This paper aims to explore the development strategies for subject services in university libraries within the context of the“double first-class”initiative.By examining the relationship between“double first-class”c...This paper aims to explore the development strategies for subject services in university libraries within the context of the“double first-class”initiative.By examining the relationship between“double first-class”construction and university library subject services,the study analyzes the current state of subject services,including resource development,service models,and team building.Drawing on domestic and international case studies,the paper proposes a series of targeted and practical strategies to enhance the quality of subject services in university libraries,thereby providing robust support for the advancement of the“double first-class”initiative.展开更多
With the advancement of the“Double First-Class”initiative,universities are increasingly focusing on attracting top-tier talent to enhance faculty quality and strengthen academic disciplines.The blind competition for...With the advancement of the“Double First-Class”initiative,universities are increasingly focusing on attracting top-tier talent to enhance faculty quality and strengthen academic disciplines.The blind competition for high-end talent among universities reflects an overshadowing of academic values by economic considerations,neglecting the growth patterns of top talent and the development laws of higher education.This study investigates and reflects on the real-world challenges of faculty mobility in universities,aiming to provide effective guidance for managing university faculty teams.展开更多
Against the background of the“double first-class”construction,the training of innovative graduate talent has become an important issue in higher education.This article discusses the importance of the training of top...Against the background of the“double first-class”construction,the training of innovative graduate talent has become an important issue in higher education.This article discusses the importance of the training of top graduate innovative talent,analyzes the status of the training of top graduate innovative talent at home and abroad,and summarizes the current challenges in the training of graduate innovative talent in China.Lastly,this paper proposes relevant reform suggestions in response to problems in the training of innovative graduate talent,which provides important references for improving the quality of innovative graduate training.展开更多
From the perspective of the development of world-class universities,internationalization is an essential strategic choice and external feature,and also an inevitable choice to improve the discourse power and competiti...From the perspective of the development of world-class universities,internationalization is an essential strategic choice and external feature,and also an inevitable choice to improve the discourse power and competitiveness of international higher education.In line with the national“double first-class”international development strategy of higher education,based on the cultivation of students’overall quality,the improvement of teachers’professional ability,and the development of school’s improvement of quality and efficiency,we School of Software,Northwestern Polytechnical University,explore new ideas and new measures for the cultivation of international software engineering talents,build a set of international teaching resources construction system,to form a reference standard and scheme for the cultivation of international software engineering talents.At present,we have achieved excellent results.展开更多
To build the top class of higher education by focusing on the goal of the“Double First-Class”,it needs to analyze the defect and deficiency and identify the demand for the training of the talent under the background...To build the top class of higher education by focusing on the goal of the“Double First-Class”,it needs to analyze the defect and deficiency and identify the demand for the training of the talent under the background of“Double First-Class”.Considering of those issues,it is suggested that building the curriculum system scientifically and rationally in following aspects:deepening the training objectives,professionalizing the structure and contents of the curriculum system,optimizing the content,enhancing the construction of practical education system and internationalizing the curriculum system.Also,with those aspects,a reference is provided for the cultivation of talents with innovative consciousness and ability to solve complex engineering problems under the background of the“Double First-Class”construction.展开更多
Data services,knowledge services,and information services are the core service elements of university libraries in the context of the Double First-Class Initiative.Combined with the current situation of insufficient o...Data services,knowledge services,and information services are the core service elements of university libraries in the context of the Double First-Class Initiative.Combined with the current situation of insufficient overall service capacity of libraries,this paper proposed strategies and implementation paths for optimizing the service system from three aspects:the construction of the professional qualification system for librarians,the establishment of post institutions,and the construction of library culture.Long-term path:putting library human resource management into the legal track,taking the lead in local legislation,and promoting the construction of library legislation and professional qualification certification system;optimizing the personnel system,implementing hierarchical management and classified assessment for professional librarians and auxiliary librarians.Short-term path:intensive post allocation,namely,assigning the core strength in the core post,and tackling the temporary major work combining multiple forces in the form of a"working group";building an open knowledge service ecosystem,accelerate the cross-border integration of libraries and other organizations,and striving to build the core competitiveness of libraries.展开更多
