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Phase distortion correction of fringe patterns in spaceborne Doppler asymmetric spatial heterodyne interferometry 被引量:1
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作者 PEI Hui-yi JIANG Lun +4 位作者 WANG Jin-jiang CUI Yong FANG Yuan-xiang ZHANG Jia-ming CHEN Ci 《中国光学(中英文)》 北大核心 2025年第2期382-392,共11页
As an advanced device for observing atmospheric winds,the spaceborne Doppler Asymmetric Spatial Heterodyne(DASH)interferometer also encounters challenges associated with phase distortion,par-ticularly in limb sounding... As an advanced device for observing atmospheric winds,the spaceborne Doppler Asymmetric Spatial Heterodyne(DASH)interferometer also encounters challenges associated with phase distortion,par-ticularly in limb sounding scenarios.This paper discusses interferogram modeling and phase distortion cor-rection techniques for spaceborne DASH interferometers.The modeling of phase distortion interferograms with and without Doppler shift for limb observation was conducted,and the effectiveness of the analytical expression was verified through numerical simulation.The simulation results indicate that errors propagate layer by layer while using the onion-peeling inversion algorithm to handle phase-distorted interferograms.In contrast,the phase distortion correction algorithm can achieve effective correction.This phase correction method can be successfully applied to correct phase distortions in the interferograms of the spaceborne DASH interferometer,providing a feasible solution to enhance its measurement accuracy. 展开更多
关键词 Doppler asymmetric spatial heterodyne spectroscopy phase distortion phase inversion atmospheric wind measurement
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Metamorphopsia after surgery for rhegmatogenous retinal detachment 被引量:1
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作者 Han-Tao Zhou Zhong Lin 《International Journal of Ophthalmology(English edition)》 2025年第1期168-177,共10页
Improvements in surgical techniques have led to 90% success in the surgical repair of rhegmatogenous retinal detachment(RRD).However,anatomical reattachment of the retina does not ensure complete recovery of visual fu... Improvements in surgical techniques have led to 90% success in the surgical repair of rhegmatogenous retinal detachment(RRD).However,anatomical reattachment of the retina does not ensure complete recovery of visual function.The incidence of metamorphopsia remains the most common postoperative complaint,from 24% to 88.6%.Currently,the risk factors of metamorphopsia are categorized into macular involvement,retinal shift,outer retinal folds,subretinal fluid,secondary epiretinal membrane,outer retinal layer damage,and surgical approach.The associations of metamorphopsia with postoperative best-corrected visual acuity and postoperative vision-related quality of life were still controversial.The most popular methods for assessment of metamorphopsia remain the Amsler grid and M-Charts.Most treatments cannot progress beyond the management of negative visual sensations,through methods such as occlusion therapy and aniseikonia-correcting spectacles.The main treatment approach involves RRD prevention and the management of risk factors that can lead to postoperative metamorphopsia after RRD repair.Additional research concerning metamorphopsia treatment,further upgrades of auxiliary inspection methods,and more accurate microstructural assessments are needed to address this common complication. 展开更多
关键词 retinal detachment rhegmatogenous retinal detachment METAMORPHOPSIA visual distortion
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Suppressing high voltage chemo-mechanical degradation in single crystal nickel-rich cathodes for high-performance all-solid-state lithium batteries 被引量:1
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作者 Yirong Xiao Le Yang +5 位作者 Chaoyuan Zeng Ze Hua Shuangquan Qu Niaz Ahmad Ruiwen Shao Wen Yang 《Journal of Energy Chemistry》 2025年第3期377-385,共9页
