A series of blue and blue‑green Ir(Ⅲ)complexes has been investigated theoretically to explore their electronic structures,photophysical properties,efficiency roll‑off effect,and thermal activation delayed fluorescenc...A series of blue and blue‑green Ir(Ⅲ)complexes has been investigated theoretically to explore their electronic structures,photophysical properties,efficiency roll‑off effect,and thermal activation delayed fluorescence(TADF)properties.All calculations were performed using density functional theory(DFT)and time‑dependent density functional theory(TDDFT).Calculations for electronic structures,frontier molecular orbital characteristics(which determine the efficiency roll‑off effect of the complexes),and photophysical properties were conducted using the Gaussian 09 software package.The calculation of spin‑orbit coupling matrix elements<T|HSOC|S>,which determine the TADF properties of the complexes,was performed using the ORCA software package.The calculation results show that the auxiliary ligand tetraphenylimidodiphosphinate(tpip),a strong electron‑withdrawing group,can mitigate the efficiency roll‑off effect of the complex.Furthermore,TADF is observed in one of the designed complexes,(F_(3)Phppy)_(2)Ir(tpip),where F_(3)Phppy=2‑[4‑(2,4,6‑trifluorophenyl)phenyl]pyridine.展开更多
The goal of the present work is to demonstrate the potential of Artificial Neural Network(ANN)-driven Genetic Algorithm(GA)methods for energy efficiency and economic performance optimization of energy efficiency measu...The goal of the present work is to demonstrate the potential of Artificial Neural Network(ANN)-driven Genetic Algorithm(GA)methods for energy efficiency and economic performance optimization of energy efficiency measures in a multi-family house building in Greece.The energy efficiency measures include different heating/cooling systems(such as low-temperature and high-temperature heat pumps,natural gas boilers,split units),building envelope components for floor,walls,roof and windows of variable heat transfer coefficients,the installation of solar thermal collectors and PVs.The calculations of the building loads and investment and operating and maintenance costs of the measures are based on the methodology defined in Directive 2010/31/EU,while economic assumptions are based on EN 15459-1 standard.Typically,multi-objective optimization of energy efficiency measures often requires the simulation of very large numbers of cases involving numerous possible combinations,resulting in intense computational load.The results of the study indicate that ANN-driven GA methods can be used as an alternative,valuable tool for reliably predicting the optimal measures which minimize primary energy consumption and life cycle cost of the building with greatly reduced computational requirements.Through GA methods,the computational time needed for obtaining the optimal solutions is reduced by 96.4%-96.8%.展开更多
Shock waves in the nozzle during supersonic separation under different conditions can disrupt the flow field’s thermodynamic equilibrium.While it contributes to the recovery of pressure energy,it also leads to the di...Shock waves in the nozzle during supersonic separation under different conditions can disrupt the flow field’s thermodynamic equilibrium.While it contributes to the recovery of pressure energy,it also leads to the dissipation of mechanical energy.This study aimed to investigate the effects of changes in back pressure on the shock wave position and its subsequent impact on the refrigeration performance of nozzles.A mathematical model for the supersonic gas in a nozzle was established and evaluated via experiments.The results show that when the back pressure is less than 0.2 MPa,no shock wave is generated in the nozzle,and high refrigeration and liquefaction efficiency can be ensured while effective pressure recovery is achieved.When the back pressure(pb)is increased from 0.3 to 0.6 MPa,the refrigeration efficiency of the nozzle decreases,and the shock wave position(x shock)is advanced from 157 to 118 mm.The maximum Mach number(Ma)that can be reached by the fluid in the nozzle is reduced from 1.97 to 1.27.When the back pressure is increased from 0.2 to 0.6 MPa,the minimum temperature is increased by 55.18 K.When the back pressure is greater than 0.3 MPa,the Mach number upstream of the shock wave is reduced from 1.97 to 1.27,the shock wave intensity is weakened,and the thickness of the boundary layer separation caused by the shock wave is also decreased accordingly.Therefore,to ensure refrigeration efficiency,measures should be taken to control the back pressure within a reasonable range.展开更多
Curtain wall systems have evolved from aesthetic facade elements into multifunctional building envelopes that actively contribute to energy efficiency and climate responsiveness.This reviewpresents a comprehensive exa...Curtain wall systems have evolved from aesthetic facade elements into multifunctional building envelopes that actively contribute to energy efficiency and climate responsiveness.This reviewpresents a comprehensive examination of curtain walls from an energy-engineering perspective,highlighting their structural typologies(Stick and Unitized),material configurations,and integration with smart technologies such as electrochromic glazing,parametric design algorithms,and Building Management Systems(BMS).Thestudy explores the thermal,acoustic,and solar performance of curtain walls across various climatic zones,supported by comparative analyses and iconic case studies including Apple Park,Burj Khalifa,and Milad Tower.Key challenges—including installation complexity,high maintenance costs,and climate sensitivity—are critically assessed alongside proposed solutions.A central innovation of this work lies in framing curtain walls not only as passive architectural elements but as dynamic interfaces that modulate energy flows,reduce HVAC loads,and enhance occupant comfort.The reviewed data indicate that optimized curtain wall configurations—especially those integrating electrochromic glazing and BIPV modules—can achieve annual energy consumption reductions ranging fromapproximately 5%to 27%,depending on climate,control strategy,and facade typology.The findings offer a valuable reference for architects,energy engineers,and decision-makers seeking to integrate high-performance facades into future-ready building designs.展开更多
Hard carbon is a vital anode material for sodium-ion batteries;however,the nonuniform growth of solid electrolyte interphase(SEI)film substantially diminishes its initial coulombic efficiency(ICE)and cycle life.The ch...Hard carbon is a vital anode material for sodium-ion batteries;however,the nonuniform growth of solid electrolyte interphase(SEI)film substantially diminishes its initial coulombic efficiency(ICE)and cycle life.The chemical and morphological properties of surface highly influence the electrode/electrolyte interfacial reactions.In this study,we have tuned orbital hybridization states forming an interface enriched with sp^(2) hybridized carbon(sp^(2)-C),which decreases the binding energy to solvent molecules and inhibits excessive solvent decomposition during SEI formation.Benefiting from successfully constructed inorganic-rich SEI,the ICE increased to 91%and sodium storage capacity reached 346 mAh/g.Besides,the capacity retention rate was 90.7%after 700 cycles at 1 A/g higher than pristine electrode(83.8%).展开更多
Evaluating the effectivenes s of forest restoration projects is crucial for designing adaptive restoration strategies.However,existing studies have primarily focused on ecological outcomes while overlooking cost input...Evaluating the effectivenes s of forest restoration projects is crucial for designing adaptive restoration strategies.However,existing studies have primarily focused on ecological outcomes while overlooking cost inputs.This gap can lead to increased uncertainties in restoration planning.Here we investigated forest dynamics in China's Upper Yangtze River Basin(UYRB)using kernel Normalized Difference Vegetation Index(kNDVI),Leaf Area Index(LAI),Gross Primary Productivity(GPP),Ku-band Vegetation Optical Depth(Ku-VOD)time series and climate data from1982 to 2020.Subsequently,we employed a residual trend analysis integrating temporal effects to determine the relative contributions of climate change and human activities to forest dynamics before and after the implementation of forest restoration engineering in 1998.Additionally,we developed an Afforestation Efficiency Index(AEI)to quantitatively assess the cost efficiency of afforestation projects.Results indicated that forest in the UYRB showed sustained increases during 1982-2020,with most areas experiencing greater growth after 1998 than before.Temporal effects of climatic factors influenced over 42.7%of the forest,and incorporating time-lag and cumulative effects enhanced climate-based explanations of forest variations by 1.61-24.73%.Human activities emerged as the dominant driver of forest dynamics post 1998,whereas climate variables predominated before this period.The cost-effectiveness of forest restoration projects in the UYRB typically ranges from moderate to high,with higher success predominantly observed in the northeastern and eastern counties,while the central,western,and northwestern counties mainly showed relatively low efficiency.These findings stress the need for assessing forest restoration outcomes from both ecological and cost perspectives,and can offer valuable insights for optimizing the layout of forest restoration initiatives in the UYRB.展开更多
