The local electronic structure of a transition metal can be adjusted by changing the metal octahedral linking mode in order to control its electrocatalytic activity.Perovskite(corner-sharing octahedra)and layered hydr...The local electronic structure of a transition metal can be adjusted by changing the metal octahedral linking mode in order to control its electrocatalytic activity.Perovskite(corner-sharing octahedra)and layered hydroxide(edge-sharing octahedra)structures have previously been studied as OER electrocatalysts.However,catalysts with face-sharing octahedra have still rarely been studied to date.In this work,a nickel–cobalt phosphite including local structural motifs with face-sharing octahedra has been studied as a model electrocatalyst for OER.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51302282)the Natural Science Foundation of Shaanxi Province(No.201701D221055)+1 种基金the Natural Science Foundation of Zhejiang Province(No.LY19E010002)the State Key Laboratory of Special Functional Waterproof Materials(No.SKLW2018006).
文摘The local electronic structure of a transition metal can be adjusted by changing the metal octahedral linking mode in order to control its electrocatalytic activity.Perovskite(corner-sharing octahedra)and layered hydroxide(edge-sharing octahedra)structures have previously been studied as OER electrocatalysts.However,catalysts with face-sharing octahedra have still rarely been studied to date.In this work,a nickel–cobalt phosphite including local structural motifs with face-sharing octahedra has been studied as a model electrocatalyst for OER.
