The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor ...The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.展开更多
Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usu...Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usually involves complex procedures and extremely depends on unidirectional freezing technique.Herein,we propose a groundbreaking approach that leverages the assemblies of salting-out protein induced by ammonium metatungstate(AM)as the precursor,and then acquire directional three-dimensional carbon-based foams through simple pyrolysis.The electrostatic interaction between AM and protein ensures well dispersion of WC_(1−x)nanoparticles on carbon frameworks.The content of WC_(1−x)nanoparticles can be rationally regulated by AM dosage,and it also affects the electromagnetic(EM)properties of final carbon-based foams.The optimized foam exhibits exceptional EM absorption performance,achieving a remarkable minimum reflection loss of−72.0 dB and an effective absorption bandwidth of 6.3 GHz when EM wave propagates parallel to the directional pores.Such performance benefits from the synergistic effects of macroporous architecture and compositional design.Although there is a directional dependence of EM absorption,radar stealth simulation demonstrates that these foams can still promise considerable reduction in radar cross section with the change of incident angle.Moreover,COMSOL simulation further identifies their good performance in preventing EM interference among different electronic components.展开更多
For a multi-frequency non-reciprocal optical device,we first realize multi-frequency optical non-reciprocal transmission using a non-Hermitian multi-mode resonator array.Practically,multi-frequency operation can add c...For a multi-frequency non-reciprocal optical device,we first realize multi-frequency optical non-reciprocal transmission using a non-Hermitian multi-mode resonator array.Practically,multi-frequency operation can add channels to the non-reciprocal optical device and the non-reciprocity can route optical signals and prevent the reverse flow of noise.Using the Scully–Lamb model and gain saturation effect,we accomplish dual-frequency non-reciprocal transmission by introducing nonlinearity into a linear array of four-mode resonators.The accomplishment is directly demonstrated by the non-reciprocal transmission phenomena present in the non-divergent peaks.For example,a directional cyclic amplifier is constructed with non-reciprocal units.Regarding potential applications,non-reciprocal optical systems can be employed in dual-frequency control,parallel information processing,photonic integrated circuits,optical devices and so on.展开更多
In 2025,I had the honor of delivering keynote speeches at the conferences of the International Society for Diet and Activity Methods in Toronto,Canada,and the International Society of Behavioural Nutrition and Physica...In 2025,I had the honor of delivering keynote speeches at the conferences of the International Society for Diet and Activity Methods in Toronto,Canada,and the International Society of Behavioural Nutrition and Physical Activity in Auckland,Aotearoa,New Zealand.These opportunities prompted deep reflection on scientific research in general,and on physical activity and health research specifically.展开更多
Aiming at mitigating the high risks associated with conventional explosive blasting,this study developed a safe directional fracturing technique,i.e.instantaneous expansion with a single fracture(IESF),using a coal-ba...Aiming at mitigating the high risks associated with conventional explosive blasting,this study developed a safe directional fracturing technique,i.e.instantaneous expansion with a single fracture(IESF),using a coal-based solid waste expanding agent.First,the mechanism of directional fracturing blasting by the IESF was analyzed,and the criterion of directional crack initiation was established.On this basis,laboratory experiments and numerical simulations were conducted to systematically evaluate the directional fracturing blasting performance of the IESF.The results indicate that the IESF presents an excellent directional fracturing effect,with average surface undulation differences ranging from 8.1 mm to 22.7 mm on the fracture surfaces.Moreover,during concrete fracturing tests,the stresses and strains in the fracturing direction are measured to be 2.16-3.71 times and 8 times larger than those in the nonfracturing direction,respectively.Finally,the IESF technique was implemented for no-pillar mining with gob-side entry retaining through roof cutting and pressure relief in an underground coal mine.The IESF technique effectively created directional cracks in the roof without causing severe roadway deformation,achieving an average cutting rate and maximum roadway deformation of 94%and 197 mm,respectively.These on-site test results verified its excellent directional rock fracturing performance.The IESF technique,which is safe,efficient,and green,has considerable application prospects in the field of rock mechanics and engineering.展开更多
To investigate the effects of the maximum principal stress direction(θ)and cross-section shape on the failure characteristics of sandstone,true-triaxial compression experiments were conducted using cubic samples with...To investigate the effects of the maximum principal stress direction(θ)and cross-section shape on the failure characteristics of sandstone,true-triaxial compression experiments were conducted using cubic samples with rectangular,circular,and D-shaped holes.Asθincreases from 0°to 60°in the rectangular hole,the left failure location shifts from the left corner to the left sidewall,the left corner,and then the floor,while the right failure location shifts from the right corner to the right sidewall,right roof corner,and then the roof.Furthermore,the initial failure vertical stress first decreases and then increases.In comparison,the failure severity in the rectangular hole decreases for variousθvalues as 30°>45°>60°>0°.With increasingθ,the fractal dimension(D)of rock slices first increases and then decreases.For the rectangular and D-shaped holes,whenθ=0°,30°,and 90°,D for the rectangular hole is less than that of the D-shaped hole.Whenθ=45°and 60°,D for the rectangular hole is greater than that of the D-shaped hole.Theoretical analysis indicates that the stress concentration at the rectangular and D-shaped corners is greater than the other areas.The failure location rotates with the rotation ofθ,and the failure occurs on the side with a high concentration of compressive stress,while the side with the tensile and compressive stresses remains relatively stable.Therefore,the fundamental reason for the rotation of failure location is the rotation of stress concentration,and the external influencing factor is the rotation ofθ.展开更多
