Passive-roof duplexes accommodate shortening at the mountain front of many fold-and-thrust belts worldwide.These structures typically manifest at the surface by hinterland-verging backthrusts that decouple thin-skinne...Passive-roof duplexes accommodate shortening at the mountain front of many fold-and-thrust belts worldwide.These structures typically manifest at the surface by hinterland-verging backthrusts that decouple thin-skinned thrust sheets from underlying foreland-verging duplexes.Although the main fac-tors controlling the development of passive-roof duplexes have mostly been identified,some of their intrinsic characteristics are still poorly defined.These relate to their spatio-temporal relationships to thrust faults located further inland in orogens,and their ability to transport younger rocks over older ones.This study explores these issues in the Casentino-Romagna axial sector of the Northern Apennines,which expose regional forethrusts and backthrusts.Detailed field mapping and analysis of superposed tectonic structures were integrated with apatite fission-track dating for constraining the tim-ing of rock exhumation and correlated tectonic events.Collectively,the results have allowed us to inter-pret the evolution of the study area in terms of two main deformation stages.Specifically,a first,long phase(D_(1))progressed from NE-directed,in-sequence thrusting(∼18 to∼10-9 Ma)to late out-of-sequence thrusting(∼8-5 Ma).A successive deformation phase,that we refer to as D_(2)(∼4-2 Ma),con-sisted of backthrusts and associated folds that were ubiquitous and systematically overprinted onto the foreland-verging D_(1)structures.Such retrovergent structures identify a late deformation phase dom-inated by the development of passive-roof duplexes that propagated hinterlandward into the orogen up to beyond the primary watershed ridge.Orogen-scale processes controlled the evolution of forelandward D_(1)-phase thrusts,although late erosion could have played a major role by bringing the Apennine thrust wedge toward an undercritical state.The latter conditions could have contributed to keeping the out-of-sequence thrusts active,and eventually promoted the development of the D_(2)passive-roof duplexes.展开更多
The non-covalent complexes of duplexes DNA and 9 ginsenosides（1 aglycone and 8 glycosides） were investigated using electrospray ionization mass spectrometry（ESI-MS） in the gas phase. The results of relative bindin...The non-covalent complexes of duplexes DNA and 9 ginsenosides（1 aglycone and 8 glycosides） were investigated using electrospray ionization mass spectrometry（ESI-MS） in the gas phase. The results of relative binding affinities in negative ion mode revealed that several factors impact on the duplexbinding properties of ginsenosides. Glycosylations of 20（S）-protopanaxadiol ginsenosides at the position C-20 and 20（S）-protopanaxatriol classification at the position C-6 enhanced the fraction of bound DNA sharply. A rhamnose moiety shows little lower binding intensities than glucose at the same position.Ginsenosides of 20（S）-protopanaxatriol result in subtle higher binding affinities toward the duplex DNA than 20（S）-protopanaxadiol family. However, glycosylation with two sugar moieties does not show a higher binding affinity than with only one moiety. The collision-induced dissociation experimental data demonstrate the gas-phase stability and fragmentation patterns of the ginsenoside/DNA complexes are related to the glycoside number. Positive ion ESI mass spectra of the complexes were also recorded. The result of ESI-MS suggests that hydrogen bonds are the dominate interaction between ginsenosides and DNA. Similar results were obtained in solution-phase by UV spectroscopy, which exhibit a hyperchromism and blue-shift effect when DNA solution was titrated by individual ginsenoside.展开更多
Structure of the duplex consisting of 23 pairs of bases was studied before and after the methylation of two cytosine molecules from different chains of the duplex. The study was performed in a buffer solution using an...Structure of the duplex consisting of 23 pairs of bases was studied before and after the methylation of two cytosine molecules from different chains of the duplex. The study was performed in a buffer solution using an IR Fourier spectrometer. The absorption bands corresponding to the duplex backbone were found to change their characteristics after the methylation. Firstly, the integrated intensity ratio of the absorption bands, S1044/S1085, decreased by a factor of 1.5. The absorption band at 1044 cm-1 corresponds to the COC bond of deoxyribose, and the band at 1085 cm-1 to the PO2symm.vibr bond. Secondly, a substantial shift of the absorption band 1085→1112 cm-1 (Δν = 27 cm-1) was observed. In addition, pronounced changes in the absorption region of CH stretching vibrations took place. In particular, shifting of some absorption bands assigned to the stretching vibrations of CH bonds;the 2979→2945.7 shift was equal to 33.3 cm-1. In addition to the indicated changes, some bands corresponding to the Z structure appeared in the methylated duplex. Thus, methylation of two cytosine molecules in the duplex leads to the order→order structural transition, most likely to the B→Z transition.展开更多