Throughout the world＇s first-class universities, the university culture is the soul of the universities＇ survival and development, and the cultural competitiveness has become an important symbol of the core competit...Throughout the world＇s first-class universities, the university culture is the soul of the universities＇ survival and development, and the cultural competitiveness has become an important symbol of the core competitiveness of the universities. The first-class university culture is very important to the construction of the ＂double first-class＂. Therefore, our country should bring the university cultural construction into the big pattern of the ＂double first-class＂ construction, guide the construction of the university cultures with the socialist core values, strengthen the cultural confidence, inherit the Chinese excellent traditional cultures, pay attention to the rational exchange of the multicultural cultures, highlight the Chinese characteristics of the first-class university cultures, and realize the dream of the Chinese nation of a power of the higher education.展开更多
The construction of“double first-class”universities is the strategic goal of the development of Chinese universities in the new period.On the basis of fully researching the domestic“double first-class”talent train...The construction of“double first-class”universities is the strategic goal of the development of Chinese universities in the new period.On the basis of fully researching the domestic“double first-class”talent training model,this paper builds a new type of talent training model with Chinese characteristics suitable for the“double first-class”development requirements through reference,digestion,comparison and integration,hoping to further improve universities Quality of teaching.展开更多
Objective: to explore the application effect of virtual medical technology in reproductive teaching under the background of "two-class" universities. Methods: the subjects of the study were the undergraduate...Objective: to explore the application effect of virtual medical technology in reproductive teaching under the background of "two-class" universities. Methods: the subjects of the study were the undergraduate students of clinical medicine in Anhui Medical University. The number is about 80. They were randomly divided into two groups with 40 people in each group. There was no significant difference in learning achievement and intelligence test scores between the two groups. The teaching time and place of the two groups of students are basically the same. All students are required to preview the teaching contents in advance. The traditional teaching group was the control group, while the virtual medical technology teaching group was the research group (P<0.05). Results: after comparison, the study group's students' academic performance was higher than that of the control group, and the study group's students' satisfaction with the teaching methods was higher than that of the control group (P<0.05). Conclusion: the effect of applying virtual medical technology in reproductive teaching is better than that of traditional teaching method. The students' test scores are ideal and they have high recognition of virtual medical technology.展开更多
Purpose:This critical policy analysis aims to comprehensively examine the second round of China's first-class discipline development project,commonly known as the Double First-Class Initiative(DFC Initiative or Sh...Purpose:This critical policy analysis aims to comprehensively examine the second round of China's first-class discipline development project,commonly known as the Double First-Class Initiative(DFC Initiative or Shuang Yiliu Jianshe).Design/Approach/Methods:We conducted desk research between May 2022 and December 2023 using relevant policy documents,academic literature,news sources,and commentaries that specifically focused on the second round of the DFC Initiative in China.Employing a critical policy analysis approach,we analyzed the gathered data from three key perspectives:policy as text,policy as discourse,and policy effects(including both first-and second-order effects).Findings:The second round of the DFC Initiative was implemented within the context of strengthened state regulation,prevalent managerialism,and an emphasis on promoting education equality in China's higher education development.A notable shift in structural dynamics occurred between the first and second round.These include the possibility of universities being added to or removed from the official list,increased academic autonomy for selected universities,and the promotion of interdisciplinary research within specific institutions.The implementation of the second round of the DFC Initiative reflects China's commitment to developing an internationalization strategy with Chinese characteristics.This strategy aims to align with China's national strategic needs and position the country as a cooperative partner,promoter,competitor,and potential leader in global scholarship.Originality/Value:By employing a critical policy analysis approach,this study offers a comprehensive examination of the second round of the DFC Initiative in China,contributing to existing knowledge on the development of world-class university policies in the country.展开更多
