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A Combination of Residual Distribution and the Active Flux Formulations or a New Class of Schemes That Can Combine Several Writings of the Same Hyperbolic Problem:Application to the 1D Euler Equations
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作者 R.Abgrall 《Communications on Applied Mathematics and Computation》 2023年第1期370-402,共33页
We show how to combine in a natural way(i.e.,without any test nor switch)the conservative and non-conservative formulations of an hyperbolic system that has a conservative form.This is inspired from two different clas... We show how to combine in a natural way(i.e.,without any test nor switch)the conservative and non-conservative formulations of an hyperbolic system that has a conservative form.This is inspired from two different classes of schemes:the residual distribution one(Abgrall in Commun Appl Math Comput 2(3):341–368,2020),and the active flux formulations(Eyman and Roe in 49th AIAA Aerospace Science Meeting,2011;Eyman in active flux.PhD thesis,University of Michigan,2013;Helzel et al.in J Sci Comput 80(3):35–61,2019;Barsukow in J Sci Comput 86(1):paper No.3,34,2021;Roe in J Sci Comput 73:1094–1114,2017).The solution is globally continuous,and as in the active flux method,described by a combination of point values and average values.Unlike the“classical”active flux methods,the meaning of the point-wise and cell average degrees of freedom is different,and hence follow different forms of PDEs;it is a conservative version of the cell average,and a possibly non-conservative one for the points.This new class of scheme is proved to satisfy a Lax-Wendroff-like theorem.We also develop a method to perform nonlinear stability.We illustrate the behaviour on several benchmarks,some quite challenging. 展开更多
关键词 Hyperbolic problems high order Active flux MOOD Residual distribution methods
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Improved finite difference method for pressure distribution of aerostatic bearing 被引量:4
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作者 郑书飞 蒋书运 《Journal of Southeast University(English Edition)》 EI CAS 2009年第4期501-505,共5页
An improved finite difference method (FDM)is described to solve existing problems such as low efficiency and poor convergence performance in the traditional method adopted to derive the pressure distribution of aero... An improved finite difference method (FDM)is described to solve existing problems such as low efficiency and poor convergence performance in the traditional method adopted to derive the pressure distribution of aerostatic bearings. A detailed theoretical analysis of the pressure distribution of the orifice-compensated aerostatic journal bearing is presented. The nonlinear dimensionless Reynolds equation of the aerostatic journal bearing is solved by the finite difference method. Based on the principle of flow equilibrium, a new iterative algorithm named the variable step size successive approximation method is presented to adjust the pressure at the orifice in the iterative process and enhance the efficiency and convergence performance of the algorithm. A general program is developed to analyze the pressure distribution of the aerostatic journal bearing by Matlab tool. The results show that the improved finite difference method is highly effective, reliable, stable, and convergent. Even when very thin gas film thicknesses (less than 2 Win)are considered, the improved calculation method still yields a result and converges fast. 展开更多
关键词 aerostatic bearing: pressure distribution Reynolds equation: finite difference method: variable step size
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Stability of the Dividing Distribution Function Method for ParticleSize Distribution Analysis in Small Angle X-Ray Scattering 被引量:2
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作者 Zhang Jinyuan Liu Chunlan Chen Yan 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 1996年第1期51-52,63+54-55,共5页
The Dividing Distribution Function (DDF) method is one of the methods by which the particle size distribution of ultrafine powder can be evaluated from its small angle X-ray scattering data. In this paper, the stabili... The Dividing Distribution Function (DDF) method is one of the methods by which the particle size distribution of ultrafine powder can be evaluated from its small angle X-ray scattering data. In this paper, the stability of the solution obtained from DDF method has been investigated through optimizing the coefficient matrix, introducing a damping factor and a least square treatment. All calculations were accomplished with a microcomputer. It was shown that the average deviations of the size distribution obtained are not larger than the assigned random errors to the scattering intensities as long as the corresponding requirements are satisfied. 展开更多
关键词 ultrafine powder particle size distribution small angle X-ray scattering dividing distribution function method
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Security Simulation of Continuous-Variable Quantum Key Distribution over Air-to-Water Channel Using Monte Carlo Method 被引量:1
