Cylindrical and spherical (nonplanar) solitary waves (SWs) and double layers (DLs) in a multi-ion plasma system (containing inertial positively as well as negatively charged ions, non-inertial degenerate electrons, an...Cylindrical and spherical (nonplanar) solitary waves (SWs) and double layers (DLs) in a multi-ion plasma system (containing inertial positively as well as negatively charged ions, non-inertial degenerate electrons, and negatively charged static dust) are studied by employing the standard reductive perturbation method. The modified Gardner (MG) equation describing the nonlinear propagation of the dust ion-acoustic (DIA) waves is derived, and its nonplanar SWs and DLs solutions are numerically analyzed. The parametric regimes for the existence of SWs, which are associated with both positive and negative potential, and DLs which are associated with negative potential, are obtained. The basic features of nonplanar DIA SWs, and DLs, which are found to be different from planar ones, are also identified.展开更多
A precise theoretical investigation has been made on the cylindrical and spherical (nonplanar) Gardner solitons (GSs) and double layers (DLs) in a dusty electronegative plasma (composed of inertial positive and...A precise theoretical investigation has been made on the cylindrical and spherical (nonplanar) Gardner solitons (GSs) and double layers (DLs) in a dusty electronegative plasma (composed of inertial positive and negative ions, Maxwellian cold electrons, non-thermal hot electrons, and negatively charged static dust). The reductive perturbation method has been used in derivation of the modified Gardner (MG) equation describing the nonlinear propagation of the dust ion-acoustic (DIA) waves. The MG equation admits solitary waves (SWs) and DLs solutions for σ around its critical value σ c (where σc is the value of σ corresponding to the vanishing of the nonlinear coefficient of the Korteweg de-Vries (K-dV) equation). The nonplanar SWs and DLs solutions are numerically analyzed and the parametric regimes for the existence of the positive as well as negative SWs and negative DLs are obtained. The basic features of nonplanar DIA SWs and DLs, which are found to be different from planar ones, are also identified. The implications of our results to different space and laboratory dusty plasma situations, are discussed.展开更多
Simple and double layers first appeared in electrostatics and later found various applications in mathematical physics. In this paper, we present the jump discontinuity conditions for their second-order spatial deriva...Simple and double layers first appeared in electrostatics and later found various applications in mathematical physics. In this paper, we present the jump discontinuity conditions for their second-order spatial derivatives.展开更多
Large amplitude dust ion acoustic (DIA) solitons as well as double layers (DLs) are studied in a dusty plasma having a high-energy-tail electron distribution. The influence of electron deviation from the Maxwellia...Large amplitude dust ion acoustic (DIA) solitons as well as double layers (DLs) are studied in a dusty plasma having a high-energy-tail electron distribution. The influence of electron deviation from the Maxwellian distribution and ion streaming on the existence domain of solitons is discussed in the (M, f) space using the pseudo-potential approach. It is found that in the presence of streaming ions and for a fixed f, solitons may appear for larger values of M. This means that in the presence of ion streaming, high values of the Mach number are needed to have soliton. The DIA solitary waves profile is highly sensitive to the ion streaming speed. Their amplitude is found to decrease with an increase of the ion streaming speed. In addition, we find that the ion streaming effect may lead to the appearance of double layers. The results of this axticle should be useful in understanding the basic nonlinear features of DIA waves propagating in space dusty plasmas, especially those including a relative motion between species, such as comet tails and solar wind streams, etc.展开更多
The internal energy and specific heat of a Heisenberg ferro- antiferromagnetic double-layer system are studied by using spin-wave theory and the retarded Green function method at low temperatures. Numerical results sh...The internal energy and specific heat of a Heisenberg ferro- antiferromagnetic double-layer system are studied by using spin-wave theory and the retarded Green function method at low temperatures. Numerical results show that the antiferromagnetic intralayer coupling J2 has an important influence on internal energy and specific heat for a four-sublattice system with antiferromagnetic (or ferrimagnetic) interlayer couplings.展开更多
Spin-wave theory is used to study magnetic properties of ferromagnetic double layers with a ferrimagnetic interlayer coupling at zero temperature. The spin-wave spectra and four sublattices magnetizations and internal...Spin-wave theory is used to study magnetic properties of ferromagnetic double layers with a ferrimagnetic interlayer coupling at zero temperature. The spin-wave spectra and four sublattices magnetizations and internal energy are calculated by employing retarded Green function technique. The sublattice magnetizations at ground state are smaller than their classical values, owing to the zero-point quantum fluctuations of the spins.展开更多
Vortex double layers (VDLs) and vortex projectiles (VPs) are the essential coherent structures which emerge in the shock excited (s/f/s) planar parallel "curtain" simulations of a 2D shock tube with PPM. The...Vortex double layers (VDLs) and vortex projectiles (VPs) are the essential coherent structures which emerge in the shock excited (s/f/s) planar parallel "curtain" simulations of a 2D shock tube with PPM. These opposite signed layers, formed by shock induced baroclinic deposition of vorticity, "ind" and are strongly affected by secondary reflected shocks and vortex interactions. In our visiometric mode of working, we quantify several of these processes and introduce time epochs to discuss the emerging phenomena and normalizations to scale (collapse) the data at M =1.5 and 2.0. This versatile configuration, easily obtained in the laboratory, allows us to study the formation, evolution and reacceleration of VPs and stratified turbulence and mixing.展开更多
