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Stathmin destabilizing microtubule dynamics promotes malignant potential in cancer cells by epithelial-mesenchymal transition 被引量:6
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作者 Yu Lu Chen Liu +4 位作者 Yong-Feng Xu He Cheng Si Shi Chun-Tao Wu Xian-Jun Yu 《Hepatobiliary & Pancreatic Diseases International》 SCIE CAS 2014年第4期386-394,共9页
BACKGROUND: Stathmin is a ubiquitous cytosolic regulatory phosphoprotein and is overexpressed in different human malignancies. The main physiological function of stathmin is to interfere with microtubule dynamics by ... BACKGROUND: Stathmin is a ubiquitous cytosolic regulatory phosphoprotein and is overexpressed in different human malignancies. The main physiological function of stathmin is to interfere with microtubule dynamics by promoting depolymerization of microtubules or by preventing polymerization of tubulin heterodimers. Stathmin plays important roles in regulating many cellular functions as a result of its microtubuledestabilizing activity. Currently, the critical roles of stathmin in cancer cells, as well as in lymphocytes have been valued. This review discusses stathmin and microtubule dynamics in cancer development, and hypothesizes their possible relationship with epithelial-mesenchymal transition(EMT).DATA SOURCES: A PubMed search using such terms as "stathmin", "microtubule dynamics", "epithelial-mesenchymal transition", "EMT", "malignant potential" and "cancer" was performed to identify relevant studies published in English.More than 100 related articles were reviewed.RESULTS: The literature clearly documented the relationship between stathmin and its microtubule-destabilizing activity of cancer development. However, the particular mechanism is poorly understood. Microtubule disruption is essential for EMT, which is a crucial process during cancer development. As a microtubule-destabilizing protein, stathmin may promote malignant potential in cancer cells by initiating EMT.CONCLUSIONS: We propose that there is a stathminmicrotubule dynamics-EMT(S-M-E) axis during cancer development. By this axis, stathmin together with itsmicrotubule-destabilizing activity contributes to EMT, which stimulates the malignant potential in cancer cells. 展开更多
关键词 stathmin microtubule dynamics epithelial-mesenchymal transition malignant potential cancer
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Photoluminescence and Optical Transition Dynamics of Er^(3+) Ions in Porous Si 被引量:1
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作者 Xinwei ZHAO Hideo Isshiki Yoshinobu Aoyagi and Takuo Sugano(Frontier Research Program, The Institute of Physical and Chemical Research (RIKEN), 2-1 Hirosawa, Wako, Saitama 351-0198, Japan)Shuji Komuro(Faculty of Engineering. Toyo University, Kawagoe, Sa 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1999年第4期357-362,共6页
Er was doped into porous Si by immersing the porous Si sample in a saturated ErCl3,ethanol solution. Sharp and intense 1.54 μm photoluminescence caused by intra-4f-shefl transitions in Er3+ ions was observed up to ro... Er was doped into porous Si by immersing the porous Si sample in a saturated ErCl3,ethanol solution. Sharp and intense 1.54 μm photoluminescence caused by intra-4f-shefl transitions in Er3+ ions was observed up to room temperature. It is shown that the immersing process is valid to dope Er in high concentration in porous Si. Time resolved study of the Er-doped porous Si revealed that the doped Er3+ ions are excited by energy transfer from photo-generated electron-hole pairs in the host. The energy back transfer process from the excited 4f electrons in the Er3+ion to the host is not a dominant factor to quench the Er-related emission in porous Si. Ourresults are well explained by a proposed model in which an intermediate state was introduced. 展开更多
关键词 OO Photoluminescence and Optical transition dynamics of Er Ions in Porous Si FIGURE OK
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Phase transition in a two-dimensional Ising ferromagnet based on the generalized zero-temperature Glauber dynamics
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作者 孟庆宽 冯东太 +1 位作者 高绪团 梅玉雪 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第12期461-465,共5页
At zero temperature, based on the Ising model, the phase transition in a two-dimensional square lattice is studied using the generalized zero-temperature Glauber dynamics. Using Monte Carlo (MC) renormalization grou... At zero temperature, based on the Ising model, the phase transition in a two-dimensional square lattice is studied using the generalized zero-temperature Glauber dynamics. Using Monte Carlo (MC) renormalization group methods, the static critical exponents and the dynamic exponent are studied; the type of phase transition is found to be of the first order. 展开更多
关键词 zero-temperature Glauber dynamics phase transition Monte Carlo renormalization group
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Frequency Switches at Transition Temperature in Voltage-Gated Ion Channel Dynamics of Neural Oscillators
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作者 Yasuomi D.Sato 《Chinese Physics Letters》 SCIE CAS CSCD 2018年第5期152-155,共4页
