resistance and excellent electrochemical properties despite the low CNT contents of 0.6 wt%compared to the pristine-applied electrode with 0.85 wt%CNT contents.Moreover,our strategy enables faster drying,which increases the coating speed,thereby offering potential energy savings and supporting carbon neutrality in wet-based electrode manufacturing processes.展开更多
Objective:To investigate the spatial gradient of intraoperative impedance across the cochlear electrode array in pediatric cochlear implant recipients and assess its potential as a physiological indicator for the elec...Objective:To investigate the spatial gradient of intraoperative impedance across the cochlear electrode array in pediatric cochlear implant recipients and assess its potential as a physiological indicator for the electrode-neural interface.Methods:A prospective observational study involving 56 pediatric patients underwent cochlear implantation with Cochlear Nucleus devices.Intraoperative polarized impedance and electrically evoked compound action potential(ECAP)threshold were recorded across all 1232 electrodes using AutoNRT software.Eight electrodes with open-or short-circuit were excluded,leaving 1,224 for analysis.Impedance values were categorized by cochlear region(basal,middle,apical),and electrodes with elevated impedance(10-20 kΩ)were analyzed for regional distribution and clinical relevance.Data were analyzed for spatial patterns and correlation with the ECAP threshold profiles.Results:A consistent basal-to-apical increase in impedance was observed(7.7±1.9,9.2±1.4,10.8±1.5 kΩ;p<0.001).Impedance and ECAP threshold were weakly correlated(ρ=-0.20,p<0.001;β=-1.26,p<0.001),with a positive association in the apical region(ρ=0.12,p=0.048).Electrodes with higher impedance(1020 kΩ)were less likely to show elevated or absent TNRT(OR=0.175,p=0.02).The impedance gradient persisted across age groups and was significantly correlated with ECAP threshold patterns.Conclusion:Intraoperative impedance monitoring reveals a strong and physiologically consistent gradient,with higher values in apical electrodes.This gradient reflects anatomical and tissue interface variations,which may offer a valuable physiological indicator for intraoperative electrode positioning and neural interface integrity.展开更多
Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that p...Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that possess both high thermopower and rapid redox kinetics.This work addresses this challenge by leveraging our recently developed copper(Ⅰ/Ⅱ)(Cu^(+)/Cu^(2+))redox couple.We significantly enhance the performance of Cu-based liquid thermocells by integrating a thermosensitive crystallization process with etched carbon cloth electrodes,achieving synergistic improvements in thermodynamic and kinetic performance.The thermosensitive crystallization process establishes a persistent Cu^(2+)concentration gradient,boosting the thermopower from 1.47 to 2.93 mV K^(-1).Moreover,the etched carbon cloth electrodes provide a larger electroactive surface area and demonstrate a higher current density.Consequently,the optimized Cu^(+)/Cu^(2+)system achieved an exceptional normalized power density P_(max)(ΔT)^(-2)of 3.97 mW m^(-2)K^(-2).A thermocell module comprised of 20 cells directly power various electronic devices at a temperature difference of 40 K.This work successfully exhibits potential of Cu^(+)/Cu^(2+)redox couple in thermoelectric conversion and introduces a valuable redox couple for highperformance thermocells.展开更多
Aqueous hydrogen(H_(2))gas batteries with unmatched lifespan are ideal for grid-scale energy storage,yet their deployment remains limited by the lack of low-cost,efficient,and durable hydrogen electrodes.Here,we repor...Aqueous hydrogen(H_(2))gas batteries with unmatched lifespan are ideal for grid-scale energy storage,yet their deployment remains limited by the lack of low-cost,efficient,and durable hydrogen electrodes.Here,we report a high-throughput and durable gas diffusion electrode(GDE)based on a simply preparable carbon-coated nickel(Ni@C)catalyst and the design of H_(2) diffusion channels.By optimizing the carbon layer structure,a balance between the intrinsic activity and stability of the catalyst can be achieved.This Ni@C catalyst exhibits a hydrogen oxidation reaction(HOR)activity of 44 A g^(-1) as well as remarkable hydrogen evolution reaction(HER)performance.Experimental results and theoretical calculations confirm the electronic interaction between the carbon shell and Ni.In combination with a hydrophobic design,a robust and durable Ni@C-GDE has been fabricated.This electrode achieves a low HOR polarization of only 91 mV at 30 mA cm^(-2),outperforming Pt/C-GDE(154 mV),and operates stably over 4500cycles(3200 h)for HOR/HER reversing.Enabled by this electrode,a 10 Ah Ni-H_(2) battery with an energy density of 156.3 Wh kg^(-1) and cost of 62.2$kWh^(-1) is demonstrated.This work offers a viable strategy for practical and scalable hydrogen gas batteries.展开更多
