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Passive earth pressure of narrow backfill considering seismic-unsaturated seepage multi-field coupling effect 被引量:1
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作者 WANG Ze-yue LIN Hang 《Journal of Central South University》 2025年第4期1447-1467,共21页
Narrow backfill earth pressure estimation is applied to study the stability of supporting structures in the vicinity of existing buildings.Previous narrow backfill earth pressure studies have neglected seismic-unsatur... Narrow backfill earth pressure estimation is applied to study the stability of supporting structures in the vicinity of existing buildings.Previous narrow backfill earth pressure studies have neglected seismic-unsaturated seepage multi-field coupling,resulting in inaccurate estimates.To address these deficiencies,this paper proposed a calculation method for seismic passive earth pressure in unsaturated narrow backfill,based on inclined thin-layer units.It considers the interlayer shear stress,arching effect,and the multi-field coupling of seismic-unsaturated seepage.Additionally,this paper includes a parametric sensitivity analysis.The outcomes indicate that the earthquake passive ground pressure of unsaturated narrow backfill can be reduced by increasing the aspect ratio,seismic acceleration coefficient,and unsaturation parameterα.It can also be reduced by decreasing the effective interior friction angle,soil cohesion,wallearth friction angle,and vertical discharge.Furthermore,for any width soil,lowering the elevation of the action point of passive thrust can be attained by raising the effective interior friction angle,wall-earth friction angle,and unsaturation parameterα.Reducing soil cohesion,seismic acceleration coefficient,and vertical discharge can also lower the height of the application point of passive thrust. 展开更多
关键词 passive earth pressure unsaturated steady seepage arching effect narrow backfill EARTHQUAKE
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Temperature effects on strain distribution of reduced-activation ferritic/martensitic steel during tensile tests
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作者 Shang-Ming Chen Cheng-Jun Zhu +6 位作者 Yi-Fan Shi Lei Peng Jing-Yi Shi Yong-Jie Sun Ye-Shang Hu Yi-Fei Liu Zhen-Yu Wei 《Nuclear Science and Techniques》 2025年第6期109-122,共14页
The reduced-activation ferritic/martensitic(RAFM)steel CLF-1 has been designed as a candidate structural material for nuclear fusion energy reactors.For engineering mechanical design,the effects of temperature on the ... The reduced-activation ferritic/martensitic(RAFM)steel CLF-1 has been designed as a candidate structural material for nuclear fusion energy reactors.For engineering mechanical design,the effects of temperature on the strain distribution of CLF-1 steel during uniaxial tensile tests were explored within the temperature range from room temperature to 650°C using uniaxial tensile tests combined with in situ digital image correlation analysis.Strain-concentrated regions alternately distributed±45°along the tensile direction could be attributed to the shear stress having the maximum value at±45°along the tensile direction and the coordinated deformation of the microstructure.The total strain distribution changed from a normal distribution to a lognormal distribution with increasing deformation owing to the competition between the elastic and plastic strains at all test temperatures.Strain localization has a strong relationship with temperature at the same engineering strain because of the temperature effects on dynamic strain aging(DSA).The stronger the DSA effect,the stronger the strain localization.With increasing temperature,the stronger the strain localization at the same strain,the weaker the plasticity,that is,DSA-induced embrittlement,and the slower the strength decline,that is,DSA-induced hardening. 展开更多
关键词 RAFM steel Tensile test Strain distribution Temperature effect
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Effects of Planting Density on Yield of Oilseed Rape(Brassica napus L.)