Understanding of the mechanisms of neural phase transitions is crucial for clarifying cognitive processes in the brain. We investigate a neural oscillator that undergoes different bifurcation transitions from the big ... Understanding of the mechanisms of neural phase transitions is crucial for clarifying cognitive processes in the brain. We investigate a neural oscillator that undergoes different bifurcation transitions from the big saddle homoclinic orbit type to the saddle node on an invariant circle type, and the saddle node on an invariant circle type to the small saddle homoclinic orbit type. The bifurcation transitions are accompanied by an increase in thermodynamic temperature that affects the voltage-gated ion channel in the neural oscillator. We show that nonlinear and thermodynamical mechanisms are responsible for different switches of the frequency in the neural oscillator. We report a dynamical role of the phase response curve in switches of the frequency, in terms of slopes of frequency-temperature curve at each bifurcation transition. Adopting the transition state theory of voltagegated ion channel dynamics, we confirm that switches of the frequency occur in the first-order phase transition temperature states and exhibit different features of their potential energy derivatives in the ion channel. Each bifurcation transition also creates a discontinuity in the Arrhenius plot used to compute the time constant of the ion channel. 展开更多
关键词 Frequency Switches at transition Temperature in Voltage-Gated Ion Channel dynamics of Neural Oscillators
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Variational Quantum Simulation of Dynamical Quantum Phase Transition in Markovian Open Quantum Systems
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作者 Yukai Guo Jinjian Yu Xing Gao 《Chinese Journal of Chemical Physics》 2025年第4期391-400,I0104,共11页
We investigate dynamical quantum phase transitions(DQPTs)in Marko-vian open quantum systems using a variational quantum simulation(VQS)algorithm based on quantum state diffusion(QSD).This approach reformulates the Lin... We investigate dynamical quantum phase transitions(DQPTs)in Marko-vian open quantum systems using a variational quantum simulation(VQS)algorithm based on quantum state diffusion(QSD).This approach reformulates the Lindblad master equation as an ensemble of pure-state trajectories,enabling efficient simula-tion of dissipative quantum dynam-ics with effectively reduced quantum resources.Focusing on the one-di-mensional transverse-field Ising mod-el(TFIM),we simulate quench dynamics under both local and global Lindblad dissipation.The QSD-VQS algorithm accurately captures the nonanalytic cusps in the Loschmidt rate function,and reveals their modulation by dissipation strength and system size.Notably,DQPTs are gradually suppressed under strong local dissipation,while they persist under strong global dissipation due to collective environmental effects.Benchmarking against exact Lindblad solutions confirms the high accuracy and scalability of our method. 展开更多
关键词 Variational quantum simulation Dynamical quantum phase transition Quan-tum state diffusion Transverse-field Ising model
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Metallogenic Effect of Transition of Tectonic Dynamic System 被引量:15
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作者 DengJun WangQingfei +3 位作者 WeiYanguang WangJianping SunZhongshi YangLiqiang 《Journal of China University of Geosciences》 SCIE CSCD 2004年第1期23-28,共6页
Tectonic dynamic system transition, one of the main factors in metallogenesis, controls metallogenic fluid movement and ore body location in orefields and on an ore deposit scale (mainly in the continental tectonic se... Tectonic dynamic system transition, one of the main factors in metallogenesis, controls metallogenic fluid movement and ore body location in orefields and on an ore deposit scale (mainly in the continental tectonic setting), and even the formation and distribution of large-scale deposit clusters. Tectonic dynamic system transition can be classified as the spacious difference of the tectonic dynamic system in various geological units and the temporal alteration of different tectonic dynamic systems. The former results in outburst of mineralization, while the latter leads to the metallogenic diversity. Both of them are the main contents of metallogenic effect of tectonic dynamic system transition, that is, the alteration of dynamic system, the occurrence of mineralization, and the difference of regional tectonic dynamic system and metallogenic diversity. Generally speaking, the coupling of spatial difference of tectonic dynamic system and its successive alternation controlled the tempo-spatial evolution regularity of mineralization on a larger scale. In addition, the analysis of mineralization factors and processes of typical ore deposits proved that the changes of tectonic stress field, the direct appearance of tectonic dynamic system transition, may lead to the accident of mineralization physical-chemical field and the corresponding accidental interfaces were always located at ore bodies. 展开更多
关键词 tectonic dynamic system transition metallogenic diversity interface mineralization.