Driven by the trend of device miniaturization and high-density integration,the interaction between adjacent electrodes has become a critical factor affecting the interfacial reliability of thermoelectric(TE)structures...Driven by the trend of device miniaturization and high-density integration,the interaction between adjacent electrodes has become a critical factor affecting the interfacial reliability of thermoelectric(TE)structures.This study investigates the influence of adjoining electrode interactions on the interfacial response of a multi-electrode/TE substrate structure,including interfacial stresses and stress intensity factors at the electrode ends.To solve the corresponding boundary-value problem,the Fourier transforms are adopted to derive a governing integro-differential equation for the interfacial shear stress in multi-electrode systems,incorporating the TE effects as generalized forces on the right-hand side.The results show that both the interfacial tension and transverse stress in the electrodes are significantly affected by the presence of adjacent electrodes.The interaction between neighboring electrodes diminishes as their spacing increases or when an adhesive interlayer is introduced.Furthermore,the softer and thinner electrodes,the softer and thicker adhesive interlayer,and the smaller TE loads are found to be beneficial for improving the interfacial performance.These findings may contribute to the accurate measurement in surface sensors and layout design of multi-point health monitoring systems for TE structures.展开更多
文摘In this paper a pH microprobe technique was developed to measure in-situ the pH value at the electrode/solution interface. Iridium oxide was used as a pH sensitive material with good response behavior in the measured solutions. The experimental results indicated that the interfacial pH increased with the applied potential, first jumped to a maximum, then slowly decreased at the controlled potential during the electrodeposition process of functional ceramics.
基金supported by the National Natural Science Foundation of China(Nos.U22A20145,51904115,52072151,52171211,and 52271218)Jinan Independent Innovative Team(No.2020GXRC015)the Major Program of Shandong Province Natural Science Foundation(Nos.ZR2023ZD43 and ZR2021ZD05).
文摘The low specific capacitances(SCs)of traditional carbonaceous negative electrodes significantly limit the enhancement in energy density of aqueous hybrid supercapacitors(AHCs).It is still hugely challengeable to explore a candidate with large SCs,which can stably operate in the negative potential region mean-while.For this propose,we design and fabricate solid-solution Ru_(x)Cu_(1-x)O_(2) nanocrystals(NCs),which exhibit competitive SCs and electrochemical stability within the potential range from-0.9 V to 0.0 V in the aqueous KOH electrolyte.The incorporation of Cu enhances the electrochemical utilization of RuO_(2),reaction kinetics,electronic conductivity,and hydrogen evolution overpotentials,which are all highly dependent upon the added contents of Cu species.The optimized Ru_(0.8)Cu_(0.2)O_(2)(RuCu82)electrode of a high mass loading of 5 mg cm^(-2) reveals the best electrochemical capacitances in terms of reversible SCs and capacitance degradation at room temperature and-20℃.Furthermore,the reversible K^(+)-(de)intercalation induced pseudocapacitance is proposed for electrochemical charge storage process of RuCu82.In particu-lar,remarkable specific energy of 59.1 Wh kg-1 at 400 W kg-1 and excellent cycling stability are achieved in the assembled NiCoO_(2)//RuCu82 AHCs.Our contribution here presents a new promising negative elec-trode platform with high SCs and electrochemical stability for next-generation AHCs.
