Reconstruction during the oxygen evolution reaction(OER)significantly transforms the geometric structure of transition metal compounds,leading to enhanced catalytic performance.However,the resulting structural disorde...Reconstruction during the oxygen evolution reaction(OER)significantly transforms the geometric structure of transition metal compounds,leading to enhanced catalytic performance.However,the resulting structural disorder complicates the development of accurate theoretical models.In this study,CoS2 is used as a model system to establish a framework for rationally modeling reconstructed OER catalysts based on density functional theory(DFT).In the reconstruction process,sulfur atoms are likely to be substituted by oxygen atoms,leading to the formation of the CoOOH phase.Based on the difference in reconstruction degree,we constructed three types of models:doping,heterostructure,and fully reconstructed,representing the reconstruction degree from minimal to full phase transition,respectively.Fully reconstructed models,which account for strain and vacancy effects,effectively simulate the unique coordination environments of reconstructed catalysts.Model e-CoOOH achieves a theoretical overpotential of 0.38 V,outperforming pristine CoOOH(0.56 V),demonstrating that the unique structural features resulting from reconstruction improve OER performance.The doping model and the heterostructure model are helpful to explain the electronic structure and performance transformation of the reconstruction process.This work provides a rational theoretical modeling approach,which is conducive to improving the reliability of the theoretical OER performance of the reconstructed catalyst.展开更多
During strike-slip fault dislocation,multiple fault planes are commonly observed.The resulting permanent ground deformation can lead to profound structural damage to tunnels.However,existing analytical models do not c...During strike-slip fault dislocation,multiple fault planes are commonly observed.The resulting permanent ground deformation can lead to profound structural damage to tunnels.However,existing analytical models do not consider multiple fault planes.Instead,they concentrate the entire fault displacement onto a single fault plane for analysis,thereby giving rise to notable errors in the calculated results.To address this issue,a refined nonlinear theoretical model was established to analyze the mechanical responses of the tunnels subjected to multiple strike-slip fault dislocations.The analytical model considers the number of fault planes,nonlinear soil‒tunnel interactions,geometric nonlinearity,and fault zone width,leading to a significant improvement in its range of applicability and calculation accuracy.The results of the analytical model are in agreement,both qualitatively and quantitatively,with the model test and numerical results.Then,based on the proposed theoretical model,a sensitivity analysis of parameters was conducted,focusing on the variables such as the number of fault planes,fault plane distance(d),fault displacement ratio(η),burial depth(C),crossing angle(β),tunnel diameter(D),fault zone width(Wf),and strike-slip fault displacement(Δfs).The results show that the peak shear force(Vmax),bending moment(Mmax),and axial force(Nmax)decrease with increasing d.The Vmax of the tunnel is found at the fault plane with the largest fault displacement.C,D,andΔfs contribute to the increases in Vmax,Mmax,and Nmax.Additionally,increasing the number of fault planes reduces Vmax and Mmax,whereas the variation in Nmax remains minimal.展开更多
Scale effect of ISWs loads on Floating Production Storage and Offloading(FPSO) is studied in this paper. The application conditions of KdV, eKdV and MCC ISWs theories are used in the numerical method. The depthaverage...Scale effect of ISWs loads on Floating Production Storage and Offloading(FPSO) is studied in this paper. The application conditions of KdV, eKdV and MCC ISWs theories are used in the numerical method. The depthaveraged velocities induced by ISWs are used for the velocity-inlet boundary. Three scale ratio numerical models λ=1, 20 and 300 were selected, which the scale ratio is the size ratio of numerical models to the experimental model.The comparisons between the numerical and former experimental results are performed to verify the feasibility of numerical method. The comparisons between the numerical and simplified theoretical results are performed to discuss the applicability of the simplified theoretical model summarized from the load experiments. Firstly, the numerical results of λ=1 numerical model showed a good agreement with former experimental and simplified theoretical results. It is feasible to simulate the ISWs loads on FPSO by the numerical method. Secondly, the comparisons between the results of three scale ratio numerical models and experimental results indicated that the scale ratios have more significant influence on the experimental horizontal forces than the vertical forces. The scale effect of horizontal forces mainly results from the different viscosity effects associated with the model’s dimension.Finally, through the comparisons between the numerical and simplified theoretical results for three scale ratio models, the simplified theoretical model of the pressure difference and friction forces exerted by ISWs on FPSO is applied for large-scale or full-scale FPSO.展开更多
Urban waste solids are now becoming one of the most crucial environmental problems. There are several different kinds of technologies normally used for waste solids disposal, among which landfill is more favorable in ...Urban waste solids are now becoming one of the most crucial environmental problems. There are several different kinds of technologies normally used for waste solids disposal, among which landfill is more favorable in China than others, especially for urban waste solids. Most of the design works up to now are based on a roughly estimation of the amount of urban waste solids without any theoretical support, which lead to a series problems. To meet the basic information requirements for the design work, the amount of the urban waste solids was predicted in this research by applying the gray theoretical model GM (1,1) through non linear differential equation simulation. The model parameters were estimated with the least square method (LSM) by running a certain MATALAB program, and the hypothesis test results show that the residual between the prediction value and the actual value approximately comply with the normal distribution N (0,0 21 2), and the probability of the residual within the range (-0 17, 0 19) is more than 95%, which indicate obviously that the model can be well used for the prediction of the amount of waste solids and those had been already testified by the latest two years data about the urban waste solids from Loudi City of China. With this model, the predicted amount of the waste solids produced in Loudi City in the next 30 years is 8049000 ton in total.展开更多
Abstract With the recent products being more reliable, engineers cannot obtain enough failure or degradation information through the design period and even the product lifetime, therefore, accel erated life test （ALT...Abstract With the recent products being more reliable, engineers cannot obtain enough failure or degradation information through the design period and even the product lifetime, therefore, accel erated life test （ALT） ihas become the most popular way to quantify the life characteristics of prod ucts. Test design is the most essential topic, such as testing duration, stress profile, data inference, etc. In this paper, a method and procedure based on theoretical life models is proposed to determine the accelerated stress profile. Firstly, the method for theoretical life calculation is put forward based on the main failure mechanism analysis and the theoretical life models. Secondly, the method is pro vided to determine the accelerated stress profile, including the method to determine the accelerated stress types and the stress range on the basis of the main failure mechanism analysis, the method to determine the acceleration factor and the accelerated stress level based on life quantitative calcula tion models, and the collaborative analysis method of the accelerated test time while taking the mul tiple failure mechanisms into consideration. Lastly, the actuator is taken as an example to describe the procedure of the method and the engineering applicability and the validity are verified.展开更多
