A Storm Water Pumping Station funded by the World Bank is under construction and commissioning,of which the earthing system design is a crucial part for the electrical design.Based on IEEE and BS standards,this articl...A Storm Water Pumping Station funded by the World Bank is under construction and commissioning,of which the earthing system design is a crucial part for the electrical design.Based on IEEE and BS standards,this article fully introduces the analysis methodology and calculation of the system within the framework of the World Bank supported project.A solution of this practical case satisfied with the requirements of international standards is shown in order to bring experience and convenience for engineers who are dedicated to projects abroad.展开更多
This paper presents and tests three earthing systems (TT, TN and IT) for Micro-Grid (MG) protection against various fault types when the MG transferred to the islanding mode. The main contribution of this work is incl...This paper presents and tests three earthing systems (TT, TN and IT) for Micro-Grid (MG) protection against various fault types when the MG transferred to the islanding mode. The main contribution of this work is including the models of all micro sources which interfaced to the MG by power electronic inverters. Inverters in turns are provided with current limiters and this also included with the inverter models to exactly simulate the real situation in the MG during fault times. Results proved that the most suitable earthing system for MG protection during the islanding mode is the TN earthing system. That system leads to a suitable amount of fault current sufficient to activate over current pro-tection relays. With using TN earthing system, touch voltages at the faulted bus and all other consumer’s buses are less than the safety limited values during islanding mode. For the two others earthing systems (TT and IT), fault currents are small and nearly equal to the over load currents which make over current protection relay can not differentiate between fault currents and overload currents. All models of micro sources, earthing systems, inverters and control schemes are built using Matlab?/Simulink? environment.展开更多
This paper presents, tests and compares three earthing systems (TT, TN and IT) for Micro-Grid (MG) protection against various fault types during the connected mode. The main contribution of this work is including the ...This paper presents, tests and compares three earthing systems (TT, TN and IT) for Micro-Grid (MG) protection against various fault types during the connected mode. The main contribution of this work is including the models of all the micro sources which interfaced to the MG by power electronic inverters. Inverters in turns are provided with current limiters and this also included in the inverter models to exactly simulate the real situation in the MG during fault times. Results proved that the most suitable earthing system for MG protection during the connecting mode is the TN earthing system. That system leads to a suitable amount of fault current sufficient to activate over current protection relays. With using TN system, Touch voltages at the faulted bus and all other consumer’s buses are less than the safety limited value if current limiter is included with the transformer of the main grid which connects MG. For the two others earthing systems (TT and IT), fault current is small and nearly equal to the over load current which make over current protection relay can not differentiate between fault current and overload current. All models of micro sources, earthing systems, inverters, main grid and control schemes are built using Matlab?/Simulink? environment.展开更多
The reaction of carbon-free oxide-based(corundum,spinel,zirconia,and mullite)submerged entry nozzle(SEN)lining with rare earth inclusions and its anti-clogging effects under near working conditions were systematically...The reaction of carbon-free oxide-based(corundum,spinel,zirconia,and mullite)submerged entry nozzle(SEN)lining with rare earth inclusions and its anti-clogging effects under near working conditions were systematically studied.A variety of lining composite test methods were innovatively used to ensure the consistency of test conditions.The experimental results showed that the mullite(acidic oxide)has strong reactivity with rare earth inclusions,and the spinel(basic oxide)has stable chemical properties and weak reactivity with rare earth inclusions.Because alumina is one of the main reactants of clogging formation,corundum is not suitable for SEN lining.There are less clogs on the surface of zirconia,but it will be exsoluted and unstable.Therefore,solving the problem of zirconia exsolution will greatly strengthen its application in SEN lining.展开更多
The recovery of rare earths from industrial rare earth leaching solution is typically achieved through the ammonium carbonate precipitation method,which presents challenges in terms of prolonged production cycle and a...The recovery of rare earths from industrial rare earth leaching solution is typically achieved through the ammonium carbonate precipitation method,which presents challenges in terms of prolonged production cycle and ammonia nitrogen pollution.The present study explored the synthesis of crystalline yttrium carbonate in a sodium carbonate system,employing a conventional mother liquor derived from yttrium chloride.The growth of yttrium carbonate was explored through the lens of density functional theory(DFT)calculations,unveiling a novel perspective on its formation mechanism.The synthesized yttrium carbonate demonstrates enhanced crystallinity,with a D50value of 19.75μm achieved under reaction conditions comprising a temperature of 60℃,stirring rate of 200 r/min,feeding rate of 4 mL/min,and aging time of 30 h.The molar ratio for precipitation is set at 1.6:1.The morphology of yttrium carbonate undergoes a transition from needle-like structures to sheet-like formations,ultimately culminating in the formation of spherical aggregates.The variation in surface energy among distinct crystal planes and CO_(3)^(2-)configurations within crystal cells accounts for this phenomenon.The DFT calculations unveil a progression of growth and trans formation in yttrium carbonate,commencing from a one-dimensional configuration and culminating in a multidimensional morphology.展开更多
