Despite significant advancements in the power conversion efficiency(PCE)of perovskite/silicon tandem solar cells,improving carrier management in top cells remains challenging due to the defective dual interfaces of wi...Despite significant advancements in the power conversion efficiency(PCE)of perovskite/silicon tandem solar cells,improving carrier management in top cells remains challenging due to the defective dual interfaces of wide-bandgap perovskite,particularly on textured silicon surfaces.Herein,a series of halide ions(Cl^(-),Br^(-),I^(-))substituted piperazinium salts are designed and synthesized as post-treatment modifiers for perovskite surfaces.Notably,piperazinium chloride induces an asymmetric bidirectional ions distribution from the top to the bottom surface,with large piperazinium cations concentrating at the perovskite surface and small chloride anions migrating downward to accumulate at the buried interface.This results in effective dual-interface defect passivation and energy band modulation,enabling wide-bandgap(1.68 eV)perovskite solar cells to achieve a PCE of 22.3%and a record product of open-circuit voltage×fill factor(84.4%relative to the Shockley-Queisser limit).Furthermore,the device retains 91.3%of its initial efficiency after 1200 h of maximum power point tracking without encapsulation.When integrated with double-textured silicon heterojunction solar cells,a remarkable PCE of 31.5%is achieved for a 1.04 cm^(2) monolithic perovskite/silicon tandem solar cell,exhibiting excellent long-term operational stability(T_(80)=755 h)without encapsulation in ambient air.This work provides a convenient strategy on dual-interface engineering for making high-efficiency and stable perovskite platforms.展开更多
This paper reviews the latest advancements in artificial intelligence-assisted R&D project initiation,aiming to provide intelligent solutions for R&D management.It thoroughly examines the value of artificial i...This paper reviews the latest advancements in artificial intelligence-assisted R&D project initiation,aiming to provide intelligent solutions for R&D management.It thoroughly examines the value of artificial intelligence technologies in four core areas:intelligent requirement analysis,technical feasibility assessment,market prospect forecasting,and automated risk identification.Furthermore,it proposes three forward-looking trends—enhanced intelligence,the establishment of industry standards,and deeper human-machine collaboration.These insights are expected to improve project approval success rates and shorten initiation timelines,driving a paradigm shift in R&D management from experience-based to data-driven decision-making.The review highlights how artificial intelligence,through machine learning,natural language processing,and data mining,effectively addresses chronic challenges in traditional initiation processes such as inefficiency,delayed decisions,and resource misallocation.It also identifies critical hurdles,including data quality,model interpretability,and organizational transformation,offering a vital reference framework for the future of intelligent R&D development.展开更多
Back-arc basins are key sites for oceanic lithosphere formation and consumption at convergent plate boundaries,and their formation and subduction processes can be highly variable.The tectonic setting and evolution of ...Back-arc basins are key sites for oceanic lithosphere formation and consumption at convergent plate boundaries,and their formation and subduction processes can be highly variable.The tectonic setting and evolution of the Meso-Tethys Shiquanhe-Jiali ophiolite sub-belt(SJO sub-belt)within BangongNujiang Suture Zone(BNSZ),central xizang,are disputed for the complex rock composition and ages.In this paper,we present geochronology,geochemistry and field observations on the Shiquanhe ophiolite,providing a representative ophiolite example in the western end of SJO.Based on investigation of the petrogenesis and tectonic setting of different rock types,combined with the U-Pb dating,we propose a twostage subduction model for explaining the tectonic evolution of SJO as well as the wither away of a backarc basin.Geochemical and geochronological data indicate that the ca.183 Ma LAN(north of Lameila)gabbros formed in the forearc setting and represent the early-stage subduction of the Bangong MesoTethys.This subduction induced the back-arc spreading recorded in the ca.170 Ma gabbros and lower pillow basalts of PL-SDN(Pagelizanong-Shiquanhe Dam Nan)ophiolitic fragments in the Shiquanhe ophiolite.The basaltic lavas overlying the lower basalts,represented by the ca.168–164 Ma diabasic and boninite dikes have forearc characteristics,and they represent the back-arc basin subduction initiation at a late stage.This work thus recovered the multiple tectonic evolution of SJO sub-belt and emphasise the importance of the back-arc basin subduction in the evolution of ancient oceans.展开更多
The conventional view suggests that the subduction of the South China Sea plate beneath Luzon occurred due to the oceanic lithosphere’s high density,facilitating subduction initiation.However,before the South China S...The conventional view suggests that the subduction of the South China Sea plate beneath Luzon occurred due to the oceanic lithosphere’s high density,facilitating subduction initiation.However,before the South China Sea opened,a continental margin likely existed,meaning that Luzon was directly adjacent to the continental margin rather than the oceanic basin.This would make subduction initiation more challenging.Here,we propose a new model suggesting that during the formation of the South China Sea,extensive mafic magmatic underplating occurred along its continental margin.The high-density magmatic additions may have increased the overall density of the continental margin,potentially exceeding that of Luzon,thereby enabling subduction to proceed.展开更多
Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fa...Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fatigue tests on Ti-6Al-3Nb-2Zr-1Mo alloy with bimodal microstructure to reveal its microstructural characteristics and crack initiation mechanisms.The study demonstrated that the faceted primaryα nodules located near the specimen surface acted as crack initiation sites during both fatigue and dwell fatigue tests.Slip trace analysis revealed that faceted cracking occurred at(0001)basal plane with the maximum Schmid factor value through a special cracking mode referred to as(0001)twist boundary cracking.Innovative criteria of parameters C1 and C2 were proposed based on experimental observation and molecular dynamics simulations,which well identify candidates for(0001)twist boundary crack nucleation.It demonstrated that grain pairs combining a moderately high Schmid factor for basal slip and a well-orientated Burgers vector in the out-of-surface plane was the preferable location for surface(0001)twist-boundary crack initiation,and grain pairs combining a high Schmid factor for basal slip and a high normal stress on basal plane are perfect candidates for subsurface cracking.Based on this,phenomeno-logical models are proposed to explain the surface(0001)twist-boundary cracking mechanism from the perspective of surface extrusion-intrusion-induced micro-notches.展开更多