The small amplitude dust ion-acoustic double layers in a collisionless four-component unmagnetized dusty plasma system containing nonextensive electrons, inertial negative ions, Maxwellian positive ions, and negativel...The small amplitude dust ion-acoustic double layers in a collisionless four-component unmagnetized dusty plasma system containing nonextensive electrons, inertial negative ions, Maxwellian positive ions, and negatively charged static dust grains are investigated theoretically. Using the pseudo-potential approach and reductive perturbation method, an energy integral equation for the system has been derived and its solution in the form of double layers is obtained. The results appear that the existence regime of the double layer is very sensitive to the plasma parameters, e.g., electron nonextensivity,negative-to-positive ion number density ratio etc. It has been observed that for the selected set of parameters, the system supports rarefactive,(compressive) double layers depending upon the degree of nonextensivity of electrons.展开更多
A theoretical analysis on the electric double layer formed near the surface of an infinite cylinder with an elliptical cross section and a prescribed electric potential in an ionic conductor was performed using the li...A theoretical analysis on the electric double layer formed near the surface of an infinite cylinder with an elliptical cross section and a prescribed electric potential in an ionic conductor was performed using the linearized Gouy–Chapman theory. A semi-analytical solution in terms of the Mathieu functions was obtained. The distributions of the electric potential, cations, anions, and electric field were calculated. The effects of various physical and geometric parameters were examined. The fields vary rapidly near the elliptical boundary and are nearly uniform at far field. Electric field concentrations were found at the ends of the semi-major and semi-minor axes of the ellipse. These concentrations are sensitive to the physical and geometric parameters.展开更多
As an industry accepted storage scheme, hafnium oxide(HfO_x) based resistive random access memory(RRAM)should further improve its thermal stability and data retention for practical applications. We therefore fabri...As an industry accepted storage scheme, hafnium oxide(HfO_x) based resistive random access memory(RRAM)should further improve its thermal stability and data retention for practical applications. We therefore fabricated RRAMs with HfO_x/ZnO double-layer as the storage medium to study their thermal stability as well as data retention. The HfO_x/ZnO double-layer is capable of reversible bipolar switching under ultralow switching current(〈 3 μA) with a Schottky emission dominant conduction for the high resistance state and a Poole–Frenkel emission governed conduction for the low resistance state. Compared with a drastically increased switching current at 120℃ for the single HfO_x layer RRAM, the HfO_x/ZnO double-layer exhibits excellent thermal stability and maintains neglectful fluctuations in switching current at high temperatures(up to 180℃), which might be attributed to the increased Schottky barrier height to suppress current at high temperatures. Additionally, the HfO_x/ZnO double-layer exhibits 10-year data retention @85℃ that is helpful for the practical applications in RRAMs.展开更多
A novel bifacial photovoltaic wall combining thermochromic material and double layers PCM(BPVW-TC+PCM)is proposed to passively regulate building heat gain and photovoltaic(PV)power generation through the dynamic color...A novel bifacial photovoltaic wall combining thermochromic material and double layers PCM(BPVW-TC+PCM)is proposed to passively regulate building heat gain and photovoltaic(PV)power generation through the dynamic color change properties of thermochromic glass and the latent heat storage capacity of the phase change material(PCM).Physical and numerical models of the composite wall system were developed,followed by numerical simulations to analyze indoor air temperature,PV power generation,and annual energy consumption in both ordinary and composite wall rooms.Additionally,optimization studies were conducted to determine the ideal phase change layer temperature and arrangement.The results indicate that this novel wall system significantly reduces indoor air temperature fluctuations and enhances PV power generation by approximately 16%in both summer and winter compared to conventional mono facial PV walls.The system achieves its lowest energy consumption when the high-temperature phase change layer is maintained at 28°C and the low-temperature phase change layer at 18℃,with both layers positioned on the interior side,resulting in an energy saving rate of 22.6%.展开更多
Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)is considered to be the most potential light-absorbing material to replace CuInGaSe_(2)(CIGS),but the actual photoelectric conversion efficiency of such cells is much lower than that of CIG...Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)is considered to be the most potential light-absorbing material to replace CuInGaSe_(2)(CIGS),but the actual photoelectric conversion efficiency of such cells is much lower than that of CIGS.One of the reasons is the high recombination rate of carriers at the interface.In this paper,in order to reduce the carrier recombination,a new solar cell structure with double absorber layers of Al-doped ZnO(AZO)/intrinsic(i)-ZnO/CdS/CZTS_(x1)Se_(1−x1)(CZTSSe_(1))/CZTS_(x2)Se_(1−x2)(CZTSSe_(2))/Mo was proposed,and the optimal conduction band offsets(CBOs)of CdS/CZTSSe_(1) interface and CZTSSe_(1)/CZTSSe_(2) interface were determined by changing the S ratio in CZTSSe_(1) and CZTSSe_(2),and the effect of thickness of CZTSSe_(1) on the performance of the cell was studied.The efficiencies of the optimized single and double absorber layers reached 17.97%and 23.4%,respectively.Compared with the single absorber layer structure,the proposed structure with double absorber layers has better cell performance.展开更多