This study details a comprehensive approach focusing on the effective separation of light rare earth elements(REEs)via solvent extraction technique.A stock solution containing lanthanum,cerium,neodymium,praseodymium,a...This study details a comprehensive approach focusing on the effective separation of light rare earth elements(REEs)via solvent extraction technique.A stock solution containing lanthanum,cerium,neodymium,praseodymium,and samarium was prepared by dissolving their pure mixed oxide(reclaimed from spent Ni-MH batteries)in a diluted HCl solution.Key extractants,including bis(2,4,4-trimethylpentyl)phosphinic acid(Cyanex 272),Cyanex 572,trialkylphosphine oxide(Cyanex 923),and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester(PC 88A),along with tributyl phosphate(TBP)as a phase modifier,were utilized to form organic systems.The extraction behavior and separability of these systems at various pH levels as well as their extraction mechanisms were investigated.The results demonstrated a direct relationship between the extraction trend and the experimental pH value,with enhanced selectivity when TBP was added.Notably,Nd and Pr exhibited similar extraction behaviors,with minor deviations from Ce,making their separation difficult to achieve.Sm extraction followed a distinct trend,allowing for its separation from other elements at pH≤2.In contrast,La exhibited a low affinity for coordination with extractants when pH was≤3.5,facilitating the separation of other elements from La,which could then be isolated in the raffinate.Among the studied organic systems,combinations of Cyanex 572 and PC 88A with TBP demonstrated superior performance in element separation.Optimum separation factors were calculated withβ_(Ce/La)=12,βNd/La=87,β_(Pr/La)=127,andβ_(Sm/La)=3191 for the former,andβ_(Sm/Ce)=54,β_(Sm/Nd)=20,andβ_(Sm/Pr)=14 for the latter.These findings provide valuable insights for selecting extraction systems and designing experiments for the effective solvent extraction separation of light REEs from their mixture.展开更多
The Vietnamese Mekong Delta(VMD),a critical agricultural hub,faces recurrent flooding that poses substantial threats to livelihoods and productivity.Ben Tre province,with its low-lying coastal terrain,is particularly ...The Vietnamese Mekong Delta(VMD),a critical agricultural hub,faces recurrent flooding that poses substantial threats to livelihoods and productivity.Ben Tre province,with its low-lying coastal terrain,is particularly vulnerable.Effective risk management and sustainable agricultural development necessitate a thorough understanding of these flood dynamics.This study leveraged the Google Earth Engine(GEE)platform and Sentinel-1 Synthetic Aperture Radar(SAR)imagery to analyze flood inundation patterns and their impacts on diverse agricultural land uses in Ben Tre province from 2015 to 2023.The methodology involved SAR data pre-processing,Otsu thresholding for water body delineation from VH polarization data and change detection using a 2020 land use map to quantify annual flooded areas and their impact on specific agricultural categories.The total inundated area peaked in 2018 at 58,334 ha,a significant increase from 27,934 ha in 2015,before stabilizing around 42,000–44,000 ha in 2021–2023.Flooded agricultural land mirrored this trend,increasing from 18,615 ha(2015)to a peak of 39,514 ha(2018),then decreasing to 28,841 ha(2023).Notably,wet rice cultivation experienced a 37.8%increase in its flooded area over the study period,while other annual crops and perennial crops saw increases of 38.9% and 68.4%,respectively.This research demonstrates the GEE platform’s efficacy with Sentinel-1 SAR for robust,long-term flood monitoring and impact assessment,revealing escalating flood pressure on key agricultural systems and an expansion of flooding beyond traditional low-lying zones,providing crucial data for adaptive land use planning.展开更多
The health of cropland systems is directly related to the degree of food security guarantee,and the‘quantity-quality-ecology as a whole’protection is of great significance for maintaining the health of cropland syst...The health of cropland systems is directly related to the degree of food security guarantee,and the‘quantity-quality-ecology as a whole’protection is of great significance for maintaining the health of cropland systems.Taking the typical black soil region in Northeast China(TBSN)as an example,this paper combined the concept of‘quantity-quality-ecology as a whole’protection with crop-land systems health,constructed a health assessment model for cropland systems,and used Google Earth Engine to conduct a quantitat-ive analysis of the temporal and spatial evolution of cropland systems health in TBSN during 2003–2023.By coupling the geographical detector and the Multi-scale Geographically Weighted Regression(MGWR)model,the driving factors of cropland health changes were explored.The study finds that during the research period,the health status of cropland systems in TBSN showed a slight downward trend,and the distribution pattern of cropland systems health gradually shifted from‘better in the east’to‘high in the northeast and low in the southwest’.Changes in average annual sunshine duration,relative humidity,and precipitation had a significant impact on the spa-tial differentiation of cropland systems health in the early stages,and were considered as dominant factors.Meanwhile,the influence of dual dominant factors in the natural environment on cropland systems health is increasing.Furthermore,the MGWR model performed better in revealing the complex relationships between natural and social factors and changes in cropland systems health,demonstrating the significant spatial heterogeneity of the impacts of natural environment and human activities on cropland systems health.The re-search can provide scientific guidance for the sustainable development of TBSN and formulate more precise and effective cropland pro-tection policies.展开更多
