In this study,we investigated improving the performance of a layered double hydroxide(LDH)for the adsorption of As(III)and As(V)by controlling the morphology of LDH crystals.The LDH was synthesized via a simple coprec...In this study,we investigated improving the performance of a layered double hydroxide(LDH)for the adsorption of As(III)and As(V)by controlling the morphology of LDH crystals.The LDH was synthesized via a simple coprecipitation method using barely soluble MgO as a precursor and succinic acid(SA)as a morphological control agent.Doping the LDH crystals with carboxylate ions(RCOO−)derived from SA caused the crystals to develop in a radial direction.This changed the pore characteristics and increased the density of active surface sites.Subsequently,SA/MgFe-LDH showed excellent affinity for As(III)and As(V)with maximum sorption densities of 2.42 and 1.60 mmol/g,respectively.By comparison,the pristine MgFe-LDH had sorption capacities of 1.56 and 1.31 mmol/g for As(III)and As(V),respectively.The LDH was effective over a wide pH range for As(III)adsorption(pH 3-8.5)and As(V)adsorption(pH 3-6.5).Using a combination of spectroscopy and sorption modeling calculations,the main sorption mechanism of As(III)and As(V)on SA/MgFe-LDH was identified as inner-sphere complexation via ligand exchangewith hydroxyl group(-OH)and RCOO−.Specifically,bidentate As-Fe complexeswere proposed for both As(III)and As(V)uptake,with the magnitude of formation varying with the initial As concentration.Importantly,the As-laden adsorbent had satisfactory stability in simulated real landfill leachate.These findings demonstrate that SA/MgFe-LDH exhibits considerable potential for remediation of As-contaminated water.展开更多
The alpine ecosystem has great potential for carbon sequestration.Soil organic carbon(SOC)and total nitrogen(TN)are highly sensitive to climate change,and their dynamics are crucial to revealing the effect of climate ...The alpine ecosystem has great potential for carbon sequestration.Soil organic carbon(SOC)and total nitrogen(TN)are highly sensitive to climate change,and their dynamics are crucial to revealing the effect of climate change on the structure,function,and services of the ecosystem.However,the spatial distribution and controlling factors of SOC and TN across various soil layers and vegetation types within this unique ecosystem remain inadequately understood.In this study,256 soil samples in 89 sites were collected from the Three River Headwaters Region(TRHR)in China to investigate SOC and TN and to explore the primary factors affecting their distribution,including soil,vegetation,climate,and geography factors.The results show that SOC and TN contents in 0-20,20-40,40-60,and 60-80 cm soil layers are 24.40,18.03,14.04,12.40 g/kg and 2.46,1.90,1.51,1.17 g/kg,respectively;with higher concentrations observed in the southeastern region compared to the northwest of the TRHR.One-way analysis of variance reveals that SOC and TN levels are elevated in the alpine meadow and the alpine shrub relative to the alpine steppe in the 0-60 cm soil layers.The structural equation model explores that soil water content is the main controlling factor affecting the variation of SOC and TN.Moreover,the geography,climate,and vegetation factors notably indirectly affect SOC and TN through soil factors.Therefore,it can effectively improve soil water and nutrient conditions through vegetation restoration,soil improvement,and grazing management,and the change of SOC and TN can be fully understood by establishing monitoring networks to better protect soil carbon and nitrogen.展开更多
Due to the coexistence of compressibility,viscosity,and threedimensional effects,laminar flow is difficult to maintain for high-speed boundary layer on complex geometries.The unstable disturbance waves in the boundary...Due to the coexistence of compressibility,viscosity,and threedimensional effects,laminar flow is difficult to maintain for high-speed boundary layer on complex geometries.The unstable disturbance waves in the boundary layer are excited and rapidly increase during the receptivity process,so sufficiently large Reynolds stress causes the basic flow velocity profile to change,and the formation of turbulence is inevitable.展开更多