基金supported by the National Natural Science Foundation of China (Grant Nos 20825311, 20773026, and 20721063)Sci & Tech Comm of Shanghai Municipality (08DZ2270500)Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institute of Higher Learning
文摘Theoretical simulations on complex electrochemical processes have been developed on the basis of the understanding in electrochemistry,which has benefited from quantum mechanics calculations.This article reviews the recent progress on the theory and applications in electrocatalysis.Two representative reactions,namely water electrolysis and oxygen reduction,are selected to illustrate how the theoretical methods are applied to electrocatalytic reactions.The microscopic nature of these electrochemical reactions under the applied potentials is described and the understanding of the reactions is summarized.The thermodynamics and kinetics of the electrochemical reactions affected by the interplay of the electrochemical potential,the bonding strength and the local surface structure are addressed at the atomic level.
基金Project(51374185) supported by the National Natural Science Foundation of China
文摘As-Sb alloy was electrodeposited from high arsenic-containing solutions. The influences of current density, Sb（3＋） concentration, reaction temperature and HCl concentration on the electrolyte composition, cell voltage and current efficiency were investigated. The surface morphology, composition and structure of the deposits were analyzed by scanning electron microscopy（SEM）, inductively coupled plasma mass spectrometry（ICP-MS） and X-ray diffraction（XRD）, respectively. The results show that the prepared As-Sb alloy shows an amorphous structure under all conditions. Under the optimized condition, i.e., 10 g/L As（3＋）, 2 g/L Sb（3＋）, 4 mol/L HCl, current density of 4 mA/cm2 and temperature of 20 °C, desired As-Sb alloy with a composition of 70.26% As and 29.74% Sb（mass fraction） is obtained. What is more, the current efficiency is as high as 94.74% and high arsenic removal rate is achieved under this condition.
基金supported by the University of Seoul’s 2025 Research Fund.
文摘Vanadium redox flow batteries(VRFBs)are a means of large-scale energy storage due to their excellent scalability,safety,long cycling life,and decoupled power and energy capacities.However,the slow redox kinetics of vanadium species on conventional carbon electrodes remains a major limitation to their performance.We investigated the deposition of carbon black,carbon nanotubes,and electrochemically exfoliated graphene(Exf-Gr)onto thermally-activated carbon paper(ACP)by spray coating to increase the electrode electrocatalytic activity.The modified electrodes were characterized using scanning electron microscopy,X-ray diffraction,Raman spectroscopy,X-ray photoelectron microscopy,and surface area analysis,while their electrochemical properties were evaluated by cyclic voltammetry,electrochemical impedance spectroscopy,and singlecell VRFB testing.Among the modified electrodes,Exf-Gr/ACP had the best performance,achieving a 2.9-fold reduction in charge transfer resistance compared to pristine ACP and delivering 2.5 times the discharge capacity in single-cell tests.This improvement is attributed to Exf-Gr’s high surface area,favorable catalytic activity,and excellent dispersion on the ACP substrate.Surface modification with electrochemically exfoliated graphene is a highly effective strategy for improving the electrode performance in VRFB systems,with significant implications for large-scale energy storage.
基金Gansu Provincial Science and Technology Major Special Program(24ZDWA008)Fourth Batch of Top Leading Talents Fund Projects in Gansu Province(ZZ2023G50100013)。
文摘In this study,FeCr_(x)MnAlCu(x=0,0.5,1.0,1.5,2.0)high-entropy alloys were fabricated using vacuum arc melting,and the corrosion behavior of these alloys in 3.5wt%NaCl solution at room temperature was investigated by electrochemical dynamic potential polarization curves and immersion experiments.The microstructure results show that the high-entropy alloy with x=0 has a body-centered cubic phase structure,whereas the high-entropy alloys with x=0.5–2.0 have a mixed face-centered cubic+body-centered cubic dual-phase structure.The corrosion results show that the corrosion resistance of the high-entropy alloy is increased with the increase in Cr content.Among them,the high-entropy alloy with x=2.0 exhibits the optimal corrosion resistance:the highest self-corrosion potential(E_(corr)=−0.354 V vs.Ag/AgCl),the smallest self-corrosion current density(I_(corr)=1.991×10^(−6)A·cm^(−2)),and the smallest corrosion rate(0.0292 mm/a).The composite passivation film of oxides and hydroxides is formed on the surface of the corroded high-entropy alloys,and the Cr_(2)O_(3)content is increased with the increase in Cr content,which effectively improves the stability and protective properties of the passivation film.