Taking the Paleozoic of the Sichuan and Tarim basins in China as example,the controlling effects of the Earth system evolution and multi-spherical interactions on the formation and enrichment of marine ultra-deep petr...Taking the Paleozoic of the Sichuan and Tarim basins in China as example,the controlling effects of the Earth system evolution and multi-spherical interactions on the formation and enrichment of marine ultra-deep petroleum in China have been elaborated.By discussing the development of“source-reservoir-seal”controlled by the breakup and assembly of supercontinents and regional tectonic movements,and the mechanisms of petroleum generation and accumulation controlled by temperature-pressure system and fault conduit system,Both the South China and Tarim blocks passed through the intertropical convergence zone(ITCZ)of the low-latitude Hadley Cell twice during their drifts,and formed hydrocarbon source rocks with high quality.It is proposed that deep tectonic activities and surface climate evolution jointly controlled the types and stratigraphic positions of ultra-deep hydrocarbon source rocks,reservoirs,and seals in the Sichuan and Tarim basins,forming multiple petroleum systems in the Ediacaran-Cambrian,Cambrian-Ordovician,Cambrian-Permian and Permian-Triassic strata.The matching degree of source-reservoir-seal,the type of organic matter in source rocks,the deep thermal regime of basin,and the burial-uplift process across tectonic periods collectively control the entire process from the generation to the accumulation of oil and gas.Three types of oil and gas enrichment models are formed,including near-source accumulation in platform marginal zones,distant-source accumulation in high-energy beaches through faults,and three-dimensional accumulation in strike-slip fault zones,which ultimately result in the multi-layered natural gas enrichment in ultra-deep layers of the Sichuan Basin and co-enrichment of oil and gas in the ultra-deep layers of the Tarim Basin.展开更多
In this study,the mechanism of the reduction-diffusion reaction in a Sm-Fe binary system at low temperature was studied to investigate the possibility of synthesis of a Fe-rich TbCu_(7)-type SmFe_(x)(x>9)by the low...In this study,the mechanism of the reduction-diffusion reaction in a Sm-Fe binary system at low temperature was studied to investigate the possibility of synthesis of a Fe-rich TbCu_(7)-type SmFe_(x)(x>9)by the low-temperature diffusion-reduction(LTRD)process using LiCl-KCl eutectic molten salts.Firstly,the Sm-Fe phase transformation depending on the Sm-Fe composition,the LTRD temperature,and time was investigated,and it is found that the obtained metastable phase is only TbCu_(7)-type SmFe_(~8.5),which is not a Fe-rich phase.This Fe content does not change even after an expended LTRD process,and the metastable TbCu_(7)-type SmFe_(~8.5)tends to transform to the stable Sm_(2)Fe_(17)phase.In addition,it is found that the Sm-Fe phase starts to synthesize from the Sm-rich phase in the order of SmFe_(2),SmFe_(3),and SmFe_(8.5)as the LTRD temperature increases(when the time was 10 h)or the LTRD time increases(when the temperature was 550℃).Core-shell-like particles are observed in the case of a short LTRD time,and the core and the shell are Fe and the Sm-rich Sm-Fe phase,respectively,indicating that the Sm-rich phase begins to produce on the surface of the Fe particles.It is difficult to synthesize a Fe-rich TbCu_(7)-type SmFe_(x)(x>9)phase with the Sm-Fe binary system,suggesting that a different approach,such as addition of other elements,will be necessary.展开更多
This work reports the synthesis,characterization,and energy focused applications of the novel lanthanides co-doped tantalum pentoxide hetero-system(Sm^(3+)-Eu^(3+)-Tm^(3+):Ta_(2)O_(5)).Ln^(3+)-doped Ta_(2)O_(5) expres...This work reports the synthesis,characterization,and energy focused applications of the novel lanthanides co-doped tantalum pentoxide hetero-system(Sm^(3+)-Eu^(3+)-Tm^(3+):Ta_(2)O_(5)).Ln^(3+)-doped Ta_(2)O_(5) express excellent opto-electronic features reflected by the narrow band gap energy of 3.87 eV.Different vibrations confirm the presence of Ta-O-Ta and Ta-O bonds.The synthesized system possesses orthorhombic geometry with 59.46 nm particle size.With the smoother and compact morphology,the synthesized material succeeds in augmenting the performance of different systems aimed at energy applications.Fully ambient perovskite solar cell device fabricated with the Ln^(3+)-doped Ta_(2)O_(5) as an electron transport layer excels in achieving an efficiency and fill factor of 14.17% and 76% under artificial sun.This device was marked by the negligible hysteresis behavior showing profound photovoltaic performance.The electrochemical activity of the Ln^(3+)-doped Ta_(2)O_(5) decorated electrode was evaluated for electrical charge storage potential with pseudocapacitive behavior,With the highest specific capacitance of 355.39 F/g and quicker ionic diffusion rate,the designed electrode excels conventionally used materials.Electro-catalysis of water with Ln^(3+)-doped Ta_(2)O_(5) material indicates its capacity for H_(2) production with the lowest overpotential and Tafel slope values of 148 and 121.2 mV/dec,while the O_(2) generation is comparatively lower.With the stable electrochemical output,this rare earth modified material has the potential to replace conventionally used environmentally perilous and costly materials.展开更多
The UHVDC transmission line transports large-capacity power, and its safety operation has very important rule on the safe operation of grid. Currently, in the DC transmission system, the earthing electrode line has th...The UHVDC transmission line transports large-capacity power, and its safety operation has very important rule on the safe operation of grid. Currently, in the DC transmission system, the earthing electrode line has the functions of ground potential fixing and bipolar imbalance current circulation during the operation of bipolar balance. Therefore the monitoring to the earthing electrode line operation is very essential. This article firstly introduced the current situation of the research on the earthing electrode line fault location method, then built the relevant PSCAD/EMTDC model for simulation verification of the current using Time Domain Reflectometry for the UHVDC earthing electrode line, and at last analyzed the reasons for the formation of the blind monitoring zones.展开更多