A nonfused ring electron acceptor(NFREA),designated as TT-Ph-C6,has been synthesized with the aim of enhancing the power conversion efficiency(PCE)of organic solar cells(OSCs).By integrating asymmetric phenylalkylamin...A nonfused ring electron acceptor(NFREA),designated as TT-Ph-C6,has been synthesized with the aim of enhancing the power conversion efficiency(PCE)of organic solar cells(OSCs).By integrating asymmetric phenylalkylamino side groups,TT-Ph-C6 demonstrates excellent solubility and its crystal structure exhibits compact packing structures with a three-dimensional molecular stacking network.These structural attributes markedly promote exciton diffusion and charge carrier mobility,particularly advantageous for the fabrication of thick-film devices.TT-Ph-C6-based devices have attained a PCE of 18.01%at a film thickness of 100 nm,and even at a film thickness of 300 nm,the PCE remains at 14.64%,surpassing that of devices based on 2BTh-2F.These remarkable properties position TT-Ph-C6 as a highly promising NFREA material for boosting the efficiency of OSCs.展开更多
In the quest to enhance energy efficiency and reduce environmental impact in the transportation sector,the recovery of waste heat from diesel engines has become a critical area of focus.This study provided an exhausti...In the quest to enhance energy efficiency and reduce environmental impact in the transportation sector,the recovery of waste heat from diesel engines has become a critical area of focus.This study provided an exhaustive thermodynamic analysis optimizing Organic Rankine Cycle(ORC)systems forwaste heat recovery fromdiesel engines.Thestudy assessed the performance of five candidateworking fluids—R11,R123,R113,R245fa,and R141b—under a range of operating conditions,specifically varying overheat temperatures and evaporation pressures.The results indicated that the choice of working fluid substantially influences the system’s exergetic efficiency,net output power,and thermal efficiency.R245fa showed an outstanding net output power of 30.39 kW at high overheat conditions,outperforming R11,which is significant for high-temperature waste heat recovery.At lower temperatures,R11 and R113 demonstrated higher exergetic efficiencies,with R11 reaching a peak exergetic efficiency of 7.4%at an evaporation pressure of 10 bar and an overheat of 10℃.The study also revealed that controlling the overheat and optimizing the evaporation pressure are crucial for enhancing the net output power of the ORC system.Specifically,at an evaporation pressure of 30 bar and an overheat of 0℃,R113 exhibited the lowest exergetic destruction of 544.5 kJ/kg,making it a suitable choice for minimizing irreversible losses.These findings are instrumental for understanding the performance of ORC systems in waste heat recovery applications and offer valuable insights for the design and operation of more efficient and environmentally friendly diesel engine systems.展开更多
Emerging and powerful genome editing tools,particularly CRISPR/Cas9,are facilitating functional genomics research and accelerating crop improvement(Jiang et al.2021;Cao et al.2023;Chen C et al.2023;Liu et al.2023a).Ho...Emerging and powerful genome editing tools,particularly CRISPR/Cas9,are facilitating functional genomics research and accelerating crop improvement(Jiang et al.2021;Cao et al.2023;Chen C et al.2023;Liu et al.2023a).However,the detection and screening of transgenic lines remain major bottlenecks,being time-consuming,labor-intensive,and inefficient during transformation and subsequent mutation identification.A simple and efficient visual marker system plays a critical role in addressing these challenges.Recent studies demonstrated that the GmW1 and RUBY reporter systems were used to obtain visual transgenic soybean(Glycine max) plants(Chen L et al.2023;Chen et al.2024).展开更多
Transforming urban spatial structures to promote green and low-carbon development is an effective strategy.Although prior studies have examined the impact of urban polycentricity on carbon emissions and economic devel...Transforming urban spatial structures to promote green and low-carbon development is an effective strategy.Although prior studies have examined the impact of urban polycentricity on carbon emissions and economic development,research on its role in the synergistic relationship between these factors regarding carbon emission efficiency is limited.Furthermore,existing literature often overlooks nonlinear effects and interactions with other urban variables.This paper analyzed data from 295 Chinese cities in 2020,calculating urban population polycentricity,population dispersion indices,and carbon emission efficiency.Utilizing local spatial autocorrelation tools,we reveal interactions among urban population polycentricity,dispersion,carbon emissions,and carbon emission efficiency.We then employ a gradient boosting decision tree model(GBDT)to explore nonlinear and synergistic effects of polycentric urbanization.Key findings include:1)polycentric urbanization in Chinese cities exhibits significant spatial differentiation characteristics.The Polycentricity index is relatively high in economically developed eastern coastal regions with an overall low level,carbon emissions are concentrated in industrialized north-central cities and some Yangtze River Delta hubs,and carbon emission efficiency is the highest in the Yangtze River Delta while relatively low in Northeast China;there are significant spatially heterogeneous interaction characteristics among population polycentricity,population dispersion,carbon emissions,and carbon emission efficiency.2)Urban population polycentricity contributes 9.42%to total carbon emissions and 6.24%to carbon emission efficiency.3)The polycentricity index has a nonlinear impact on carbon emissions and carbon emission efficiency:no significant effect when below 0.50 or above 0.55,increased carbon emissions in 0.50-0.53,and reduced carbon emissions with improved efficiency in 0.53-0.55.4)The polycentricity index has an interaction effect with other variables;specifically,when the polycentricity index is between 0.53 and 0.55,its interaction with urban gross domestic product(GDP),urban population,urban built-up area,green coverage rate in built-up areas,urban technological expenditure,and the proportion of the output value of the secondary industry will reduce carbon emissions and improve carbon emission efficiency.These findings enhance the understanding of urban spatial structures and carbon emissions,providing valuable insights for policymakers in developing green and low-carbon strategies.展开更多
Conventional superconducting nanowire single-photon detectors(SNSPDs)have been typically limited in their applications due to their size,weight,and power consumption,which confine their use to laboratory settings.Howe...Conventional superconducting nanowire single-photon detectors(SNSPDs)have been typically limited in their applications due to their size,weight,and power consumption,which confine their use to laboratory settings.However,with the rapid development of remote imaging,sensing technologies,and long-range quantum communication with fewer topographical constraints,the demand for high-efficiency single-photon detectors integrated with avionic platforms is rapidly growing.We herein designed and manufactured the first drone-based SNSPD system with a system detection efficiency(SDE)as high as 91.8%.This drone-based system incorporates high-performance NbTiN SNSPDs,a self-developed miniature liquid helium dewar,and custom-built integrated electrical setups,making it capable of being launched in complex topographical conditions.Such a drone-based SNSPD system may open the use of SNSPDs for applications that demand high SDE in complex environments.展开更多