As a major aspect of the ′China Model′, urbanization in China is being heatedly discussed in the Anglophone literature in the last two decades. By considering China′s urbanization as a ′testing ground′ of ′west...As a major aspect of the ′China Model′, urbanization in China is being heatedly discussed in the Anglophone literature in the last two decades. By considering China′s urbanization as a ′testing ground′ of ′western′ theories, these studies are important for the understanding of China′s ongoing urban restructuring and exchanging knowledge with ′western′ insights. Based on a survey of existing studies, this paper identifies various endogenous and exogenous concepts and explanations of China′s urbanization. It is suggested that China′s urbanization is mainly driven by a combination of political decentralization and neoliberalization with various forms of social stratification and mobility. However, it is argued that the distinctness of the ′China Model′, which is usually used to support the legitimacy of studies of China′s urbanization, has led to many controversial arguments and diminished the due contributions of Chinese scholars in the knowledge production of China′s urbanization. To consolidate the legitimacy of studies on China′s urbanization and enhance the roles of Chinese scholars, we suggest future studies to pay more attentions to the fundamental theories with looser constraints and ′true questions′ on China′s urbanization.展开更多
On the basis of the existing originally modified calculation models of theoretical combustion temperature（TCT）,some factors,such as the combustion ratio of pulverized coal injection（PCI）,the decomposition heat of ...On the basis of the existing originally modified calculation models of theoretical combustion temperature（TCT）,some factors,such as the combustion ratio of pulverized coal injection（PCI）,the decomposition heat of PCI and the heat consumption of SiO2 in ash reduced in high temperature environment,were amended and improved to put forward a more comprehensive model for calculating TCT.The influences of each improvement on TCT were studied and the results were analyzed compared with those of traditional model and originally modified model,which showed that the present model could reflect the thermal state of a hearth more effectively.展开更多
This paper presents a theoretical model on the normal(head-on) collision between soft-spheres on the basis of elastic loading of the Hertz contact for compression process and a nonlinear plastic unloading for restitut...This paper presents a theoretical model on the normal(head-on) collision between soft-spheres on the basis of elastic loading of the Hertz contact for compression process and a nonlinear plastic unloading for restitution one,in which the parameters all are determined in terms of the material and geometric ones of the spheres,and the behaviors of perfect elastic,inelastic,and perfect plastic collisions appeared in the classical mechanics are fully described once a value of coefficient of restitution is specified in the region of 0 ≤ ε ≤ 1.After an empirical formula of the coefficient of restitution dependent on the impact velocity is suggested to fit the existing experimental measurements by means of the least square method,the predictions of the dependency and the collision duration are in well quantitative agreement with their experimental measurements.It is found that the measurable quantities are dependent on both the impact velocity and the parameters of spheres.Following this model,finally,an approach to determine the spring coefficient in the linear viscoelastic model of the collision is also displayed.These results obtained here will be significantly beneficial for the applications where a collision model is requested in the simulations of relevant grain flows and impact dynamics etc..展开更多
Axial piston pumps have been widely used in aircraft hydraulic systems to supply the system with pressurized fluid. The continuous improvement of the aircraft performance has put forward the demand on aviation piston ...Axial piston pumps have been widely used in aircraft hydraulic systems to supply the system with pressurized fluid. The continuous improvement of the aircraft performance has put forward the demand on aviation piston pumps for high power density, safety, and reliability. The lubricating interfaces in axial piston machines are the key design issue that greatly determines the pump performance and service life. The cylinder block/valve plate interface is one of these critical lubricating interfaces and has received considerable attention from many researchers in the last half century. This study aims to review the state-of-the-art literature on the cylinder block/valve plate interface comprehensively and systematically. First, we introduce various theoretical models developed to investigate the lubrication behaviors of the interface and compare them in terms of their assumptions and limitations. Second, the experimental studies on the cylinder block/valve plate interface are presented comprehensively, where the involved test rigs are divided into three types according to their fidelity levels and measurement functionality. Third, we summarize some typical approaches of structure optimization, surface shaping, and surface strengthening, which help improve the load-carrying and anti-wear capacities of the interface under severe operating conditions. Finally, the challenges and future trends of the cylinder block/valve plate interface research are discussed briefly.展开更多
The theoretical flame temperature （TFT） before tuyere, always highly concerned by blast furnace （BF） operators, is one of the most important parameters for evaluating the thermal state of hearth. However, some inf...The theoretical flame temperature （TFT） before tuyere, always highly concerned by blast furnace （BF） operators, is one of the most important parameters for evaluating the thermal state of hearth. However, some influ- encing parameters, for example, the SiO2 reduction by carbon, were always neglected or inaccurate when calculating the TFT. According to the definition of TFT, the temperature of coke into raceway and the reduction rate of SiO2 in ash of coke and pulverized coal were obtained by analyzing the samples before tuyere in blast furnace. Taking full ac- count of different factors, a modified model for calculating the TFT in blast furnace was established. The effects of the oxygen enrichment rate, the reduction rate of SiO2 in raceway, the ash content in coke and pulverized coal and the pulverized coal injection （PCI） rate on TFT were determined quantitatively. The modified model was applied to selecting the used coal for PCI in blast furnace. Considering the different SiO2 contents of mixed coal, the calculated TFT remained a stable level. This showed that the selected coal could be suitable for PCI in blast furnace.展开更多