Rational design of hierarchical structures and a dual-interface built-in electric field(BIEF)are vital for enhancing dielectric loss and directional charge transport in microwave absorption materials(MAMs).Herein,we p...Rational design of hierarchical structures and a dual-interface built-in electric field(BIEF)are vital for enhancing dielectric loss and directional charge transport in microwave absorption materials(MAMs).Herein,we propose a dual-interface BIEF engineering strategy to construct a multifunctional MoS_(2)@C/CoS_(x)composites.Inspired by the spiderweb hunting mechanism,magnetic Co-based Prussian blue(PB)is electro spun with polyacrylonitrile to form Co@CoO/C nanofibers,followed by sulfidation to induce ordered array architectures.The structural evolution enables the formation of heterogeneous MoS_(2)-CoSx-C interfaces and modulates the interfacial electric field intensity to enhance dielectric polarization.Density functional theory(DFT)calculations confirm that the work function difference(ΔΦ)of C/CoS_(2)/MoS_(2) is 6.179 eV,which indicates that the differencesΔΦamong MoS_(2),CoS_(x)and C components drive the spontaneous formation of dual-interface BIEF.This facilitates directional charge migration and strong dipolar/interface polarization,significantly improving the microwave attenuation capability.Benefiting from this design,the composite achieves a minimum reflection loss(RL_(min))of-63.83 dB and a maximum effective absorption bandwidth(EAB_(max))of 6.96 GHz,covering both C and Ku bands.In addition,the material reveals excellent infrared stealth performance due to its unique spiderweb-inspired ordered array structure.This study provides new insights into interfacial electric field modulation and a generalizable approach for designing multi-band and tunable microwave absorbers with synergistic electromagnetic and thermal stealth functions.展开更多
In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated i...In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated in a bimodal Ti-5Al-4 V alloy subjected to low-cycle fatigue and dwell-fatigue loadings at room temperature.The low fraction of primary α grains was not associated with a lack of sensitivity to BTGB cracking.Transmission electron microscopy and electron back-scattered diffraction were used to characterize BTGBs in the initial microstructure.The fatigue mechanisms were then analyzed with a focus on dislocation activity.α_(p) grains adjacent to cracked BTGBs contained a high dislocation density.It was primarily composed of planar slip bands of dislocations.In addition,<c+a>dislocations were noticed in the vicinity of cracked BTGBs.They supposedly pertain to crack tip plasticity during growth,and no evidence of a role of an incoming slip event in crack nucleation was obtained.Also,basal slip bands extending across adjacent grains were found to emerge from BTGBs.This feature provides an easier path for crack extension when growth along the grain boundary becomes difficult owing to a deviation from the basal plane.Atom probe tomography analyses evidenced V and Fe segregation at a grain boundary with a significant deviation from the BTGB configuration.This suggests a possible contribution of local solute segregation to the high cracking resistance of general α_(p)/α_(p) grain boundaries.This work provides new insights into the mechanisms involved in cracking of BTGB in Ti alloys subjected to cyclic loadings.展开更多
Subduction initiation is a critical part of the plate tectonic system,but its geodynamic process is still poorly understood due to the lack of well-preserved geological records.Based on new zircon U–Pb–Hf isotopic a...Subduction initiation is a critical part of the plate tectonic system,but its geodynamic process is still poorly understood due to the lack of well-preserved geological records.Based on new zircon U–Pb–Hf isotopic and whole-rock geochemical data,we report the first discovery of a latest Cambrian–Early Ordovician forearc-arc rock sequence in the Eastern Alps.This sequence includes granitic gneisses,amphibolites,and amphibole plagiogneisses from the ophiolitic Speik Complex and Gleinalpe Complex.These rocks exhibit geochemical affinities with typical oceanic plagiogranites,forearc basalts(FABs),and island arc basalts,respectively.The latest Cambrian plagiogranitic protoliths(491±2 Ma)are shearing-type plagiogranites that were formed in the tectonic setting of forearc spreading.The latest Cambrian FABs(496–489 Ma)have similar geochemical compositions and positiveεHf(t)values(+2.5 to+14.9)to the depleted mid-ocean ridge basalts.However,they show depletion in high field strength elements(HFSEs;e.g.,Nb,Ta,and Zr)and have relatively low Ti/V ratios.These features suggest that they were derived from a depleted mantle source modified by subducting slab-released components in a forearc environment.The Early Ordovician basaltic protoliths(476–472 Ma)of amphibole plagiogneisses show enrichment in large ion lithophile elements and depletion in HFSEs(e.g.Nb,Ta,Zr,and Hf),implying a mature island arc environment.These metaigneous rocks,along with the coeval boninite-like high-Mg amphibolites near the study area,form a typical rock sequence resembling that of the Izu–Bonin–Mariana(IBM)arc system.The Speik and Gleinalpe complexes document a complete magmatic evolution from subduction initiation to mature arc development within the West Proto-Tethys Ocean.Integrating our new data with published work,we reconstruct the late Ediacaran–early Paleozoic tectonic evolution of the northern Gondwana.During the late Ediacaran–early Cambrian,the rollback of the West Proto-Tethys oceanic plate triggered the separation of the Wechsel-Silvretta-Gleinalpe continental arc from the northern Gondwana.This process led to the formation of the Speik back-arc oceanic basin,a southwestern branch of the West Proto-Tethys Ocean.In the latest Cambrian–Early Ordovician,subduction initiation occurred in the Speik Ocean,which subsequently developed into an intra-oceanic arc system.During the Early Devonian,the Speik Ocean closed and the Wechsel-Silvretta-Gleinalpe continental arc reattached to the Gondwana,as evidenced by the metamorphic event at ca.400 Ma.展开更多
The evolution of cracks in shale directly affects the efficient production of shale gas.However,there is a lack of research on the characteristics of crack initiation in deep dense shale under different stress conditi...The evolution of cracks in shale directly affects the efficient production of shale gas.However,there is a lack of research on the characteristics of crack initiation in deep dense shale under different stress conditions.In this work,considering the different combinations of confining pressure and bedding plane inclination angle(α),biaxial mechanical loading experiments were conducted on shale containing circular holes.The research results indicate that the confining pressure and inclination angle of the bedding planes significantly influence the failure patterns of shale containing circular holes.The instability of shale containing circular holes can be classified into five types:tensile failure along the bedding planes,tensile failure through the bedding planes,shear slip along the bedding planes,shear failure through the bedding planes,and block instability failure.Furthermore,the evolution of strain and stress fields around the circular holes was found to be the fundamental cause of variations in the initiation characteristics and locations of shale cracks.The crack initiation criterion for shale containing circular hole was established,providing a new method for evaluating the trajectory of shale hole wall fractures.This study holds significant importance for evaluating the evolution and stability of fracture networks within shale reservoirs.展开更多
Throughout the lifespan,an animal can encounter predators frequently,thus the ability to avoid attacks from predators is crucial for its survival.The chances of evading danger can be greatly improved if the animal can...Throughout the lifespan,an animal can encounter predators frequently,thus the ability to avoid attacks from predators is crucial for its survival.The chances of evading danger can be greatly improved if the animal can respond immediately to the threat.Therefore,when an animal detects a threat through its visual system,it must quickly direct its gaze and attention toward the source of danger,assess the threat level,and take appropriate action.展开更多