Sulfide-based all-solid-state lithium batteries suffer from electrochemo-mechanical damage to Ni-rich oxide-based cathode active materials(CAMs),primarily caused by severe volume changes,results in significant stress ... Sulfide-based all-solid-state lithium batteries suffer from electrochemo-mechanical damage to Ni-rich oxide-based cathode active materials(CAMs),primarily caused by severe volume changes,results in significant stress and strain,causes micro-cracks and interfacial contact loss at potentials>4.3 V(vs.Li/Li^(+)).Quantifying micro-cracks and voids in CAMs can reveal the degradation mechanisms of Ni-rich oxidebased cathodes during electrochemical cycling.Nonetheless,the origin of electrochemical-mechanical damage remains unclear.Herein,We have developed a multifunctional PEG-based soft buffer layer(SBL)on the surface of carbon black(CB).This layer functions as a percolation network in the single crystal LiNi_(0.83)Co_(0.07)Mn_(0.1)O_(2)and Li_(6)PS_(5)Cl composite cathode layer,ensuring superior ionic conductivity,reducing void formation and particle cracking,and promoting uniform utilization of the cathode active material in all-solid-state lithium batteries(ASSLBs).High-angle annular dark-field STEM combined with nanoscale X-ray holo-tomography and plasma-focused ion beam scanning electron microscopy confirmed that the PEG-based SBL mitigated strain induced by reaction heterogeneity in the cathode.This strain produces lattice stretches,distortions,and curved transition metal oxide layers near the surface,contributing to structural degradation at elevated voltages.Consequently,ASSLBs with a LiNi_(0.83)Co_(0.07)Mn_(0.1)O_(2)cathode containing LCCB-10(CB/PEG mass ratio:100/10)demonstrate a high areal capacity(2.53 mAh g^(-1)/0.32 mA g^(-1))and remarkable rate capability(0.58 mAh g^(-1)at 1.4 mA g^(-1)),with88%capacity retention over 1000 cycles. 展开更多
关键词 Single crystal nickel-rich oxide cathode Lattice stretches and distortions Reaction heterogeneity Percolation network All-solid-state lithium batteries
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Structure-tailored superlattice Bi_(7)Ti_(4)NbO_(21):Coupling octahedral tilting and rotation induced high ferroelectric polarization for efficient piezo-photocatalytic CO_(2) reduction 被引量:1
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作者 Jingren Ni Rufang Zhao +8 位作者 Chendi Shi Yuanyuan Ji Aize Hao Aiting Xie Hongjian Yu Siew Kheng Boong Hiang Kwee Lee Chuanqiang Zhou Jie Han 《Advanced Powder Materials》 2025年第2期12-21,共10页
Intergrowth ferroelectric semiconductors with excellent spontaneous polarization field are highly promising piezo-photocatalytic candidate materials.In addition,developing structural design and revealing polarization ... Intergrowth ferroelectric semiconductors with excellent spontaneous polarization field are highly promising piezo-photocatalytic candidate materials.In addition,developing structural design and revealing polarization enhancement in-depth mechanism are top priorities.Herein,we introduce the intergrowth ferroelectrics Bi_(7)Ti_(4)NbO_(21)thin-layer nanosheets for piezo-photocatalytic CO_(2)reduction.Density functional theory(DFT)calculations indicate that interlayer lattice mismatch leads to increased tilting and rotation angle of Ti/NbO_(6)octahedra on perovskite-like layers,serving as the main reason for increased polarization.Furthermore,the tilting and rotation angle of the interlayer octahedron further increase under stress,suggesting a stronger driving force generated to facilitate charge carrier separation efficiency.Meanwhile,Bi_(7)Ti_(4)NbO_(21)nanosheets provide abundant active sites to effectively adsorb CO_(2)and acquire sensitive stress response,thereby presenting synergistically advanced piezo-photocatalytic CO_(2)reduction activity with a high CO generation rate of 426.97μmol g^(-1)h^(-1).Our work offers new perspectives and directions for initiating and investigating the mechanisms of high-performance intergrowth piezo-photocatalysts. 展开更多
关键词 ntergrowth Bi_(7)Ti_(4)NbO_(21)nanosheets Structural tailoring Ferroelectric polarization Octahedral distortion Piezo-photocatalytic CO_(2)reduction
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海外英文期刊中国共产党研究成果题录(2016年)
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作者 王野(整理) 《国外理论动态》 北大核心 2025年第2期F0003-F0003,共1页
1.C.Li,"Holding‘China Inc.’Together:The CCP and The Rise of China’s Yangqi",The China Quarterly,Vol.228,2016,pp.927-949.2.J.Gao,"‘Bypass the Lying Mouths’:How Does the CCP Tackle Information Distor... 1.C.Li,"Holding‘China Inc.’Together:The CCP and The Rise of China’s Yangqi",The China Quarterly,Vol.228,2016,pp.927-949.2.J.Gao,"‘Bypass the Lying Mouths’:How Does the CCP Tackle Information Distortion at Local Levels?",The China Quarterly,Vol.228,2016,pp.950-969.3.C.Sorace,"Party Spirit Made Flesh:The Production of Legitimacy in the Aftermath of the 2008Sichuan Earthquake",The China Journal,Vol.76,2016,pp.41-62.4.Y.Yeo,"Complementing the Local Discipline Inspection Commissions of the CCP:Empowerment of the Central Inspection Groups",Journal of Contemporary China,Vol.25,No.97,2016,pp.59-74. 展开更多