Based on current theories of diffusion and creep cavity closure at high temperature, a theoretical analysis of phase transformation diffusion bonding for T8/T8 eutectoid steel is carried out. The diffusion bonding is ...Based on current theories of diffusion and creep cavity closure at high temperature, a theoretical analysis of phase transformation diffusion bonding for T8/T8 eutectoid steel is carried out. The diffusion bonding is mainly described as two-stage process: Ⅰ The interfacial cavity with shape change from diamond to cylinder.Ⅱ The radius of the cylindrical cavity are reduced and eliminated gradually. A new theoretical model is established for the process of transformation superplastic diffusion bonding (TSDB) on the basis of a theoretical model for isothermal superplastic diffusion. The model can predict the bonding quality which is affected by technological parameters, such as limit cycling temperature, the compressive stress, the numbers of thermal cycles and temperature cycling through the phase transformation in the thermal cycling and so on. Results show that the maximum temperature, the compressive stress, the numbers of thermal cycles and the rate of temperature changing speed in the thermal cycling have an important influence on TSDB process. Meanwhile, reasonable technological parameters chosen from theoretical analysis is in good agreement with those obtained from experimental results.展开更多
The current design and optimization of the occupant restraint system（ORS） are based on numerous actual tests and mathematic simulations. These two methods are overly time-consuming and complex for the concept design...The current design and optimization of the occupant restraint system（ORS） are based on numerous actual tests and mathematic simulations. These two methods are overly time-consuming and complex for the concept design phase of the ORS, though they＇re quite effective and accurate. Therefore, a fast and directive method of the design and optimization is needed in the concept design phase of the ORS. Since the airbag system is a crucial part of the ORS, in this paper, a theoretical model for the vehicle airbag is established in order to clarify the interaction between occupants and airbags, and further a fast design and optimization method of airbags in the concept design phase is made based on the proposed theoretical model. First, the theoretical expression of the simplified mechanical relationship between the airbag＇s design parameters and the occupant response is developed based on classical mechanics, then the momentum theorem and the ideal gas state equation are adopted to illustrate the relationship between airbag＇s design parameters and occupant response. By using MATLAB software, the iterative algorithm method and discrete variables are applied to the solution of the proposed theoretical model with a random input in a certain scope. And validations by MADYMO software prove the validity and accuracy of this theoretical model in two principal design parameters, the inflated gas mass and vent diameter, within a regular range. This research contributes to a deeper comprehension of the relation between occupants and airbags, further a fast design and optimization method for airbags＇ principal parameters in the concept design phase, and provides the range of the airbag＇s initial design parameters for the subsequent CAE simulations and actual tests.展开更多
The excellent vectoring characteristic of Dual Synthetic Jet(DSJ)provides a new control strategy for the active flow control,such as thrust vectoring control,large area cooling,separated flow control and so on.For inc...The excellent vectoring characteristic of Dual Synthetic Jet(DSJ)provides a new control strategy for the active flow control,such as thrust vectoring control,large area cooling,separated flow control and so on.For incompressible flow,the influence relation of source variables,such as structure parameters of actuators,driving parameters and material attributes of piezoelectric vibrating diaphragm,on the vectoring DSJ and a theoretical model are established based on theoretical and regression analysis,which are all verified by numerical simulations.The two synthetic jets can be deemed as a main flow with a higher jet velocity and a disturbing flow with a lower jet velocity.The results indicate that the influence factors contain the low-pressure area formed at the exit of the disturbing flow,which could promote the vectoring deflection,and the impact effect of the disturbing flow and the suppressive effect of the main flow with the effect of restraining the vectoring deflection.The vectoring angle is a complex parameter coupled by all source variables.The detailed theoretical model,whose error is controlled within 3.6 degrees,can be used to quantitatively assess the vectoring feature of DSJ and thus to provide a guidance for designing the control law applied in the active flow control.展开更多
As an essential model of magnetoelastic interaction between magnetic field and mechanical deformation, the study on magnetoelastic buckling phenomenon of soft ferromagnetic plates in a magnetic environment has been co...As an essential model of magnetoelastic interaction between magnetic field and mechanical deformation, the study on magnetoelastic buckling phenomenon of soft ferromagnetic plates in a magnetic environment has been conducted. One of the key steps for the theoretical prediction of the critical magnetic field is how to formulate magnetic force exerted on the magnetized medium. Till today, the theoretical predictions, from theoretical models in publications, of the magnetoelastic buckling of ferromagnetic cantilevered beam-plate in transverse magnetic field are all higher than their experimental data. Sometimes, the discrepancy between them is as high as 100%. In this paper, the macroscope formulation of the magnetic forces is strictly obtained from the microscope Amperion current model. After that, a new theoretical model is established to describe the magnetoelastic buckling phenomenon of ferromagnetic thin plates with geometrically nonlinear deformation in a nonuniform transverse magnetic field. The numerical method for quantitative analysis is employed by combining the finite elemental method for magnetic fields and the finite difference method for deformation of plates. The numerical results obtained from this new theoretical model show that the theoretical predictions of critical values of the buckling magnetic field for the ferromagnetic cantilevered beam-plate are in excellent agreement with their experimental data. By the way, the region of applicability to the Moon-Pao's model, or the couple model, is checked by quantitative results.展开更多
To investigate the effects of temperature and moisture content(MC) on acoustic wave velocity(AWV)in wood,the relationships between wood temperature,MC,and AWV were theoretically analyzed.According to the theoretical p...To investigate the effects of temperature and moisture content(MC) on acoustic wave velocity(AWV)in wood,the relationships between wood temperature,MC,and AWV were theoretically analyzed.According to the theoretical propagation characteristics of the acoustic waves in the wood mixture and the differences in velocity among various media(including ice,water,pure wood or oven-dried wood),theoretical relationships of temperature,MC,and AWV were established,assuming that the samples in question were composed of a simple mixture of wood and water or of wood and ice.Using the theoretical model,the phase transition of AWV in green wood near the freezing point(as derived from previous experimental results) was plausibly described.By comparative analysis between theoretical and experimental models for American red pine(Pinus resinosa) samples,it was established that the theoretically predicted AWV values matched the experiment results when the temperature of the wood was below the freezing point of water,with an averageprediction error of 1.66%.The theoretically predicted AWV increased quickly in green wood as temperature decreased and changed suddenly near 0 °C,consistent with the experimental observations.The prediction error of the model was relatively large when the temperature of the wood was above the freezing point,probably due to an overestimation of the effect of the liquid water content on the acoustic velocity and the limited variables of the model.The high correlation between the predicted and measured acoustic velocity values in frozen wood samples revealed the mechanisms of temperature,MC,and water status and how these affected the wood(particularly its acoustic velocity below freezing point of water).This result also verified the reliability of a previous experimental model used to adjust for the effect of temperature during field testing of trees.展开更多