基金financial support from the National Natural Science Foundation of China(52473248,52203123,52125301,22279070 and U21A20170)the State Key Laboratory of Polymer Materials Engineering(Grant No:sklpme 2023-1-05 and sklpme 2024-2-04)+3 种基金the Ministry of Science and Technology of China(No.2019YFA0705703)the Sichuan Science and Technology Program(2023NSFSC0991 and 2025ZNSFSC1411)the Fundamental Research Funds for the Central Universitiespartially sponsored by the Double First-Class Construction Funds of Sichuan University.
文摘The development of shape-customizable and bulk flexible electrochemical devices through processing technologies as versatile as those used for plastics promises to revolutionize the future of battery technology.However,this pursuit has been fundamentally hindered by the absence of transformative battery materials capable of delivering the necessary electrochemical functions,robust interface adhesion,and,crucially,the suitable rheological properties required for on-demand shaping.In this work,we introduce a concept of a multifunctional plasticine electrode matrix(PEM)featuring nano-interpenetrating networks(nano-IPN)to address this challenge.Utilizing the nonflammable liquid-electrolyte hydration combined with conductive nanomaterials,we have realized a PEM in the form of a multifunctional nanocomposite that integrates ion and electron conduction,component binding,non-flammability,and plasticine-like moldability.With this PEM,we have successfully fabricated a variety of bulk-flexible electrodes with high mass loading of active material(AM)(>70 wt%)using industry-friendly extrusion and compression molding techniques.Moreover,these high AM-loading composite electrodes achieve an unparalleled bulk conformability and flexibility,remaining structurally intact even under severe mechanical stress.Ultimately,we have successfully produced shape-patternable and flexible batteries via extrusion molding.This study underscores the potential of the PEM to revolutionize battery microstructures,interfaces,manufacturing processes,and performance characteristics.
基金Supported by the Doctoral Research Start-up Project of Yuncheng University(YQ-2023067)Project of Shanxi Natural Science Foundation(202303021211189)+1 种基金Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Provinces(20220036)Shanxi ProvinceIntelligent Optoelectronic Sensing Application Technology Innovation Center and Shanxi Province Optoelectronic Information Science and TechnologyLaboratory,Yuncheng University.
文摘In this study,a straightforward one-step hydrothermal method was successfully utilized to synthesize the solid solution Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)-Na_(2)Ni_(2)Ti_(6)O_(16)(NNMTO-x),where x denotes the molar percentage of Na_(2)Ni_(2)Ti_(6)O_(16)(NNTO)within Na_(0.9)Mg_(0.45)Ti_(3.55)O_(8)(NMTO),with x values of 10,20,30,40,and 50.Both XPS(X-ray Photoelectron Spectroscopy)and EDX(Energy Dispersive X-ray Spectroscopy)analyses unequivocally validated the formation of the NNMTO-x solid solutions.It was observed that when x is below 40,the NNMTO-x solid solution retains the structural characteristics of the original NMTO.However,beyond this threshold,significant alterations in crystal morphology were noted,accompanied by a noticeable decline in photocatalytic activity.Notably,the absorption edge of NNMTO-x(x<40)exhibited a shift towards the visible-light spectrum,thereby substantially broadening the absorption range.The findings highlight that NNMTO-30 possesses the most pronounced photocatalytic activity for the reduction of CO_(2).Specifically,after a 6 h irradiation period,the production rates of CO and CH_(4)were recorded at 42.38 and 1.47μmol/g,respectively.This investigation provides pivotal insights that are instrumental in the advancement of highly efficient and stable photocatalysts tailored for CO_(2)reduction processes.