关键词 Sichuan Earthquake local discipline inspection commissions production legitimacy China Inc Yangqi Information Distortion LEGITIMACY information distortion
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Effect of lattice distortion of CeO_(2) on direct synthesis of dimethyl carbonate from CO_(2) and methanol
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作者 ZHAO Jiangtao AI Peipei +3 位作者 ZHANG Xuyan SHAO Xuhao TAN Minghui HUANG Wei 《燃料化学学报(中英文)》 北大核心 2025年第11期1590-1602,共13页
The conversion of CO_(2)to dimethyl carbonate(DMC)offers a promising route for CO_(2)utilization.In this study,four CeO2 catalysts with distinct nanostructures were synthesized via a template-free hydrothermal method ... The conversion of CO_(2)to dimethyl carbonate(DMC)offers a promising route for CO_(2)utilization.In this study,four CeO2 catalysts with distinct nanostructures were synthesized via a template-free hydrothermal method by systematically varying the types and concentrations of precipitants as well as the hydrothermal reaction conditions,and they were employed for DMC synthesis from CO_(2)and methanol.The atomic arrangements of CeO_(2)varied significantly with its morphology,leading to differences in lattice distortion,which directly influenced the concentration of oxygen vacancies.Notably,the CeO_(2)nanospheres,which exhibited the highest lattice distortion and oxygen vacancy concentration,achieved a DMC yield(11.12 mmol/g)48 times greater than that of the nanocubes(0.23 mmol/g).The results indicated that oxygen vacancies played a pivotal role in the catalytic process by facilitating the adsorption and activation of CO_(2)to form bidentate carbonates,as well as activating methanol to generate methoxy species.These processes collectively promoted the formation of the key intermediate(*CH3OCOO).This study proposes a strategy to enhance the oxygen vacancy concentration by increasing lattice distortion,providing valuable insights for designing high-performance CeO_(2)catalysts for DMC synthesis. 展开更多
关键词 cerium dioxide lattice distortion oxygen vacancy
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Studying and Estimating Visual Pollution in Irbid City (Centre of Irbid City-Case Study)
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作者 Mohmd Addad Shehadeh A-Taani 《Journal of Environmental Science and Engineering(A)》 CAS 2025年第1期14-30,共17页
Despite the global attention towards pollution,it remains a significant global threat and challenge for both developed and developing countries.Urbanization and economic development influence different types of pollut... Despite the global attention towards pollution,it remains a significant global threat and challenge for both developed and developing countries.Urbanization and economic development influence different types of pollution.Visual pollution is considered a new phenomenon referring to the impact of existing and growing mainstream pollution which impairs an individual’s ability to enjoy visits or views.Recently,Jordanian cities have expanded in response to urbanization and ongoing development.Irbid City has the second largest population in Jordan after the capital Amman City highest population density in Jordan.In the modern era,Irbid City dramatically increased in population and dimension.The growth of the demographic population has been significant and has led to overpopulation,rapid urbanization,and unresolved problems associated with spatial planning and infrastructures leading to different types of pollution including visual pollution.The study area focuses on the city center with the most crowded population through field visits and actual observations.The study technique is descriptive and analytical,with a focus on meticulous monitoring and a follow-up-based questionnaire which is a tool for the study,involving data collection,classification,presentation,analysis,interpretation,and exploration to identify new facts and generalizations that can help solve current issues of visual pollution.The study provides recommendations for Irbid Municipal to eliminate visual pollution,in parallel with stricter supervision from the municipality during the building process to ensure proper implementation of the new rules,adopting an integrated policy for the city with the rest of the social,political,sensory,cultural,economic,and functional aspects,so that this policy is in the short and long term. 展开更多
关键词 Visual pollution Irbid city spatial planning OVERPOPULATION QUESTIONNAIRE visual distortion urban planning.