The AlGaN-based deep ultraviolet light-emitting diodes(LED) with double electron blocking layers(d-EBLs) on both sides of the active region are investigated theoretically. They possess many excellent performances ...The AlGaN-based deep ultraviolet light-emitting diodes(LED) with double electron blocking layers(d-EBLs) on both sides of the active region are investigated theoretically. They possess many excellent performances compared with the conventional structure with only a single electron blocking layer, such as a higher recombination rate, improved light output power and internal quantum efficiency(IQE). The reasons can be concluded as follows. On the one hand, the weakened electrostatic field within the quantum wells(QWs) enhances the electron–hole spatial overlap in QWs, and therefore increases the probability of radioactive recombination. On the other hand, the added n-AlGaN layer can not only prevent holes from overflowing into the n-side region but also act as another electron source, providing more electrons.展开更多
Among the many strategies to fabricate the silicon/carbon composite,yolk/double-shells structure can be regarded as an effective strategy to overcome the intrinsic defects of Si-based anode materials for Li-ion batter...Among the many strategies to fabricate the silicon/carbon composite,yolk/double-shells structure can be regarded as an effective strategy to overcome the intrinsic defects of Si-based anode materials for Li-ion batteries(LIBs).Hereon,a facile and inexpensive technology to prepare silicon/carbon composite with yolk/double-shells structure is proposed,in which the double buffering carbon shells are fabricated.The silicon/carbon nanoparticles with core-shell structure are encapsulated by SiO_(2)and external carbon layer,and it shows the yolk/double-shells structure via etching the SiO_(2)sacrificial layer.The multiply shells structure not only significantly improves the electrical conductivity of composite,but also effectively prevents the exposure of Si particles from the electrolyte composition.Meanwhile,the yolk/double-shells structure can provide enough space to accommodate the volume change of the electrode during charge/discharge process and avoid the pulverization of Si particles.Moreover,the as-prepared YDS-Si/C shows excellent performance as anode of LIBs,the reversible capacity is as high as 1066 mA h g^(-1) at the current density of 0.5 A g^(-1) after 200 cycles.At the same time,the YDS-Si/C has high capacity retention and good cyclic stability.Therefore,the unique architecture design of yolk/double-shells for Si/C composite provides an instructive exploration for the development of next generation anode materials of LIBs with high electrochemical performances and structural stability.展开更多
A novel A1GaN/GaN high electron mobility transistor (HEMT) with double buried p-type layers (DBPLs) in the GaN buffer layer and its mechanism are studied. The DBPL A1GaN/GaN HEMT is characterized by two equi-long ...A novel A1GaN/GaN high electron mobility transistor (HEMT) with double buried p-type layers (DBPLs) in the GaN buffer layer and its mechanism are studied. The DBPL A1GaN/GaN HEMT is characterized by two equi-long p-type GaN layers which are buried in the GaN buffer layer under the source side. Under the condition of high-voltage blocking state, two reverse p-n junctions introduced by the buried p-type layers will effectively modulate the surface and bulk electric fields. Meanwhile, the buffer leakage is well suppressed in this structure and both lead to a high breakdown voltage. The simulations show that the breakdown voltage of the DBPL structure can reach above 2000 V from 467 V of the conventional structure with the same gate-drain length of 8μm.展开更多
Electric double layer capacitors(EDLCs)as promising electrical energy storage devices are faced with thermal management issues,which concern the performance and lifetime of the devices.Heat transfer at the solid-liqui...Electric double layer capacitors(EDLCs)as promising electrical energy storage devices are faced with thermal management issues,which concern the performance and lifetime of the devices.Heat transfer at the solid-liquid interface has a crucial impact on the thermal management of EDLCs.In this work,the interfacial thermal resistance(Kapitza resistance)of the interface between ionic liquid(IL)and graphite electrode is determined,and the heat transfer resistance in the uncharged/charged system with different temperatures is investigated via molecular dynamics simulations.It is found that Kapitza resistance near the negative-charged interface decreases by 23%compared to that in the uncharged system,while the temperature effect on Kapitza resistance is little in our simulation.The unique ion layer structure of ILs formed at the interface may influence the thermal transport performance.Simulations are performed to investigate the effects of surface charge and working temperature on the heat transfer resistance of interfacial ILs from three aspects:ionic spacing,inter-ion interaction,and heat capacity.With the influence of surface charge,ionic spacing in the electric double layer is found to decrease while the inter-ion interaction and heat capacity increase,leading to the reduction in thermal resistance of interfacial ILs.However,rising temperature has small effects on the three thermal properties,with a slight tendency to increase the thermal resistance of ILs.展开更多