基金Key Program of National Natural Science Foundation of China(52431001)。
文摘To investigate the effect of solution treatment and aging process parameters on the microstructure and mechanical properties of TB18 titanium alloy,process optimization research was conducted based on the mixed-level orthogonal experiment design of factor levels.Results show that through range analysis,the significance order of process parameters is determined as follows:solution cooling method>solution temperature>aging time>aging temperature>solution time.Considering the strength-ductility matching and engineering application requirements,the benchmark parameters are selected as solution time of 1 h,solution cooling method of air cooling(AC),aging temperature of 525℃,and aging time of 4 h.Furthermore,the effects of solution temperature in the range of 790–870℃ on the impact toughness and micro-fracture characteristics of the alloy were studied.The results reveal that the larger the area of shear lip and fibrous zone,and the smaller the area of radiation zone,the better the toughness of the alloy.With the increase in solution temperature,the length of secondary cracks on the fracture surface increases,the number of dimples increases,and the toughness is enhanced.Based on the collaborative optimization of strength and toughness,the optimal heat treatment process for TB18 alloy is determined as 870℃/1 h,AC+525℃/4 h,AC.
基金Supported by the National Natural Science Foundation of China(12226412)Natural Science Foundation of Jiangsu Province(BK20221339)。
文摘In this paper,we consider a Schr¨odinger-Poisson system with sublinear nonlinearity.The growth of nonlinearity depends on potential function and a bounded function.We first obtain the existence of nontrivial solution sequence with negative energy for the system via a variant Clark’s theorem.Then we get the asymptotical property of the solution sequence by L∞norm.
基金supported by the Basic and Applied Basic Research Foundation of Guangdong province(2024A1515030155 and 2022A1515010272)Natural Science Foundation of China(61904067)+2 种基金Basic and Applied Basic Research Foundation of Guangzhou city(202102020758)Open funding from State Key Laboratory of Optoelectronic Materials and Technologies(Sun Yat-Sen University,OEMT2022-KF-08)Fundamental Research Funds for the Central Universities(11625109,11621405)。
文摘Metals,indispensable since the Bronze Age,remain pivotal in modern technologies due to their exceptional properties and versatility.Beyond traditional machining,advanced nano/micro-machining techniques enable the fabrication of metallic nano/micro structures with high precision in shape,size,and pattern.These structures endow flexible electrodes with outstanding electrical,mechanical,optical,and electrochemical performance,enabling growing applications in flexible optoelectronics,epidermal electronics,energy harvesting,and biochemical sensing.This review provides a comprehensive overview of the fabrication strategies for flexible electrodes made from metal meshes,metal nanowires,and liquid metals.The current advancements,existing challenges,and emerging technologies are systematically discussed.Furthermore,the progression toward ultra-thin,soft epidermal electrodes is explored,with an emphasis on novel in situ and transfer fabrication methods.We examine the underlying mechanisms,performance indicators,and their integration for on-skin applications,including bioelectric sensing,electrical stimulation,and energy harvesting.Finally,we highlight the remaining challenges in performance improvement and industrialization of flexible and epidermal electrodes,along with future opportunities for integrating multimodal systems and leveraging artificial intelligence to enhance their functionalities.
基金supported by the National Natural Science Foundation of China(Grant No.12362027)the Scientific Research Ability of Youth Teachers of Inner Mongolia Agricultural University(Grant No.BR230110)+3 种基金Inner Mongolia National Science Fund for Excellent Young Scholars(Grant No.2025YQ033)Foundation for Basic Science Research Initiation at Inner Mongolia Agricultural University(Grant No.JC2021001)The Natural Science Foundation of Inner Mongolia Autonomous Region(2025MS01020)Supported by the Basic and Applied Basic Research Science and Technology Program Projects of Hohhot(2025-rule-basic-60)。
文摘This study investigates the dimensionless quasi-geostrophic potential vorticity(QG-PV)equation with external sources.Employing the Gardner-Morikawa transformation and weakly nonlinear perturbation expansion,we derive the nonlinear Boussinesq equation with external sources.We demonstrate the existence of explicit zero-order and first-order Wronskian solutions for the model equation whenα_4=0.Furthermore,using a modified Jacobi elliptic function method,we obtain soliton-like solutions for bothα_4=0 andα_4≠0.Analysis of these solutions reveals that the generalizedβ-plane approximation and shear flow are significant factors in inducing nonlinear Rossby waves,and that external sources play a crucial role in influencing Rossby wave behavior.