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Shrinking India:Visualizing time-space implication of introduction of semihigh-speed trains in India
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作者 Vimal Kumar Arulmozhi Shreyas P.Bharule 《High-Speed Railway》 2025年第2期93-104,共12页
Indian Railways have been the largest people moving transport infrastructure in India.Over the years the systems and trains have been upgraded resulting in both better passenger amenities and reduction in travel time.... Indian Railways have been the largest people moving transport infrastructure in India.Over the years the systems and trains have been upgraded resulting in both better passenger amenities and reduction in travel time.The newest addition is the Vande Bharat Express,a semi-high-speed train that was introduced in India in 2019.The train currently runs between 10 routes and has brought significant changes to India’s railway network.This article explores the introduction of Vande Bharat Express trains in India and its effects on the country’s interstation time-space shrinkage using cartographic techniques.The cartographic techniques like stepwise multidimensional scaling and interpolation using the distance cartogram plugin in QGIS are mainly used for generating the time-space maps for various speeds.The limitations of these techniques and the methods to overcome those limitations are also explored in this article. 展开更多
关键词 Vande Bharat trains Multidimensional scaling INTERPOLATION Time-space Map distortion
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Visible and near-infrared image fusion based on information complementarity
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作者 Zhuo Li Shiliang Pu +2 位作者 Mengqi Ji Feng Zeng Bo Li 《CAAI Transactions on Intelligence Technology》 2025年第1期193-206,共14页
Images with complementary spectral information can be recorded using image sensors that can identify visible and near-infrared spectrum.The fusion of visible and nearinfrared(NIR)aims to enhance the quality of images ... Images with complementary spectral information can be recorded using image sensors that can identify visible and near-infrared spectrum.The fusion of visible and nearinfrared(NIR)aims to enhance the quality of images acquired by video monitoring systems for the ease of user observation and data processing.Unfortunately,current fusion algorithms produce artefacts and colour distortion since they cannot make use of spectrum properties and are lacking in information complementarity.Therefore,an information complementarity fusion(ICF)model is designed based on physical signals.In order to separate high-frequency noise from important information in distinct frequency layers,the authors first extracted texture-scale and edge-scale layers using a two-scale filter.Second,the difference map between visible and near-infrared was filtered using the extended-DoG filter to produce the initial visible-NIR complementary weight map.Then,to generate a guide map,the near-infrared image with night adjustment was processed as well.The final complementarity weight map was subsequently derived via an arctanI function mapping using the guide map and the initial weight maps.Finally,fusion images were generated with the complementarity weight maps.The experimental results demonstrate that the proposed approach outperforms the state-of-the-art in both avoiding artificial colours as well as effectively utilising information complementarity. 展开更多
关键词 color distortion image fusion information complementarity low light NEAR-INFRARED
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Tuning the e_(g)^(*) band broadening of the in-situ NiOOH by W doping for efficient biomass electrooxidation
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作者 Jinlv Wei Jianlong Zhang +5 位作者 Huan Wen Zhixiang Zhai Fangyuan Guan Zelong Sun Jia Wu Shibin Yin 《Chinese Journal of Structural Chemistry》 2025年第5期19-27,共9页
5-Hydroxymethylfurfural electrooxidation reaction(HMFOR)provides a promising route for producing highvalue-added compounds.It is generally believed that NiOOH is the active species in HMFOR process,but its inherently ... 5-Hydroxymethylfurfural electrooxidation reaction(HMFOR)provides a promising route for producing highvalue-added compounds.It is generally believed that NiOOH is the active species in HMFOR process,but its inherently poor electron transfer ability leads to limited catalytic activity.In this work,a W doping strategy is adopted to regulate the electron transfer between NiOOH and reaction molecules.Electrochemical results show that W-doped Ni_(5)P_(4)-R exhibits excellent electrochemical performance for the oxidation of HMF to FDCA with the conversion of HMF and yield of FDCA both close to~100%.Density functional theory and in-situ characterization reveal that the introduction of W causes the distortion of NiOOH lattice,resulting in the Jahn-Teller distortion and the elimination of orbital degeneracy,thereby broadening the e_(g)^(*)band of NiOOH.This feature is beneficial for the electron transfer between W-doped NiOOH and HMF(1.31 e^(-)),thereby promoting the C–H bond activation of the aldehyde group in HMF and effectively reducing the energy barrier of rate-determining step(RDS). 展开更多