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作者 Cai-Lang Xie Ying Guo +2 位作者 Yi-Jun Wang Duan Huang Ling Zhang 《Chinese Physics Letters》 SCIE CAS CSCD 2018年第9期10-13,共4页
Considering the ocean water's optical attenuation and the roughness of the sea surface, we analyze the security of continuous-variable (CV) quantum key distribution (QKD) based Mr-to-water channel. The effects of... Considering the ocean water's optical attenuation and the roughness of the sea surface, we analyze the security of continuous-variable (CV) quantum key distribution (QKD) based Mr-to-water channel. The effects of the absorp- tion and scattering on the transmittance of underwater quantum channel and the maximum secure transmission distance are studied. Considering the roughness of the sea surface, we simulate the performance bounds of CV QKD with different wind speeds using the Monte Carlo method. The results show that even if the secret key rate gradually reduces as the wind speed increases, the maximum transmission distance will not be affected obviously. Compared to the works regarding short-distance underwater optical communication, our research represents a significant step towards establishing secure communication between air platform and submarine vehicle. 展开更多
关键词 QKD Security Simulation of Continuous-Variable Quantum Key distribution over Air-to-Water Channel Using Monte Carlo Method CV
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Numerical method for wave height distribution within the artificial harbor with water depth of steep variation
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《Acta Oceanologica Sinica》 SCIE CAS CSCD 1998年第3期417-421,共5页
NumericalmethodforwaveheightdistributionwithintheartificialharborwithwaterdepthofsteepvariationINTRODUCTIONA... NumericalmethodforwaveheightdistributionwithintheartificialharborwithwaterdepthofsteepvariationINTRODUCTIONAnartificialharbor... 展开更多
关键词 WAVE Numerical method for wave height distribution within the artificial harbor with water depth of steep variation
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THE CHARACTERISTICS OF THUNDERSTORM FREQUENCY VARIATION AND THEIR POSSIBLE RELATION WITH THE ADJUSTMENT OF CROP DISTRIBUTION IN THE LEIZHOU PENINSULA
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作者 张羽 牛生杰 《Journal of Tropical Meteorology》 SCIE 2009年第1期89-92,共4页
In order to research possible influences of the adjustment of plant distribution on the development frequency of thunderstorms over the Leizhou Peninsula, mathematic statistic methods, including correlation analyses, ... In order to research possible influences of the adjustment of plant distribution on the development frequency of thunderstorms over the Leizhou Peninsula, mathematic statistic methods, including correlation analyses, 11 kinds of fitting models and all-variable regression methods, were used for analyses and research. The results show that the average trend of the number of annual thunderstorm days is descending obviously, and there are thunderstorms in all seasons, in which warm post-midday thunderstorms have taken up the most part, and high frequency is found from May to September, and the starting and ending dates of thunderstorms have a great annual discrepancy. The vegetation structure has been improved along with the reduction of rice fields and the area increment of sugarcane and fruits planting, which results in the decrease of the number of thunderstorm days; the change in the characteristics of winter spare fields, which is caused by the planting of vegetables, limits the formation of thunderstorms in early winter and late spring. Meanwhile, the area adjustment of peanut planting has little influence on the variation of thunderstorm days. The adjustment of principal crop distribution, such as rice, sugarcane, fruits and vegetables, may have obvious influence on the formation of thunderstorms, and sugarcane has the largest effect, followed in turn by rice, vegetables and fruits, and the adjustment of crop distribution has little influence on the starting and ending dates of thunderstorms. 展开更多
关键词 atmospheric physics thunderstorm frequency variation mathematic statistic methods adjustment of crop distribution
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Xiaomi India's New Distribution Method in the Post-Pandemic Era
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作者 Wanyu Li 《Proceedings of Business and Economic Studies》 2021年第4期65-70,共6页
In recent years,the Indian smartphone market has grown rapidly,and Xiaomi's expansion in this market has never stopped.However,Xiaomi India has and would face even more changes and challenges due to the impact of ... In recent years,the Indian smartphone market has grown rapidly,and Xiaomi's expansion in this market has never stopped.However,Xiaomi India has and would face even more changes and challenges due to the impact of the COVID-19 pandemic.This paper focuses on how Xiaomi India can adhere to its ethical business practices in changes and developments that will improve its distribution layout. 展开更多
关键词 Post-pandemic era Xiaomi India distribution method Ethical business
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Measurement of the g Factor of the 3.1232 MeV 19/2^(-) Level in ^(43)Sc by Perturbed Angular Distribution Method