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Dynamic transition mechanism analysis of the impact of energy development on urbanization in Central Asia 被引量:2
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作者 ZHOU Yannan YANG Yu +3 位作者 SONG Zhouying HE Ze XIA Siyou REN Yawen 《Journal of Geographical Sciences》 SCIE CSCD 2020年第11期1825-1848,共24页
Energy development has a significant impact on urbanization. This study employs the entropy method to evaluate the level of urbanization in Central Asia and further analyzes the possible dynamic transition mechanisms ... Energy development has a significant impact on urbanization. This study employs the entropy method to evaluate the level of urbanization in Central Asia and further analyzes the possible dynamic transition mechanisms of the impact of energy development (characterized by energy development scale, energy trade, energy consumption, and energy endowment) on urbanization using the Panel Smooth Transition Regression model (PSTR). The results demonstrate that energy development in this region is characterized by “three highs and one low”, namely, high production volume, high export volume, high endowment, and low self-consumption, and plays a crucial role in the progress of urbanization. A nonlinear relationship is found to exist between energy development and comprehensive urbanization in the transition economies of Central Asia. Generally speaking, as energy development continues to expand, its impact on urbanization in this region has shifted from constraint to promotion, with the latter gradually tending to flatten out. Energy development characterized by energy development scale, energy consumption, and energy trade can prove the point, whose threshold is 1.47 million tons oil equivalent (Mtoe), 0.29 tons oil equivalent (toe) per capita, and 20.95 Mtoe, respectively. However, not all energy development models exhibit this behavior. Energy development characterized by energy endowment is such a case where the positive effect of it on comprehensive urbanization will be restrained when it exceeds 3.18. These findings can aid decision makers in seeking a better energy development model to promote the sustainable development of urbanization in Central Asia, avoiding energy resources waste and disorderly development. 展开更多
关键词 energy development URBANIZATION dynamic transition mechanism PSTR model Central Asia
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Demage Spreading in the Ising Model with a special Metropolis Dynamics Approach 被引量:1
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作者 LIUCe-Jun HUJia-Zhen 《Communications in Theoretical Physics》 SCIE CAS CSCD 2001年第4期480-484,共5页
The time evolution of the Hamming distance (damage spreading) for the and Ising models on the square lattice is performed with a special metropolis dynamics algorithm. Two distinct regimes are observed according to ... The time evolution of the Hamming distance (damage spreading) for the and Ising models on the square lattice is performed with a special metropolis dynamics algorithm. Two distinct regimes are observed according to the temperature range for both models: a low-temperature one where the distance in the long-time limit is finite and seems not to depend on the initial distance and the system size; a high-temperature one where the distance vanishes in the long-time limit. Using the finite size scaling method, the dynamical phase transition (damage spreading transition) temperature is obtained as for the Ising model. 展开更多
关键词 S=1/2 S=1 Ising models dynamical phase transition damage spreading special metropolis dynamics
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Dynamic phase transition of ferroelectric nanotube described by a spin-1/2 transverse Ising model 被引量:1
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作者 Chundong Wang Ying Wu +1 位作者 Yulin Cao Xinying Xue 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第2期227-231,共5页
The dynamic phase transition properties for ferroelectric nanotube under a spin-1/2 transverse Ising model are studied under the effective field theory(EFT)with correlations.The temperature effects on the pseudo-spin ... The dynamic phase transition properties for ferroelectric nanotube under a spin-1/2 transverse Ising model are studied under the effective field theory(EFT)with correlations.The temperature effects on the pseudo-spin systems are unveiled in three-dimensional(3-D)and two-dimensional(2-D)phase diagrams.Moreover,the dynamic behaviors of exchange interactions on the 3-D and 2-D phase transitions under high temperature are exhibited.The results present that it is hard to obtain pure ferroelectric phase under high temperature;that is,the vibration of orderly pseudo-spins cannot be eliminated completely. 展开更多