关键词 5-Hydroxymethylfurfural oxidation 2 5-Furandicarboxylic acid W-doped Jahn-Teller distortion NIOOH
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Differential-geometry-based multi-dimensional joint position-velocity estimation using Crab pulsar profile distortion
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作者 Jin LIU Huanzi ZHANG +1 位作者 Xiaolin NING Xin MA 《Chinese Journal of Aeronautics》 2025年第1期551-567,共17页
The traditional orbit determination method based on pulsar profile distortion can determine the six elements of the orbit.However,the estimation accuracies of these methods are limited and the computational load of a ... The traditional orbit determination method based on pulsar profile distortion can determine the six elements of the orbit.However,the estimation accuracies of these methods are limited and the computational load of a six-dimensional search is huge.To solve this problem,the differential-geometry-based Multi-dimensional Joint Position-Velocity Estimation(MJPVE)using Crab pulsar profile distortion is proposed in this paper.Firstly,through theoretical analysis,it is found that the pulsar profile distortion caused by the initial state error in some joint positionvelocity directions is very small.In other words,the accuracies of estimation in these directions are very low.Namely,the search dimension can be reduced,which in turn greatly reduces the computational load.Then,we construct the chi-squared function of the pulsar profile with respect to the estimation error in joint position-velocity direction and use differential geometry to find the joint position-velocity directions corresponding to different degrees of distortion.Finally,we utilize the grid search based on directory folding in these joint position-velocity directions corresponding to large degrees of distortion to obtain the joint position-velocity estimation.The experimental results show that compared with the grouping bi-chi-squared inversion method,MJPVE has high precision and extensive navigation information. 展开更多
关键词 Joint Position-Velocity Estimation PULSARS Profile Distortion Orbit Determination Differential Geometry
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Frequency Adaptive Grid Synchronization Detection Algorithm Based on SOGI
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作者 Jie Shao Zihao Zhang +5 位作者 Quan Xu Tiantian Cai Junye Li Baicheng Xiang Shijie Li Xianfeng Xu 《Energy Engineering》 2025年第6期2291-2307,共17页
In response to the complex working conditions of the power grid caused by the high proportion of new energy access,which leads to insufficient output accuracy of the second-order generalized integrator(SOGI)phaselocke... In response to the complex working conditions of the power grid caused by the high proportion of new energy access,which leads to insufficient output accuracy of the second-order generalized integrator(SOGI)phaselocked loop,this article proposes an improved frequency adaptive phase-locked loop structure for SOGI.Firstly,an amplitude compensation branch is introduced to compensate for the SOGI tracking fundamental frequency signal,ensuring the accuracy of the SOGI output orthogonal signal under frequency fluctuation conditions.Secondly,by cascading two adaptive SOGI modules,the suppression capability of low-order harmonics and Direct Current(DC)components has been improved.Finally,the positive and negative sequence separation method of orthogonal signals is introduced to eliminate the influence of unbalanced components on the phase-locked loop.The comparative experiment with the classic SOGI-PLL method shows that the proposed phase-locked loop structure effectively improves the accuracy of power grid synchronization detection under complex working conditions such as harmonic components,unbalanced components,and frequency fluctuations.It can complete frequency detection within 1.5 power frequency cycles,and the detected fundamental frequency positive sequence voltage has a higher sinuosity and harmonic distortion rate within 0.5%. 展开更多
关键词 Phase-locked loop second-order generalized integrator pre-filtering frequency adaptation harmonic distortion
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Numerical Evaluation of the Performance Enhancement of S-Shaped Diffuser at the Intake of Gas Turbine by Energy Promoters
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作者 Hussain H.Al-Kayiem Raed A.Jessam +1 位作者 Sinan S.Hamdi Ali M.Tukkee 《Energy Engineering》 2025年第4期1311-1335,共25页