The trade-offbetween strength and ductility remains a persistent obstacle in the development of advanced structural materials.In the present study,a novel dual-heterogeneous structure with a bimodal grain distribution...The trade-offbetween strength and ductility remains a persistent obstacle in the development of advanced structural materials.In the present study,a novel dual-heterogeneous structure with a bimodal grain distribution in both ferrite and austenite phases was fabricated via cold rolling and partial recrystallization annealing on solution-treated 2205 duplex stainless steel(DSS).The processed steel exhibited superior mechanical properties,with the yield strength increasing from 586 MPa to 903 MPa,and the ultimate tensile strength from 796 MPa to 1082 MPa,while maintaining a high total elongation of 35.3%.Based on in-situ electron backscatter diffraction(EBSD)and scanning electron microscope(SEM)analyses,the microstructural deformation behavior and strengthening mechanisms of the dual-heterostructured 2205 DSS were elucidated.The outstanding combination of strength and ductility was ascribed to the synergistic effects of grain refinement,dislocation strengthening,and hetero-deformation induced(HDI)strengthening.Moreover,the high ductility in DSS was attributed to the coactivation of cross-slip systems in ferrite{110}and{112}along with the single-slip systems in austenite{111}.These findings provide a new strategy for the design and development of high-strength and ultra-high-strength DSSs.展开更多
The microstructures and corrosion behavior of 1.0wt%Gd-containing neutron-absorbing duplex stainless steel annealed at different temperatures were studied.Results reveal that the content of Gd-containing secondary pha...The microstructures and corrosion behavior of 1.0wt%Gd-containing neutron-absorbing duplex stainless steel annealed at different temperatures were studied.Results reveal that the content of Gd-containing secondary phase increases with increasing the annealing temperatures to 1080℃,and then decreases.In the sample annealed at 1080℃,M-Gd(M=Fe,Cr,Ni)intermetallic with M_(3)Gd as the core phase and M_(12)Gd as the shell is the primary secondary phase.In the sample annealed at 1140℃,M_(3)Gd phase is dominant.The corrosion behavior of the two annealed steel samples were analyzed in NaCl,HCl and H_(3)BO_(3) solutions.It is found that the sample annealed at 1140℃ has lower corrosion rate.M_(3)Gd is more electrochemically active than M_(12)Gd when the sample is immersed in NaCl and HCl solutions,but more noble in H_(3)BO_(3) solution.展开更多
Super duplex stainless steels(SDSSs)and hyper duplex stainless steels(HDSSs),with more alloying elements content,are more corrosion resistant than the standard grades.Progresses of research works on weldability of SDS...Super duplex stainless steels(SDSSs)and hyper duplex stainless steels(HDSSs),with more alloying elements content,are more corrosion resistant than the standard grades.Progresses of research works on weldability of SDSSs and HDSSs in recent years are reviewed in this paper.If proper heat input is provided,SDSSs and HDSSs can be welded with most fusion welding processes,while tungsten inert gas welding is the most popular process.SDSSs and HDSSs are more prone to secondary phases precipitation than the standard and lean grades,and heat input for SDSSs and HDSSs welding is restricted to a smaller range.Matching filler materials are usually recommended for SDSSs and HDSSs welding,rather than Ni-riched ones for standard and lean grades.Nitrogen addition in shielding gas is always beneficial.Post weld heat treatment with slow cooling rate will be harmful.Hot cracking tendency of SDSSs and HDSSs joints is not high,but sometimes they can suffer from hydrogen induced stress cracking.展开更多
The precipitation behavior,corrosion,and passivation performance of solutionized and severely sensitized SAF 2507 super-duplex stainless steel subjected to a temperature of 900℃for 10 h are investigated in a twofold ...The precipitation behavior,corrosion,and passivation performance of solutionized and severely sensitized SAF 2507 super-duplex stainless steel subjected to a temperature of 900℃for 10 h are investigated in a twofold concentrated seawater at 60℃.The sensitized alloy exhibits 66.1%γphases and 33.9%σphases,and the originalαphases have completely decomposed through eutectoid transformation,resulting in a microstructure characterized by coarse blockyσ/γ2 aggregates.High defect densities and an increased amount of oxyhydroxides and hydroxides are present in the passive film on the sensitized alloy,thereby enhancing n-type semiconducting character.The inferior performance of the passive film on the sensitized alloy is ascribed to the increased potential drop across the film/solution interface,the high defect densities,and the pronounced n-type character of the passive film resulting from the variations in its constituents.The precipitation ofσphase during sensitization significantly increases intergranular corrosion susceptibility and decreases critical pitting temperature,breakdown potential,and polarization resistance in hot concentrated seawater.展开更多