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作者 Zhiqi YANG Yankun WANG 《Asian Agricultural Research》 2025年第8期16-26,共11页
The rapeseed,as the second oilseed crop in China,is an important source of edible oil.Reasonable planting density can improve rapeseed production efficiency,and indirectly increase farmers'the production enthusias... The rapeseed,as the second oilseed crop in China,is an important source of edible oil.Reasonable planting density can improve rapeseed production efficiency,and indirectly increase farmers'the production enthusiasm of planting rapeseed.To gain a more comprehensive understanding of the study on effect of rapeseed yield to planting density,this article reviews the effect on planting density to yield in rapeseed,including the influences of the interaction between cultivation factors(variety,sowing period,and fertilization),the impact of plant density to lodging resistance and growth and development(biological characteristics,agronomic characteristics,yield traits,and quality tracts),and planting density and the relationship between light and planting density,are reviewed.The lodging resistance of oilseed rape and population yield of different rape varieties can be improved by choosing the appropriate sowing date and fertilizer application,and give full play to the rational utilization of resources and the maximization of benefits.The oilseed rape can make rational use of light and nutrients,which is conducive to dry matter accumulation and yield improvement,with proper planting density.This review will provide a theoretical basis and practical support for rapeseed planting,management,and mechanized production. 展开更多
关键词 RAPEseeD PLANTING DENSITY YIELD effect
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Exploring the Effectiveness of a Rapid Diagnostic Kit for Identifying Snake Venom Types in Blood Tests
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作者 Linfeng Zheng Ming Liu +1 位作者 Ying Gao Biao Wu 《Journal of Clinical and Nursing Research》 2025年第4期110-115,共6页
Objective:To develop a rapid diagnostic kit for identifying snake venom types,aimed at providing a basis for clinical diagnosis and laying a foundation for early treatment through quick blood testing of injured patien... Objective:To develop a rapid diagnostic kit for identifying snake venom types,aimed at providing a basis for clinical diagnosis and laying a foundation for early treatment through quick blood testing of injured patients.Methods:Anti-snake venom immunoglobulin(IgG)was prepared,biotinylated specific IgG was screened,detection enzyme-labeled strips were produced,and rapid identification of snakebites was performed.Pre-experimental verification was conducted to establish standard curves and confirm specificity.The kit was tested on clinical samples and the results were analyzed.Repeatability and stability were evaluated through multiple repeated tests and experiments under different storage conditions.Finally,sensitivity and specificity were calculated,receiver operating characteristic curves(ROC curves)were drawn,and statistical analysis software was used for data analysis to ensure the reliability and effectiveness of the kit.Results:The test showed high sensitivity and specificity.Conclusion:The rapid diagnostic kit for identifying snake venom types in blood tests demonstrates high reliability and effectiveness in clinical diagnosis. 展开更多
关键词 Blood test Snake venom types Rapid diagnostic kit
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Effects of weak interlayers on seismic performance of bedding slopes based on shaking table tests
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作者 Hailong Yang Xiangjun Pei +2 位作者 Shenghua Cui Zhihao He Jin Lei 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第10期6517-6529,共13页
Weak interlayers play a crucial role in the seismic performance of bedding slopes;however,the effects of structural surface development within these layers remain underexplored.This study presents two scaled models of... Weak interlayers play a crucial role in the seismic performance of bedding slopes;however,the effects of structural surface development within these layers remain underexplored.This study presents two scaled models of bedding slopes,each with different weak interlayers:one with a homogeneous weak layer and another with discontinuous interfaces.Shaking table tests were conducted to compare their seismic performance.The results show that the peak ground acceleration(PGA)values above the weak interlayer in model A were significantly higher than those in model B,with the differences increasing as the input wave amplitude increased.The peak earth pressure(PEP)values at the tensile failure boundary at the rear edge of model A were also higher,whereas those within the weak layer at the toe of model A were lower than those in model B.Deformation analysis revealed that the maximum principal strain in model A initially appeared at the upper part of the tensile failure boundary,while the maximum shear strain was concentrated near the rear edge within the weak layer.In contrast,model B exhibited the opposite strain distribution.These findings provide insight into the impact of weak interlayers on the dynamic response and deformation of bedding slopes,highlighting the importance of considering this factor in seismic landslide investigations and failure mode predictions. 展开更多