In this study,we explore some of the best proximity point results for generalized proximal contractions in the setting of double-controlled metric-type spaces.A non-trivial example is given to elucidate our analysis,a...In this study,we explore some of the best proximity point results for generalized proximal contractions in the setting of double-controlled metric-type spaces.A non-trivial example is given to elucidate our analysis,and some novel results are derived.The discovered results generalize previously known results in the context of a double controlled metric type space environment.This article’s proximity point results are the first of their kind in the realm of controlled metric spaces.To build on the results achieved in this article,we present an application demonstrating the usability of the given results.展开更多
Our concern is to investigate controlled remote implementation of partially unknown operations with multiple layers.We first propose a scheme to realize the remote implementation of singlequbit operations belonging to...Our concern is to investigate controlled remote implementation of partially unknown operations with multiple layers.We first propose a scheme to realize the remote implementation of singlequbit operations belonging to the restricted sets.Then,the proposed scheme is extended to the case of single-qudit operations.As long as the controller and the higher-layer senders consent,the receiver can restore the desired state remotely operated by the sender.It is worth mentioning that the recovery operation is deduced by general formulas which clearly reveal the relationship with the measurement outcomes.For the sake of clarity,two specific examples with two levels are given respectively.In addition,we discuss the influence of amplitude-damping noise and utilize weak measurement and measurement reversal to effectively resist noise.展开更多
The phenomenon of shock/shock interaction(SSI)is widely observed in high-speed flow,and the double wedge SSI represents one of the typical problems encountered.The control effect of single-pulse plasma synthetic jet(P...The phenomenon of shock/shock interaction(SSI)is widely observed in high-speed flow,and the double wedge SSI represents one of the typical problems encountered.The control effect of single-pulse plasma synthetic jet(PSJ)on double wedge type-Ⅵand type-ⅤSSI was investigated experimentally and numerically,and the influence of discharge energy was also explored.The findings indicate that the interaction between PSJ and the high-speed freestream results in the formation of a plasma layer and a jet shock,which collectively governs the control of SSI.The control mechanism of single-pulse PSJ on SSI lies in its capacity to attenuate both shock and SSI.For type-ⅥSSI,the original second-wedge oblique shock is eliminated under the control of PSJ,resulting in a new type-ⅥSSI formed by the jet shock and the first-wedge oblique shock.For type-ⅤSSI,the presence of PSJ effectively mitigates the intensity of Mach stem,supersonic jet,and reflected shocks,thereby facilitating its transition into type-ⅥSSI.The numerical results indicate that the peak pressure can be reduced by approximately 32.26%at maximum.Furthermore,the development of PSJ also extends in the Z direction.The pressure decreases in the area affected by both PSJ and jet shock due to the attenuation of the SSI zone.With increasing discharge energy,the control effect of PSJ on SSI is gradually enhanced.展开更多
With a three-dimensional semiclassical ensemble method, we theoretically investigated the nonsequential double ionization of Ar driven by the spatially inhomogeneous few-cycle negatively chirped laser pulses. Our resu...With a three-dimensional semiclassical ensemble method, we theoretically investigated the nonsequential double ionization of Ar driven by the spatially inhomogeneous few-cycle negatively chirped laser pulses. Our results show that the recollision time window can be precisely controlled within an isolated time interval of several hundred attoseconds, which is useful for understanding the subcycle correlated electron dynamics. More interestingly, the correlated electron momentum distribution (CEMD) exhibits a strong dependence on laser intensity. That is, at lower laser intensity, CEMD is located in the first quadrant. As the laser intensity increases,CEMD shifts almost completely to the second and fourth quadrants, and then gradually to the third quadrant.The underlying physics governing the CEMD's dependence on laser intensity is explained.展开更多