Lanthanide ions(Ln^(3+))doping provides a potential strategy to control over the luminescent properties of lead-free halide double perovskite nanocrystals(DP NCs).However,due to the low energy transfer efficiency betw...Lanthanide ions(Ln^(3+))doping provides a potential strategy to control over the luminescent properties of lead-free halide double perovskite nanocrystals(DP NCs).However,due to the low energy transfer efficiency between self-trapped exciton(STE)and Ln^(3+)ions,the characteristic emissions of Ln^(3+)ions are not prominent.Furthermore,the energy transfer mechanism between STE and Ln^(3+)ions is also elusive and requires in-depth study.We chose trace Bi^(3+)-doped Cs_(2)Ag_(0.6)Na_(0.4)InCl_(6-x)Br_(x) as a representative DP matrix to demonstrate that by tuning the bromide concentration,the Ln^(3+)emission can be greatly enhanced.Such enhanced STE and Ln^(3+)ions energy transfer originates from the high covalency of Ln-Br bond,which contributes to improve ment of the characteristic emission of Ln^(3+)ions.Furthermo re,optical spectroscopy reveals that the energy transfer mechanism from DP to Eu^(3+)ions is different from all the other doped Ln^(3+)ions.The energy transfer from DP to Eu^(3+)ions is mostly through Eu-Br charge transfer while the other Ln^(3+)ions are excited by energy transfer from STE.The distinct energy transfer mechanism has resulted from the energy separation between the excited energy level of Ln^(3+)ions and the bottom of conduction band of DP.With increasing the energy separation,the energy transfer from STE to Ln^(3+)ions is less efficient because of the generation of a larger number of phonons and finally becomes impossible for Eu^(3+)ions.Our results provide new insight into tuning the energy transfer of Ln^(3+)-doped DP NCs.展开更多
Lead-free hybrid double perovskites(LFHDPs) have received a lot of attention due to their environmental friendliness and promising attributes. However, studying the effect of film thickness on LFHDPs optoelectronic pr...Lead-free hybrid double perovskites(LFHDPs) have received a lot of attention due to their environmental friendliness and promising attributes. However, studying the effect of film thickness on LFHDPs optoelectronic properties has not yet been investigated. Herein, we synthesized two new Ruddlesden–Popper LFHDPs, namely(C_(5)H_(12)N)_(4)AgBiI_(8)(CAB-1) and(C_(6)H_(14)N)_(4)Ag Bi I8(CAB-2) using cyclopentylamine and cyclohexylamine as monoamine ligands. Indeed, these two Ag(Ⅰ)-Bi(Ⅲ) LFHDPs form smooth and uniform films ranging in thickness from 250 nm to 1 μm, with preferred orientations. Notably, the studies on the optical properties showed that the direct band gap value decreased from 2.17 e V to 1.91 e V for CAB-1 and from 2.05 e V to 1.86 e V for CAB-2 with increasing thickness. Accordingly, photo-current response using a xenon lamp revealed a significant difference of over 1000 n A between light and dark conditions for1 μm-thickness films, suggesting potential for light harvesting. Other than that, thicker films of CAB-1and CAB-2 exhibit high stability for 90 days in a relatively humid environment(RH of 55%), paving the way for promising optoelectronic applications.展开更多
The increased demand for personalized customization calls for new production modes to enhance collaborations among a wide range of manufacturing practitioners who unnecessarily trust each other.In this article,a block...The increased demand for personalized customization calls for new production modes to enhance collaborations among a wide range of manufacturing practitioners who unnecessarily trust each other.In this article,a blockchain-enabled manufacturing collaboration framework is proposed,with a focus on the production capacity matching problem for blockchainbased peer-to-peer(P2P)collaboration.First,a digital model of production capacity description is built for trustworthy and transparent sharing over the blockchain.Second,an optimization problem is formulated for P2P production capacity matching with objectives to maximize both social welfare and individual benefits of all participants.Third,a feasible solution based on an iterative double auction mechanism is designed to determine the optimal price and quantity for production capacity matching with a lack of personal information.It facilitates automation of the matching process while protecting users'privacy via blockchainbased smart contracts.Finally,simulation results from the Hyperledger Fabric-based prototype show that the proposed approach increases social welfare by 1.4%compared to the Bayesian game-based approach,makes all participants profitable,and achieves 90%fairness of enterprises.展开更多
Multicomponent Gd_(1−x)Sm_(x)Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)double perovskites are optimized for application in terms of chemical composi-tion and morphology for the use as oxygen electrodes in solid oxide cells.Structur...Multicomponent Gd_(1−x)Sm_(x)Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)double perovskites are optimized for application in terms of chemical composi-tion and morphology for the use as oxygen electrodes in solid oxide cells.Structural studies of other physicochemical properties are con-ducted on a series of materials obtained by the sol-gel method with different ratios of Gd and Sm cations.It is documented that changing the x value,and the resulting adjustment of the average ionic radius,have a significant impact on the crystal structure,stability,as well as on the total conductivity and thermomechanical properties of the materials,with the best results obtained for the Gd_(0.75)Sm_(0.2)5Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)composition.Oxygen electrodes are prepared using the selected compound,allowing to obtain low polarization