Quantitative structure-biodegradability relationships （QSBRs） were established to develop predictive models and mechanistic explanations for acid dyestuffs as well as biological activities. With a total of four desc...Quantitative structure-biodegradability relationships （QSBRs） were established to develop predictive models and mechanistic explanations for acid dyestuffs as well as biological activities. With a total of four descriptors, molecular weight （MW）, energies of the highest occupied molecular orbital （EHOMO）, the lowest unoccupied molecular orbital （ELUMO）, and the excited state （EES）, calculated using quantum chemical semi-empirical methodology, a series of models were analyzed between the dye biodegradability and each descriptor. Results showed that EHOMO and Mw were the dominant parameters controlling the biodegradability of acid dyes. A statistically robust QSBR model was developed for all studied dyes, with the combined application of EHOMO and Mw. The calculated biodegradations fitted well with the experimental data monitored in a facultative-aerobic process, indicative of the reliable prediction and mechanistic character of the developed model.展开更多
Two-phase electrophoresis was used to separate the dyestuffs from their dilute solutions. Several dyestuffs (naphthol green B, acid-chrome blue K, methyl blue and direct fast torquoise blue GL, and n-butanol) were tr...Two-phase electrophoresis was used to separate the dyestuffs from their dilute solutions. Several dyestuffs (naphthol green B, acid-chrome blue K, methyl blue and direct fast torquoise blue GL, and n-butanol) were treated in a self-designed experimental setup and the mass transfer characteristics in this process were studied. The results confirm the potential of this technique for recovering dyestuffs from their dilute solutions.展开更多
Due to the high cost of adsorbents and their thermal regeneration in recent years, much research has fo- cused on the search for cheaper adsorbents for treating wastewater from textile industry. The single component a...Due to the high cost of adsorbents and their thermal regeneration in recent years, much research has fo- cused on the search for cheaper adsorbents for treating wastewater from textile industry. The single component ad-sorption of an acidic dye, Acid Yellow 117, and a basic dye, Methylene Blue, onto several adsoroents-bamooo, waste wood, bamboo char, waste wood char, bamboo activated carbon, wood activated carbon and active carbon F400 were conducted. Based on a Langmuir analysis, the monolayer adsorption capacities were determined. Three of the adsorbents were selected for binary layer adsorption to check the multilayer concept and the potential application for better adsorbent usage. The two cheapest adsorbents, bamboo and wood are compared with the commer-cial activated carbon F400, and all three systems were successful.展开更多
This work aimed at effectively utilizing the chemically depolymerized waste poly（ethylene terephthalate）（PET） fibers into useful products for the textile industry.PET fibers were glycolytically degraded by excess ...This work aimed at effectively utilizing the chemically depolymerized waste poly（ethylene terephthalate）（PET） fibers into useful products for the textile industry.PET fibers were glycolytically degraded by excess ethylene glycol as depolymerizing agent and zinc acetate dihydrate as catalyst.The glycolysis product,bis（2-hydroxyethyl） terephthalate（BHET）,was purified through repeated crystallization to get an average yield above 80%.Then,BHET was nitrated,reduced,and azotized to get diazonium salt.Finally,the produced diazonium salt was coupled with 1-（4-sulfophenyl）-3-methyl-5-pyrazolone to get azo dyestuff.The structures of BHET and azo dyestuff were identified by FT1 R and ^1H NMR spectra and elemental analysis.Nylon filaments dyed by the synthesized azo dyestuff with the dye bath pH from 4.14 to 5.88 showed bright yellow color.The performances of the dyestuff were described with dye uptake,color fastness,K/S,L^＊,a^＊,b^＊.and △E^＊ values.展开更多
Novel dyestuff polymers were successfully obtained through oxidative polymerization technique. The synthesized Schiff base and its polymer were soluble in alkaline＇aqueous medium and they have various colors in diffe...Novel dyestuff polymers were successfully obtained through oxidative polymerization technique. The synthesized Schiff base and its polymer were soluble in alkaline＇aqueous medium and they have various colors in different solutions. Also, it can be said that the synthesized compounds are suitable as coloring agent （dyestuff） for textile applications. Fluorescence properties of the compounds were determined in DMF with different concentrations （mg/L）. Poly-tris（4- aminophenyl）methanol （P-TAPM） has quite high emission and excitation intensity values. Optical and electrochemical band gaps of the polymers were lower than those of the monomers indicating the more conjugated structure of the polymers. The oxidized states of the novel dyestuff compounds were examined by cyclic voltammetry （CV） technique. The solid state conductivity measurements showed that the synthesized polymers were semiconductors when exposed to the iodine vapour their conductivities could be increased. P-TAPM had the highest undoped conductivity. Thermal characterizations of the synthesized compounds were carried out by TG-DTA and DSC methods.展开更多