To make agricultural systems sustainable in terms of their greenness and efficiency,optimizing the tillage and fertilization practices is essential.To assess the effects of tilling and fertilization practices in wheat...To make agricultural systems sustainable in terms of their greenness and efficiency,optimizing the tillage and fertilization practices is essential.To assess the effects of tilling and fertilization practices in wheat-maize cropping systems,a three-year field experiment was designed to quantify the carbon footprint(CF)and energy efficiency of the cropping systems in the North China Plain.The study parameters included four tillage practices(no tillage(NT),conventional tillage(CT),rotary tillage(RT),and subsoiling rotary tillage(SRT))and two fertilizer regimes(inorganic fertilizer(IF)and hybrid fertilizer with organic and inorganic components(HF)).The results indicated that the most prominent energy inputs and greenhouse gas(GHG)emissions could be ascribed to the use of fertilizers and fuel consumption.Under the same fertilization regime,ranking the tillage patterns with respect to the value of the crop yield,profit,CF,energy use efficiency(EUE)or energy productivity(EP)for either wheat or maize always gave the same sequence of SRT>RT>CT>NT.For the same tillage,the energy consumption associated with HF was higher than IF,but its GHG emissions and CF were lower while the yield and profit were higher.In terms of overall performance,tilling is more beneficial than NT,and reduced tillage practices(RT and SRT)are more beneficial than CT.The fertilization regime with the best overall performance was HF.Combining SRT with HF has significant potential for reducing CF and increasing EUE,thereby improving sustainability.Adopting measures that promote these optimizations can help to overcome the challenges posed by a lack of food security,energy crises and ecological stress.展开更多
Backscatter communication(BC)is con-sidered a key technology in self-sustainable commu-nications,and the unmanned aerial vehicle(UAV)as a data collector can improve the efficiency of data col-lection.We consider a UAV...Backscatter communication(BC)is con-sidered a key technology in self-sustainable commu-nications,and the unmanned aerial vehicle(UAV)as a data collector can improve the efficiency of data col-lection.We consider a UAV-aided BC system,where the power beacons(PBs)are deployed as dedicated radio frequency(RF)sources to supply power for backscatter devices(BDs).After harvesting enough energy,the BDs transmit data to the UAV.We use stochastic geometry to model the large-scale BC sys-tem.Specifically,the PBs are modeled as a type II Mat´ern hard-core point process(MHCPP II)and the BDs are modeled as a homogeneous Poisson point process(HPPP).Firstly,the BDs’activation proba-bility and average coverage probability are derived.Then,to maximize the energy efficiency(EE),we opti-mize the RF power of the PBs under different PB den-sities.Furthermore,we compare the coverage proba-bility and EE performance of our system with a bench-mark scheme,in which the distribution of PBs is mod-eled as a HPPP.Simulation results show that the PBs modeled as MHCPP II has better performance,and we found that the higher the density of PBs,the smaller the RF power required,and the EE is also higher.展开更多
The impact of the adaptive cruise control（ ACC）system on improving fuel efficiency is evaluated based on the vehicle-specific power. The intelligent driver model was first modified to simulate the ACC system and it ...The impact of the adaptive cruise control（ ACC）system on improving fuel efficiency is evaluated based on the vehicle-specific power. The intelligent driver model was first modified to simulate the ACC system and it was calibrated by using empirical traffic data. Then, a five-step procedure based on the vehicle-specific power was introduced to calculate fuel efficiency. Five scenarios with different ACC ratios were tested in simulation experiments, and sensitivity analyses of two key ACC factors affecting the perception-reaction time and time headway were also conducted. The simulation results indicate that all the scenarios with ACC vehicles have positive impacts on reducing fuel consumption. Furthermore, from the perspective of fuel efficiency, the extremely small value of the perception-reaction time of the ACC system is not necessary due to the fact that the value of 0.5 and 0.1 s can almost lead to the same reduction in fuel consumption. Finally, the designed time headway of the ACC system is also proposed to be large enough for fuel efficiency, although its small value can increase capacity. The findings of this study provide useful information for connected vehicles and autonomous vehicle manufacturers to improve fuel efficiency on roadways.展开更多
[Objective] The aim was to explore function and efficiency of emergy input/ output of Hunan agricultural ecosystem to reveal relationship of human being with natural resources and environment. [Method] Emergy structur...[Objective] The aim was to explore function and efficiency of emergy input/ output of Hunan agricultural ecosystem to reveal relationship of human being with natural resources and environment. [Method] Emergy structure, function and efficien- cy of Hunan agricultural ecosystem were analyzed based on input/output data in Hunan Province in 2009 as per emergy theory. [Result] The structure characters of agricultural ecosystem were as follows： Hunan is characterized with traditional agri- culture, depending greatly on both human and animal labor. For industrial accessory emergy, chemical fertilizers make most contribution to the system, and agricultural mechanization is not satisfied. Furthermore, renewable ratio of industrial accessory emergy is lower, and development and potential of green energy is promising. In addition, prices of the products are lower, without consideration of contribution made by natural resources and environment. It also suggested that Hunan agricultural chain is short and added value of products is not high. In general, emergy output of farming and animal husbandry dominates and the prices are lower than those of forestry and fishery. The function of the system was as follows： With lower environ- mental load ratio, the system is overloaded by population and the index of sustain- able development was 5.96, suggesting that the system enjoys vitality and potential, but the economy is undeveloped and the pressure from natural resources and envi- ronment is not high. The emergy output ratio was a little lower than national level in 2009, suggesting Hunan agricultural production is extensive. [Conclusion] The re- search indicated that rapid increase of population should be controlled; surplus labor should be transferred; agricultural structure and products structure should be further adjusted; agricultural technology should be further developed; agdcultural mechaniza- tion and modernization should be improved.展开更多
Studies on root development, soil physical properties, grain yield, and water-use efficiency are important for identifying suitable soil management practices for sustainable crop production. A field experiment was con...Studies on root development, soil physical properties, grain yield, and water-use efficiency are important for identifying suitable soil management practices for sustainable crop production. A field experiment was conducted from 2006 through 2008 in arid northwestern China to determine the effects of four tillage systems on soil properties, root development, water-use efficiency, and grain yield of winter wheat （Triticum aestivum L.）. The cultivar Fan 13 was grown under four tillage systems：conventional tillage （CT） without wheat stubble, no-tillage without wheat stubble mulching （NT）, no-tillage with wheat stubble standing （NTSS）, and no-tillage with wheat stubble mulching （NTS）. The soil bulk density （BD） under CT system increased gradually from sowing to harvest, but that in NT, NTSS, and NTS systems had little change. Compared to the CT system, the NTSS and NTS systems improved total soil water storage （0-150 cm） by 6.1-9.6 and 10.5- 15.3% before sowing, and by 2.2-8.9 and 13.0-15.1% after harvest, respectively. The NTSS and NTS systems also increased mean dry root weight density （DRWD） as compared to CT system. The NTS system significantly improved water-use efficiency by 17.2-17.5% and crop yield by 15.6-16.8%, and the NTSS system improved that by 7.8-9.6 and 7.0-12.8%, respectively, compared with the CT system. Our results suggested that Chinese farmers should consider adopting conservation tillage practices in arid northwestern China because of benefits to soil bulk density, water storage, root system, and winter wheat yield.展开更多
