Purely organic room-temperature phosphorescence(RTP)is current hotspot in the research fields of chemistry,biology,materials etc.Herein,we report that photo-thermal double response reversible ultralong RTP flexible el...Purely organic room-temperature phosphorescence(RTP)is current hotspot in the research fields of chemistry,biology,materials etc.Herein,we report that photo-thermal double response reversible ultralong RTP flexible elastic material with multicolor delayed fluorescence,which is constructed by 4-biphenylboronic acid(BOH),polyethylene glycol,2,2-bis(hydroxymethyl)propionic acid,isophorone diamine and isophorone diisocyanate copolymer.Importantly,the supramolecular phosphorescent elastomer not only exhibits extending RTP emission with a lifetime up to 1.21 s,but also gives a visible afterglow of 20 s via encapsulation of BOH unities by the deep cavities of hydroxypropyl-β-cyclodextrin(β-CD-HP)and in situ polymerization.Especially,after doping organic dyes(Fluorescein isothiocyanate,Sulforhodamine 101,Rhodamine B),supramolecular phosphorescent elastomer achieves multicolor delayed fluorescence realized by RTP energy transfer from phosphorescent donor to dye acceptors,which possesses reversible photo-thermal responsiveness and maintains high efficiency in delayed emission even after dozens of cycles.Present research provides a new approach for constructing multicolor delayed fluorescent supramolecular elastomers.展开更多
We synthesize hollow-structured Ag@Au nanoparticles with single porous shell and Ag@Au/Ag@Au double shells by using the galvanic replacement reaction and investigate their linear and nonlinear optical properties. Our ...We synthesize hollow-structured Ag@Au nanoparticles with single porous shell and Ag@Au/Ag@Au double shells by using the galvanic replacement reaction and investigate their linear and nonlinear optical properties. Our results show that the surface plasmon resonance wavelength of the hollow porous nanoparticles could be easily tuned in a wide range in the visible and near infrared region by controlling the volume of HAuCl4. The nonlinear optical refraction of the double-shelled Ag@Au/Ag@Au nanoparticles is prominently enhanced by the plasmon resonance. Our findings may find applications in biosensors and nonlinear optical nanodevices.展开更多
In this study, we investigate the nonlinear cou- pling magneto-electric （ME） effect of a giant magnetostric- tive/piezoelectric composite cylinder. The nonlinear consti- tutive relations of the ME material are taken...In this study, we investigate the nonlinear cou- pling magneto-electric （ME） effect of a giant magnetostric- tive/piezoelectric composite cylinder. The nonlinear consti- tutive relations of the ME material are taken into account, and the influences of the nonlinear material properties on the ME effect are investigated for the static and dynamic cases, respectively. The influences of different constraint conditions on the ME effect are discussed. In the dynamic case considering nonlinear material properties, the double frequency ME response （The response frequency is twice the applied magnetic frequency） is obtained and discussed, which can be used to explain the experiment phenomenon in which the input signal with frequency f is converted to the output signal with 2f in ME laminated structures. Some calculations on nonlinear ME effect are conducted. The obtained results indicate that the nonlinear material properties affect not only the magnitude of the ME effect in the static case but also the ME response frequency in the dynamic case展开更多
The effects of doubled carbon dioxide on rainfall responses to radiative processes of water clouds are investigated in this study.Two groups of two-dimensional cloud-resolving model sensitivity experiments with regard...The effects of doubled carbon dioxide on rainfall responses to radiative processes of water clouds are investigated in this study.Two groups of two-dimensional cloud-resolving model sensitivity experiments with regard to pre-summer heavy rainfall around the summer solstice and tropical rainfall around the winter solstice are conducted and their five-day averages over the model domain are analyzed.In the presence of radiative effects of ice clouds,doubled carbon dioxide changes pre-summer rainfall from the decrease associated with the enhanced atmospheric cooling to the increase associated with the enhanced infrared cooling as a result of the exclusion of radiative effects of water clouds.Doubled carbon dioxide leads to the reduction in tropical rainfall,caused by the removal of radiative effects of water clouds through the suppressed infrared cooling.In the absence of radiative effects of ice clouds,doubled carbon dioxide changes pre-summer rainfall from the increase associated with the strengthened atmospheric warming to the decrease associated with the weakened release of latent heat caused by the elimination of radiative effects of water clouds.The exclusion of radiative effects of water clouds increases tropical rainfall through the strengthened infrared cooling,which is insensitive to the change in carbon dioxide.展开更多