Accuracy allocation is crucial in the accuracy design of machining tools.Current accuracy allocation methods primarily focus on positional deviation,with little consideration for tool direction deviation.To address th...Accuracy allocation is crucial in the accuracy design of machining tools.Current accuracy allocation methods primarily focus on positional deviation,with little consideration for tool direction deviation.To address this issue,we propose a geometric error cost sensitivity-based accuracy allocation method for five-axis machine tools.A geometric error model consisting of 4l error components is constructed based on homogeneous transformation matrices.Volumetric points with positional and tool direction deviations are randomly sampled to evaluate the accuracy of the machine tool.The sensitivity of each error component at these sampling points is analyzed using the Sobol method.To balance the needs of geometric precision and manufacturing cost,a geometric error cost sensitivity function is developed to estimate the required cost.By allocating error components affecting tool direction deviation first and the remaining components second,this allocation scheme ensures that both deviations meet the requirements.We also perform numerical simulation of a BC-type(B-axis and C-axis type)five-axis machine tool to validate the method.The results show that the new allocation scheme reduces the total geometric error cost by 27.8%compared to a uniform allocation scheme,and yields the same positional and tool direction machining accuracies.展开更多
Currently,there are a limited number of dynamic models available for braided composite plates with large overall motions,despite the incorporation of three-dimensional(3D)braided composites into rotating blade compone...Currently,there are a limited number of dynamic models available for braided composite plates with large overall motions,despite the incorporation of three-dimensional(3D)braided composites into rotating blade components.In this paper,a dynamic model of 3D 4-directional braided composite thin plates considering braiding directions is established.Based on Kirchhoff's plate assumptions,the displacement variables of the plate are expressed.By incorporating the braiding directions into the constitutive equation of the braided composites,the dynamic model of the plate considering braiding directions is obtained.The effects of the speeds,braiding directions,and braided angles on the responses of the plate with fixed-axis rotation and translational motion,respectively,are investigated.This paper presents a dynamic theory for calculating the deformation of 3D braided composite structures undergoing both translational and rotational motions.It also provides a simulation method for investigating the dynamic behavior of non-isotropic material plates in various applications.展开更多
Columnar grains offer considerable advantages in terms of microstructure for resisting high-temperature low-cycle fatigue. In additive manufacturing, the formation of fine columnar grains is common. However, post-heat...Columnar grains offer considerable advantages in terms of microstructure for resisting high-temperature low-cycle fatigue. In additive manufacturing, the formation of fine columnar grains is common. However, post-heat treatment often transforms these grains into equiaxed grains. This study aimed to tailor the grain morphology by controlling the precipitation of carbides. By balancing the restraining effects of carbide pinning and grain growth, we achieved carbide-assisted in situ-directional recrystallization. This process preserved the columnar grains created via laser powder bed fusion, even after high-temperature heat treatment. The approach emphasizes promoting the longitudinal growth of columnar grains while preventing their broadening. Additionally, we characterized the evolution of carbides and γ′ precipitates and examined their role in nucleation and growth during recrystallization. This study supports the viability of carbide-assisted in situ-directional recrystallization in additive manufacturing alloys, introducing an innovative strategy for microstructure customization. The implementation of carbon stabilization (CS) treatment to control the carbide distribution led to a 40 % improvement in the creep life at 900 ℃ and 150 MPa.展开更多
Developing high-strength and ductile metallic parts with designable shapes is an unfading research topic for material science and engineering.As a revolutionary technology,additive manufacturing(AM)pro-vides a new pat...Developing high-strength and ductile metallic parts with designable shapes is an unfading research topic for material science and engineering.As a revolutionary technology,additive manufacturing(AM)pro-vides a new pathway for producing complex-shaped metallic parts with the possibility of in situ tailoring their microstructure.However,AM is not always ideally applicable for all metals and alloys.Eutectic high entropy alloys(EHEAs)contain both the advantages of the eutectic alloys and high entropy alloys(HEAs),and EHEAs show significant potential in AM due to their excellent mechanical properties and good fluid-ity.Herein,heterogeneous and ultra-fine eutectic lamellar microstructure with directional growth along the deposition direction(DD)was obtained by adjusting the process parameters of AM to improve the strength and ductility of EHEAs.Compared with the as-cast sample,the simultaneous increment in both strength and ductility is achieved by AM.Combination of strength and ductility of the AM sample ten-sile along the DD direction(yield strength σ_(y)=1115 MPa,ultimate tensile strength σ_(UTS)=1417 MPa,ultimate tensile strain ε_(U)=23%)in this work was superior to most of the additive manufactured al-loys and comparable to the thermomechanical-treated EHEAs with the best mechanical properties.The high strength and good ductility of the AM were mainly attributed to the ultra-fine lamellar nature and fully constrained soft and hard lamellar microstructure,which produces an obvious hetero-deformation induced(HDI)strengthening and high crack buffering effect during the deformation.This work provides a new possibility to achieve high strength and ductile complex-shaped metallic parts via designing direc-tional lamellar eutectic structures by AM.展开更多
To enhance the recuperation rate of the mine and comply with the stipulations of green mining technology, it is vital to expeditiously recuperate the coal pillar resources in the final stage, thus preventing the consi...To enhance the recuperation rate of the mine and comply with the stipulations of green mining technology, it is vital to expeditiously recuperate the coal pillar resources in the final stage, thus preventing the considerable squandering of resources. The coal pillar resource of the main roadway and its branch roadway constitutes a significant recovery subject. Its coal pillar shape is regular and possesses a considerable strike distance, facilitating the arrangement of the coal pillar recovery working face (CPRWF) for mining operations. However, for the remaining coal pillars with a thick and hard roof (THF) and multiple tectonic zones, CPRWF encounters challenges in selecting an appropriate layout, managing excessive roof pressure, and predicting mining stress. Aiming at the roadway coal pillar group with THF and multi-structural areas in specific projects, a method of constructing multi-stage CPRWF by one side gob-side entry driving (GSED) and one side roadway reusing is proposed. Through theoretical calculation of roof fracture and numerical simulation verification, combined with field engineering experience and economic analysis, the width of the narrow coal pillar (NCP) in the GSED is determined to be 10 m and the length of the CPRWF is 65 m. Concurrently, the potential safety hazard that the roof will fall asymmetrically and THF is difficult to break during CPRWF mining after GSED is analyzed and verified. Then, a control method involving the pre-cutting of the roof in the reused roadway before mining is proposed. This method has been shown to facilitate the complete collapse of THF, reduce the degree of mine pressure, and facilitate the symmetrical breaking of the roof. Accordingly, a roof-cutting scheme based on a directional drilling rig, bidirectional shaped polyvinyl chloride (PVC) pipe, and emulsion explosive was devised, and the pre-splitting of 8.2 m THF was accomplished. Field observations indicate that directional cracks are evident in the roof, the coal wall is flat during CPRWF mining, and the overall level of mining pressure is within the control range. Therefore, the combined application of GSED and roof-cutting technology for coal pillar recovery has been successfully implemented, thereby providing new insights and engineering references for the construction and pressure relief mining of CPRWF.展开更多
