The setting values of thresholds for fault feature parameters are critical in all kinds of protection schemes.When the detected feature parameter value exceeds the setting value,the protection will trip.However,the se...The setting values of thresholds for fault feature parameters are critical in all kinds of protection schemes.When the detected feature parameter value exceeds the setting value,the protection will trip.However,the setting value based conventional protection schemes sometimes cannot satisfy the protection requirements of neutral ineffectively earthed power systems(NIEPS)due to wide variations in operating conditions and the complexities of fault cases.In this paper,a novel single phase grounding fault protection scheme without threshold setting is proposed.The fault detection is achieved based on operating states rather than setting values.A fuzzy c-means algorithm is used to divide the operating state of the protected feeder into non-fault states and fault states.The cluster center of each state is then obtained by classifying the historical feature samples of the protected feeder extracted under various operating conditions into their corresponding states in a constructed multi-dimensional fault feature space.The distances between the detected feature samples and the cluster centers of the non-fault and the fault states are calculated.If the distance to the fault state is shorter than that to the non-fault state,a fault is detected.Otherwise,the feeder is considered normal.A PSCAD/EMTDC simulator is used to simulate a 35 kV NIEPS under various operating conditions,non-linear loads,and complex fault cases.Results show that the proposed single phase grounding fault protection scheme without threshold setting can protect the system correctly under all kinds of faults.展开更多
0 INTRODUCTION Earth science is a natural science concerned with the composition,dynamics,spatiotemporal evolution,and formation mechanisms of Earth materials(Chen and Yang,2023).Traditional Earth science research has...0 INTRODUCTION Earth science is a natural science concerned with the composition,dynamics,spatiotemporal evolution,and formation mechanisms of Earth materials(Chen and Yang,2023).Traditional Earth science research has largely been discipline-based,relying on field investigations,data collection,experimental analyses,and data interpretation to study individual components of the Earth system.展开更多
In 2025,the global rare earth exploration and development sector achieved breakthroughs across multiple fronts.Projects advanced intensively across the Americas,Oceania,Africa,and Europe,with significant growth in res...In 2025,the global rare earth exploration and development sector achieved breakthroughs across multiple fronts.Projects advanced intensively across the Americas,Oceania,Africa,and Europe,with significant growth in resources,continuous emergence of new deposits,and strong impetus injected into the industry by technological innovation and policy support.The global rare earth resource supply pattern was further optimized (Table 1).1.Fruitful results in resource growth and new deposit discoveriesBrazil emerged as a core region for resource growth.The Colossus rare earth deposit saw a 150%increase in resources and announced its first reserve estimate.The Caldeira rare earth deposit’s resource estimate grew by 50%.The combined ore resources in the Caladão rare earth deposit’s Zones A and B reached 5.72×10~8 tonnes,with a total rare earth oxide(TREO) grade of 0.1506%,concurrently hosting 2.29×10~4tonnes of gallium metal resources.展开更多
Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating p...Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating packed bed(RPB)in premixing and crystallization on crystallinity and RE utilization rate was further investigated.The results indicate that lanthanide(La)cations are successfully introduced into the sodalite cage of Y-type zeolite.The optimized conditions are that the molar ratio of Si/La is 150,premixing for 5 h,crystallization at 90℃ for 18 h,and calcination at 550℃ for 3.5 h.At this stage,the RE utilization rate reaches 74.5%.Compared with the conventional stirred tank reactor(STR),RPB can effectively shorten the premixing time and crystallization time by 4.3 h and 6 h,improve the crystallinity by 23%and RE utilization rate by 7.5%.The RE utilization rate is more than 80%by RPB,surpassing the effectiveness of using the one-exchange one-calcination process in the traditional liquid ion exchange process.It is expected to provide a reference for the in-situ efficient and green synthesis of RE zeolite.展开更多
1.Introduction Artificial intelligence(AI)is rapidly reshaping geoscience,from Earth observation interpretation and hazard forecasting to subsurface characterisation and Earth system modelling(Kochupillai et al.,2022;...1.Introduction Artificial intelligence(AI)is rapidly reshaping geoscience,from Earth observation interpretation and hazard forecasting to subsurface characterisation and Earth system modelling(Kochupillai et al.,2022;Sun et al.,2024).These capabilities emerge at a time when geoscientific evidence is increasingly informing high-stakes decisions about climate adaptation,resource development,and disaster risk reduction(McGovern et al.,2022).展开更多