To evaluate the effects of various rotation systems on rice grain yield and N use efficiency, a paddy–upland cropping experiment(2013–2016) was conducted in southeastern China. The experiment was designed using six ...To evaluate the effects of various rotation systems on rice grain yield and N use efficiency, a paddy–upland cropping experiment(2013–2016) was conducted in southeastern China. The experiment was designed using six different rice––winter crop rotations: rice–fallow(RF),rice–wheat(RW), rice–potato with rice straw mulch(RP), rice–green manure(Chinese milk vetch; RC–G), rice–oilseed rape(RO), and rice–green manure crop(oilseed rape with fresh straw incorporated into soil at flowering; RO–G) and three N rates, N0(0 kg N ha-1), N1(142.5 kg N ha-1), and N2(202.5 kg N ha-1). Average rice yields in the RF(5.93 t ha-1) rotation were significantly lower than those in the rotations with winter crops(7.20–7.48 t ha-1)under the N0 treatment, suggesting that incorporation of straw might be more effective for increasing soil N than winter fallow. The rice yield differences among the rotations varied by year with the N input. In general, the grain yields in the RP and RO–G rotations –were respectively 11.6–28.5% and 14.80–37.19% higher than those in the RF in plots with N applied. Increasing the N rate may have tended to minimize the average yield gap between the RF and the other rotations; the yield gaps were 18.55%, 4.14%, and 0.23% in N0, N1, and N2, respectively. However, the N recovery efficiency in the RF was significantly lower than that in other rotations, except for 2015 under both N1 and N2 rates, a finding that implies a large amount of chemical N loss. No significant differences in nitrogen agronomic efficiency(NAE) and physiological efficiency(NPE) were found between the rotations with legume(RC–G) and non–legume(RO and RW) winter crops, a result that may be due partly to straw incorporation. For this reason, we concluded that the return of straw could reduce differences in N use efficiency between rotations with and without legume crops. The degree of synchrony between the crop N demand and the N supply was evaluated by comparison of nitrogen balance degree(NBD) values. The NBD values in the RP and RW were significantly lower than those in the other rotations under both N1 and N2 rates. Thus,in view of the higher grain yield in the RP compared to the RW under the N1 rate, the RP rotation might be a promising practice with comparable grain yield and greater N use efficiency under reduced N input relative to the other rotations. The primary yield components of the RF and RP were identified as number of panicles m-2 and numbers of kernels panicle-1, respectively. The NAE and NPE were positively correlated with harvest index, possibly providing a useful indicator for evaluating N use efficiency.展开更多
Agronomically optimizing the timing and rates of nitrogen(N) fertilizer application can increase crop yield and decrease N loss to the environment. Wheat(Triticum aestivum L.)–peanut(Arachis hypogaea L.) relay interc...Agronomically optimizing the timing and rates of nitrogen(N) fertilizer application can increase crop yield and decrease N loss to the environment. Wheat(Triticum aestivum L.)–peanut(Arachis hypogaea L.) relay intercropping systems are a mainstay of economic and food security in China. We performed a field experiment to investigate the effects of N fertilizer on N recovery efficiency, crop yield, and N loss rate in wheat–peanut relay intercropping systems in the Huang-Huai-Hai Plain, China during 2015–2017. The N was applied on the day before sowing, the jointing stage(G30) or the booting stage(G40) of winter wheat, and the anthesis stage(R1) of peanut in the following percentage splits: 50-50-0-0(N1), 35-35-0-30(N2), and 35-0-35-30(N3), using 300 kg N ha-1, with 0 kg N ha-1(N0) as control. ^(15)N-labeled(20.14 atom %) urea was used to trace the fate of N in microplots. The yields of wheat and peanut increased by 12.4% and 15.4% under the N2 and N3 treatments, relative to those under the N1 treatment. The ^(15)N recovery efficiencies( ^(15)NRE) were 64.9% and 58.1% for treatments N2 and N3, significantly greater than that for the N1 treatment(45.3%). The potential N loss rates for the treatments N2 and N3 were23.7% and 7.0%, significantly lower than that for treatment N1(30.1%). Withholding N supply until the booting stage(N3) did not reduce the wheat grain yield; however, it increased the N content derived from ^(15)N-labeled urea in peanuts, promoted the distribution of ^(15)N to pods, and ultimately increased pod yields in comparison with those obtained by topdressing N at jointing stage(N2). In comparison with N2, the N uptake and N recovery efficiency(NRE) of N3 was increased by 12.0% and 24.1%,respectively, while the apparent N loss decreased by 16.7%. In conclusion, applying N fertilizer with three splits and delaying topdressing fertilization until G40 of winter wheat increased total grain yields and NRE and reduced N loss. This practice could be an environment-friendly N management strategy for wheat–peanut relay intercropping systems in China.展开更多
Water use efficiency(WUE),as a pivotal indicator of the coupling degree within the carbon–water cycle of ecosystems,holds considerable importance in assessment of the carbon–water balance within terrestrial ecosyste...Water use efficiency(WUE),as a pivotal indicator of the coupling degree within the carbon–water cycle of ecosystems,holds considerable importance in assessment of the carbon–water balance within terrestrial ecosystems.However,in the context of global warming,WUE evolution and its primary drivers on the Tibetan Plateau remain unclear.This study employed the ensemble empirical mode decomposition method and the random forest algorithm to decipher the nonlinear trends and drivers of WUE on the Tibetan Plateau in 2001–2020.Results indicated an annual mean WUE of 0.8088 gC/mm·m^(2)across the plateau,with a spatial gradient reflecting decrease from the southeast toward the northwest.Areas manifesting monotonous trends of increase or decrease in WUE accounted for 23.64%and 9.69%of the total,respectively.Remarkably,66.67%of the region exhibited trend reversals,i.e.,39.94%of the area of the Tibetan Plateau showed transition from a trend of increase to a trend of decrease,and 26.73%of the area demonstrated a shift from a trend of decrease to a trend of increase.Environmental factors accounted for 70.79%of the variability in WUE.The leaf area index and temperature served as the major driving forces of WUE variation.展开更多
Deep placement of nitrogen fertilizer is a key strategy for improving nitrogen use efficiency. A two-year field experiment was conducted during the early rice growing seasons(March–July) of 2016 and 2017.The experime...Deep placement of nitrogen fertilizer is a key strategy for improving nitrogen use efficiency. A two-year field experiment was conducted during the early rice growing seasons(March–July) of 2016 and 2017.The experimental treatments comprised two rice cultivars: Wufengyou 615(WFY 615) and Yuxiangyouzhan(YXYZ), and three N treatments: mechanical deep placement of all fertilizers as basal dose at 10 cm soil depth(one-time deep-placement fertilization, namely OTDP fertilization);manual surface broadcast(the common farmer practice) of 40% N fertilizer at one day before sowing(basal fertilizer)followed by broadcast application of 30% each at tillering and panicle initiation stages;and no fertilizer application at any growth stage as a control. One-time deep-placement fertilization increased grain yield of both rice cultivars by 11.8%–19.6%, total nitrogen accumulation by 10.3%–13.1%, nitrogen grain production efficiency by 29.7%–31.5%, nitrogen harvest index by 27.8%–30.0%, nitrogen agronomic efficiency by 71.3%–77.2%, and nitrogen recovery efficiency by 42.4%–56.7% for both rice cultivars, compared with the multiple-broadcast treatment. One-time deep-placement fertilization reduced CH4-induced global warming potential(GWP) by 20.7%–25.3%, N2O-induced GWP by 7.2%–12.3%, and total GWP by 14.7%–22.9% for both rice cultivars relative to the multiple-broadcast treatment. The activities of glutamine synthetase and nitrate reductase were increased at both panicle-initiation and heading stages in both rice cultivars following one-time deep-placement fertilization treatment. Larger leaf area index at heading stage and more favorable root morphological traits expressed as larger total root length, mean root diameter, and total root volume per hill were also observed. One-time deep-placement fertilization could be an effective strategy for increasing grain yield and nitrogen use efficiency and lowering greenhouse-gas emissions under mechanical direct-seeded cropping systems.展开更多
文摘A series of blue and blue‑green Ir(Ⅲ)complexes has been investigated theoretically to explore their electronic structures,photophysical properties,efficiency roll‑off effect,and thermal activation delayed fluorescence(TADF)properties.All calculations were performed using density functional theory(DFT)and time‑dependent density functional theory(TDDFT).Calculations for electronic structures,frontier molecular orbital characteristics(which determine the efficiency roll‑off effect of the complexes),and photophysical properties were conducted using the Gaussian 09 software package.The calculation of spin‑orbit coupling matrix elements<T|HSOC|S>,which determine the TADF properties of the complexes,was performed using the ORCA software package.The calculation results show that the auxiliary ligand tetraphenylimidodiphosphinate(tpip),a strong electron‑withdrawing group,can mitigate the efficiency roll‑off effect of the complex.Furthermore,TADF is observed in one of the designed complexes,(F_(3)Phppy)_(2)Ir(tpip),where F_(3)Phppy=2‑[4‑(2,4,6‑trifluorophenyl)phenyl]pyridine.
