The characterization and testing methods of the dynamic fractureinitiation toughness of elas- tic-plastic materials under tensileimpact are studied. By using the self-designed bar-bar tensile impactappa- ratus, a nove...The characterization and testing methods of the dynamic fractureinitiation toughness of elas- tic-plastic materials under tensileimpact are studied. By using the self-designed bar-bar tensile impactappa- ratus, a novel test method for studying dynamicfracture-initiation ahs been proposed based on the one-di- mensionaltest principle. The curve of average load v. s. displacement (P-δ)is smooth until unstable crack propagation, and the kinetic energywhich does not contribute to the crack growth can be removed fromtotal work done by external-force to the specimen.展开更多
The crack tip stress-strain fields of the elastic-plastic cracked specimens have been analyzed using finite element calculations.The crack initiation and steady propagation behaviours have also been investigated by me...The crack tip stress-strain fields of the elastic-plastic cracked specimens have been analyzed using finite element calculations.The crack initiation and steady propagation behaviours have also been investigated by means of slip line pattern etching technique and mechanical tests. The results show that there are HRR near field and distant field in the crack tip region,and the later depends on the specimen configuration.The crack initiation behaviour is controlled by a single parameter J.In contrast,the steady crack propagation is affected by the distant strain field and can not be described by single parameter only.展开更多
In the present paper it is shown that the elastic range in the second Piola-Kirchhoff stress space can be chosen in a hyperplane which is through the origin of Lagrangian stress space and perpendicular to the normal o...In the present paper it is shown that the elastic range in the second Piola-Kirchhoff stress space can be chosen in a hyperplane which is through the origin of Lagrangian stress space and perpendicular to the normal of the constraint manifold at the plastic configuration, if the determinate stress response of the elastic-plastic material with simple internal constraints with some condition is correctly chosen, otherwise, it is in general in a hypersurface and the normal flow rule by Ⅱ yushin＇s postulate will have an indeterminate part. The choice of deterrninate stress response is probable because of its indeterminacy. Therefore the yield function should be a function of the second Piola-Kirchhoff stress lying in the hyperplane so that it is more simple and the back stress as the geometric center of the elastic range in general is inside the elastic range. Finally some examples are concerned.展开更多
Author researches a lot of the mathematical models and the related conventional material constants in the traditional and the modem mechanics; to adopt two types of variables a and D, for the fatigue-damage-fracture b...Author researches a lot of the mathematical models and the related conventional material constants in the traditional and the modem mechanics; to adopt two types of variables a and D, for the fatigue-damage-fracture behaviors to elastic-plastic steels contained flaws, to put forward several calculation models, which are the driving force and the life prediction expressions at each stage and in whole process; for the key parameters .A1 and ,A2 in two stages, there are functional relation with other conventional material constants σF,m1 and M2,λ2, they are defined as the new calculable comprehensive material constants, and indicate their physical and geometrical meanings. In addition, for conversion methods between two types of variables, relevant calculating example is provided. Thereby, make a linking between the fracture mechanics and the damage mechanics, communicating their relationships. This works for saving man powers and funds on fatigue-damage-fracture testing that will be having practical significance.展开更多
Bifurcation problems both for static and dynamical cavitation in a solid sphere composed of the incompressible hyperelasticplastic material, under uniformly distributed tensile boundary dead load were studied. For eac...Bifurcation problems both for static and dynamical cavitation in a solid sphere composed of the incompressible hyperelasticplastic material, under uniformly distributed tensile boundary dead load were studied. For each problem, cavity forms at the center of the sphere when the tensile load is larger than its critical value. Bifurcation curves and the growth curves for the plastic deformation region were given. For static cavitation, the deformation displays three stages, namely, fully elastic, elasto-plastic and fully plastic stages. For dynamical cavitation, the cavity grows without bound and the sphere displays plastic flow.展开更多
Ultrasonic-Assisted Grinding(UAG)is a novel manufacturing technology that shows promising promise for use in processing Ceramic Matrix Composites(CMCs).Nevertheless,analyzing the material removal process of CMCs with ...Ultrasonic-Assisted Grinding(UAG)is a novel manufacturing technology that shows promising promise for use in processing Ceramic Matrix Composites(CMCs).Nevertheless,analyzing the material removal process of CMCs with multidirectional structure during UAG is challenging,impeding the progress and improvement of the UAG process.This work examined the impact of ultrasonic vibration on the dynamic mechanical characteristics during processing.Additionally,we experimentally elucidated the material removal mechanism of CMCs during the scratching process under the influence of vertical vibration.The results indicate that the introduction of ultrasonic vibration causes a strain rate effect,resulting in a modification of the material removal mechanism,subsequently impacting the processing quality.Ultrasonic vibration increases the dynamic strength and brittleness of the fibers in CMCs,leading to more cracks at fracture,which changes from the original bending fracture to shear fracture.In addition,ultrasonic vibration can effectively inhibit the impact of scratching depth and anisotropy on the removal mechanism of CMCs,resulting in a more uniform surface of CMCs after processing.展开更多
Standardization is necessary for the early industrialization of the new materials and technology.It is achieved by having agreed practices for the measurement of properties and other characteristics.The promising use ...Standardization is necessary for the early industrialization of the new materials and technology.It is achieved by having agreed practices for the measurement of properties and other characteristics.The promising use of graphene-based materials in fields like electronics,energy,and composites has resulted in standards for their nomenclature,the measurement of key characteristics,and their specification,etc.Among these,standards for measuring the key characteristics are crucial.The critical parameters are the number of layers,the type and concentration of defects and functional groups,elemental composition,sheet resistance,and carrier mobility.Standards for characterizing these have been analyzed by the International Organization for Standardization Technical Committee in ISO/TC229 and the International Electrotechnical Commission Technical Committee in IEC/TC113.These give details of applicable or preferred samples,the fundamental principles of the techniques,specific precautions,and points for attention in the relevant standards.The pivotal role of the ISO/TC229 and IEC/TC113 standards is considered and challenges and future trends are outlined.展开更多
