In recent years,the direct introduction of sulfonyl and sulfenyl groups into unsaturated substrates by using thiosulfonates as unique dual functional reagents has inarguably provided chemists a new platform for the di...In recent years,the direct introduction of sulfonyl and sulfenyl groups into unsaturated substrates by using thiosulfonates as unique dual functional reagents has inarguably provided chemists a new platform for the diverse synthesis of important S-containing derivatives.These 1,n-thiosulfonylation reactions usually feature simple procedures,100%atom economy,and high regioselectivity.This review focuses on the recent advancements in the transformations of thiosulfonates through 1,n-thiosulfonylation involving the formation of two distinct C-S bonds under transition-metal-catalyzed or metal-free conditions,where thiosulfonates act as both a sulfonyl and a sulfenyl component.展开更多
Bioactive glass-chitosan-alginate hybrid scaffolds （BG-C-A scaffolds） were fabricated using BG sol as a dual function additive, which behaves as both bioactive inorganic phase to confer the bioactivity and cross-lin...Bioactive glass-chitosan-alginate hybrid scaffolds （BG-C-A scaffolds） were fabricated using BG sol as a dual function additive, which behaves as both bioactive inorganic phase to confer the bioactivity and cross-linker to improve the structural stability and mechanical properties. The microstructure, physicochemical and mechanical properties, in vitro bioactivity and cellular biocompatibility of the scaffolds were investigated. The results indicated that BG component was successfully incorporated into the BG-C-A scaffolds through a facile BG sol-immersing method and the original interconnected microstructure could be well preserved. The obtained BG-C-A scaffolds showed improved mechanical properties and structural stability as compared to C-A scaffolds. At the same time, they presented excellent in vitro bioactivity and cellular compatibility. All these results demonstrated that these BG-C-A scaffolds have promising potential for tissue engineering.展开更多
Integrated CO_(2)capture and utilization(ICCU)technology requires dual functional materials(DFMs)to carry out the process in a single reaction system.The influence of the calcination atmosphere on efficiency of 4%Ru-8...Integrated CO_(2)capture and utilization(ICCU)technology requires dual functional materials(DFMs)to carry out the process in a single reaction system.The influence of the calcination atmosphere on efficiency of 4%Ru-8%Na_(2)CO_(3)-8%CaO/γ-Al_(2)O_(3)DFM is studied.The adsorbent precursors are first co-impregnated onto alumina and calcined in air.Then,Ru precursor is impregnated and four aliquotes are subjected to different calcination protocols:static air in muffle or under different mixtures(10%H_(2)/N_(2),50%H_(2)/N_(2)and N_(2))streams.Samples are characterized by XRD,N_(2)adsorption-desorption,H_(2)chemisorption,TEM,XPS,H_(2)-TPD,H_(2)-TPR,CO_(2)-TPD and TPSR.The catalytic behavior is evaluated,in cycles of CO_(2)adsorption and hydrogenation to CH_(4),and temporal evolution of reactants and products concentrations is analyzed.The calcination atmosphere influences the physicochemical properties and,ultimately,activity of DFMs.Characterization data and catalytic performance discover the acccomodation of Ru nanoparticles disposition and basic sites is mostly influencing the catalytic activity.DFM calcined under N_(2)flow(RuNaCa-N_(2))shows the highest CH_(4)production(449μmol/g at 370℃),because a well-controlled decomposition of precursors which favors the better accomodation of adsorbent and Ru phases,maximizing the specific surface area,the Ru-basic sites interface and the participation of different basic sites in the CO_(2)methanation reaction.Thus,the calcination in a N_(2)flow is revealed as the optimal calcination protocol to achieve highly efficient DFM for integrated CO_(2)adsorption and hydrogenation applications.展开更多
A fluorescent active organic–inorganic hybrid material Py N-SBA-15 was synthesized by implementing pyrene derivatives into mesoporous SBA-15 silica.Py N-SBA-15 had detection and removal functionalities toward Al^(3+)...A fluorescent active organic–inorganic hybrid material Py N-SBA-15 was synthesized by implementing pyrene derivatives into mesoporous SBA-15 silica.Py N-SBA-15 had detection and removal functionalities toward Al^(3+),Cu^(2+),and Hg^(2+).On the one hand,Py N-SBA-15 was used as a fluorescence sensor and displayed high sensitivity toward Al^(3+),Cu^(2+),and Hg^(2+)cations (limit of detection:8.0×10^(-7),1.1×10^(-7),and 2.9×10^(-6)mol·L^(–1),respectively) among various analytes with“turn-off”response.On the other hand,the adsorption studies for these toxic analytes (Cu^(2+),Hg^(2+),and Al^(3+)) showed that the ion removal capacity could reach up to 45,581,and 85 mg·g^(-1),respectively.Moreover,the Langmuir isotherm models were better fitted with the adsorption data,indicating that the adsorption was mono-layer adsorption.Kinetic analysis revealed that the adsorption process was well described by the pseudo-second-order kinetic model for Cu^(2+)and Hg^(2+)and pseudo-first-order kinetic model for Al^(3+).The prepared silica material could be reused in four recycles without significantly decreasing its adsorption capacity.Therefore,the Py N-SBA-15 material can serve as a promising candidate for the simultaneous rapid detection and efficient adsorption of metal ions.展开更多