The rail weighbridge system of a railway freight station is introduced firstly, and then the earthing method for protection of the rail weighbridge system against lightning based on YLG-60 equipotential bonding surge ...The rail weighbridge system of a railway freight station is introduced firstly, and then the earthing method for protection of the rail weighbridge system against lightning based on YLG-60 equipotential bonding surge protection device is shown.展开更多
Plasma discharge stability is an important problem in atmosphere-breathing electric propulsion system when maintaining long-term missions at ultra-low earth orbit.This paper designed an inductively coupled plasma sour...Plasma discharge stability is an important problem in atmosphere-breathing electric propulsion system when maintaining long-term missions at ultra-low earth orbit.This paper designed an inductively coupled plasma source to imitate the ionization section.The effect of inflow rate and Radio Frequency(RF)power on the plasma discharge mode transition is experimentally studied.A discharge mode detection method is proposed,which determines the discharge mode by identifying the morphology of the plasma core.By using the method,the discharge mode transition is quantified and a control model based on the parameter sensitivity is constructed.To verify the method,the spectra are measured and the electron temperature spatial distribution is calculated.And the method has been proven effective.The results show that the inductively coupled discharge contains capacitive components affected by the mass flow rate and the radio frequency power.The plasma characteristics can be maintained stably by controlling the radio frequency power when the mass flow rate randomly changes in a certain range.It is demonstrated that the application of detection method effectively identifies the discharge mode,which is a promising active control method for the plasma discharge mode.展开更多
An analysis of a 68-year monthly hindcast output from an eddy-resolving ocean general circulation model reveals the relationship between the interannual variability of the Kerama Gap transport(KGT)and the Kuroshio/Ryu...An analysis of a 68-year monthly hindcast output from an eddy-resolving ocean general circulation model reveals the relationship between the interannual variability of the Kerama Gap transport(KGT)and the Kuroshio/Ryukyu Current system.The study found a significant difference in the interannual variability of the upstream and downstream transports of the East China Sea-(ECS-)Kuroshio and the Ryukyu Current.The interannual variability of the KGT was found to be of paramount importance in causing the differences between the upstream and downstream ECS-Kuroshio.Additionally,it contributed approximately 37%to the variability of the Ryukyu Current.The interannual variability of the KGT was well described by a two-layer rotating hydraulic theory.It was dominated by its subsurface-intensified flow core,and the upper layer transport made a weaker negative contribution to the total KGT.The subsurface flow core was found to be mainly driven by the subsurface pressure head across the Kerama Gap,and the pressure head was further dominated by the subsurface density anomalies on the Pacific side.These density anomalies could be traced back to the eastern open ocean,and their propagation speed was estimated to be about 7.4 km/d,which is consistent with the speed of the local first-order baroclinic Rossby wave.When the negative(positive)density anomaly signal reached the southern region of the Kerama Gap,it triggered the increase(decrease)of the KGT towards the Pacific side and the formation of an anticyclonic(cyclonic)vortex by baroclinic adjustment.Meanwhile,there is an increase(decrease)in the upstream transport of the entire Kuroshio/Ryukyu Current system and an offshore flow that decreases(increases)the downstream Ryukyu Current.展开更多
Desalination is emerging as a promising alternative among various technologies to resolve water shortage. However, desalination requires a sufficient energy and cooling device and therefore poses limitations for its i...Desalination is emerging as a promising alternative among various technologies to resolve water shortage. However, desalination requires a sufficient energy and cooling device and therefore poses limitations for its installation and application. In particular, many countries suffering water deficits are economically underdeveloped and cannot afford the technology. As this technology, which changes seawater into freshwater, has little environmental impact, developed countries will need to assist less developed countries to introduce this technology as a humanitarian effort. This will help reduce the number of countries that have experienced difficulty with development.展开更多
This article details how AN Zhisheng and his colleagues,through decades of dedicated research,began with the study of loess in China and integrated it with climatic and environmental researches.AN and his team develop...This article details how AN Zhisheng and his colleagues,through decades of dedicated research,began with the study of loess in China and integrated it with climatic and environmental researches.AN and his team developed a novel research approach to identifying the dynamics of changes of natural environments,including loess environment in East Asia.Their work has not only highlighted the global significance of Chinese loess as a record for global climate change,but also led to the formulation of the monsoon control theory regarding environmental changes in East Asia,as well as insights into Asian and global monsoon dynamics.The paradigm shift from a singular discipline of Quaternary science into a comprehensive Earth system science has happened.Their contributions have been instrumental in promoting sustainable development of the society in the Chinese Loess Plateau and western China.展开更多
文摘A Storm Water Pumping Station funded by the World Bank is under construction and commissioning,of which the earthing system design is a crucial part for the electrical design.Based on IEEE and BS standards,this article fully introduces the analysis methodology and calculation of the system within the framework of the World Bank supported project.A solution of this practical case satisfied with the requirements of international standards is shown in order to bring experience and convenience for engineers who are dedicated to projects abroad.