CO_(2) capture and utilization(CCU)technologies have been recognized as crucial strategies for mitigating global warming,reducing carbon emission,and promoting resource circularity.As such,the design and development o...CO_(2) capture and utilization(CCU)technologies have been recognized as crucial strategies for mitigating global warming,reducing carbon emission,and promoting resource circularity.As such,the design and development of related materials have attracted considerable research attention.Carbon-based materials,characterized by tunable pore structures,abundant active sites,high specific surface area,and excellent chemical stability,demonstrate significant potential for applications in CO_(2) capture and utilization.This review systematically analyzes the adsorption behaviors and performance variations of typical carbon materials,including activated carbon,porous carbon,graphene,and carbon nanotubes during CO_(2) capture processes.Concerning CO_(2) utilization,emphasis is placed on recent advances in the catalytic applications of carbon-based materials in key reactions such as methanation,reverse water-gas shift,dry reforming of methane,and alcohol synthesis.Moreover,the benefits and drawbacks of carbon materials in terms of CO_(2) adsorption capacity,catalytic activity,and stability are thoroughly evaluated,and their potential applications in integrated CO_(2) capture and utilization technologies are discussed.Finally,key strategies for enhancing the performance of carbonaceous materials through structural modulation and surface modification are elucidated.This review aims to provide theoretical guidance for the future development and large-scale implementation of carbon-based materials in CCU technologies.展开更多
Moisture electricity generation(MEG)has emerged as a sustainable and versatile energy-harvesting technology capable of converting ubiquitous environmental moisture into electrical energy,which holds great promise for ...Moisture electricity generation(MEG)has emerged as a sustainable and versatile energy-harvesting technology capable of converting ubiquitous environmental moisture into electrical energy,which holds great promise for renewable energy and constructing self-powered electronics.In this review,we begin by outlining the fundamental mechanisms—ion diffusion,electric double layer formation,and streaming potential—that govern charge transport for MEG in moist environments.A comprehensive survey of material innovations follows,highlighting breakthroughs in carbon-based materials,conductive polymers,hydrogels,and bio-inspired systems that enhance MEG performance,scalability,and biocompatibility.We then explore a range of device architectures,from planar and layered systems to flexible,miniaturized,and textile-integrated designs,engineered for both energy conversion and sensor integration.Key challenges are analyzed,along with strategies for overcoming them.We conclude with a forward-looking perspective on future directions,including hybrid energy systems,AI-assisted material design,and real-world deployment.This review presents a timely and comprehensive overview of MEG technologies and their trajectory toward practical and sustainable energy solutions.展开更多
The capture of atmospheric carbon dioxide by adsorbents is an important strategy to deal with the greenhouse effect.Compared with traditional CO_(2) adsorption materials like activated carbon,silica gel,and zeolite mo...The capture of atmospheric carbon dioxide by adsorbents is an important strategy to deal with the greenhouse effect.Compared with traditional CO_(2) adsorption materials like activated carbon,silica gel,and zeolite molecular sieves,covalent organic frameworks(COFs)have excellent thermal and chemical stabilities and can be produced in many different forms.Using their different possible construction units,ordered structures for specific applications can be produced,giving them broad prospects in fields such as gas storage.This review analyzes the different types of COFs that have been synthesized and their different methods of CO_(2) capture.It then discusses different ways to increase CO_(2) adsorption by changing the internal structure of COFs and modifying their surfaces.The limitations of COF-derived carbon materials in CO_(2) capture are reviewed and,finally,the key role of machine learning and computational simulation in improving CO_(2) adsorption is mentioned,and the current status and future possible uses of COFs are summarized.展开更多
The reactive materials filled structure(RMFS)is a structural penetrator that replaces high explosive(HE)with reactive materials,presenting a novel self-distributed initiation,multiple deflagrations behavior during pen...The reactive materials filled structure(RMFS)is a structural penetrator that replaces high explosive(HE)with reactive materials,presenting a novel self-distributed initiation,multiple deflagrations behavior during penetrating multi-layered plates,and generating a multipeak overpressure behind the plates.Here analytical models of RMFS self-distributed energy release and equivalent deflagration are developed.The multipeak overpressure formation model based on the single deflagration overpressure expression was promoted.The impact tests of RMFS on multi-layered plates at 584 m/s,616 m/s,and819 m/s were performed to validate the analytical model.Further,the influence of a single overpressure peak and time intervals versus impact velocity is discussed.The analysis results indicate that the deflagration happened within 20.68 mm behind the plate,the initial impact velocity and plate thickness are the crucial factors that dominate the self-distributed multipeak overpressure effect.Three formation patterns of multipeak overpressure are proposed.展开更多
Photocatalytic nitrogen fixation (PNF) is a promising alternative to the Haber-Bosch process.It achieves green ammonia production by utilizing solar energy for nitrogen fixation under mild conditions.While nanoscale p...Photocatalytic nitrogen fixation (PNF) is a promising alternative to the Haber-Bosch process.It achieves green ammonia production by utilizing solar energy for nitrogen fixation under mild conditions.While nanoscale photocatalysts offer enhanced performance due to their high surface area and abundant active sites,their small size makes them difficult to recover and prone to agglomeration.These bottlenecks severely limit industrial application.A promising solution is to immobilize the catalysts onto support surfaces.This paper provides a systematic review of recent advances in the design of immobilized photocatalysts for ammonia synthesis.It begins by outlining the key benefits of immobilization strategies,particularly in improving catalyst stability,recyclability,and overall photocatalytic performance.The working mechanisms and features of various immobilization techniques are then categorized and explained,covering physical adsorption/deposition,chemical bonding,in situ growth,and hybrid physico-chemical methods.Supported materials and common substrate types are also summarized.Furthermore,the widely used configurations of photoreactors suitable for immobilized systems are introduced.Finally,the review identifies current research limitations and challenges,and offers perspectives on future developments in the field of immobilized photocatalysis.展开更多