Recessive resistance mediated by mutations in the eukaryotic translation initiation factor 4E(eIF4E),has proven effective against diverse potyviruses and is extensively utilized in breeding programs.However,the rise o...Recessive resistance mediated by mutations in the eukaryotic translation initiation factor 4E(eIF4E),has proven effective against diverse potyviruses and is extensively utilized in breeding programs.However,the rise of resistance-breaking(RB)strains and emerging potyviral species necessitates the development of more durable and broad-spectrum resistance strategies.In this study,our field survey in Yunnan,China,identified potato virus Y(PVY)RB isolates,as well as the prevalence of tobacco vein banding mosaic virus(TVBMV)and chilli veinal mottle virus(ChiVMV),in tobacco carrying the recessive va locus,which lacks the eIF4E1-S susceptibility gene,due to a chromosomal deletion.Protein interaction and viral infection assays demonstrated that both eIF4E1-S and eIFiso4E-T are used by PVY RB as susceptibility factors for infection,with the combined inactivation of these genes confering durable resistance.Similarly,the knockout of eIFiso4E-S,in the va genetic background,provided effective resistance to TVBMV and reduced susceptibility to ChiVMV.Notably,pyramiding mutations in eIFiso4E-S and eIFiso4E-T,in va tobacco,generated plants exhibiting robust,broad-spectrum resistance,to all three viruses,without compromising plant development.These findings underscore the potential of stacking eIF4E mutations to engineer durable,broad-spectrum resistance to potyviruses in tobacco,offering a promising strategy for crop improvement.展开更多
Hydrogen has emerged as a promising clean energy source,leading to numerous recent efforts to integrate hydrogen into turbine engine applications[1].This integration has the potential to significantly enhance engine e...Hydrogen has emerged as a promising clean energy source,leading to numerous recent efforts to integrate hydrogen into turbine engine applications[1].This integration has the potential to significantly enhance engine efficiency while reducing carbon dioxide emissions[2].However,the degradation of nickel alloys induced by hydrogen has been well documented[3-7].Consequently,hydrogen-assisted failure of nickel alloys poses a critical concern for the design and safe operation of hydrogen-powered turbine engines.展开更多
To study the effects of the initiation position on the damage and fracture characteristics of linear-charge blasting, blasting model experiments were conducted in this study using computed tomography scanning and thre...To study the effects of the initiation position on the damage and fracture characteristics of linear-charge blasting, blasting model experiments were conducted in this study using computed tomography scanning and three-dimensional reconstruction methods. The fractal damage theory was used to quantify the crack distribution and damage degree of sandstone specimens after blasting. The results showed that regardless of an inverse or top initiation, due to compression deformation and sliding frictional resistance, the plugging medium of the borehole is effective. The energy of the explosive gas near the top of the borehole is consumed. This affects the effective crushing of rocks near the top of the borehole, where the extent of damage to Sections Ⅰ and Ⅱ is less than that of Sections Ⅲ and Ⅳ. In addition, the analysis revealed that under conditions of top initiation, the reflected tensile damage of the rock at the free face of the top of the borehole and the compression deformation of the plug and friction consume more blasting energy, resulting in lower blasting energy efficiency for top initiation. As a result, the overall damage degree of the specimens in the top-initiation group was significantly smaller than that in the inverse-initiation group. Under conditions of inverse initiation, the blasting energy efficiency is greater, causing the specimen to experience greater damage. Therefore, in the engineering practice of rock tunnel cut blasting, to utilize blasting energy effectively and enhance the effects of rock fragmentation, using the inverse-initiation method is recommended. In addition, in three-dimensional(3D) rock blasting, the bottom of the borehole has obvious end effects under the conditions of inverse initiation, and the crack distribution at the bottom of the borehole is trumpet-shaped. The occurrence of an end effect in the 3D linear-charge blasting model experiment is related to the initiation position and the blocking condition.展开更多
Water freezing in rock fractures causes volumetric expansion and fracture development through frost heaving.This study introduces a novel analytical model to investigate how uneven freezing force and surrounding rock ...Water freezing in rock fractures causes volumetric expansion and fracture development through frost heaving.This study introduces a novel analytical model to investigate how uneven freezing force and surrounding rock pressure influence fracture initiation,based on mass conservation,elasticity,and water-ice phase transition principles.A model for rock fracture initiation considering freezing temperature,uneven freezing expansion,in-situ stress,and lateral pressure was proposed based on fracture mechanics.Equations for stress intensity factors were developed and validated using the phase field method.The effects of rock elastic modulus anisotropy and critical fracture energy density on fracture initiation were also discussed.The results show that the values of KI and KII exhibit an upward trend as the freezing temperature,uneven expansion,in-situ stress,and lateral pressure increase.The uneven freezing expansion has the most significant influence on KI and KII values among these parameters.As the uneven freezing expansion coefficient increases to 0.5,the fracture initiation mode shifts from tensile fracture to shear fracture.As the lateral pressure coefficient increases to 1,the fracture initiation mode shifts from tensile fracture to shear fracture.Rock elastic modulus anisotropy causes fractures to propagate in a clockwise direction,forming a'butterfly'pattern.Critical fracture energy density an isotropy causes counterclockwise deviation in propagation direction,resulting in branching paths and an'H'-shaped pattern.展开更多
Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresea...Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresearch introduces a computational model designed to predict the lifespan of corrosion initiation in reinforced concretesquare piles when applied reverse-seepage pressure.The model considers the impacts of chloride binding and the tripletime-dependence property among the permeability,the corrected surface chloride concentration,and the diffusioncoefficient.The proposed numerical model is solved using the alternating direction implicit(ADI)approach,and itsaccuracy and reliability are evaluated by contrasting the computational outcomes with the analytical solution andexperimental results.Furthermore,the primary factors contributing to the corrosion of reinforced concrete square pilesare analyzed.The results indicate that applying RST can decrease the chloride penetration depth and prolong the lifespanof corrosion initiation in square piles.The water-cement ratio and reverse seepage pressure are the most influentialfactors.A water pressure of 0.4 MPa can double the life of concrete,and the durable life of concrete with a water-cementratio of 0.3 can reach 100 years.展开更多