resistance values,such as 0.086Ω·cm^(2)at 800℃.Systematic studies of electrocatalytic activity are conducted using La_(0.8)Sr_(0.2)Ga_(0.8)Mg_(_(0.2))O_(3−δ)as the electrolyte for all electrodes,and Ce_(0.8)Gd_(0.2)O_(2−δ)electrolyte for the best performing Gd_(0.75)Sm_(0.2)5Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)electrodes.The electrochemical data are analyzed using the distribution of relaxation times method.Also,the influence of the preparation method of the electrode material is in-ve`stigated using the electrospinning technique.Finally,the performance of the Gd_(0.75)Sm_(0.2)5Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)electrodes is tested in a Ni-YSZ(yttria-stabilized zirconia)anode-supported cell with a Ce_(0.8)Gd_(0.2)O_(2−δ)buffer layer,in the fuel cell and electrolyzer operating modes.With the electrospun electrode,a power density of 462 mW·cm^(−2)is obtained at 700℃,with a current density of ca.0.2 A·cm^(−2)at 1.3 V for the electrolysis at the same temperature,indicating better performance compared to the sol-gel-based electrode.展开更多
Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)is considered to be the most potential light-absorbing material to replace CuInGaSe_(2)(CIGS),but the actual photoelectric conversion efficiency of such cells is much lower than that of CIG...Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)is considered to be the most potential light-absorbing material to replace CuInGaSe_(2)(CIGS),but the actual photoelectric conversion efficiency of such cells is much lower than that of CIGS.One of the reasons is the high recombination rate of carriers at the interface.In this paper,in order to reduce the carrier recombination,a new solar cell structure with double absorber layers of Al-doped ZnO(AZO)/intrinsic(i)-ZnO/CdS/CZTS_(x1)Se_(1−x1)(CZTSSe_(1))/CZTS_(x2)Se_(1−x2)(CZTSSe_(2))/Mo was proposed,and the optimal conduction band offsets(CBOs)of CdS/CZTSSe_(1) interface and CZTSSe_(1)/CZTSSe_(2) interface were determined by changing the S ratio in CZTSSe_(1) and CZTSSe_(2),and the effect of thickness of CZTSSe_(1) on the performance of the cell was studied.The efficiencies of the optimized single and double absorber layers reached 17.97%and 23.4%,respectively.Compared with the single absorber layer structure,the proposed structure with double absorber layers has better cell performance.展开更多
ACKGROUND The hemoglobin glycation index(HGI)represents the discrepancy between the glucose management indicator(GMI)based on mean blood glucose levels and laboratory values of glycated hemoglobin(HbA1c).The HGI is a ...ACKGROUND The hemoglobin glycation index(HGI)represents the discrepancy between the glucose management indicator(GMI)based on mean blood glucose levels and laboratory values of glycated hemoglobin(HbA1c).The HGI is a promising indicator for identifying individuals with excessive glycosylation,facilitating personalized evaluation and prediction of diabetic complications.However,the factors influencing the HGI in patients with type 1 diabetes(T1D)remain unclear.Autoimmune destruction of pancreaticβcells is central in T1D pathogenesis,yet insulin resistance can also be a feature of patients with T1D and their coexistence is called“double diabetes”(DD).However,knowledge regarding the relationship between DD features and the HGI in T1D is limited.AIM To assess the association between the HGI and DD features in adults with T1D.METHODS A total of 83 patients with T1D were recruited for this cross-sectional study.Laboratory HbA1c and GMI from continuous glucose monitoring data were collected to calculate the HGI.DD features included a family history of type 2 diabetes,overweight/obesity/central adiposity,hypertension,atherogenic dyslipidemia,an abnormal percentage of body fat(PBF)and/or visceral fat area(VFA)and decreased estimated insulin sensitivity.Skin autofluorescence of advanced glycation end products(SAF-AGEs),diabetic complications,and DD features were assessed,and their association with the HGI was analyzed.RESULTS A discrepancy was observed between HbA1c and GMI among patients with T1D and DD.A higher HGI was associated with an increased number of SAF-AGEs and a higher prevalence of diabetic microangiopathy(P=0.030),particularly retinopathy(P=0.031).Patients with three or more DD features exhibited an eight-fold increased risk of having a high HGI,compared with those without DD features(adjusted odds ratio=8.12;95%confidence interval:1.52-43.47).Specifically,an elevated PBF and/or VFA and decreased estimated insulin sensitivity were associated with high HGI.Regression analysis identified estimated insulin sensitivity and VFA as factors independently associated with HGI.CONCLUSION In patients with T1D,DD features are associated with a higher HGI,which represents a trend toward excessive glycosylation and is associated with a higher prevalence of chronic diabetic complications.展开更多
基金Heilongjiang Provincial Library Work Committee Project“Double First-Class Construction Research on the Development Strategy of Subject Services in University Libraries”(2024-016-B)。
文摘This paper aims to explore the development strategies for subject services in university libraries within the context of the“double first-class”initiative.By examining the relationship between“double first-class”construction and university library subject services,the study analyzes the current state of subject services,including resource development,service models,and team building.Drawing on domestic and international case studies,the paper proposes a series of targeted and practical strategies to enhance the quality of subject services in university libraries,thereby providing robust support for the advancement of the“double first-class”initiative.