As an important strategic rare-earth resource,bastnaesite has long been a global research focus.The carbochlorination process,as an efficient and low-cost extraction method,can be applied to treat bastnaesite,achievin...As an important strategic rare-earth resource,bastnaesite has long been a global research focus.The carbochlorination process,as an efficient and low-cost extraction method,can be applied to treat bastnaesite,achieving ideal rare-earth extraction results in just one-step reaction.By using inexpensive chlorine gas as the chlorinating agent,it avoids lengthy procedural steps and the generation of acid-base waste liquids.Based on this,we propose a novel carbochlorination process for bastnaesite involving a fluorine-fixing agent.Thermodynamic data for the carbochlorination process of bastnaesite were calculated using the group contribution method.Thermodynamic feasibility was verified through Gibbs free energy.The effects of different chlorination times,fluorine-fixing agent dosages,chlorine flow rates,and chlorination temperatures on the carbochlorination process of bastnaesite were investigated.Experimental studies showed that under optimal chlorination conditions,a temperature of 800℃,a duration of 60 min,a fluorine-fixing agent dosage of 10%,and a chlorine flow rate of 10 L·min^(−1),the chlorination rates of rare-earth elements,Ca,Ba,and Fe in bastnaesite reached 96%,99%,98%,and 99%,respectively.The reaction mechanism was explored and analyzed based on characterization results such as mineral phase composition,micromorphology and thermogravimetry of water-washed residues under different chlorination conditions.Additionally,kinetic experiments were conducted at varying reaction temperatures and chlorine flow rates,revealing that the carbon-chlorination process is primarily controlled by chemical reactions.展开更多
A novel macroparticle magnesium-modified biochar/yttrium alginate(Mg-BC/SA-Y)hybrid biogel composite was successfully developed through a facile solution reaction of magnesium-modified BC and yttrium alginate polymer,...A novel macroparticle magnesium-modified biochar/yttrium alginate(Mg-BC/SA-Y)hybrid biogel composite was successfully developed through a facile solution reaction of magnesium-modified BC and yttrium alginate polymer,and its properties were characterized.The obtained Mg-BC/SA-Y biogel beads have a particle size of approximately 1.5 mm,featuring abundant network pores and an uneven,distinctive surface.The performance and mechanisms of Mg-BC/SA-Y for phosphate adsorption were thoroughly investigated.The findings indicate that Mg-BC/SA-Y removes up to 95.7%of phosphate at pH4.0 and 298 K,and also achieves a phosphate removal efficiency of over 80%within a pH range of3.0-11.0.The adsorption capacity of Mg-BC/SA-Y for phosphate is nearly four times that of BC.The spontaneous adsorption processes and endothermic adsorption behavior can be elucidated by the pseudo-second-order rate and Langmuir equations,respectively.Phosphate adsorption is almost unaffected by water ionic strength and common coexisting ions,except for the influence of highconcentration F-ions.The recyclable biogel beads can be reused after adsorbing phosphate,and represent excellent stability and practicability in real water.The mechanisms of ligand exchange,innersphere complexation and electrostatic attraction are involved in phosphate removal.Mg-BC/SA-Y biogel polymer is a desirable and sustainable biosorbent for treating water with excessive phosphate levels and reducing pollution and carbon emissions.展开更多
The process of utilizing solar-driven semiconductor water splitting for the production of hydrogen is a vital strategy in the pursuit of a zero-carbon economy.Zn_(0.1)Cd_(0.9)S,a rod-like semiconductor metal sulfide,e...The process of utilizing solar-driven semiconductor water splitting for the production of hydrogen is a vital strategy in the pursuit of a zero-carbon economy.Zn_(0.1)Cd_(0.9)S,a rod-like semiconductor metal sulfide,encounters considerable difficulties stemming from the swift recombination of charge carriers generated by light.Overcoming the coulombic interactions between charge carriers is essential for achieving efficient separation.In this study,we modified Zn_(0.1)Cd_(0.9)S with dodecahedral rare-earth compound CeVO_(4) and employed ultrasonic self-assembly to tightly couple the two materials.This integration established a built-in electric field and constructed an S-scheme heterojunction.Within this configuration,Zn_(0.1)Cd_(0.9)S serves as an electron acceptor while CeVO_(4) functions as an electron donor.Driven by the built-in electric field,electrons rapidly traverse the tightly coupled interface,minimizing their path length.The S-scheme heterojunction preserves the catalyst's strong redox capabilities and facilitates the vectorial separation of photogenerated charge carriers.In situ irradiated X-ray photoelectron spectroscopy(XPS)and electron paramagnetic resonance(EPR)analyses further validated the charge transfer mechanism of the S-scheme heterojunction.Density functional theory calculations elucidated the electronic states and roles of the catalyst,thereby establishing a theoretical framework for the investigation of S-scheme heterojunctions.This work lays a theoretical basis for the design and mechanistic investigation of S-scheme heterojunction catalysts.展开更多