The study of irradiation hardening and embrittlement is critically important for the development of next-generation structural materials tolerant to neutron irradiation,and could dramatically affect the approach to th...The study of irradiation hardening and embrittlement is critically important for the development of next-generation structural materials tolerant to neutron irradiation,and could dramatically affect the approach to the design of components for advanced nuclear reactors.In addition,a growing interest is observed in the field of research and development of irradiation-resistant materials.This review aims to provide an overview of the theoretical development related to irradiation hardening and embrittlement at moderate irradiation conditions achieved in recent years,which can help extend our fundamental knowledge on nuclear structural materials.After a general introduction to the irradiation effects on metallic materials,recent research progress covering theoretical modelling is summarized for different types of structural materials.The fundamental mechanisms are elucidated within a wide range of temporal and spatial scales.This review closes with the current understanding of irradiation hardening and embrittlement,and puts some perspectives deserving further study.展开更多
In this paper, the basic equations of beam-wave interaction for designing the 220 GHz folded waveguide （FW） backward wave oscillator （BWO） are described. On the whole, these equations are mainly classified into sm...In this paper, the basic equations of beam-wave interaction for designing the 220 GHz folded waveguide （FW） backward wave oscillator （BWO） are described. On the whole, these equations are mainly classified into small signal model （SSM）, large signal model （LSM）, and simplified small signal model （SSSM）. Using these linear and nonlinear one-dimensional （1D） models, the oscillation characteristics of the FW BWO of a given configuration of slow wave struc- ture （SWS） can be calculated by numerical iteration algorithm, which is more time efficient than three-dimensional （3D） particle-in-cell （PIC） simulation. The SSSM expressed by analytical formulas is innovatively derived for determining the initial values of the FW SWS conveniently. The dispersion characteristics of the FW are obtained by equivalent circuit analysis. The space charge effect, the end reflection effect, the lossy wall effect, and the relativistic effect are all considered in our models to offer more accurate results. The design process of the FW BWO tube with output power of watt scale in a frequency range between 215 GHz and 225 GHz based on these 1D models is demonstrated. The 3D PIC method is adopted to verify the theoretical design results, which shows that they are in good agreement with each other.展开更多
In this study,through experimental research and an investigation on large datasets of the durability parameters in ocean engineering,the values,ranges,and types of distribution of the durability parameters employed fo...In this study,through experimental research and an investigation on large datasets of the durability parameters in ocean engineering,the values,ranges,and types of distribution of the durability parameters employed for the durability design in ocean engineering in northern China were confirmed.Based on a modified theoretical model of chloride diffusion and the reliability theory,the service lives of concrete structures exposed to the splash,tidal,and underwater zones were calculated.Mixed concrete proportions meeting the requirement of a service life of 100 or 120 years were designed,and a cover thickness requirement was proposed.In addition,the effects of the different time-varying relationships of the boundary condition(Cs)and diffusion coefficient(Df)on the service life were compared;the results showed that the time-varying relationships used in this study(i.e.,Cscontinuously increased and then remained stable,and Dfcontinuously decreased and then remained stable)were beneficial for the durability design of concrete structures in marine environment.展开更多
To avoid the machine problems of excessive axial force, complex process flow and frequent tool changing during robotic drilling holes, a new hole-making technology (i.e., helical milling hole) was introduced for desig...To avoid the machine problems of excessive axial force, complex process flow and frequent tool changing during robotic drilling holes, a new hole-making technology (i.e., helical milling hole) was introduced for designing a new robotic helical milling hole system, which could further improve robotic hole-making ability in airplane digital assembly. After analysis on the characteristics of helical milling hole, advantages and limitations of two typical robotic helical milling hole systems were summarized. Then, vector model of helical milling hole movement was built on vector analysis method. Finally, surface roughness calculation formula was deduced according to the movement principle of helical milling hole, then the influence of main technological parameters on surface roughness was analyzed. Analysis shows that theoretical surface roughness of hole becomes poor with the increase of tool speed ratio and revolution radius. Meanwhile, the roughness decreases according to the increase of tool teeth number. The research contributes greatly to the construction of roughness prediction model in helical milling hole.展开更多
The Value of the World＇s Ecosystem Services and Natural Capital by Costanza in 1997 is generally regarded as a monumem for the research of valuing ecosystem services. However, the classification of ecosystem services...The Value of the World＇s Ecosystem Services and Natural Capital by Costanza in 1997 is generally regarded as a monumem for the research of valuing ecosystem services. However, the classification of ecosystem services, the method of various services summation and the purpose for static global value had be confronted by many criticisms. Based on the summary of these criticisms, suggestions, related function assessment and further study direction, the sustainability of ecosystem Services is presented. The two basic indicators in ecology, productivity and biodiversity, respectively charactering the ability of producing and self-organizing, not only represent the internal function of ecosystem, but also are proportioned to its external function of supporting and providing for human life. On presenting the general.form of ecosystem services assessment, this paper improves the mathematical formula by giving a function adjusting coefficient composea of productivity and biodiversity. Theoretically, the integration of the two indicators reflects the changes of ecosystem services at spatial and temporal scales, can physically assess the sustainability of ecosystem services, and build a firm scientific fundament of value assessment for ecosystem services. Objectively, its application should be strictly tested in next step.展开更多
基金supported by the National Key Research and Development program(2022YFA1504000)the National Natural Science Foundation of China(22302101)+4 种基金the Fundamental Research Funds for the Central Universities(63185015)Shenzhen Science and Technology Program(JCYJ20210324121002007,JCYJ20230807151503007)Yunnan Provincial Science and Technology Project at Southwest United Graduate School(202402AO370001)China Postdoctoral Science Foundation(2022M721699)Guangdong Basic and Applied Basic Research Foundation(2024A1515010347).