Over the past few years,the Cu element has attracted much attention in duplex stainless steels.It undoubtedly holds advantageous in regulating the two-phase proportion and austenite stability and is also one of the cr...Over the past few years,the Cu element has attracted much attention in duplex stainless steels.It undoubtedly holds advantageous in regulating the two-phase proportion and austenite stability and is also one of the crucial factors affecting the corrosion resistance.However,the systematic research on the impact of Cu addition to lean duplex stainless steels remains insufficient.In this study,a novel Cu-alloyed Mn-N-type 20Cr lean duplex stainless steel was developed and the effect of Cu on the strain hardening capacity and corrosion resistance was analyzed.The results show that the Cu addition increases the volume fraction and stability of the austenite,retards the martensitic transformation,and extends the transformation-induced plasticity effect to a wider strain range.Compared to the Cu-free steel,the plasticity of Cu-containing steel can be increased by~26%.Additionally,the addition of Cu redistributes the Cr and N elements in the ferrite and austenite phases,thereby improving the corrosion resistance of the lean duplex stainless steel.展开更多
Codebooks have been indispensable for wireless communication standard since the first release of the Long-Term Evolution in 2009.They offer an efficient way to acquire the channel state information(CSI)for multiple an...Codebooks have been indispensable for wireless communication standard since the first release of the Long-Term Evolution in 2009.They offer an efficient way to acquire the channel state information(CSI)for multiple antenna systems.Nowadays,a codebook is not limited to a set of pre-defined precoders,it refers to a CSI feedback framework,which is more and more sophisticated.In this paper,we review the codebooks in 5G New Radio(NR)standards.The codebook timeline and the evolution trend are shown.Each codebook is elaborated with its motivation,the corresponding feedback mechanism,and the format of the precoding matrix indicator.Some insights are given to help grasp the underlying reasons and intuitions of these codebooks.Finally,we point out some unresolved challenges of the codebooks for future evolution of the standards.In general,this paper provides a comprehensive review of the codebooks in 5G NR and aims to help researchers understand the CSI feedback schemes from a standard and industrial perspective.展开更多
Traditional metals often exhibit a trade-offbetween strength and plasticity,limiting their wide application of metals in aerospace,transportation,energy industry and other fields[1-3].In order to overcome this dilemma...Traditional metals often exhibit a trade-offbetween strength and plasticity,limiting their wide application of metals in aerospace,transportation,energy industry and other fields[1-3].In order to overcome this dilemma,high-entropy alloys(HEAs),proposed by Yeh et al.and Cantor et al.,are currently of great interest in the materials community due to their excellent mechanical properties[4-7].To further promote the wide application of HEAs in industrial production,Lu et al.developed a new eutectic high-entropy alloy(EHEAs)by combining the potential advantages of traditional eutectic alloys and HEAs[8-11].展开更多
This paper study the finite time internal synchronization and the external synchronization(hybrid synchronization)for duplex heterogeneous complex networks by time-varying intermittent control.There few study hybrid s...This paper study the finite time internal synchronization and the external synchronization(hybrid synchronization)for duplex heterogeneous complex networks by time-varying intermittent control.There few study hybrid synchronization of heterogeneous duplex complex networks.Therefore,we study the finite time hybrid synchronization of heterogeneous duplex networks,which employs the time-varying intermittent control to drive the duplex heterogeneous complex networks to achieve hybrid synchronization in finite time.To be specific,the switch frequency of the controllers can be changed with time by devise Lyapunov function and boundary function,the internal synchronization and external synchronization are achieved simultaneously in finite time.Finally,numerical examples are presented to illustrate the validness of theoretical results.展开更多
The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress ...The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress curves reveal a balance between work hardening and dynamic recovery at the beginning of the deformation and subsequently demonstrate various softening mechanisms with the increase of strain.At high strain rates,dynamic recovery is the prevailing mechanism,whereas,at medium and low strain rates,dynamic recrystallization becomes dominant.The constitutive equation was constructed,and the deformation activation energy was calculated to be 645.46 kJ·mol^(-1).The hot processing map was drawn based on the dynamic material model at a strain of 0.8.The results indicate that the hot workability of 2707 HDSS decreases due to its high alloying content.The microstructure evolution of 2707 HDSS at 1,050℃ was identified by means of electron backscatter diffraction and transmission electron microscopy.The results demonstrate that the ferrite completes dynamic recrystallization at the strain rate of 1 s^(-1).The softening process of austenite is influenced by ferrite and mainly experiences dynamic recovery.The austenite located at the α/γ phase boundaries tends to undergo dynamic recrystallization.展开更多