Eu^(2+)-doped phosphors show broadband absorption,tunable emission and high quantum efficiency due to the parity-allowed 5d→4f transitions,allowing them to be used in solid-state lighting.To expand their applications...Eu^(2+)-doped phosphors show broadband absorption,tunable emission and high quantum efficiency due to the parity-allowed 5d→4f transitions,allowing them to be used in solid-state lighting.To expand their applications in other fields such as detection and sensing technologies,the Eu^(2+)emission needs to be tuned into the near-infrared region,but it is a big challenge to obtain Eu^(2+)near-infrared region emitters due to the absence of host compounds with extremely large crystal-field splitting.In this work,we chose M_(4)Li(BN_(2))_(3)(M=Ca,Sr,Ba)as a host and realize the near-infrared region emission of Eu^(2+)in it.Among these phosphors,Ba4Li(BN_(2))_(3):Eu^(2+)exhibits the longest emission of 880 nm and the largest full-width at half maximum of 276 nm under 450 nm excitation,while Ca_(4)Li(BN_(2))_(3):Eu^(2+)and Sr_(4)Li(BN_(2))_(3):Eu^(2+)emit at740 and 680 nm,respectively.We observe an interesting phenomenon that the energy shift of emission is linearly related to the radius difference between the alkaline earth cation and the activator Eu^(2+)in this system.展开更多
基金supported in part by National Natural Science Foundation of China under Grant 61233008 and Grant 51277014.
文摘The setting values of thresholds for fault feature parameters are critical in all kinds of protection schemes.When the detected feature parameter value exceeds the setting value,the protection will trip.However,the setting value based conventional protection schemes sometimes cannot satisfy the protection requirements of neutral ineffectively earthed power systems(NIEPS)due to wide variations in operating conditions and the complexities of fault cases.In this paper,a novel single phase grounding fault protection scheme without threshold setting is proposed.The fault detection is achieved based on operating states rather than setting values.A fuzzy c-means algorithm is used to divide the operating state of the protected feeder into non-fault states and fault states.The cluster center of each state is then obtained by classifying the historical feature samples of the protected feeder extracted under various operating conditions into their corresponding states in a constructed multi-dimensional fault feature space.The distances between the detected feature samples and the cluster centers of the non-fault and the fault states are calculated.If the distance to the fault state is shorter than that to the non-fault state,a fault is detected.Otherwise,the feeder is considered normal.A PSCAD/EMTDC simulator is used to simulate a 35 kV NIEPS under various operating conditions,non-linear loads,and complex fault cases.Results show that the proposed single phase grounding fault protection scheme without threshold setting can protect the system correctly under all kinds of faults.
基金supported by National Key R&D Program of China(No.2021YFF0501301)the National Natural Science Foundation of China(No.42172231)。
文摘0 INTRODUCTION Earth science is a natural science concerned with the composition,dynamics,spatiotemporal evolution,and formation mechanisms of Earth materials(Chen and Yang,2023).Traditional Earth science research has largely been discipline-based,relying on field investigations,data collection,experimental analyses,and data interpretation to study individual components of the Earth system.
文摘In 2025,the global rare earth exploration and development sector achieved breakthroughs across multiple fronts.Projects advanced intensively across the Americas,Oceania,Africa,and Europe,with significant growth in resources,continuous emergence of new deposits,and strong impetus injected into the industry by technological innovation and policy support.The global rare earth resource supply pattern was further optimized (Table 1).1.Fruitful results in resource growth and new deposit discoveriesBrazil emerged as a core region for resource growth.The Colossus rare earth deposit saw a 150%increase in resources and announced its first reserve estimate.The Caldeira rare earth deposit’s resource estimate grew by 50%.The combined ore resources in the Caladão rare earth deposit’s Zones A and B reached 5.72×10~8 tonnes,with a total rare earth oxide(TREO) grade of 0.1506%,concurrently hosting 2.29×10~4tonnes of gallium metal resources.
