The Sinian Dengying Formation in China hosts one of the oldest gas-bearing reservoirs in the world.With a long geological history,it has developed into the reservoir rocks,whose quality depends on chemical dissolution...The Sinian Dengying Formation in China hosts one of the oldest gas-bearing reservoirs in the world.With a long geological history,it has developed into the reservoir rocks,whose quality depends on chemical dissolution and cementation.Despite presence of cavities and pores in the algal dolomites of the Dengying Formation,they were mostly filled with various forms of dolomite cements.Therefore,the investigation of these dolomites and their evolution is significant for analyzing the mechanism of pore space preservation.There are five types of cements in the Dengying Formation,which were well sampled for lab measurements such as thin section,cathodeluminescence,minor elements,isotope analysis of carbon,oxygen and strontium,in attempt to explore the fillers' geochemical characteristics and the diagenetic fluids.They are characterized as follows:firstly,fibrous rim dolomite cement is a typical product formed at sea bottom,and geochemically very similar to the matrix(micrite and microcrystalline dolomite),which could be a reflection of the geochemical characteristics of water at that time;secondly,the diagenetic fluids of the foliated dolomite cements tend to be inheriting,derived from the shallow burial "imprisoned" seawater;thirdly,fine-to medium-grained dolomite cements with fairly high strontium isotopes and low carbon and oxygen isotopes were precipitated chiefly in freshwater during the period of uplifting caused by Tongwan tectonic movement;fourthly,coarse-grained dolomite cements bear a relatively high percentage of Mn element,but low in Fe and Sr,with carbon and oxygen isotopes remarkably shifted to negative values,which all show that they are related to hydrocarbon maturation and migration,and corresponding Thermochemical Sulfate Reduction;lastly,saddle-shaped dolomite cements are hydrothermally associated,and they were formed in high-temperature brine,which had passed through the areas rich in radioactive strontium isotopes.展开更多
Abstract The study examines a Lower Jurassic （late Liassic） cyclic lagoonal-peritidal stratigraphic unit outcropping in central western Crete （Tripolis unit）, which corresponds to the eastern （internal） part of ...Abstract The study examines a Lower Jurassic （late Liassic） cyclic lagoonal-peritidal stratigraphic unit outcropping in central western Crete （Tripolis unit）, which corresponds to the eastern （internal） part of the mainland Gavrovo-Tripotis platform, the most significant external platform of the Hetlenides. The studied Tripolis carbonate sequence consists of meter-scale, shallowing-upward successions of restricted inner- carbonate platform facies, including cyclically repeated subtidal, intertidal and supratidal facies, that are separated by erosion surfaces （elementary cycles）. Each cycle starts with relatively open-marine facies, which are overlain by shallower, more restricted facies （tidal fiat progradation）. The lithofacies association includes dotomitic intraclastic-peloidal-bioclastic wackestones-packstones/floatstones and grainstones/rudstones dominated by a restricted shallow-marine fauna （bivalves, gastropods, ostracods and seldom benthic fora- minifers）, representing a shaUow subtidal to intertidal, moderately high-energy environment within an inner- platform setting （peritidal environment to restricted lagoon）. This lithofacies association has been intermit- tently subaeriaUy exposed and has undergone diagenetic processes in an inter- or supratidal environment, exhibiting features of vadose diagenesis and pedogenesis due to long-lasting exposure along certain horizons. The peritidat facies are capped by dolocretes controlled by root-activities （laminar dolocretes, petoi- dat-pisoid dolocretes and massive dotocretes）, marking the end of each depositional cycle, and, thus, dis- tinguishing the successive episodes of a prolonged subaerial exposure period and birth of pateosol horizons. Dotocretes consist a diagenetic facies, characterized by several vadose and pedogenic fabrics, including fenestral cavities with geopetal structures, ＂flower spar＂ to blocky sparry cement in primary pores, micritic coatings, crudely pelleted watts, atveotar-septat texture, infilts of rootlet moulds, inter-granular micritic bridges, meniscus cement, sinuous desiccation cracks, circum-granular cracking and in-situ brecciation. The stratigraphic distribution of the cyclothems, suggests relative sea-level control on the peritidal cyclicity controlled by uniform tectonic subsidence and eustasy （attocyctic processes）, in an inner- ramp-to-shelf carbonate setting with tidal fiat and restricted lagoon depositional environment. However, a combination of attocyctic with autocyctic processes controtting accommodation space and sediment accumutation, shoutd be atso taken in consideration. The studied high-frequency cyctes are interpreted to have been formed during the fatting stage and correspond to towstand systems tract （LST） sediments, which consists part of a regressive peak of the Lower/htiddte Jurassic Transgressive-Regressive Facies Low Frequency Cycte （2nd order）. Due to the absence of massive evaporites, dolomitization has been attributed to reflux of stightly increased-satinity marine fluids （i.e. penesatine）, that are driven into the undertying tagoonat-peritidat carbonate sediments during periods of tong term sea-fever fatl in a marginal marine setting.展开更多