基金Sponsored by the Ministry of Education Humanities and Social Sciences Research Planning Fund Project(22YJA880085)the Project of the Center for Party Political Construction Research,Ministry of Industry and Information Technology(GXZY2245).
文摘With the advancement of the“Double First-Class”initiative,universities are increasingly focusing on attracting top-tier talent to enhance faculty quality and strengthen academic disciplines.The blind competition for high-end talent among universities reflects an overshadowing of academic values by economic considerations,neglecting the growth patterns of top talent and the development laws of higher education.This study investigates and reflects on the real-world challenges of faculty mobility in universities,aiming to provide effective guidance for managing university faculty teams.
基金Foundation for Development Research of Disciplines of China University of Geosciences(Beijing)(2022XK218 and 2023XK110)。
文摘Against the background of the“double first-class”construction,the training of innovative graduate talent has become an important issue in higher education.This article discusses the importance of the training of top graduate innovative talent,analyzes the status of the training of top graduate innovative talent at home and abroad,and summarizes the current challenges in the training of graduate innovative talent in China.Lastly,this paper proposes relevant reform suggestions in response to problems in the training of innovative graduate talent,which provides important references for improving the quality of innovative graduate training.
文摘From the perspective of the development of world-class universities,internationalization is an essential strategic choice and external feature,and also an inevitable choice to improve the discourse power and competitiveness of international higher education.In line with the national“double first-class”international development strategy of higher education,based on the cultivation of students’overall quality,the improvement of teachers’professional ability,and the development of school’s improvement of quality and efficiency,we School of Software,Northwestern Polytechnical University,explore new ideas and new measures for the cultivation of international software engineering talents,build a set of international teaching resources construction system,to form a reference standard and scheme for the cultivation of international software engineering talents.At present,we have achieved excellent results.
文摘To build the top class of higher education by focusing on the goal of the“Double First-Class”,it needs to analyze the defect and deficiency and identify the demand for the training of the talent under the background of“Double First-Class”.Considering of those issues,it is suggested that building the curriculum system scientifically and rationally in following aspects:deepening the training objectives,professionalizing the structure and contents of the curriculum system,optimizing the content,enhancing the construction of practical education system and internationalizing the curriculum system.Also,with those aspects,a reference is provided for the cultivation of talents with innovative consciousness and ability to solve complex engineering problems under the background of the“Double First-Class”construction.
文摘Data services,knowledge services,and information services are the core service elements of university libraries in the context of the Double First-Class Initiative.Combined with the current situation of insufficient overall service capacity of libraries,this paper proposed strategies and implementation paths for optimizing the service system from three aspects:the construction of the professional qualification system for librarians,the establishment of post institutions,and the construction of library culture.Long-term path:putting library human resource management into the legal track,taking the lead in local legislation,and promoting the construction of library legislation and professional qualification certification system;optimizing the personnel system,implementing hierarchical management and classified assessment for professional librarians and auxiliary librarians.Short-term path:intensive post allocation,namely,assigning the core strength in the core post,and tackling the temporary major work combining multiple forces in the form of a"working group";building an open knowledge service ecosystem,accelerate the cross-border integration of libraries and other organizations,and striving to build the core competitiveness of libraries.
文摘Throughout the world＇s first-class universities, the university culture is the soul of the universities＇ survival and development, and the cultural competitiveness has become an important symbol of the core competitiveness of the universities. The first-class university culture is very important to the construction of the ＂double first-class＂. Therefore, our country should bring the university cultural construction into the big pattern of the ＂double first-class＂ construction, guide the construction of the university cultures with the socialist core values, strengthen the cultural confidence, inherit the Chinese excellent traditional cultures, pay attention to the rational exchange of the multicultural cultures, highlight the Chinese characteristics of the first-class university cultures, and realize the dream of the Chinese nation of a power of the higher education.