基金supported by the NationalKey Research and Development Program of China(2023YFA1507701)National Natural Science Foundation of China(U22B6011,22288102)“Announcement and Challenge”Science and Technology Project of Xinjiang Uygur Autonomous Region(XJKJTJBGS-2023).
文摘Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating packed bed(RPB)in premixing and crystallization on crystallinity and RE utilization rate was further investigated.The results indicate that lanthanide(La)cations are successfully introduced into the sodalite cage of Y-type zeolite.The optimized conditions are that the molar ratio of Si/La is 150,premixing for 5 h,crystallization at 90℃ for 18 h,and calcination at 550℃ for 3.5 h.At this stage,the RE utilization rate reaches 74.5%.Compared with the conventional stirred tank reactor(STR),RPB can effectively shorten the premixing time and crystallization time by 4.3 h and 6 h,improve the crystallinity by 23%and RE utilization rate by 7.5%.The RE utilization rate is more than 80%by RPB,surpassing the effectiveness of using the one-exchange one-calcination process in the traditional liquid ion exchange process.It is expected to provide a reference for the in-situ efficient and green synthesis of RE zeolite.
基金supported by the Natural Science Foundation of Jiangsu Province,China(Grant No.BK20240937)the Natural Science Foundation of Shandong Province(Grant No.ZR2021QE187)+2 种基金the Shandong Higher Education“Young Entrepreneurship Talents Introduction and Cultivation Program”Project(Grant No.ZXQT20221228001)the Natural Science Foundation of China(Grant No.42502273)the Science and Technology Innovation Program of Hunan Province(Grant No.2022RC4028).
文摘1.Introduction Artificial intelligence(AI)is rapidly reshaping geoscience,from Earth observation interpretation and hazard forecasting to subsurface characterisation and Earth system modelling(Kochupillai et al.,2022;Sun et al.,2024).These capabilities emerge at a time when geoscientific evidence is increasingly informing high-stakes decisions about climate adaptation,resource development,and disaster risk reduction(McGovern et al.,2022).
基金supported by the National Natural Science Foundation of China(ZX20230386)the 2023 Special Project for High-Industrial Base Reconstruction Quality Development of the Manufacturing Industry(2023ZY01019-11)the sixth batch of top talent support funds(QNBJ-2022-04).
文摘As an important strategic rare-earth resource,bastnaesite has long been a global research focus.The carbochlorination process,as an efficient and low-cost extraction method,can be applied to treat bastnaesite,achieving ideal rare-earth extraction results in just one-step reaction.By using inexpensive chlorine gas as the chlorinating agent,it avoids lengthy procedural steps and the generation of acid-base waste liquids.Based on this,we propose a novel carbochlorination process for bastnaesite involving a fluorine-fixing agent.Thermodynamic data for the carbochlorination process of bastnaesite were calculated using the group contribution method.Thermodynamic feasibility was verified through Gibbs free energy.The effects of different chlorination times,fluorine-fixing agent dosages,chlorine flow rates,and chlorination temperatures on the carbochlorination process of bastnaesite were investigated.Experimental studies showed that under optimal chlorination conditions,a temperature of 800℃,a duration of 60 min,a fluorine-fixing agent dosage of 10%,and a chlorine flow rate of 10 L·min^(−1),the chlorination rates of rare-earth elements,Ca,Ba,and Fe in bastnaesite reached 96%,99%,98%,and 99%,respectively.The reaction mechanism was explored and analyzed based on characterization results such as mineral phase composition,micromorphology and thermogravimetry of water-washed residues under different chlorination conditions.Additionally,kinetic experiments were conducted at varying reaction temperatures and chlorine flow rates,revealing that the carbon-chlorination process is primarily controlled by chemical reactions.