文摘The goal of the present work is to demonstrate the potential of Artificial Neural Network(ANN)-driven Genetic Algorithm(GA)methods for energy efficiency and economic performance optimization of energy efficiency measures in a multi-family house building in Greece.The energy efficiency measures include different heating/cooling systems(such as low-temperature and high-temperature heat pumps,natural gas boilers,split units),building envelope components for floor,walls,roof and windows of variable heat transfer coefficients,the installation of solar thermal collectors and PVs.The calculations of the building loads and investment and operating and maintenance costs of the measures are based on the methodology defined in Directive 2010/31/EU,while economic assumptions are based on EN 15459-1 standard.Typically,multi-objective optimization of energy efficiency measures often requires the simulation of very large numbers of cases involving numerous possible combinations,resulting in intense computational load.The results of the study indicate that ANN-driven GA methods can be used as an alternative,valuable tool for reliably predicting the optimal measures which minimize primary energy consumption and life cycle cost of the building with greatly reduced computational requirements.Through GA methods,the computational time needed for obtaining the optimal solutions is reduced by 96.4%-96.8%.
基金supported by the National Science and Technology Major Project of China(2025ZD1406703)the Open Fund of Key Laboratory of Oil&Gas Equipment,Ministry of Education(Southwest Petroleum University)(Grant No.OGE20230206).
文摘Shock waves in the nozzle during supersonic separation under different conditions can disrupt the flow field’s thermodynamic equilibrium.While it contributes to the recovery of pressure energy,it also leads to the dissipation of mechanical energy.This study aimed to investigate the effects of changes in back pressure on the shock wave position and its subsequent impact on the refrigeration performance of nozzles.A mathematical model for the supersonic gas in a nozzle was established and evaluated via experiments.The results show that when the back pressure is less than 0.2 MPa,no shock wave is generated in the nozzle,and high refrigeration and liquefaction efficiency can be ensured while effective pressure recovery is achieved.When the back pressure(pb)is increased from 0.3 to 0.6 MPa,the refrigeration efficiency of the nozzle decreases,and the shock wave position(x shock)is advanced from 157 to 118 mm.The maximum Mach number(Ma)that can be reached by the fluid in the nozzle is reduced from 1.97 to 1.27.When the back pressure is increased from 0.2 to 0.6 MPa,the minimum temperature is increased by 55.18 K.When the back pressure is greater than 0.3 MPa,the Mach number upstream of the shock wave is reduced from 1.97 to 1.27,the shock wave intensity is weakened,and the thickness of the boundary layer separation caused by the shock wave is also decreased accordingly.Therefore,to ensure refrigeration efficiency,measures should be taken to control the back pressure within a reasonable range.
文摘Curtain wall systems have evolved from aesthetic facade elements into multifunctional building envelopes that actively contribute to energy efficiency and climate responsiveness.This reviewpresents a comprehensive examination of curtain walls from an energy-engineering perspective,highlighting their structural typologies(Stick and Unitized),material configurations,and integration with smart technologies such as electrochromic glazing,parametric design algorithms,and Building Management Systems(BMS).Thestudy explores the thermal,acoustic,and solar performance of curtain walls across various climatic zones,supported by comparative analyses and iconic case studies including Apple Park,Burj Khalifa,and Milad Tower.Key challenges—including installation complexity,high maintenance costs,and climate sensitivity—are critically assessed alongside proposed solutions.A central innovation of this work lies in framing curtain walls not only as passive architectural elements but as dynamic interfaces that modulate energy flows,reduce HVAC loads,and enhance occupant comfort.The reviewed data indicate that optimized curtain wall configurations—especially those integrating electrochromic glazing and BIPV modules—can achieve annual energy consumption reductions ranging fromapproximately 5%to 27%,depending on climate,control strategy,and facade typology.The findings offer a valuable reference for architects,energy engineers,and decision-makers seeking to integrate high-performance facades into future-ready building designs.
基金support from the Heilongjiang Province"Double First Class"Discipline Collaborative Innovation Project(No.LJGXCG2023-061).
文摘Hard carbon is a vital anode material for sodium-ion batteries;however,the nonuniform growth of solid electrolyte interphase(SEI)film substantially diminishes its initial coulombic efficiency(ICE)and cycle life.The chemical and morphological properties of surface highly influence the electrode/electrolyte interfacial reactions.In this study,we have tuned orbital hybridization states forming an interface enriched with sp^(2) hybridized carbon(sp^(2)-C),which decreases the binding energy to solvent molecules and inhibits excessive solvent decomposition during SEI formation.Benefiting from successfully constructed inorganic-rich SEI,the ICE increased to 91%and sodium storage capacity reached 346 mAh/g.Besides,the capacity retention rate was 90.7%after 700 cycles at 1 A/g higher than pristine electrode(83.8%).
基金supported by the National Natural Science Foundation of China(42071238)the Jiuzhaigou Post-Disaster Restoration and Reconstruction Program(5132202020000046)+1 种基金the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)the Ministry of Science and Technology of the People's Republic of China(2019QZKK0402)。
文摘Evaluating the effectivenes s of forest restoration projects is crucial for designing adaptive restoration strategies.However,existing studies have primarily focused on ecological outcomes while overlooking cost inputs.This gap can lead to increased uncertainties in restoration planning.Here we investigated forest dynamics in China's Upper Yangtze River Basin(UYRB)using kernel Normalized Difference Vegetation Index(kNDVI),Leaf Area Index(LAI),Gross Primary Productivity(GPP),Ku-band Vegetation Optical Depth(Ku-VOD)time series and climate data from1982 to 2020.Subsequently,we employed a residual trend analysis integrating temporal effects to determine the relative contributions of climate change and human activities to forest dynamics before and after the implementation of forest restoration engineering in 1998.Additionally,we developed an Afforestation Efficiency Index(AEI)to quantitatively assess the cost efficiency of afforestation projects.Results indicated that forest in the UYRB showed sustained increases during 1982-2020,with most areas experiencing greater growth after 1998 than before.Temporal effects of climatic factors influenced over 42.7%of the forest,and incorporating time-lag and cumulative effects enhanced climate-based explanations of forest variations by 1.61-24.73%.Human activities emerged as the dominant driver of forest dynamics post 1998,whereas climate variables predominated before this period.The cost-effectiveness of forest restoration projects in the UYRB typically ranges from moderate to high,with higher success predominantly observed in the northeastern and eastern counties,while the central,western,and northwestern counties mainly showed relatively low efficiency.These findings stress the need for assessing forest restoration outcomes from both ecological and cost perspectives,and can offer valuable insights for optimizing the layout of forest restoration initiatives in the UYRB.