Introduction: Actors of psychoactive drug initiation refer to those who introduce others to psychoactive drug use (initiators) and those who are introduced to psychoactive drugs (users). By identifying their features,...Introduction: Actors of psychoactive drug initiation refer to those who introduce others to psychoactive drug use (initiators) and those who are introduced to psychoactive drugs (users). By identifying their features, better prevention and intervention programs can be developed to reduce psychoactive drug use among adolescents. This article describes the role of actors of psychoactive drug initiation among teenagers in secondary schools in Yaoundé (Cameroon). Methodology: A cross sectional study was carried out in twelve secondary schools in Yaoundé from October 2022 to May 2023. Adolescents from Form four to upper sixth, who assented to participate in the study and received parental consent were included. Data were collected in a structured self-reported questionnaire and analyzed using SPSS 23. Quantitative variables were expressed using means, standard deviations, median and interquartile ranges depending on the distribution of data. Qualitative variables were expressed in the form of frequency and percentages. Results: Drug use was more prevalent among male adolescents (55.3%) from nuclear families (91.4%) who received relatively high pocket money. The main sources of drug exposure were non-family members (49.7%), especially friends outside school. The most frequent place of initiation was snack bars (33.1%). Conclusion: The study revealed the importance of the family, friends and leisure places in the initiation process of drug use in teenagers. Based on these results, parents and school authorities should work together to create a safe and supportive environment that fosters communication, education to prevent drug abuse among adolescents in Yaoundé.展开更多
A debris flow,with terraced fields as the source area,broke out on June 25th,2018 in the Xiaotuga area of Yunnan Province,China,and this kind of debris flow is rarely recorded.Two purposes in this study:(1)the influen...A debris flow,with terraced fields as the source area,broke out on June 25th,2018 in the Xiaotuga area of Yunnan Province,China,and this kind of debris flow is rarely recorded.Two purposes in this study:(1)the influence of flow drag force on slope stability;(2)back-analyze the movement process of debris flow.First,the geological background and movement of this debris flow were described based on a field investigation.Then,drag force,calculated by the laminar flow theory,is added to the slope stability calculation model,which elaborates the initiation process of this disaster.Moreover,dynamic simulation software(DAN3D)was used to simulate the kinematic process of the debris flow with a variety of combination models.The study shows that the terrace area can quickly produce surface runoff and create a drag force under rainfall conditions,which is the essential reason for the initiation of debris flow.In addition,the use of the FVV(Frictional-Voellmy-Voellmy)model is found to provide the best performance in simulating this type of debris flow,which reveals that it lasts approximately 200 s and that the maximum velocity is 12 m/s.展开更多
Low-cycle fatigue crack initiation behavior of nickel-based single crystal superalloy at 530℃ was investigated.Results show that the behavior of crack initiation is closely related to the maximum strain.When the maxi...Low-cycle fatigue crack initiation behavior of nickel-based single crystal superalloy at 530℃ was investigated.Results show that the behavior of crack initiation is closely related to the maximum strain.When the maximum strain is 2.0%,the fatigue crack is originated at the position of persistent slip bands on the surface of specimen,which is located on the{111}slip plane.No defects are observed at the crack initiation position.When the maximum strain is lower than 1.6%,the cracks are initiated at the casting defects on sub-surface or at interior of the specimen.The casting defects are located on the{100}slip plane vertical to the axial force.The crack is initiated along the{100}slip plane and then expanded along different{111}slip planes after a short stage of expansion.As the maximum strain decreases,the position of crack initiation gradually changes from the surface to the interior.Moreover,the secondary cracks extending inward along the fracture surface appear in the crack initiation area,and there is obvious stress concentration near the secondary cracks.The dislocation density is high near the fracture surface in the crack initiation zone,where a lot of dislocations cutting into the γ'phase exist.An oxide layer of 50‒100 nm is presented on the fracture surface,and Ni,Al,Cr and Co elements are mainly segregated into the oxide layer of the surface.展开更多
Discontinuously reinforced titanium matrix composites(DRTMCs)with a network structure have been extensively researched due to their superior combination of strength and ductility.However,their fatigue performance has ...Discontinuously reinforced titanium matrix composites(DRTMCs)with a network structure have been extensively researched due to their superior combination of strength and ductility.However,their fatigue performance has remained unknown.In order to elucidate the fatigue behavior of DRTMCs,a tension-tension fatigue test was performed on a TiB/nearα-Ti composite with network structure.The results showed that the variability of fatigue lifetime increased as the stress level decreased.Fractography analysis indicated that fatigue crack initiation was associated with facet formation,while the subsequent propagation was hindered by the network structure comprising TiB whiskers and silicides.Crystallographic characterization further revealed that facets formed due to a combination of shear and normal stress.The reduction in fatigue lifetime was attributed to an increase in the effective slip length,which was influenced by the orientation of grains near the crack-initiation sites toward basal slip in the life-limiting specimen.Quasi in situ observation suggested that the crack initiation was facilitated by both basal and prismatic slip ofα-Ti as well as fracture of TiBw.Crack propagation was found to be associated with basal and prismatic slip systems with high Schmid factors,regardless of whether the crack was intergranular or intragranular.展开更多
Fatigue failure can still occur beyond 107 cycles,i.e.very-high-cycle fatigue(VHCF),in many metallic materials,such as aluminium alloys and high-strength steels.For VHCF of high-strength steels,a fine granular area(FG...Fatigue failure can still occur beyond 107 cycles,i.e.very-high-cycle fatigue(VHCF),in many metallic materials,such as aluminium alloys and high-strength steels.For VHCF of high-strength steels,a fine granular area(FGA)surrounding an inclusion is commonly identified as the characteristic region of crack initiation on the fracture surface.However,no such FGA feature and related crack initiation behaviour were observed in VHCF of conventionally cast or wrought aluminium alloys.Here,we first reported the distinct mechanisms of crack initiation and early growth,namely the microstructure feature and the role of FGA in VHCF performance for an additively manufactured(AM)AlSi10Mg alloy.The AM pores play a key role in fatigue crack initiation similar to that of the inclusions in high-strength steels,resulting in almost identical FGA behaviour for different materials under a range of mean stress with a stress ratio at R<0 or R>0.The profile microstructure of FGA is identified as a nanograin layer with Si rearrangement and grain boundary transition.This process consumes a large amount of cyclic plastic energy making FGA undertake a vast majority of VHCF life.These results will deepen the understanding of VHCF nature and shed light on crack initiation mechanism of other aluminium and AM alloys.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.62204245,U23A200098)Baima Lake Laboratory Joint Funds of the Zhejiang Provincial Natural Science Foundation of China(Grant No.LBMHD24E020002)+4 种基金Key Research and Development Program of Zhejiang Province(Grant No.2022C01215,2024C01092)China Postdoctoral Science Foundation(Grant No.2023M743620,2024T170960)Key Research and Development Program of Ningbo(Grant No.2023Z151)National Key Research and Development Program of China(Grant No.2024YFB3817304)Zhejiang Provincial Natural Science Foundation of China(Grant No.LY24F040003).