基金Project supported by the National Natural Science Foundation of China(21167011)the Natural Science Foundation of Inner Mongolia Autonomous Region,China(2020LH02009)the Collaborative Innovation Center for Water Environment Security of Inner Mongolia Autonomous Region,China(XTCX003)。
文摘A novel macroparticle magnesium-modified biochar/yttrium alginate(Mg-BC/SA-Y)hybrid biogel composite was successfully developed through a facile solution reaction of magnesium-modified BC and yttrium alginate polymer,and its properties were characterized.The obtained Mg-BC/SA-Y biogel beads have a particle size of approximately 1.5 mm,featuring abundant network pores and an uneven,distinctive surface.The performance and mechanisms of Mg-BC/SA-Y for phosphate adsorption were thoroughly investigated.The findings indicate that Mg-BC/SA-Y removes up to 95.7%of phosphate at pH4.0 and 298 K,and also achieves a phosphate removal efficiency of over 80%within a pH range of3.0-11.0.The adsorption capacity of Mg-BC/SA-Y for phosphate is nearly four times that of BC.The spontaneous adsorption processes and endothermic adsorption behavior can be elucidated by the pseudo-second-order rate and Langmuir equations,respectively.Phosphate adsorption is almost unaffected by water ionic strength and common coexisting ions,except for the influence of highconcentration F-ions.The recyclable biogel beads can be reused after adsorbing phosphate,and represent excellent stability and practicability in real water.The mechanisms of ligand exchange,innersphere complexation and electrostatic attraction are involved in phosphate removal.Mg-BC/SA-Y biogel polymer is a desirable and sustainable biosorbent for treating water with excessive phosphate levels and reducing pollution and carbon emissions.
基金Project supported by the National Natural Science Foundation of China(22271106,52073286)the Natural Science Foundation of Fujian Province(2006L2005)。
文摘The process of utilizing solar-driven semiconductor water splitting for the production of hydrogen is a vital strategy in the pursuit of a zero-carbon economy.Zn_(0.1)Cd_(0.9)S,a rod-like semiconductor metal sulfide,encounters considerable difficulties stemming from the swift recombination of charge carriers generated by light.Overcoming the coulombic interactions between charge carriers is essential for achieving efficient separation.In this study,we modified Zn_(0.1)Cd_(0.9)S with dodecahedral rare-earth compound CeVO_(4) and employed ultrasonic self-assembly to tightly couple the two materials.This integration established a built-in electric field and constructed an S-scheme heterojunction.Within this configuration,Zn_(0.1)Cd_(0.9)S serves as an electron acceptor while CeVO_(4) functions as an electron donor.Driven by the built-in electric field,electrons rapidly traverse the tightly coupled interface,minimizing their path length.The S-scheme heterojunction preserves the catalyst's strong redox capabilities and facilitates the vectorial separation of photogenerated charge carriers.In situ irradiated X-ray photoelectron spectroscopy(XPS)and electron paramagnetic resonance(EPR)analyses further validated the charge transfer mechanism of the S-scheme heterojunction.Density functional theory calculations elucidated the electronic states and roles of the catalyst,thereby establishing a theoretical framework for the investigation of S-scheme heterojunctions.This work lays a theoretical basis for the design and mechanistic investigation of S-scheme heterojunction catalysts.
基金Project supported by the National Key Research and Development Program(2022YFE0108800)。
文摘Eu^(2+)-doped phosphors show broadband absorption,tunable emission and high quantum efficiency due to the parity-allowed 5d→4f transitions,allowing them to be used in solid-state lighting.To expand their applications in other fields such as detection and sensing technologies,the Eu^(2+)emission needs to be tuned into the near-infrared region,but it is a big challenge to obtain Eu^(2+)near-infrared region emitters due to the absence of host compounds with extremely large crystal-field splitting.In this work,we chose M_(4)Li(BN_(2))_(3)(M=Ca,Sr,Ba)as a host and realize the near-infrared region emission of Eu^(2+)in it.Among these phosphors,Ba4Li(BN_(2))_(3):Eu^(2+)exhibits the longest emission of 880 nm and the largest full-width at half maximum of 276 nm under 450 nm excitation,while Ca_(4)Li(BN_(2))_(3):Eu^(2+)and Sr_(4)Li(BN_(2))_(3):Eu^(2+)emit at740 and 680 nm,respectively.We observe an interesting phenomenon that the energy shift of emission is linearly related to the radius difference between the alkaline earth cation and the activator Eu^(2+)in this system.