In order to obtain union colour on the blends of Tencel and shrink-proofing wool and improve the efficiency of dyeing process, the dyeing behavior on the blends of Tencel and shrink-proofing wool in the same bath was ...In order to obtain union colour on the blends of Tencel and shrink-proofing wool and improve the efficiency of dyeing process, the dyeing behavior on the blends of Tencel and shrink-proofing wool in the same bath was studied. The Argazol TW reactive dyestuffs were involved in the dyeing process. The parameters under different conditions such as exhaustion, fixation,compatibility as well as soaping fastness were investigated in detail. It is shown that the Argazol TW reactive dyestuffs are suitable for dyeing of blends of Tencel and shrink-proofing wool and good dyeing behavior can be expected.展开更多
In the study, hair colouring by utilising enzymatic oxidation of nine species of bio-catechols, which are biobased materials having the catechol (o-dihydroxybenzene) group, was examined. The bio-catechols used are (+)...In the study, hair colouring by utilising enzymatic oxidation of nine species of bio-catechols, which are biobased materials having the catechol (o-dihydroxybenzene) group, was examined. The bio-catechols used are (+)-catechin (Cat), (-)-epicatechin (EC), L-3,4-dihydroxyphenylalanine (DOPA), hematoxylin (HX), brazilin (BZ), rosmarinic acid (RA), caffeic acid (CA), chlorogenic acid (ChA) or ellagic acid (EA). The dyeability of human white hair samples dyed by two kinds of dyeing methods using the bio-catechols was compared. First one is dyeing hair during the enzymatic oxidation of a bio-catechol dye precursor in a dye solution (simultaneous oxidation dyeing method). Second one is dyeing hair by oxidising enzymatically the precursor on hair, which is pre-treated with a bio-catechol solution (post-oxidation dyeing method). The results show that the bio-catechols except EA are oxidised to give colourants and Cat, EC, DOPA, HX and BZ are available for hair dyeing. Overall, the dyeability of simultaneous oxidation dyeing method is higher than that of post-oxidation one. The colour of the hair dyed by simultaneous method is yellowish brown for Cat or EC, grey for DOPA, dark yellowish brown for HX or reddish brown for BZ, respectively. The most vivid or deepest colour of dyed hair is obtained by dyeing with Cat or HX, respectively, in the simultaneous technique. It was found that the bio-catechols having chroman (3, 4-dihydro-2H-1-benzopyran) structure in the molecule such as Cat, EC, HX and BZ are useful for hair colouring.展开更多
Fabric is a kind of turbid materials with strong light scattering, to which the Kubelka-Munk theory can be applied to describe it optical behavior. In this paper, the light absorption coefficients of dyestuff in fabri...Fabric is a kind of turbid materials with strong light scattering, to which the Kubelka-Munk theory can be applied to describe it optical behavior. In this paper, the light absorption coefficients of dyestuff in fabrics are obtained by test and calculation through a special method proposed by the authors. Then the optical behaviours of dyestuff in fabric are studied. Results show that, the absorption coefficient of dye in fabric is non-scalable and exponential to dye concentration in fabric which is totally different from that of the dye in transparent media like water.展开更多
The paper was monitored the conductivity （g.L＂l of NaCI）, the absorbances values （Abs） and the amount of TOC （total organic carbon）, before and after five consecutive dyeings made with reuse water, obtained fro...The paper was monitored the conductivity （g.L＂l of NaCI）, the absorbances values （Abs） and the amount of TOC （total organic carbon）, before and after five consecutive dyeings made with reuse water, obtained from treated effluent by UV/H202 photocatalysis. All rates of decolorization were above 92%, the removal of total organic carbon was above 89% in all treatments and the economy of NaCI was from 3.10 in the first recipe, 3.17 in the second, 3.49 in the third, 3.79 in the fourth and 4.05 in the fifth recipe. The five dyeings compared with same dyeings made with deionized water presented a color deviation （AE＊） below 1. The conventional dyeings would consume 80 L/kg against 40 L/kg used in the dyeing process proposed in this study, representing a great economy of water, with no discharge of effluents.展开更多
