Cu-Ti alloys are a kind of elastic copper alloys with excellent comprehensive properties.They are often used in electronic and electrical fields.However,discontinuous precipitation may occur during the preparation pro...Cu-Ti alloys are a kind of elastic copper alloys with excellent comprehensive properties.They are often used in electronic and electrical fields.However,discontinuous precipitation may occur during the preparation process of Cu-Ti alloys,and they can lead to the significant deterioration of mechanical properties.To solve this problem,three Cu-Ti alloys with various Fe contents(Cu-2.7Ti,Cu-2.7Ti-0.1Fe and Cu-2.7Ti-0.2Fe)were designed and prepared in this paper to investigate the effects of Fe on the discontinuous precipitation.The results showed that after aging at any given aging time and temperature,the area fraction of cellular structure decreased with the increase of Fe content.The addition of Fe into Cu-Ti alloys resulted in Fe doping inβ'-Cu_(4)Ti phase andβ-Cu_(4)Ti phase.For 450℃/144 h-aged Cu-2.7Ti-0.2Fe alloy,the Fe content inβ'-Cu_(4)Ti phase andβ-Cu_(4)Ti phase was 1.59 at%and 0.90 at%,respectively.The tensile tests showed that under the same aging treatment conditions,Cu-2.7Ti-0.2Fe alloy possessed better mechanical properties.First-principles calculation confirmed that the thermodynamic stability ofβ'-Cu_(4)Ti phase was enhanced by decreasing its cohesive energy through Fe doping.At the same time,the enthalpy of formation ofβ-Cu_(4)Ti phase was generally increased by Fe doping,making it difficult to generate.In short,Fe addition in Cu-Ti alloys suppressed discontinuous precipitation by Fe doping in the precipitates and helped to improve mechanical properties.展开更多
Mechanism of discontinuous precipitation(DP) in AZ80 alloy was investigated by phase-orientation correlated characterization.The results show DPs nucleate by turning the original grain boundaries(GBs) as reaction fron...Mechanism of discontinuous precipitation(DP) in AZ80 alloy was investigated by phase-orientation correlated characterization.The results show DPs nucleate by turning the original grain boundaries(GBs) as reaction front(RF),and further driving the RF to realize their growth.The DPs regions retained the same orientations as their parent grains.The misorientation angle and rotation axis of RFs had strong influence on DPs nucleation.The low-angle GBs,twin boundaries(TBs) and the GBs with specific misorientation axis which are known as low energy and low mobility GBs can hardly initiate DPs.In addition,the TBs had a strong ability to inhibit the growth of DPs,but it should be noticed that the growth of DPs cannot be totally inhibited by TBs.DPs can engulf the twins when the growth direction is approximately parallel to the long axis of TBs.The inhibition behavior is related to the distribution of Al solute atoms near the RF,boundary interactions of the TBs and twin tips with the RF,and the morphology of the continuous precipitations within the twins.展开更多
Simultaneously achieving high strength and high electrical conductivity in Cu–Ni–Si alloys pose a significant challenge, which greatly constrains its applications in the electronics industry. This paper offers a new...Simultaneously achieving high strength and high electrical conductivity in Cu–Ni–Si alloys pose a significant challenge, which greatly constrains its applications in the electronics industry. This paper offers a new pathway to improve properties, by preparation of nanometer lamellar discontinuous precipitates(DPs) arranged with the approximate same direction through a combination of deformationaging and cold rolling process. The strengthening effect is primarily attributed to nanometer-lamellar DPs strengthening and dislocation strengthening mechanism. The accumulation of dislocations at the interface between nanometer lamellar DPs and matrix during cold deformation process can results in the decrease of dislocation density inside the matrix grains, leading to the acceptably slight reduction of electrical conductivity during cold rolling. The alloy exhibits an electrical conductivity of 45.32%IACS(international annealed copper standard, IACS), a tensile strength of 882.67 MPa, and a yield strength of 811.33 MPa by this method. This study can provide a guidance for the composition and microstructure design of a Cu–Ni–Si alloy in the future, by controlling the morphology and distribution of DPs.展开更多
This work presents the modified precipitation behavior of the β phase in a Mg-8.0Al-0.5Zn-0.2Mn-0.4Ce alloy(wt%,designated as AZ80+0.4%Ce),which has been subjected to room-temperature pre-compression and a subsequent...This work presents the modified precipitation behavior of the β phase in a Mg-8.0Al-0.5Zn-0.2Mn-0.4Ce alloy(wt%,designated as AZ80+0.4%Ce),which has been subjected to room-temperature pre-compression and a subsequent dual-stage aging treatment,thereby imparting it with the pronounced basal texture.It was found that the synergistic application of pre-compression and dual-stage aging protocol markedly accelerates the age-hardening response and architecture of the continuous precipitates(CPs)in the present AZ80+0.4%Ce alloy.Consequently,this alloy achieves an exceptional balance between strength and ductility,boasting a yield strength of approximately 229.0 MPa alongside an elongation of around 7.0%.A series of microstructural characterizations reveal that high-density intragranular dislocations introduced by pre-compression serve as catalysts for the preferential formation of CPs over the discontinuous precipitates,effectively suppressing the latter.Notably,this also facilitates static recrystallization,which refines the grain structure and alleviates the residual stresses induced by deformation,further enhancing the mechanical properties.This research contributes a novel perspective to the thermomechanical processing design of precipitation-hardened lightweight alloys,offering a pathway to optimize their performance through tailored thermomechanical strategies.展开更多