关键词 ferroelectric nanotube three-dimensional(3-D)phase diagram Ising model dynamic phase transitions
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Numerical method for simulating rarefaction shocks in the approximation of phase-flip hydrodynamics 被引量:1
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作者 M.M.BASKO 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2021年第6期871-884,共14页
A finite-difference algorithm is proposed for numerical modeling of hydrodynamic flows with rarefaction shocks, in which the fluid undergoes a jump-like liquid-gas phase transition. This new type of flow discontinuity... A finite-difference algorithm is proposed for numerical modeling of hydrodynamic flows with rarefaction shocks, in which the fluid undergoes a jump-like liquid-gas phase transition. This new type of flow discontinuity, unexplored so far in computational fluid dynamics, arises in the approximation of phase-flip(PF) hydrodynamics, where a highly dynamic fluid is allowed to reach the innermost limit of metastability at the spinodal, upon which an instantaneous relaxation to the full phase equilibrium(EQ) is assumed. A new element in the proposed method is artificial kinetics of the phase transition, represented by an artificial relaxation term in the energy equation for a "hidden"component of the internal energy, temporarily withdrawn from the fluid at the moment of the PF transition. When combined with an appropriate variant of artificial viscosity in the Lagrangian framework, the latter ensures convergence to exact discontinuous solutions, which is demonstrated with several test cases. 展开更多
关键词 fluid dynamics with phase transitions two-phase flow rarefaction shock Lagrangian scheme artificial viscosity artificial kinetics
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Reliability Analysis of Multi-State Repairable System with Dynamic Transition Probabilities
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作者 古莹奎 陈佳 +1 位作者 承姿辛 胡康 《Journal of Shanghai Jiaotong university(Science)》 EI 2016年第5期615-620,共6页
Inadequate maintenance decisions lead to incremental overall costs. In order to minimize costs in maintenance of the multi-state repairable system, we model a preventive maintenance(PM) scheme of the multistate repair... Inadequate maintenance decisions lead to incremental overall costs. In order to minimize costs in maintenance of the multi-state repairable system, we model a preventive maintenance(PM) scheme of the multistate repairable system using non-Markov process. The periodically decreasing reliability model of the non-Markov dynamic system with dynamic transition probabilities is established to satisfy the probability change. The diesel engine system is taken as an example to illustrate the model. The reliability of the diesel engine is analyzed and its PM scheme is worked out. RENO software is used to simulate the diesel engine system. The maintenance cost of components and the optimal PM interval data of the system are obtained by using the minimal average cost as the objective function. The adaptability of PM is judged, and the optimal PM scheme is presented. 展开更多
关键词 non-Markov process multi-state repairable system preventive maintenance(PM) minimal average cost dynamic transition probability
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Nonequilibrium Phase Transition in Spin-S Ising Ferromagnet Driven by Propagating and Standing Magnetic Field Wave
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作者 Ajay Halder Muktish Acharyya 《Communications in Theoretical Physics》 SCIE CAS CSCD 2017年第11期600-610,共11页
The dynamical response of spin-S(S=1, 3/2, 2, 3) Ising ferromagnet to the plane propagating wave, standing magnetic field wave and uniformly oscillating field with constant frequency are studied separately in two dime... The dynamical response of spin-S(S=1, 3/2, 2, 3) Ising ferromagnet to the plane propagating wave, standing magnetic field wave and uniformly oscillating field with constant frequency are studied separately in two dimensions by extensive Monte Carlo simulation. Depending upon the strength of the magnetic field and the value of the spin state of the Ising spin lattice two different dynamical phases are observed. For a fixed value of S and the amplitude of the propagating magnetic field wave the system undergoes a dynamical phase transition from propagating phase to pinned phase as the temperature of the system is cooled down. Similarly in case with standing magnetic wave the system undergoes dynamical phase transition from high temperature phase where spins oscillate coherently in alternate bands of half wavelength of the standing magnetic wave to the low temperature pinned or spin frozen phase. For a fixed value of the amplitude of magnetic field oscillation the transition temperature is observed to decrease to a limiting value as the value of spin S is increased. The time averaged magnetisation over a full cycle of the magnetic field oscillation plays the role of the dynamic order parameter. A comprehensive phase boundary is drawn in the plane of magnetic field amplitude and dynamic transition temperature. It is found that the phase boundary shrinks inwards for high value of spin state S.Also in the low temperature(and high field) region the phase boundaries are closely spaced. 展开更多