文摘This paper presents and tests three earthing systems (TT, TN and IT) for Micro-Grid (MG) protection against various fault types when the MG transferred to the islanding mode. The main contribution of this work is including the models of all micro sources which interfaced to the MG by power electronic inverters. Inverters in turns are provided with current limiters and this also included with the inverter models to exactly simulate the real situation in the MG during fault times. Results proved that the most suitable earthing system for MG protection during the islanding mode is the TN earthing system. That system leads to a suitable amount of fault current sufficient to activate over current pro-tection relays. With using TN earthing system, touch voltages at the faulted bus and all other consumer’s buses are less than the safety limited values during islanding mode. For the two others earthing systems (TT and IT), fault currents are small and nearly equal to the over load currents which make over current protection relay can not differentiate between fault currents and overload currents. All models of micro sources, earthing systems, inverters and control schemes are built using Matlab?/Simulink? environment.
文摘This paper presents, tests and compares three earthing systems (TT, TN and IT) for Micro-Grid (MG) protection against various fault types during the connected mode. The main contribution of this work is including the models of all the micro sources which interfaced to the MG by power electronic inverters. Inverters in turns are provided with current limiters and this also included in the inverter models to exactly simulate the real situation in the MG during fault times. Results proved that the most suitable earthing system for MG protection during the connecting mode is the TN earthing system. That system leads to a suitable amount of fault current sufficient to activate over current protection relays. With using TN system, Touch voltages at the faulted bus and all other consumer’s buses are less than the safety limited value if current limiter is included with the transformer of the main grid which connects MG. For the two others earthing systems (TT and IT), fault current is small and nearly equal to the over load current which make over current protection relay can not differentiate between fault current and overload current. All models of micro sources, earthing systems, inverters, main grid and control schemes are built using Matlab?/Simulink? environment.
基金supported by the National Outstanding Youth Science Fund Project of National Natural Science Foundation of China(52302031)National Natural Science Foundation of China(51932008 and 51772277)Central China Thousand Talents Project(204200510011).
文摘The reaction of carbon-free oxide-based(corundum,spinel,zirconia,and mullite)submerged entry nozzle(SEN)lining with rare earth inclusions and its anti-clogging effects under near working conditions were systematically studied.A variety of lining composite test methods were innovatively used to ensure the consistency of test conditions.The experimental results showed that the mullite(acidic oxide)has strong reactivity with rare earth inclusions,and the spinel(basic oxide)has stable chemical properties and weak reactivity with rare earth inclusions.Because alumina is one of the main reactants of clogging formation,corundum is not suitable for SEN lining.There are less clogs on the surface of zirconia,but it will be exsoluted and unstable.Therefore,solving the problem of zirconia exsolution will greatly strengthen its application in SEN lining.
基金Project supported by the National Natural Science Foundation of China(52174250,92062110)the Youth Jinggang Scholars Program in Jiangxi Province(QNJG2020048)。
文摘The recovery of rare earths from industrial rare earth leaching solution is typically achieved through the ammonium carbonate precipitation method,which presents challenges in terms of prolonged production cycle and ammonia nitrogen pollution.The present study explored the synthesis of crystalline yttrium carbonate in a sodium carbonate system,employing a conventional mother liquor derived from yttrium chloride.The growth of yttrium carbonate was explored through the lens of density functional theory(DFT)calculations,unveiling a novel perspective on its formation mechanism.The synthesized yttrium carbonate demonstrates enhanced crystallinity,with a D50value of 19.75μm achieved under reaction conditions comprising a temperature of 60℃,stirring rate of 200 r/min,feeding rate of 4 mL/min,and aging time of 30 h.The molar ratio for precipitation is set at 1.6:1.The morphology of yttrium carbonate undergoes a transition from needle-like structures to sheet-like formations,ultimately culminating in the formation of spherical aggregates.The variation in surface energy among distinct crystal planes and CO_(3)^(2-)configurations within crystal cells accounts for this phenomenon.The DFT calculations unveil a progression of growth and trans formation in yttrium carbonate,commencing from a one-dimensional configuration and culminating in a multidimensional morphology.