Through microstructure observation and X-ray diffraction analysis, the equilibrium phase constituents of Al-Zn alloy that contains 2 at. pct Cu at room temperature have been determined as Al-based solid solution (α),...Through microstructure observation and X-ray diffraction analysis, the equilibrium phase constituents of Al-Zn alloy that contains 2 at. pct Cu at room temperature have been determined as Al-based solid solution (α), Zn-based solid solution and AI4Cu3Zn phase (T'-phase), which are different from a phase, Zn phase and CuZn4 phase originally believed. It is determined that the products of discontinuous precipitation transformation below 277℃ are not the equilibrium phase constituents, but the metastable phases made up of a phase, Zn phase and CuZn4 phase. The phase constituents after discontinuous precipitation of AIZn-2Cu alloy would transform to the ones in equilibrium status: Al-based solid solution (α) in fcc structure, Zn-based solid solution in hcp structure and AI4Cu3Zn phase (T'-phase) ultimately through plastic deformation at room temperature and re-heating treatment below 277℃.展开更多
Recrystallization of cold-rolled discontinuous, precipitation microstructurewhich has fine laminar structure in an Al-40 percent Zn (atom fraction) binary alloy is investigatedby optical microscopy, SEM and TEM. It is...Recrystallization of cold-rolled discontinuous, precipitation microstructurewhich has fine laminar structure in an Al-40 percent Zn (atom fraction) binary alloy is investigatedby optical microscopy, SEM and TEM. It is found that there are two kinds of recrystallizationmechanisms: continuous coarsening (CC) and discontinuous coarsening (DC). The latter can be dividedinto coarsening mainly driven by stored deformation energy at colony boundaries and slip bands andthe one mainly driven by boundary energy in the area with little deformation. It is shown that theaddition of Cu can retard the nucleation of coarsening cells and their growth. X-Ray diffractionanalysis indicated the metastable phase CuZn_4 transformed into equilibrium phase A;_4Cu_3Zn duringthe heating process.展开更多
The effect of Cu additions on discontinuous precipitation of AlZn alloy were studied with optical microscopy, scanning electron microscopy and X-ray diffraction. It is found that the effect of addition of 2 at. pct Cu...The effect of Cu additions on discontinuous precipitation of AlZn alloy were studied with optical microscopy, scanning electron microscopy and X-ray diffraction. It is found that the effect of addition of 2 at. pct Cu on cellular nucleation site is not remarkable, while the effect of aging temperature on cellular nucleation site of AlZn and AIZn-2Cu alloys is fairly obvious. The cell growth rate of discontinuous precipitation of AlZn alloy is remarkably accelerated with the addition of 2 at. pct Cu. The discontinuous precipitation microstructure of AlZn alloy is not apparently affected with the addition of 2 at. pct Cu and the cellular front is still fine microstructure of spinodal decomposition. The phase constituents consist of a fcc Al-rich phase, a hcp Zn-rich phase and a CuZn4 phase. The transformation rate of discontinuous precipitation of AlZn alloy is remarkably accelerated with the addition of 2 at. pct Cu.展开更多
The study of the discontinuous precipitation reaction and the lamellar precipitate dissolution in the alloy Cu-In system provoked a considerable benefit and has been the subject of many theoretical and experimental in...The study of the discontinuous precipitation reaction and the lamellar precipitate dissolution in the alloy Cu-In system provoked a considerable benefit and has been the subject of many theoretical and experimental investigations. The aim of this work is to make the evidence on the one hand the effect of the plastic deformation on the mechanism of the discontinuous precipitation reaction such as nucleation, growth and lamellar coarsening and in other hand the effect of temperature on the characteristics and front behavior movement of the opposite reaction (discontinuous dissolution). Different techniques of analysis have been used in this respect such as the optical microscopy, the differential thermal analysis and the microhardness Vickers. The obtained results confirm various works achieved in this field.展开更多
The discontinuous precipitation and dissolution in the alloy Al-Zn system has been the subject of many theoretical and experimental investigations that have contributed to the understanding of the different mechanisms...The discontinuous precipitation and dissolution in the alloy Al-Zn system has been the subject of many theoretical and experimental investigations that have contributed to the understanding of the different mechanisms which control them. However, many questions remain unanswered because of the complexity of the constituted phases which are affected by the speed of the quenched, deformation, the temperature of homogenization and ageing effect. The purpose of this work is to clarify the effect of temperature and deformation on the mechanisms of these two reactions during ageing of Al-15 at.% Zn and Al-30 at.% Zn alloy. The techniques of analysis used in this respect are the optical microscopy, the X-ray diffraction and the hardness Vickers.展开更多
Combining analytical transmission electron microscopy systematic tilting, scanning transmission electron microscopy mapping and nano-beam electron diffraction operations, we obtain direct experimental proofs on the bo...Combining analytical transmission electron microscopy systematic tilting, scanning transmission electron microscopy mapping and nano-beam electron diffraction operations, we obtain direct experimental proofs on the boundary type, elemental distribution and structure of the cellular reerystallization reaction front for a single- crystal superalloy. It is demonstrated that the cellular recrystallization reaction front usually corresponds to coincidence site lattice boundaries, and a thin layer of γ-forming elements such as Re, Cr, Mo and Co invariably exists in the direct reaction front. Furthermore, the thin layer with γ-forming elements is proved to be γ phase, with the same orientation as the neighboring original matrix.展开更多