This paper investigates vibration control of beam through electro-magnetic constrained layer damping （EMCLD） which consists of electromagnet layer, permanent magnet layer and viscoelastic damping layer. When the coi...This paper investigates vibration control of beam through electro-magnetic constrained layer damping （EMCLD） which consists of electromagnet layer, permanent magnet layer and viscoelastic damping layer. When the coil of the electromagnet is electrified with proper control strategy, the electromagnet can exert magnetic force opposite to the direction of structural deformation so that the structural vibration is attenuated. A mathematical model is developed based on the equivalent current method to calculate the electromagnetic control force produced by EMCLD. The governing equations of the system are obtained using Hamilton＇s Principle and then reduced with the assumed-mode method. A simulation on vibration control of a cantilever beam is conducted under the velocity proportional feedback to demonstrate the energy dissipation capability of EMCLD, and the beam system with the same parameter is experimented. The results of experiment and simulation are compared and the results show that the EMCLD is an effective means for suppressing modal vibration. The results also indicate that the beam system has better control performance for larger control current. The EMCLD method presented in this paper provides an applicable and efficient tool for the vibration control of structures.展开更多
Effects of process parameters on microstructure and mechanical properties of the AM50A magnesium alloy components formed by double control forming （DCF） were investigated via a four-factor and four-level orthogonal ...Effects of process parameters on microstructure and mechanical properties of the AM50A magnesium alloy components formed by double control forming （DCF） were investigated via a four-factor and four-level orthogonal experiment. The variable curves of DCF showed that the forging procedure was started in the following 35 ms after the injection procedure was completed. It was confirmed that the high-speed filling and high-pressure densifying were combined together in the DCF process. Better surface quality and higher mechanical properties were achieved in the components formed by DCF as compared to die casting （DC） due to the refined and uniform microstructure with a few defects or without defects. Injection speed affected more effectively the yield strength （YS）, ultimate tensile strength （UTS） and elongation as compared to pouring temperature, die temperature and forging force. But the pouring temperature had a more significant effect on hardness as compared to injection speed, die temperature and forging force. Pouring temperature of 675 ＆#176;C, injection speed of 2.7 m/s and forging force of 4000 kN except for die temperature were the optimal parameters for obtaining the highest YS, UTS, elongation and Vickers hardness. Die temperatures of 205, 195, 195 and 225 ＆#176;C were involved in achieving the highest YS, UTS, elongation and Vickers hardness, respectively. Obvious microporosity and microcracks were found on the fracture surface of the components formed by DC, deteriorating the mechanical properties. However, the tensile fracture morphology of the components formed by DCF was characterized by ductile fracture due to a large number of dimples and no defects, which was beneficial for improving the mechanical properties.展开更多
A new type of brushless DC motor has been developed by using a square wave rare earth permanent magnet synchronous motor with its double loop control circuit. The double loop control scheme of the drive system yie...A new type of brushless DC motor has been developed by using a square wave rare earth permanent magnet synchronous motor with its double loop control circuit. The double loop control scheme of the drive system yields a combination of desired characteristics including simplified control structure, small ripple torque, high speed accuracy, wide operating speed range, and fast dynamic response. Experimental results confirm excellent characteristics of the motor.展开更多