文摘The construction of“double first-class”universities is the strategic goal of the development of Chinese universities in the new period.On the basis of fully researching the domestic“double first-class”talent training model,this paper builds a new type of talent training model with Chinese characteristics suitable for the“double first-class”development requirements through reference,digestion,comparison and integration,hoping to further improve universities Quality of teaching.
文摘Objective: to explore the application effect of virtual medical technology in reproductive teaching under the background of "two-class" universities. Methods: the subjects of the study were the undergraduate students of clinical medicine in Anhui Medical University. The number is about 80. They were randomly divided into two groups with 40 people in each group. There was no significant difference in learning achievement and intelligence test scores between the two groups. The teaching time and place of the two groups of students are basically the same. All students are required to preview the teaching contents in advance. The traditional teaching group was the control group, while the virtual medical technology teaching group was the research group (P<0.05). Results: after comparison, the study group's students' academic performance was higher than that of the control group, and the study group's students' satisfaction with the teaching methods was higher than that of the control group (P<0.05). Conclusion: the effect of applying virtual medical technology in reproductive teaching is better than that of traditional teaching method. The students' test scores are ideal and they have high recognition of virtual medical technology.
基金supported by China's National Education Scientific Planning Project(CGA230337).
文摘Purpose:This critical policy analysis aims to comprehensively examine the second round of China's first-class discipline development project,commonly known as the Double First-Class Initiative(DFC Initiative or Shuang Yiliu Jianshe).Design/Approach/Methods:We conducted desk research between May 2022 and December 2023 using relevant policy documents,academic literature,news sources,and commentaries that specifically focused on the second round of the DFC Initiative in China.Employing a critical policy analysis approach,we analyzed the gathered data from three key perspectives:policy as text,policy as discourse,and policy effects(including both first-and second-order effects).Findings:The second round of the DFC Initiative was implemented within the context of strengthened state regulation,prevalent managerialism,and an emphasis on promoting education equality in China's higher education development.A notable shift in structural dynamics occurred between the first and second round.These include the possibility of universities being added to or removed from the official list,increased academic autonomy for selected universities,and the promotion of interdisciplinary research within specific institutions.The implementation of the second round of the DFC Initiative reflects China's commitment to developing an internationalization strategy with Chinese characteristics.This strategy aims to align with China's national strategic needs and position the country as a cooperative partner,promoter,competitor,and potential leader in global scholarship.Originality/Value:By employing a critical policy analysis approach,this study offers a comprehensive examination of the second round of the DFC Initiative in China,contributing to existing knowledge on the development of world-class university policies in the country.
基金Project supported by the Research Project of Mindu Innovation Laboratory(2021ZZ114)Natural Science Foundation of Xiamen(3502Z20227255)+1 种基金Major Research Project of Xiamen(3502Z20191015)the Science and Technology Major Project of Fujian Province(2021HZ021013)。
文摘Lanthanide ions(Ln^(3+))doping provides a potential strategy to control over the luminescent properties of lead-free halide double perovskite nanocrystals(DP NCs).However,due to the low energy transfer efficiency between self-trapped exciton(STE)and Ln^(3+)ions,the characteristic emissions of Ln^(3+)ions are not prominent.Furthermore,the energy transfer mechanism between STE and Ln^(3+)ions is also elusive and requires in-depth study.We chose trace Bi^(3+)-doped Cs_(2)Ag_(0.6)Na_(0.4)InCl_(6-x)Br_(x) as a representative DP matrix to demonstrate that by tuning the bromide concentration,the Ln^(3+)emission can be greatly enhanced.Such enhanced STE and Ln^(3+)ions energy transfer originates from the high covalency of Ln-Br bond,which contributes to improve ment of the characteristic emission of Ln^(3+)ions.Furthermo re,optical spectroscopy reveals that the energy transfer mechanism from DP to Eu^(3+)ions is different from all the other doped Ln^(3+)ions.The energy transfer from DP to Eu^(3+)ions is mostly through Eu-Br charge transfer while the other Ln^(3+)ions are excited by energy transfer from STE.The distinct energy transfer mechanism has resulted from the energy separation between the excited energy level of Ln^(3+)ions and the bottom of conduction band of DP.With increasing the energy separation,the energy transfer from STE to Ln^(3+)ions is less efficient because of the generation of a larger number of phonons and finally becomes impossible for Eu^(3+)ions.Our results provide new insight into tuning the energy transfer of Ln^(3+)-doped DP NCs.