In this paper,we proved that the infinitesimal generator of a strongly continuous cosine operator function is preserved under the time-dependent perturbation in the sun-reflexive case,where the perturbed operator is ...In this paper,we proved that the infinitesimal generator of a strongly continuous cosine operator function is preserved under the time-dependent perturbation in the sun-reflexive case,where the perturbed operator is a bounded linear operator from X into a bigger space Xθ(not X),then the corresponding 2-order abstract Cauchy problem is uniformly well-posed.展开更多
A family of Said-Bézier type generalized Ball （SBGB） bases and surfaces with a parameter H over triangular domain is introduced,which unifies Bézier surface and Said-Ball surface and includes several inter...A family of Said-Bézier type generalized Ball （SBGB） bases and surfaces with a parameter H over triangular domain is introduced,which unifies Bézier surface and Said-Ball surface and includes several intermediate surfaces. To convert different bases and surfaces,the dual functionals of bases are presented. As an application of dual functionals,the subdivision formulas for surfaces are established.展开更多
Using dual function one direction S-rough sets, this article gives the f-law, the F-law, law distance and the concept of system law collided by the F-law. The characteristics presented by the system law collided by th...Using dual function one direction S-rough sets, this article gives the f-law, the F-law, law distance and the concept of system law collided by the F-law. The characteristics presented by the system law collided by the F-law, the recognition of these characteristics and recognition criterion are also proposed. The dual function one direction S-rough sets is one of the basic forms of function S-rough sets. Its basic theory and application in the study of system law collision are reviewed.展开更多
Several common dual quaternion functions,such as the power function,the magnitude function,the 2-norm function,and the kth largest eigenvalue of a dual quaternion Hermitian matrix,are standard dual quaternion function...Several common dual quaternion functions,such as the power function,the magnitude function,the 2-norm function,and the kth largest eigenvalue of a dual quaternion Hermitian matrix,are standard dual quaternion functions,i.e.,the standard parts of their function values depend upon only the standard parts of their dual quaternion variables.Furthermore,the sum,product,minimum,maximum,and composite functions of two standard dual functions,the logarithm and the exponential of standard unit dual quaternion functions,are still standard dual quaternion functions.On the other hand,the dual quaternion optimization problem,where objective and constraint function values are dual numbers but variables are dual quaternions,naturally arises from applications.We show that to solve an equality constrained dual quaternion optimization(EQDQO)problem,we only need to solve two quaternion optimization problems.If the involved dual quaternion functions are all standard,the optimization problem is called a standard dual quaternion optimization problem,and some better results hold.Then,we show that the dual quaternion optimization problems arising from the hand-eye calibration problem and the simultaneous localization and mapping(SLAM)problem are equality constrained standard dual quaternion optimization problems.展开更多
Organic materials are of great interest in various applications owing to their intrinsic designability,molecular controllability,ease of synthesis,and ecological sustainability.In this work,a facile and mild wet-chemi...Organic materials are of great interest in various applications owing to their intrinsic designability,molecular controllability,ease of synthesis,and ecological sustainability.In this work,a facile and mild wet-chemical strategy was carried out to construct a conjugated Ni-BTA coordination polymer via the π-d hybridization with 1,2,4,5-benzenetetramine(BTA)as π-conjugated ligands and Ni^(2+)as metallic centers,which exhibits a unique two-dimensional nanosheet-like structure with available active sites,sufficient electrochemical activity,and multi-electron redox capability.On the one hand,the as-prepared Ni-BTA coordination polymer as electrode material exhibits a rapid,reversible,and efficient energy storage behavior with a large reversible capacity of 198 mA·h·g^(-1)at 1 A·g^(-1) and a high-rate capability of 150 mA·h·g^(-1) at 20 A·g^(-1) in alkali-ion aqueous electrolyte,which are further demonstrated by the in-situ Raman investigation.On the other hand,the Ni-BTA coordination polymer as anti-corrosion additive was introduced into the epoxy resin to achieve a Ni-BTA epoxy coating,which shows a long-term anticorrosion performance with a low corrosion rate of 4.62×10_(-6) mm·a^(-1) and a high corrosion inhibition efficiency of 99.86%,suggesting its great engineering potential as the bi-functional organic material for high-performance energy storage and corrosion protection.展开更多