[Objective] This study aimed to explore the effects of continuous application of controlled release nitrogen fertilizer under double rice cropping system. [Method] By modeling three types of paddy soils in Dong-Ting L...[Objective] This study aimed to explore the effects of continuous application of controlled release nitrogen fertilizer under double rice cropping system. [Method] By modeling three types of paddy soils in Dong-Ting Lake area, four treatments as no fertilizer （CK）, urea, controlled release nitrogen fertilizer （CRNF） and 70% controlled release nitrogen fertilizer （70% CRNF） were designed in the micro-plot trials from 2005 to 2008. [Result] The rice yield in treatment CRNF at N 150 kg/hm2 was increased by 10.3%, 8.0% and 2.4% compared with treatment of urea, in alluvial sandy loamy paddy soil （ALS）, purple calcareous clayey paddy soil （PCS）, and reddish yellow loamy paddy soil （RYS）, respectively; and the yield in treatment of 70% CRNF was increased by 6.1%, 2.6% and -0.8%, respectively. The ranking order of nitrogen uptake amount by plant in early rice and late rice was CRNF 70% CRNF urea CK in all three types of soil. Nitrogen utilization efficiency of CRNF in above three types of soil was 60.7%, 59.6% and 56.3%, increased by 23.8%, 19.4% and 16.3% compared with that in treatment of urea, respectively. Nitrogen utilization efficiency of CRNF in early rice was increased year by year, and was higher than that of 70% CRNF during the whole experiment stage, while that in late rice was increased first and then decreased from the 3rd year. [Conclusion] Continuous application CRNF could alleviate the decreasing of soil nitrogen fertility and organic carbon especially in ALS, increase rice yield and nitrogen utilization efficiency in double-rice cropping system.展开更多
The electric double layer(EDL)at the electrochemical interface is crucial for ion transport,charge transfer,and surface reactions in aqueous rechargeable zinc batteries(ARZBs).However,Zn anodes routinely encounter per...The electric double layer(EDL)at the electrochemical interface is crucial for ion transport,charge transfer,and surface reactions in aqueous rechargeable zinc batteries(ARZBs).However,Zn anodes routinely encounter persistent dendrite growth and parasitic reactions,driven by the inhomogeneous charge distribution and water-dominated environment within the EDL.Compounding this,classical EDL theory,rooted in meanfield approximations,further fails to resolve molecular-scale interfacial dynamics under battery-operating conditions,limiting mechanistic insights.Herein,we established a multiscale theoretical calculation framework from single molecular characteristics to interfacial ion distribution,revealing the EDL’s structure and interactions between different ions and molecules,which helps us understand the parasitic processes in depth.Simulations demonstrate that water dipole and sulfate ion adsorption at the inner Helmholtz plane drives severe hydrogen evolution and by-product formation.Guided by these insights,we engineered a“water-poor and anion-expelled”EDL using 4,1’,6’-trichlorogalactosucrose(TGS)as an electrolyte additive.As a result,Zn||Zn symmetric cells with TGS exhibited stable cycling for over 4700 h under a current density of 1 mA cm^(−2),while NaV_(3)O_(8)·1.5H_(2)O-based full cells kept 90.4%of the initial specific capacity after 800 cycles at 5 A g^(−1).This work highlights the power of multiscale theoretical frameworks to unravel EDL complexities and guide high-performance ARZB design through integrated theory-experiment approaches.展开更多
文摘In this study,we investigated improving the performance of a layered double hydroxide(LDH)for the adsorption of As(III)and As(V)by controlling the morphology of LDH crystals.The LDH was synthesized via a simple coprecipitation method using barely soluble MgO as a precursor and succinic acid(SA)as a morphological control agent.Doping the LDH crystals with carboxylate ions(RCOO−)derived from SA caused the crystals to develop in a radial direction.This changed the pore characteristics and increased the density of active surface sites.Subsequently,SA/MgFe-LDH showed excellent affinity for As(III)and As(V)with maximum sorption densities of 2.42 and 1.60 mmol/g,respectively.By comparison,the pristine MgFe-LDH had sorption capacities of 1.56 and 1.31 mmol/g for As(III)and As(V),respectively.The LDH was effective over a wide pH range for As(III)adsorption(pH 3-8.5)and As(V)adsorption(pH 3-6.5).Using a combination of spectroscopy and sorption modeling calculations,the main sorption mechanism of As(III)and As(V)on SA/MgFe-LDH was identified as inner-sphere complexation via ligand exchangewith hydroxyl group(-OH)and RCOO−.Specifically,bidentate As-Fe complexeswere proposed for both As(III)and As(V)uptake,with the magnitude of formation varying with the initial As concentration.Importantly,the As-laden adsorbent had satisfactory stability in simulated real landfill leachate.These findings demonstrate that SA/MgFe-LDH exhibits considerable potential for remediation of As-contaminated water.