关键词 Ising model dynamic phase transition Monte-Carlo algorithm propagating wave standing wave
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Stochastic resonance and nonequilibrium dynamic phase transition of Ising spin system driven by a joint external field
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作者 邵元智 钟伟荣 +1 位作者 林光明 李坚灿 《Chinese Physics B》 SCIE EI CAS CSCD 2005年第10期2110-2116,共7页
The dynamic response and stochastic resonance of a kinetic Ising spin system (ISS) subject to the joint action of an external field of weak sinusoidal modulation and stochastic white-nolse are studied by solving the... The dynamic response and stochastic resonance of a kinetic Ising spin system (ISS) subject to the joint action of an external field of weak sinusoidal modulation and stochastic white-nolse are studied by solving the mean-field equation of motion based on Glauber dynamics. The periodically driven stochastic ISS shows that the characteristic stochastic resonance as well as nonequilibrium dynamic phase transition (NDPT) occurs when the frequency ω and amplitude h0 of driving field, the temperature t of the system and noise intensity D are all specifically in accordance with each other in quantity. There exist in the system two typical dynamic phases, referred to as dynamic disordered paramagnetic and ordered ferromagnetic phases respectively, corresponding to a zero- and a unit-dynamic order parameter. The NDPT boundary surface of the system which separates the dynamic paramagnetic phase from the dynamic ferromagnetic phase in the 3D parameter space of ho-t-D is also investigated. An interesting dynamical ferromagnetic phase with an intermediate order parameter of 0.66 is revealed for the first time in the ISS subject to the perturbation of a joint determinant and stochastic field. The intermediate order dynamical ferromagnetic phase is dynamically metastable in nature and owns a peculiar characteristic in its stability as well as the response to external driving field as compared with a fully order dynamic ferromagnetic phase. 展开更多
关键词 Ising spin system stochastic resonance dynamic phase transition dynamical symmetry
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Dynamical quantum phase transition in XY chains with the Dzyaloshinskii-Moriya and XZY-YZX three-site interactions
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作者 Kaiyuan Cao Ming Zhong Peiqing Tong 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第6期260-266,共7页
We study the dynamical quantum phase transitions(DQPTs)in the XY chains with the Dzyaloshinskii-Moriya interaction and the XZY-YZX type of three-site interaction after a sudden quench.Both the models can be mapped to ... We study the dynamical quantum phase transitions(DQPTs)in the XY chains with the Dzyaloshinskii-Moriya interaction and the XZY-YZX type of three-site interaction after a sudden quench.Both the models can be mapped to the spinless free fermion models by the Jordan-Wigner and Bogoliubov transformations with the form■where the quasiparticle excitation spectraεkmay be smaller than 0 for some k and are asymmetrical■It is found that the factors of Loschmidt echo equal 1 for some k corresponding to the quasiparticle excitation spectra of the pre-quench Hamiltonian satisfyingε_(k)·ε_(-k)<0,when the quench is from the gapless phase.By considering the quench from different ground states,we obtain the conditions for the occurrence of DQPTs for the general XY chains with gapless phase,and find that the DQPTs may not occur in the quench across the quantum phase transitions regardless of whether the quench is from the gapless phase to gapped phase or from the gapped phase to gapless phase.This is different from the DQPTs in the case of quench from the gapped phase to gapped phase,in which the DQPTs will always appear.Moreover,we analyze the different reasons for the absence of DQPTs in the quench from the gapless phase and the gapped phase.The conclusion can also be extended to the general quantum spin chains. 展开更多
关键词 dynamical quantum phase transition gapless phase asymmetry excitation spectra
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Floquet dynamical quantum phase transitions in transverse XY spin chains under periodic kickings