Size reduction of the gas turbines(GT)by reducing the inlet S-shaped diffuser length increases the powerto-weight ratio.It improves the techno-economic features of the GT by lesser fuel consumption.However,this Length... Size reduction of the gas turbines(GT)by reducing the inlet S-shaped diffuser length increases the powerto-weight ratio.It improves the techno-economic features of the GT by lesser fuel consumption.However,this Length reduction of a bare S-shaped diffuser to an aggressive S-shaped diffuser would risk flow separation and performance reduction of the diffuser and the air intake of the GT.The objective of this research is to propose and assess fitted energy promoters(EPs)to enhance the S-shaped diffuser performance by controlling and modifying the flow in the high bending zone of the diffuser.After experimental assessment,the work has been extended to cover more cases by numerical investigations on bare,bare aggressive,and aggressive with energy promoters S-shaped diffusers.Three types of EPs,namely co-rotating low-profile,co-rotating streamline sheet,and trapezoidal submerged EPs were tested with various combinations over a range of Reynolds numbers from 40,000 to 75,000.The respective S-shaped diffusers were simulated by computational fluid dynamics(CFD)using ANSYS software adopting a steady,3D,standard k-εturbulence model to acquire the details of the flow structure,which cannot be visualized in the experiment.The diffuser performance has been evaluated by the performance indicators of static pressure recovery coefficient,total pressure loss coefficient,and distortion coefficient(DC(45°)).The enhancements in the static pressure recovery of the S-shaped aggressive diffuser with energy promoters are 19.5%,22.2%,and 24.5%with EPs at planes 3,4 and 5,respectively,compared to the aggressive bare diffuser.In addition,the installation of the EPs resulted in a DC(45°)reduction at the outlet plane of the diffuser of about 43%at Re=40,000.The enhancements in the performance parameters confirm that aggravating the internal flow eliminates the flow separation and enhances the GT intake efficiency. 展开更多
关键词 Energy promoters distortion coefficient gas turbine S-shaped diffuser static pressure recovery total pressure loss
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Optimal Control for Vienna Rectifier in Unbalanced Conditions
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作者 LIU Chengzi HUANG Xiaoqi +1 位作者 MA Yaopeng BEN Guicin 《Transactions of Nanjing University of Aeronautics and Astronautics》 2025年第3期385-394,共10页
The Vienna rectifier is a widely adopted solution for high-power rectification due to its efficiency and straightforward design.However,its performance can degrade under unbalanced three phase voltage conditions,leadi... The Vienna rectifier is a widely adopted solution for high-power rectification due to its efficiency and straightforward design.However,its performance can degrade under unbalanced three phase voltage conditions,leading to current zero-crossing distortion and compromised dynamic response.This paper investigates the causes of these distortions,identifying a phase shift between the input current and the grid voltage as a primary factor,and proposes an effective distortion phase identification strategy.Furthermore,the dynamic performance is enhanced through improved current reference calculations and a refined power feedforward strategy.This approach optimizes the system's response to load changes and maintains output voltage stability under unbalanced conditions.Simulation results validate the effectiveness of the proposed methods in reducing current distortion and improving overall performance. 展开更多
关键词 zero-crossing distortion three-phase voltage unbalanced RECTIFIER power feedforward
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Crystal structure,sintering behavior,and microwave dielectric properties of LiF-tailored high entropy Li2 Mg_(6)ZnTi_(6)O_(20)ceramics
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作者 Qianbiao Du Linzhao Ma +3 位作者 Jianhong Duan Longxiang Jiang Hao Li Hanning Xiao 《Journal of Materials Science & Technology》 2025年第17期290-298,共9页
This study designs and synthesizes highly dense Li2 Mg_(6)ZnTi_(6)O_(20)microwave dielectric ceramics based on a high-entropy strategy,focusing on achieving stable structures,low sintering temperatures,and excellent c... This study designs and synthesizes highly dense Li2 Mg_(6)ZnTi_(6)O_(20)microwave dielectric ceramics based on a high-entropy strategy,focusing on achieving stable structures,low sintering temperatures,and excellent comprehensive performance.The ceramics exhibit a predominant face-centered cubic disordered phase(Fd-3 m)sintered at 1200-1280°C,alongside an increased presence of the second phase MgTiO3 at higher temperatures.Remarkably,these ceramics demonstrate excellent microwave dielectric properties(ε_(r)=16.69,Q×f=88,230 GHz,andτ_(f)=−36.5 ppm/°C).Additionally,we have explored the addition of x wt%LiF(1≤x≤5)to the Li2 Mg_(6)ZnTi_(6)O_(20)ceramics to enhance their applicability.The ceramics feature a spinel structure for LiF contents up to 3 wt%,while