基金support from the Australian Research Council’s Industrial Transformation Research Hub funding scheme(project IH190100009).
文摘This study details a comprehensive approach focusing on the effective separation of light rare earth elements(REEs)via solvent extraction technique.A stock solution containing lanthanum,cerium,neodymium,praseodymium,and samarium was prepared by dissolving their pure mixed oxide(reclaimed from spent Ni-MH batteries)in a diluted HCl solution.Key extractants,including bis(2,4,4-trimethylpentyl)phosphinic acid(Cyanex 272),Cyanex 572,trialkylphosphine oxide(Cyanex 923),and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester(PC 88A),along with tributyl phosphate(TBP)as a phase modifier,were utilized to form organic systems.The extraction behavior and separability of these systems at various pH levels as well as their extraction mechanisms were investigated.The results demonstrated a direct relationship between the extraction trend and the experimental pH value,with enhanced selectivity when TBP was added.Notably,Nd and Pr exhibited similar extraction behaviors,with minor deviations from Ce,making their separation difficult to achieve.Sm extraction followed a distinct trend,allowing for its separation from other elements at pH≤2.In contrast,La exhibited a low affinity for coordination with extractants when pH was≤3.5,facilitating the separation of other elements from La,which could then be isolated in the raffinate.Among the studied organic systems,combinations of Cyanex 572 and PC 88A with TBP demonstrated superior performance in element separation.Optimum separation factors were calculated withβ_(Ce/La)=12,βNd/La=87,β_(Pr/La)=127,andβ_(Sm/La)=3191 for the former,andβ_(Sm/Ce)=54,β_(Sm/Nd)=20,andβ_(Sm/Pr)=14 for the latter.These findings provide valuable insights for selecting extraction systems and designing experiments for the effective solvent extraction separation of light REEs from their mixture.
基金funded by the University of Science,VNU-HCM under grant number T2023-107.
文摘The Vietnamese Mekong Delta(VMD),a critical agricultural hub,faces recurrent flooding that poses substantial threats to livelihoods and productivity.Ben Tre province,with its low-lying coastal terrain,is particularly vulnerable.Effective risk management and sustainable agricultural development necessitate a thorough understanding of these flood dynamics.This study leveraged the Google Earth Engine(GEE)platform and Sentinel-1 Synthetic Aperture Radar(SAR)imagery to analyze flood inundation patterns and their impacts on diverse agricultural land uses in Ben Tre province from 2015 to 2023.The methodology involved SAR data pre-processing,Otsu thresholding for water body delineation from VH polarization data and change detection using a 2020 land use map to quantify annual flooded areas and their impact on specific agricultural categories.The total inundated area peaked in 2018 at 58,334 ha,a significant increase from 27,934 ha in 2015,before stabilizing around 42,000–44,000 ha in 2021–2023.Flooded agricultural land mirrored this trend,increasing from 18,615 ha(2015)to a peak of 39,514 ha(2018),then decreasing to 28,841 ha(2023).Notably,wet rice cultivation experienced a 37.8%increase in its flooded area over the study period,while other annual crops and perennial crops saw increases of 38.9% and 68.4%,respectively.This research demonstrates the GEE platform’s efficacy with Sentinel-1 SAR for robust,long-term flood monitoring and impact assessment,revealing escalating flood pressure on key agricultural systems and an expansion of flooding beyond traditional low-lying zones,providing crucial data for adaptive land use planning.
基金Under the auspices of National Natural Science Foundation Youth Fund Project(No.41701424)Open Research Fund of State Key Laboratory of Remote Sensing Science(No.OFSLRSS201716)+1 种基金Jilin Province Science and Technology Development Plan Project(No.20240701167FG)Science and Technology Research Project of Education Department of Jilin Province(No.JJKH20230502KJ)。
文摘The health of cropland systems is directly related to the degree of food security guarantee,and the‘quantity-quality-ecology as a whole’protection is of great significance for maintaining the health of cropland systems.Taking the typical black soil region in Northeast China(TBSN)as an example,this paper combined the concept of‘quantity-quality-ecology as a whole’protection with crop-land systems health,constructed a health assessment model for cropland systems,and used Google Earth Engine to conduct a quantitat-ive analysis of the temporal and spatial evolution of cropland systems health in TBSN during 2003–2023.By coupling the geographical detector and the Multi-scale Geographically Weighted Regression(MGWR)model,the driving factors of cropland health changes were explored.The study finds that during the research period,the health status of cropland systems in TBSN showed a slight downward trend,and the distribution pattern of cropland systems health gradually shifted from‘better in the east’to‘high in the northeast and low in the southwest’.Changes in average annual sunshine duration,relative humidity,and precipitation had a significant impact on the spa-tial differentiation of cropland systems health in the early stages,and were considered as dominant factors.Meanwhile,the influence of dual dominant factors in the natural environment on cropland systems health is increasing.Furthermore,the MGWR model performed better in revealing the complex relationships between natural and social factors and changes in cropland systems health,demonstrating the significant spatial heterogeneity of the impacts of natural environment and human activities on cropland systems health.The re-search can provide scientific guidance for the sustainable development of TBSN and formulate more precise and effective cropland pro-tection policies.
