Reversible oxygen sensing abilities based on blue and orange photoluminescence in the solid state are achieved by using newly synthesized copper(I)complexes bearing diimine and dodecafluorinated diphosphine ligands.We...Reversible oxygen sensing abilities based on blue and orange photoluminescence in the solid state are achieved by using newly synthesized copper(I)complexes bearing diimine and dodecafluorinated diphosphine ligands.We found that the blue emission of[Cu(dmp)(dfppe)]PF_(6)(dmp=2,9-dimethyl-1,10-phenanthroline,dfppe=1,2-bis[bis(pentafluorophenyl)phosphino]ethane)in the solid state is very strong under argon,while it is nearly invisible under air.展开更多
基金supported by JSPS KAKENHI Grant Number JP16 K17881,the Iketani Science and Technology Foundation,and a grant from the Faculty of Science and Technology,Seikei University.
文摘Reversible oxygen sensing abilities based on blue and orange photoluminescence in the solid state are achieved by using newly synthesized copper(I)complexes bearing diimine and dodecafluorinated diphosphine ligands.We found that the blue emission of[Cu(dmp)(dfppe)]PF_(6)(dmp=2,9-dimethyl-1,10-phenanthroline,dfppe=1,2-bis[bis(pentafluorophenyl)phosphino]ethane)in the solid state is very strong under argon,while it is nearly invisible under air.