文摘Despite significant advancements in the power conversion efficiency(PCE)of perovskite/silicon tandem solar cells,improving carrier management in top cells remains challenging due to the defective dual interfaces of wide-bandgap perovskite,particularly on textured silicon surfaces.Herein,a series of halide ions(Cl^(-),Br^(-),I^(-))substituted piperazinium salts are designed and synthesized as post-treatment modifiers for perovskite surfaces.Notably,piperazinium chloride induces an asymmetric bidirectional ions distribution from the top to the bottom surface,with large piperazinium cations concentrating at the perovskite surface and small chloride anions migrating downward to accumulate at the buried interface.This results in effective dual-interface defect passivation and energy band modulation,enabling wide-bandgap(1.68 eV)perovskite solar cells to achieve a PCE of 22.3%and a record product of open-circuit voltage×fill factor(84.4%relative to the Shockley-Queisser limit).Furthermore,the device retains 91.3%of its initial efficiency after 1200 h of maximum power point tracking without encapsulation.When integrated with double-textured silicon heterojunction solar cells,a remarkable PCE of 31.5%is achieved for a 1.04 cm^(2) monolithic perovskite/silicon tandem solar cell,exhibiting excellent long-term operational stability(T_(80)=755 h)without encapsulation in ambient air.This work provides a convenient strategy on dual-interface engineering for making high-efficiency and stable perovskite platforms.
文摘This paper reviews the latest advancements in artificial intelligence-assisted R&D project initiation,aiming to provide intelligent solutions for R&D management.It thoroughly examines the value of artificial intelligence technologies in four core areas:intelligent requirement analysis,technical feasibility assessment,market prospect forecasting,and automated risk identification.Furthermore,it proposes three forward-looking trends—enhanced intelligence,the establishment of industry standards,and deeper human-machine collaboration.These insights are expected to improve project approval success rates and shorten initiation timelines,driving a paradigm shift in R&D management from experience-based to data-driven decision-making.The review highlights how artificial intelligence,through machine learning,natural language processing,and data mining,effectively addresses chronic challenges in traditional initiation processes such as inefficiency,delayed decisions,and resource misallocation.It also identifies critical hurdles,including data quality,model interpretability,and organizational transformation,offering a vital reference framework for the future of intelligent R&D development.
基金supported by the Guangdong Basic and Applied Basic Research Foundation,China(Grant Nos.2024A1515010439,2025A1515010724)National Nature Science Foundation of China(Grant Nos.41972049,41472054,42072229,41977231)+4 种基金Young Innovative Talent Project of Department of Education of Guangdong Province(Natural ScienceGrant No.2022KQNCX184)Natural Research Project of Guangdong Polytechnic of Industry&Commerce(Grant No.2022-ZKT-01)China State Scholarship Fund of visiting scholar(Grant No.20170638507)High-level Talent Special Support Program of Guangdong Polytechnic of Industry&Commerce(Grant No.2023-gc-03).
文摘Back-arc basins are key sites for oceanic lithosphere formation and consumption at convergent plate boundaries,and their formation and subduction processes can be highly variable.The tectonic setting and evolution of the Meso-Tethys Shiquanhe-Jiali ophiolite sub-belt(SJO sub-belt)within BangongNujiang Suture Zone(BNSZ),central xizang,are disputed for the complex rock composition and ages.In this paper,we present geochronology,geochemistry and field observations on the Shiquanhe ophiolite,providing a representative ophiolite example in the western end of SJO.Based on investigation of the petrogenesis and tectonic setting of different rock types,combined with the U-Pb dating,we propose a twostage subduction model for explaining the tectonic evolution of SJO as well as the wither away of a backarc basin.Geochemical and geochronological data indicate that the ca.183 Ma LAN(north of Lameila)gabbros formed in the forearc setting and represent the early-stage subduction of the Bangong MesoTethys.This subduction induced the back-arc spreading recorded in the ca.170 Ma gabbros and lower pillow basalts of PL-SDN(Pagelizanong-Shiquanhe Dam Nan)ophiolitic fragments in the Shiquanhe ophiolite.The basaltic lavas overlying the lower basalts,represented by the ca.168–164 Ma diabasic and boninite dikes have forearc characteristics,and they represent the back-arc basin subduction initiation at a late stage.This work thus recovered the multiple tectonic evolution of SJO sub-belt and emphasise the importance of the back-arc basin subduction in the evolution of ancient oceans.
基金support from the National Natural Science Foundation of China (Grant No. 42276049)。
文摘The conventional view suggests that the subduction of the South China Sea plate beneath Luzon occurred due to the oceanic lithosphere’s high density,facilitating subduction initiation.However,before the South China Sea opened,a continental margin likely existed,meaning that Luzon was directly adjacent to the continental margin rather than the oceanic basin.This would make subduction initiation more challenging.Here,we propose a new model suggesting that during the formation of the South China Sea,extensive mafic magmatic underplating occurred along its continental margin.The high-density magmatic additions may have increased the overall density of the continental margin,potentially exceeding that of Luzon,thereby enabling subduction to proceed.
基金supported by the National Natural Science Foundation of China(Nos.52074231,52274396 and 52001258)the Chongqing Natural Science Foundation(No.cstc2020jcyj-msxmX1056).
文摘Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fatigue tests on Ti-6Al-3Nb-2Zr-1Mo alloy with bimodal microstructure to reveal its microstructural characteristics and crack initiation mechanisms.The study demonstrated that the faceted primaryα nodules located near the specimen surface acted as crack initiation sites during both fatigue and dwell fatigue tests.Slip trace analysis revealed that faceted cracking occurred at(0001)basal plane with the maximum Schmid factor value through a special cracking mode referred to as(0001)twist boundary cracking.Innovative criteria of parameters C1 and C2 were proposed based on experimental observation and molecular dynamics simulations,which well identify candidates for(0001)twist boundary crack nucleation.It demonstrated that grain pairs combining a moderately high Schmid factor for basal slip and a well-orientated Burgers vector in the out-of-surface plane was the preferable location for surface(0001)twist-boundary crack initiation,and grain pairs combining a high Schmid factor for basal slip and a high normal stress on basal plane are perfect candidates for subsurface cracking.Based on this,phenomeno-logical models are proposed to explain the surface(0001)twist-boundary cracking mechanism from the perspective of surface extrusion-intrusion-induced micro-notches.