基金Financial support from the National Natural Science Foundation of China(22375024,21975031,21734009,51933001,22109080,and 52173174)the Natural Science Foundation of Shandong Province(No.ZR2022YQ45)+2 种基金the Taishan Scholars Program(Nos.tstp20221121 and tsqnz20221134)The Beijing Natural Science Foundation(No.2244073)supported by State Key Laboratory of Bio-Fibers and Eco-Textiles(Qingdao University)(RZ2200002821)is acknowledged.
文摘A nonfused ring electron acceptor(NFREA),designated as TT-Ph-C6,has been synthesized with the aim of enhancing the power conversion efficiency(PCE)of organic solar cells(OSCs).By integrating asymmetric phenylalkylamino side groups,TT-Ph-C6 demonstrates excellent solubility and its crystal structure exhibits compact packing structures with a three-dimensional molecular stacking network.These structural attributes markedly promote exciton diffusion and charge carrier mobility,particularly advantageous for the fabrication of thick-film devices.TT-Ph-C6-based devices have attained a PCE of 18.01%at a film thickness of 100 nm,and even at a film thickness of 300 nm,the PCE remains at 14.64%,surpassing that of devices based on 2BTh-2F.These remarkable properties position TT-Ph-C6 as a highly promising NFREA material for boosting the efficiency of OSCs.
基金funded by the Huaiyin Institute of Technology—Institute of Smart Energy.
文摘In the quest to enhance energy efficiency and reduce environmental impact in the transportation sector,the recovery of waste heat from diesel engines has become a critical area of focus.This study provided an exhaustive thermodynamic analysis optimizing Organic Rankine Cycle(ORC)systems forwaste heat recovery fromdiesel engines.Thestudy assessed the performance of five candidateworking fluids—R11,R123,R113,R245fa,and R141b—under a range of operating conditions,specifically varying overheat temperatures and evaporation pressures.The results indicated that the choice of working fluid substantially influences the system’s exergetic efficiency,net output power,and thermal efficiency.R245fa showed an outstanding net output power of 30.39 kW at high overheat conditions,outperforming R11,which is significant for high-temperature waste heat recovery.At lower temperatures,R11 and R113 demonstrated higher exergetic efficiencies,with R11 reaching a peak exergetic efficiency of 7.4%at an evaporation pressure of 10 bar and an overheat of 10℃.The study also revealed that controlling the overheat and optimizing the evaporation pressure are crucial for enhancing the net output power of the ORC system.Specifically,at an evaporation pressure of 30 bar and an overheat of 0℃,R113 exhibited the lowest exergetic destruction of 544.5 kJ/kg,making it a suitable choice for minimizing irreversible losses.These findings are instrumental for understanding the performance of ORC systems in waste heat recovery applications and offer valuable insights for the design and operation of more efficient and environmentally friendly diesel engine systems.
基金supported by the Jilin Science and Technology Development Program,China (20240602032RC)the Jilin Agricultural Science and Technology Innovation Project,China (CXGC2024ZD001)+1 种基金the Jilin Agricultural Science and Technology Innovation Project,China (CXGC2024ZY012)the Jilin Province Development and Reform Commission-Project for Improving the Independent Innovation Capacity of Major Grain Crops,China (2024C002)。
文摘Emerging and powerful genome editing tools,particularly CRISPR/Cas9,are facilitating functional genomics research and accelerating crop improvement(Jiang et al.2021;Cao et al.2023;Chen C et al.2023;Liu et al.2023a).However,the detection and screening of transgenic lines remain major bottlenecks,being time-consuming,labor-intensive,and inefficient during transformation and subsequent mutation identification.A simple and efficient visual marker system plays a critical role in addressing these challenges.Recent studies demonstrated that the GmW1 and RUBY reporter systems were used to obtain visual transgenic soybean(Glycine max) plants(Chen L et al.2023;Chen et al.2024).
基金Under the auspices of National Natural Science Foundation of China(No.42571300)。
文摘Transforming urban spatial structures to promote green and low-carbon development is an effective strategy.Although prior studies have examined the impact of urban polycentricity on carbon emissions and economic development,research on its role in the synergistic relationship between these factors regarding carbon emission efficiency is limited.Furthermore,existing literature often overlooks nonlinear effects and interactions with other urban variables.This paper analyzed data from 295 Chinese cities in 2020,calculating urban population polycentricity,population dispersion indices,and carbon emission efficiency.Utilizing local spatial autocorrelation tools,we reveal interactions among urban population polycentricity,dispersion,carbon emissions,and carbon emission efficiency.We then employ a gradient boosting decision tree model(GBDT)to explore nonlinear and synergistic effects of polycentric urbanization.Key findings include:1)polycentric urbanization in Chinese cities exhibits significant spatial differentiation characteristics.The Polycentricity index is relatively high in economically developed eastern coastal regions with an overall low level,carbon emissions are concentrated in industrialized north-central cities and some Yangtze River Delta hubs,and carbon emission efficiency is the highest in the Yangtze River Delta while relatively low in Northeast China;there are significant spatially heterogeneous interaction characteristics among population polycentricity,population dispersion,carbon emissions,and carbon emission efficiency.2)Urban population polycentricity contributes 9.42%to total carbon emissions and 6.24%to carbon emission efficiency.3)The polycentricity index has a nonlinear impact on carbon emissions and carbon emission efficiency:no significant effect when below 0.50 or above 0.55,increased carbon emissions in 0.50-0.53,and reduced carbon emissions with improved efficiency in 0.53-0.55.4)The polycentricity index has an interaction effect with other variables;specifically,when the polycentricity index is between 0.53 and 0.55,its interaction with urban gross domestic product(GDP),urban population,urban built-up area,green coverage rate in built-up areas,urban technological expenditure,and the proportion of the output value of the secondary industry will reduce carbon emissions and improve carbon emission efficiency.These findings enhance the understanding of urban spatial structures and carbon emissions,providing valuable insights for policymakers in developing green and low-carbon strategies.
基金the Innovation Program for Quantum Science and Technology(Grant No.2023ZD0300100)the National Key Research and Development Program of China(Grant Nos.2023YFB3809600 and 2023YFC3007801)+1 种基金the National Natural Science Foundation of China(Grant Nos.62301543 and U24A20320)the Shanghai Sailing Program(Grant No.21YF1455700).
文摘Conventional superconducting nanowire single-photon detectors(SNSPDs)have been typically limited in their applications due to their size,weight,and power consumption,which confine their use to laboratory settings.However,with the rapid development of remote imaging,sensing technologies,and long-range quantum communication with fewer topographical constraints,the demand for high-efficiency single-photon detectors integrated with avionic platforms is rapidly growing.We herein designed and manufactured the first drone-based SNSPD system with a system detection efficiency(SDE)as high as 91.8%.This drone-based system incorporates high-performance NbTiN SNSPDs,a self-developed miniature liquid helium dewar,and custom-built integrated electrical setups,making it capable of being launched in complex topographical conditions.Such a drone-based SNSPD system may open the use of SNSPDs for applications that demand high SDE in complex environments.
基金supported by research grants from the Natural Science Foundation of Shandong Province,China(ZR2020MC092)the Key Research and Development Project of Shandong Province,China(2019TSCYCX-33)the Key Research and Development Project of Shandong Province,China(LJNY202025).