Coal cinder is an abundant byproduct of the extensive consumption of coal in industrial production and daily life.Making full use of the cinder is conducive to a low-carbon economy.In this study,inspired by the burnin...Coal cinder is an abundant byproduct of the extensive consumption of coal in industrial production and daily life.Making full use of the cinder is conducive to a low-carbon economy.In this study,inspired by the burning of coal,a new method for constructing a silica-based composite porous material(SiO_(2)-CPM)was developed by combusting a siloxane-modified anthracite coal gel(CSiO_(2) gel).During this process,the combustion product was directly converted into a porous material,and the calorific value of the coal remained nearly unchanged(~98%of the original calorific value was retained),demonstrating the viability of this method for energy-efficient applications.The SiO_(2)-CPM exhibited an ultra-low thermal conductivity(0.036 W/(m·K)at room temperature),outperforming conventional insulation materials(e.g.,cotton~0.05 W/(m·K)).Additionally,it showed enhanced mechanical strength(fracture stress of 41.8 kPa)compared to the powder state of the coal cinder.Experimental results indicate that the amount of siloxane,structure-directing agent,and an acidic environment were critical for mechanical enhancement.The SiO_(2)-CPM showed good dimensional stability against thermal expansion and exhibited excellent thermal insulation and fire resistance even at 900℃.Meanwhile,the SiO_(2)-CPM with complex geometry could be easily fabricated using this method owing to the excellent shaping ability of the CSiO_(2) gel.Compared to conventional methods such as sol-gel synthesis or freeze-drying,this approach for fabricating SiO_(2)-CPM is simpler and cost-effective and allows the direct utilization of coal cinder post-combustion.展开更多
Intelligent refractory materials represent a new generation of high-temperature functional materials that significantly enhance the service performance of traditional refractories in extreme environments through integ...Intelligent refractory materials represent a new generation of high-temperature functional materials that significantly enhance the service performance of traditional refractories in extreme environments through integrated sensing,response,and adaptive mechanisms.A comprehensive overview of intelligent refractory materials was provided,focusing on their classification,preparation techniques,and industrial applications.Firstly,the categories and design principles of intelligent refractory materials are introduced,including self-healing,self-regulating,and self-diagnosing types,which enhance durability and performance under extreme conditions.Subsequently,advanced preparation technologies are discussed,such as 3D printing for complex geometries,nanocomposite engineering for improved mechanical and thermal properties,gradient design for optimized thermal stress resistance and information technology including machine learning,health monitoring,digital twin.Finally,the industrial applications of these materials are highlighted,particularly in steel metallurgy,building materials industry,and energy.It aims to bridge the gap between research advancements and practical implementation,offering insights into future trends in intelligent refractory material development.展开更多
Biomedical applications necessitate natural or synthetic biomaterials that can maintain,improve,or even replace damaged tissue or a biological function,facilitating healing for people who have suffered from an injury ...Biomedical applications necessitate natural or synthetic biomaterials that can maintain,improve,or even replace damaged tissue or a biological function,facilitating healing for people who have suffered from an injury or disease.Metallic biomaterials show superior mechanical properties with greater service life than other materials.Biodegradable materials can avoid the inevitable second operation of removing the implant in the case of temporary implantation,reducing the risk of infections,medical complications,healing time,and cost.Magnesium(Mg),zinc(Zn),iron(Fe),and their alloys are potential biodegradable metallic materials.The characteristics of biodegradable metallic materials are variable and depend on many factors,such as alloying elements,microstructure,existing phases,and thermomechanical treatment.The current review emphasizes the impact of alloying element addition on the characteristics of metallic biodegradable materials,with particular attention to the relationships between alloying elements,microstructure,mechanical performance,corrosion,and biocompatibility.Mg alloys show good mechanical and corrosion properties with excellent biocompatibility.Using biocompatible alloying elements can improve Mg alloy mechanical and corrosion properties without af-fecting their biocompatibility.However,critical limitations are still maintained,like rapid degradation and gas bubble formation.Zn alloys could overcome the limitations of Mg alloys with appropriate degradation rates,ease of casting and processing,and good biocompatibility.Alloying,particularly with Mg,Li,and Cu,combined with thermomechanical treatment,can significantly affect the microstructure and mechanical performance of Zn alloys and overcome the problem of unsuitable mechanical properties.Fe alloys have excellent mechanical performance,formability,and biocompatibility with a low degradation rate.Applying surface treatment,using novel structures,alloying with the appropriate amount of alloying elements,and using advanced manufacturing techniques may present a way to solve the problems associated with biodegradable metallic materials,which could open new horizons and increase their applicability in biomedical applications.展开更多
To solve the problem of abnormal abrasion of Cu-Based Friction Materials(CBFMs),Bionic Non-Smooth Surface(BNS)on friction surface of CBFMs was constructed based on bionic principles,and the optimal bionic prototype wa...To solve the problem of abnormal abrasion of Cu-Based Friction Materials(CBFMs),Bionic Non-Smooth Surface(BNS)on friction surface of CBFMs was constructed based on bionic principles,and the optimal bionic prototype was selected by Finite Element Method(FEM).In addition,the bionic parameters were optimized by Response Surface Method(RSM).Samples holding BNS were prepared by Laser Processing,tribological properties were tested by a Friction and Wear Tester and worn surface morphology was characterized by a Scanning Electron Microscope(SEM).The results showed that BNS on friction surface could regulate the stress distribution and alleviate the peak stress.Among all samples,the coupled texture of pit-hexagonal got the minimum peak stress.During braking,bionic texture could also collect wear debris or change the motion forms from sliding to rotation,which can reduce abnormal abrasion.The wear rate was reduced by 19.31%.The results in this paper can provide a new idea for enhancing the tribological properties of CBFMs,and can also lay the foundation for further research of bionic tribology.展开更多