Aiming at the problem that infrared small target detection faces low contrast between the background and the target and insufficient noise suppression ability under the complex cloud background,an infrared small targe...Aiming at the problem that infrared small target detection faces low contrast between the background and the target and insufficient noise suppression ability under the complex cloud background,an infrared small target detection method based on the tensor nuclear norm and direction residual weighting was proposed.Based on converting the infrared image into an infrared patch tensor model,from the perspective of the low-rank nature of the background tensor,and taking advantage of the difference in contrast between the background and the target in different directions,we designed a double-neighborhood local contrast based on direction residual weighting method(DNLCDRW)combined with the partial sum of tensor nuclear norm(PSTNN)to achieve effective background suppression and recovery of infrared small targets.Experiments show that the algorithm is effective in suppressing the background and improving the detection ability of the target.展开更多
Professor Paul Crosthwaite,from the School of Literature,Languages,and Cultures at the University of Edinburgh,is a prominent scholar in the interdisciplinary field of literature and economics.He is a co-editor of the...Professor Paul Crosthwaite,from the School of Literature,Languages,and Cultures at the University of Edinburgh,is a prominent scholar in the interdisciplinary field of literature and economics.He is a co-editor of the Palgrave Studies in Literature,Culture,and Economics series and The Cambridge Companion to Literature and Economics(2022).In recent years,he has significantly influenced the intersection of literature and economics,advocating particularly for a shift towards the Economic Humanities.This interview covers:1.The definition and theoretical origin of the Economic Humanities;2.The internal heterogeneity and critical limitations of the New Economic Criticism,and the theoretical advantages and potential development of the Economic Humanities;3.What research paradigms do Environmental Humanities,Medical Humanities,and Digital Humanities provide for the Economic Humanities;4.How literary researchers can work at the interface of the Economic Humanities research.As a novel interdisciplinary interface between literature and economics,Professor Paul Crosthwaite’s concept of the Economic Humanities not only pioneers methodological tools for interdisciplinary studies of literature and economics but also underscores the interpretative potential and disciplinary benefits of literary viewpoints on economics.This underscores the vital role of literature in human knowledge,meriting attention from the literary research academia.展开更多
In this paper, the problem of pre-specified performance fault-tolerant cluster consensus control and fault direction identification is solved for the human-in-the-loop(HIL) swarm unmanned aerial vehicles(UAVs) in the ...In this paper, the problem of pre-specified performance fault-tolerant cluster consensus control and fault direction identification is solved for the human-in-the-loop(HIL) swarm unmanned aerial vehicles(UAVs) in the presence of possible nonidentical and unknown direction faults(NUDFs) in the yaw channel.The control strategy begins with the design of a pre-specified performance event-triggered observer for each individual UAV.These observers estimate the outputs of the human controlled UAVs, and simultaneously achieve the distributed design of actual control signals as well as cluster consensus of the observer output.It is worth mentioning that these observers require neither the high-order derivatives of the human controlled UAVs' output nor a priori knowledge of the initial conditions. The fault-tolerant controller realizes the pre-specified performance output regulation through error transformation and the Nussbaum function. It should be pointed out that there are no chattering caused by the jump of the Nussbaum function when a reverse fault occurs. In addition, to provide a basis for further solving the problem of physical malfunctions, a fault direction identification algorithm is proposed to accurately identify whether a reverse fault has occurred. Simulation results verify the effectiveness of the proposed control and fault direction identification strategies when the reverse faults occur.展开更多
Background Agility and change of direction speed(COD)are essential skills in sports,their development being the focus of training and research.While these terms have been used interchangeably,it is crucial to distingu...Background Agility and change of direction speed(COD)are essential skills in sports,their development being the focus of training and research.While these terms have been used interchangeably,it is crucial to distinguish between agility and COD,as the latter involves a sudden change in direction without the presence of external stimuli.Objective This meta-analysis aims to summarize studies that have included COD and agility tests and explore the potential relationship between these two physical qualities.Method Following the PRISMA guidelines,a meta-analysis was conducted using studies published between 2005 and 2021.All studies identified for inclusion were peer-reviewed and published in English and Spanish,using an athlete population as participants.For all analyses,a significance level was set at P<0.05.Results The meta-analysis,which included 21 studies with 945 participants from various team sports,found a moderate correlation(r=0.46)between agility and COD.This study considers moderator variables such as Age,Sex,Sport,Test Pattern,Test Combination,and Agility Stimulus.Conclusion The results of this study revealed that while COD and agility have commonalities,these two constructs represent distinct different qualities.Younger participants show a stronger correlation between the two,emphasizing age-related differences in physical development.Coaches should consider these findings in designing training programs and assessments,tailoring approaches based on the specific demands of each skill.The study contributes valuable insights into the nuanced relationship between agility and COD in team sports.展开更多