基金financially supported by the National Natural Science Foundation of China(No.22131008)。
文摘Purely organic room-temperature phosphorescence(RTP)is current hotspot in the research fields of chemistry,biology,materials etc.Herein,we report that photo-thermal double response reversible ultralong RTP flexible elastic material with multicolor delayed fluorescence,which is constructed by 4-biphenylboronic acid(BOH),polyethylene glycol,2,2-bis(hydroxymethyl)propionic acid,isophorone diamine and isophorone diisocyanate copolymer.Importantly,the supramolecular phosphorescent elastomer not only exhibits extending RTP emission with a lifetime up to 1.21 s,but also gives a visible afterglow of 20 s via encapsulation of BOH unities by the deep cavities of hydroxypropyl-β-cyclodextrin(β-CD-HP)and in situ polymerization.Especially,after doping organic dyes(Fluorescein isothiocyanate,Sulforhodamine 101,Rhodamine B),supramolecular phosphorescent elastomer achieves multicolor delayed fluorescence realized by RTP energy transfer from phosphorescent donor to dye acceptors,which possesses reversible photo-thermal responsiveness and maintains high efficiency in delayed emission even after dozens of cycles.Present research provides a new approach for constructing multicolor delayed fluorescent supramolecular elastomers.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11174229,11204221 and 11374236the National Basic Research Program of China under Grant No 2011CB922201
文摘We synthesize hollow-structured Ag@Au nanoparticles with single porous shell and Ag@Au/Ag@Au double shells by using the galvanic replacement reaction and investigate their linear and nonlinear optical properties. Our results show that the surface plasmon resonance wavelength of the hollow porous nanoparticles could be easily tuned in a wide range in the visible and near infrared region by controlling the volume of HAuCl4. The nonlinear optical refraction of the double-shelled Ag@Au/Ag@Au nanoparticles is prominently enhanced by the plasmon resonance. Our findings may find applications in biosensors and nonlinear optical nanodevices.
基金supported by the National Natural Science Foundation of China (11072093)the State Key Program of National Natural Science of China (11032006)the Fundamental Research Funds for the Central Universities (lzujbky-2012-k05)
文摘In this study, we investigate the nonlinear cou- pling magneto-electric （ME） effect of a giant magnetostric- tive/piezoelectric composite cylinder. The nonlinear consti- tutive relations of the ME material are taken into account, and the influences of the nonlinear material properties on the ME effect are investigated for the static and dynamic cases, respectively. The influences of different constraint conditions on the ME effect are discussed. In the dynamic case considering nonlinear material properties, the double frequency ME response （The response frequency is twice the applied magnetic frequency） is obtained and discussed, which can be used to explain the experiment phenomenon in which the input signal with frequency f is converted to the output signal with 2f in ME laminated structures. Some calculations on nonlinear ME effect are conducted. The obtained results indicate that the nonlinear material properties affect not only the magnitude of the ME effect in the static case but also the ME response frequency in the dynamic case
基金Supported by the National Natural Science Foundation of China(41475039)National Key Basic Research and Development (973) Program of China(2015CB953601)
文摘The effects of doubled carbon dioxide on rainfall responses to radiative processes of water clouds are investigated in this study.Two groups of two-dimensional cloud-resolving model sensitivity experiments with regard to pre-summer heavy rainfall around the summer solstice and tropical rainfall around the winter solstice are conducted and their five-day averages over the model domain are analyzed.In the presence of radiative effects of ice clouds,doubled carbon dioxide changes pre-summer rainfall from the decrease associated with the enhanced atmospheric cooling to the increase associated with the enhanced infrared cooling as a result of the exclusion of radiative effects of water clouds.Doubled carbon dioxide leads to the reduction in tropical rainfall,caused by the removal of radiative effects of water clouds through the suppressed infrared cooling.In the absence of radiative effects of ice clouds,doubled carbon dioxide changes pre-summer rainfall from the increase associated with the strengthened atmospheric warming to the decrease associated with the weakened release of latent heat caused by the elimination of radiative effects of water clouds.The exclusion of radiative effects of water clouds increases tropical rainfall through the strengthened infrared cooling,which is insensitive to the change in carbon dioxide.