Though the formation of polysulfide is desirable,as it contributes to the capacity build-up,it must not leak into the electrolyte.The loss of polysulfide causes capacity fade,a change in the local chemistry of the ele...Though the formation of polysulfide is desirable,as it contributes to the capacity build-up,it must not leak into the electrolyte.The loss of polysulfide causes capacity fade,a change in the local chemistry of the electrolyte,and anode poisoning.Constant efforts are in progress to find suitable polysulfide-absorbing materials;however,the magical polysulfide absorber is yet to be discovered or developed.Experimental methods alone often fall short in accelerating the investigations may be due to the complex Nature of the testing.This review focuses on the importance of computational methods,particularly density functional theory(DFT),in screening suitable polysulfide absorbers.It highlights the critical role of anchoring materials in improving Na-S battery performance,including pristine and doped graphene,metal–organic frameworks,carbon Nanofibers,vanadium disulfide,MXenes,and metal sulfides.By examining adsorption energies,charge transfer mechanisms,and catalytic properties,this review provides insights into the design of advanced materials that can effectively immobilize polysulfides and enhance battery stability.The review aims to guide future research efforts toward the development of high-performance RT Na-S batteries through a comprehensive understanding of the polysulfide-absorbing materials.展开更多
Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement ...Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement fails to reconcile ecological responsibility with advanced functional performance.By incorporating tailored fillers into cement matrices,the resulting composites achieve enhanced thermoelectric(TE)conversion capabilities.These materials can harness solar radiation from building envelopes and recover waste heat from indoor thermal gradients,facilitating bidirectional energy conversion.This review offers a comprehensive and timely overview of cementbased thermoelectric materials(CTEMs),integrating material design,device fabrication,and diverse applications into a holistic perspective.It summarizes recent advancements in TE performance enhancement,encompassing fillers optimization and matrices innovation.Additionally,the review consolidates fabrication strategies and performance evaluations of cement-based thermoelectric devices(CTEDs),providing detailed discussions on their roles in monitoring and protection,energy harvesting,and smart building.We also address sustainability,durability,and lifecycle considerations of CTEMs,which are essential for real-world deployment.Finally,we outline future research directions in materials design,device engineering,and scalable manufacturing to foster the practical application of CTEMs in sustainable and intelligent infrastructure.展开更多
Responsive colorimetric materials exhibit significant potential for application in fields such as smart food packaging and wound monitoring.The functional integration of pH-indicators with material carriers enables br...Responsive colorimetric materials exhibit significant potential for application in fields such as smart food packaging and wound monitoring.The functional integration of pH-indicators with material carriers enables breakthrough applications in nontraditional domains.In this study,we developed a novel material covalently grafted with a pH indicator that exhibited naked-eye pH-responsive color shifts.The covalent grafting of pH-responsive bromothymol blue onto carboxymethyl cellulose(CMC)was confirmed using advanced characterization techniques,including Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy.The pH-sensitive chromophore was covalently immobilized onto the CMC matrix through esterification,thereby establishing firm chemical conjugation.Moreover,a superior color-changing performance was achieved within several minutes in response to different pH values.The reusability and stability of this material offer distinct advantages over single-use pH test strips.pH-responsive colorimetric materials hold promise for efficient,noninvasive monitoring in intelligent packaging(food freshness),medical diagnostics(wound status,infections),biosensing,and environmental applications.展开更多
The demand for sustainable energy storage has accelerated the development of cellulose-based materials(CBMs)for flexible supercapacitors(FSCs).However,widespread commercialization of FSCs remains challenged by their l...The demand for sustainable energy storage has accelerated the development of cellulose-based materials(CBMs)for flexible supercapacitors(FSCs).However,widespread commercialization of FSCs remains challenged by their low gravimetric energy density(approximately 35 Wh kg^(-1)),far below lithium-ion batteries(exceeding 200 Wh kg^(-1)),and a limited operational temperature range(from-20℃ to 60℃),restricting their use in extreme environments.To date,no comprehensive review has elucidated the crucial role of the chemistry and structure-property relationships of CBMs in advancing FSC technology.This review fills this gap by examining the chemical attributes and versatility of cellulose and its derivatives,including their physicochemical characteris-tics,assembly methodologies,and functional modifications such as oxidation,esterification,etherification,grafting polymerization,nucleophilic substitution,and crosslinking reactions.We further provide an overview of the chemistry and structure-function correlations of various cellulose forms used in advanced electrodes,solid electrolytes,separators,binders,current collectors,and substrate/encapsulation materials,alongside relevant microelectrode processing technologies.Given that large-scale application of FSCs is still in its early stages,we offer insightful design principles for guiding future development of cellulose-based FSCs.By proposing a“chemistry-performance-sustainability”design framework,this review not only addresses existing limitations but also outlines a roadmap for next-generation eco-friendly FSCs.展开更多
文摘The characterization and testing methods of the dynamic fractureinitiation toughness of elas- tic-plastic materials under tensileimpact are studied. By using the self-designed bar-bar tensile impactappa- ratus, a novel test method for studying dynamicfracture-initiation ahs been proposed based on the one-di- mensionaltest principle. The curve of average load v. s. displacement (P-δ)is smooth until unstable crack propagation, and the kinetic energywhich does not contribute to the crack growth can be removed fromtotal work done by external-force to the specimen.