基金supported by the National Natural Science Foundation of China (Nos. 22375157 and W2433042)the Key Scientific and Technological Innovation Team of Shaanxi Province(No. 2020TD-001)+1 种基金the Fundamental Research Funds for Central Universities, State Key Laboratory of Electrical Insulation and Power Equipment (No. EIPE23409)the Instrument Analysis Center of Xi’an Jiaotong University for assistance。
文摘Lead-free hybrid double perovskites(LFHDPs) have received a lot of attention due to their environmental friendliness and promising attributes. However, studying the effect of film thickness on LFHDPs optoelectronic properties has not yet been investigated. Herein, we synthesized two new Ruddlesden–Popper LFHDPs, namely(C_(5)H_(12)N)_(4)AgBiI_(8)(CAB-1) and(C_(6)H_(14)N)_(4)Ag Bi I8(CAB-2) using cyclopentylamine and cyclohexylamine as monoamine ligands. Indeed, these two Ag(Ⅰ)-Bi(Ⅲ) LFHDPs form smooth and uniform films ranging in thickness from 250 nm to 1 μm, with preferred orientations. Notably, the studies on the optical properties showed that the direct band gap value decreased from 2.17 e V to 1.91 e V for CAB-1 and from 2.05 e V to 1.86 e V for CAB-2 with increasing thickness. Accordingly, photo-current response using a xenon lamp revealed a significant difference of over 1000 n A between light and dark conditions for1 μm-thickness films, suggesting potential for light harvesting. Other than that, thicker films of CAB-1and CAB-2 exhibit high stability for 90 days in a relatively humid environment(RH of 55%), paving the way for promising optoelectronic applications.
基金supported in part by the National Natural Science Foundation of China(62273310)the Natural Science Foundation of Zhejiang Province of China(LY22F030006,LZ24F030009)
文摘The increased demand for personalized customization calls for new production modes to enhance collaborations among a wide range of manufacturing practitioners who unnecessarily trust each other.In this article,a blockchain-enabled manufacturing collaboration framework is proposed,with a focus on the production capacity matching problem for blockchainbased peer-to-peer(P2P)collaboration.First,a digital model of production capacity description is built for trustworthy and transparent sharing over the blockchain.Second,an optimization problem is formulated for P2P production capacity matching with objectives to maximize both social welfare and individual benefits of all participants.Third,a feasible solution based on an iterative double auction mechanism is designed to determine the optimal price and quantity for production capacity matching with a lack of personal information.It facilitates automation of the matching process while protecting users'privacy via blockchainbased smart contracts.Finally,simulation results from the Hyperledger Fabric-based prototype show that the proposed approach increases social welfare by 1.4%compared to the Bayesian game-based approach,makes all participants profitable,and achieves 90%fairness of enterprises.
基金funded by the National Science Centre,Poland,on the basis of the decision number UMO-2020/37/B/ST8/02097supported by the program“Excellence Initiative-Research University”for the AGH University of Krakow(IDUB AGH,No.501.696.7996,Action 4,ID 9880).
文摘Multicomponent Gd_(1−x)Sm_(x)Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)double perovskites are optimized for application in terms of chemical composi-tion and morphology for the use as oxygen electrodes in solid oxide cells.Structural studies of other physicochemical properties are con-ducted on a series of materials obtained by the sol-gel method with different ratios of Gd and Sm cations.It is documented that changing the x value,and the resulting adjustment of the average ionic radius,have a significant impact on the crystal structure,stability,as well as on the total conductivity and thermomechanical properties of the materials,with the best results obtained for the Gd_(0.75)Sm_(0.2)5Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)composition.Oxygen electrodes are prepared using the selected compound,allowing to obtain low polarization resistance values,such as 0.086Ω·cm^(2)at 800℃.Systematic studies of electrocatalytic activity are conducted using La_(0.8)Sr_(0.2)Ga_(0.8)Mg_(_(0.2))O_(3−δ)as the electrolyte for all electrodes,and Ce_(0.8)Gd_(0.2)O_(2−δ)electrolyte for the best performing Gd_(0.75)Sm_(0.2)5Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)electrodes.The electrochemical data are analyzed using the distribution of relaxation times method.Also,the influence of the preparation method of the electrode material is in-ve`stigated using the electrospinning technique.Finally,the performance of the Gd_(0.75)Sm_(0.2)5Ba_(0.5)Sr_(0.5)CoCuO_(5+δ)electrodes is tested in a Ni-YSZ(yttria-stabilized zirconia)anode-supported cell with a Ce_(0.8)Gd_(0.2)O_(2−δ)buffer layer,in the fuel cell and electrolyzer operating modes.With the electrospun electrode,a power density of 462 mW·cm^(−2)is obtained at 700℃,with a current density of ca.0.2 A·cm^(−2)at 1.3 V for the electrolysis at the same temperature,indicating better performance compared to the sol-gel-based electrode.