关键词 Dynamic response Seismic deformation Bedding slopes Weak interlayer Shaking table test
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An enhanced numerical model for considering coupled strainsoftening and seepage effects on rock masses surrounding a submarine tunnel
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作者 Lan Cui Wenyu Yang +4 位作者 Qian Sheng Junjie Zheng Wengang Zhang Kai Guan Fei Song 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第3期1445-1458,共14页
The seepage of groundwater and the strain-softening of rock mass in a submarine tunnel expand the plastic region of rock,thereby affecting its overall stability.It is therefore essential to study the stress and strain... The seepage of groundwater and the strain-softening of rock mass in a submarine tunnel expand the plastic region of rock,thereby affecting its overall stability.It is therefore essential to study the stress and strain fields in the rocks surrounding the submarine tunnel by considering the coupled effect of strainsoftening and seepage.However,the evolution equation for the hydro-mechanical parameters in the existing fully coupled solution is a uniform equation that is unable to reproduce the characteristics of rock mass in practice.In this study,an updated numerical procedure for the submarine tunnel is derived by coupling strain-softening and seepage effect based on the experimental results.According to the hydro-mechanical coupling theory,the hydro-mechanical parameters such as elastic modulus,Poisson's ratio,Biot's coefficient and permeability coefficient of rocks are characterized by the fitting equations derived from the experimental data.Then,the updated numerical procedure is deduced with the governing equations,boundary conditions,seepage equations and fitting equations.The updated numerical procedure is verified accurately compared with the previous analytical solution.By utilizing the updated numerical procedure,the characteristics of stress field and the influences of initial pore water pressure,Biot's coefficient,and permeability coefficient on the stress,displacement and water-inflow of the surrounding rocks are discussed.Regardless of the variations in hydro-mechanical parameters,the stress distribution has a similar trend.The initial permeability coefficient exerts the most significant influence on the stress field.With the increases in initial pore water pressure and Biot's coefficient,the plastic region expands,and the water-inflow and displacement increase accordingly.Given the fact that the stability of the tunnel is more sensitive to the seepage force controlled by the hydraulic parameters,it is suggested to dewater the ground above the submarine tunnel to control the initial pore water pressure. 展开更多
关键词 seepage force STRAIN-SOFTENING Submarine tunnel Numerical procedure Coupling effect
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Effects of confinedaquifer on water-sand gushing disasters in soft soil
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作者 Liangjin Li Yafei Qiao +1 位作者 Jinchun Chai Wenqi Ding 《Journal of Rock Mechanics and Geotechnical Engineering》 2026年第2期1126-1137,共12页
Water-sand gushing(WSG)disasters in confinedaquifers pose significantchallenges to the utilization of deep underground spaces in soft soil areas.Since few studies have considered the impact of confined aquifer thickne... Water-sand gushing(WSG)disasters in confinedaquifers pose significantchallenges to the utilization of deep underground spaces in soft soil areas.Since few studies have considered the impact of confined aquifer thickness and confinedwater pressure on WSG disasters,a novel visual model test system was developed to investigate the influencingcharacteristics and mechanisms of the two aforementioned factors.The test results showed that the WSG process in clay aquiclude-confinedaquifer composite strata exhibits two prominent stages.First,the sand loss zone expands vertically in an ellipsoid shape.Then,it expands horizontally once the ellipsoid reaches the boundary of the clay layer.The sand loss continues until the overlying clay