In this paper, we present a general approach to the construction of the Said-type generalized Ball basis functions. The advantage of our approach lies in the fact that it can be used to derive the expressions for poly...In this paper, we present a general approach to the construction of the Said-type generalized Ball basis functions. The advantage of our approach lies in the fact that it can be used to derive the expressions for polynomials of not only odd degrees but also even degrees in terms of the Said-type generalized Ball basis functions. We then define dual functionals for the Said-type generalized Ball basis in a very natural manner and bring to light the integral property of the Said-type generalized Ball basis functions. Last but not least, new polynomial basis functions are defined which include the Said-type generalized Ball basis functions as their special case, and the corresponding dual functionals and Marsden-like identity are obtained.展开更多
The dual algorithm for minimax problems is further studied in this paper.The resulting theoretical analysis shows that the condition number of the corresponding Hessian of the smooth modified Lagrange function with ch...The dual algorithm for minimax problems is further studied in this paper.The resulting theoretical analysis shows that the condition number of the corresponding Hessian of the smooth modified Lagrange function with changing parameter in the dual algorithm is proportional to the reciprocal of the parameter,which is very important for the efficiency of the dual algorithm.At last,the numerical experiments are reported to validate the analysis results.展开更多
Achieving efficient adsorption and separation of C_(2)H_(2)/CO_(2)mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies i...Achieving efficient adsorption and separation of C_(2)H_(2)/CO_(2)mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies in industry today.High-nuclearity metal cluster-based MOFs with different functionalities are promising for this separation,but it is a complicated and difficult task to precisely control their structures.The strategy of pore-space partition(PSP)is a powerful way to construct this type MOFs,which has the characteristic of isostructural relationship,and can be resulted in a similar performance for them.Therefore,it is an interesting work to explore the effect of MOFs property by adjusting the size of PSP dividers.Herein,three tetranuclear Cu(Ⅱ)cluster-based MOFs(FJU-112/113/114)with dual functionalities has been successfully obtained by PSP strategy with various lengths of divider units.With the highest microporosity and unique functional site,FJU-114 realized a good improvement in the adsorption and separation performance of C_(2)H_(2)/CO_(2).The gas adsorption and lab-scale C_(2)H_(2)/CO_(2)breakthrough experiments demonstrated that FJU-114 exhibits the highest adsorption uptake of 77 cm^(3)/g for C_(2)H_(2),and shows the best separation factor of 4.2 among three MOFs.The GCMC simulation reveals that a stronger adsorption binding site of C_(2)H_(2)in FJU-114a located in the cage II near the unchanged tetranuclear copper node,combined with its high microporosity to achieve the effect of dual functionalities for the improvement performance of C_(2)H_(2)adsorption and separation.展开更多
Flexible electronic devices are integral for meeting the diverse and complex requirements of wearable and multifunctional applications.Conductive papers with characteristics of light-weight,good processability,and deg...Flexible electronic devices are integral for meeting the diverse and complex requirements of wearable and multifunctional applications.Conductive papers with characteristics of light-weight,good processability,and degradability,offer significant benefits to wearable electronics.However,it often suffers from discontinuous distribution of the conductive network,inferior ductility,and conformability,which hinders its application.Herein,we present a conductive paper consisting of high-performance aramid paper as the matrix,and MXene and carbon nanotubes as the conductive fillers,fabricated through a mature papermaking technique and a kirigami design.The resultant dual functional kirigami paper(DFKP)exhibits desirable flexibility and breathability,excellent conductivity(1245.7 S/m),superior mechanical properties(tensile strength of 53.8 MPa),and ideal ductility(an elongation of~612.1%),demonstrating promising capabilities in simultaneously wearable motion-sensing and electrical thermotherapy applications.The DFKP enables flexible deformation,better skin attachment,and three-dimensional(3D)supports for precise monitoring of physiological changes in response to different motions,featuring rapid response and recovery times as short as 30 ms.Furthermore,it exhibits a rapid temperature increase and reaches 95.3℃within 35 s upon applying a voltage of 6 V.Remarkably,the DFKP proves stabilities under repeated deformations,maintaining a stable operational state even after 8000 cycles of stretching.Therefore,this unique wearable DFKP holds great promise for simultaneously being employed in human health monitoring and electrothermal therapy.展开更多