基金supported by National Natural Science Foundation of China (Grant No. 40739903)
文摘The Sinian Dengying Formation in China hosts one of the oldest gas-bearing reservoirs in the world.With a long geological history,it has developed into the reservoir rocks,whose quality depends on chemical dissolution and cementation.Despite presence of cavities and pores in the algal dolomites of the Dengying Formation,they were mostly filled with various forms of dolomite cements.Therefore,the investigation of these dolomites and their evolution is significant for analyzing the mechanism of pore space preservation.There are five types of cements in the Dengying Formation,which were well sampled for lab measurements such as thin section,cathodeluminescence,minor elements,isotope analysis of carbon,oxygen and strontium,in attempt to explore the fillers' geochemical characteristics and the diagenetic fluids.They are characterized as follows:firstly,fibrous rim dolomite cement is a typical product formed at sea bottom,and geochemically very similar to the matrix(micrite and microcrystalline dolomite),which could be a reflection of the geochemical characteristics of water at that time;secondly,the diagenetic fluids of the foliated dolomite cements tend to be inheriting,derived from the shallow burial "imprisoned" seawater;thirdly,fine-to medium-grained dolomite cements with fairly high strontium isotopes and low carbon and oxygen isotopes were precipitated chiefly in freshwater during the period of uplifting caused by Tongwan tectonic movement;fourthly,coarse-grained dolomite cements bear a relatively high percentage of Mn element,but low in Fe and Sr,with carbon and oxygen isotopes remarkably shifted to negative values,which all show that they are related to hydrocarbon maturation and migration,and corresponding Thermochemical Sulfate Reduction;lastly,saddle-shaped dolomite cements are hydrothermally associated,and they were formed in high-temperature brine,which had passed through the areas rich in radioactive strontium isotopes.
基金co-financed by the University of Athens Program KAPODISTRIAS/Special Account for Research Grants of the National and Kapodistrian University of Athens(S.A.R.G)
文摘Abstract The study examines a Lower Jurassic （late Liassic） cyclic lagoonal-peritidal stratigraphic unit outcropping in central western Crete （Tripolis unit）, which corresponds to the eastern （internal） part of the mainland Gavrovo-Tripotis platform, the most significant external platform of the Hetlenides. The studied Tripolis carbonate sequence consists of meter-scale, shallowing-upward successions of restricted inner- carbonate platform facies, including cyclically repeated subtidal, intertidal and supratidal facies, that are separated by erosion surfaces （elementary cycles）. Each cycle starts with relatively open-marine facies, which are overlain by shallower, more restricted facies （tidal fiat progradation）. The lithofacies association includes dotomitic intraclastic-peloidal-bioclastic wackestones-packstones/floatstones and grainstones/rudstones dominated by a restricted shallow-marine fauna （bivalves, gastropods, ostracods and seldom benthic fora- minifers）, representing a shaUow subtidal to intertidal, moderately high-energy environment within an inner- platform setting （peritidal environment to restricted lagoon）. This lithofacies association has been intermit- tently subaeriaUy exposed and has undergone diagenetic processes in an inter- or supratidal environment, exhibiting features of vadose diagenesis and pedogenesis due to long-lasting exposure along certain horizons. The peritidat facies are capped by dolocretes controlled by root-activities （laminar dolocretes, petoi- dat-pisoid dolocretes and massive dotocretes）, marking the end of each depositional cycle, and, thus, dis- tinguishing the successive episodes of a prolonged subaerial exposure period and birth of pateosol horizons. Dotocretes consist a diagenetic facies, characterized by several vadose and pedogenic fabrics, including fenestral cavities with geopetal structures, ＂flower spar＂ to blocky sparry cement in primary pores, micritic coatings, crudely pelleted watts, atveotar-septat texture, infilts of rootlet moulds, inter-granular micritic bridges, meniscus cement, sinuous desiccation cracks, circum-granular cracking and in-situ brecciation. The stratigraphic distribution of the cyclothems, suggests relative sea-level control on the peritidal cyclicity controlled by uniform tectonic subsidence and eustasy （attocyctic processes）, in an inner- ramp-to-shelf carbonate setting with tidal fiat and restricted lagoon depositional environment. However, a combination of attocyctic with autocyctic processes controtting accommodation space and sediment accumutation, shoutd be atso taken in consideration. The studied high-frequency cyctes are interpreted to have been formed during the fatting stage and correspond to towstand systems tract （LST） sediments, which consists part of a regressive peak of the Lower/htiddte Jurassic Transgressive-Regressive Facies Low Frequency Cycte （2nd order）. Due to the absence of massive evaporites, dolomitization has been attributed to reflux of stightly increased-satinity marine fluids （i.e. penesatine）, that are driven into the undertying tagoonat-peritidat carbonate sediments during periods of tong term sea-fever fatl in a marginal marine setting.