文摘The crack tip stress-strain fields of the elastic-plastic cracked specimens have been analyzed using finite element calculations.The crack initiation and steady propagation behaviours have also been investigated by means of slip line pattern etching technique and mechanical tests. The results show that there are HRR near field and distant field in the crack tip region,and the later depends on the specimen configuration.The crack initiation behaviour is controlled by a single parameter J.In contrast,the steady crack propagation is affected by the distant strain field and can not be described by single parameter only.
基金The project supported by the National Natural Science Foundation of China(10272055)
文摘In the present paper it is shown that the elastic range in the second Piola-Kirchhoff stress space can be chosen in a hyperplane which is through the origin of Lagrangian stress space and perpendicular to the normal of the constraint manifold at the plastic configuration, if the determinate stress response of the elastic-plastic material with simple internal constraints with some condition is correctly chosen, otherwise, it is in general in a hypersurface and the normal flow rule by Ⅱ yushin＇s postulate will have an indeterminate part. The choice of deterrninate stress response is probable because of its indeterminacy. Therefore the yield function should be a function of the second Piola-Kirchhoff stress lying in the hyperplane so that it is more simple and the back stress as the geometric center of the elastic range in general is inside the elastic range. Finally some examples are concerned.
文摘Author researches a lot of the mathematical models and the related conventional material constants in the traditional and the modem mechanics; to adopt two types of variables a and D, for the fatigue-damage-fracture behaviors to elastic-plastic steels contained flaws, to put forward several calculation models, which are the driving force and the life prediction expressions at each stage and in whole process; for the key parameters .A1 and ,A2 in two stages, there are functional relation with other conventional material constants σF,m1 and M2,λ2, they are defined as the new calculable comprehensive material constants, and indicate their physical and geometrical meanings. In addition, for conversion methods between two types of variables, relevant calculating example is provided. Thereby, make a linking between the fracture mechanics and the damage mechanics, communicating their relationships. This works for saving man powers and funds on fatigue-damage-fracture testing that will be having practical significance.
基金Project supported by National Natural Science Foundation of China （Grant Nos. 10402018, 10272069）
文摘Bifurcation problems both for static and dynamical cavitation in a solid sphere composed of the incompressible hyperelasticplastic material, under uniformly distributed tensile boundary dead load were studied. For each problem, cavity forms at the center of the sphere when the tensile load is larger than its critical value. Bifurcation curves and the growth curves for the plastic deformation region were given. For static cavitation, the deformation displays three stages, namely, fully elastic, elasto-plastic and fully plastic stages. For dynamical cavitation, the cavity grows without bound and the sphere displays plastic flow.
基金supported by the National Science Foundation for Distinguished Young Scholars of China(No.52325506)the Fundamental Research Funds for the Central Universities(No.DUT22LAB501)。
文摘Ultrasonic-Assisted Grinding(UAG)is a novel manufacturing technology that shows promising promise for use in processing Ceramic Matrix Composites(CMCs).Nevertheless,analyzing the material removal process of CMCs with multidirectional structure during UAG is challenging,impeding the progress and improvement of the UAG process.This work examined the impact of ultrasonic vibration on the dynamic mechanical characteristics during processing.Additionally,we experimentally elucidated the material removal mechanism of CMCs during the scratching process under the influence of vertical vibration.The results indicate that the introduction of ultrasonic vibration causes a strain rate effect,resulting in a modification of the material removal mechanism,subsequently impacting the processing quality.Ultrasonic vibration increases the dynamic strength and brittleness of the fibers in CMCs,leading to more cracks at fracture,which changes from the original bending fracture to shear fracture.In addition,ultrasonic vibration can effectively inhibit the impact of scratching depth and anisotropy on the removal mechanism of CMCs,resulting in a more uniform surface of CMCs after processing.
文摘Standardization is necessary for the early industrialization of the new materials and technology.It is achieved by having agreed practices for the measurement of properties and other characteristics.The promising use of graphene-based materials in fields like electronics,energy,and composites has resulted in standards for their nomenclature,the measurement of key characteristics,and their specification,etc.Among these,standards for measuring the key characteristics are crucial.The critical parameters are the number of layers,the type and concentration of defects and functional groups,elemental composition,sheet resistance,and carrier mobility.Standards for characterizing these have been analyzed by the International Organization for Standardization Technical Committee in ISO/TC229 and the International Electrotechnical Commission Technical Committee in IEC/TC113.These give details of applicable or preferred samples,the fundamental principles of the techniques,specific precautions,and points for attention in the relevant standards.The pivotal role of the ISO/TC229 and IEC/TC113 standards is considered and challenges and future trends are outlined.