A dual-functional nanoplatform is demonstrated that is found to have the characteristics of cancer cell targeting,pH response,near-infrared fluorescence imaging,and lysosome targeting.It can simultaneously achieve pyr...A dual-functional nanoplatform is demonstrated that is found to have the characteristics of cancer cell targeting,pH response,near-infrared fluorescence imaging,and lysosome targeting.It can simultaneously achieve pyroptosis and ferroptosis under the mediation of photons for cancer immunotherapy.展开更多
The development of dual functional material for cyclic CO_(2)capture and hydrogenation is of great significance for converting diluted CO_(2)into valuable fuels,but suffers from kinetic limitation and deactivation of ...The development of dual functional material for cyclic CO_(2)capture and hydrogenation is of great significance for converting diluted CO_(2)into valuable fuels,but suffers from kinetic limitation and deactivation of adsorbent and catalyst.Herein,we engineered a series of RuNa/γ-Al_(2)O_(3)materials,varying the size of ruthenium from single atoms to clusters/nanoparticles.The coordination environment and structure sensitivity of ruthenium were quantitatively investigated at atomic scale.Our findings reveal that the reduced Ru nanoparticles,approximately 7.1 nm in diameter with a Ru-Ru coordination number of 5.9,exhibit high methane formation activity and selectivity at 340°C.The Ru-Na interfacial sites facilitate CO_(2)migration through a deoxygenation pathway,involving carbonate dissociation,carbonyl formation,and hydrogenation.In-situ experiments and theoretical calculations show that stable carbonyl intermediates on metallic Ru nanoparticles facilitate heterolytic C–O scission and C–H bonding,significantly lowering the energy barrier for activating stored CO_(2).展开更多
Nickel-based cathodes in aqueous nickel-zinc batteries typically suffer from sluggish reaction kinetics and limited energy density.In situ introduction of metal phosphides and rational construction of heterostructures...Nickel-based cathodes in aqueous nickel-zinc batteries typically suffer from sluggish reaction kinetics and limited energy density.In situ introduction of metal phosphides and rational construction of heterostructures can effectively promote electron/ion transport.However,the complex evolution of phosphidation and intractable phosphidizing degree greatly affect the composition of active phase,active sites,charge transfer rate,and ion adsorption strength of cathodes.Herein,the critical bimetallic phosphide layer(CBPL)is constructed on the NiCo-layered double hydroxide(NiCo-LDH)skeleton by a controllable anion-exchange strategy,yielding a novel nanohybrid cathode(NiCo-P1.0,1.0 representing the mass ratio of Na_(2)H_(2)PO_(2)to NiCo-LDH).The high-conductivity CBPL with the inner NiCo-LDH forms extensive heterostructures,effectively regulating the electronic structure via charge transfer,thereby improving electrical conductivity.Remarkably,the CBPL exhibits unexpected electrochemical activity and synergizes with NiCo-LDH for electrode reactions,ultimately delivering extra energy.Benefiting from the bifunctional CBPL,NiCo-P1.0 delivers an optimal capacity of 286.64 mAh g^(−1)at 1C(1C=289 mAh g^(−1))and superb rate performance(a capacity retention of 72.22%at 40C).The assembled NiCo-P1.0//Zn battery achieves ultrahigh energy/power density(503.62 Wh kg^(−1)/18.62 kW kg^(−1),based on the mass loading of active material on the cathode),and the flexible quasi-solid-state pouch cell validates its practicality.This work demonstrates the superiority of bifunctional CBPL for surface modification,providing an effective and scalable compositing strategy in achieving high-performance cathodes for aqueous batteries.展开更多
基金financial support from the Natural Science Foundation of China(No.22001121)Natural Science Foundation of Jiangsu Province(No.BK20180690)+1 种基金Nanjing Tech University(Start-up Grant Nos.39837118 and39837146)Xuzhou Medical University(Start-up Grant No.RC20552038)。
文摘In recent years,the direct introduction of sulfonyl and sulfenyl groups into unsaturated substrates by using thiosulfonates as unique dual functional reagents has inarguably provided chemists a new platform for the diverse synthesis of important S-containing derivatives.These 1,n-thiosulfonylation reactions usually feature simple procedures,100%atom economy,and high regioselectivity.This review focuses on the recent advancements in the transformations of thiosulfonates through 1,n-thiosulfonylation involving the formation of two distinct C-S bonds under transition-metal-catalyzed or metal-free conditions,where thiosulfonates act as both a sulfonyl and a sulfenyl component.