基金Supported by National Key Research and Development Program of China(2017YFC0603101)National Natural Science Foundation of China(42225303,42372162,42102146)+1 种基金Strategic Priority Research Program of the Chinese Academy of Sciences(XDA14010101)Basic and Forward-Looking Major Technology Project of China National Petroleum Corporation(2023ZZ0203)。
文摘Taking the Paleozoic of the Sichuan and Tarim basins in China as example,the controlling effects of the Earth system evolution and multi-spherical interactions on the formation and enrichment of marine ultra-deep petroleum in China have been elaborated.By discussing the development of“source-reservoir-seal”controlled by the breakup and assembly of supercontinents and regional tectonic movements,and the mechanisms of petroleum generation and accumulation controlled by temperature-pressure system and fault conduit system,Both the South China and Tarim blocks passed through the intertropical convergence zone(ITCZ)of the low-latitude Hadley Cell twice during their drifts,and formed hydrocarbon source rocks with high quality.It is proposed that deep tectonic activities and surface climate evolution jointly controlled the types and stratigraphic positions of ultra-deep hydrocarbon source rocks,reservoirs,and seals in the Sichuan and Tarim basins,forming multiple petroleum systems in the Ediacaran-Cambrian,Cambrian-Ordovician,Cambrian-Permian and Permian-Triassic strata.The matching degree of source-reservoir-seal,the type of organic matter in source rocks,the deep thermal regime of basin,and the burial-uplift process across tectonic periods collectively control the entire process from the generation to the accumulation of oil and gas.Three types of oil and gas enrichment models are formed,including near-source accumulation in platform marginal zones,distant-source accumulation in high-energy beaches through faults,and three-dimensional accumulation in strike-slip fault zones,which ultimately result in the multi-layered natural gas enrichment in ultra-deep layers of the Sichuan Basin and co-enrichment of oil and gas in the ultra-deep layers of the Tarim Basin.
文摘In this study,the mechanism of the reduction-diffusion reaction in a Sm-Fe binary system at low temperature was studied to investigate the possibility of synthesis of a Fe-rich TbCu_(7)-type SmFe_(x)(x>9)by the low-temperature diffusion-reduction(LTRD)process using LiCl-KCl eutectic molten salts.Firstly,the Sm-Fe phase transformation depending on the Sm-Fe composition,the LTRD temperature,and time was investigated,and it is found that the obtained metastable phase is only TbCu_(7)-type SmFe_(~8.5),which is not a Fe-rich phase.This Fe content does not change even after an expended LTRD process,and the metastable TbCu_(7)-type SmFe_(~8.5)tends to transform to the stable Sm_(2)Fe_(17)phase.In addition,it is found that the Sm-Fe phase starts to synthesize from the Sm-rich phase in the order of SmFe_(2),SmFe_(3),and SmFe_(8.5)as the LTRD temperature increases(when the time was 10 h)or the LTRD time increases(when the temperature was 550℃).Core-shell-like particles are observed in the case of a short LTRD time,and the core and the shell are Fe and the Sm-rich Sm-Fe phase,respectively,indicating that the Sm-rich phase begins to produce on the surface of the Fe particles.It is difficult to synthesize a Fe-rich TbCu_(7)-type SmFe_(x)(x>9)phase with the Sm-Fe binary system,suggesting that a different approach,such as addition of other elements,will be necessary.
基金supported by Researchers Supporting Project number RSP2023R176,King Saud University,Riyadh,Saudi Arabia。
文摘This work reports the synthesis,characterization,and energy focused applications of the novel lanthanides co-doped tantalum pentoxide hetero-system(Sm^(3+)-Eu^(3+)-Tm^(3+):Ta_(2)O_(5)).Ln^(3+)-doped Ta_(2)O_(5) express excellent opto-electronic features reflected by the narrow band gap energy of 3.87 eV.Different vibrations confirm the presence of Ta-O-Ta and Ta-O bonds.The synthesized system possesses orthorhombic geometry with 59.46 nm particle size.With the smoother and compact morphology,the synthesized material succeeds in augmenting the performance of different systems aimed at energy applications.Fully ambient perovskite solar cell device fabricated with the Ln^(3+)-doped Ta_(2)O_(5) as an electron transport layer excels in achieving an efficiency and fill factor of 14.17% and 76% under artificial sun.This device was marked by the negligible hysteresis behavior showing profound photovoltaic performance.The electrochemical activity of the Ln^(3+)-doped Ta_(2)O_(5) decorated electrode was evaluated for electrical charge storage potential with pseudocapacitive behavior,With the highest specific capacitance of 355.39 F/g and quicker ionic diffusion rate,the designed electrode excels conventionally used materials.Electro-catalysis of water with Ln^(3+)-doped Ta_(2)O_(5) material indicates its capacity for H_(2) production with the lowest overpotential and Tafel slope values of 148 and 121.2 mV/dec,while the O_(2) generation is comparatively lower.With the stable electrochemical output,this rare earth modified material has the potential to replace conventionally used environmentally perilous and costly materials.