基金Supported by National Key R&D Program of China(2025YFE0109700)the National Natural Science Foundation of China(52106150)。
文摘CO_(2) capture and utilization(CCU)technologies have been recognized as crucial strategies for mitigating global warming,reducing carbon emission,and promoting resource circularity.As such,the design and development of related materials have attracted considerable research attention.Carbon-based materials,characterized by tunable pore structures,abundant active sites,high specific surface area,and excellent chemical stability,demonstrate significant potential for applications in CO_(2) capture and utilization.This review systematically analyzes the adsorption behaviors and performance variations of typical carbon materials,including activated carbon,porous carbon,graphene,and carbon nanotubes during CO_(2) capture processes.Concerning CO_(2) utilization,emphasis is placed on recent advances in the catalytic applications of carbon-based materials in key reactions such as methanation,reverse water-gas shift,dry reforming of methane,and alcohol synthesis.Moreover,the benefits and drawbacks of carbon materials in terms of CO_(2) adsorption capacity,catalytic activity,and stability are thoroughly evaluated,and their potential applications in integrated CO_(2) capture and utilization technologies are discussed.Finally,key strategies for enhancing the performance of carbonaceous materials through structural modulation and surface modification are elucidated.This review aims to provide theoretical guidance for the future development and large-scale implementation of carbon-based materials in CCU technologies.
基金supported by the National Natural Science Foundation of China(52305388,BE0200030)Shanghai Pujiang Program(22PJ1407600)+1 种基金SJTU Explore X programShanghai Jiao Tong University Initiative Scientific Research Program(WH220402021)。
文摘Moisture electricity generation(MEG)has emerged as a sustainable and versatile energy-harvesting technology capable of converting ubiquitous environmental moisture into electrical energy,which holds great promise for renewable energy and constructing self-powered electronics.In this review,we begin by outlining the fundamental mechanisms—ion diffusion,electric double layer formation,and streaming potential—that govern charge transport for MEG in moist environments.A comprehensive survey of material innovations follows,highlighting breakthroughs in carbon-based materials,conductive polymers,hydrogels,and bio-inspired systems that enhance MEG performance,scalability,and biocompatibility.We then explore a range of device architectures,from planar and layered systems to flexible,miniaturized,and textile-integrated designs,engineered for both energy conversion and sensor integration.Key challenges are analyzed,along with strategies for overcoming them.We conclude with a forward-looking perspective on future directions,including hybrid energy systems,AI-assisted material design,and real-world deployment.This review presents a timely and comprehensive overview of MEG technologies and their trajectory toward practical and sustainable energy solutions.
文摘The capture of atmospheric carbon dioxide by adsorbents is an important strategy to deal with the greenhouse effect.Compared with traditional CO_(2) adsorption materials like activated carbon,silica gel,and zeolite molecular sieves,covalent organic frameworks(COFs)have excellent thermal and chemical stabilities and can be produced in many different forms.Using their different possible construction units,ordered structures for specific applications can be produced,giving them broad prospects in fields such as gas storage.This review analyzes the different types of COFs that have been synthesized and their different methods of CO_(2) capture.It then discusses different ways to increase CO_(2) adsorption by changing the internal structure of COFs and modifying their surfaces.The limitations of COF-derived carbon materials in CO_(2) capture are reviewed and,finally,the key role of machine learning and computational simulation in improving CO_(2) adsorption is mentioned,and the current status and future possible uses of COFs are summarized.
基金the support received from the National Natural Science Foundation of China(Grant No.12302460)the State Key Laboratory of Explosion Science and Safety Protection(Grant No.YBKT24-02)。
文摘The reactive materials filled structure(RMFS)is a structural penetrator that replaces high explosive(HE)with reactive materials,presenting a novel self-distributed initiation,multiple deflagrations behavior during penetrating multi-layered plates,and generating a multipeak overpressure behind the plates.Here analytical models of RMFS self-distributed energy release and equivalent deflagration are developed.The multipeak overpressure formation model based on the single deflagration overpressure expression was promoted.The impact tests of RMFS on multi-layered plates at 584 m/s,616 m/s,and819 m/s were performed to validate the analytical model.Further,the influence of a single overpressure peak and time intervals versus impact velocity is discussed.The analysis results indicate that the deflagration happened within 20.68 mm behind the plate,the initial impact velocity and plate thickness are the crucial factors that dominate the self-distributed multipeak overpressure effect.Three formation patterns of multipeak overpressure are proposed.
基金support for carrying out this work was provided by the Doctoral Research Foundation of Weifang University(2024BS20)Science and Technology Development Plan Foundation of Weifang(2024GX017).
文摘Photocatalytic nitrogen fixation (PNF) is a promising alternative to the Haber-Bosch process.It achieves green ammonia production by utilizing solar energy for nitrogen fixation under mild conditions.While nanoscale photocatalysts offer enhanced performance due to their high surface area and abundant active sites,their small size makes them difficult to recover and prone to agglomeration.These bottlenecks severely limit industrial application.A promising solution is to immobilize the catalysts onto support surfaces.This paper provides a systematic review of recent advances in the design of immobilized photocatalysts for ammonia synthesis.It begins by outlining the key benefits of immobilization strategies,particularly in improving catalyst stability,recyclability,and overall photocatalytic performance.The working mechanisms and features of various immobilization techniques are then categorized and explained,covering physical adsorption/deposition,chemical bonding,in situ growth,and hybrid physico-chemical methods.Supported materials and common substrate types are also summarized.Furthermore,the widely used configurations of photoreactors suitable for immobilized systems are introduced.Finally,the review identifies current research limitations and challenges,and offers perspectives on future developments in the field of immobilized photocatalysis.