基金supported by the Science and Technology Innovation Development Program(No.70304901).
文摘Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)is considered to be the most potential light-absorbing material to replace CuInGaSe_(2)(CIGS),but the actual photoelectric conversion efficiency of such cells is much lower than that of CIGS.One of the reasons is the high recombination rate of carriers at the interface.In this paper,in order to reduce the carrier recombination,a new solar cell structure with double absorber layers of Al-doped ZnO(AZO)/intrinsic(i)-ZnO/CdS/CZTS_(x1)Se_(1−x1)(CZTSSe_(1))/CZTS_(x2)Se_(1−x2)(CZTSSe_(2))/Mo was proposed,and the optimal conduction band offsets(CBOs)of CdS/CZTSSe_(1) interface and CZTSSe_(1)/CZTSSe_(2) interface were determined by changing the S ratio in CZTSSe_(1) and CZTSSe_(2),and the effect of thickness of CZTSSe_(1) on the performance of the cell was studied.The efficiencies of the optimized single and double absorber layers reached 17.97%and 23.4%,respectively.Compared with the single absorber layer structure,the proposed structure with double absorber layers has better cell performance.
基金Supported by the National Key R D Program of China,No.2022YFC2010102Natural Science Foundation of Hunan Province,No.2021JC0003+1 种基金National Natural Science Foundation of China,No.82070812the Sinocare Diabetes Foundation,No.LYF2022039.
文摘ACKGROUND The hemoglobin glycation index(HGI)represents the discrepancy between the glucose management indicator(GMI)based on mean blood glucose levels and laboratory values of glycated hemoglobin(HbA1c).The HGI is a promising indicator for identifying individuals with excessive glycosylation,facilitating personalized evaluation and prediction of diabetic complications.However,the factors influencing the HGI in patients with type 1 diabetes(T1D)remain unclear.Autoimmune destruction of pancreaticβcells is central in T1D pathogenesis,yet insulin resistance can also be a feature of patients with T1D and their coexistence is called“double diabetes”(DD).However,knowledge regarding the relationship between DD features and the HGI in T1D is limited.AIM To assess the association between the HGI and DD features in adults with T1D.METHODS A total of 83 patients with T1D were recruited for this cross-sectional study.Laboratory HbA1c and GMI from continuous glucose monitoring data were collected to calculate the HGI.DD features included a family history of type 2 diabetes,overweight/obesity/central adiposity,hypertension,atherogenic dyslipidemia,an abnormal percentage of body fat(PBF)and/or visceral fat area(VFA)and decreased estimated insulin sensitivity.Skin autofluorescence of advanced glycation end products(SAF-AGEs),diabetic complications,and DD features were assessed,and their association with the HGI was analyzed.RESULTS A discrepancy was observed between HbA1c and GMI among patients with T1D and DD.A higher HGI was associated with an increased number of SAF-AGEs and a higher prevalence of diabetic microangiopathy(P=0.030),particularly retinopathy(P=0.031).Patients with three or more DD features exhibited an eight-fold increased risk of having a high HGI,compared with those without DD features(adjusted odds ratio=8.12;95%confidence interval:1.52-43.47).Specifically,an elevated PBF and/or VFA and decreased estimated insulin sensitivity were associated with high HGI.Regression analysis identified estimated insulin sensitivity and VFA as factors independently associated with HGI.CONCLUSION In patients with T1D,DD features are associated with a higher HGI,which represents a trend toward excessive glycosylation and is associated with a higher prevalence of chronic diabetic complications.