文摘The UHVDC transmission line transports large-capacity power, and its safety operation has very important rule on the safe operation of grid. Currently, in the DC transmission system, the earthing electrode line has the functions of ground potential fixing and bipolar imbalance current circulation during the operation of bipolar balance. Therefore the monitoring to the earthing electrode line operation is very essential. This article firstly introduced the current situation of the research on the earthing electrode line fault location method, then built the relevant PSCAD/EMTDC model for simulation verification of the current using Time Domain Reflectometry for the UHVDC earthing electrode line, and at last analyzed the reasons for the formation of the blind monitoring zones.
文摘The rail weighbridge system of a railway freight station is introduced firstly, and then the earthing method for protection of the rail weighbridge system against lightning based on YLG-60 equipotential bonding surge protection device is shown.
基金funded by the National Natural Science Foundation of China (No. T2221002)the Hunan Provincial Natural Science Foundation, China (No. 2024JJ5405)
文摘Plasma discharge stability is an important problem in atmosphere-breathing electric propulsion system when maintaining long-term missions at ultra-low earth orbit.This paper designed an inductively coupled plasma source to imitate the ionization section.The effect of inflow rate and Radio Frequency(RF)power on the plasma discharge mode transition is experimentally studied.A discharge mode detection method is proposed,which determines the discharge mode by identifying the morphology of the plasma core.By using the method,the discharge mode transition is quantified and a control model based on the parameter sensitivity is constructed.To verify the method,the spectra are measured and the electron temperature spatial distribution is calculated.And the method has been proven effective.The results show that the inductively coupled discharge contains capacitive components affected by the mass flow rate and the radio frequency power.The plasma characteristics can be maintained stably by controlling the radio frequency power when the mass flow rate randomly changes in a certain range.It is demonstrated that the application of detection method effectively identifies the discharge mode,which is a promising active control method for the plasma discharge mode.
基金The Fundamental Research Funds for the Central Universities under contract No.B220201024.
文摘An analysis of a 68-year monthly hindcast output from an eddy-resolving ocean general circulation model reveals the relationship between the interannual variability of the Kerama Gap transport(KGT)and the Kuroshio/Ryukyu Current system.The study found a significant difference in the interannual variability of the upstream and downstream transports of the East China Sea-(ECS-)Kuroshio and the Ryukyu Current.The interannual variability of the KGT was found to be of paramount importance in causing the differences between the upstream and downstream ECS-Kuroshio.Additionally,it contributed approximately 37%to the variability of the Ryukyu Current.The interannual variability of the KGT was well described by a two-layer rotating hydraulic theory.It was dominated by its subsurface-intensified flow core,and the upper layer transport made a weaker negative contribution to the total KGT.The subsurface flow core was found to be mainly driven by the subsurface pressure head across the Kerama Gap,and the pressure head was further dominated by the subsurface density anomalies on the Pacific side.These density anomalies could be traced back to the eastern open ocean,and their propagation speed was estimated to be about 7.4 km/d,which is consistent with the speed of the local first-order baroclinic Rossby wave.When the negative(positive)density anomaly signal reached the southern region of the Kerama Gap,it triggered the increase(decrease)of the KGT towards the Pacific side and the formation of an anticyclonic(cyclonic)vortex by baroclinic adjustment.Meanwhile,there is an increase(decrease)in the upstream transport of the entire Kuroshio/Ryukyu Current system and an offshore flow that decreases(increases)the downstream Ryukyu Current.
文摘Desalination is emerging as a promising alternative among various technologies to resolve water shortage. However, desalination requires a sufficient energy and cooling device and therefore poses limitations for its installation and application. In particular, many countries suffering water deficits are economically underdeveloped and cannot afford the technology. As this technology, which changes seawater into freshwater, has little environmental impact, developed countries will need to assist less developed countries to introduce this technology as a humanitarian effort. This will help reduce the number of countries that have experienced difficulty with development.
基金supported by the Project on Frontier and Interdisciplinary Research Assessment,Academic Divisions of the Chinese Academy of Sciences(Grant No.XK2023DXC002)the National Natural Science Foundation of China(No.L2324210).
文摘This article details how AN Zhisheng and his colleagues,through decades of dedicated research,began with the study of loess in China and integrated it with climatic and environmental researches.AN and his team developed a novel research approach to identifying the dynamics of changes of natural environments,including loess environment in East Asia.Their work has not only highlighted the global significance of Chinese loess as a record for global climate change,but also led to the formulation of the monsoon control theory regarding environmental changes in East Asia,as well as insights into Asian and global monsoon dynamics.The paradigm shift from a singular discipline of Quaternary science into a comprehensive Earth system science has happened.Their contributions have been instrumental in promoting sustainable development of the society in the Chinese Loess Plateau and western China.