According to the measurement principle of the traditional interferometer,a narrowband signal model is established and used,however,for wideband signals or multiple signals,this model is invalid.For the problems of dir...According to the measurement principle of the traditional interferometer,a narrowband signal model is established and used,however,for wideband signals or multiple signals,this model is invalid.For the problems of direction finding with interferometer for wideband signals and multiple signals scene,a frequency domain phase interferometer is proposed and the concrete implementation scheme is given.The proposed method computes the phase difference in frequency domain,and finds multi-target results with judging the spectrum amplitude changing,and uses the frequency phase difference to compute the arrival angle.Theoretical analysis and simulation results show that the proposed method effectively solves the problem of the angle estimation with phase interferometer for wideband signals,and has good performance in multiple signals scene with nonoverlapping spectrum or partially overlapping.In addition,the wider the signal bandwidth,the better direction finding performance of this algorithm.展开更多
Lacustrine rift basins in China are characterized by pronounced structural segmentation,strong sedimentary heterogeneity,extensive fault-fracture development,and significant variability in thermal maturity and mobilit...Lacustrine rift basins in China are characterized by pronounced structural segmentation,strong sedimentary heterogeneity,extensive fault-fracture development,and significant variability in thermal maturity and mobility of shale oil.This study reviews the current status of exploration and development of shale oil in such basins and examines theoretical frameworks such as“binary enrichment”and source-reservoir configuration,with a focus on five key subjects:(1)sedimentation-diagenesis coupling mechanisms of fine-grained shale reservoir formation;(2)dynamic diagenetic evolution and hydrocarbon occurrence mechanisms of organic-rich shale;(3)dominant controls and evaluation methods for shale oil enrichment;(4)fracturing mechanisms of organic-rich shale and simulation of artificial fracture networks;and(5)flow mechanisms and effective development strategies for shale oil.Integrated analysis suggests that two major scientific challenges must be addressed:the coupled evolution of fine-grained sedimentation,differential diagenesis,and hydrocarbon generation under tectonic influence and its control on shale oil occurrence and enrichment;and multi-scale,multiphase flow mechanisms and three-dimensional development strategies for lacustrine shale oil in complex fault blocks.In response to current exploration and development bottlenecks,future research will be conducted primarily to:(1)deeply understand organic-inorganic interactions and reservoir formation mechanisms in organic-rich shales,and clarify the influence of high-frequency sequence evolution and diagenetic fluids on reservoir space;(2)elucidate the dynamic processes of hydrocarbon generation,expulsion,and retention across different lithofacies,and quantify their relationship with thermal maturity,including the conditions for the formation of self-sealing systems;(3)develop a geologically adaptive,data-and intelligence-driven shale oil classification and grading evaluation system of shale oil;(4)reveal artificial fracture propagation pattern and optimize physical field coupled fracturing technologies for complex lithofacies assemblages;and(5)overcome challenges in multi-scale geological modeling and multiphase flow characterization,and establish advanced numerical simulation methodologies.展开更多
The effect of seismic directionality is crucial for curved bridges,a subject generally overlooked in seismic vulnerability analysis.This paper focuses on seismic fragility development as a function of seismic incidenc...The effect of seismic directionality is crucial for curved bridges,a subject generally overlooked in seismic vulnerability analysis.This paper focuses on seismic fragility development as a function of seismic incidence directions for a geometrically curved bridge.A series of non-linear time history analyses were carried out for a representative finite element model of the bridge by considering actual ground motions.For reliable seismic demand models,a total of eleven intensity measures(IM)were analyzed based on optimality metrics.To quantify the sensitivity of fragility functions to input incidence directions,fragility surfaces were developed throughout the horizontal plane by considering spectral acceleration at one second(Sa_(1.0))as the optimal IM.Results show that the optimal IM ranking is insignificantly influenced by seismic directionality.However,seismic orientation influences fragility,which intensifies in higher damage states,particularly for piers.For a bridge system,the differences in median demand corresponding to the least and most vulnerable direction for slight,moderate,extensive,and collapse states are about 9.0%,7.31%,10.32%,and 11.60%,respectively.These results imply that while evaluating the vulnerability of curved bridges,the optimality of IM in demand estimation and the impact of seismic directionality should not be disregarded.展开更多
Suffusion is the process defined as the migration of relatively small soil particles through the pores of a soil matrix composed of relatively large particles,driven by substantial hydrodynamic forces and weak attract...Suffusion is the process defined as the migration of relatively small soil particles through the pores of a soil matrix composed of relatively large particles,driven by substantial hydrodynamic forces and weak attraction energies.This study investigates the influence of flow direction(upward and downward)on suffusion induced by interaction energies in sand-clay mixtures under both saturated and unsaturated conditions.The impact of clay mineralogy(kaolinite,illite,and montmorillonite),sand-grain size,and ionic concentration(IC)gradient were discussed based on the observed breakthrough curves(BTCs)and relative saturation rate(Sr)during injection(particularly for unsaturated conditions).Under saturated conditions,higher susceptibility to suffusion was observed in sand-kaolinite and sand-illite mixtures under downward flow compared to upward flow,whereas the suffusion of montmorillonite was more significant under upward flow than under downward flow.In contrast,for unsaturated conditions,more substantial suffusion of kaolinite and illite particles occurred under upward flow compared to downward flow,whereas the opposite trend was observed in sand-montmorillonite mixtures.In addition,the impact of sand-grain size(or the size ratio between sand and clay)on the suffusion of kaolinite and illite under unsaturated conditions suggests a reduced size ratio that leads to relatively significant suffusion under downward flow compared to upward flow.The findings presented in this study contribute to a comprehensive understanding of the influence of flow direction on suffusion in sand-clay mixtures under both saturated and unsaturated conditions.展开更多
In May 2025,Australia held a federal election in which the Labor Party won with an overwhelming majority and the Liberal-National Party coalition(the Coalition)suffered a historic defeat.Around the election period,Aus...In May 2025,Australia held a federal election in which the Labor Party won with an overwhelming majority and the Liberal-National Party coalition(the Coalition)suffered a historic defeat.Around the election period,Australia faced profound changes in both domestic and international circumstances.展开更多
文摘The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.