文摘Reconstruction during the oxygen evolution reaction(OER)significantly transforms the geometric structure of transition metal compounds,leading to enhanced catalytic performance.However,the resulting structural disorder complicates the development of accurate theoretical models.In this study,CoS2 is used as a model system to establish a framework for rationally modeling reconstructed OER catalysts based on density functional theory(DFT).In the reconstruction process,sulfur atoms are likely to be substituted by oxygen atoms,leading to the formation of the CoOOH phase.Based on the difference in reconstruction degree,we constructed three types of models:doping,heterostructure,and fully reconstructed,representing the reconstruction degree from minimal to full phase transition,respectively.Fully reconstructed models,which account for strain and vacancy effects,effectively simulate the unique coordination environments of reconstructed catalysts.Model e-CoOOH achieves a theoretical overpotential of 0.38 V,outperforming pristine CoOOH(0.56 V),demonstrating that the unique structural features resulting from reconstruction improve OER performance.The doping model and the heterostructure model are helpful to explain the electronic structure and performance transformation of the reconstruction process.This work provides a rational theoretical modeling approach,which is conducive to improving the reliability of the theoretical OER performance of the reconstructed catalyst.
基金support from the National Natural Science Foundation of China(Grant Nos.52378411,52208404)China National Railway Group Limited Science and Technology Research and Development Program(Grant No.K2023G041).
文摘During strike-slip fault dislocation,multiple fault planes are commonly observed.The resulting permanent ground deformation can lead to profound structural damage to tunnels.However,existing analytical models do not consider multiple fault planes.Instead,they concentrate the entire fault displacement onto a single fault plane for analysis,thereby giving rise to notable errors in the calculated results.To address this issue,a refined nonlinear theoretical model was established to analyze the mechanical responses of the tunnels subjected to multiple strike-slip fault dislocations.The analytical model considers the number of fault planes,nonlinear soil‒tunnel interactions,geometric nonlinearity,and fault zone width,leading to a significant improvement in its range of applicability and calculation accuracy.The results of the analytical model are in agreement,both qualitatively and quantitatively,with the model test and numerical results.Then,based on the proposed theoretical model,a sensitivity analysis of parameters was conducted,focusing on the variables such as the number of fault planes,fault plane distance(d),fault displacement ratio(η),burial depth(C),crossing angle(β),tunnel diameter(D),fault zone width(Wf),and strike-slip fault displacement(Δfs).The results show that the peak shear force(Vmax),bending moment(Mmax),and axial force(Nmax)decrease with increasing d.The Vmax of the tunnel is found at the fault plane with the largest fault displacement.C,D,andΔfs contribute to the increases in Vmax,Mmax,and Nmax.Additionally,increasing the number of fault planes reduces Vmax and Mmax,whereas the variation in Nmax remains minimal.
基金financially supported by the National Natural Science Foundation of China(Grant No.11372184)the National Basic Research Program of China(973 Program,Grant Nos.2015CB251203-3 and 2013CB036103)
文摘Scale effect of ISWs loads on Floating Production Storage and Offloading(FPSO) is studied in this paper. The application conditions of KdV, eKdV and MCC ISWs theories are used in the numerical method. The depthaveraged velocities induced by ISWs are used for the velocity-inlet boundary. Three scale ratio numerical models λ=1, 20 and 300 were selected, which the scale ratio is the size ratio of numerical models to the experimental model.The comparisons between the numerical and former experimental results are performed to verify the feasibility of numerical method. The comparisons between the numerical and simplified theoretical results are performed to discuss the applicability of the simplified theoretical model summarized from the load experiments. Firstly, the numerical results of λ=1 numerical model showed a good agreement with former experimental and simplified theoretical results. It is feasible to simulate the ISWs loads on FPSO by the numerical method. Secondly, the comparisons between the results of three scale ratio numerical models and experimental results indicated that the scale ratios have more significant influence on the experimental horizontal forces than the vertical forces. The scale effect of horizontal forces mainly results from the different viscosity effects associated with the model’s dimension.Finally, through the comparisons between the numerical and simplified theoretical results for three scale ratio models, the simplified theoretical model of the pressure difference and friction forces exerted by ISWs on FPSO is applied for large-scale or full-scale FPSO.
文摘Urban waste solids are now becoming one of the most crucial environmental problems. There are several different kinds of technologies normally used for waste solids disposal, among which landfill is more favorable in China than others, especially for urban waste solids. Most of the design works up to now are based on a roughly estimation of the amount of urban waste solids without any theoretical support, which lead to a series problems. To meet the basic information requirements for the design work, the amount of the urban waste solids was predicted in this research by applying the gray theoretical model GM (1,1) through non linear differential equation simulation. The model parameters were estimated with the least square method (LSM) by running a certain MATALAB program, and the hypothesis test results show that the residual between the prediction value and the actual value approximately comply with the normal distribution N (0,0 21 2), and the probability of the residual within the range (-0 17, 0 19) is more than 95%, which indicate obviously that the model can be well used for the prediction of the amount of waste solids and those had been already testified by the latest two years data about the urban waste solids from Loudi City of China. With this model, the predicted amount of the waste solids produced in Loudi City in the next 30 years is 8049000 ton in total.