We fabricate a kind of novel efficient blue fluorescent organic light emitting device(OLED) based on p-n heterojunctions composed of hole transporting layer(HTL) N,N '-bis(naphthalen-1-yl)-N,N '-bis(phenyl)-...We fabricate a kind of novel efficient blue fluorescent organic light emitting device(OLED) based on p-n heterojunctions composed of hole transporting layer(HTL) N,N '-bis(naphthalen-1-yl)-N,N '-bis(phenyl)-benzidine(NPB) and electron transporting layer(ETL) 4,7-diphnenyl-1,10-phenanthroline(BPhen),into which a new blue material,DNCA(a derivation of N 6,N 6,N 12,N 12-tetrap-tolylchrysene-6,12-diamine),is partially doped simultaneously,and double emitting layers are configured.With a turn-on voltage of 2.6 V at 1 cd/m 2,this type of OLED presents a maximum luminance efficiency(η max) of 8.83 cd/A at 5.818 mA/cm 2 and a maximum luminance of over 40000 cd/m 2.Meanwhile,the Commission Internationale De L'Eclairage(CIE) coordinates of this device change slightly from(0.13,0.27) to(0.13,0.23) as the driving voltage increases from 3 V to 11 V.This improvement in the electroluminescent characteristics is attributed mainly to the ideal p-n heterojunction which can confine and distribute excitons evenly on two sides of the heterojunction interface so as to improve the carrier combination rate and expand the light-emitting region.展开更多
To investigate the wind⁃induced vibration re⁃sponse characteristics of multispan double⁃layer cable photo⁃voltaic(PV)support structures,wind tunnel tests using an aeroelastic model were carried out to obtain the wind⁃...To investigate the wind⁃induced vibration re⁃sponse characteristics of multispan double⁃layer cable photo⁃voltaic(PV)support structures,wind tunnel tests using an aeroelastic model were carried out to obtain the wind⁃induced vibration response data of a three⁃span four⁃row double⁃layer cable PV support system.The wind⁃induced vibration characteristics with different PV module tilt angles,wind speeds,and wind direction angles were analyzed.The results showed that the double⁃layer cable large⁃span flexible PV support can effectively control the wind⁃induced vibration response and prevent the occur⁃rence of flutter under strong wind conditions.The maxi⁃mum value of the wind⁃induced vibration displacement of the flexible PV support system occurs in the windward first row.The upstream module has a significant shading effect on the downstream module,with a maximum effect of 23%.The most unfavorable wind direction angles of the structure are 0°and 180°.The change of the wind direction angle in the range of 0°to 30°has little effect on the wind vi⁃bration response.The change in the tilt angle of the PV modules has a greater impact on the wind vibration in the downwind direction and a smaller impact in the upwind di⁃rection.Special attention should be paid to the structural wind⁃resistant design of such systems in the upwind side span.展开更多
The practical application of emerging rechargeable aqueous zinc(Zn)batteries is challenged by the poor reversibility and cycling stability of Zn anodes,primarily due to parasitic side reactions.While numerous strategi...The practical application of emerging rechargeable aqueous zinc(Zn)batteries is challenged by the poor reversibility and cycling stability of Zn anodes,primarily due to parasitic side reactions.While numerous strategies have been proposed,balancing the suppression of side reactions with the maintenance of fast Zn plating/stripping kinetics remains a significant challenge.In this study,sucrose,a sterically-hindered organic molecule with abundant hydroxyl groups,is employed to suppress the side reactions and maintain the moderate kinetics of Zn plating/stripping by modulating the hydrogen bond network without altering the Zn^(2+)solvation structure.Its steric hindrance effect further impedes the lateral diffusion of Zn atoms on the electrode surface within the electric double layer,effectively mitigating dendrite growth and stabilizing the electrodeposition process.Consequently,the formulated Suc/ZnSO_(4)electrolyte achieves a remarkably Coulombic efficiency of 99.90% over 2600 cycles at 3 mA cm^(-2)for 1 mAh cm^(-2)in Zn‖Cu cells.The enhanced Zn anode reversibility leads to excellent cycling stability in Zn‖LiFePO_(4)cells and Zn‖β-MnO_(2)cells.This study underscores the potential of sterically-hindered organic molecule strategies to enhance Zn anode stability while maintaining favorable Zn deposition/stripping dynamics in aqueous Zn batteries.展开更多
The electric double layer(EDL),formed by charge adsorption at the electrolyte–electrode interface,constitutes the microenvironment governing electrochemical reactions.However,due to scale mismatch between the EDL thi...The electric double layer(EDL),formed by charge adsorption at the electrolyte–electrode interface,constitutes the microenvironment governing electrochemical reactions.However,due to scale mismatch between the EDL thickness and electrode topography,solving the two-dimensional(2D)nonhomogeneous Poisson–Nernst–Planck(N-PNP)equations remains computationally intractable.This limitation hinders understanding of fundamental phenomena such as curvature-driven instabilities in 2D EDL.Here,we propose a dimensionality-decomposition strategy embedding a fully connected neural network(FCNN)to solve 2D N-PNP equations,in which the FCNN is trained on key electrochemical parameters by reducing the electrostatic boundary into multiple equivalent 1D representations.Through a representative case of LiPF6 reduction on lithium metal half-cell,nucleus size is unexpectedly found to have an important influence on dendrite morphology and tip kinetics.This work paves the way for bridging nanoscale and macroscale simulations with expandability to 2D situations of other 1D EDL models.展开更多
文摘Cylindrical and spherical (nonplanar) solitary waves (SWs) and double layers (DLs) in a multi-ion plasma system (containing inertial positively as well as negatively charged ions, non-inertial degenerate electrons, and negatively charged static dust) are studied by employing the standard reductive perturbation method. The modified Gardner (MG) equation describing the nonlinear propagation of the dust ion-acoustic (DIA) waves is derived, and its nonplanar SWs and DLs solutions are numerically analyzed. The parametric regimes for the existence of SWs, which are associated with both positive and negative potential, and DLs which are associated with negative potential, are obtained. The basic features of nonplanar DIA SWs, and DLs, which are found to be different from planar ones, are also identified.