基金supported by the National Natural Science Foundation of China(No.52462026)Postdoctoral Research Foundation of China(No.2018M643699)Shaanxi Province Postdoctoral Science Foundation(No.2018BSHEDZZ 101).
文摘Rational design of hierarchical structures and a dual-interface built-in electric field(BIEF)are vital for enhancing dielectric loss and directional charge transport in microwave absorption materials(MAMs).Herein,we propose a dual-interface BIEF engineering strategy to construct a multifunctional MoS_(2)@C/CoS_(x)composites.Inspired by the spiderweb hunting mechanism,magnetic Co-based Prussian blue(PB)is electro spun with polyacrylonitrile to form Co@CoO/C nanofibers,followed by sulfidation to induce ordered array architectures.The structural evolution enables the formation of heterogeneous MoS_(2)-CoSx-C interfaces and modulates the interfacial electric field intensity to enhance dielectric polarization.Density functional theory(DFT)calculations confirm that the work function difference(ΔΦ)of C/CoS_(2)/MoS_(2) is 6.179 eV,which indicates that the differencesΔΦamong MoS_(2),CoS_(x)and C components drive the spontaneous formation of dual-interface BIEF.This facilitates directional charge migration and strong dipolar/interface polarization,significantly improving the microwave attenuation capability.Benefiting from this design,the composite achieves a minimum reflection loss(RL_(min))of-63.83 dB and a maximum effective absorption bandwidth(EAB_(max))of 6.96 GHz,covering both C and Ku bands.In addition,the material reveals excellent infrared stealth performance due to its unique spiderweb-inspired ordered array structure.This study provides new insights into interfacial electric field modulation and a generalizable approach for designing multi-band and tunable microwave absorbers with synergistic electromagnetic and thermal stealth functions.
基金financially supported by the National Natural Science Foundation of China(No.U21A2050)support of the Chinese Scholarship Council(No.202006290165).
文摘In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated in a bimodal Ti-5Al-4 V alloy subjected to low-cycle fatigue and dwell-fatigue loadings at room temperature.The low fraction of primary α grains was not associated with a lack of sensitivity to BTGB cracking.Transmission electron microscopy and electron back-scattered diffraction were used to characterize BTGBs in the initial microstructure.The fatigue mechanisms were then analyzed with a focus on dislocation activity.α_(p) grains adjacent to cracked BTGBs contained a high dislocation density.It was primarily composed of planar slip bands of dislocations.In addition,<c+a>dislocations were noticed in the vicinity of cracked BTGBs.They supposedly pertain to crack tip plasticity during growth,and no evidence of a role of an incoming slip event in crack nucleation was obtained.Also,basal slip bands extending across adjacent grains were found to emerge from BTGBs.This feature provides an easier path for crack extension when growth along the grain boundary becomes difficult owing to a deviation from the basal plane.Atom probe tomography analyses evidenced V and Fe segregation at a grain boundary with a significant deviation from the BTGB configuration.This suggests a possible contribution of local solute segregation to the high cracking resistance of general α_(p)/α_(p) grain boundaries.This work provides new insights into the mechanisms involved in cracking of BTGB in Ti alloys subjected to cyclic loadings.
基金supported by the National Natural Science Foundation of China(Grant Nos.42272244 and 91755212)Taishan Scholars(Grant No.ts20190918).
文摘Subduction initiation is a critical part of the plate tectonic system,but its geodynamic process is still poorly understood due to the lack of well-preserved geological records.Based on new zircon U–Pb–Hf isotopic and whole-rock geochemical data,we report the first discovery of a latest Cambrian–Early Ordovician forearc-arc rock sequence in the Eastern Alps.This sequence includes granitic gneisses,amphibolites,and amphibole plagiogneisses from the ophiolitic Speik Complex and Gleinalpe Complex.These rocks exhibit geochemical affinities with typical oceanic plagiogranites,forearc basalts(FABs),and island arc basalts,respectively.The latest Cambrian plagiogranitic protoliths(491±2 Ma)are shearing-type plagiogranites that were formed in the tectonic setting of forearc spreading.The latest Cambrian FABs(496–489 Ma)have similar geochemical compositions and positiveεHf(t)values(+2.5 to+14.9)to the depleted mid-ocean ridge basalts.However,they show depletion in high field strength elements(HFSEs;e.g.,Nb,Ta,and Zr)and have relatively low Ti/V ratios.These features suggest that they were derived from a depleted mantle source modified by subducting slab-released components in a forearc environment.The Early Ordovician basaltic protoliths(476–472 Ma)of amphibole plagiogneisses show enrichment in large ion lithophile elements and depletion in HFSEs(e.g.Nb,Ta,Zr,and Hf),implying a mature island arc environment.These metaigneous rocks,along with the coeval boninite-like high-Mg amphibolites near the study area,form a typical rock sequence resembling that of the Izu–Bonin–Mariana(IBM)arc system.The Speik and Gleinalpe complexes document a complete magmatic evolution from subduction initiation to mature arc development within the West Proto-Tethys Ocean.Integrating our new data with published work,we reconstruct the late Ediacaran–early Paleozoic tectonic evolution of the northern Gondwana.During the late Ediacaran–early Cambrian,the rollback of the West Proto-Tethys oceanic plate triggered the separation of the Wechsel-Silvretta-Gleinalpe continental arc from the northern Gondwana.This process led to the formation of the Speik back-arc oceanic basin,a southwestern branch of the West Proto-Tethys Ocean.In the latest Cambrian–Early Ordovician,subduction initiation occurred in the Speik Ocean,which subsequently developed into an intra-oceanic arc system.During the Early Devonian,the Speik Ocean closed and the Wechsel-Silvretta-Gleinalpe continental arc reattached to the Gondwana,as evidenced by the metamorphic event at ca.400 Ma.
基金Projects(52104143,52109135,52374099)supported by the National Natural Science Foundation of ChinaProject(2025YFHZ0323)supported by the Natural Science Foundation of Sichuan Province,China。
文摘The evolution of cracks in shale directly affects the efficient production of shale gas.However,there is a lack of research on the characteristics of crack initiation in deep dense shale under different stress conditions.In this work,considering the different combinations of confining pressure and bedding plane inclination angle(α),biaxial mechanical loading experiments were conducted on shale containing circular holes.The research results indicate that the confining pressure and inclination angle of the bedding planes significantly influence the failure patterns of shale containing circular holes.The instability of shale containing circular holes can be classified into five types:tensile failure along the bedding planes,tensile failure through the bedding planes,shear slip along the bedding planes,shear failure through the bedding planes,and block instability failure.Furthermore,the evolution of strain and stress fields around the circular holes was found to be the fundamental cause of variations in the initiation characteristics and locations of shale cracks.The crack initiation criterion for shale containing circular hole was established,providing a new method for evaluating the trajectory of shale hole wall fractures.This study holds significant importance for evaluating the evolution and stability of fracture networks within shale reservoirs.