The effect of adding Cr and Mg on the microstructure and properties of Cu−Ti alloys was examined.Cu−Ti−Cr−Mg alloys were fabricated using vacuum induction melting.The microstructure and phase composition of Cu−Ti−Cr−M...The effect of adding Cr and Mg on the microstructure and properties of Cu−Ti alloys was examined.Cu−Ti−Cr−Mg alloys were fabricated using vacuum induction melting.The microstructure and phase composition of Cu−Ti−Cr−Mg alloys in different aging states were characterized.Additionally,the hardness and electrical conductivity of the materials were investigated.Results show that the precipitation pattern in Cu−Ti−Cr−Mg alloys resembled that of binary Cu−Ti alloys,with Cr and Ti forming the intermetallic compound of Cr_(2)Ti during casting.The introduction of Cr and Mg increased the hardness of the alloy.Increasing the Mg content in the Cu−Ti−Cr−Mg alloy led to grain refinement and fast nucleation of continuous precipitates during the early aging stage.Moreover,the addition of Mg impeded discontinuous precipitate growth by segregating along the precipitate surfaces.Consequently,the Cu−4Ti−0.5Cr−1Mg alloy exhibited limited discontinuous precipitates at the grain boundaries and a gradual decline in hardness during the over-aging period.展开更多
The limited creep resistance of wrought Mg-Al alloys restricts their lightweight applications at intermediate temperatures due to the softening effect of discontinuous precipitation(DP)on the dislocation-controlled cr...The limited creep resistance of wrought Mg-Al alloys restricts their lightweight applications at intermediate temperatures due to the softening effect of discontinuous precipitation(DP)on the dislocation-controlled creep.Here,we developed a creep-resistant wrought Mg-Al alloy through microalloying of Y and Ca.The resulting alloy exhibited an order of magnitude enhancement in the creep resistance at 125℃/50±100 MPa.In contrast to the grain boundary instabilities by DP in the previously reported wrought Mg-Al alloys,we show that the addition of 0.21Y+0.15Ca wt%produces a(Zn+Ca)co-segregation at the grain boundaries as a result of their segregation energy and the activation energy of grain boundary migration,thereby stabilizing the grain boundaries.The(Zn+Ca)co-segregation inhibits the dynamic DP and promotes the formation of intragranular Al-enriched clusters,which favorthe formation of Al_(2)Y,Mg_(17)Al_(12)nano precipitates,thereby impeding intragranular dislocation motion during creep.Furthermore,the addition of 0.21Y+0.15Ca wt%facilitates the formation of a fine and uniform recrystallization structure in the microalloyed alloys compared to AZ80 due to the high activation energy of mobility for the(Zn+Ca)segregated grain boundary.Therefore,the microalloyed alloys exhibit good tensile properties with 380 MPa tensile strength and 18%elongation.Our constitutive analysis revealed that the(Y+Ca)microalloying decreased the creep stress exponent by 29%and increased the creep resistance in the medium to high-stress range.Microalloying provides a promising way to develop low-cost creep-resistant wrought Mg-Al alloys.展开更多
The evolution of precipitates and mechanical properties of AZ80A magnesium alloy with aging time was studied by in situ observation with SEM,TEM and tensile testing.The results show that the continuous precipitation(C...The evolution of precipitates and mechanical properties of AZ80A magnesium alloy with aging time was studied by in situ observation with SEM,TEM and tensile testing.The results show that the continuous precipitation(CP)phases near the reaction front(RF)are replaced by the discontinuous precipitation(DP)phases at the early aging stage.In DP regions,the elliptical phases coarsen obviously with the increase of aging time,which results in a slightly slow reduction of the intracrystalline hardness of DP regions.In CP regions,some small plate phases reprecipitate simultaneously with the growth of the initial precipitates,which contributes to a slight increase in the intracrystalline hardness in CP regions at the later aging stage.The aging hardening of DP regions is faster and stronger than that of CP regions.However,the age strengthening of CP regions not only compensates for the overaging softening of DP regions but also improves the strength of the alloy.展开更多
In this study,we carried out a comparative study of two different numerical strategies for the modeling of the biogeochemical processes in microbially induced calcite precipitation(MICP)process.A simplified MICP model...In this study,we carried out a comparative study of two different numerical strategies for the modeling of the biogeochemical processes in microbially induced calcite precipitation(MICP)process.A simplified MICP model was used,which is based on the mass transport theory.Two numerical strategies,namely the operator splitting(OS)and the global implicit(GI)strategies,were adopted to solve the coupled reactive mass transport problems.These two strategies were compared in the aspects of numerical accuracy,convergence property and computational efficiency by solving the presented MICP model.To look more into the details of the model,sensitivity analysis of some important modeling parameters was also carried out in this paper.展开更多