文摘A precise theoretical investigation has been made on the cylindrical and spherical (nonplanar) Gardner solitons (GSs) and double layers (DLs) in a dusty electronegative plasma (composed of inertial positive and negative ions, Maxwellian cold electrons, non-thermal hot electrons, and negatively charged static dust). The reductive perturbation method has been used in derivation of the modified Gardner (MG) equation describing the nonlinear propagation of the dust ion-acoustic (DIA) waves. The MG equation admits solitary waves (SWs) and DLs solutions for σ around its critical value σ c (where σc is the value of σ corresponding to the vanishing of the nonlinear coefficient of the Korteweg de-Vries (K-dV) equation). The nonplanar SWs and DLs solutions are numerically analyzed and the parametric regimes for the existence of the positive as well as negative SWs and negative DLs are obtained. The basic features of nonplanar DIA SWs and DLs, which are found to be different from planar ones, are also identified. The implications of our results to different space and laboratory dusty plasma situations, are discussed.
文摘Simple and double layers first appeared in electrostatics and later found various applications in mathematical physics. In this paper, we present the jump discontinuity conditions for their second-order spatial derivatives.
文摘Large amplitude dust ion acoustic (DIA) solitons as well as double layers (DLs) are studied in a dusty plasma having a high-energy-tail electron distribution. The influence of electron deviation from the Maxwellian distribution and ion streaming on the existence domain of solitons is discussed in the (M, f) space using the pseudo-potential approach. It is found that in the presence of streaming ions and for a fixed f, solitons may appear for larger values of M. This means that in the presence of ion streaming, high values of the Mach number are needed to have soliton. The DIA solitary waves profile is highly sensitive to the ion streaming speed. Their amplitude is found to decrease with an increase of the ion streaming speed. In addition, we find that the ion streaming effect may lead to the appearance of double layers. The results of this axticle should be useful in understanding the basic nonlinear features of DIA waves propagating in space dusty plasmas, especially those including a relative motion between species, such as comet tails and solar wind streams, etc.
基金Project supported by the Natural Science Foundation of Liaoning Province (Grant No 20041021), the Scientific Foundation of the Educational Department of Liaoning Province (Grant No 2004C006) and the Postdoctoral Foundation of Shenyang University of Technology.
文摘The internal energy and specific heat of a Heisenberg ferro- antiferromagnetic double-layer system are studied by using spin-wave theory and the retarded Green function method at low temperatures. Numerical results show that the antiferromagnetic intralayer coupling J2 has an important influence on internal energy and specific heat for a four-sublattice system with antiferromagnetic (or ferrimagnetic) interlayer couplings.
基金supported by the Natural Science Foundation of Liaoning Province under Grant No.20041021the Scientific Foundation of the Educational Department of Liaoning Province under Grant Nos.2004C006 and 20060638the Postdoctoral Foundation of Shenyang University of Technology
文摘Spin-wave theory is used to study magnetic properties of ferromagnetic double layers with a ferrimagnetic interlayer coupling at zero temperature. The spin-wave spectra and four sublattices magnetizations and internal energy are calculated by employing retarded Green function technique. The sublattice magnetizations at ground state are smaller than their classical values, owing to the zero-point quantum fluctuations of the spins.
文摘Vortex double layers (VDLs) and vortex projectiles (VPs) are the essential coherent structures which emerge in the shock excited (s/f/s) planar parallel "curtain" simulations of a 2D shock tube with PPM. These opposite signed layers, formed by shock induced baroclinic deposition of vorticity, "ind" and are strongly affected by secondary reflected shocks and vortex interactions. In our visiometric mode of working, we quantify several of these processes and introduce time epochs to discuss the emerging phenomena and normalizations to scale (collapse) the data at M =1.5 and 2.0. This versatile configuration, easily obtained in the laboratory, allows us to study the formation, evolution and reacceleration of VPs and stratified turbulence and mixing.