基金supported by the National Natural Science Foundation of China(32471055 and 82171090)Shanghai Municipal Science and Technology Major Project(2018SHZDZX01)ZJLab,Shanghai Center for Brain Science and Brain-Inspired Technology,the Lingang Laboratory(LG-QS-202203-12).
文摘Throughout the lifespan,an animal can encounter predators frequently,thus the ability to avoid attacks from predators is crucial for its survival.The chances of evading danger can be greatly improved if the animal can respond immediately to the threat.Therefore,when an animal detects a threat through its visual system,it must quickly direct its gaze and attention toward the source of danger,assess the threat level,and take appropriate action.
基金supported by National Natural Science Foundation of China(31860490)YNTC funds(2023530000241007 and 2017YN02)+1 种基金Yunnan Daguan Lab(YNDG202302ZY01)CLZ is supported by the Postdoctoral Fellowship Program of CPSF under grant number GZC20241527。
文摘Recessive resistance mediated by mutations in the eukaryotic translation initiation factor 4E(eIF4E),has proven effective against diverse potyviruses and is extensively utilized in breeding programs.However,the rise of resistance-breaking(RB)strains and emerging potyviral species necessitates the development of more durable and broad-spectrum resistance strategies.In this study,our field survey in Yunnan,China,identified potato virus Y(PVY)RB isolates,as well as the prevalence of tobacco vein banding mosaic virus(TVBMV)and chilli veinal mottle virus(ChiVMV),in tobacco carrying the recessive va locus,which lacks the eIF4E1-S susceptibility gene,due to a chromosomal deletion.Protein interaction and viral infection assays demonstrated that both eIF4E1-S and eIFiso4E-T are used by PVY RB as susceptibility factors for infection,with the combined inactivation of these genes confering durable resistance.Similarly,the knockout of eIFiso4E-S,in the va genetic background,provided effective resistance to TVBMV and reduced susceptibility to ChiVMV.Notably,pyramiding mutations in eIFiso4E-S and eIFiso4E-T,in va tobacco,generated plants exhibiting robust,broad-spectrum resistance,to all three viruses,without compromising plant development.These findings underscore the potential of stacking eIF4E mutations to engineer durable,broad-spectrum resistance to potyviruses in tobacco,offering a promising strategy for crop improvement.
基金supported by the Science Center for Gas Turbine Project(No.P2022-B-IV-009-002).
文摘Hydrogen has emerged as a promising clean energy source,leading to numerous recent efforts to integrate hydrogen into turbine engine applications[1].This integration has the potential to significantly enhance engine efficiency while reducing carbon dioxide emissions[2].However,the degradation of nickel alloys induced by hydrogen has been well documented[3-7].Consequently,hydrogen-assisted failure of nickel alloys poses a critical concern for the design and safe operation of hydrogen-powered turbine engines.
基金supported by the National Natural Science Foundation of China (No.52204085)the Interdisciplinary Research Project for Young Teachers of USTB,Fundamental Research Funds for the Central Universities (No.FRF-IDRY-21-006).
文摘To study the effects of the initiation position on the damage and fracture characteristics of linear-charge blasting, blasting model experiments were conducted in this study using computed tomography scanning and three-dimensional reconstruction methods. The fractal damage theory was used to quantify the crack distribution and damage degree of sandstone specimens after blasting. The results showed that regardless of an inverse or top initiation, due to compression deformation and sliding frictional resistance, the plugging medium of the borehole is effective. The energy of the explosive gas near the top of the borehole is consumed. This affects the effective crushing of rocks near the top of the borehole, where the extent of damage to Sections Ⅰ and Ⅱ is less than that of Sections Ⅲ and Ⅳ. In addition, the analysis revealed that under conditions of top initiation, the reflected tensile damage of the rock at the free face of the top of the borehole and the compression deformation of the plug and friction consume more blasting energy, resulting in lower blasting energy efficiency for top initiation. As a result, the overall damage degree of the specimens in the top-initiation group was significantly smaller than that in the inverse-initiation group. Under conditions of inverse initiation, the blasting energy efficiency is greater, causing the specimen to experience greater damage. Therefore, in the engineering practice of rock tunnel cut blasting, to utilize blasting energy effectively and enhance the effects of rock fragmentation, using the inverse-initiation method is recommended. In addition, in three-dimensional(3D) rock blasting, the bottom of the borehole has obvious end effects under the conditions of inverse initiation, and the crack distribution at the bottom of the borehole is trumpet-shaped. The occurrence of an end effect in the 3D linear-charge blasting model experiment is related to the initiation position and the blocking condition.
基金This study was funded by the National Natural Science Foundation of China(No.51978039).
文摘Water freezing in rock fractures causes volumetric expansion and fracture development through frost heaving.This study introduces a novel analytical model to investigate how uneven freezing force and surrounding rock pressure influence fracture initiation,based on mass conservation,elasticity,and water-ice phase transition principles.A model for rock fracture initiation considering freezing temperature,uneven freezing expansion,in-situ stress,and lateral pressure was proposed based on fracture mechanics.Equations for stress intensity factors were developed and validated using the phase field method.The effects of rock elastic modulus anisotropy and critical fracture energy density on fracture initiation were also discussed.The results show that the values of KI and KII exhibit an upward trend as the freezing temperature,uneven expansion,in-situ stress,and lateral pressure increase.The uneven freezing expansion has the most significant influence on KI and KII values among these parameters.As the uneven freezing expansion coefficient increases to 0.5,the fracture initiation mode shifts from tensile fracture to shear fracture.As the lateral pressure coefficient increases to 1,the fracture initiation mode shifts from tensile fracture to shear fracture.Rock elastic modulus anisotropy causes fractures to propagate in a clockwise direction,forming a'butterfly'pattern.Critical fracture energy density an isotropy causes counterclockwise deviation in propagation direction,resulting in branching paths and an'H'-shaped pattern.