sinks to the bottom to clog the gushing crack,creating a large sinkhole at the surface.Increasing the confinedaquifer thickness can increase the vertical expansion of the ellipsoid and delay the clay-clogging effects,thereby considerably increasing the severity of sand loss,stratum deformation,and surface settlement.An increase in the confinedwater pressure markedly increases the hydraulic gradient along the seepage path,which contributes to increasing the gushing rates of water and sand.As a result,substantial sand loss occurs before the clay clogs the gushing crack,inducing more cracks and deeper sinkholes at the surface.All the aforementioned results provide insights into the effects of confinedaquifer on WSG disasters in clay aquiclude-confinedaquifer composite strata. 展开更多
关键词 Water-sand gushing(WSG)disasters Confinedaquifer thickness Confinedwater pressure Beam-bearing mechanism Clay-clogging effects Model test
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Effects of non-plastic silt and soil aging on re-liquefaction resistance of sandy soils
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作者 Tadao Enomoto 《Journal of Rock Mechanics and Geotechnical Engineering》 2026年第2期1601-1620,共20页
To investigate the influencesof non-plastic silt and soil aging on the re-liquefaction resistance of sands,a series of undrained triaxial tests was performed on sand-silt mixtures with finescontent ranging from 0%to 1... To investigate the influencesof non-plastic silt and soil aging on the re-liquefaction resistance of sands,a series of undrained triaxial tests was performed on sand-silt mixtures with finescontent ranging from 0%to 100%,as well as on undisturbed and reconstituted non-plastic sandy soils retrieved from earth structures with a history of earthquake-induced damage.The specimens on sand-silt mixtures were produced under an initial degree of compaction of 95%.In these tests,liquefaction histories were applied three times to a single specimen under the same cyclic stress ratio after the respective consolidation stages with the measurements of the shear wave velocities.The following conclusions can be obtained from the test results:(1)The liquefaction resistance obtained in the firstto third cyclicloading stages decreased initially with increasing finescontent up to about 45%,while it increased afterward.Therefore,the susceptibility of sands containing a relatively large amount of non-plastic silt to reliquefaction may be more significantthan that of clean sands;(2)The liquefaction resistance and the shear wave velocity decreased significantlyduring the second cyclic-loading stage and after the second consolidation,respectively,despite an increase in the specimen density caused by the first liquefaction history,while they increased in the third stage.The possible reason for this change would be the disturbance of soil structures due to liquefaction,which may be partially evaluated by the volumetric strain during the respective consolidation stages,and the stress-induced anisotropy formed in the previous liquefaction stage;and(3)The liquefaction resistance and the shear wave velocity of the undisturbed specimens,which were measured in the firstto third stages,were larger than those of the reconstituted ones due to the aging effects,respectively.That is,the aging effects may not necessarily be eliminated by the subsequent liquefaction history and may remain partially in some cases. 展开更多
关键词 Multiple liquefaction Non-plastic silt Undisturbed non-plastic sandy soil Aging effect Triaxial liquefaction test Shear wave velocity
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Amino‑modified F‑containing silica slag for the construction of multi‑functional interlayer and the inhibitory effect on the polysulfide shuttle effect in lithium‑sulfur batteries
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作者 LIAO Yuxin SHEN Xianheng +4 位作者 CHEN Li TIAN Yujia LUO Zhihong CHEN Xiaoli SHAO Jiaojing 《无机化学学报》 北大核心 2026年第2期375-386,共12页
Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms lig... Herein,3‑aminopropyltriethoxysilane(APTES)was used to modify F‑containing silica slag(SS)by simple grafting and served as a multifunctional barrier layer.The amino group(—NH2)in the amino‑modified SS(NH2‑SS)forms ligand bonds or hydrogen bonds with sulfur ions in lithium polysulfides(LiPSs),thus inhibiting the shuttle effect.Electrochemical analyses demonstrated that lithium‑sulfur(Li‑S)batteries employing the NH2‑SS interlayer exhibited discharge specific capacities of 1048 and 789 mAh·g^(-1) at 0.2C and 2C,respectively,and even at 4C,the initial discharge specific capacity remained at 590 mAh·g^(-1),outperforming the Li‑S battery with unmodified SS as the interlayer. 展开更多