基金supported by the National Natural Science Foundation of China(No. 51773209)the National Basic Research Program(No. 2017YFC1103300)the Strategic Priority Research Program of Chinese Academy of Sciences(No. XDB12020300)
文摘Bioactive glass-chitosan-alginate hybrid scaffolds （BG-C-A scaffolds） were fabricated using BG sol as a dual function additive, which behaves as both bioactive inorganic phase to confer the bioactivity and cross-linker to improve the structural stability and mechanical properties. The microstructure, physicochemical and mechanical properties, in vitro bioactivity and cellular biocompatibility of the scaffolds were investigated. The results indicated that BG component was successfully incorporated into the BG-C-A scaffolds through a facile BG sol-immersing method and the original interconnected microstructure could be well preserved. The obtained BG-C-A scaffolds showed improved mechanical properties and structural stability as compared to C-A scaffolds. At the same time, they presented excellent in vitro bioactivity and cellular compatibility. All these results demonstrated that these BG-C-A scaffolds have promising potential for tissue engineering.
基金supported by Ministry of Science and InnovationNational Research Agency(Project PID2019-105960RBC21)+1 种基金by the Basque Government(Project IT1509-2022)One of the authors(JAOC)acknowledges the post-doctoral research grant(DOCREC20/49)provided by the University of the Basque Country。
文摘Integrated CO_(2)capture and utilization(ICCU)technology requires dual functional materials(DFMs)to carry out the process in a single reaction system.The influence of the calcination atmosphere on efficiency of 4%Ru-8%Na_(2)CO_(3)-8%CaO/γ-Al_(2)O_(3)DFM is studied.The adsorbent precursors are first co-impregnated onto alumina and calcined in air.Then,Ru precursor is impregnated and four aliquotes are subjected to different calcination protocols:static air in muffle or under different mixtures(10%H_(2)/N_(2),50%H_(2)/N_(2)and N_(2))streams.Samples are characterized by XRD,N_(2)adsorption-desorption,H_(2)chemisorption,TEM,XPS,H_(2)-TPD,H_(2)-TPR,CO_(2)-TPD and TPSR.The catalytic behavior is evaluated,in cycles of CO_(2)adsorption and hydrogenation to CH_(4),and temporal evolution of reactants and products concentrations is analyzed.The calcination atmosphere influences the physicochemical properties and,ultimately,activity of DFMs.Characterization data and catalytic performance discover the acccomodation of Ru nanoparticles disposition and basic sites is mostly influencing the catalytic activity.DFM calcined under N_(2)flow(RuNaCa-N_(2))shows the highest CH_(4)production(449μmol/g at 370℃),because a well-controlled decomposition of precursors which favors the better accomodation of adsorbent and Ru phases,maximizing the specific surface area,the Ru-basic sites interface and the participation of different basic sites in the CO_(2)methanation reaction.Thus,the calcination in a N_(2)flow is revealed as the optimal calcination protocol to achieve highly efficient DFM for integrated CO_(2)adsorption and hydrogenation applications.