higher LiF concentrations induce the formation of a secondary phase,LiTiO2,characterized by a rock salt structure.Notably,the lattice distortion induced by LiF leads to a constant decrease in ε_(r).A moderate degree of lattice distortion serves to enhance the lattice stability of ceramics,which is reflected in increased lattice energy.Excellent microwave dielectric properties(ε_(r)=16.23,Q×f=89,728 GHz,τ_(f)=−43.5 ppm/°C)were obtained for x=3 ceramic sintered at 1140°C.Even at x=5,the ceramic retains excellent microwave dielectric properties(ε_(r)=16.02,Q×f=63,079 GHz,τ_(f)=−26 ppm/°C)at a low sintering temperature of 900°C.This work realizes the multiple effects of LiF and confirms good chemical compatibility with silver for LTCC(low-temperature co-fired ceramics)applications. 展开更多
关键词 Microwave dielectric ceramics High-entropy strategy Spinel structure Lattice distortion
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Proximity-engineered Ru single-atom sites modulate Fe-N_(4) spatial distortion for enhanced acidic oxygen reduction reaction
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作者 Shu-Hu Yin Xiao-Yang Cheng +6 位作者 Yu Han Ting Zhu Zhong-Wei Yu Rui Huang Jun Xu Yan-Xia Jiang Shi-Gang Sun 《Chinese Journal of Catalysis》 2025年第11期343-353,共11页
Fe-N-C catalysts are promising substitutes for precious-metal platinum in acidic oxygen reduction reactions(ORR),yet their moderate intrinsic activity and susceptibility to reactive oxygen species(ROS)-induced degrada... Fe-N-C catalysts are promising substitutes for precious-metal platinum in acidic oxygen reduction reactions(ORR),yet their moderate intrinsic activity and susceptibility to reactive oxygen species(ROS)-induced degradation hinder practical implementation.Herein,we fabricate a Ru-Fe dual-site catalyst(RuFe-N-C)through a two-step pyrolysis strategy.Structural characterization reveals atomic-scale proximity between Ru single atoms and Fe-N_(4) moieties,exhibiting a projected distance of~1.7Å.This configuration induces Fe–N bond elongation accompanied by 2.5%lattice distortion.The optimized RuFe-N-C catalyst exhibits high ORR performance,with a half-wave potential(E_(1/2))of 0.840 V and peak power density(P_(max))of 938 mW cm^(-2) under 150 kPa absolute H_(2)-O_(2).These metrics signify substantial enhancements relative to conventional Fe-N-C benchmarks(+21 mV in E_(1/2) and+42%in P_(max)).Moreover,the catalyst maintains outstanding stability,showing merely 17 mV E_(1/2) decay after 10000 accelerated durability test(ADT)cycles.Experimental analyses reveal a bifunctional mechanism:(1)Adjacent Ru sites substantially enhance the intrinsic ORR activity of Fe-N_(4) moieties,delivering a notable turnover frequency(TOF=17.86 e site^(-1) s^(-1) at 0.85 V vs.RHE)that exceeds state-of-the-art Fe-N-C benchmarks by 1-2 orders of magnitude(<1 e site^(-1) s^(-1));(2)Ru centers function as electron relays that facilitate ROS scavenging,thus suppressing degradation.This work establishes a paradigm for engineering bimetallic single-atom catalysts through synergistic electronic modulation to concurrently enhance activity and stability. 展开更多
关键词 Oxygen reduction reaction PGM-free catalyst Ru-Fe dual site Spatial distortion Fuel cells
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Comment on autonomous celestial navigation technology for spacecraft
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作者 Haonan YANG Xiaolin NING 《Chinese Journal of Aeronautics》 2025年第7期288-290,共3页
1. Introduction Celestial navigation is a kind of navigation with a long history.With the increasing demand for intelligent autonomy and antielectromagnetic interference in spacecraft, celestial navigation has become ... 1. Introduction Celestial navigation is a kind of navigation with a long history.With the increasing demand for intelligent autonomy and antielectromagnetic interference in spacecraft, celestial navigation has become one of the current research hotspots in spacecraft autonomous navigation. Spacecraft face complex electromagnetic interference in orbit. The time-varying, non-Gaussian interference from internal devices and external environment can lead to measurement distortion. 展开更多
关键词 celestial navigation spacecraft autonomous navigation autonomous navigation electromagnetic interference measurement distortion intelligent autonomy SPACECRAFT antielectromagnetic interference
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Mesopore carbon spheres anchored atomic Fe catalysis enables high performance oxygen reduction and ultralong-life rechargeable Znair batteries
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作者 Yifei Liu Zumin Wang +1 位作者 Lingbo Zong Lei Wang 《Nano Research》 2025年第11期493-503,共11页