基金Project supported by the “Strategic Priority Research Program” of the Chinese Academy of Sciences(Grant No.XDA01020304)the National Natural Science Foundation of China(Grant Nos.11747306 and 11565022)the Youth Science and Technology Foundation of Gansu Province,China(Grant No.1606RJYA263)
文摘The small amplitude dust ion-acoustic double layers in a collisionless four-component unmagnetized dusty plasma system containing nonextensive electrons, inertial negative ions, Maxwellian positive ions, and negatively charged static dust grains are investigated theoretically. Using the pseudo-potential approach and reductive perturbation method, an energy integral equation for the system has been derived and its solution in the form of double layers is obtained. The results appear that the existence regime of the double layer is very sensitive to the plasma parameters, e.g., electron nonextensivity,negative-to-positive ion number density ratio etc. It has been observed that for the selected set of parameters, the system supports rarefactive,(compressive) double layers depending upon the degree of nonextensivity of electrons.
基金supported by the National Natural Science Foundation of China (Grants 11502108 and 11232007)the Program for New Century Excellent Talents in Universities (Grant NCET-12-0625)+2 种基金the Natural Science Foundation of Jiangsu Province (Grant BK20140037)the Fundamental Research Funds for Central Universities (Grant NE2013101)Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
文摘A theoretical analysis on the electric double layer formed near the surface of an infinite cylinder with an elliptical cross section and a prescribed electric potential in an ionic conductor was performed using the linearized Gouy–Chapman theory. A semi-analytical solution in terms of the Mathieu functions was obtained. The distributions of the electric potential, cations, anions, and electric field were calculated. The effects of various physical and geometric parameters were examined. The fields vary rapidly near the elliptical boundary and are nearly uniform at far field. Electric field concentrations were found at the ends of the semi-major and semi-minor axes of the ellipse. These concentrations are sensitive to the physical and geometric parameters.
基金supported by the National Natural Science Foundation of China(Grant Nos.61006003 and 61674038)the Natural Science Foundation of Fujian Province,China(Grant Nos.2015J01249 and 2010J05134)+1 种基金the Science Foundation of Fujian Education Department of China(Grant No.JAT160073)the Science Foundation of Fujian Provincial Economic and Information Technology Commission of China(Grant No.83016006)
文摘As an industry accepted storage scheme, hafnium oxide(HfO_x) based resistive random access memory(RRAM)should further improve its thermal stability and data retention for practical applications. We therefore fabricated RRAMs with HfO_x/ZnO double-layer as the storage medium to study their thermal stability as well as data retention. The HfO_x/ZnO double-layer is capable of reversible bipolar switching under ultralow switching current(〈 3 μA) with a Schottky emission dominant conduction for the high resistance state and a Poole–Frenkel emission governed conduction for the low resistance state. Compared with a drastically increased switching current at 120℃ for the single HfO_x layer RRAM, the HfO_x/ZnO double-layer exhibits excellent thermal stability and maintains neglectful fluctuations in switching current at high temperatures(up to 180℃), which might be attributed to the increased Schottky barrier height to suppress current at high temperatures. Additionally, the HfO_x/ZnO double-layer exhibits 10-year data retention @85℃ that is helpful for the practical applications in RRAMs.
基金supported by the grants from the Key Research and Development Program of Anhui Province(no.S202203f07020001)。
文摘A novel bifacial photovoltaic wall combining thermochromic material and double layers PCM(BPVW-TC+PCM)is proposed to passively regulate building heat gain and photovoltaic(PV)power generation through the dynamic color change properties of thermochromic glass and the latent heat storage capacity of the phase change material(PCM).Physical and numerical models of the composite wall system were developed,followed by numerical simulations to analyze indoor air temperature,PV power generation,and annual energy consumption in both ordinary and composite wall rooms.Additionally,optimization studies were conducted to determine the ideal phase change layer temperature and arrangement.The results indicate that this novel wall system significantly reduces indoor air temperature fluctuations and enhances PV power generation by approximately 16%in both summer and winter compared to conventional mono facial PV walls.The system achieves its lowest energy consumption when the high-temperature phase change layer is maintained at 28°C and the low-temperature phase change layer at 18℃,with both layers positioned on the interior side,resulting in an energy saving rate of 22.6%.
基金supported by the Science and Technology Innovation Development Program(No.70304901).
文摘Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)is considered to be the most potential light-absorbing material to replace CuInGaSe_(2)(CIGS),but the actual photoelectric conversion efficiency of such cells is much lower than that of CIGS.One of the reasons is the high recombination rate of carriers at the interface.In this paper,in order to reduce the carrier recombination,a new solar cell structure with double absorber layers of Al-doped ZnO(AZO)/intrinsic(i)-ZnO/CdS/CZTS_(x1)Se_(1−x1)(CZTSSe_(1))/CZTS_(x2)Se_(1−x2)(CZTSSe_(2))/Mo was proposed,and the optimal conduction band offsets(CBOs)of CdS/CZTSSe_(1) interface and CZTSSe_(1)/CZTSSe_(2) interface were determined by changing the S ratio in CZTSSe_(1) and CZTSSe_(2),and the effect of thickness of CZTSSe_(1) on the performance of the cell was studied.The efficiencies of the optimized single and double absorber layers reached 17.97%and 23.4%,respectively.Compared with the single absorber layer structure,the proposed structure with double absorber layers has better cell performance.