基金supported by the National Natural Science Foundation of China (21966006)。
文摘A fluorescent active organic–inorganic hybrid material Py N-SBA-15 was synthesized by implementing pyrene derivatives into mesoporous SBA-15 silica.Py N-SBA-15 had detection and removal functionalities toward Al^(3+),Cu^(2+),and Hg^(2+).On the one hand,Py N-SBA-15 was used as a fluorescence sensor and displayed high sensitivity toward Al^(3+),Cu^(2+),and Hg^(2+)cations (limit of detection:8.0×10^(-7),1.1×10^(-7),and 2.9×10^(-6)mol·L^(–1),respectively) among various analytes with“turn-off”response.On the other hand,the adsorption studies for these toxic analytes (Cu^(2+),Hg^(2+),and Al^(3+)) showed that the ion removal capacity could reach up to 45,581,and 85 mg·g^(-1),respectively.Moreover,the Langmuir isotherm models were better fitted with the adsorption data,indicating that the adsorption was mono-layer adsorption.Kinetic analysis revealed that the adsorption process was well described by the pseudo-second-order kinetic model for Cu^(2+)and Hg^(2+)and pseudo-first-order kinetic model for Al^(3+).The prepared silica material could be reused in four recycles without significantly decreasing its adsorption capacity.Therefore,the Py N-SBA-15 material can serve as a promising candidate for the simultaneous rapid detection and efficient adsorption of metal ions.
文摘In this paper,we proved that the infinitesimal generator of a strongly continuous cosine operator function is preserved under the time-dependent perturbation in the sun-reflexive case,where the perturbed operator is a bounded linear operator from X into a bigger space Xθ(not X),then the corresponding 2-order abstract Cauchy problem is uniformly well-posed.
文摘A family of Said-Bézier type generalized Ball （SBGB） bases and surfaces with a parameter H over triangular domain is introduced,which unifies Bézier surface and Said-Ball surface and includes several intermediate surfaces. To convert different bases and surfaces,the dual functionals of bases are presented. As an application of dual functionals,the subdivision formulas for surfaces are established.
基金Natural Science Foundation of Shandong Province of China (Y2004A04)Education Hall Foundation of Fujian Education Official of China(JA04268).
文摘Using dual function one direction S-rough sets, this article gives the f-law, the F-law, law distance and the concept of system law collided by the F-law. The characteristics presented by the system law collided by the F-law, the recognition of these characteristics and recognition criterion are also proposed. The dual function one direction S-rough sets is one of the basic forms of function S-rough sets. Its basic theory and application in the study of system law collision are reviewed.
基金Hong Kong Innovation and Technology Commission(InnoHK Project CIMDA).
文摘Several common dual quaternion functions,such as the power function,the magnitude function,the 2-norm function,and the kth largest eigenvalue of a dual quaternion Hermitian matrix,are standard dual quaternion functions,i.e.,the standard parts of their function values depend upon only the standard parts of their dual quaternion variables.Furthermore,the sum,product,minimum,maximum,and composite functions of two standard dual functions,the logarithm and the exponential of standard unit dual quaternion functions,are still standard dual quaternion functions.On the other hand,the dual quaternion optimization problem,where objective and constraint function values are dual numbers but variables are dual quaternions,naturally arises from applications.We show that to solve an equality constrained dual quaternion optimization(EQDQO)problem,we only need to solve two quaternion optimization problems.If the involved dual quaternion functions are all standard,the optimization problem is called a standard dual quaternion optimization problem,and some better results hold.Then,we show that the dual quaternion optimization problems arising from the hand-eye calibration problem and the simultaneous localization and mapping(SLAM)problem are equality constrained standard dual quaternion optimization problems.
基金supported by the National Natural Science Foundation of China(52002157 and 51873083)the Natural Science Foundation of Jiangsu Province(BK20190976)。
文摘Organic materials are of great interest in various applications owing to their intrinsic designability,molecular controllability,ease of synthesis,and ecological sustainability.In this work,a facile and mild wet-chemical strategy was carried out to construct a conjugated Ni-BTA coordination polymer via the π-d hybridization with 1,2,4,5-benzenetetramine(BTA)as π-conjugated ligands and Ni^(2+)as metallic centers,which exhibits a unique two-dimensional nanosheet-like structure with available active sites,sufficient electrochemical activity,and multi-electron redox capability.On the one hand,the as-prepared Ni-BTA coordination polymer as electrode material exhibits a rapid,reversible,and efficient energy storage behavior with a large reversible capacity of 198 mA·h·g^(-1)at 1 A·g^(-1) and a high-rate capability of 150 mA·h·g^(-1) at 20 A·g^(-1) in alkali-ion aqueous electrolyte,which are further demonstrated by the in-situ Raman investigation.On the other hand,the Ni-BTA coordination polymer as anti-corrosion additive was introduced into the epoxy resin to achieve a Ni-BTA epoxy coating,which shows a long-term anticorrosion performance with a low corrosion rate of 4.62×10_(-6) mm·a^(-1) and a high corrosion inhibition efficiency of 99.86%,suggesting its great engineering potential as the bi-functional organic material for high-performance energy storage and corrosion protection.