Catechinone hair dyestuff was produced chemically from (+)-catechin by the oxidation with O2 in basic water/alcohol mixed solution. The effects of reaction conditions such as basicity, sorts of added base, temperature...Catechinone hair dyestuff was produced chemically from (+)-catechin by the oxidation with O2 in basic water/alcohol mixed solution. The effects of reaction conditions such as basicity, sorts of added base, temperature, alcohol molar fraction of solvent and sorts of added alcohols on the catechinone formation were studied in order to increase the efficiency of the dyestuff production. The amount of obtained catechinone increases with increasing basicity of the reaction solution. The dyestuff is obtained by adding monoethanol amine, diethanol amine, triethanol amine, l-arginine, Na2CO3, K2CO3, Na3PO4 or NaOH into the solution as a base and the most preferable base is monoethanol amine. The optimum temperature for the production in water/ethanol solution is 30°C. It was found that water-soluble alcohols such as methanol, ethanol, 2-propanol, 1-propanol and tert-butyl alcohol are available for preparing the dyestuff. The optimum alcohol molar fraction of the mixed solvent used for the dye formation is 0.45 for methanol, 0.25 for ethanol and 0.20 for 2-propanol, 0.15 for 1-propanol and 0.10 for tert-butyl alcohol. The amount of the obtained dyestuff reaches a maximum at 1) 0.35 and 0.59, 2) 0.35 or 3) 0.35 mol·kg¨1 of the concentration of (+)-catechin for the 1) water/methanol, 2) water/ethanol or 3) water/1-propanol system, respectively.展开更多
In thousands of years from the Pre-Qin Dynasty to the Qing Dynasty,crimson represents sacredness and good fortune in several dynasties and is honored in the hierarchy of colors.Meanwhile,introduction to the exotic Mat...In thousands of years from the Pre-Qin Dynasty to the Qing Dynasty,crimson represents sacredness and good fortune in several dynasties and is honored in the hierarchy of colors.Meanwhile,introduction to the exotic Materia Medica for dyeing from the Silk Road trade greatly expands the dyeing category of red color.The exotic red dyestuff is eventually integrated into the red culture of the Central Plains through the localization process.Therefore,it becomes the color symbol on behalf of Chinese nation.展开更多
《染料品种大全》(ISBN978-7-5441-7600-2),上、下共两卷,2461页,590万字,刊载了5000多个染料化学结构式,是近期世界上出版的染料化学结构式较多的专著。Monograph“Dyestuffs Varieties”(ISBN 978-7-5441-7600-2),with two volumes,24...《染料品种大全》(ISBN978-7-5441-7600-2),上、下共两卷,2461页,590万字,刊载了5000多个染料化学结构式,是近期世界上出版的染料化学结构式较多的专著。Monograph“Dyestuffs Varieties”(ISBN 978-7-5441-7600-2),with two volumes,2461 pages and 5.9 million words,publishes more than 5000 dye chemical structural formulas,which is the monograph with the largest number of dye structures published in the world recently.展开更多
基金Project supported by the Natural Science Foundation of Shanghai, China(No. 06ZR14002).
文摘Quantitative structure-biodegradability relationships （QSBRs） were established to develop predictive models and mechanistic explanations for acid dyestuffs as well as biological activities. With a total of four descriptors, molecular weight （MW）, energies of the highest occupied molecular orbital （EHOMO）, the lowest unoccupied molecular orbital （ELUMO）, and the excited state （EES）, calculated using quantum chemical semi-empirical methodology, a series of models were analyzed between the dye biodegradability and each descriptor. Results showed that EHOMO and Mw were the dominant parameters controlling the biodegradability of acid dyes. A statistically robust QSBR model was developed for all studied dyes, with the combined application of EHOMO and Mw. The calculated biodegradations fitted well with the experimental data monitored in a facultative-aerobic process, indicative of the reliable prediction and mechanistic character of the developed model.
基金Supported by the National Natural Science Foundation of China and Tsinghua University Foundation.
文摘Two-phase electrophoresis was used to separate the dyestuffs from their dilute solutions. Several dyestuffs (naphthol green B, acid-chrome blue K, methyl blue and direct fast torquoise blue GL, and n-butanol) were treated in a self-designed experimental setup and the mass transfer characteristics in this process were studied. The results confirm the potential of this technique for recovering dyestuffs from their dilute solutions.