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作者 Zhu Sheng-yun Li An-li +2 位作者 Gou Zheng-hui Zheng Sheng-nan Li Guang-sheng 《Chinese journal of nuclear physics》 1994年第3期239-242,共4页
The g-factor hence the magnetic moment,of the isomeric state <sup>43</sup>Sc(|9/2<sup>-</sup>,3.1232 MeV)has been measured by the time differential perturbed angular distributionmethod.The me... The g-factor hence the magnetic moment,of the isomeric state <sup>43</sup>Sc(|9/2<sup>-</sup>,3.1232 MeV)has been measured by the time differential perturbed angular distributionmethod.The measured values are g=0.3279(19)and μ=3.108(18)nm. 展开更多
关键词 G-FACTOR Magnetic moment Perturbed angular distribution method ^(43)Sc(19/2^(-))
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A Study on the Reasonable Distribution of Total Funds
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作者 Cui'e Liu Guojie Zhao 《Chinese Business Review》 2006年第1期47-51,共5页
How to distribute total sum of funds among different investment priorities? It is not only a theoretical problem in Management Accounting, but also a realistic problem in the investment decision of an enterprise. In ... How to distribute total sum of funds among different investment priorities? It is not only a theoretical problem in Management Accounting, but also a realistic problem in the investment decision of an enterprise. In this paper, the author queries the method of "use linear programming to find out optimum combination", which put forward in management accounting, and gives a convenient and reasonable method---effective gradient method. 展开更多
关键词 reasonable distribution of total funds linear programming effective gradient method optimum combination
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Fiber Bundle Topology Optimization for Surface Flows
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作者 Yongbo Deng Weihong Zhang +2 位作者 Jihong Zhu Yingjie Xu Jan G Korvink 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第3期236-264,共29页
This paper presents a topology optimization approach for the surface flows on variable design domains.Via this approach,the matching between the pattern of a surface flow and the 2-manifold used to define the pattern ... This paper presents a topology optimization approach for the surface flows on variable design domains.Via this approach,the matching between the pattern of a surface flow and the 2-manifold used to define the pattern can be optimized,where the 2-manifold is implicitly defined on another fixed 2-manifold named as the base manifold.The fiber bundle topology optimization approach is developed based on the description of the topological structure of the surface flow by using the differential geometry concept of the fiber bundle.The material distribution method is used to achieve the evolution of the pattern of the surface flow.The evolution of the implicit 2-manifold is realized via a homeomorphous map.The design variable of the pattern of the surface flow and that of the implicit 2-manifold are regularized by two sequentially implemented surface-PDE filters.The two surface-PDE filters are coupled,because they are defined on the implicit 2-manifold and base manifold,respectively.The surface Navier-Stokes equations,defined on the implicit 2-manifold,are used to describe the surface flow.The fiber bundle topology optimization problem is analyzed using the continuous adjoint method implemented on the first-order Sobolev space.Several numerical examples have been provided to demonstrate this approach,where the combination of the viscous dissipation and pressure drop is used as the design objective. 展开更多
关键词 Fiber bundle Topology optimization 2-MANIFOLD Surface flow Material distribution method Porous medium model
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A new topology optimization method of an asymmetric phononic crystal for enhancing bandgap distributions
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作者 Liming GUO Chiye YANG +3 位作者 Jing LIU Hengtai NI Guang PAN Baowei SONG 《Science China(Technological Sciences)》 2025年第10期493-494,共2页
To address the challenges for vibration suppression in the precision sensors of underwater vehicles,phononic crystals have attracted significant attention due to the superior capabilities in elastic wave manipulation ... To address the challenges for vibration suppression in the precision sensors of underwater vehicles,phononic crystals have attracted significant attention due to the superior capabilities in elastic wave manipulation and vibration suppression.Unlike conventional damping materials,the phononic crystals can effectively suppress the wave propagation in the specific frequency ranges due to the unique periodic microstructures. 展开更多
关键词 A new topology optimization method of an asymmetric phononic crystal for enhancing bandgap distributions
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Clinical efficacy observation of thalamic pain treated with acupuncture under the guidance of evidence-based medicine 被引量:2
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作者 樊小农 张雪 +1 位作者 武连仲 王海荣 《World Journal of Acupuncture-Moxibustion》 2012年第3期1-5,17,共6页