基金Project supported by the Special Strategic Emerging Industries of Guangdong Province,China(Grant No.2012A080304006)the Major Scientific and Technological Projects of Zhongshan City,Guangdong Province,China(Grant No.2014A2FC204)the Forefront of Technology Innovation and Key Technology Projects of Guangdong Province,China(Grant Nos.2014B010121001 and 2014B010119004)
文摘The AlGaN-based deep ultraviolet light-emitting diodes(LED) with double electron blocking layers(d-EBLs) on both sides of the active region are investigated theoretically. They possess many excellent performances compared with the conventional structure with only a single electron blocking layer, such as a higher recombination rate, improved light output power and internal quantum efficiency(IQE). The reasons can be concluded as follows. On the one hand, the weakened electrostatic field within the quantum wells(QWs) enhances the electron–hole spatial overlap in QWs, and therefore increases the probability of radioactive recombination. On the other hand, the added n-AlGaN layer can not only prevent holes from overflowing into the n-side region but also act as another electron source, providing more electrons.
基金the National Natural Science Foundation of China(No.21703191)Key Project of Strategic New Industry of Hunan Province(No.2016GK4005 and No.2016GK4030)Research Innovation Project for Graduate students of Hunan Province(No.CX2017B302)。
文摘Among the many strategies to fabricate the silicon/carbon composite,yolk/double-shells structure can be regarded as an effective strategy to overcome the intrinsic defects of Si-based anode materials for Li-ion batteries(LIBs).Hereon,a facile and inexpensive technology to prepare silicon/carbon composite with yolk/double-shells structure is proposed,in which the double buffering carbon shells are fabricated.The silicon/carbon nanoparticles with core-shell structure are encapsulated by SiO_(2)and external carbon layer,and it shows the yolk/double-shells structure via etching the SiO_(2)sacrificial layer.The multiply shells structure not only significantly improves the electrical conductivity of composite,but also effectively prevents the exposure of Si particles from the electrolyte composition.Meanwhile,the yolk/double-shells structure can provide enough space to accommodate the volume change of the electrode during charge/discharge process and avoid the pulverization of Si particles.Moreover,the as-prepared YDS-Si/C shows excellent performance as anode of LIBs,the reversible capacity is as high as 1066 mA h g^(-1) at the current density of 0.5 A g^(-1) after 200 cycles.At the same time,the YDS-Si/C has high capacity retention and good cyclic stability.Therefore,the unique architecture design of yolk/double-shells for Si/C composite provides an instructive exploration for the development of next generation anode materials of LIBs with high electrochemical performances and structural stability.
基金Supported by the National Natural Science Foundation of China under Grant Nos 61334002,61106106,and 61204085the China Postdoctoral Science Foundation Funded Project under Grant No 2015M582610
文摘A novel A1GaN/GaN high electron mobility transistor (HEMT) with double buried p-type layers (DBPLs) in the GaN buffer layer and its mechanism are studied. The DBPL A1GaN/GaN HEMT is characterized by two equi-long p-type GaN layers which are buried in the GaN buffer layer under the source side. Under the condition of high-voltage blocking state, two reverse p-n junctions introduced by the buried p-type layers will effectively modulate the surface and bulk electric fields. Meanwhile, the buffer leakage is well suppressed in this structure and both lead to a high breakdown voltage. The simulations show that the breakdown voltage of the DBPL structure can reach above 2000 V from 467 V of the conventional structure with the same gate-drain length of 8μm.
基金financially supported by the National Natural Science Foundation of China(52161135104,51876072)the Hubei Provincial Natural Science Foundation of China(2020CFA093)supported by the Program for HUST Academic Frontier Youth Team。
文摘Electric double layer capacitors(EDLCs)as promising electrical energy storage devices are faced with thermal management issues,which concern the performance and lifetime of the devices.Heat transfer at the solid-liquid interface has a crucial impact on the thermal management of EDLCs.In this work,the interfacial thermal resistance(Kapitza resistance)of the interface between ionic liquid(IL)and graphite electrode is determined,and the heat transfer resistance in the uncharged/charged system with different temperatures is investigated via molecular dynamics simulations.It is found that Kapitza resistance near the negative-charged interface decreases by 23%compared to that in the uncharged system,while the temperature effect on Kapitza resistance is little in our simulation.The unique ion layer structure of ILs formed at the interface may influence the thermal transport performance.Simulations are performed to investigate the effects of surface charge and working temperature on the heat transfer resistance of interfacial ILs from three aspects:ionic spacing,inter-ion interaction,and heat capacity.With the influence of surface charge,ionic spacing in the electric double layer is found to decrease while the inter-ion interaction and heat capacity increase,leading to the reduction in thermal resistance of interfacial ILs.However,rising temperature has small effects on the three thermal properties,with a slight tendency to increase the thermal resistance of ILs.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 60906022 and 60876046)the Tianjin Natural Science Foundation,China (Grant No. 10JCYBJC01100)
文摘We fabricate a kind of novel efficient blue fluorescent organic light emitting device(OLED) based on p-n heterojunctions composed of hole transporting layer(HTL) N,N '-bis(naphthalen-1-yl)-N,N '-bis(phenyl)-benzidine(NPB) and electron transporting layer(ETL) 4,7-diphnenyl-1,10-phenanthroline(BPhen),into which a new blue material,DNCA(a derivation of N 6,N 6,N 12,N 12-tetrap-tolylchrysene-6,12-diamine),is partially doped simultaneously,and double emitting layers are configured.With a turn-on voltage of 2.6 V at 1 cd/m 2,this type of OLED presents a maximum luminance efficiency(η max) of 8.83 cd/A at 5.818 mA/cm 2 and a maximum luminance of over 40000 cd/m 2.Meanwhile,the Commission Internationale De L'Eclairage(CIE) coordinates of this device change slightly from(0.13,0.27) to(0.13,0.23) as the driving voltage increases from 3 V to 11 V.This improvement in the electroluminescent characteristics is attributed mainly to the ideal p-n heterojunction which can confine and distribute excitons evenly on two sides of the heterojunction interface so as to improve the carrier combination rate and expand the light-emitting region.