基金support provided by the Natural Science Foundation of Jilin Province(YDZJ202401316ZYTS)the Innovation Laboratory Development Program of the Education Department of Jilin Province and the Industry and Information Technology Department of Jilin Province,China(The Joint Laboratory of MXene Materials)the MXene Research Support Plan of Jilin 11 Technology Co.,Ltd.,China,and Future(Jilin)Material Technology Co.,Ltd.
文摘As the carrier of charge storage,the electrode determines the efficiency of the energy conversion reaction between the battery and the substance.However,with the continuous development of scientific research,electrode preparation is still facing complex technical problems,and it is difficult to achieve a balance in performance,cost,and technology.Based on the ion dissolution and deposition behavior of Mn^(2+)/MnO_(2) and Al^(3+)/Al,a novel cathode-free aqueous ion dissolution/deposition battery is designed,which can contribute 15 mAh at 16 cm^(2) in a voltage window of 0.5-1.8 V.The charge storage and the attenuation mechanism are systematically investigated.The battery model with compensable electrolyte was constructed,and the cycle characteristics of the cathode-free aqueous ion dissolution/deposition battery were optimized,which could achieve 1000 h continuous operation.This system provides a low-cost and high-safety solution for future high-energy density and large-scale energy storage.Future research will focus on optimizing electrolytes,controlling deposition morphology,and improving interface stability to further promote the commercialization of cathode-free batteries.
基金supported by Thailand Science Research and Inno-vation(TSRI)Fundamental Fund,fiscal year 2024(TUFF14/2567)by the Research Unit in Bioenergy and Catalysis(Thammasat University)+2 种基金partially supported by Thailand Science Research and Innovation(TSRI)under Project No.180677funded by Hub Talent:Sustainable Materials for Circular Economy,National Research Council of Thailand(NRCT)supported by Synchrotron Light Research Institute(SLRI:Beamline 3.2b).
文摘Hydrothermal carbonization(HTC)is a promising techno-economic method for biomass waste valorization owing to its advantages over other thermochemical processes.This study focused on carbon sequestration from sugarcane bioethanol distillery wastewater via HTC and chemical activation to produce activated carbon(AC).The resulting AC was then applied as an active material for supercapacitor electrodes.The introduction of redox molecules,such as 1,4-anthraquinone(AQ)and 9,10-phenanthrenequinone(PQ),on AC increased charge storage capability via redox transformation and enhanced the electrochemical performance of the supercapacitor elec-trode.Electrochemical testing showed that AC loaded with 16 wt%PQ achieved the highest specific capacitance of 488.21 F g^(-1) with remarkable capacitance retention of 95.3% after 1000 charge-discharge cycles.N-doped AC obtained from the HTC of wastewater and melamine presented a slightly enhanced specific capacitance.Various commercial LEDs with a voltage range of 1.8-3.0 V were illuminated simultaneously by connecting them to two series of symmetric supercapacitors,demonstrating the potential application of our proposed strategy in energy storage systems.This study proposes a simple and efficient strategy to utilize wastewater and achieve net-zero emission goals in a Bio-Circular-Green Economy model.
基金Supported by National Natural Science Foundation of China(Grant No.62173161).