基金supported by the National Science Foundation for Distinguished Young Scholars(No.42425107)Ecological Civilization Special Project of Key Research&and Development Program in Gansu Province(No.24YFFA009)the Top Talent Project of Gansu Province,Chinese Academy of Sciences Young Crossover Team Project(No.JCTD-2022-18)。
文摘The alpine ecosystem has great potential for carbon sequestration.Soil organic carbon(SOC)and total nitrogen(TN)are highly sensitive to climate change,and their dynamics are crucial to revealing the effect of climate change on the structure,function,and services of the ecosystem.However,the spatial distribution and controlling factors of SOC and TN across various soil layers and vegetation types within this unique ecosystem remain inadequately understood.In this study,256 soil samples in 89 sites were collected from the Three River Headwaters Region(TRHR)in China to investigate SOC and TN and to explore the primary factors affecting their distribution,including soil,vegetation,climate,and geography factors.The results show that SOC and TN contents in 0-20,20-40,40-60,and 60-80 cm soil layers are 24.40,18.03,14.04,12.40 g/kg and 2.46,1.90,1.51,1.17 g/kg,respectively;with higher concentrations observed in the southeastern region compared to the northwest of the TRHR.One-way analysis of variance reveals that SOC and TN levels are elevated in the alpine meadow and the alpine shrub relative to the alpine steppe in the 0-60 cm soil layers.The structural equation model explores that soil water content is the main controlling factor affecting the variation of SOC and TN.Moreover,the geography,climate,and vegetation factors notably indirectly affect SOC and TN through soil factors.Therefore,it can effectively improve soil water and nutrient conditions through vegetation restoration,soil improvement,and grazing management,and the change of SOC and TN can be fully understood by establishing monitoring networks to better protect soil carbon and nitrogen.
文摘Due to the coexistence of compressibility,viscosity,and threedimensional effects,laminar flow is difficult to maintain for high-speed boundary layer on complex geometries.The unstable disturbance waves in the boundary layer are excited and rapidly increase during the receptivity process,so sufficiently large Reynolds stress causes the basic flow velocity profile to change,and the formation of turbulence is inevitable.
文摘In this study,we explore some of the best proximity point results for generalized proximal contractions in the setting of double-controlled metric-type spaces.A non-trivial example is given to elucidate our analysis,and some novel results are derived.The discovered results generalize previously known results in the context of a double controlled metric type space environment.This article’s proximity point results are the first of their kind in the realm of controlled metric spaces.To build on the results achieved in this article,we present an application demonstrating the usability of the given results.
基金supported by the National Natural Science Foundation of China(Grant Nos.62172341,12071132)the Natural Science Foundation of Henan Province of China(Grant No.242300420276)the Joint Fund of Henan Province Science and Technology R&D Program(Grant No.225200810032)。
文摘Our concern is to investigate controlled remote implementation of partially unknown operations with multiple layers.We first propose a scheme to realize the remote implementation of singlequbit operations belonging to the restricted sets.Then,the proposed scheme is extended to the case of single-qudit operations.As long as the controller and the higher-layer senders consent,the receiver can restore the desired state remotely operated by the sender.It is worth mentioning that the recovery operation is deduced by general formulas which clearly reveal the relationship with the measurement outcomes.For the sake of clarity,two specific examples with two levels are given respectively.In addition,we discuss the influence of amplitude-damping noise and utilize weak measurement and measurement reversal to effectively resist noise.
基金supported by the Independent Innovation Science Fund of National University of Defense Technology(No.24-ZZCX-BC-05)National Natural Science Foundation of China(Nos.92271110 and 12202488)+2 种基金the Major National Science and Technology Project(No.J2019-Ⅲ0010-0054)the National Postdoctoral Researcher Program of China(No.GZB20230985)the Natural Science Program of National University of Defense Technology(No.ZK22-30)。
文摘The phenomenon of shock/shock interaction(SSI)is widely observed in high-speed flow,and the double wedge SSI represents one of the typical problems encountered.The control effect of single-pulse plasma synthetic jet(PSJ)on double wedge type-Ⅵand type-ⅤSSI was investigated experimentally and numerically,and the influence of discharge energy was also explored.The findings indicate that the interaction between PSJ and the high-speed freestream results in the formation of a plasma layer and a jet shock,which collectively governs the control of SSI.The control mechanism of single-pulse PSJ on SSI lies in its capacity to attenuate both shock and SSI.For type-ⅥSSI,the original second-wedge oblique shock is eliminated under the control of PSJ,resulting in a new type-ⅥSSI formed by the jet shock and the first-wedge oblique shock.For type-ⅤSSI,the presence of PSJ effectively mitigates the intensity of Mach stem,supersonic jet,and reflected shocks,thereby facilitating its transition into type-ⅥSSI.The numerical results indicate that the peak pressure can be reduced by approximately 32.26%at maximum.Furthermore,the development of PSJ also extends in the Z direction.The pressure decreases in the area affected by both PSJ and jet shock due to the attenuation of the SSI zone.With increasing discharge energy,the control effect of PSJ on SSI is gradually enhanced.