An alternating magnetic field(AMF)was introduced into the narrow gap laser-arc hybrid welding process for 2205 duplex stainless steel thick plates.The corrosion performance of the welded joints was evaluated through e...An alternating magnetic field(AMF)was introduced into the narrow gap laser-arc hybrid welding process for 2205 duplex stainless steel thick plates.The corrosion performance of the welded joints was evaluated through electrochemical studies.The results revealed that joints welded with the application of AMF had a lower corrosion current density compared to those welded without an external AMF.Additionally,these joints showed higher pitting potential and polarization resistance.Microscopic electrochemical analysis indicated that joints subjected to AMF exhibited minimal cathodic current in simulated seawater,with only slight fluctuations in the anodic current peak.Overall,the corrosion levels on the joint surfaces were relatively low.After 4 h of immersion in the corrosive medium,the average impedance of joints exposed to AMF increased by 60.7%compared to those not influenced by a magnetic field.These findings suggest that applying AMF during the narrow gap laser-arc hybrid welding process can significantly improve the corrosion resistance of duplex stainless steel welded joints,reducing their susceptibility to stress corrosion in seawater-like environments.展开更多
Characteristics of microstructures of electroless Ni-P/Ni-W-P duplex coatings were investigated using SEM/EDX and XRD analysis techniques. Microhardness and wear behaviour of the coatings before and after laser crysta...Characteristics of microstructures of electroless Ni-P/Ni-W-P duplex coatings were investigated using SEM/EDX and XRD analysis techniques. Microhardness and wear behaviour of the coatings before and after laser crystallization were evaluated by measurements of hardnesses of coating surface and cross-section, and by unlubricated friction and wear experiments. The results indicate that it is possible to prepare electroless Ni-P/Ni-W-P duplex coatings by sequential immersion in two different plating baths. After laser crystallization, the microstructures of electroless Ni-P/Ni-W-P duplex coatings present the characteristics of higher degree of crystallization and larger grain size for outer layer Ni-W-P than inner Ni-P, but outer layer has a higher hardness. The wear resistance of laser-treated duplex coatings in a given process parameter conditions is superior to the as-plated ones. Laser treatment was performed directly in air without argon protection, which provides the possibility for application of industrialized production.展开更多
AIM To determine whether serum vascular endothelial growth factor (VEGF) levels correlates with the severity of liver cirrhosis and whether portal hypertension impacts on the expression of serum VEGF protein. METHOD...AIM To determine whether serum vascular endothelial growth factor (VEGF) levels correlates with the severity of liver cirrhosis and whether portal hypertension impacts on the expression of serum VEGF protein. METHODS Fifty three patients (mean age 56±2 years) with HCV ( n =26), HBV ( n =13), and cryptogenic liver cirrhosis ( n =14) (Child Pughs class A: 24, B: 19 and C: 12) and normal renal function constitute the patient population, who were all diagnosed by clinical, histological and radiological findings. Six healthy people and six patients with acute hepatitis served as controls. Severity of liver disease was evaluated by the CP score. Serum levels of IGF 1 and VEGF were measured by radioimmunoassay and ELISA, respectively. Portal hypertension was assessed using pulsed Doppler ultrasound. RESULTS The mean serum VEGF levels in all cirrhotic patients (73±58) were significantly lower than those of healthy controls (360±217, P <0 01) and acute hepatitis (1123±1261, P <0 01) respectively. No significant difference in median serum VEGF levels were noted among the different Child Pughs classes (class A: median, 49 4ng/L , range, 21ng/L - 260ng/L , Class B: median 59 9ng/L ; range 21-92, and Class C: median 69; range 20ng/L - 247ng/L ). A significant correlation was noted between serum VEGF and two accurate parameters of portal hypertension: portal blood flow velocity ( r =0 6) and spleen size ( r =0 55). No correlation was found between VEGF serum levels and serum albumin, IGF 1, platelets count and aminotrasnferases ( r =0 2, r =0 1, r =0 2 and r =0 2, respectively). CONCLUSION Circulating VEGF level in patients with liver cirrhosis could not serve as an indicator of the progression of chronic liver disease but rather, they may reflect increased portal hypertension or decreased hepatic regenerative activity or the combination of both.展开更多