文摘Let A be a 3×3 singular or diagonalizable matrix,all solutions to the Yang-Baxter-like matrix equation have been determined.However,finding all solutions for full rank,non-diagonalizable matrices remains challenging.By utilizing classification techniques,we establish all solutions of the Yang-Baxter-like matrix equation in this paper when the coefficient matrix A is similar to non-diagonalizable matrix diag(λ,J_(2)(λ))withλ̸=0.More specifically,we divide the non-diagonal elements of the solution into 10 different cases.By discussing each situation,we establish all solutions of the Yang-Baxter-like matrix equation.The results of this work enrich the existing ones.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(No.2022M3H4A6A0103720142)the National Research Council of Science&Technology(NST)grant by the Korea government(MSIT)(No.GTL24011-000)+1 种基金the Technology Innovation Program(RS-2024-00404165)through the Korea Planning&Evaluation Institute of Industrial Technology(KEIT)funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea)supported by the Samsung SDI Co.Ltd.and the Korea Institute of Science and Technology(KIST)institutional program(2E33942,2E3394B)。
文摘Strategies for achieving high-energy-density lithium-ion batteries include using high-capacity materials such as high-nickel NCM,increasing the active material content in the electrode by utilizing high-conductivity carbon nanotubes(CNT)conductive materials,and electrode thickening.However,these methods are still limited due to the limitation in the capacity of high-nickel NCM,aggregation of CNT conductive materials,and nonuniform material distribution of thick-film electrodes,which ultimately damage the mechanical and electrical integrity of the electrode,leading to a decrease in electrochemical performance.Here,we present an integrated binder-CNT composite dispersion solution to realize a high-solids-content(>77 wt%)slurry for high-mass-loading electrodes and to mitigate the migration of binder and conductive additives.Indeed,the approach reduces solvent usage by approximately 30%and ensures uniform conductive additive-binder domain distribution during electrode manufacturing,resulting in improved coating quality and adhesive strength for high-mass-loading electrodes(>12 mAh cm^(−2)).In terms of various electrode properties,the presented electrode showed low resistance and excellent electrochemical properties despite the low CNT contents of 0.6 wt%compared to the pristine-applied electrode with 0.85 wt%CNT contents.Moreover,our strategy enables faster drying,which increases the coating speed,thereby offering potential energy savings and supporting carbon neutrality in wet-based electrode manufacturing processes.
文摘Objective:To investigate the spatial gradient of intraoperative impedance across the cochlear electrode array in pediatric cochlear implant recipients and assess its potential as a physiological indicator for the electrode-neural interface.Methods:A prospective observational study involving 56 pediatric patients underwent cochlear implantation with Cochlear Nucleus devices.Intraoperative polarized impedance and electrically evoked compound action potential(ECAP)threshold were recorded across all 1232 electrodes using AutoNRT software.Eight electrodes with open-or short-circuit were excluded,leaving 1,224 for analysis.Impedance values were categorized by cochlear region(basal,middle,apical),and electrodes with elevated impedance(10-20 kΩ)were analyzed for regional distribution and clinical relevance.Data were analyzed for spatial patterns and correlation with the ECAP threshold profiles.Results:A consistent basal-to-apical increase in impedance was observed(7.7±1.9,9.2±1.4,10.8±1.5 kΩ;p<0.001).Impedance and ECAP threshold were weakly correlated(ρ=-0.20,p<0.001;β=-1.26,p<0.001),with a positive association in the apical region(ρ=0.12,p=0.048).Electrodes with higher impedance(1020 kΩ)were less likely to show elevated or absent TNRT(OR=0.175,p=0.02).The impedance gradient persisted across age groups and was significantly correlated with ECAP threshold patterns.Conclusion:Intraoperative impedance monitoring reveals a strong and physiologically consistent gradient,with higher values in apical electrodes.This gradient reflects anatomical and tissue interface variations,which may offer a valuable physiological indicator for intraoperative electrode positioning and neural interface integrity.