基金Supported by the National Natural Science Foundation of China(Grant No.61472466)
文摘In this paper, we present a general approach to the construction of the Said-type generalized Ball basis functions. The advantage of our approach lies in the fact that it can be used to derive the expressions for polynomials of not only odd degrees but also even degrees in terms of the Said-type generalized Ball basis functions. We then define dual functionals for the Said-type generalized Ball basis in a very natural manner and bring to light the integral property of the Said-type generalized Ball basis functions. Last but not least, new polynomial basis functions are defined which include the Said-type generalized Ball basis functions as their special case, and the corresponding dual functionals and Marsden-like identity are obtained.
文摘The dual algorithm for minimax problems is further studied in this paper.The resulting theoretical analysis shows that the condition number of the corresponding Hessian of the smooth modified Lagrange function with changing parameter in the dual algorithm is proportional to the reciprocal of the parameter,which is very important for the efficiency of the dual algorithm.At last,the numerical experiments are reported to validate the analysis results.
基金financially supported by the National Natural Science Foundation of China(Nos.21975044,21971038,21922810 and 22271046)the Fujian Provincial Department of Science and Technology(Nos.2023J01355,2023J011106 and 2022R1022001).
文摘Achieving efficient adsorption and separation of C_(2)H_(2)/CO_(2)mixtures is a goal that people have always pursued to improve the situation of high energy consumption brought by traditional separation technologies in industry today.High-nuclearity metal cluster-based MOFs with different functionalities are promising for this separation,but it is a complicated and difficult task to precisely control their structures.The strategy of pore-space partition(PSP)is a powerful way to construct this type MOFs,which has the characteristic of isostructural relationship,and can be resulted in a similar performance for them.Therefore,it is an interesting work to explore the effect of MOFs property by adjusting the size of PSP dividers.Herein,three tetranuclear Cu(Ⅱ)cluster-based MOFs(FJU-112/113/114)with dual functionalities has been successfully obtained by PSP strategy with various lengths of divider units.With the highest microporosity and unique functional site,FJU-114 realized a good improvement in the adsorption and separation performance of C_(2)H_(2)/CO_(2).The gas adsorption and lab-scale C_(2)H_(2)/CO_(2)breakthrough experiments demonstrated that FJU-114 exhibits the highest adsorption uptake of 77 cm^(3)/g for C_(2)H_(2),and shows the best separation factor of 4.2 among three MOFs.The GCMC simulation reveals that a stronger adsorption binding site of C_(2)H_(2)in FJU-114a located in the cage II near the unchanged tetranuclear copper node,combined with its high microporosity to achieve the effect of dual functionalities for the improvement performance of C_(2)H_(2)adsorption and separation.
基金financially supported by Shaanxi Province Key Research and Development Project(No.2024GX-YBXM-331)China Scholarship Council(No.CXXM20210077)+1 种基金the National Natural Science Foundation of China(No.22278260)Scientific Research Plan Projects of Shaanxi Education Department(No.24JC009).