基金Projects(52178371,52108355,52178321)supported by the National Natural Science Foundation of ChinaProject(202305)supported by the Research Project of Engineering Research Centre of Rock-Soil Drilling&Excavation and Protection,Ministry of Education,China。
文摘Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresearch introduces a computational model designed to predict the lifespan of corrosion initiation in reinforced concretesquare piles when applied reverse-seepage pressure.The model considers the impacts of chloride binding and the tripletime-dependence property among the permeability,the corrected surface chloride concentration,and the diffusioncoefficient.The proposed numerical model is solved using the alternating direction implicit(ADI)approach,and itsaccuracy and reliability are evaluated by contrasting the computational outcomes with the analytical solution andexperimental results.Furthermore,the primary factors contributing to the corrosion of reinforced concrete square pilesare analyzed.The results indicate that applying RST can decrease the chloride penetration depth and prolong the lifespanof corrosion initiation in square piles.The water-cement ratio and reverse seepage pressure are the most influentialfactors.A water pressure of 0.4 MPa can double the life of concrete,and the durable life of concrete with a water-cementratio of 0.3 can reach 100 years.
文摘Introduction: Actors of psychoactive drug initiation refer to those who introduce others to psychoactive drug use (initiators) and those who are introduced to psychoactive drugs (users). By identifying their features, better prevention and intervention programs can be developed to reduce psychoactive drug use among adolescents. This article describes the role of actors of psychoactive drug initiation among teenagers in secondary schools in Yaoundé (Cameroon). Methodology: A cross sectional study was carried out in twelve secondary schools in Yaoundé from October 2022 to May 2023. Adolescents from Form four to upper sixth, who assented to participate in the study and received parental consent were included. Data were collected in a structured self-reported questionnaire and analyzed using SPSS 23. Quantitative variables were expressed using means, standard deviations, median and interquartile ranges depending on the distribution of data. Qualitative variables were expressed in the form of frequency and percentages. Results: Drug use was more prevalent among male adolescents (55.3%) from nuclear families (91.4%) who received relatively high pocket money. The main sources of drug exposure were non-family members (49.7%), especially friends outside school. The most frequent place of initiation was snack bars (33.1%). Conclusion: The study revealed the importance of the family, friends and leisure places in the initiation process of drug use in teenagers. Based on these results, parents and school authorities should work together to create a safe and supportive environment that fosters communication, education to prevent drug abuse among adolescents in Yaoundé.
基金supported by the National Natural Science Foundation of China(No.42077277)。
文摘A debris flow,with terraced fields as the source area,broke out on June 25th,2018 in the Xiaotuga area of Yunnan Province,China,and this kind of debris flow is rarely recorded.Two purposes in this study:(1)the influence of flow drag force on slope stability;(2)back-analyze the movement process of debris flow.First,the geological background and movement of this debris flow were described based on a field investigation.Then,drag force,calculated by the laminar flow theory,is added to the slope stability calculation model,which elaborates the initiation process of this disaster.Moreover,dynamic simulation software(DAN3D)was used to simulate the kinematic process of the debris flow with a variety of combination models.The study shows that the terrace area can quickly produce surface runoff and create a drag force under rainfall conditions,which is the essential reason for the initiation of debris flow.In addition,the use of the FVV(Frictional-Voellmy-Voellmy)model is found to provide the best performance in simulating this type of debris flow,which reveals that it lasts approximately 200 s and that the maximum velocity is 12 m/s.
基金National Science and Technology Major Project(J2019-VI-0022-0138)。
文摘Low-cycle fatigue crack initiation behavior of nickel-based single crystal superalloy at 530℃ was investigated.Results show that the behavior of crack initiation is closely related to the maximum strain.When the maximum strain is 2.0%,the fatigue crack is originated at the position of persistent slip bands on the surface of specimen,which is located on the{111}slip plane.No defects are observed at the crack initiation position.When the maximum strain is lower than 1.6%,the cracks are initiated at the casting defects on sub-surface or at interior of the specimen.The casting defects are located on the{100}slip plane vertical to the axial force.The crack is initiated along the{100}slip plane and then expanded along different{111}slip planes after a short stage of expansion.As the maximum strain decreases,the position of crack initiation gradually changes from the surface to the interior.Moreover,the secondary cracks extending inward along the fracture surface appear in the crack initiation area,and there is obvious stress concentration near the secondary cracks.The dislocation density is high near the fracture surface in the crack initiation zone,where a lot of dislocations cutting into the γ'phase exist.An oxide layer of 50‒100 nm is presented on the fracture surface,and Ni,Al,Cr and Co elements are mainly segregated into the oxide layer of the surface.
基金financially supported by the National Key R&D Program of China(No.2021YFB3701203)the National Natural Science Foundation of China(NSFC,Grant Nos.52171137,52261135543 and U22A20113)the Heilongjiang Provincial Natural Science Foundation of China(Grant No.TD2020E001).
文摘Discontinuously reinforced titanium matrix composites(DRTMCs)with a network structure have been extensively researched due to their superior combination of strength and ductility.However,their fatigue performance has remained unknown.In order to elucidate the fatigue behavior of DRTMCs,a tension-tension fatigue test was performed on a TiB/nearα-Ti composite with network structure.The results showed that the variability of fatigue lifetime increased as the stress level decreased.Fractography analysis indicated that fatigue crack initiation was associated with facet formation,while the subsequent propagation was hindered by the network structure comprising TiB whiskers and silicides.Crystallographic characterization further revealed that facets formed due to a combination of shear and normal stress.The reduction in fatigue lifetime was attributed to an increase in the effective slip length,which was influenced by the orientation of grains near the crack-initiation sites toward basal slip in the life-limiting specimen.Quasi in situ observation suggested that the crack initiation was facilitated by both basal and prismatic slip ofα-Ti as well as fracture of TiBw.Crack propagation was found to be associated with basal and prismatic slip systems with high Schmid factors,regardless of whether the crack was intergranular or intragranular.
基金financially supported by the National Natural Science Foundation of China(No.11932020).
文摘Fatigue failure can still occur beyond 107 cycles,i.e.very-high-cycle fatigue(VHCF),in many metallic materials,such as aluminium alloys and high-strength steels.For VHCF of high-strength steels,a fine granular area(FGA)surrounding an inclusion is commonly identified as the characteristic region of crack initiation on the fracture surface.However,no such FGA feature and related crack initiation behaviour were observed in VHCF of conventionally cast or wrought aluminium alloys.Here,we first reported the distinct mechanisms of crack initiation and early growth,namely the microstructure feature and the role of FGA in VHCF performance for an additively manufactured(AM)AlSi10Mg alloy.The AM pores play a key role in fatigue crack initiation similar to that of the inclusions in high-strength steels,resulting in almost identical FGA behaviour for different materials under a range of mean stress with a stress ratio at R<0 or R>0.The profile microstructure of FGA is identified as a nanograin layer with Si rearrangement and grain boundary transition.This process consumes a large amount of cyclic plastic energy making FGA undertake a vast majority of VHCF life.These results will deepen the understanding of VHCF nature and shed light on crack initiation mechanism of other aluminium and AM alloys.
