This study was conducted to extract scarce natural liquor flavorings desired by many liquor factories from yellow water. Five straight-chain saturated fatty acids were firstly extracted from 15 fractions of yellow wat...This study was conducted to extract scarce natural liquor flavorings desired by many liquor factories from yellow water. Five straight-chain saturated fatty acids were firstly extracted from 15 fractions of yellow water, forming 1 fraction of the ethanol solution composed of the mixture of the five straight-chain saturated fatty acids. Then, 100 fractions of the ethanol solution could produce 94.857 6 fractions of esterification liquid through catalytic esterification at 80 ℃. The esterification liquid contains five esters： ethyl acetate, ethyl propionate, ethyl butyrate, ethyl valerate and ethyl caproate, with contents of 17.68%, 2.58%, 6.32%, 0.06% and 19.40%, respectively. The esterification liquid prepared from 1 fraction of yellow water could blend 10.54 fractions of white liquor into top-grade Luzhou-flavor liquor after esterification. It indicates that yellow water has very good recycling and utilization value.展开更多
Hybrid capacitive deionization(HCDI)shows promise for desalinating brackish and saline water by utilizing the pseudocapacitive properties of faradaic electrodes.Organic materials,with their low environmental impact an...Hybrid capacitive deionization(HCDI)shows promise for desalinating brackish and saline water by utilizing the pseudocapacitive properties of faradaic electrodes.Organic materials,with their low environmental impact and adaptable structures,are attractive for this application.However,their scarcity of active sites and tendency to dissolve in water-based solutions remain significant challenges.Herein,we synthesized a polynaphthalenequinoneimine(PCON)polymer with stable long-range ordered framework and rough three-dimensional floral surface morphology,along with high-density active sites provided by C=O and C=N functional groups,enabling efficient redox reactions and achieving a high Na^(+)capture capability.The synthesized PCON polymer showcases outstanding electroadsorption characteristics and notable structural robustness,attaining an impressive specific capacitance of 500.45 F g^(-1) at 1 A g^(-1) and maintaining 86.1%of its original capacitance following 5000 charge–discharge cycles.Benefiting from the superior pseudocapacitive properties of the PCON polymer,we have developed an HCDI system that not only exhibits exceptional salt removal capacity of 100.8 mg g^(-1) and a remarkable rapid average removal rate of 3.36 mg g^(-1) min-1 but also maintains 97%of its initial desalination capacity after 50 cycles,thereby distinguishing itself in the field of state-ofthe-art desalination technologies with its comprehensive performance that significantly surpasses reported organic capacitive deionization materials.Prospectively,the synthesis paradigm of the double active-sites PCON polymer may be extrapolated to other organic electrodes,heralding new avenues for the design of high-performance desalination systems.展开更多
基金Supported by Shandong Province Key Research and Development Planning Project(No.2017GSF2160092017GGX10136)
文摘This study was conducted to extract scarce natural liquor flavorings desired by many liquor factories from yellow water. Five straight-chain saturated fatty acids were firstly extracted from 15 fractions of yellow water, forming 1 fraction of the ethanol solution composed of the mixture of the five straight-chain saturated fatty acids. Then, 100 fractions of the ethanol solution could produce 94.857 6 fractions of esterification liquid through catalytic esterification at 80 ℃. The esterification liquid contains five esters： ethyl acetate, ethyl propionate, ethyl butyrate, ethyl valerate and ethyl caproate, with contents of 17.68%, 2.58%, 6.32%, 0.06% and 19.40%, respectively. The esterification liquid prepared from 1 fraction of yellow water could blend 10.54 fractions of white liquor into top-grade Luzhou-flavor liquor after esterification. It indicates that yellow water has very good recycling and utilization value.
基金supported by the National Key R&D Program of China(Grant Nos.2023YFC3009900)National Natural Science Foundation of China(Grant Nos.61904116)+1 种基金Natural Science Foundation of Jiangsu Province(Grant Nos.BK20211029)the young scientific talent lifting project of Jiangsu Association for Science and Technology(Grant Nos.JSTJ-2023-018).
文摘Hybrid capacitive deionization(HCDI)shows promise for desalinating brackish and saline water by utilizing the pseudocapacitive properties of faradaic electrodes.Organic materials,with their low environmental impact and adaptable structures,are attractive for this application.However,their scarcity of active sites and tendency to dissolve in water-based solutions remain significant challenges.Herein,we synthesized a polynaphthalenequinoneimine(PCON)polymer with stable long-range ordered framework and rough three-dimensional floral surface morphology,along with high-density active sites provided by C=O and C=N functional groups,enabling efficient redox reactions and achieving a high Na^(+)capture capability.The synthesized PCON polymer showcases outstanding electroadsorption characteristics and notable structural robustness,attaining an impressive specific capacitance of 500.45 F g^(-1) at 1 A g^(-1) and maintaining 86.1%of its original capacitance following 5000 charge–discharge cycles.Benefiting from the superior pseudocapacitive properties of the PCON polymer,we have developed an HCDI system that not only exhibits exceptional salt removal capacity of 100.8 mg g^(-1) and a remarkable rapid average removal rate of 3.36 mg g^(-1) min-1 but also maintains 97%of its initial desalination capacity after 50 cycles,thereby distinguishing itself in the field of state-ofthe-art desalination technologies with its comprehensive performance that significantly surpasses reported organic capacitive deionization materials.Prospectively,the synthesis paradigm of the double active-sites PCON polymer may be extrapolated to other organic electrodes,heralding new avenues for the design of high-performance desalination systems.