关键词 SILICA INTERLAYER shuttle effect lithium‑sulfur batteries
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Fracture Behaviours and Notch Effects of 2D Carbon/Carbon Composites Performing by Bending and Tensile Tests
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作者 CAO Dake LIU Xiaogen +3 位作者 TIAN Yuan LüKuilin YANG Haotian WAN Detian 《Journal of Wuhan University of Technology(Materials Science)》 2025年第5期1198-1205,共8页
The fracture behaviours and notch effects of single-edge-notched(SEN)and double-edge-notched(DEN)2D carbon fibre reinforced carbon matrix composites(C/Cs)were discussed and compared.The fracture behaviours of DEN and ... The fracture behaviours and notch effects of single-edge-notched(SEN)and double-edge-notched(DEN)2D carbon fibre reinforced carbon matrix composites(C/Cs)were discussed and compared.The fracture behaviours of DEN and SEN were performed by tensile and bending load-displacement relationships,and the effects of notch depth on notch sensitivity were determined by DEN specimens.The results from mechanical tests indicated that the SEN exhibited a brittle behaviour with linear elasticity,while the DEN exhibited a ductile behaviour with nonlinearity.It was also found that increasing notch depth and decreasing ligament width can lead to a higher ultimate tensile strength of DEN.On the other hand,the digital image correlation(DIC)method and acoustic emission(AE)system were also applied during the mechanical tests to study the local mechanical characteristics of shear damage,strain concentration and fracture behaviour of 2D C/Cs.The results revealed the mechanisms of notch insensitivity and explained the differences in fracture behaviours between SEN and DEN. 展开更多
关键词 C/C composites notch effects mechanical properties digital image correlation acoustic emission
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In-Flight Heating Process of Cerium Oxide Powders in Radio Frequency Thermal Plasma Considering Thermal Resistance Effect
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作者 Su Yi Liu Ruizhe +3 位作者 Ahmad Hilal Zhao Peng Jin Xingyue Zhu Hailong 《稀有金属材料与工程》 北大核心 2026年第3期581-594,共14页
The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF... The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF)argon plasma,and the temperatures were measured using a DPV-2000 monitor.A model combining the electromagnetism,thermal flow,and heat transfer characteristics of powder during in-flight heating in argon plasma was proposed.The melting processes of CeO_(2)powders of different diameters,with and without thermal resistance effect,were investigated.Results show that the heating process of CeO_(2)powder particles consists of three main stages,one of which is relevant to a dimensionless parameter known as the Biot number.When the Biot value≥0.1,thermal resistance increases significantly,especially for the larger powders.The predicted temperature of the particles at the outlet(1800–2880 K)is in good agreement with the experimental result. 展开更多
关键词 RF thermal plasma thermal resistance effect heating process Biot number
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Effects of manufacturing agglomeration on PM_(2.5) and spatial spillover in prefecture-level cities in China
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作者 Dan Wang Hongxiao Zhao +1 位作者 Yun Wang Yu Cheng 《Chinese Journal of Population,Resources and Environment》 2026年第1期67-76,共10页
Agglomeration supports the high-quality development of the manufacturing industry,and its associated resource and environmental effects play a crucial role in driving green economic development.Based on data from pref... Agglomeration supports the high-quality development of the manufacturing industry,and its associated resource and environmental effects play a crucial role in driving green economic development.Based on data from prefecture-level cities in China from 2005 to 2019,this study employs the inverse distance weighting method,the bivariate local indicator of spatial association model,the spatial Durbin model,and other techniques to explore the relationship between manufacturing agglomeration and PM_(2.5)concentrations,and to assess the impact of its manufacturing agglomeration.Four correlation patterns are observed:high-high,low-low,high-low,and low-high.Among these,high-high and low-low patterns dominate in terms of number of cities.These correlation patterns demonstrate strong temporal stability,with a clear“Matthew effect”.The effect of manufacturing agglomeration on PM_(2.5)levels is significantly negative and helps reduce concentrations regionally,indicating the need to further enhance agglomeration levels regionally.However,it can increase PM_(2.5)levels in neighboring areas due to a siphon effect,and the impact of varies across regions.Compared with levels in 2005-2013,the significance of the relationship between manufacturing agglomeration and PM_(2.5)weakened in the 2013-2019 period.Accordingly,this study proposes countermeasures and policy recommendations aimed at strengthening regional collaborative governance and inspiring differentiated agglomeration strategies to support sustainable economic development in China. 展开更多