基金supported by the National Natural Science Foundation of China (Grant No. 12074329)Nanhu Scholars Program for Young Scholars of Xinyang Normal University。
文摘With a three-dimensional semiclassical ensemble method, we theoretically investigated the nonsequential double ionization of Ar driven by the spatially inhomogeneous few-cycle negatively chirped laser pulses. Our results show that the recollision time window can be precisely controlled within an isolated time interval of several hundred attoseconds, which is useful for understanding the subcycle correlated electron dynamics. More interestingly, the correlated electron momentum distribution (CEMD) exhibits a strong dependence on laser intensity. That is, at lower laser intensity, CEMD is located in the first quadrant. As the laser intensity increases,CEMD shifts almost completely to the second and fourth quadrants, and then gradually to the third quadrant.The underlying physics governing the CEMD's dependence on laser intensity is explained.
基金National Natural Science Foundation of China (50275114)
文摘This paper investigates vibration control of beam through electro-magnetic constrained layer damping （EMCLD） which consists of electromagnet layer, permanent magnet layer and viscoelastic damping layer. When the coil of the electromagnet is electrified with proper control strategy, the electromagnet can exert magnetic force opposite to the direction of structural deformation so that the structural vibration is attenuated. A mathematical model is developed based on the equivalent current method to calculate the electromagnetic control force produced by EMCLD. The governing equations of the system are obtained using Hamilton＇s Principle and then reduced with the assumed-mode method. A simulation on vibration control of a cantilever beam is conducted under the velocity proportional feedback to demonstrate the energy dissipation capability of EMCLD, and the beam system with the same parameter is experimented. The results of experiment and simulation are compared and the results show that the EMCLD is an effective means for suppressing modal vibration. The results also indicate that the beam system has better control performance for larger control current. The EMCLD method presented in this paper provides an applicable and efficient tool for the vibration control of structures.
基金Project(51075099)supported by the National Natural Science Foundation of ChinaProject(E201038)supported by the Natural Science Foundation of Heilongjiang Province,China+2 种基金Project(HIT.NSRIF.2013007)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(2011RFQXG010)supported by the Harbin City Young Scientists Foundation,ChinaProject(LBH-T1102)supported by Specially Postdoctoral Science Foundation of Heilongjiang Province,China
文摘Effects of process parameters on microstructure and mechanical properties of the AM50A magnesium alloy components formed by double control forming （DCF） were investigated via a four-factor and four-level orthogonal experiment. The variable curves of DCF showed that the forging procedure was started in the following 35 ms after the injection procedure was completed. It was confirmed that the high-speed filling and high-pressure densifying were combined together in the DCF process. Better surface quality and higher mechanical properties were achieved in the components formed by DCF as compared to die casting （DC） due to the refined and uniform microstructure with a few defects or without defects. Injection speed affected more effectively the yield strength （YS）, ultimate tensile strength （UTS） and elongation as compared to pouring temperature, die temperature and forging force. But the pouring temperature had a more significant effect on hardness as compared to injection speed, die temperature and forging force. Pouring temperature of 675 ＆#176;C, injection speed of 2.7 m/s and forging force of 4000 kN except for die temperature were the optimal parameters for obtaining the highest YS, UTS, elongation and Vickers hardness. Die temperatures of 205, 195, 195 and 225 ＆#176;C were involved in achieving the highest YS, UTS, elongation and Vickers hardness, respectively. Obvious microporosity and microcracks were found on the fracture surface of the components formed by DC, deteriorating the mechanical properties. However, the tensile fracture morphology of the components formed by DCF was characterized by ductile fracture due to a large number of dimples and no defects, which was beneficial for improving the mechanical properties.