The morphology and growth kinetics of the discontinuous precipitate in a deformed and undeformed Ni-7.5at.%In alloy have been investigated at temperatures ranging from 667?K to?1030?K using light and scanning microsco...The morphology and growth kinetics of the discontinuous precipitate in a deformed and undeformed Ni-7.5at.%In alloy have been investigated at temperatures ranging from 667?K to?1030?K using light and scanning microscopy. Also, the dependence of the growth rate on some diffusion parameters was experimentally and theoretically studied. The investigation is observed that at all aging temperatures the alloy was observed to decompose completely by discontinuous precipitation into a fine lamellar structure of nickel-rich solid solution and?β?(Ni3In) precipitate phase. The precipitation rate depends strongly on the degree of deformation, this dependence being identical for each of the aging temperatures under investigation. Analysis of the growth rates, lamellar spacing and phase compositions for the discontinuous precipitation reaction showed that they were controlled by grain boundary diffusion. Moreover, a generally applicable procedure for calculating the driving force is presented. The driving forces, calculated in this way, should be more reliable than those calculated with the approximations based on Peterman and Hornbogen laws.展开更多
The discontinuous precipitation kinetics and mechanism of the α (Ag-rich) phase in Cu-7 wt% Ag alloy has been investigated using dilatometric and calorimetric anisothermal analysis, optical microscopy, scanning and t...The discontinuous precipitation kinetics and mechanism of the α (Ag-rich) phase in Cu-7 wt% Ag alloy has been investigated using dilatometric and calorimetric anisothermal analysis, optical microscopy, scanning and transmission electron microscopy and X-ray diffraction. Dilatometric and calorimetric curves present at ~ 500°C an important effect related to the ? (Ag-rich) phase formation and consequently the matrix β (Cu-rich) depletion. The nucleation and growth of the precipitated phase show cells formation at initial grain boundaries;a fine lamellar structure is detected by SEM and TEM and consists of alternate lamellar of the α (Ag-rich) and β (Cu-rich)-solid solutions. Cellular precipitation leads to the simultaneous appearance of two diffraction peaks and occurs apparently according to the Fournelle and Clark’s mechanism. Obtained results give an Avrami exponent n = 2.0 ± 0.2 in agreement with an interfacial controlled process having an activation energy Ea equals to 99 ± 7 kJ/mol obtained from anisothermal analysis by using different isoconversion methods. This activation energy expresses the discrepancy between isoconversion methods and the analytical diffusive model. Moreover, the supersaturation rate has an effect on the lamella spacing of the precipitated cells.展开更多
An evaluation of Radar Precipitation Feature (RPF) characteristics and distribution of convective intensity is performed across 12 regions in West Africa. Results presented in this study have shown that these characte...An evaluation of Radar Precipitation Feature (RPF) characteristics and distribution of convective intensity is performed across 12 regions in West Africa. Results presented in this study have shown that these characteristics over West Africa revealed interesting results which were not observed on a larger spatial scale. The ice scattering characteristics and heights attained by the 15, 20, 30, and 40 dBZ echoes show patterns that agree with the season and movement of the Inter-Tropical Discontinuity (ITD). Some locations in the Western-coast rainforest, Nigeria/Cameroon rainforest and South Sudan savannah had strong potential for convective intensity during MAM, JJA, and SON as shown by their 37-GHz and 85-GHz PCT which fell below 250 K and 225 K respectively while the maximum height attained by their 20 dBZ, 30 dBZ and 40 dBZ are well above the freezing level in those locations. One result revealed a location on the eastern part of south-central Sahel (SC Sahel) where the maximum height attained by the 30 dBZ reflectivity is above 12 km and the maximum height attained by the 40 dBZ reflectivity is above 10 km during SON. The 37-GHz and 85-GHz PCT for this particular location are below 215 K and 150 K respectively indicating a very strong potential for intense convection and hence destructive storms. The distribution of convective intensity, considering only the 85-GHz PCT ice scattering signature, revealed that the percentage of convective intensity increases, especially in the rainforest and savannah, as the ITD shifts northwards during MAM, JJA and during its retreat in SON.展开更多
The volume fractions and morphology of precipitates in precipitation-strengthened Cu-Ti alloys,which precipitate mainly as continuous and discontinuous precipitates,are important for the application of the alloy.This ...The volume fractions and morphology of precipitates in precipitation-strengthened Cu-Ti alloys,which precipitate mainly as continuous and discontinuous precipitates,are important for the application of the alloy.This study employed hardness and electrical conductivity tests transmission electron microscopy(TEM),atom probe tomography(APT),and first-principles calculations to demonstrate that the addition of Mg is effective for accelerating nanosized continuousβ'-Cu_(4)Ti precipitation as well as for suppressing the precipitation of coarse lamellar discontinuousβ-Cu_(4)Ti precipitates along the grain boundaries,resulting in Cu-Ti alloys with high yield strength and good electrical conductivity.The results showed that the continuous precipitation ofβ'-Cu_(4)Ti was accelerated by the Mg additions,which reduced the supersaturation of the matrix,thereby reducing the chemical driving force for the discontinuous precipitates.On the other hand,Mg additions increased the mismatch between the discontinuousβ-Cu_(4)Ti precipitates and matrix decreased the nucleation rate of the discontinuous precipitates,and increased the spacing of the discontinuous precipitation layer,resulting in a lower growth rate of the discontinuous precipitates.Therefore,the addition of Mg to Cu-Ti alloys enhances the strength and improves the resistance to over-ageing.展开更多
基金supported by the National Natural Science Foundation of China(No.U2202255)Hunan Provincial Natural Science Foundation of China(No.2024JJ2076)the Key Technology Research Program of Ningbo(No.2023Z092).