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作者 栾丽娜 张镁玉 王林成 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第9期144-152,共9页
Floquet dynamical quantum phase transitions(DQPTs),which are nonanalytic phenomena recuring periodically in time-periodic driven quantum many-body systems,have been widely studied in recent years.In this article,the F... Floquet dynamical quantum phase transitions(DQPTs),which are nonanalytic phenomena recuring periodically in time-periodic driven quantum many-body systems,have been widely studied in recent years.In this article,the Floquet DQPTs in transverse XY spin chains under the modulation ofδ-function periodic kickings are investigated.We analytically solve the system,and by considering the eigenstate as well as the ground state as the initial state of the Floquet dynamics,we study the corresponding multiple Floquet DQPTs emerged in the micromotion with different kicking moments.The rate function of return amplitude,the Pancharatnam geometric phase and the dynamical topological order parameter are calculated,which consistently verify the emergence of Floquet DQPTs in the system. 展开更多
关键词 Floquet dynamical quantum phase transitions periodic kick XY spin chains
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Change of State of a Dynamical Unit in the Transition of Coherence
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作者 杨言晋 杜如海 +2 位作者 王圣军 金涛 屈世显 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第1期18-21,共4页
The change of state of one map in the network of nonlocal coupled logistic maps at the transition of coherence is studied. With the increase of coupling strength, the network dynamics transits from the incoherent stat... The change of state of one map in the network of nonlocal coupled logistic maps at the transition of coherence is studied. With the increase of coupling strength, the network dynamics transits from the incoherent state into the coherent state. In the process, the iteration of the map first changes from chaos to period state, then from periodic to chaotic state again. For the periodic doubling bifurcations, similar to an isolated map, the largest Lyapunov exponent tends to zero from a negative value. However, the states of coupled maps exhibit complex behavior rather than converge to a few fixed values. The behavior brings a new chimera state of coupled logistic maps. The bifurcation diagram is identical to the phase order of maps iterations. For the bifurcation between 1-band and multi-band chaos, the symmetry of chaotic bands emerges and the transition of the order of iteration direction occurs. 展开更多
关键词 net Change of State of a Dynamical Unit in the transition of Coherence
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Dynamic Investigations of Pressure-Induced Abnormal Phase Transitions in PbTiO3
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作者 吴宏博 段益峰 +4 位作者 刘坤 吕东 秦丽霞 石礼伟 唐刚 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第5期138-141,共4页
The effects of pressure on phonon modes of ferroeleetrie tetragonal P4mm and paraelectric cubic Pm3m PbTiOa are systematically investigated by using first-principles simulations. The pressure-induced tetragonal-to-cub... The effects of pressure on phonon modes of ferroeleetrie tetragonal P4mm and paraelectric cubic Pm3m PbTiOa are systematically investigated by using first-principles simulations. The pressure-induced tetragonal-to-cubie and subsequent cubic-to-tetragonal phase transitions are the second-order transitions, which are different from the phase transitions induced by temperature [Phys. Rev. Lett. 25 (1970) 167]. As pressure increases, the lowest A1 and E modes of the tetragonal phase become softer and converge to the F1u mode of the cubic phase. As pressure further increases, the lowest Flu mode first hardens and then softens again, and finally diverges into A1 and E modes. The behaviors of optical phonon modes confirm the ferroelectric-to-paraelectric-to-ferroeleetric phase transitions. 展开更多
关键词 Ti Pb Dynamic Investigations of Pressure-Induced Abnormal Phase transitions in PbTiO3
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Quantum-coherence-assisted dynamical phase transition in the one-dimensional transverse-field Ising model
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作者 Bao-Ming Xu 《Communications in Theoretical Physics》 CSCD 2024年第12期73-82,共10页