Objective To study the feasibility of the crossover trial design and the minimal imbalance index random distribution method in the clinical small-sample-size randomized controlled trial(RCT) research of thalamic pai... Objective To study the feasibility of the crossover trial design and the minimal imbalance index random distribution method in the clinical small-sample-size randomized controlled trial(RCT) research of thalamic pain treated with acupuncture under the guidance of evidence-based medicine(EBM).Methods The crossover trial design was adopted.Eleven cases with the definite diagnosis were randomized into a program-I group(6 cases,treated with acupuncture before western medicine) and a program-II group(5 cases,treated with western medicine before acupuncture) according to the minimal imbalance index method.In the statistical analysis,the groups were named as an acupuncture group and a western medicine group separately,11 cases in each one.Acupuncture was applied to Xìmén(郄门 PC 4),Yīnxì(阴郄 HT 6),Xuèhǎi(血海 SP 10),etc.In the control treatment,Carbamazepine was prescribed for oral administration.Either the duration of treatment or the wash-out period was 10 days.The visual analogue scale(VAS) was adopted for the efficacy assessment.Results The total effective was 100.0%(11/11) after treatment in either group.The remarkably effective rates were 63.6%(7/11) and 36.4%(4/11) in the acupuncture group and the western medicine group separately,without statistically significant difference in comparison.Conclusion The crossover trial design and the minimal imbalance index distribution method can accomplish RCT of the clinical acupuncture and moxibustion research with the small sample size involved.They can provide the high-quality evidences for clinical acupuncture research.Acupuncture therapy can achieve the same therapeutic effect as Carbamazepine,the common western medicine,and the efficacy of it is potentially superior to that of western medicine. 展开更多
关键词 thalamic pain acupuncture therapy evidence-based medicine(EBM) crossover trial design random minimal imbalance index distribution method
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Improved Calculation of Vibrational Energy Levels in F2 Molecule using the RKR Method
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作者 王建坤 吴振森 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第2期155-159,I0001,共6页
The potential energy curves of the ground state X2∑+g of the fluorine molecule have been accurately reconstructed employing the Ryderg-Klein-Rees (RKR) method extrapolated by a Hulburt and Hirschfeler potential fu... The potential energy curves of the ground state X2∑+g of the fluorine molecule have been accurately reconstructed employing the Ryderg-Klein-Rees (RKR) method extrapolated by a Hulburt and Hirschfeler potential function for longer internuclear distances. Solving the corresponding radial one-dimensional Schr?dinger equation of nuclear motion yields 22 bound vibrational levels above v=0. The comparison of these theoretical levels with the experimental data yields a mean absolute deviation of about 7.6 cm^-1 over the 23 levels. The highest vibrational level energy obtained using this method is 13308.16 cm?1 and the relative deviation compared with the experimental datum of 13408.49 cm^-1 is only 0.74%. The value from our method is much closer and more accurate than the value obtained by the quantum mechanical ab initio method by Bytautas. The reported agreement of the vibrational levels and dissociation energy with experiment is contingent upon the potential energy curve of the F2 ground state. 展开更多
关键词 Potential energy function Fluorine Vibrational levels distribution RKR method
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基于WVD/ATDM的铝合金板孔损伤位置与区域识别
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作者 徐建新 宋旭东 武耀罡 《中国民航大学学报》 CAS 2022年第1期53-59,共7页
为识别铝合金板孔损伤位置及区域,以Lamb波为研究基础,提出基于魏格纳-威利分布(WVD,WignerVille distribution)和到达时间差值法(ATDM,arrival time difference method)的损伤识别技术。首先,采集实验铝合金板健康和有损模型的Lamb信号... 为识别铝合金板孔损伤位置及区域,以Lamb波为研究基础,提出基于魏格纳-威利分布(WVD,WignerVille distribution)和到达时间差值法(ATDM,arrival time difference method)的损伤识别技术。首先,采集实验铝合金板健康和有损模型的Lamb信号,对其差值信号进行WVD分析,准确提取损伤反射信号到达时间;其次,通过ATDM建立各传感器间的距离差值关系,确定孔损伤位置中心并预测最大损伤半径,从而实现对孔损伤关键指标的识别;最后,通过数值模拟进一步验证该方法,结果表明,基于WVD/ATDM的损伤识别技术不仅能准确识别出孔损伤位置,而且能够有效地识别损伤区域面积。 展开更多
关键词 铝合金板 LAMB波 WVD(Wigner-Ville distribution)/ATDM(arrival time difference method)方法 孔损伤 位置识别 区域识别
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Numerical simulation of multi-phase combustion flow in solid rocket motors with metalized propellant 被引量:5
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作者 SHAFQAT Wahab 《航空动力学报》 EI CAS CSCD 北大核心 2009年第7期1654-1660,共7页