文摘Flexible electronic devices are integral for meeting the diverse and complex requirements of wearable and multifunctional applications.Conductive papers with characteristics of light-weight,good processability,and degradability,offer significant benefits to wearable electronics.However,it often suffers from discontinuous distribution of the conductive network,inferior ductility,and conformability,which hinders its application.Herein,we present a conductive paper consisting of high-performance aramid paper as the matrix,and MXene and carbon nanotubes as the conductive fillers,fabricated through a mature papermaking technique and a kirigami design.The resultant dual functional kirigami paper(DFKP)exhibits desirable flexibility and breathability,excellent conductivity(1245.7 S/m),superior mechanical properties(tensile strength of 53.8 MPa),and ideal ductility(an elongation of~612.1%),demonstrating promising capabilities in simultaneously wearable motion-sensing and electrical thermotherapy applications.The DFKP enables flexible deformation,better skin attachment,and three-dimensional(3D)supports for precise monitoring of physiological changes in response to different motions,featuring rapid response and recovery times as short as 30 ms.Furthermore,it exhibits a rapid temperature increase and reaches 95.3℃within 35 s upon applying a voltage of 6 V.Remarkably,the DFKP proves stabilities under repeated deformations,maintaining a stable operational state even after 8000 cycles of stretching.Therefore,this unique wearable DFKP holds great promise for simultaneously being employed in human health monitoring and electrothermal therapy.
文摘A dual-functional nanoplatform is demonstrated that is found to have the characteristics of cancer cell targeting,pH response,near-infrared fluorescence imaging,and lysosome targeting.It can simultaneously achieve pyroptosis and ferroptosis under the mediation of photons for cancer immunotherapy.
基金National Key R&D Program of China(2022YFE0105900)National Natural Science Foundation of China(52306179)+1 种基金Science and Technology Innovation Program of Hunan Province(2021RC4006)High Performance Computing Center of Central South University。
文摘The development of dual functional material for cyclic CO_(2)capture and hydrogenation is of great significance for converting diluted CO_(2)into valuable fuels,but suffers from kinetic limitation and deactivation of adsorbent and catalyst.Herein,we engineered a series of RuNa/γ-Al_(2)O_(3)materials,varying the size of ruthenium from single atoms to clusters/nanoparticles.The coordination environment and structure sensitivity of ruthenium were quantitatively investigated at atomic scale.Our findings reveal that the reduced Ru nanoparticles,approximately 7.1 nm in diameter with a Ru-Ru coordination number of 5.9,exhibit high methane formation activity and selectivity at 340°C.The Ru-Na interfacial sites facilitate CO_(2)migration through a deoxygenation pathway,involving carbonate dissociation,carbonyl formation,and hydrogenation.In-situ experiments and theoretical calculations show that stable carbonyl intermediates on metallic Ru nanoparticles facilitate heterolytic C–O scission and C–H bonding,significantly lowering the energy barrier for activating stored CO_(2).
基金supported by the National Natural Science Foundation of China(No.52373249,W2433146)the Science and Technology Project of Yibin Sanjiang New Area(No.2023SJXQSXZJ003)the Fundamental Research Funds for the Central Universities(No.20822041F4045).
文摘Nickel-based cathodes in aqueous nickel-zinc batteries typically suffer from sluggish reaction kinetics and limited energy density.In situ introduction of metal phosphides and rational construction of heterostructures can effectively promote electron/ion transport.However,the complex evolution of phosphidation and intractable phosphidizing degree greatly affect the composition of active phase,active sites,charge transfer rate,and ion adsorption strength of cathodes.Herein,the critical bimetallic phosphide layer(CBPL)is constructed on the NiCo-layered double hydroxide(NiCo-LDH)skeleton by a controllable anion-exchange strategy,yielding a novel nanohybrid cathode(NiCo-P1.0,1.0 representing the mass ratio of Na_(2)H_(2)PO_(2)to NiCo-LDH).The high-conductivity CBPL with the inner NiCo-LDH forms extensive heterostructures,effectively regulating the electronic structure via charge transfer,thereby improving electrical conductivity.Remarkably,the CBPL exhibits unexpected electrochemical activity and synergizes with NiCo-LDH for electrode reactions,ultimately delivering extra energy.Benefiting from the bifunctional CBPL,NiCo-P1.0 delivers an optimal capacity of 286.64 mAh g^(−1)at 1C(1C=289 mAh g^(−1))and superb rate performance(a capacity retention of 72.22%at 40C).The assembled NiCo-P1.0//Zn battery achieves ultrahigh energy/power density(503.62 Wh kg^(−1)/18.62 kW kg^(−1),based on the mass loading of active material on the cathode),and the flexible quasi-solid-state pouch cell validates its practicality.This work demonstrates the superiority of bifunctional CBPL for surface modification,providing an effective and scalable compositing strategy in achieving high-performance cathodes for aqueous batteries.