基金financially supported by the National Natural Science Foundation of China(Nos.22475057 and No.52373262).
文摘Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usually involves complex procedures and extremely depends on unidirectional freezing technique.Herein,we propose a groundbreaking approach that leverages the assemblies of salting-out protein induced by ammonium metatungstate(AM)as the precursor,and then acquire directional three-dimensional carbon-based foams through simple pyrolysis.The electrostatic interaction between AM and protein ensures well dispersion of WC_(1−x)nanoparticles on carbon frameworks.The content of WC_(1−x)nanoparticles can be rationally regulated by AM dosage,and it also affects the electromagnetic(EM)properties of final carbon-based foams.The optimized foam exhibits exceptional EM absorption performance,achieving a remarkable minimum reflection loss of−72.0 dB and an effective absorption bandwidth of 6.3 GHz when EM wave propagates parallel to the directional pores.Such performance benefits from the synergistic effects of macroporous architecture and compositional design.Although there is a directional dependence of EM absorption,radar stealth simulation demonstrates that these foams can still promise considerable reduction in radar cross section with the change of incident angle.Moreover,COMSOL simulation further identifies their good performance in preventing EM interference among different electronic components.
基金supported by the National Nature Science Foundation of China(Grant Nos.12475019 and 12073056)the Major National Science and Technology Project of China(Grant No.BX2024B054)+1 种基金National Lab of Solid State Microstructure of Nanjing University(Grant Nos.M35040,M35053,and M37014)the Natural Science Foundation of Shandong Province(Grant No.ZR2024MA038)。
文摘For a multi-frequency non-reciprocal optical device,we first realize multi-frequency optical non-reciprocal transmission using a non-Hermitian multi-mode resonator array.Practically,multi-frequency operation can add channels to the non-reciprocal optical device and the non-reciprocity can route optical signals and prevent the reverse flow of noise.Using the Scully–Lamb model and gain saturation effect,we accomplish dual-frequency non-reciprocal transmission by introducing nonlinearity into a linear array of four-mode resonators.The accomplishment is directly demonstrated by the non-reciprocal transmission phenomena present in the non-divergent peaks.For example,a directional cyclic amplifier is constructed with non-reciprocal units.Regarding potential applications,non-reciprocal optical systems can be employed in dual-frequency control,parallel information processing,photonic integrated circuits,optical devices and so on.
文摘In 2025,I had the honor of delivering keynote speeches at the conferences of the International Society for Diet and Activity Methods in Toronto,Canada,and the International Society of Behavioural Nutrition and Physical Activity in Auckland,Aotearoa,New Zealand.These opportunities prompted deep reflection on scientific research in general,and on physical activity and health research specifically.
基金supported by the National Natural Science Foundation of China(Grant No.52404155)State Key Laboratory of Mining Disaster Prevention and Control(Shandong University of Science and Technology)+1 种基金Ministry of Education(Grant No.JMDPC202402)supported by the opening project of State Key Laboratory of Explosion Science and Safety Protection(Beijing Institute of Technology).The opening project number is KFJJ24-20M.
文摘Aiming at mitigating the high risks associated with conventional explosive blasting,this study developed a safe directional fracturing technique,i.e.instantaneous expansion with a single fracture(IESF),using a coal-based solid waste expanding agent.First,the mechanism of directional fracturing blasting by the IESF was analyzed,and the criterion of directional crack initiation was established.On this basis,laboratory experiments and numerical simulations were conducted to systematically evaluate the directional fracturing blasting performance of the IESF.The results indicate that the IESF presents an excellent directional fracturing effect,with average surface undulation differences ranging from 8.1 mm to 22.7 mm on the fracture surfaces.Moreover,during concrete fracturing tests,the stresses and strains in the fracturing direction are measured to be 2.16-3.71 times and 8 times larger than those in the nonfracturing direction,respectively.Finally,the IESF technique was implemented for no-pillar mining with gob-side entry retaining through roof cutting and pressure relief in an underground coal mine.The IESF technique effectively created directional cracks in the roof without causing severe roadway deformation,achieving an average cutting rate and maximum roadway deformation of 94%and 197 mm,respectively.These on-site test results verified its excellent directional rock fracturing performance.The IESF technique,which is safe,efficient,and green,has considerable application prospects in the field of rock mechanics and engineering.
基金supported by the National Natural Science Foundation of China (Grant Nos.52304227 and 52104133)Scientific and Technological Research Platform for Disaster Prevention and Control of Deep Coal Mining (Anhui University of Science and Technology) (Grant No.DPDCM2208).
文摘To investigate the effects of the maximum principal stress direction(θ)and cross-section shape on the failure characteristics of sandstone,true-triaxial compression experiments were conducted using cubic samples with rectangular,circular,and D-shaped holes.Asθincreases from 0°to 60°in the rectangular hole,the left failure location shifts from the left corner to the left sidewall,the left corner,and then the floor,while the right failure location shifts from the right corner to the right sidewall,right roof corner,and then the roof.Furthermore,the initial failure vertical stress first decreases and then increases.In comparison,the failure severity in the rectangular hole decreases for variousθvalues as 30°>45°>60°>0°.With increasingθ,the fractal dimension(D)of rock slices first increases and then decreases.For the rectangular and D-shaped holes,whenθ=0°,30°,and 90°,D for the rectangular hole is less than that of the D-shaped hole.Whenθ=45°and 60°,D for the rectangular hole is greater than that of the D-shaped hole.Theoretical analysis indicates that the stress concentration at the rectangular and D-shaped corners is greater than the other areas.The failure location rotates with the rotation ofθ,and the failure occurs on the side with a high concentration of compressive stress,while the side with the tensile and compressive stresses remains relatively stable.Therefore,the fundamental reason for the rotation of failure location is the rotation of stress concentration,and the external influencing factor is the rotation ofθ.