文摘Passive-roof duplexes accommodate shortening at the mountain front of many fold-and-thrust belts worldwide.These structures typically manifest at the surface by hinterland-verging backthrusts that decouple thin-skinned thrust sheets from underlying foreland-verging duplexes.Although the main fac-tors controlling the development of passive-roof duplexes have mostly been identified,some of their intrinsic characteristics are still poorly defined.These relate to their spatio-temporal relationships to thrust faults located further inland in orogens,and their ability to transport younger rocks over older ones.This study explores these issues in the Casentino-Romagna axial sector of the Northern Apennines,which expose regional forethrusts and backthrusts.Detailed field mapping and analysis of superposed tectonic structures were integrated with apatite fission-track dating for constraining the tim-ing of rock exhumation and correlated tectonic events.Collectively,the results have allowed us to inter-pret the evolution of the study area in terms of two main deformation stages.Specifically,a first,long phase(D_(1))progressed from NE-directed,in-sequence thrusting(∼18 to∼10-9 Ma)to late out-of-sequence thrusting(∼8-5 Ma).A successive deformation phase,that we refer to as D_(2)(∼4-2 Ma),con-sisted of backthrusts and associated folds that were ubiquitous and systematically overprinted onto the foreland-verging D_(1)structures.Such retrovergent structures identify a late deformation phase dom-inated by the development of passive-roof duplexes that propagated hinterlandward into the orogen up to beyond the primary watershed ridge.Orogen-scale processes controlled the evolution of forelandward D_(1)-phase thrusts,although late erosion could have played a major role by bringing the Apennine thrust wedge toward an undercritical state.The latter conditions could have contributed to keeping the out-of-sequence thrusts active,and eventually promoted the development of the D_(2)passive-roof duplexes.
基金supported by the National Natural Science Foundation of China (Nos. 21073178 and 21175128)
文摘The non-covalent complexes of duplexes DNA and 9 ginsenosides（1 aglycone and 8 glycosides） were investigated using electrospray ionization mass spectrometry（ESI-MS） in the gas phase. The results of relative binding affinities in negative ion mode revealed that several factors impact on the duplexbinding properties of ginsenosides. Glycosylations of 20（S）-protopanaxadiol ginsenosides at the position C-20 and 20（S）-protopanaxatriol classification at the position C-6 enhanced the fraction of bound DNA sharply. A rhamnose moiety shows little lower binding intensities than glucose at the same position.Ginsenosides of 20（S）-protopanaxatriol result in subtle higher binding affinities toward the duplex DNA than 20（S）-protopanaxadiol family. However, glycosylation with two sugar moieties does not show a higher binding affinity than with only one moiety. The collision-induced dissociation experimental data demonstrate the gas-phase stability and fragmentation patterns of the ginsenoside/DNA complexes are related to the glycoside number. Positive ion ESI mass spectra of the complexes were also recorded. The result of ESI-MS suggests that hydrogen bonds are the dominate interaction between ginsenosides and DNA. Similar results were obtained in solution-phase by UV spectroscopy, which exhibit a hyperchromism and blue-shift effect when DNA solution was titrated by individual ginsenoside.
文摘Structure of the duplex consisting of 23 pairs of bases was studied before and after the methylation of two cytosine molecules from different chains of the duplex. The study was performed in a buffer solution using an IR Fourier spectrometer. The absorption bands corresponding to the duplex backbone were found to change their characteristics after the methylation. Firstly, the integrated intensity ratio of the absorption bands, S1044/S1085, decreased by a factor of 1.5. The absorption band at 1044 cm-1 corresponds to the COC bond of deoxyribose, and the band at 1085 cm-1 to the PO2symm.vibr bond. Secondly, a substantial shift of the absorption band 1085→1112 cm-1 (Δν = 27 cm-1) was observed. In addition, pronounced changes in the absorption region of CH stretching vibrations took place. In particular, shifting of some absorption bands assigned to the stretching vibrations of CH bonds;the 2979→2945.7 shift was equal to 33.3 cm-1. In addition to the indicated changes, some bands corresponding to the Z structure appeared in the methylated duplex. Thus, methylation of two cytosine molecules in the duplex leads to the order→order structural transition, most likely to the B→Z transition.
基金supported by the National Natural Science Foundation of China(Nos.U1960115 and U21A20116)the Fundamental Research Funds for the Central Universities(No.N232405-10)Special thanks are due to the instrumental and data analysis from Analytical and Testing Center,Northeastern University.