文摘Cu-Ti alloys are a kind of elastic copper alloys with excellent comprehensive properties.They are often used in electronic and electrical fields.However,discontinuous precipitation may occur during the preparation process of Cu-Ti alloys,and they can lead to the significant deterioration of mechanical properties.To solve this problem,three Cu-Ti alloys with various Fe contents(Cu-2.7Ti,Cu-2.7Ti-0.1Fe and Cu-2.7Ti-0.2Fe)were designed and prepared in this paper to investigate the effects of Fe on the discontinuous precipitation.The results showed that after aging at any given aging time and temperature,the area fraction of cellular structure decreased with the increase of Fe content.The addition of Fe into Cu-Ti alloys resulted in Fe doping inβ'-Cu_(4)Ti phase andβ-Cu_(4)Ti phase.For 450℃/144 h-aged Cu-2.7Ti-0.2Fe alloy,the Fe content inβ'-Cu_(4)Ti phase andβ-Cu_(4)Ti phase was 1.59 at%and 0.90 at%,respectively.The tensile tests showed that under the same aging treatment conditions,Cu-2.7Ti-0.2Fe alloy possessed better mechanical properties.First-principles calculation confirmed that the thermodynamic stability ofβ'-Cu_(4)Ti phase was enhanced by decreasing its cohesive energy through Fe doping.At the same time,the enthalpy of formation ofβ-Cu_(4)Ti phase was generally increased by Fe doping,making it difficult to generate.In short,Fe addition in Cu-Ti alloys suppressed discontinuous precipitation by Fe doping in the precipitates and helped to improve mechanical properties.
基金supported by National Natural Science Foundation of China (52201107)Research Program of Chongqing Municipal Education Commission (KJQN202201151)Natural Science Foundation of Chongqing (CSTB2023NSCQ-MSX0067).
文摘Mechanism of discontinuous precipitation(DP) in AZ80 alloy was investigated by phase-orientation correlated characterization.The results show DPs nucleate by turning the original grain boundaries(GBs) as reaction front(RF),and further driving the RF to realize their growth.The DPs regions retained the same orientations as their parent grains.The misorientation angle and rotation axis of RFs had strong influence on DPs nucleation.The low-angle GBs,twin boundaries(TBs) and the GBs with specific misorientation axis which are known as low energy and low mobility GBs can hardly initiate DPs.In addition,the TBs had a strong ability to inhibit the growth of DPs,but it should be noticed that the growth of DPs cannot be totally inhibited by TBs.DPs can engulf the twins when the growth direction is approximately parallel to the long axis of TBs.The inhibition behavior is related to the distribution of Al solute atoms near the RF,boundary interactions of the TBs and twin tips with the RF,and the morphology of the continuous precipitations within the twins.
基金supported by the National Key Research and Development Program of China (No. 2023YFB3812601)the National Natural Science Founda tion of China (Nos. 51925401, 92066205, and 92266301)。
文摘Simultaneously achieving high strength and high electrical conductivity in Cu–Ni–Si alloys pose a significant challenge, which greatly constrains its applications in the electronics industry. This paper offers a new pathway to improve properties, by preparation of nanometer lamellar discontinuous precipitates(DPs) arranged with the approximate same direction through a combination of deformationaging and cold rolling process. The strengthening effect is primarily attributed to nanometer-lamellar DPs strengthening and dislocation strengthening mechanism. The accumulation of dislocations at the interface between nanometer lamellar DPs and matrix during cold deformation process can results in the decrease of dislocation density inside the matrix grains, leading to the acceptably slight reduction of electrical conductivity during cold rolling. The alloy exhibits an electrical conductivity of 45.32%IACS(international annealed copper standard, IACS), a tensile strength of 882.67 MPa, and a yield strength of 811.33 MPa by this method. This study can provide a guidance for the composition and microstructure design of a Cu–Ni–Si alloy in the future, by controlling the morphology and distribution of DPs.
基金supported by the Innovative Talents Support Program of Higher Education Institutions in Shanxi Province and the North University of China Project of Science and Technology in 2022(20221878).