Single atom catalysts(SACs)featuring Fe-N4 active sites anchored on carbon supports exhibit exceptional electrocatalytic performance in oxygen reduction reactions(ORR).Herein,a rigid ligand confined strategy was used ... Single atom catalysts(SACs)featuring Fe-N4 active sites anchored on carbon supports exhibit exceptional electrocatalytic performance in oxygen reduction reactions(ORR).Herein,a rigid ligand confined strategy was used to synthesize edge-anchored Fe-N4 active sites with geometric distortion on mesoporous-dominated carbon spheres(Fe-N-MESs).Furthermore,in situ Fourier transform infrared spectroscopy(FTIR)demonstrates that Fe-N-MESs weaken the O-O band,inhibiting the formation of H2O2.The density functional theory(DFT)calculations reveal that the exceptional ORR activity stems from optimized oxygen intermediate adsorption free energy and reduced OH*desorption energy barrier.Electrochemical measurements verify the remarkable ORR activity of Fe-N-MESs,demonstrating a half-wave potential of 0.90 V and excellent stability,with approximately 94%of the initial current density after 50 h of operation.When used as the air cathode in aqueous Zn-air batteries,Fe-N-MESs display a large open circuit voltage of 1.53 V and an extra-long stability of 1500 h.Moreover,Fe-N-MESs exhibit a remarkable open circuit voltage of 1.50 V and an impressive peak power density up to 260.4 mW·cm^(−2) in quasi-solid-state Zn-air batteries.This work provides valuable insights into the boosted ORR origin,while offering a novel and economical synthesis technique for SACs applicable to other electrocatalytic reactions. 展开更多
关键词 single atom catalysts high temperature shock geometric distortion oxygen reduction reaction Zn-air batteries
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Angular deviations and influential factors of Burgers orientation relationship duringβ→αphase transformation in titanium alloys
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作者 Ming-bing LI Kai WANG +6 位作者 Bin WANG Chao LV Xin-nan WANG Xing LI Zhi-shou ZHU Hui-long HOU Xin-qing ZHAO 《Transactions of Nonferrous Metals Society of China》 2025年第9期2903-2917,共15页
The angular deviations and influential factors of Burgers orientation relationship(BOR)in Ti-6Al-4V and Ti-6.5Al-2Zr-1Mo-1V alloys were investigated by optical microscope(OM),scanning electron microscope(SEM),electron... The angular deviations and influential factors of Burgers orientation relationship(BOR)in Ti-6Al-4V and Ti-6.5Al-2Zr-1Mo-1V alloys were investigated by optical microscope(OM),scanning electron microscope(SEM),electron backscattered diffraction(EBSD)and high-angle annular dark-field scanning transmission electron microscope(HAADF-STEM).A spherical center angle model was introduced to calculate the angular deviations from the ideal BOR between α and β phases.The results indicate thatαand β phases in α colonies of both alloys do not follow the perfect BOR during β→α phase transformation,with angular deviation values less than 3°.Through detailed microstructure characterization,the broad face of α/β interfaces viewed along two different electron incident directions shows the atomic-scale terrace-ledge structure,and many dislocations are observed within α and β phases and near α/β interfaces.Further studies reveal that the angular deviations mainly originate from lattice distortions caused by dislocations in α and β phases and lattice mismatches at α/β interfaces. 展开更多
关键词 titanium alloy Burgers orientation relationship angular deviation α/βinterface DISLOCATION lattice distortion
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Effect of impedance boundary-controlled casing treatment on performance of a fan subjected to inlet swirls
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作者 Yuqing WANG Dakun SUN +3 位作者 Jia LI Chunwang GENG Xu DONG Xiaofeng SUN 《Chinese Journal of Aeronautics》 2025年第2期1-14,共14页
An experimental investigation is conducted to evaluate the performance and the stalling process of a fan subjected to inlet swirls,as well as the effectiveness of an Impedance Boundary-Controlled(IBC)Casing Treatment(... An experimental investigation is conducted to evaluate the performance and the stalling process of a fan subjected to inlet swirls,as well as the effectiveness of an Impedance Boundary-Controlled(IBC)Casing Treatment(CT)on the stall margin recovery.An operating cycle is proposed based on the hysteresis effect of harmonic flap oscillation of airfoils and parallel compressor theory to explain the pressure characteristic of the fan under twin swirl inlets.Twin swirls are observed to reduce the stall margin of the fan,and the circumferential location where the spike is detected turns to the intersection area of the twin swirl.The IBC CT is proven to extend the stall margin of the fan for 12.7%–22.3%when subjected to inlet swirls with an efficiency loss of around 1%.The IBC CT helps to reduce the size of the operating cycle of the fan by redistributing the blade loading and adding the system damping to dissipate the perturbation energy. 展开更多
关键词 Axial fan/compressor Swirl inlet distortion Casing treatment Flow stability Unsteady flow
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