基金The National Natural Science Foundation of China(No.52338011).
文摘To investigate the wind⁃induced vibration re⁃sponse characteristics of multispan double⁃layer cable photo⁃voltaic(PV)support structures,wind tunnel tests using an aeroelastic model were carried out to obtain the wind⁃induced vibration response data of a three⁃span four⁃row double⁃layer cable PV support system.The wind⁃induced vibration characteristics with different PV module tilt angles,wind speeds,and wind direction angles were analyzed.The results showed that the double⁃layer cable large⁃span flexible PV support can effectively control the wind⁃induced vibration response and prevent the occur⁃rence of flutter under strong wind conditions.The maxi⁃mum value of the wind⁃induced vibration displacement of the flexible PV support system occurs in the windward first row.The upstream module has a significant shading effect on the downstream module,with a maximum effect of 23%.The most unfavorable wind direction angles of the structure are 0°and 180°.The change of the wind direction angle in the range of 0°to 30°has little effect on the wind vi⁃bration response.The change in the tilt angle of the PV modules has a greater impact on the wind vibration in the downwind direction and a smaller impact in the upwind di⁃rection.Special attention should be paid to the structural wind⁃resistant design of such systems in the upwind side span.
基金funded by the National Key Research and Development Program of China(2022YFB2404500)the Shenzhen Outstanding Talents Training Fund(01090100002)the National Natural Science Foundation of China(52201280)。
文摘The practical application of emerging rechargeable aqueous zinc(Zn)batteries is challenged by the poor reversibility and cycling stability of Zn anodes,primarily due to parasitic side reactions.While numerous strategies have been proposed,balancing the suppression of side reactions with the maintenance of fast Zn plating/stripping kinetics remains a significant challenge.In this study,sucrose,a sterically-hindered organic molecule with abundant hydroxyl groups,is employed to suppress the side reactions and maintain the moderate kinetics of Zn plating/stripping by modulating the hydrogen bond network without altering the Zn^(2+)solvation structure.Its steric hindrance effect further impedes the lateral diffusion of Zn atoms on the electrode surface within the electric double layer,effectively mitigating dendrite growth and stabilizing the electrodeposition process.Consequently,the formulated Suc/ZnSO_(4)electrolyte achieves a remarkably Coulombic efficiency of 99.90% over 2600 cycles at 3 mA cm^(-2)for 1 mAh cm^(-2)in Zn‖Cu cells.The enhanced Zn anode reversibility leads to excellent cycling stability in Zn‖LiFePO_(4)cells and Zn‖β-MnO_(2)cells.This study underscores the potential of sterically-hindered organic molecule strategies to enhance Zn anode stability while maintaining favorable Zn deposition/stripping dynamics in aqueous Zn batteries.
基金supported by the National Natural Science Foundation of China(Grant Nos.92472207,52472223,and 92572301)。
文摘The electric double layer(EDL),formed by charge adsorption at the electrolyte–electrode interface,constitutes the microenvironment governing electrochemical reactions.However,due to scale mismatch between the EDL thickness and electrode topography,solving the two-dimensional(2D)nonhomogeneous Poisson–Nernst–Planck(N-PNP)equations remains computationally intractable.This limitation hinders understanding of fundamental phenomena such as curvature-driven instabilities in 2D EDL.Here,we propose a dimensionality-decomposition strategy embedding a fully connected neural network(FCNN)to solve 2D N-PNP equations,in which the FCNN is trained on key electrochemical parameters by reducing the electrostatic boundary into multiple equivalent 1D representations.Through a representative case of LiPF6 reduction on lithium metal half-cell,nucleus size is unexpectedly found to have an important influence on dendrite morphology and tip kinetics.This work paves the way for bridging nanoscale and macroscale simulations with expandability to 2D situations of other 1D EDL models.