文摘This work presents the modified precipitation behavior of the β phase in a Mg-8.0Al-0.5Zn-0.2Mn-0.4Ce alloy(wt%,designated as AZ80+0.4%Ce),which has been subjected to room-temperature pre-compression and a subsequent dual-stage aging treatment,thereby imparting it with the pronounced basal texture.It was found that the synergistic application of pre-compression and dual-stage aging protocol markedly accelerates the age-hardening response and architecture of the continuous precipitates(CPs)in the present AZ80+0.4%Ce alloy.Consequently,this alloy achieves an exceptional balance between strength and ductility,boasting a yield strength of approximately 229.0 MPa alongside an elongation of around 7.0%.A series of microstructural characterizations reveal that high-density intragranular dislocations introduced by pre-compression serve as catalysts for the preferential formation of CPs over the discontinuous precipitates,effectively suppressing the latter.Notably,this also facilitates static recrystallization,which refines the grain structure and alleviates the residual stresses induced by deformation,further enhancing the mechanical properties.This research contributes a novel perspective to the thermomechanical processing design of precipitation-hardened lightweight alloys,offering a pathway to optimize their performance through tailored thermomechanical strategies.
文摘Through microstructure observation and X-ray diffraction analysis, the equilibrium phase constituents of Al-Zn alloy that contains 2 at. pct Cu at room temperature have been determined as Al-based solid solution (α), Zn-based solid solution and AI4Cu3Zn phase (T'-phase), which are different from a phase, Zn phase and CuZn4 phase originally believed. It is determined that the products of discontinuous precipitation transformation below 277℃ are not the equilibrium phase constituents, but the metastable phases made up of a phase, Zn phase and CuZn4 phase. The phase constituents after discontinuous precipitation of AIZn-2Cu alloy would transform to the ones in equilibrium status: Al-based solid solution (α) in fcc structure, Zn-based solid solution in hcp structure and AI4Cu3Zn phase (T'-phase) ultimately through plastic deformation at room temperature and re-heating treatment below 277℃.
文摘Recrystallization of cold-rolled discontinuous, precipitation microstructurewhich has fine laminar structure in an Al-40 percent Zn (atom fraction) binary alloy is investigatedby optical microscopy, SEM and TEM. It is found that there are two kinds of recrystallizationmechanisms: continuous coarsening (CC) and discontinuous coarsening (DC). The latter can be dividedinto coarsening mainly driven by stored deformation energy at colony boundaries and slip bands andthe one mainly driven by boundary energy in the area with little deformation. It is shown that theaddition of Cu can retard the nucleation of coarsening cells and their growth. X-Ray diffractionanalysis indicated the metastable phase CuZn_4 transformed into equilibrium phase A;_4Cu_3Zn duringthe heating process.
基金This work was financially supported by the National Natural Science Foundation of China under No.59971015.We are grateful to Prof.H.Ding for discussion and proof in English.
文摘The effect of Cu additions on discontinuous precipitation of AlZn alloy were studied with optical microscopy, scanning electron microscopy and X-ray diffraction. It is found that the effect of addition of 2 at. pct Cu on cellular nucleation site is not remarkable, while the effect of aging temperature on cellular nucleation site of AlZn and AIZn-2Cu alloys is fairly obvious. The cell growth rate of discontinuous precipitation of AlZn alloy is remarkably accelerated with the addition of 2 at. pct Cu. The discontinuous precipitation microstructure of AlZn alloy is not apparently affected with the addition of 2 at. pct Cu and the cellular front is still fine microstructure of spinodal decomposition. The phase constituents consist of a fcc Al-rich phase, a hcp Zn-rich phase and a CuZn4 phase. The transformation rate of discontinuous precipitation of AlZn alloy is remarkably accelerated with the addition of 2 at. pct Cu.
文摘The study of the discontinuous precipitation reaction and the lamellar precipitate dissolution in the alloy Cu-In system provoked a considerable benefit and has been the subject of many theoretical and experimental investigations. The aim of this work is to make the evidence on the one hand the effect of the plastic deformation on the mechanism of the discontinuous precipitation reaction such as nucleation, growth and lamellar coarsening and in other hand the effect of temperature on the characteristics and front behavior movement of the opposite reaction (discontinuous dissolution). Different techniques of analysis have been used in this respect such as the optical microscopy, the differential thermal analysis and the microhardness Vickers. The obtained results confirm various works achieved in this field.
文摘The discontinuous precipitation and dissolution in the alloy Al-Zn system has been the subject of many theoretical and experimental investigations that have contributed to the understanding of the different mechanisms which control them. However, many questions remain unanswered because of the complexity of the constituted phases which are affected by the speed of the quenched, deformation, the temperature of homogenization and ageing effect. The purpose of this work is to clarify the effect of temperature and deformation on the mechanisms of these two reactions during ageing of Al-15 at.% Zn and Al-30 at.% Zn alloy. The techniques of analysis used in this respect are the optical microscopy, the X-ray diffraction and the hardness Vickers.
基金Supported by the Scientific Research Foundation of Xi’an University of Technology under Grant No 101-451115007the National Natural Science Foundation of China under Grant No 51174161the Pivot Innovation Team of Shaanxi Electric Materials and Infiltration Technique under Grant No 2012KCT-25
文摘Combining analytical transmission electron microscopy systematic tilting, scanning transmission electron microscopy mapping and nano-beam electron diffraction operations, we obtain direct experimental proofs on the boundary type, elemental distribution and structure of the cellular reerystallization reaction front for a single- crystal superalloy. It is demonstrated that the cellular recrystallization reaction front usually corresponds to coincidence site lattice boundaries, and a thin layer of γ-forming elements such as Re, Cr, Mo and Co invariably exists in the direct reaction front. Furthermore, the thin layer with γ-forming elements is proved to be γ phase, with the same orientation as the neighboring original matrix.