关键词 Manufacturing agglomeration PM_(2.5) Impact effect Spatial spillover effect
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Silver chloride/chitosan‑based chloramine nanohybrid with excellent antibacterial activity:Design and structure characterization as well as Ag^(+)‑Cl^(-)synergistic antibacterial effect
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作者 ZHANG Xinzhe XU Jiarong +4 位作者 GAO Mochou LIU Yage ZHAO Yanbao CUI Jingzeng ZOU Xueyan 《无机化学学报》 北大核心 2026年第2期428-438,共11页
Chitosan(CTS)was grafted onto the surface of amino‑functionalized silver chloride silicon dioxide(AgCl@SiO_(2)‑NH_(2))cores to obtain AgCl@SiO_(2)/CTS hybrid nanoparticles.The as‑obtained AgCl@SiO_(2)/CTS nanoparticle... Chitosan(CTS)was grafted onto the surface of amino‑functionalized silver chloride silicon dioxide(AgCl@SiO_(2)‑NH_(2))cores to obtain AgCl@SiO_(2)/CTS hybrid nanoparticles.The as‑obtained AgCl@SiO_(2)/CTS nanoparticles were chlorinated by NaClO solution to get AgCl@SiO_(2)/CTS‑based chloramine nano‑hybrid materials,denoted as AgCl@SiO_(2)/CTS‑Cl.A transmission electron microscope was used to observe the morphology of the as‑prepared samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.At the same time,an X‑ray diffractometer and an infrared spectroscope were utilized to characterize their crystal and chemical structures.Besides,ζpotentials were measured to elucidate the surface modification of AgCl nanoparticles by—NH_(2),the antibacterial mechanism of AgCl@SiO_(2)/CTS‑Cl was investigated by scanning electron microscopy,and Escherichia coli(E.coli)and Staphylococcus aureus(S.aureus)were used as the to‑be‑tested strains to evaluate the antimicrobial activity of samples AgCl@SiO_(2)/CTS and AgCl@SiO_(2)/CTS‑Cl.Findings demonstrate that sample AgCl@SiO_(2)/CTS exhibits a chain‑like structure ascribed to the interaction between—NH_(2),and each AgCl@SiO_(2)/CTS hybrid nanoparticle contains several AgCl cores.In the meantime,sample AgCl@SiO_(2)/CTS‑Cl exhibits excellent antibacterial activity against E.coli and S.aureus,which is attributed to the synergistic antibacterial effect of Ag^(+)and Cl^(-).Sample AgCl@SiO_(2)/CTS‑Cl with a dosage of 640.00μg·mL^(-1) could completely kill the two kinds of tested bacteria in 12 h of incubation;it retains a high antibacterial efficiency even after 10 cycles of antibacterial tests. 展开更多
关键词 AgCl@SiO_(2)/CTS‑Cl hybrid nanoparticle synergistic effect antibacterial activity
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Trichoderma gamsii strain TC959 with comprehensive functions to effectively reduce seedling damping-off and promote growth of pepper by direct and indirect action mechanisms
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作者 Hengxu Wang Hao Hu +2 位作者 Tianyou Zhao Zhaoqing Zeng Wenying Zhuang 《Journal of Integrative Agriculture》 2025年第10期3926-3940,共15页
Several Trichoderma species serve as biocontrol agents in agriculture through their phytopathogen growth inhibition capabilities.However,the antagonistic mechanism of certain strains primarily operates through direct ... Several Trichoderma species serve as biocontrol agents in agriculture through their phytopathogen growth inhibition capabilities.However,the antagonistic mechanism of certain strains primarily operates through direct action.This study aims to explore an effective strain with comprehensive capabilities and elucidate its practical viability and action mechanism.Trichoderma gamsii strain TC959,exhibiting robust antagonistic and plant growth-promoting properties,was identified.The strain directly inhibits plant pathogen through the production of secondary metabolites,siderophores,and chitinase/xylanase,while promotes plant growth via indole-3-acetic acid/gibberellin release.Additionally,the strain activates induced systemic resistance by enhancing the chlorophyll a/b ratio and jasmonic acid content in pepper seedlings through root colonization,leading to elevated defense-related gene expression,antioxidant enzyme activity,and indole-3-acetic acid/gibberellin production.These mechanisms collectively enhance disease resistance and promote plant growth.Moreover,TC959 demonstrates superior resistance to oxidation and chemical fungicides,facilitating strain viability maintenance and ensuring healthy pepper seedling development.The study concludes that strain TC959 exhibits significant biocontrol potential and comprehensive functions against pepper damping-off disease,warranting further practical applications. 展开更多