基金supported by the Key R&D Program of Zhejiang Province(Nos.2023C01166 and 2024SJCZX0046)the Zhejiang Provincial Natural Science Foundation of China(Nos.LDT23E05013E05 and LD24E050009)the Natural Science Foundation of Ningbo(No.2021J150),China.
文摘Accuracy allocation is crucial in the accuracy design of machining tools.Current accuracy allocation methods primarily focus on positional deviation,with little consideration for tool direction deviation.To address this issue,we propose a geometric error cost sensitivity-based accuracy allocation method for five-axis machine tools.A geometric error model consisting of 4l error components is constructed based on homogeneous transformation matrices.Volumetric points with positional and tool direction deviations are randomly sampled to evaluate the accuracy of the machine tool.The sensitivity of each error component at these sampling points is analyzed using the Sobol method.To balance the needs of geometric precision and manufacturing cost,a geometric error cost sensitivity function is developed to estimate the required cost.By allocating error components affecting tool direction deviation first and the remaining components second,this allocation scheme ensures that both deviations meet the requirements.We also perform numerical simulation of a BC-type(B-axis and C-axis type)five-axis machine tool to validate the method.The results show that the new allocation scheme reduces the total geometric error cost by 27.8%compared to a uniform allocation scheme,and yields the same positional and tool direction machining accuracies.
基金Project supported by the National Natural Science Foundation of China(Nos.12372071 and 12372070)the Aeronautical Science Fund of China(No.2022Z055052001)the Foundation of China Scholarship Council(No.202306830079)。
文摘Currently,there are a limited number of dynamic models available for braided composite plates with large overall motions,despite the incorporation of three-dimensional(3D)braided composites into rotating blade components.In this paper,a dynamic model of 3D 4-directional braided composite thin plates considering braiding directions is established.Based on Kirchhoff's plate assumptions,the displacement variables of the plate are expressed.By incorporating the braiding directions into the constitutive equation of the braided composites,the dynamic model of the plate considering braiding directions is obtained.The effects of the speeds,braiding directions,and braided angles on the responses of the plate with fixed-axis rotation and translational motion,respectively,are investigated.This paper presents a dynamic theory for calculating the deformation of 3D braided composite structures undergoing both translational and rotational motions.It also provides a simulation method for investigating the dynamic behavior of non-isotropic material plates in various applications.
基金supported by the National Key Research and Development Program of China(Grant No.2019YFA0705300)the National Natural Science Foundation of China(Grant No.51974057)the Fundamental Research Funds for the Central Universities。
文摘Columnar grains offer considerable advantages in terms of microstructure for resisting high-temperature low-cycle fatigue. In additive manufacturing, the formation of fine columnar grains is common. However, post-heat treatment often transforms these grains into equiaxed grains. This study aimed to tailor the grain morphology by controlling the precipitation of carbides. By balancing the restraining effects of carbide pinning and grain growth, we achieved carbide-assisted in situ-directional recrystallization. This process preserved the columnar grains created via laser powder bed fusion, even after high-temperature heat treatment. The approach emphasizes promoting the longitudinal growth of columnar grains while preventing their broadening. Additionally, we characterized the evolution of carbides and γ′ precipitates and examined their role in nucleation and growth during recrystallization. This study supports the viability of carbide-assisted in situ-directional recrystallization in additive manufacturing alloys, introducing an innovative strategy for microstructure customization. The implementation of carbon stabilization (CS) treatment to control the carbide distribution led to a 40 % improvement in the creep life at 900 ℃ and 150 MPa.
基金supported by the National Key Re-search and Development Program of China(No.2024YFC2816500)the National Natural Science Foundation of China(Nos.U2341261 and 52471121)the Fundamental Research Funds for the Cen-tral Universities(No.DUT24RC(3)107).
文摘Developing high-strength and ductile metallic parts with designable shapes is an unfading research topic for material science and engineering.As a revolutionary technology,additive manufacturing(AM)pro-vides a new pathway for producing complex-shaped metallic parts with the possibility of in situ tailoring their microstructure.However,AM is not always ideally applicable for all metals and alloys.Eutectic high entropy alloys(EHEAs)contain both the advantages of the eutectic alloys and high entropy alloys(HEAs),and EHEAs show significant potential in AM due to their excellent mechanical properties and good fluid-ity.Herein,heterogeneous and ultra-fine eutectic lamellar microstructure with directional growth along the deposition direction(DD)was obtained by adjusting the process parameters of AM to improve the strength and ductility of EHEAs.Compared with the as-cast sample,the simultaneous increment in both strength and ductility is achieved by AM.Combination of strength and ductility of the AM sample ten-sile along the DD direction(yield strength σ_(y)=1115 MPa,ultimate tensile strength σ_(UTS)=1417 MPa,ultimate tensile strain ε_(U)=23%)in this work was superior to most of the additive manufactured al-loys and comparable to the thermomechanical-treated EHEAs with the best mechanical properties.The high strength and good ductility of the AM were mainly attributed to the ultra-fine lamellar nature and fully constrained soft and hard lamellar microstructure,which produces an obvious hetero-deformation induced(HDI)strengthening and high crack buffering effect during the deformation.This work provides a new possibility to achieve high strength and ductile complex-shaped metallic parts via designing direc-tional lamellar eutectic structures by AM.