Quantum coherence will undoubtedly play a fundamental role in understanding the dynamics of quantum many-body systems;therefore, to be able to reveal its genuine contribution is of great importance. In this paper, we ... Quantum coherence will undoubtedly play a fundamental role in understanding the dynamics of quantum many-body systems;therefore, to be able to reveal its genuine contribution is of great importance. In this paper, we focus our discussions on the one-dimensional transverse field quantum Ising model initialized in the coherent Gibbs state, and investigate the effects of quantum coherence on dynamical quantum phase transition(DQPT). After quenching the strength of the transverse field, the effects of quantum coherence are studied using Fisher zeros and the rate function of the Loschmidt echo. We find that quantum coherence not only recovers DQPT destroyed by thermal fluctuations, but also generates some entirely new DQPTs, which are independent of the equilibrium quantum critical point. We also find that the Fisher zero cutting the imaginary axis is not sufficient to generate DQPT because it also requires the Fisher zeros to be tightly bound close enough to the neighborhood of the imaginary axis. It can be manifested that DQPTs are rooted in quantum fluctuations. This work reveals new information on the fundamental connection between quantum critical phenomena and quantum coherence. 展开更多
关键词 dynamical quantum phase transition quantum coherence Fisher zero winding number
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Effect of Branching Architecture on Glass Transition Behavior of Hyperbranched Copolystyrenes:the Experiment and Simulation Studies
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作者 Xiang Luo Shi-jie Xie +3 位作者 黄卫 Bo-na Dai 吕中元 De-yue Yan 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2016年第1期77-87,共11页
By controlling the feed ratio of CMS/styrene and the polymerization time, a series of hyperbranched copolystyrenes(HBCPS) were synthesized with comparable weight-averaged molecular weights(Mw) but different degree... By controlling the feed ratio of CMS/styrene and the polymerization time, a series of hyperbranched copolystyrenes(HBCPS) were synthesized with comparable weight-averaged molecular weights(Mw) but different degree of branching(DB) through atom transfer radical self-condensing vinyl copolymerization(ATR-SCVCP) with Cu Br/2,2?-bipyridyl as the catalyst. The resulting HBCPS samples were used to investigate the effect of branching architecture on their glass transition behavior. With the DB increased, the glass transition temperatures(Tg) of HBCPS samples measured by DMA and DSC both decreased. Their spin-lattice relaxation times(1H T1r) of protons displayed the same downtrend with increasing DB. Besides, a correlation between the Tgs and the DB was well established by all-atom molecular dynamics(MD) simulations. The values of MD-determined Tgs are little higher than the corresponding experimental ones. However, the dependence of Tgs on DB is in good agreement with the experimental results, i.e., Tg decreases both in experiments and simulations with increasing DB. 展开更多
关键词 All-atom molecular dynamics simulation Degree of branching Glass transition temperature Hyperbranched copolystyrene
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Positioning a fluorescent probe at the core of a glassy star polymer for detection of local dynamics
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作者 Desheng Li Jingfa Yang Jiang Zhao 《Chinese Chemical Letters》 SCIE CAS CSCD 2018年第3期374-380,共7页
Accessing local dynamics within a single macromolecule is the key to understand the physical origin of the viscoelasticity and especially the glass transition. In order to extract specific information on the dynamics ... Accessing local dynamics within a single macromolecule is the key to understand the physical origin of the viscoelasticity and especially the glass transition. In order to extract specific information on the dynamics of the branch point of a star polymer around its glass transition temperature, four-arm star poly (n-butyl methacrylate) with a fluorescent core was synthesized using perylene diimide as initiator and polymerization conducted via atom transfer radical polymerization. The process is found to be effective in positioning the fluorophore at the branch point with the fluorophore intact, which allows the successful application of single molecule fluorescence defocus imaging in examining the local site- sensitive dynamics. The power spectra of rotation trajectories, the population of rotating fluorophores as well as the distribution of angular displacement were used to revel the difference in local dynamics between branch point and the arm's end. It is discovered that the local dynamics at the core of the star polymer is much less activated than that at the arm's end. The results demonstrate the strong effect dues to the topological constrain at the branch point and the more free space at the arm's end. 展开更多
关键词 Perylene diimide Star polymer Glass transition Fluorescence defocus imaging Local dynamics
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