文摘To make agricultural systems sustainable in terms of their greenness and efficiency,optimizing the tillage and fertilization practices is essential.To assess the effects of tilling and fertilization practices in wheat-maize cropping systems,a three-year field experiment was designed to quantify the carbon footprint(CF)and energy efficiency of the cropping systems in the North China Plain.The study parameters included four tillage practices(no tillage(NT),conventional tillage(CT),rotary tillage(RT),and subsoiling rotary tillage(SRT))and two fertilizer regimes(inorganic fertilizer(IF)and hybrid fertilizer with organic and inorganic components(HF)).The results indicated that the most prominent energy inputs and greenhouse gas(GHG)emissions could be ascribed to the use of fertilizers and fuel consumption.Under the same fertilization regime,ranking the tillage patterns with respect to the value of the crop yield,profit,CF,energy use efficiency(EUE)or energy productivity(EP)for either wheat or maize always gave the same sequence of SRT>RT>CT>NT.For the same tillage,the energy consumption associated with HF was higher than IF,but its GHG emissions and CF were lower while the yield and profit were higher.In terms of overall performance,tilling is more beneficial than NT,and reduced tillage practices(RT and SRT)are more beneficial than CT.The fertilization regime with the best overall performance was HF.Combining SRT with HF has significant potential for reducing CF and increasing EUE,thereby improving sustainability.Adopting measures that promote these optimizations can help to overcome the challenges posed by a lack of food security,energy crises and ecological stress.
文摘Backscatter communication(BC)is con-sidered a key technology in self-sustainable commu-nications,and the unmanned aerial vehicle(UAV)as a data collector can improve the efficiency of data col-lection.We consider a UAV-aided BC system,where the power beacons(PBs)are deployed as dedicated radio frequency(RF)sources to supply power for backscatter devices(BDs).After harvesting enough energy,the BDs transmit data to the UAV.We use stochastic geometry to model the large-scale BC sys-tem.Specifically,the PBs are modeled as a type II Mat´ern hard-core point process(MHCPP II)and the BDs are modeled as a homogeneous Poisson point process(HPPP).Firstly,the BDs’activation proba-bility and average coverage probability are derived.Then,to maximize the energy efficiency(EE),we opti-mize the RF power of the PBs under different PB den-sities.Furthermore,we compare the coverage proba-bility and EE performance of our system with a bench-mark scheme,in which the distribution of PBs is mod-eled as a HPPP.Simulation results show that the PBs modeled as MHCPP II has better performance,and we found that the higher the density of PBs,the smaller the RF power required,and the EE is also higher.
基金The National Natural Science Foundation of China(No.51338003,51478113,51378120)
文摘The impact of the adaptive cruise control（ ACC）system on improving fuel efficiency is evaluated based on the vehicle-specific power. The intelligent driver model was first modified to simulate the ACC system and it was calibrated by using empirical traffic data. Then, a five-step procedure based on the vehicle-specific power was introduced to calculate fuel efficiency. Five scenarios with different ACC ratios were tested in simulation experiments, and sensitivity analyses of two key ACC factors affecting the perception-reaction time and time headway were also conducted. The simulation results indicate that all the scenarios with ACC vehicles have positive impacts on reducing fuel consumption. Furthermore, from the perspective of fuel efficiency, the extremely small value of the perception-reaction time of the ACC system is not necessary due to the fact that the value of 0.5 and 0.1 s can almost lead to the same reduction in fuel consumption. Finally, the designed time headway of the ACC system is also proposed to be large enough for fuel efficiency, although its small value can increase capacity. The findings of this study provide useful information for connected vehicles and autonomous vehicle manufacturers to improve fuel efficiency on roadways.
基金Supported by National Social Science Foundation (11BJY029)Hunan Social ScienceFoundation (2010YBB348)+1 种基金Innovation Platform Funds of Hunan High Institutions(10K080)Hunan Soft Science Key Project (2011ZK2046)~~
文摘[Objective] The aim was to explore function and efficiency of emergy input/ output of Hunan agricultural ecosystem to reveal relationship of human being with natural resources and environment. [Method] Emergy structure, function and efficien- cy of Hunan agricultural ecosystem were analyzed based on input/output data in Hunan Province in 2009 as per emergy theory. [Result] The structure characters of agricultural ecosystem were as follows： Hunan is characterized with traditional agri- culture, depending greatly on both human and animal labor. For industrial accessory emergy, chemical fertilizers make most contribution to the system, and agricultural mechanization is not satisfied. Furthermore, renewable ratio of industrial accessory emergy is lower, and development and potential of green energy is promising. In addition, prices of the products are lower, without consideration of contribution made by natural resources and environment. It also suggested that Hunan agricultural chain is short and added value of products is not high. In general, emergy output of farming and animal husbandry dominates and the prices are lower than those of forestry and fishery. The function of the system was as follows： With lower environ- mental load ratio, the system is overloaded by population and the index of sustain- able development was 5.96, suggesting that the system enjoys vitality and potential, but the economy is undeveloped and the pressure from natural resources and envi- ronment is not high. The emergy output ratio was a little lower than national level in 2009, suggesting Hunan agricultural production is extensive. [Conclusion] The re- search indicated that rapid increase of population should be controlled; surplus labor should be transferred; agricultural structure and products structure should be further adjusted; agricultural technology should be further developed; agdcultural mechaniza- tion and modernization should be improved.
基金funded by the Ph D Programs Foundation, Ministry of Education, China(20106202110002)the National Public Welfare Foundation for Industry Scheme of China (201103001)the National Natural Science Foundation of China (201131160265)
文摘Studies on root development, soil physical properties, grain yield, and water-use efficiency are important for identifying suitable soil management practices for sustainable crop production. A field experiment was conducted from 2006 through 2008 in arid northwestern China to determine the effects of four tillage systems on soil properties, root development, water-use efficiency, and grain yield of winter wheat （Triticum aestivum L.）. The cultivar Fan 13 was grown under four tillage systems：conventional tillage （CT） without wheat stubble, no-tillage without wheat stubble mulching （NT）, no-tillage with wheat stubble standing （NTSS）, and no-tillage with wheat stubble mulching （NTS）. The soil bulk density （BD） under CT system increased gradually from sowing to harvest, but that in NT, NTSS, and NTS systems had little change. Compared to the CT system, the NTSS and NTS systems improved total soil water storage （0-150 cm） by 6.1-9.6 and 10.5- 15.3% before sowing, and by 2.2-8.9 and 13.0-15.1% after harvest, respectively. The NTSS and NTS systems also increased mean dry root weight density （DRWD） as compared to CT system. The NTS system significantly improved water-use efficiency by 17.2-17.5% and crop yield by 15.6-16.8%, and the NTSS system improved that by 7.8-9.6 and 7.0-12.8%, respectively, compared with the CT system. Our results suggested that Chinese farmers should consider adopting conservation tillage practices in arid northwestern China because of benefits to soil bulk density, water storage, root system, and winter wheat yield.