基金supported by the National Natural Science Foundation of China(No.52201226)Fundamental Research Program of Shanxi Province,China(No.202103021223036)+1 种基金the Key Scientific Research Project in Shanxi Province,China(No.202102050201007)the special fund for Science and Technology Innovation Teams of Shanxi Province,China(No.202204051001004)。
文摘The effect of adding Cr and Mg on the microstructure and properties of Cu−Ti alloys was examined.Cu−Ti−Cr−Mg alloys were fabricated using vacuum induction melting.The microstructure and phase composition of Cu−Ti−Cr−Mg alloys in different aging states were characterized.Additionally,the hardness and electrical conductivity of the materials were investigated.Results show that the precipitation pattern in Cu−Ti−Cr−Mg alloys resembled that of binary Cu−Ti alloys,with Cr and Ti forming the intermetallic compound of Cr_(2)Ti during casting.The introduction of Cr and Mg increased the hardness of the alloy.Increasing the Mg content in the Cu−Ti−Cr−Mg alloy led to grain refinement and fast nucleation of continuous precipitates during the early aging stage.Moreover,the addition of Mg impeded discontinuous precipitate growth by segregating along the precipitate surfaces.Consequently,the Cu−4Ti−0.5Cr−1Mg alloy exhibited limited discontinuous precipitates at the grain boundaries and a gradual decline in hardness during the over-aging period.
基金financial support from the National Natural Science Foundation of China(No:52061040,No:52371121,No:52031011)China Postdoctoral Science Foundation(No:2021M692512)the 2020 open projects(No:KLATM202003)of Key Laboratory of Advanced Technologies of Materials,Ministry of Education China,Southwest Jiaotong University。
文摘The limited creep resistance of wrought Mg-Al alloys restricts their lightweight applications at intermediate temperatures due to the softening effect of discontinuous precipitation(DP)on the dislocation-controlled creep.Here,we developed a creep-resistant wrought Mg-Al alloy through microalloying of Y and Ca.The resulting alloy exhibited an order of magnitude enhancement in the creep resistance at 125℃/50±100 MPa.In contrast to the grain boundary instabilities by DP in the previously reported wrought Mg-Al alloys,we show that the addition of 0.21Y+0.15Ca wt%produces a(Zn+Ca)co-segregation at the grain boundaries as a result of their segregation energy and the activation energy of grain boundary migration,thereby stabilizing the grain boundaries.The(Zn+Ca)co-segregation inhibits the dynamic DP and promotes the formation of intragranular Al-enriched clusters,which favorthe formation of Al_(2)Y,Mg_(17)Al_(12)nano precipitates,thereby impeding intragranular dislocation motion during creep.Furthermore,the addition of 0.21Y+0.15Ca wt%facilitates the formation of a fine and uniform recrystallization structure in the microalloyed alloys compared to AZ80 due to the high activation energy of mobility for the(Zn+Ca)segregated grain boundary.Therefore,the microalloyed alloys exhibit good tensile properties with 380 MPa tensile strength and 18%elongation.Our constitutive analysis revealed that the(Y+Ca)microalloying decreased the creep stress exponent by 29%and increased the creep resistance in the medium to high-stress range.Microalloying provides a promising way to develop low-cost creep-resistant wrought Mg-Al alloys.
基金financially supported by the Natural Science Foundation of Hunan Province, China (No. 2018JJ2503)the Postgraduate Independent Exploration and Innovation Project of Central South University, China (No. 1053320171111)
文摘The evolution of precipitates and mechanical properties of AZ80A magnesium alloy with aging time was studied by in situ observation with SEM,TEM and tensile testing.The results show that the continuous precipitation(CP)phases near the reaction front(RF)are replaced by the discontinuous precipitation(DP)phases at the early aging stage.In DP regions,the elliptical phases coarsen obviously with the increase of aging time,which results in a slightly slow reduction of the intracrystalline hardness of DP regions.In CP regions,some small plate phases reprecipitate simultaneously with the growth of the initial precipitates,which contributes to a slight increase in the intracrystalline hardness in CP regions at the later aging stage.The aging hardening of DP regions is faster and stronger than that of CP regions.However,the age strengthening of CP regions not only compensates for the overaging softening of DP regions but also improves the strength of the alloy.
基金financial support from the German Research Foundation(DFG)(Grant No.NA 330/20-1)the DFG under grant No.FE 1962/1-1(426819984)for financial supportthe Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences(Grant No.Z019002)。
文摘In this study,we carried out a comparative study of two different numerical strategies for the modeling of the biogeochemical processes in microbially induced calcite precipitation(MICP)process.A simplified MICP model was used,which is based on the mass transport theory.Two numerical strategies,namely the operator splitting(OS)and the global implicit(GI)strategies,were adopted to solve the coupled reactive mass transport problems.These two strategies were compared in the aspects of numerical accuracy,convergence property and computational efficiency by solving the presented MICP model.To look more into the details of the model,sensitivity analysis of some important modeling parameters was also carried out in this paper.