基金financially supported by research grants from Innovative Research Group Project of National Natural Science Foundation of China(52021004)the National Key Research and Development Program of China(2022YFB3803300)+1 种基金the National Natural Science Foundation of China(62474026,62205140,12204071)the China Postdoctoral Science Foundation(2022M710532)。
文摘Thermocells are garnering increasing attention as a promising thermoelectric technology for harvesting low-grade heat.However,their performance is often limited by the scarcity of high-performance redox couples that possess both high thermopower and rapid redox kinetics.This work addresses this challenge by leveraging our recently developed copper(Ⅰ/Ⅱ)(Cu^(+)/Cu^(2+))redox couple.We significantly enhance the performance of Cu-based liquid thermocells by integrating a thermosensitive crystallization process with etched carbon cloth electrodes,achieving synergistic improvements in thermodynamic and kinetic performance.The thermosensitive crystallization process establishes a persistent Cu^(2+)concentration gradient,boosting the thermopower from 1.47 to 2.93 mV K^(-1).Moreover,the etched carbon cloth electrodes provide a larger electroactive surface area and demonstrate a higher current density.Consequently,the optimized Cu^(+)/Cu^(2+)system achieved an exceptional normalized power density P_(max)(ΔT)^(-2)of 3.97 mW m^(-2)K^(-2).A thermocell module comprised of 20 cells directly power various electronic devices at a temperature difference of 40 K.This work successfully exhibits potential of Cu^(+)/Cu^(2+)redox couple in thermoelectric conversion and introduces a valuable redox couple for highperformance thermocells.
基金financially supported by the“National Natural Science Foundation of China”(No.22279082)the“Natural Science Foundation of Sichuan”(2025YFHZ0056)。
文摘Aqueous hydrogen(H_(2))gas batteries with unmatched lifespan are ideal for grid-scale energy storage,yet their deployment remains limited by the lack of low-cost,efficient,and durable hydrogen electrodes.Here,we report a high-throughput and durable gas diffusion electrode(GDE)based on a simply preparable carbon-coated nickel(Ni@C)catalyst and the design of H_(2) diffusion channels.By optimizing the carbon layer structure,a balance between the intrinsic activity and stability of the catalyst can be achieved.This Ni@C catalyst exhibits a hydrogen oxidation reaction(HOR)activity of 44 A g^(-1) as well as remarkable hydrogen evolution reaction(HER)performance.Experimental results and theoretical calculations confirm the electronic interaction between the carbon shell and Ni.In combination with a hydrophobic design,a robust and durable Ni@C-GDE has been fabricated.This electrode achieves a low HOR polarization of only 91 mV at 30 mA cm^(-2),outperforming Pt/C-GDE(154 mV),and operates stably over 4500cycles(3200 h)for HOR/HER reversing.Enabled by this electrode,a 10 Ah Ni-H_(2) battery with an energy density of 156.3 Wh kg^(-1) and cost of 62.2$kWh^(-1) is demonstrated.This work offers a viable strategy for practical and scalable hydrogen gas batteries.
基金Project supported by the National Natural Science Foundation of China(Nos.12502117,12272269,11972257)the Natural Science Foundation of Ningxia of China(No.2024AAC03018)+1 种基金the Fundamental Research Funds for the Central Universitiesthe Shanghai Gaofeng Project for University Academic Program Development。
文摘Driven by the trend of device miniaturization and high-density integration,the interaction between adjacent electrodes has become a critical factor affecting the interfacial reliability of thermoelectric(TE)structures.This study investigates the influence of adjoining electrode interactions on the interfacial response of a multi-electrode/TE substrate structure,including interfacial stresses and stress intensity factors at the electrode ends.To solve the corresponding boundary-value problem,the Fourier transforms are adopted to derive a governing integro-differential equation for the interfacial shear stress in multi-electrode systems,incorporating the TE effects as generalized forces on the right-hand side.The results show that both the interfacial tension and transverse stress in the electrodes are significantly affected by the presence of adjacent electrodes.The interaction between neighboring electrodes diminishes as their spacing increases or when an adhesive interlayer is introduced.Furthermore,the softer and thinner electrodes,the softer and thicker adhesive interlayer,and the smaller TE loads are found to be beneficial for improving the interfacial performance.These findings may contribute to the accurate measurement in surface sensors and layout design of multi-point health monitoring systems for TE structures.