基金The National Key Research and Development Program of China(2016YFD0300108,2016YFD0300208-02)the National Natural Science Foundation of China(31671638)+1 种基金the China Agriculture Research System(CARS-01-04A)the Special Fund for Agro-scientific Research in the Public Interest(201203096)partly supported this study
文摘To evaluate the effects of various rotation systems on rice grain yield and N use efficiency, a paddy–upland cropping experiment(2013–2016) was conducted in southeastern China. The experiment was designed using six different rice––winter crop rotations: rice–fallow(RF),rice–wheat(RW), rice–potato with rice straw mulch(RP), rice–green manure(Chinese milk vetch; RC–G), rice–oilseed rape(RO), and rice–green manure crop(oilseed rape with fresh straw incorporated into soil at flowering; RO–G) and three N rates, N0(0 kg N ha-1), N1(142.5 kg N ha-1), and N2(202.5 kg N ha-1). Average rice yields in the RF(5.93 t ha-1) rotation were significantly lower than those in the rotations with winter crops(7.20–7.48 t ha-1)under the N0 treatment, suggesting that incorporation of straw might be more effective for increasing soil N than winter fallow. The rice yield differences among the rotations varied by year with the N input. In general, the grain yields in the RP and RO–G rotations –were respectively 11.6–28.5% and 14.80–37.19% higher than those in the RF in plots with N applied. Increasing the N rate may have tended to minimize the average yield gap between the RF and the other rotations; the yield gaps were 18.55%, 4.14%, and 0.23% in N0, N1, and N2, respectively. However, the N recovery efficiency in the RF was significantly lower than that in other rotations, except for 2015 under both N1 and N2 rates, a finding that implies a large amount of chemical N loss. No significant differences in nitrogen agronomic efficiency(NAE) and physiological efficiency(NPE) were found between the rotations with legume(RC–G) and non–legume(RO and RW) winter crops, a result that may be due partly to straw incorporation. For this reason, we concluded that the return of straw could reduce differences in N use efficiency between rotations with and without legume crops. The degree of synchrony between the crop N demand and the N supply was evaluated by comparison of nitrogen balance degree(NBD) values. The NBD values in the RP and RW were significantly lower than those in the other rotations under both N1 and N2 rates. Thus,in view of the higher grain yield in the RP compared to the RW under the N1 rate, the RP rotation might be a promising practice with comparable grain yield and greater N use efficiency under reduced N input relative to the other rotations. The primary yield components of the RF and RP were identified as number of panicles m-2 and numbers of kernels panicle-1, respectively. The NAE and NPE were positively correlated with harvest index, possibly providing a useful indicator for evaluating N use efficiency.
基金supported by the National Key Technology R&D Program of China (2014BAD11B04-2)the National Natural Science Foundation of China (30840056, 31171496)Shandong Modern Agricultural Technology and Industry System (SDAIT-04-01)
文摘Agronomically optimizing the timing and rates of nitrogen(N) fertilizer application can increase crop yield and decrease N loss to the environment. Wheat(Triticum aestivum L.)–peanut(Arachis hypogaea L.) relay intercropping systems are a mainstay of economic and food security in China. We performed a field experiment to investigate the effects of N fertilizer on N recovery efficiency, crop yield, and N loss rate in wheat–peanut relay intercropping systems in the Huang-Huai-Hai Plain, China during 2015–2017. The N was applied on the day before sowing, the jointing stage(G30) or the booting stage(G40) of winter wheat, and the anthesis stage(R1) of peanut in the following percentage splits: 50-50-0-0(N1), 35-35-0-30(N2), and 35-0-35-30(N3), using 300 kg N ha-1, with 0 kg N ha-1(N0) as control. ^(15)N-labeled(20.14 atom %) urea was used to trace the fate of N in microplots. The yields of wheat and peanut increased by 12.4% and 15.4% under the N2 and N3 treatments, relative to those under the N1 treatment. The ^(15)N recovery efficiencies( ^(15)NRE) were 64.9% and 58.1% for treatments N2 and N3, significantly greater than that for the N1 treatment(45.3%). The potential N loss rates for the treatments N2 and N3 were23.7% and 7.0%, significantly lower than that for treatment N1(30.1%). Withholding N supply until the booting stage(N3) did not reduce the wheat grain yield; however, it increased the N content derived from ^(15)N-labeled urea in peanuts, promoted the distribution of ^(15)N to pods, and ultimately increased pod yields in comparison with those obtained by topdressing N at jointing stage(N2). In comparison with N2, the N uptake and N recovery efficiency(NRE) of N3 was increased by 12.0% and 24.1%,respectively, while the apparent N loss decreased by 16.7%. In conclusion, applying N fertilizer with three splits and delaying topdressing fertilization until G40 of winter wheat increased total grain yields and NRE and reduced N loss. This practice could be an environment-friendly N management strategy for wheat–peanut relay intercropping systems in China.
基金National Nonprofit Institute Research Grant of CAF,No.CAFYBB2018ZA004,No.CAFYBB2023ZA009Fengyun Application Pioneering Project,No.FY-APP-ZX-2023.02。
文摘Water use efficiency(WUE),as a pivotal indicator of the coupling degree within the carbon–water cycle of ecosystems,holds considerable importance in assessment of the carbon–water balance within terrestrial ecosystems.However,in the context of global warming,WUE evolution and its primary drivers on the Tibetan Plateau remain unclear.This study employed the ensemble empirical mode decomposition method and the random forest algorithm to decipher the nonlinear trends and drivers of WUE on the Tibetan Plateau in 2001–2020.Results indicated an annual mean WUE of 0.8088 gC/mm·m^(2)across the plateau,with a spatial gradient reflecting decrease from the southeast toward the northwest.Areas manifesting monotonous trends of increase or decrease in WUE accounted for 23.64%and 9.69%of the total,respectively.Remarkably,66.67%of the region exhibited trend reversals,i.e.,39.94%of the area of the Tibetan Plateau showed transition from a trend of increase to a trend of decrease,and 26.73%of the area demonstrated a shift from a trend of decrease to a trend of increase.Environmental factors accounted for 70.79%of the variability in WUE.The leaf area index and temperature served as the major driving forces of WUE variation.
基金supported by the Key-Area Research and Development Program of Guangdong Province(2019B020221003)National Natural Science Foundation of Guangdong Province(008175187004)National Natural Science Foundation of China(31471442)。
文摘Deep placement of nitrogen fertilizer is a key strategy for improving nitrogen use efficiency. A two-year field experiment was conducted during the early rice growing seasons(March–July) of 2016 and 2017.The experimental treatments comprised two rice cultivars: Wufengyou 615(WFY 615) and Yuxiangyouzhan(YXYZ), and three N treatments: mechanical deep placement of all fertilizers as basal dose at 10 cm soil depth(one-time deep-placement fertilization, namely OTDP fertilization);manual surface broadcast(the common farmer practice) of 40% N fertilizer at one day before sowing(basal fertilizer)followed by broadcast application of 30% each at tillering and panicle initiation stages;and no fertilizer application at any growth stage as a control. One-time deep-placement fertilization increased grain yield of both rice cultivars by 11.8%–19.6%, total nitrogen accumulation by 10.3%–13.1%, nitrogen grain production efficiency by 29.7%–31.5%, nitrogen harvest index by 27.8%–30.0%, nitrogen agronomic efficiency by 71.3%–77.2%, and nitrogen recovery efficiency by 42.4%–56.7% for both rice cultivars, compared with the multiple-broadcast treatment. One-time deep-placement fertilization reduced CH4-induced global warming potential(GWP) by 20.7%–25.3%, N2O-induced GWP by 7.2%–12.3%, and total GWP by 14.7%–22.9% for both rice cultivars relative to the multiple-broadcast treatment. The activities of glutamine synthetase and nitrate reductase were increased at both panicle-initiation and heading stages in both rice cultivars following one-time deep-placement fertilization treatment. Larger leaf area index at heading stage and more favorable root morphological traits expressed as larger total root length, mean root diameter, and total root volume per hill were also observed. One-time deep-placement fertilization could be an effective strategy for increasing grain yield and nitrogen use efficiency and lowering greenhouse-gas emissions under mechanical direct-seeded cropping systems.