文摘The trade-offbetween strength and ductility remains a persistent obstacle in the development of advanced structural materials.In the present study,a novel dual-heterogeneous structure with a bimodal grain distribution in both ferrite and austenite phases was fabricated via cold rolling and partial recrystallization annealing on solution-treated 2205 duplex stainless steel(DSS).The processed steel exhibited superior mechanical properties,with the yield strength increasing from 586 MPa to 903 MPa,and the ultimate tensile strength from 796 MPa to 1082 MPa,while maintaining a high total elongation of 35.3%.Based on in-situ electron backscatter diffraction(EBSD)and scanning electron microscope(SEM)analyses,the microstructural deformation behavior and strengthening mechanisms of the dual-heterostructured 2205 DSS were elucidated.The outstanding combination of strength and ductility was ascribed to the synergistic effects of grain refinement,dislocation strengthening,and hetero-deformation induced(HDI)strengthening.Moreover,the high ductility in DSS was attributed to the coactivation of cross-slip systems in ferrite{110}and{112}along with the single-slip systems in austenite{111}.These findings provide a new strategy for the design and development of high-strength and ultra-high-strength DSSs.
基金Research Foundation of Shenyang National Laboratory for Materials Science(L2019F15)Ling Chuang Research Project of China National Nuclear Corporation(CNNC-LCKY-202279)。
文摘The microstructures and corrosion behavior of 1.0wt%Gd-containing neutron-absorbing duplex stainless steel annealed at different temperatures were studied.Results reveal that the content of Gd-containing secondary phase increases with increasing the annealing temperatures to 1080℃,and then decreases.In the sample annealed at 1080℃,M-Gd(M=Fe,Cr,Ni)intermetallic with M_(3)Gd as the core phase and M_(12)Gd as the shell is the primary secondary phase.In the sample annealed at 1140℃,M_(3)Gd phase is dominant.The corrosion behavior of the two annealed steel samples were analyzed in NaCl,HCl and H_(3)BO_(3) solutions.It is found that the sample annealed at 1140℃ has lower corrosion rate.M_(3)Gd is more electrochemically active than M_(12)Gd when the sample is immersed in NaCl and HCl solutions,but more noble in H_(3)BO_(3) solution.
文摘Super duplex stainless steels(SDSSs)and hyper duplex stainless steels(HDSSs),with more alloying elements content,are more corrosion resistant than the standard grades.Progresses of research works on weldability of SDSSs and HDSSs in recent years are reviewed in this paper.If proper heat input is provided,SDSSs and HDSSs can be welded with most fusion welding processes,while tungsten inert gas welding is the most popular process.SDSSs and HDSSs are more prone to secondary phases precipitation than the standard and lean grades,and heat input for SDSSs and HDSSs welding is restricted to a smaller range.Matching filler materials are usually recommended for SDSSs and HDSSs welding,rather than Ni-riched ones for standard and lean grades.Nitrogen addition in shielding gas is always beneficial.Post weld heat treatment with slow cooling rate will be harmful.Hot cracking tendency of SDSSs and HDSSs joints is not high,but sometimes they can suffer from hydrogen induced stress cracking.
基金the financial support of the National Natural Science Foundation of China(Nos.52375339 and 52305399)the Basic and Applied Basic Research Program of Guangdong Province(No.2021A1515110729).
文摘The precipitation behavior,corrosion,and passivation performance of solutionized and severely sensitized SAF 2507 super-duplex stainless steel subjected to a temperature of 900℃for 10 h are investigated in a twofold concentrated seawater at 60℃.The sensitized alloy exhibits 66.1%γphases and 33.9%σphases,and the originalαphases have completely decomposed through eutectoid transformation,resulting in a microstructure characterized by coarse blockyσ/γ2 aggregates.High defect densities and an increased amount of oxyhydroxides and hydroxides are present in the passive film on the sensitized alloy,thereby enhancing n-type semiconducting character.The inferior performance of the passive film on the sensitized alloy is ascribed to the increased potential drop across the film/solution interface,the high defect densities,and the pronounced n-type character of the passive film resulting from the variations in its constituents.The precipitation ofσphase during sensitization significantly increases intergranular corrosion susceptibility and decreases critical pitting temperature,breakdown potential,and polarization resistance in hot concentrated seawater.
基金supported by the Jilin Scientific and Technological Development Program(No.YDZJ202201ZYTS669)the National Natural Science Foundation of China(Nos.51974032,52174355,51874043 and 51604034).