基金Project(52204164) supported by the National Natural Science Foundation of ChinaProject(2023ZKPYSB01) supported by the Fundamental Research Funds for the Central Universities,China。
文摘To enhance the recuperation rate of the mine and comply with the stipulations of green mining technology, it is vital to expeditiously recuperate the coal pillar resources in the final stage, thus preventing the considerable squandering of resources. The coal pillar resource of the main roadway and its branch roadway constitutes a significant recovery subject. Its coal pillar shape is regular and possesses a considerable strike distance, facilitating the arrangement of the coal pillar recovery working face (CPRWF) for mining operations. However, for the remaining coal pillars with a thick and hard roof (THF) and multiple tectonic zones, CPRWF encounters challenges in selecting an appropriate layout, managing excessive roof pressure, and predicting mining stress. Aiming at the roadway coal pillar group with THF and multi-structural areas in specific projects, a method of constructing multi-stage CPRWF by one side gob-side entry driving (GSED) and one side roadway reusing is proposed. Through theoretical calculation of roof fracture and numerical simulation verification, combined with field engineering experience and economic analysis, the width of the narrow coal pillar (NCP) in the GSED is determined to be 10 m and the length of the CPRWF is 65 m. Concurrently, the potential safety hazard that the roof will fall asymmetrically and THF is difficult to break during CPRWF mining after GSED is analyzed and verified. Then, a control method involving the pre-cutting of the roof in the reused roadway before mining is proposed. This method has been shown to facilitate the complete collapse of THF, reduce the degree of mine pressure, and facilitate the symmetrical breaking of the roof. Accordingly, a roof-cutting scheme based on a directional drilling rig, bidirectional shaped polyvinyl chloride (PVC) pipe, and emulsion explosive was devised, and the pre-splitting of 8.2 m THF was accomplished. Field observations indicate that directional cracks are evident in the roof, the coal wall is flat during CPRWF mining, and the overall level of mining pressure is within the control range. Therefore, the combined application of GSED and roof-cutting technology for coal pillar recovery has been successfully implemented, thereby providing new insights and engineering references for the construction and pressure relief mining of CPRWF.
基金Supported by the Key Laboratory Fund for Equipment Pre-Research(6142207210202)。
文摘Aiming at the problem that infrared small target detection faces low contrast between the background and the target and insufficient noise suppression ability under the complex cloud background,an infrared small target detection method based on the tensor nuclear norm and direction residual weighting was proposed.Based on converting the infrared image into an infrared patch tensor model,from the perspective of the low-rank nature of the background tensor,and taking advantage of the difference in contrast between the background and the target in different directions,we designed a double-neighborhood local contrast based on direction residual weighting method(DNLCDRW)combined with the partial sum of tensor nuclear norm(PSTNN)to achieve effective background suppression and recovery of infrared small targets.Experiments show that the algorithm is effective in suppressing the background and improving the detection ability of the target.
文摘Professor Paul Crosthwaite,from the School of Literature,Languages,and Cultures at the University of Edinburgh,is a prominent scholar in the interdisciplinary field of literature and economics.He is a co-editor of the Palgrave Studies in Literature,Culture,and Economics series and The Cambridge Companion to Literature and Economics(2022).In recent years,he has significantly influenced the intersection of literature and economics,advocating particularly for a shift towards the Economic Humanities.This interview covers:1.The definition and theoretical origin of the Economic Humanities;2.The internal heterogeneity and critical limitations of the New Economic Criticism,and the theoretical advantages and potential development of the Economic Humanities;3.What research paradigms do Environmental Humanities,Medical Humanities,and Digital Humanities provide for the Economic Humanities;4.How literary researchers can work at the interface of the Economic Humanities research.As a novel interdisciplinary interface between literature and economics,Professor Paul Crosthwaite’s concept of the Economic Humanities not only pioneers methodological tools for interdisciplinary studies of literature and economics but also underscores the interpretative potential and disciplinary benefits of literary viewpoints on economics.This underscores the vital role of literature in human knowledge,meriting attention from the literary research academia.
基金supported in part by the National Natural Science Foundation of China(62173028,62233015,62173024)the Guangdong Basic and Applied Basic Research Foundation(2024A1515011493)+3 种基金the Science,Technology&Innovation Project of Xiongan New Area(2023XAGG0062)Beijing Natural Science Foundation(4232060)the International Scientists Project,Beijing Natural Science Foundation(IS23065)the Brazilian Research Council(303289/2022-8)
文摘In this paper, the problem of pre-specified performance fault-tolerant cluster consensus control and fault direction identification is solved for the human-in-the-loop(HIL) swarm unmanned aerial vehicles(UAVs) in the presence of possible nonidentical and unknown direction faults(NUDFs) in the yaw channel.The control strategy begins with the design of a pre-specified performance event-triggered observer for each individual UAV.These observers estimate the outputs of the human controlled UAVs, and simultaneously achieve the distributed design of actual control signals as well as cluster consensus of the observer output.It is worth mentioning that these observers require neither the high-order derivatives of the human controlled UAVs' output nor a priori knowledge of the initial conditions. The fault-tolerant controller realizes the pre-specified performance output regulation through error transformation and the Nussbaum function. It should be pointed out that there are no chattering caused by the jump of the Nussbaum function when a reverse fault occurs. In addition, to provide a basis for further solving the problem of physical malfunctions, a fault direction identification algorithm is proposed to accurately identify whether a reverse fault has occurred. Simulation results verify the effectiveness of the proposed control and fault direction identification strategies when the reverse faults occur.
文摘Background Agility and change of direction speed(COD)are essential skills in sports,their development being the focus of training and research.While these terms have been used interchangeably,it is crucial to distinguish between agility and COD,as the latter involves a sudden change in direction without the presence of external stimuli.Objective This meta-analysis aims to summarize studies that have included COD and agility tests and explore the potential relationship between these two physical qualities.Method Following the PRISMA guidelines,a meta-analysis was conducted using studies published between 2005 and 2021.All studies identified for inclusion were peer-reviewed and published in English and Spanish,using an athlete population as participants.For all analyses,a significance level was set at P<0.05.Results The meta-analysis,which included 21 studies with 945 participants from various team sports,found a moderate correlation(r=0.46)between agility and COD.This study considers moderator variables such as Age,Sex,Sport,Test Pattern,Test Combination,and Agility Stimulus.Conclusion The results of this study revealed that while COD and agility have commonalities,these two constructs represent distinct different qualities.Younger participants show a stronger correlation between the two,emphasizing age-related differences in physical development.Coaches should consider these findings in designing training programs and assessments,tailoring approaches based on the specific demands of each skill.The study contributes valuable insights into the nuanced relationship between agility and COD in team sports.