文摘Due to the high cost of adsorbents and their thermal regeneration in recent years, much research has fo- cused on the search for cheaper adsorbents for treating wastewater from textile industry. The single component ad-sorption of an acidic dye, Acid Yellow 117, and a basic dye, Methylene Blue, onto several adsoroents-bamooo, waste wood, bamboo char, waste wood char, bamboo activated carbon, wood activated carbon and active carbon F400 were conducted. Based on a Langmuir analysis, the monolayer adsorption capacities were determined. Three of the adsorbents were selected for binary layer adsorption to check the multilayer concept and the potential application for better adsorbent usage. The two cheapest adsorbents, bamboo and wood are compared with the commer-cial activated carbon F400, and all three systems were successful.
基金financially supported by the National High-tech R&D Program of China(863 Program,No.2012AA030313)the Open Project Program of Key Laboratory of Eco-Textiles(Jiangnan University),Ministry of Education,China(No.KLET1115)+1 种基金the Fundamental Research Funds for the Central Universities(No. JUSRP11201)the Cooperative Innovation Fund-Prospective Project of Jiangsu Province,China(No.BY2012060)
文摘This work aimed at effectively utilizing the chemically depolymerized waste poly（ethylene terephthalate）（PET） fibers into useful products for the textile industry.PET fibers were glycolytically degraded by excess ethylene glycol as depolymerizing agent and zinc acetate dihydrate as catalyst.The glycolysis product,bis（2-hydroxyethyl） terephthalate（BHET）,was purified through repeated crystallization to get an average yield above 80%.Then,BHET was nitrated,reduced,and azotized to get diazonium salt.Finally,the produced diazonium salt was coupled with 1-（4-sulfophenyl）-3-methyl-5-pyrazolone to get azo dyestuff.The structures of BHET and azo dyestuff were identified by FT1 R and ^1H NMR spectra and elemental analysis.Nylon filaments dyed by the synthesized azo dyestuff with the dye bath pH from 4.14 to 5.88 showed bright yellow color.The performances of the dyestuff were described with dye uptake,color fastness,K/S,L^＊,a^＊,b^＊.and △E^＊ values.
文摘Novel dyestuff polymers were successfully obtained through oxidative polymerization technique. The synthesized Schiff base and its polymer were soluble in alkaline＇aqueous medium and they have various colors in different solutions. Also, it can be said that the synthesized compounds are suitable as coloring agent （dyestuff） for textile applications. Fluorescence properties of the compounds were determined in DMF with different concentrations （mg/L）. Poly-tris（4- aminophenyl）methanol （P-TAPM） has quite high emission and excitation intensity values. Optical and electrochemical band gaps of the polymers were lower than those of the monomers indicating the more conjugated structure of the polymers. The oxidized states of the novel dyestuff compounds were examined by cyclic voltammetry （CV） technique. The solid state conductivity measurements showed that the synthesized polymers were semiconductors when exposed to the iodine vapour their conductivities could be increased. P-TAPM had the highest undoped conductivity. Thermal characterizations of the synthesized compounds were carried out by TG-DTA and DSC methods.
文摘In order to obtain union colour on the blends of Tencel and shrink-proofing wool and improve the efficiency of dyeing process, the dyeing behavior on the blends of Tencel and shrink-proofing wool in the same bath was studied. The Argazol TW reactive dyestuffs were involved in the dyeing process. The parameters under different conditions such as exhaustion, fixation,compatibility as well as soaping fastness were investigated in detail. It is shown that the Argazol TW reactive dyestuffs are suitable for dyeing of blends of Tencel and shrink-proofing wool and good dyeing behavior can be expected.