文摘The morphology and growth kinetics of the discontinuous precipitate in a deformed and undeformed Ni-7.5at.%In alloy have been investigated at temperatures ranging from 667?K to?1030?K using light and scanning microscopy. Also, the dependence of the growth rate on some diffusion parameters was experimentally and theoretically studied. The investigation is observed that at all aging temperatures the alloy was observed to decompose completely by discontinuous precipitation into a fine lamellar structure of nickel-rich solid solution and?β?(Ni3In) precipitate phase. The precipitation rate depends strongly on the degree of deformation, this dependence being identical for each of the aging temperatures under investigation. Analysis of the growth rates, lamellar spacing and phase compositions for the discontinuous precipitation reaction showed that they were controlled by grain boundary diffusion. Moreover, a generally applicable procedure for calculating the driving force is presented. The driving forces, calculated in this way, should be more reliable than those calculated with the approximations based on Peterman and Hornbogen laws.
文摘The discontinuous precipitation kinetics and mechanism of the α (Ag-rich) phase in Cu-7 wt% Ag alloy has been investigated using dilatometric and calorimetric anisothermal analysis, optical microscopy, scanning and transmission electron microscopy and X-ray diffraction. Dilatometric and calorimetric curves present at ~ 500°C an important effect related to the ? (Ag-rich) phase formation and consequently the matrix β (Cu-rich) depletion. The nucleation and growth of the precipitated phase show cells formation at initial grain boundaries;a fine lamellar structure is detected by SEM and TEM and consists of alternate lamellar of the α (Ag-rich) and β (Cu-rich)-solid solutions. Cellular precipitation leads to the simultaneous appearance of two diffraction peaks and occurs apparently according to the Fournelle and Clark’s mechanism. Obtained results give an Avrami exponent n = 2.0 ± 0.2 in agreement with an interfacial controlled process having an activation energy Ea equals to 99 ± 7 kJ/mol obtained from anisothermal analysis by using different isoconversion methods. This activation energy expresses the discrepancy between isoconversion methods and the analytical diffusive model. Moreover, the supersaturation rate has an effect on the lamella spacing of the precipitated cells.
文摘An evaluation of Radar Precipitation Feature (RPF) characteristics and distribution of convective intensity is performed across 12 regions in West Africa. Results presented in this study have shown that these characteristics over West Africa revealed interesting results which were not observed on a larger spatial scale. The ice scattering characteristics and heights attained by the 15, 20, 30, and 40 dBZ echoes show patterns that agree with the season and movement of the Inter-Tropical Discontinuity (ITD). Some locations in the Western-coast rainforest, Nigeria/Cameroon rainforest and South Sudan savannah had strong potential for convective intensity during MAM, JJA, and SON as shown by their 37-GHz and 85-GHz PCT which fell below 250 K and 225 K respectively while the maximum height attained by their 20 dBZ, 30 dBZ and 40 dBZ are well above the freezing level in those locations. One result revealed a location on the eastern part of south-central Sahel (SC Sahel) where the maximum height attained by the 30 dBZ reflectivity is above 12 km and the maximum height attained by the 40 dBZ reflectivity is above 10 km during SON. The 37-GHz and 85-GHz PCT for this particular location are below 215 K and 150 K respectively indicating a very strong potential for intense convection and hence destructive storms. The distribution of convective intensity, considering only the 85-GHz PCT ice scattering signature, revealed that the percentage of convective intensity increases, especially in the rainforest and savannah, as the ITD shifts northwards during MAM, JJA and during its retreat in SON.
基金financially supported by the Technological Innovation 2025&Major Special Project of Ningbo(Nos.2021Z084 and 2020Z039)。
文摘The volume fractions and morphology of precipitates in precipitation-strengthened Cu-Ti alloys,which precipitate mainly as continuous and discontinuous precipitates,are important for the application of the alloy.This study employed hardness and electrical conductivity tests transmission electron microscopy(TEM),atom probe tomography(APT),and first-principles calculations to demonstrate that the addition of Mg is effective for accelerating nanosized continuousβ'-Cu_(4)Ti precipitation as well as for suppressing the precipitation of coarse lamellar discontinuousβ-Cu_(4)Ti precipitates along the grain boundaries,resulting in Cu-Ti alloys with high yield strength and good electrical conductivity.The results showed that the continuous precipitation ofβ'-Cu_(4)Ti was accelerated by the Mg additions,which reduced the supersaturation of the matrix,thereby reducing the chemical driving force for the discontinuous precipitates.On the other hand,Mg additions increased the mismatch between the discontinuousβ-Cu_(4)Ti precipitates and matrix decreased the nucleation rate of the discontinuous precipitates,and increased the spacing of the discontinuous precipitation layer,resulting in a lower growth rate of the discontinuous precipitates.Therefore,the addition of Mg to Cu-Ti alloys enhances the strength and improves the resistance to over-ageing.