文摘According to the measurement principle of the traditional interferometer,a narrowband signal model is established and used,however,for wideband signals or multiple signals,this model is invalid.For the problems of direction finding with interferometer for wideband signals and multiple signals scene,a frequency domain phase interferometer is proposed and the concrete implementation scheme is given.The proposed method computes the phase difference in frequency domain,and finds multi-target results with judging the spectrum amplitude changing,and uses the frequency phase difference to compute the arrival angle.Theoretical analysis and simulation results show that the proposed method effectively solves the problem of the angle estimation with phase interferometer for wideband signals,and has good performance in multiple signals scene with nonoverlapping spectrum or partially overlapping.In addition,the wider the signal bandwidth,the better direction finding performance of this algorithm.
基金Supported by the National Natural Science Foundation of China(U24B6002)National Science and Technology Major Project(2024ZD14001)Project of the Sinopec Science and Technology Department(P25196,P24207).
文摘Lacustrine rift basins in China are characterized by pronounced structural segmentation,strong sedimentary heterogeneity,extensive fault-fracture development,and significant variability in thermal maturity and mobility of shale oil.This study reviews the current status of exploration and development of shale oil in such basins and examines theoretical frameworks such as“binary enrichment”and source-reservoir configuration,with a focus on five key subjects:(1)sedimentation-diagenesis coupling mechanisms of fine-grained shale reservoir formation;(2)dynamic diagenetic evolution and hydrocarbon occurrence mechanisms of organic-rich shale;(3)dominant controls and evaluation methods for shale oil enrichment;(4)fracturing mechanisms of organic-rich shale and simulation of artificial fracture networks;and(5)flow mechanisms and effective development strategies for shale oil.Integrated analysis suggests that two major scientific challenges must be addressed:the coupled evolution of fine-grained sedimentation,differential diagenesis,and hydrocarbon generation under tectonic influence and its control on shale oil occurrence and enrichment;and multi-scale,multiphase flow mechanisms and three-dimensional development strategies for lacustrine shale oil in complex fault blocks.In response to current exploration and development bottlenecks,future research will be conducted primarily to:(1)deeply understand organic-inorganic interactions and reservoir formation mechanisms in organic-rich shales,and clarify the influence of high-frequency sequence evolution and diagenetic fluids on reservoir space;(2)elucidate the dynamic processes of hydrocarbon generation,expulsion,and retention across different lithofacies,and quantify their relationship with thermal maturity,including the conditions for the formation of self-sealing systems;(3)develop a geologically adaptive,data-and intelligence-driven shale oil classification and grading evaluation system of shale oil;(4)reveal artificial fracture propagation pattern and optimize physical field coupled fracturing technologies for complex lithofacies assemblages;and(5)overcome challenges in multi-scale geological modeling and multiphase flow characterization,and establish advanced numerical simulation methodologies.
基金financial support from the Ministry of Education,Culture,Sports,Science and Technology (MEXT),Japan
文摘The effect of seismic directionality is crucial for curved bridges,a subject generally overlooked in seismic vulnerability analysis.This paper focuses on seismic fragility development as a function of seismic incidence directions for a geometrically curved bridge.A series of non-linear time history analyses were carried out for a representative finite element model of the bridge by considering actual ground motions.For reliable seismic demand models,a total of eleven intensity measures(IM)were analyzed based on optimality metrics.To quantify the sensitivity of fragility functions to input incidence directions,fragility surfaces were developed throughout the horizontal plane by considering spectral acceleration at one second(Sa_(1.0))as the optimal IM.Results show that the optimal IM ranking is insignificantly influenced by seismic directionality.However,seismic orientation influences fragility,which intensifies in higher damage states,particularly for piers.For a bridge system,the differences in median demand corresponding to the least and most vulnerable direction for slight,moderate,extensive,and collapse states are about 9.0%,7.31%,10.32%,and 11.60%,respectively.These results imply that while evaluating the vulnerability of curved bridges,the optimality of IM in demand estimation and the impact of seismic directionality should not be disregarded.
基金supported by the Korea Agency for Infrastructure Technology Advancement under the Ministry of Land,Infrastructure and Transport (Grant No.RS-2024-00410248)by National Research Foundation of Korea (NRF)grants funded by the Korean government (MSIT) (Grant No.RS-2022R1C1C1007296).
文摘Suffusion is the process defined as the migration of relatively small soil particles through the pores of a soil matrix composed of relatively large particles,driven by substantial hydrodynamic forces and weak attraction energies.This study investigates the influence of flow direction(upward and downward)on suffusion induced by interaction energies in sand-clay mixtures under both saturated and unsaturated conditions.The impact of clay mineralogy(kaolinite,illite,and montmorillonite),sand-grain size,and ionic concentration(IC)gradient were discussed based on the observed breakthrough curves(BTCs)and relative saturation rate(Sr)during injection(particularly for unsaturated conditions).Under saturated conditions,higher susceptibility to suffusion was observed in sand-kaolinite and sand-illite mixtures under downward flow compared to upward flow,whereas the suffusion of montmorillonite was more significant under upward flow than under downward flow.In contrast,for unsaturated conditions,more substantial suffusion of kaolinite and illite particles occurred under upward flow compared to downward flow,whereas the opposite trend was observed in sand-montmorillonite mixtures.In addition,the impact of sand-grain size(or the size ratio between sand and clay)on the suffusion of kaolinite and illite under unsaturated conditions suggests a reduced size ratio that leads to relatively significant suffusion under downward flow compared to upward flow.The findings presented in this study contribute to a comprehensive understanding of the influence of flow direction on suffusion in sand-clay mixtures under both saturated and unsaturated conditions.
文摘In May 2025,Australia held a federal election in which the Labor Party won with an overwhelming majority and the Liberal-National Party coalition(the Coalition)suffered a historic defeat.Around the election period,Australia faced profound changes in both domestic and international circumstances.