Multi-phase flowfield simulation has been performed on solid rocket motor and effect of multi-phases on the performance prediction of the solid rocket motor(SRM) is investigation.During the combustion of aluminized pr... Multi-phase flowfield simulation has been performed on solid rocket motor and effect of multi-phases on the performance prediction of the solid rocket motor(SRM) is investigation.During the combustion of aluminized propellant,the aluminum particles in the propellant melt and formliquid aluminum at the burning propellant surface.So the flow within the rocket motor is multi phase or two phase because it contains droplets and smoke particles of Al2O3.Flowsi mulations have been performed on a large scale motor,to observe the effect of the flowfield onthe chamber and nozzle as well.Uniform particles diameters and Rosin-Rammler diameter distribution method that is based on the assumption that an exponential relationship exists betweenthe droplet diameter,dand mass fraction of droplets with diameter greater thandhave been used for the si mulation of different distribution of Al2O3 droplets present in SRM.Particles sizes in the range of 1-100μm are used,as being the most common droplets.In this approachthe complete range of particle sizes is dividedinto a set of discrete size ranges,eachto be defined by single streamthat is part of the group.Roe scheme-flux differencing splitting based on approxi mate Riemann problem has been used to si mulate the effects of the multi-phase flowfeild.This is second order upwind scheme in which flux differencing splitting method is employed.To cater for the turbulence effect,Spalart-All maras model has been used.The results obtained show the great sensitivity of this diameters distribution and particles concentrations to the SRMflowdynamics,primarily at the motor chamber and nozzle exit.The results are shown with various sizes of the particles concentrations and geometrical configurations including models for SRM and nozzle.The analysis also provides effect of multi-phase on performance prediction of solid rocket motor. 展开更多
关键词 solid rocket motor nozzle multiphase flow Rosin-Rammler diameter distribution method Roe FDS (flux differencing splitting) performance prediction
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Distributed Collaborative Response Surface Method for Mechanical Dynamic Assembly Reliability Design 被引量:25
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作者 BAI Guangchen FEI Chengwei 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2013年第6期1160-1168,共9页
Because of the randomness of many impact factors influencing the dynamic assembly relationship of complex machinery, the reliability analysis of dynamic assembly relationship needs to be accomplished considering the r... Because of the randomness of many impact factors influencing the dynamic assembly relationship of complex machinery, the reliability analysis of dynamic assembly relationship needs to be accomplished considering the randomness from a probabilistic perspective. To improve the accuracy and efficiency of dynamic assembly relationship reliability analysis, the mechanical dynamic assembly reliability(MDAR) theory and a distributed collaborative response surface method(DCRSM) are proposed. The mathematic model of DCRSM is established based on the quadratic response surface function, and verified by the assembly relationship reliability analysis of aeroengine high pressure turbine(HPT) blade-tip radial running clearance(BTRRC). Through the comparison of the DCRSM, traditional response surface method(RSM) and Monte Carlo Method(MCM), the results show that the DCRSM is not able to accomplish the computational task which is impossible for the other methods when the number of simulation is more than 100 000 times, but also the computational precision for the DCRSM is basically consistent with the MCM and improved by 0.40-4.63% to the RSM, furthermore, the computational efficiency of DCRSM is up to about 188 times of the MCM and 55 times of the RSM under 10000 times simulations. The DCRSM is demonstrated to be a feasible and effective approach for markedly improving the computational efficiency and accuracy of MDAR analysis. Thus, the proposed research provides the promising theory and method for the MDAR design and optimization, and opens a novel research direction of probabilistic analysis for developing the high-performance and high-reliability of aeroengine. 展开更多
关键词 machinery dynamic assembly reliability analysis distributed collaborative response surface method blade-tip radial running clearance
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Structural dynamic responses of a stripped solar sail subjected to solar radiation pressure 被引量:6
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作者 Junhui ZHANG Na WU +1 位作者 An TONG Yinghua LIU 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2020年第8期2204-2211,共8页
The stripped solar sail whose membrane is divided into separate narrow membrane strips is believed to have the best structural efficiency.In this paper,the stripped solar sail structure is regarded as an assembly made... The stripped solar sail whose membrane is divided into separate narrow membrane strips is believed to have the best structural efficiency.In this paper,the stripped solar sail structure is regarded as an assembly made by connecting a number of boom-strip components in sequence.Considering the coupling effects between booms and membrane strips,an exact and semianalytical method to calculate structural dynamic responses of the stripped solar sail subjected to solar radiation pressure is established.The case study of a 100 m stripped solar sail shows that the stripped architecture helps to reduce the static deflections and amplitudes of the steady-state dynamic response.Larger prestress of the membrane strips will decrease stiffness of the sail and increase amplitudes of the steady-state dynamic response.Increasing thickness of the boom will benefit to stability of the sail and reduce the resonant amplitudes.This proposed semi-analytical method provides an efficient analysis tool for structure design and attitude control of the stripped solar sail. 展开更多