文摘Over the past few years,the Cu element has attracted much attention in duplex stainless steels.It undoubtedly holds advantageous in regulating the two-phase proportion and austenite stability and is also one of the crucial factors affecting the corrosion resistance.However,the systematic research on the impact of Cu addition to lean duplex stainless steels remains insufficient.In this study,a novel Cu-alloyed Mn-N-type 20Cr lean duplex stainless steel was developed and the effect of Cu on the strain hardening capacity and corrosion resistance was analyzed.The results show that the Cu addition increases the volume fraction and stability of the austenite,retards the martensitic transformation,and extends the transformation-induced plasticity effect to a wider strain range.Compared to the Cu-free steel,the plasticity of Cu-containing steel can be increased by~26%.Additionally,the addition of Cu redistributes the Cr and N elements in the ferrite and austenite phases,thereby improving the corrosion resistance of the lean duplex stainless steel.
基金supported by the Fundamental Research Funds for the Central Universitiesthe National Natural Science Foundation of China under Grant 62071191
文摘Codebooks have been indispensable for wireless communication standard since the first release of the Long-Term Evolution in 2009.They offer an efficient way to acquire the channel state information(CSI)for multiple antenna systems.Nowadays,a codebook is not limited to a set of pre-defined precoders,it refers to a CSI feedback framework,which is more and more sophisticated.In this paper,we review the codebooks in 5G New Radio(NR)standards.The codebook timeline and the evolution trend are shown.Each codebook is elaborated with its motivation,the corresponding feedback mechanism,and the format of the precoding matrix indicator.Some insights are given to help grasp the underlying reasons and intuitions of these codebooks.Finally,we point out some unresolved challenges of the codebooks for future evolution of the standards.In general,this paper provides a comprehensive review of the codebooks in 5G NR and aims to help researchers understand the CSI feedback schemes from a standard and industrial perspective.
基金financial supported by the Natural Science Foundation of Jiangsu Provincial Education Department(No.24KJB430003)the Natural Science Foundation for Young Scholars of Jiangsu Province(No.BK20240979)+3 种基金support of Natural Science Foundation for Young Scholars of Jiangsu Province(No.BK20220628)the National Natural Science Foundation for Young Scholars of China(52301130)the Changzhou Sci&Tech program(No.GJ20220153)support of the Natural Science Foundation of Jiangsu Provincial Education Department(No.21KJB430001).
文摘Traditional metals often exhibit a trade-offbetween strength and plasticity,limiting their wide application of metals in aerospace,transportation,energy industry and other fields[1-3].In order to overcome this dilemma,high-entropy alloys(HEAs),proposed by Yeh et al.and Cantor et al.,are currently of great interest in the materials community due to their excellent mechanical properties[4-7].To further promote the wide application of HEAs in industrial production,Lu et al.developed a new eutectic high-entropy alloy(EHEAs)by combining the potential advantages of traditional eutectic alloys and HEAs[8-11].
基金Project supported by Jilin Provincial Science and Technology Development Plan(Grant No.20220101137JC).
文摘This paper study the finite time internal synchronization and the external synchronization(hybrid synchronization)for duplex heterogeneous complex networks by time-varying intermittent control.There few study hybrid synchronization of heterogeneous duplex complex networks.Therefore,we study the finite time hybrid synchronization of heterogeneous duplex networks,which employs the time-varying intermittent control to drive the duplex heterogeneous complex networks to achieve hybrid synchronization in finite time.To be specific,the switch frequency of the controllers can be changed with time by devise Lyapunov function and boundary function,the internal synchronization and external synchronization are achieved simultaneously in finite time.Finally,numerical examples are presented to illustrate the validness of theoretical results.
基金funded by the Major Science and Technology Program of Luoyang,China(Grant No.2101005A)Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology.
文摘The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress curves reveal a balance between work hardening and dynamic recovery at the beginning of the deformation and subsequently demonstrate various softening mechanisms with the increase of strain.At high strain rates,dynamic recovery is the prevailing mechanism,whereas,at medium and low strain rates,dynamic recrystallization becomes dominant.The constitutive equation was constructed,and the deformation activation energy was calculated to be 645.46 kJ·mol^(-1).The hot processing map was drawn based on the dynamic material model at a strain of 0.8.The results indicate that the hot workability of 2707 HDSS decreases due to its high alloying content.The microstructure evolution of 2707 HDSS at 1,050℃ was identified by means of electron backscatter diffraction and transmission electron microscopy.The results demonstrate that the ferrite completes dynamic recrystallization at the strain rate of 1 s^(-1).The softening process of austenite is influenced by ferrite and mainly experiences dynamic recovery.The austenite located at the α/γ phase boundaries tends to undergo dynamic recrystallization.