基金supported by the National Natural Science Foundation of China(No.52573220)the National Key R&D Program of China(No.2023YFC3404201)+1 种基金the Fundamental Research Funds for the Central Universities(No.FRF-IDRY-GD24-005)the State Key Laboratory of Solid Waste Reuse for Building Materials(No.SWR-2022-009).
文摘Coal cinder is an abundant byproduct of the extensive consumption of coal in industrial production and daily life.Making full use of the cinder is conducive to a low-carbon economy.In this study,inspired by the burning of coal,a new method for constructing a silica-based composite porous material(SiO_(2)-CPM)was developed by combusting a siloxane-modified anthracite coal gel(CSiO_(2) gel).During this process,the combustion product was directly converted into a porous material,and the calorific value of the coal remained nearly unchanged(~98%of the original calorific value was retained),demonstrating the viability of this method for energy-efficient applications.The SiO_(2)-CPM exhibited an ultra-low thermal conductivity(0.036 W/(m·K)at room temperature),outperforming conventional insulation materials(e.g.,cotton~0.05 W/(m·K)).Additionally,it showed enhanced mechanical strength(fracture stress of 41.8 kPa)compared to the powder state of the coal cinder.Experimental results indicate that the amount of siloxane,structure-directing agent,and an acidic environment were critical for mechanical enhancement.The SiO_(2)-CPM showed good dimensional stability against thermal expansion and exhibited excellent thermal insulation and fire resistance even at 900℃.Meanwhile,the SiO_(2)-CPM with complex geometry could be easily fabricated using this method owing to the excellent shaping ability of the CSiO_(2) gel.Compared to conventional methods such as sol-gel synthesis or freeze-drying,this approach for fabricating SiO_(2)-CPM is simpler and cost-effective and allows the direct utilization of coal cinder post-combustion.
基金supported by the Natural Science Foundation of Shaanxi Province(No.2023-JC-QN-0615)the National Natural Science Foundation of China(Nos.52272027 and 52372034).
文摘Intelligent refractory materials represent a new generation of high-temperature functional materials that significantly enhance the service performance of traditional refractories in extreme environments through integrated sensing,response,and adaptive mechanisms.A comprehensive overview of intelligent refractory materials was provided,focusing on their classification,preparation techniques,and industrial applications.Firstly,the categories and design principles of intelligent refractory materials are introduced,including self-healing,self-regulating,and self-diagnosing types,which enhance durability and performance under extreme conditions.Subsequently,advanced preparation technologies are discussed,such as 3D printing for complex geometries,nanocomposite engineering for improved mechanical and thermal properties,gradient design for optimized thermal stress resistance and information technology including machine learning,health monitoring,digital twin.Finally,the industrial applications of these materials are highlighted,particularly in steel metallurgy,building materials industry,and energy.It aims to bridge the gap between research advancements and practical implementation,offering insights into future trends in intelligent refractory material development.
文摘Biomedical applications necessitate natural or synthetic biomaterials that can maintain,improve,or even replace damaged tissue or a biological function,facilitating healing for people who have suffered from an injury or disease.Metallic biomaterials show superior mechanical properties with greater service life than other materials.Biodegradable materials can avoid the inevitable second operation of removing the implant in the case of temporary implantation,reducing the risk of infections,medical complications,healing time,and cost.Magnesium(Mg),zinc(Zn),iron(Fe),and their alloys are potential biodegradable metallic materials.The characteristics of biodegradable metallic materials are variable and depend on many factors,such as alloying elements,microstructure,existing phases,and thermomechanical treatment.The current review emphasizes the impact of alloying element addition on the characteristics of metallic biodegradable materials,with particular attention to the relationships between alloying elements,microstructure,mechanical performance,corrosion,and biocompatibility.Mg alloys show good mechanical and corrosion properties with excellent biocompatibility.Using biocompatible alloying elements can improve Mg alloy mechanical and corrosion properties without af-fecting their biocompatibility.However,critical limitations are still maintained,like rapid degradation and gas bubble formation.Zn alloys could overcome the limitations of Mg alloys with appropriate degradation rates,ease of casting and processing,and good biocompatibility.Alloying,particularly with Mg,Li,and Cu,combined with thermomechanical treatment,can significantly affect the microstructure and mechanical performance of Zn alloys and overcome the problem of unsuitable mechanical properties.Fe alloys have excellent mechanical performance,formability,and biocompatibility with a low degradation rate.Applying surface treatment,using novel structures,alloying with the appropriate amount of alloying elements,and using advanced manufacturing techniques may present a way to solve the problems associated with biodegradable metallic materials,which could open new horizons and increase their applicability in biomedical applications.
基金Wuxi University Research Start-up Fund for Introduced Talents(Grant No:2024r031)Technology Development Contract(Contract Registration Number:2024320205000963)+1 种基金National Natural Science Foundation of China(Grant No.52275288)Ningbo Key Research and Development Plan(Grant No.2023Z022).
文摘To solve the problem of abnormal abrasion of Cu-Based Friction Materials(CBFMs),Bionic Non-Smooth Surface(BNS)on friction surface of CBFMs was constructed based on bionic principles,and the optimal bionic prototype was selected by Finite Element Method(FEM).In addition,the bionic parameters were optimized by Response Surface Method(RSM).Samples holding BNS were prepared by Laser Processing,tribological properties were tested by a Friction and Wear Tester and worn surface morphology was characterized by a Scanning Electron Microscope(SEM).The results showed that BNS on friction surface could regulate the stress distribution and alleviate the peak stress.Among all samples,the coupled texture of pit-hexagonal got the minimum peak stress.During braking,bionic texture could also collect wear debris or change the motion forms from sliding to rotation,which can reduce abnormal abrasion.The wear rate was reduced by 19.31%.The results in this paper can provide a new idea for enhancing the tribological properties of CBFMs,and can also lay the foundation for further research of bionic tribology.