基金supported by the Ministry Level Project of China
文摘Abstract With the recent products being more reliable, engineers cannot obtain enough failure or degradation information through the design period and even the product lifetime, therefore, accel erated life test （ALT） ihas become the most popular way to quantify the life characteristics of prod ucts. Test design is the most essential topic, such as testing duration, stress profile, data inference, etc. In this paper, a method and procedure based on theoretical life models is proposed to determine the accelerated stress profile. Firstly, the method for theoretical life calculation is put forward based on the main failure mechanism analysis and the theoretical life models. Secondly, the method is pro vided to determine the accelerated stress profile, including the method to determine the accelerated stress types and the stress range on the basis of the main failure mechanism analysis, the method to determine the acceleration factor and the accelerated stress level based on life quantitative calcula tion models, and the collaborative analysis method of the accelerated test time while taking the mul tiple failure mechanisms into consideration. Lastly, the actuator is taken as an example to describe the procedure of the method and the engineering applicability and the validity are verified.
基金Under the auspices of National Natural Science Foundation of China(No.41271165,41130747)Humanities and Social Science Research Planning Fund,Ministry of Education of China(No.12YJAGJW007)
文摘As a major aspect of the ′China Model′, urbanization in China is being heatedly discussed in the Anglophone literature in the last two decades. By considering China′s urbanization as a ′testing ground′ of ′western′ theories, these studies are important for the understanding of China′s ongoing urban restructuring and exchanging knowledge with ′western′ insights. Based on a survey of existing studies, this paper identifies various endogenous and exogenous concepts and explanations of China′s urbanization. It is suggested that China′s urbanization is mainly driven by a combination of political decentralization and neoliberalization with various forms of social stratification and mobility. However, it is argued that the distinctness of the ′China Model′, which is usually used to support the legitimacy of studies of China′s urbanization, has led to many controversial arguments and diminished the due contributions of Chinese scholars in the knowledge production of China′s urbanization. To consolidate the legitimacy of studies on China′s urbanization and enhance the roles of Chinese scholars, we suggest future studies to pay more attentions to the fundamental theories with looser constraints and ′true questions′ on China′s urbanization.
基金Item Sponsored by National Natural Science Foundation of China(50974143)
文摘On the basis of the existing originally modified calculation models of theoretical combustion temperature（TCT）,some factors,such as the combustion ratio of pulverized coal injection（PCI）,the decomposition heat of PCI and the heat consumption of SiO2 in ash reduced in high temperature environment,were amended and improved to put forward a more comprehensive model for calculating TCT.The influences of each improvement on TCT were studied and the results were analyzed compared with those of traditional model and originally modified model,which showed that the present model could reflect the thermal state of a hearth more effectively.
基金supported by the Key Fund of the National Natural Science Foundation of China (11032006)
文摘This paper presents a theoretical model on the normal(head-on) collision between soft-spheres on the basis of elastic loading of the Hertz contact for compression process and a nonlinear plastic unloading for restitution one,in which the parameters all are determined in terms of the material and geometric ones of the spheres,and the behaviors of perfect elastic,inelastic,and perfect plastic collisions appeared in the classical mechanics are fully described once a value of coefficient of restitution is specified in the region of 0 ≤ ε ≤ 1.After an empirical formula of the coefficient of restitution dependent on the impact velocity is suggested to fit the existing experimental measurements by means of the least square method,the predictions of the dependency and the collision duration are in well quantitative agreement with their experimental measurements.It is found that the measurable quantities are dependent on both the impact velocity and the parameters of spheres.Following this model,finally,an approach to determine the spring coefficient in the linear viscoelastic model of the collision is also displayed.These results obtained here will be significantly beneficial for the applications where a collision model is requested in the simulations of relevant grain flows and impact dynamics etc..
基金supported by Chinese Civil Aircraft Project [No. MJ-2017-S49]China National Postdoctoral Program for Innovative Talents [No. BX20200210]China Postdoctoral Science Foundation [No. 2019M660086]。
文摘Axial piston pumps have been widely used in aircraft hydraulic systems to supply the system with pressurized fluid. The continuous improvement of the aircraft performance has put forward the demand on aviation piston pumps for high power density, safety, and reliability. The lubricating interfaces in axial piston machines are the key design issue that greatly determines the pump performance and service life. The cylinder block/valve plate interface is one of these critical lubricating interfaces and has received considerable attention from many researchers in the last half century. This study aims to review the state-of-the-art literature on the cylinder block/valve plate interface comprehensively and systematically. First, we introduce various theoretical models developed to investigate the lubrication behaviors of the interface and compare them in terms of their assumptions and limitations. Second, the experimental studies on the cylinder block/valve plate interface are presented comprehensively, where the involved test rigs are divided into three types according to their fidelity levels and measurement functionality. Third, we summarize some typical approaches of structure optimization, surface shaping, and surface strengthening, which help improve the load-carrying and anti-wear capacities of the interface under severe operating conditions. Finally, the challenges and future trends of the cylinder block/valve plate interface research are discussed briefly.
基金Sponsored by National Natural Science Foundation of China and Baosteel(51274026,50874129)National High-tech Research and Development Program of China(2009AA06Z105)
文摘The theoretical flame temperature （TFT） before tuyere, always highly concerned by blast furnace （BF） operators, is one of the most important parameters for evaluating the thermal state of hearth. However, some influ- encing parameters, for example, the SiO2 reduction by carbon, were always neglected or inaccurate when calculating the TFT. According to the definition of TFT, the temperature of coke into raceway and the reduction rate of SiO2 in ash of coke and pulverized coal were obtained by analyzing the samples before tuyere in blast furnace. Taking full ac- count of different factors, a modified model for calculating the TFT in blast furnace was established. The effects of the oxygen enrichment rate, the reduction rate of SiO2 in raceway, the ash content in coke and pulverized coal and the pulverized coal injection （PCI） rate on TFT were determined quantitatively. The modified model was applied to selecting the used coal for PCI in blast furnace. Considering the different SiO2 contents of mixed coal, the calculated TFT remained a stable level. This showed that the selected coal could be suitable for PCI in blast furnace.