关键词 biocontrol potential disease resistance of plant induced systemic resistance inhabitation effects to phytopathogens sensitivity to chemical fungicides TRICHODERMA
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Electronically Conductive Metal−Organic Framework With Photoelectric and Photothermal Effect as a Stable Cathode for High-Temperature Photo-Assisted Zn/Sn-Air Battery
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作者 Jiangchang Chen Chuntao Yang +2 位作者 Yao Dong Ya Han Yingjian 《Carbon Energy》 2026年第1期105-114,共10页
Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electro... Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis. 展开更多
关键词 electronically conductive MOFs high temperatures photo-assisted Zn/Sn-air batteries photoelectric effects photothermal effects
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Understanding the Doping Effect and Electrolyte Effect in Electrocatalytic Oxidation of Glycerol With Ligand-Protected Silver Nanoclusters Special Collection:Functional Metal Clusters
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作者 Dan Yang Mingxin Wang +7 位作者 Yiwen Zhao Zhaotong Yuan Mengjie Wu Chunmei Zhou Yihu Dai Xiaoyue Wan Yanhui Yang Yan Zhu 《Aggregate》 2026年第2期228-240,共13页
The efficient electrocatalytic oxidation of glycerol(GLY)is one of the most promising routes for the valorization of GLY.Doping has emerged as a powerful strategy to tailor the electrocatalytic performance of silver n... The efficient electrocatalytic oxidation of glycerol(GLY)is one of the most promising routes for the valorization of GLY.Doping has emerged as a powerful strategy to tailor the electrocatalytic performance of silver nanoclusters(Ag NCs),yet the effects of doping mode(surface vs.core)and the interface environment(e.g.,electrolyte concentration)on the electrocatalytic performance for Ag NCs toward GLY oxidation remain understood.In this work,surface-doped Ag_(4)M_(2)(SR)_(8) and core-doped Ag_(24)M(SR)_(18)(M=Ni,Pd,Pt;SR=SPhMe_(2))NCs were synthesized for electrocatalytic GLY oxidation.The results revealed a strong dependence of selectivity on doping mode and electrolyte concentration:under low KOH concentration,Pd-and Pt-doped Ag_(4)M_(2) NCs exhibited 100%selectivity toward oxalic acid(OA),whereas Pd-and Pt-doped Ag_(24)M NCs delivered>95%selectivity for formic acid(FA).In contrast,under high KOH concentration,Pd-and Pt-doped Ag_(4)M_(2) NCs gave rise to>80%FA,while Pd-and Pt-doped Ag_(24)M NCs produced>45%FA.Mechanism studies indicated that Ni doping predominantly enhanced catalytic activity via lowering the activation barrier of the initial reaction step(GLY→glyceraldehyde),whereas Pd and Pt doping modulated selectivity through reducing the energy barrier of the selective branch step(glyceric acid→OA,OA→FA).High KOH concentration promoted the oxidation by increasing the electrochemical active surface area and facilitating electron transfer of Ag NCs.This study provides clear guidance for designing high-performance Ag-based electrocatalysts for biomass valorization. 展开更多
关键词 atomically precise metal nanoclusters doping effect electrocatalytic oxidation of glycerol electrolyte effect silver nanocluster
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Research on Mild and Effective Sunscreen Synergistic Ingredients
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作者 Ye Xiulin Wu Bizhi +6 位作者 Huang Min Luo Shaoqiang Liu Jinghua Li Qiuxi Zeng Yunyun Huang Runmei Zhou Wei 《China Detergent & Cosmetics》 2026年第1期61-65,共5页
The UV-2600 ultraviolet(UV)spectrophotometer and the UV sunscreen index analyzer SolarLight Model 601 were used to test the UV absorption capacity and the UV damage alleviating effect of commonly used raw materials,an... The UV-2600 ultraviolet(UV)spectrophotometer and the UV sunscreen index analyzer SolarLight Model 601 were used to test the UV absorption capacity and the UV damage alleviating effect of commonly used raw materials,and the Hen’s Egg Test-Chorioallantoic Membrane were also processed to assess the mildness.As a result,bisabolol,pongamia pinnata seed extract,pterocarpus marsupium bark extract and other materials were screened as the effective and gentle sunscreen synergistic ingredients. 展开更多
关键词 ultraviolet damage sun protection synergistic effect
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Chemical composition and pharmacological effects of the Forsythia suspensa
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作者 Jiayuan Wang Zixuan Che +3 位作者 Yuzheng Xiang Meng Zhang Ying Li Yu Chen 《Asian Journal of Traditional Medicines》 2026年第1期42-57,共16页