文摘A new type of brushless DC motor has been developed by using a square wave rare earth permanent magnet synchronous motor with its double loop control circuit. The double loop control scheme of the drive system yields a combination of desired characteristics including simplified control structure, small ripple torque, high speed accuracy, wide operating speed range, and fast dynamic response. Experimental results confirm excellent characteristics of the motor.
基金Supported by the National Key Technology Research and Development Program of China during the11th Five-Year Plan Period(2008BADA4B08)Science and Technology Innovation Project of Hunan Academy of Agricultural Sciences(2010hnnkycx56)~~
文摘[Objective] This study aimed to explore the effects of continuous application of controlled release nitrogen fertilizer under double rice cropping system. [Method] By modeling three types of paddy soils in Dong-Ting Lake area, four treatments as no fertilizer （CK）, urea, controlled release nitrogen fertilizer （CRNF） and 70% controlled release nitrogen fertilizer （70% CRNF） were designed in the micro-plot trials from 2005 to 2008. [Result] The rice yield in treatment CRNF at N 150 kg/hm2 was increased by 10.3%, 8.0% and 2.4% compared with treatment of urea, in alluvial sandy loamy paddy soil （ALS）, purple calcareous clayey paddy soil （PCS）, and reddish yellow loamy paddy soil （RYS）, respectively; and the yield in treatment of 70% CRNF was increased by 6.1%, 2.6% and -0.8%, respectively. The ranking order of nitrogen uptake amount by plant in early rice and late rice was CRNF 70% CRNF urea CK in all three types of soil. Nitrogen utilization efficiency of CRNF in above three types of soil was 60.7%, 59.6% and 56.3%, increased by 23.8%, 19.4% and 16.3% compared with that in treatment of urea, respectively. Nitrogen utilization efficiency of CRNF in early rice was increased year by year, and was higher than that of 70% CRNF during the whole experiment stage, while that in late rice was increased first and then decreased from the 3rd year. [Conclusion] Continuous application CRNF could alleviate the decreasing of soil nitrogen fertility and organic carbon especially in ALS, increase rice yield and nitrogen utilization efficiency in double-rice cropping system.
基金supported by the National Natural Science Foundation of China(52471240)the Natural Science Foundation of Zhejiang Province(LZ23B030003)+2 种基金the Fundamental Research Funds for the Central Universities(226-2024-00075)support from the Engineering and Physical Sciences Research Council(EPSRC,UK)RiR grant-RIR18221018-1EU COST CA23155。
文摘The electric double layer(EDL)at the electrochemical interface is crucial for ion transport,charge transfer,and surface reactions in aqueous rechargeable zinc batteries(ARZBs).However,Zn anodes routinely encounter persistent dendrite growth and parasitic reactions,driven by the inhomogeneous charge distribution and water-dominated environment within the EDL.Compounding this,classical EDL theory,rooted in meanfield approximations,further fails to resolve molecular-scale interfacial dynamics under battery-operating conditions,limiting mechanistic insights.Herein,we established a multiscale theoretical calculation framework from single molecular characteristics to interfacial ion distribution,revealing the EDL’s structure and interactions between different ions and molecules,which helps us understand the parasitic processes in depth.Simulations demonstrate that water dipole and sulfate ion adsorption at the inner Helmholtz plane drives severe hydrogen evolution and by-product formation.Guided by these insights,we engineered a“water-poor and anion-expelled”EDL using 4,1’,6’-trichlorogalactosucrose(TGS)as an electrolyte additive.As a result,Zn||Zn symmetric cells with TGS exhibited stable cycling for over 4700 h under a current density of 1 mA cm^(−2),while NaV_(3)O_(8)·1.5H_(2)O-based full cells kept 90.4%of the initial specific capacity after 800 cycles at 5 A g^(−1).This work highlights the power of multiscale theoretical frameworks to unravel EDL complexities and guide high-performance ARZB design through integrated theory-experiment approaches.