文摘Based on current theories of diffusion and creep cavity closure at high temperature, a theoretical analysis of phase transformation diffusion bonding for T8/T8 eutectoid steel is carried out. The diffusion bonding is mainly described as two-stage process: Ⅰ The interfacial cavity with shape change from diamond to cylinder.Ⅱ The radius of the cylindrical cavity are reduced and eliminated gradually. A new theoretical model is established for the process of transformation superplastic diffusion bonding (TSDB) on the basis of a theoretical model for isothermal superplastic diffusion. The model can predict the bonding quality which is affected by technological parameters, such as limit cycling temperature, the compressive stress, the numbers of thermal cycles and temperature cycling through the phase transformation in the thermal cycling and so on. Results show that the maximum temperature, the compressive stress, the numbers of thermal cycles and the rate of temperature changing speed in the thermal cycling have an important influence on TSDB process. Meanwhile, reasonable technological parameters chosen from theoretical analysis is in good agreement with those obtained from experimental results.
基金Supported by National Natural Science Foundation of China(Grant No.51375203)Open Foundation of Zhejiang Province Key Laboratory of Automobile Safety of China(Grant No.LHY1308J00368)Changchun Municipal Science and Technology Planning Project of China(Grant No.12ZX79)
文摘The current design and optimization of the occupant restraint system（ORS） are based on numerous actual tests and mathematic simulations. These two methods are overly time-consuming and complex for the concept design phase of the ORS, though they＇re quite effective and accurate. Therefore, a fast and directive method of the design and optimization is needed in the concept design phase of the ORS. Since the airbag system is a crucial part of the ORS, in this paper, a theoretical model for the vehicle airbag is established in order to clarify the interaction between occupants and airbags, and further a fast design and optimization method of airbags in the concept design phase is made based on the proposed theoretical model. First, the theoretical expression of the simplified mechanical relationship between the airbag＇s design parameters and the occupant response is developed based on classical mechanics, then the momentum theorem and the ideal gas state equation are adopted to illustrate the relationship between airbag＇s design parameters and occupant response. By using MATLAB software, the iterative algorithm method and discrete variables are applied to the solution of the proposed theoretical model with a random input in a certain scope. And validations by MADYMO software prove the validity and accuracy of this theoretical model in two principal design parameters, the inflated gas mass and vent diameter, within a regular range. This research contributes to a deeper comprehension of the relation between occupants and airbags, further a fast design and optimization method for airbags＇ principal parameters in the concept design phase, and provides the range of the airbag＇s initial design parameters for the subsequent CAE simulations and actual tests.
基金supported by the National Natural Science Foundation of China(Nos.11972369 and 11872374)。
文摘The excellent vectoring characteristic of Dual Synthetic Jet(DSJ)provides a new control strategy for the active flow control,such as thrust vectoring control,large area cooling,separated flow control and so on.For incompressible flow,the influence relation of source variables,such as structure parameters of actuators,driving parameters and material attributes of piezoelectric vibrating diaphragm,on the vectoring DSJ and a theoretical model are established based on theoretical and regression analysis,which are all verified by numerical simulations.The two synthetic jets can be deemed as a main flow with a higher jet velocity and a disturbing flow with a lower jet velocity.The results indicate that the influence factors contain the low-pressure area formed at the exit of the disturbing flow,which could promote the vectoring deflection,and the impact effect of the disturbing flow and the suppressive effect of the main flow with the effect of restraining the vectoring deflection.The vectoring angle is a complex parameter coupled by all source variables.The detailed theoretical model,whose error is controlled within 3.6 degrees,can be used to quantitatively assess the vectoring feature of DSJ and thus to provide a guidance for designing the control law applied in the active flow control.
基金This project was supported in part by the National Natural Science Foundation of ChinaFoundation of the SEdC of China for Returned Chinese Scholars from Abroad
文摘As an essential model of magnetoelastic interaction between magnetic field and mechanical deformation, the study on magnetoelastic buckling phenomenon of soft ferromagnetic plates in a magnetic environment has been conducted. One of the key steps for the theoretical prediction of the critical magnetic field is how to formulate magnetic force exerted on the magnetized medium. Till today, the theoretical predictions, from theoretical models in publications, of the magnetoelastic buckling of ferromagnetic cantilevered beam-plate in transverse magnetic field are all higher than their experimental data. Sometimes, the discrepancy between them is as high as 100%. In this paper, the macroscope formulation of the magnetic forces is strictly obtained from the microscope Amperion current model. After that, a new theoretical model is established to describe the magnetoelastic buckling phenomenon of ferromagnetic thin plates with geometrically nonlinear deformation in a nonuniform transverse magnetic field. The numerical method for quantitative analysis is employed by combining the finite elemental method for magnetic fields and the finite difference method for deformation of plates. The numerical results obtained from this new theoretical model show that the theoretical predictions of critical values of the buckling magnetic field for the ferromagnetic cantilevered beam-plate are in excellent agreement with their experimental data. By the way, the region of applicability to the Moon-Pao's model, or the couple model, is checked by quantitative results.
基金funded by the National Natural Science Foundation of China(Grant Nos.31600453 and 31570547)Fundamental Research Funds for the Central Universities(Grant No.2572017EB02)Natural Science Foundation of Heilongjiang Province,China(Grant No.C201403)
文摘To investigate the effects of temperature and moisture content(MC) on acoustic wave velocity(AWV)in wood,the relationships between wood temperature,MC,and AWV were theoretically analyzed.According to the theoretical propagation characteristics of the acoustic waves in the wood mixture and the differences in velocity among various media(including ice,water,pure wood or oven-dried wood),theoretical relationships of temperature,MC,and AWV were established,assuming that the samples in question were composed of a simple mixture of wood and water or of wood and ice.Using the theoretical model,the phase transition of AWV in green wood near the freezing point(as derived from previous experimental results) was plausibly described.By comparative analysis between theoretical and experimental models for American red pine(Pinus resinosa) samples,it was established that the theoretically predicted AWV values matched the experiment results when the temperature of the wood was below the freezing point of water,with an averageprediction error of 1.66%.The theoretically predicted AWV increased quickly in green wood as temperature decreased and changed suddenly near 0 °C,consistent with the experimental observations.The prediction error of the model was relatively large when the temperature of the wood was above the freezing point,probably due to an overestimation of the effect of the liquid water content on the acoustic velocity and the limited variables of the model.The high correlation between the predicted and measured acoustic velocity values in frozen wood samples revealed the mechanisms of temperature,MC,and water status and how these affected the wood(particularly its acoustic velocity below freezing point of water).This result also verified the reliability of a previous experimental model used to adjust for the effect of temperature during field testing of trees.