关键词 Distributed transfer function method Frequency response Solar radiation pressure Solar sail Structural dynamic response
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Distributed wide field electromagnetic method based on high-order 2^(n) sequence pseudo random signal 被引量:5
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作者 Yang YANG Ji-shan HE +1 位作者 Fan LING Yu-zhen ZHU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第5期1609-1622,共14页
To make three-dimensional electromagnetic exploration achievable,the distributed wide field electromagnetic method(WFEM)based on the high-order 2^(n) sequence pseudo-random signal is proposed and realized.In this meth... To make three-dimensional electromagnetic exploration achievable,the distributed wide field electromagnetic method(WFEM)based on the high-order 2^(n) sequence pseudo-random signal is proposed and realized.In this method,only one set of high-order pseudo-random waveforms,which contains all target frequencies,is needed.Based on high-order sequence pseudo-random signal construction algorithm,the waveform can be customized according to different exploration tasks.And the receivers are independent with each other and dynamically adjust the acquisition parameters according to different requirements.A field test in the deep iron ore of Qihe−Yucheng showed that the distributed WFEM based on high-order pseudo-random signal realizes the high-efficiency acquisition of massive electromagnetic data in quite a short time.Compared with traditional controlled-source electromagnetic methods,the distributed WFEM is much more efficient.Distributed WFEM can be applied to the large scale and high-resolution exploration for deep resources and minerals. 展开更多
关键词 distributed wide field electromagnetic method(WFEM) high-order pseudo-random signal MULTIFREQUENCY massive data
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Analysis of Rolling Pressure in Asymmetrical Rolling Process by Slab Method 被引量:13
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作者 TIAN Yong GUO Yan-hui WANG Zhao-dong WANG Guo-dong 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2009年第4期22-26,38,共6页
The plane strain asymmetrical rolling was analyzed using slab method. The contact arc was replaced by parabola, and the constant surface friction status was adopted during the analysis. The deformation area was divide... The plane strain asymmetrical rolling was analyzed using slab method. The contact arc was replaced by parabola, and the constant surface friction status was adopted during the analysis. The deformation area was divided into three zones according to the direction of the friction. Then, the three zones were studied, respectively. A rolling force model and a rolling torque model were developed based on the analysis, and they were used to analyze the influ- ence of asymmetrical rolling factors on deformation area and unit pressure if they had good precision which was determined by comparing the calculated results with the measured ones. 展开更多
关键词 asymmetrical rolling slab method asymmetrical factor specific pressure distribution
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Structural analysis by Rietveld refinement of calcium and lanthanum phosphosilicate apatites 被引量:1
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作者 Hela Njema Khaled Boughzala +1 位作者 Habib Boughzala Khaled Bouzouita 《Journal of Rare Earths》 SCIE EI CAS CSCD 2013年第9期897-904,共8页
Britholites with the general formula Ca10-xLnx(PO4)6-x(SiO4)xF2, (0≤x≤6) are considered to be promising matrices for the confinement of the by-products in the nuclear industry. A thermodynamic study showed tha... Britholites with the general formula Ca10-xLnx(PO4)6-x(SiO4)xF2, (0≤x≤6) are considered to be promising matrices for the confinement of the by-products in the nuclear industry. A thermodynamic study showed that the stability of these compounds de-creased as the substitution rate increased. The present work was an attempt to gain more information about the structural changes in-duced by the substitution, in order to understand the observed stability decrease. The samples were successfully synthesized as a sin-gle-phase apatite by a solid-state reaction between 1200 and 1400 °C. The structural refinement indicated that the La3+ions preferen-tially occupied the 6(h) sites. A progressive shift of F-along the c-axis outside its ideal position occurred as a result of the substitution increase. This might be the cause of the observed stability decrease, especially as the energies of the La-O, La-F and Si-O bonds are higher than those of Ca-O, Ca-F and P-O. The distribution of La3+ between the two non-equivalent sites was confirmed by the charge distribution method. 展开更多
关键词 britholites Rietveld refinement infrared spectroscopy charge distribution method rare earths
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