The dried fruit of Forsythia suspensa(Oleaceae),also known as Forsythia,is a traditional Chinese medicinal herb known for its heat-clearing and detoxifying properties.It is used to disperse nodules,reduce swelling,rem... The dried fruit of Forsythia suspensa(Oleaceae),also known as Forsythia,is a traditional Chinese medicinal herb known for its heat-clearing and detoxifying properties.It is used to disperse nodules,reduce swelling,remove toxins,clear heat,and alleviate wind-heat syndromes.It also has hepatoprotective,anti-inflammatory,antiviral,antibacterial,anticancer,antioxidant,antiaging,and anti-obesity effects,as well as potential therapeutic effects on Alzheimer’s disease and diabetic nephropathy.It is used to treat scrofula,mastitis,wind-heat common cold,and other ailments.The review summarizes the chemical constituents and pharmacological effects of F.suspensa,aiming to provide a scientific foundation for its future development,research,and clinical utilization. 展开更多
关键词 Forsythia suspensa pharmacological effects chemical constituents
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IN-CLASS DEMONSTRATION OF THE ZEEMAN EFFECT:FROM QUALITATIVE OBSERVATION TO QUANTITATIVE EXPERIMENTS
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作者 QIN Shaohan MA Yuhan 《物理与工程》 2026年第1期21-27,共7页
The Zeeman effect,a fundamental quantum phenomenon,demonstrates the interaction between magnetic fields and atomic systems.While precise spectroscopic measurements of this effect have advanced significantly,there rema... The Zeeman effect,a fundamental quantum phenomenon,demonstrates the interaction between magnetic fields and atomic systems.While precise spectroscopic measurements of this effect have advanced significantly,there remains a lack of simple,visually accessible demonstration for educational purposes.Here,we present a low-cost experiment that allows for direct visual observation of the Zeeman effect.Our setup involves a flame containing sodium(from table salt)placed in front of a sodium vapor lamp.When a magnetic field is applied to the flame,the shadow cast by the flame noticeably lightens,providing a clear,naked-eye demonstration of the Zeeman effect.Furthermore,we conduct two quantitative experiments using this setup,examining the effects of varying magnetic field strength and sodium concentration.This innovative approach not only enriches the experimental demonstration for teaching atomic physics at undergraduate and high school levels but also provides an open platform for students to explore the Zeeman effect through hands-on experience. 展开更多
关键词 Zeeman effect demonstration experiment CANDLE sodium vapor SHADOW
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CUDA‑based GPU‑only computation for efficient tracking simulation of single and multi‑bunch collective effects
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作者 Keon Hee Kim Eun‑San Kim 《Nuclear Science and Techniques》 2026年第1期61-79,共19页
Beam-tracking simulations have been extensively utilized in the study of collective beam instabilities in circular accelerators.Traditionally,many simulation codes have relied on central processing unit(CPU)-based met... Beam-tracking simulations have been extensively utilized in the study of collective beam instabilities in circular accelerators.Traditionally,many simulation codes have relied on central processing unit(CPU)-based methods,tracking on a single CPU core,or parallelizing the computation across multiple cores via the message passing interface(MPI).Although these approaches work well for single-bunch tracking,scaling them to multiple bunches significantly increases the computational load,which often necessitates the use of a dedicated multi-CPU cluster.To address this challenge,alternative methods leveraging General-Purpose computing on Graphics Processing Units(GPGPU)have been proposed,enabling tracking studies on a standalone desktop personal computer(PC).However,frequent CPU-GPU interactions,including data transfers and synchronization operations during tracking,can introduce communication overheads,potentially reducing the overall effectiveness of GPU-based computations.In this study,we propose a novel approach that eliminates this overhead by performing the entire tracking simulation process exclusively on the GPU,thereby enabling the simultaneous processing of all bunches and their macro-particles.Specifically,we introduce MBTRACK2-CUDA,a Compute Unified Device Architecture(CUDA)ported version of MBTRACK2,which facilitates efficient tracking of single-and multi-bunch collective effects by leveraging the full GPU-resident computation. 展开更多
关键词 Code development GPU computing Collective effects
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