基金the National Natural Science foundation of China(NSFC)(Grants 11632001,11521202,11802344)Natural Science Foundation of Hunan Province,China(Grant 2019JJ50809).
文摘The study of irradiation hardening and embrittlement is critically important for the development of next-generation structural materials tolerant to neutron irradiation,and could dramatically affect the approach to the design of components for advanced nuclear reactors.In addition,a growing interest is observed in the field of research and development of irradiation-resistant materials.This review aims to provide an overview of the theoretical development related to irradiation hardening and embrittlement at moderate irradiation conditions achieved in recent years,which can help extend our fundamental knowledge on nuclear structural materials.After a general introduction to the irradiation effects on metallic materials,recent research progress covering theoretical modelling is summarized for different types of structural materials.The fundamental mechanisms are elucidated within a wide range of temporal and spatial scales.This review closes with the current understanding of irradiation hardening and embrittlement,and puts some perspectives deserving further study.
基金Project supported by the Innovative Research Foundation of China Academy of Engineering Physics(Grant No.426050502-2)
文摘In this paper, the basic equations of beam-wave interaction for designing the 220 GHz folded waveguide （FW） backward wave oscillator （BWO） are described. On the whole, these equations are mainly classified into small signal model （SSM）, large signal model （LSM）, and simplified small signal model （SSSM）. Using these linear and nonlinear one-dimensional （1D） models, the oscillation characteristics of the FW BWO of a given configuration of slow wave struc- ture （SWS） can be calculated by numerical iteration algorithm, which is more time efficient than three-dimensional （3D） particle-in-cell （PIC） simulation. The SSSM expressed by analytical formulas is innovatively derived for determining the initial values of the FW SWS conveniently. The dispersion characteristics of the FW are obtained by equivalent circuit analysis. The space charge effect, the end reflection effect, the lossy wall effect, and the relativistic effect are all considered in our models to offer more accurate results. The design process of the FW BWO tube with output power of watt scale in a frequency range between 215 GHz and 225 GHz based on these 1D models is demonstrated. The 3D PIC method is adopted to verify the theoretical design results, which shows that they are in good agreement with each other.
基金financial support provided by the National Natural Science Foundation of China(51508272,11832013,51878350,and 51678304)。
文摘In this study,through experimental research and an investigation on large datasets of the durability parameters in ocean engineering,the values,ranges,and types of distribution of the durability parameters employed for the durability design in ocean engineering in northern China were confirmed.Based on a modified theoretical model of chloride diffusion and the reliability theory,the service lives of concrete structures exposed to the splash,tidal,and underwater zones were calculated.Mixed concrete proportions meeting the requirement of a service life of 100 or 120 years were designed,and a cover thickness requirement was proposed.In addition,the effects of the different time-varying relationships of the boundary condition(Cs)and diffusion coefficient(Df)on the service life were compared;the results showed that the time-varying relationships used in this study(i.e.,Cscontinuously increased and then remained stable,and Dfcontinuously decreased and then remained stable)were beneficial for the durability design of concrete structures in marine environment.
基金Foundation item： Projects（50975141, 51005118） supported by the National Natural Science Foundation of China Projects（20091652018, 2010352005） supported by Aviation Science Fund of China Project（YKJ11-001） supported by Key Program of Nanjing College of Information Technology Institute, China
文摘To avoid the machine problems of excessive axial force, complex process flow and frequent tool changing during robotic drilling holes, a new hole-making technology (i.e., helical milling hole) was introduced for designing a new robotic helical milling hole system, which could further improve robotic hole-making ability in airplane digital assembly. After analysis on the characteristics of helical milling hole, advantages and limitations of two typical robotic helical milling hole systems were summarized. Then, vector model of helical milling hole movement was built on vector analysis method. Finally, surface roughness calculation formula was deduced according to the movement principle of helical milling hole, then the influence of main technological parameters on surface roughness was analyzed. Analysis shows that theoretical surface roughness of hole becomes poor with the increase of tool speed ratio and revolution radius. Meanwhile, the roughness decreases according to the increase of tool teeth number. The research contributes greatly to the construction of roughness prediction model in helical milling hole.
基金National Natural Sci-ence Foundation of China (Grant No. 30230090)
文摘The Value of the World＇s Ecosystem Services and Natural Capital by Costanza in 1997 is generally regarded as a monumem for the research of valuing ecosystem services. However, the classification of ecosystem services, the method of various services summation and the purpose for static global value had be confronted by many criticisms. Based on the summary of these criticisms, suggestions, related function assessment and further study direction, the sustainability of ecosystem Services is presented. The two basic indicators in ecology, productivity and biodiversity, respectively charactering the ability of producing and self-organizing, not only represent the internal function of ecosystem, but also are proportioned to its external function of supporting and providing for human life. On presenting the general.form of ecosystem services assessment, this paper improves the mathematical formula by giving a function adjusting coefficient composea of productivity and biodiversity. Theoretically, the integration of the two indicators reflects the changes of ecosystem services at spatial and temporal scales, can physically assess the sustainability of ecosystem services, and build a firm scientific fundament of value assessment for ecosystem services. Objectively, its application should be strictly tested in next step.