文摘In the study, hair colouring by utilising enzymatic oxidation of nine species of bio-catechols, which are biobased materials having the catechol (o-dihydroxybenzene) group, was examined. The bio-catechols used are (+)-catechin (Cat), (-)-epicatechin (EC), L-3,4-dihydroxyphenylalanine (DOPA), hematoxylin (HX), brazilin (BZ), rosmarinic acid (RA), caffeic acid (CA), chlorogenic acid (ChA) or ellagic acid (EA). The dyeability of human white hair samples dyed by two kinds of dyeing methods using the bio-catechols was compared. First one is dyeing hair during the enzymatic oxidation of a bio-catechol dye precursor in a dye solution (simultaneous oxidation dyeing method). Second one is dyeing hair by oxidising enzymatically the precursor on hair, which is pre-treated with a bio-catechol solution (post-oxidation dyeing method). The results show that the bio-catechols except EA are oxidised to give colourants and Cat, EC, DOPA, HX and BZ are available for hair dyeing. Overall, the dyeability of simultaneous oxidation dyeing method is higher than that of post-oxidation one. The colour of the hair dyed by simultaneous method is yellowish brown for Cat or EC, grey for DOPA, dark yellowish brown for HX or reddish brown for BZ, respectively. The most vivid or deepest colour of dyed hair is obtained by dyeing with Cat or HX, respectively, in the simultaneous technique. It was found that the bio-catechols having chroman (3, 4-dihydro-2H-1-benzopyran) structure in the molecule such as Cat, EC, HX and BZ are useful for hair colouring.
基金China Postdoctoral Science Foundation (No.20070410662)
文摘Fabric is a kind of turbid materials with strong light scattering, to which the Kubelka-Munk theory can be applied to describe it optical behavior. In this paper, the light absorption coefficients of dyestuff in fabrics are obtained by test and calculation through a special method proposed by the authors. Then the optical behaviours of dyestuff in fabric are studied. Results show that, the absorption coefficient of dye in fabric is non-scalable and exponential to dye concentration in fabric which is totally different from that of the dye in transparent media like water.
文摘The paper was monitored the conductivity （g.L＂l of NaCI）, the absorbances values （Abs） and the amount of TOC （total organic carbon）, before and after five consecutive dyeings made with reuse water, obtained from treated effluent by UV/H202 photocatalysis. All rates of decolorization were above 92%, the removal of total organic carbon was above 89% in all treatments and the economy of NaCI was from 3.10 in the first recipe, 3.17 in the second, 3.49 in the third, 3.79 in the fourth and 4.05 in the fifth recipe. The five dyeings compared with same dyeings made with deionized water presented a color deviation （AE＊） below 1. The conventional dyeings would consume 80 L/kg against 40 L/kg used in the dyeing process proposed in this study, representing a great economy of water, with no discharge of effluents.
文摘Catechinone hair dyestuff was produced chemically from (+)-catechin by the oxidation with O2 in basic water/alcohol mixed solution. The effects of reaction conditions such as basicity, sorts of added base, temperature, alcohol molar fraction of solvent and sorts of added alcohols on the catechinone formation were studied in order to increase the efficiency of the dyestuff production. The amount of obtained catechinone increases with increasing basicity of the reaction solution. The dyestuff is obtained by adding monoethanol amine, diethanol amine, triethanol amine, l-arginine, Na2CO3, K2CO3, Na3PO4 or NaOH into the solution as a base and the most preferable base is monoethanol amine. The optimum temperature for the production in water/ethanol solution is 30°C. It was found that water-soluble alcohols such as methanol, ethanol, 2-propanol, 1-propanol and tert-butyl alcohol are available for preparing the dyestuff. The optimum alcohol molar fraction of the mixed solvent used for the dye formation is 0.45 for methanol, 0.25 for ethanol and 0.20 for 2-propanol, 0.15 for 1-propanol and 0.10 for tert-butyl alcohol. The amount of the obtained dyestuff reaches a maximum at 1) 0.35 and 0.59, 2) 0.35 or 3) 0.35 mol·kg¨1 of the concentration of (+)-catechin for the 1) water/methanol, 2) water/ethanol or 3) water/1-propanol system, respectively.
文摘In thousands of years from the Pre-Qin Dynasty to the Qing Dynasty,crimson represents sacredness and good fortune in several dynasties and is honored in the hierarchy of colors.Meanwhile,introduction to the exotic Materia Medica for dyeing from the Silk Road trade greatly expands the dyeing category of red color.The exotic red dyestuff is eventually integrated into the red culture of the Central Plains through the localization process.Therefore,it becomes the color symbol on behalf of Chinese nation.
文摘《染料品种大全》(ISBN978-7-5441-7600-2),上、下共两卷,2461页,590万字,刊载了5000多个染料化学结构式,是近期世界上出版的染料化学结构式较多的专著。Monograph“Dyestuffs Varieties”(ISBN 978-7-5441-7600-2),with two volumes,2461 pages and 5.9 million words,publishes more than 5000 dye chemical structural formulas,which is the monograph with the largest number of dye structures published in the world recently.