基金supported by the Indian Institute of Technology Delhi (IIT Delhi)
文摘Though the formation of polysulfide is desirable,as it contributes to the capacity build-up,it must not leak into the electrolyte.The loss of polysulfide causes capacity fade,a change in the local chemistry of the electrolyte,and anode poisoning.Constant efforts are in progress to find suitable polysulfide-absorbing materials;however,the magical polysulfide absorber is yet to be discovered or developed.Experimental methods alone often fall short in accelerating the investigations may be due to the complex Nature of the testing.This review focuses on the importance of computational methods,particularly density functional theory(DFT),in screening suitable polysulfide absorbers.It highlights the critical role of anchoring materials in improving Na-S battery performance,including pristine and doped graphene,metal–organic frameworks,carbon Nanofibers,vanadium disulfide,MXenes,and metal sulfides.By examining adsorption energies,charge transfer mechanisms,and catalytic properties,this review provides insights into the design of advanced materials that can effectively immobilize polysulfides and enhance battery stability.The review aims to guide future research efforts toward the development of high-performance RT Na-S batteries through a comprehensive understanding of the polysulfide-absorbing materials.
基金supported by the National Natural Science Foundation of China(No.52242305).
文摘Cement stands as a dominant contributor to global energy consumption and carbon emissions in the construction industry.With the upgrading of infrastructure and the improvement of building standards,traditional cement fails to reconcile ecological responsibility with advanced functional performance.By incorporating tailored fillers into cement matrices,the resulting composites achieve enhanced thermoelectric(TE)conversion capabilities.These materials can harness solar radiation from building envelopes and recover waste heat from indoor thermal gradients,facilitating bidirectional energy conversion.This review offers a comprehensive and timely overview of cementbased thermoelectric materials(CTEMs),integrating material design,device fabrication,and diverse applications into a holistic perspective.It summarizes recent advancements in TE performance enhancement,encompassing fillers optimization and matrices innovation.Additionally,the review consolidates fabrication strategies and performance evaluations of cement-based thermoelectric devices(CTEDs),providing detailed discussions on their roles in monitoring and protection,energy harvesting,and smart building.We also address sustainability,durability,and lifecycle considerations of CTEMs,which are essential for real-world deployment.Finally,we outline future research directions in materials design,device engineering,and scalable manufacturing to foster the practical application of CTEMs in sustainable and intelligent infrastructure.
基金financially supported by the National Natural Science Foundation of China(No.52303209)the“Lingyan”Program of Zhejiang Province(No.2024C03076)+1 种基金Zhejiang University K.P.Chao’s High Technology Development Foundationthe generous support provided by the joint research fund from the Shaoxing Institute of Zhejiang University and Shaoxing Maternity and Child Health Care Hospital。
文摘Responsive colorimetric materials exhibit significant potential for application in fields such as smart food packaging and wound monitoring.The functional integration of pH-indicators with material carriers enables breakthrough applications in nontraditional domains.In this study,we developed a novel material covalently grafted with a pH indicator that exhibited naked-eye pH-responsive color shifts.The covalent grafting of pH-responsive bromothymol blue onto carboxymethyl cellulose(CMC)was confirmed using advanced characterization techniques,including Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy.The pH-sensitive chromophore was covalently immobilized onto the CMC matrix through esterification,thereby establishing firm chemical conjugation.Moreover,a superior color-changing performance was achieved within several minutes in response to different pH values.The reusability and stability of this material offer distinct advantages over single-use pH test strips.pH-responsive colorimetric materials hold promise for efficient,noninvasive monitoring in intelligent packaging(food freshness),medical diagnostics(wound status,infections),biosensing,and environmental applications.
基金support from the National Key R&D Program of China(Grant No.2023YFB4005204)the National Natural Science Foundation of China(Grant No.22125903,U24A20553,22579025,52502038)+2 种基金Fundamental Research Funds for the Central Universities(No.2572023CT06)Key Joint Project of the Natural Science Foundation of Heilongjiang Province,China(No.ZL2024E007)the Innovation Foundation for Doctoral Program of Forestry Engineering of Northeast Forestry University(No.LYGC202220).
文摘The demand for sustainable energy storage has accelerated the development of cellulose-based materials(CBMs)for flexible supercapacitors(FSCs).However,widespread commercialization of FSCs remains challenged by their low gravimetric energy density(approximately 35 Wh kg^(-1)),far below lithium-ion batteries(exceeding 200 Wh kg^(-1)),and a limited operational temperature range(from-20℃ to 60℃),restricting their use in extreme environments.To date,no comprehensive review has elucidated the crucial role of the chemistry and structure-property relationships of CBMs in advancing FSC technology.This review fills this gap by examining the chemical attributes and versatility of cellulose and its derivatives,including their physicochemical characteris-tics,assembly methodologies,and functional modifications such as oxidation,esterification,etherification,grafting polymerization,nucleophilic substitution,and crosslinking reactions.We further provide an overview of the chemistry and structure-function correlations of various cellulose forms used in advanced electrodes,solid electrolytes,separators,binders,current collectors,and substrate/encapsulation materials,alongside relevant microelectrode processing technologies.Given that large-scale application of FSCs is still in its early stages,we offer insightful design principles for guiding future development of cellulose-based FSCs.By proposing a“chemistry-performance-sustainability”design framework,this review not only addresses existing limitations but also outlines a roadmap for next-generation eco-friendly FSCs.