基金supported by the National Natural Science Foundation of China(No.52265054)the Inner Mongolia Autonomous Region Natural Science Foundation Project(No.2022ZD03)+3 种基金the Inner Mongolia Autonomous Region Science and Technology Plan Project(No.2020GG0313)the Inner Mongolia Autonomous Region Natural Science Foundation Doctoral Fund Project,(No.2021BS05016)the Construction project of integrated research and development platform for key technologies in the development and processing of new nonferrous metal materials(No.RZ2300001971)the Basic Research Business Fee Project for Autonomous Region Directly Affiliated Universities(Nos.JY20220199 and JY20220028).
文摘An alternating magnetic field(AMF)was introduced into the narrow gap laser-arc hybrid welding process for 2205 duplex stainless steel thick plates.The corrosion performance of the welded joints was evaluated through electrochemical studies.The results revealed that joints welded with the application of AMF had a lower corrosion current density compared to those welded without an external AMF.Additionally,these joints showed higher pitting potential and polarization resistance.Microscopic electrochemical analysis indicated that joints subjected to AMF exhibited minimal cathodic current in simulated seawater,with only slight fluctuations in the anodic current peak.Overall,the corrosion levels on the joint surfaces were relatively low.After 4 h of immersion in the corrosive medium,the average impedance of joints exposed to AMF increased by 60.7%compared to those not influenced by a magnetic field.These findings suggest that applying AMF during the narrow gap laser-arc hybrid welding process can significantly improve the corrosion resistance of duplex stainless steel welded joints,reducing their susceptibility to stress corrosion in seawater-like environments.
基金Project (ZR2011EMM014) supported by the Natural Science Foundation of Shandong Province, China
文摘Characteristics of microstructures of electroless Ni-P/Ni-W-P duplex coatings were investigated using SEM/EDX and XRD analysis techniques. Microhardness and wear behaviour of the coatings before and after laser crystallization were evaluated by measurements of hardnesses of coating surface and cross-section, and by unlubricated friction and wear experiments. The results indicate that it is possible to prepare electroless Ni-P/Ni-W-P duplex coatings by sequential immersion in two different plating baths. After laser crystallization, the microstructures of electroless Ni-P/Ni-W-P duplex coatings present the characteristics of higher degree of crystallization and larger grain size for outer layer Ni-W-P than inner Ni-P, but outer layer has a higher hardness. The wear resistance of laser-treated duplex coatings in a given process parameter conditions is superior to the as-plated ones. Laser treatment was performed directly in air without argon protection, which provides the possibility for application of industrialized production.
文摘AIM To determine whether serum vascular endothelial growth factor (VEGF) levels correlates with the severity of liver cirrhosis and whether portal hypertension impacts on the expression of serum VEGF protein. METHODS Fifty three patients (mean age 56±2 years) with HCV ( n =26), HBV ( n =13), and cryptogenic liver cirrhosis ( n =14) (Child Pughs class A: 24, B: 19 and C: 12) and normal renal function constitute the patient population, who were all diagnosed by clinical, histological and radiological findings. Six healthy people and six patients with acute hepatitis served as controls. Severity of liver disease was evaluated by the CP score. Serum levels of IGF 1 and VEGF were measured by radioimmunoassay and ELISA, respectively. Portal hypertension was assessed using pulsed Doppler ultrasound. RESULTS The mean serum VEGF levels in all cirrhotic patients (73±58) were significantly lower than those of healthy controls (360±217, P <0 01) and acute hepatitis (1123±1261, P <0 01) respectively. No significant difference in median serum VEGF levels were noted among the different Child Pughs classes (class A: median, 49 4ng/L , range, 21ng/L - 260ng/L , Class B: median 59 9ng/L ; range 21-92, and Class C: median 69; range 20ng/L - 247ng/L ). A significant correlation was noted between serum VEGF and two accurate parameters of portal hypertension: portal blood flow velocity ( r =0 6) and spleen size ( r =0 55). No correlation was found between VEGF serum levels and serum albumin, IGF 1, platelets count and aminotrasnferases ( r =0 2, r =0 1, r =0 2 and r =0 2, respectively). CONCLUSION Circulating VEGF level in patients with liver cirrhosis could not serve as an indicator of the progression of chronic liver disease but rather, they may reflect increased portal hypertension or decreased hepatic regenerative activity or the combination of both.
