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Tuning intramolecular dipole interactions in dinuclear single-molecule magnetic complexes of Er(Ⅲ)with monosubstituted cyclooctatetraenide ligands
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作者 Qiwei Chen Yousong Ding +2 位作者 Xiaofei Zhu Bingwu Wang Zhiping Zheng 《Journal of Rare Earths》 2025年第6期1213-1219,I0005,共8页
Manipulating magnetic couplings in molecular magnets is of great importance in improving the mag-netic properties of such materials.It has been proved that by adjusting the strength of magnetic cou-plings and the arra... Manipulating magnetic couplings in molecular magnets is of great importance in improving the mag-netic properties of such materials.It has been proved that by adjusting the strength of magnetic cou-plings and the arrangement of the intermolecular magnetic dipoles,magnetic blocking can be significantly enhanced.Herein manipulating the intramolecular dipole interactions by ligand modifica-tion was attempted with the use of three closely related dinuclear Er(Ⅲ)complexes of a common chemical formula of[(COT^(R))Er(μ-CI)(THF)]_(2)(COT^(R)is monosubstituted cyclooctatetraenide dianions with R=diphenylmethylsilyl(Ph_(2)MeS)for 1,triethylsilyl(TES)for 2,and triisopropylsilyl(TIPS)for 3).Each of these complexes features a centrosymmetric dinuclear core unit with their component Er(Ⅲ)ions doubly bridged by two chloro ligands and further coordinated with a capping substituted corR ligand and a coordinated THF molecule.Magnetic studies reveal that the complexes display similar ferromagnetic couplings with comparable single-molecule magnetic behaviors.The ferromagnetic couplings dominated by the intramolecular dipole interactions are found to be 0.7614,0.7380,and 0.5635 cm^(-1)for 1,2,and 3,respectively.The angles(θ)between the magnetic easy axes and the intramolecular Er-Er lines are 24.88(2)°,25.23(1),and 31.85(5),leading to transversal dipole fields of 0.0114,0.0113,and 0.0125 T for 1,2,and 3,respectively.Although the different ligand substitution generates a sizable difference of about 7 in theθangle,the resulting difference in the dipole interactions is not sufficiently strong to cause any significant differences in their magnetic properties.Further change in theθangles to the"side-by-side"(θ=90°)or"head-to-tail"(θ=0°)arrangement of the magnetic easy axes,achievable by rational mo-lecular design,is expected to lead to molecular magnetic materials with much enhanced properties. 展开更多
关键词 Single-molecule magnet dipole interaction Cyclooctatetraenide dianion Magnetic easy axe Ferromagnetic coupling RAREEARTHS
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Density distribution of ground state of one-dimensional Bose gas with dipole interaction
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作者 Shuchang Hao Yajiang Hao 《Chinese Physics B》 2025年第3期245-249,共5页
Using the Bose-Fermi mapping method,we obtain the exact ground state wavefunction of one-dimensional(1D)Bose gas with the zero-range dipolar interaction in the strongly repulsive contact interaction limit.Its ground s... Using the Bose-Fermi mapping method,we obtain the exact ground state wavefunction of one-dimensional(1D)Bose gas with the zero-range dipolar interaction in the strongly repulsive contact interaction limit.Its ground state density distributions for both repulsive and attractive dipole interactions are exhibited.It is shown that in the case of the finite dipole interaction the density profiles do not change obviously with the increase of dipole interaction and display the typical shell structure of Tonks-Girardeau gases.As the repulsive dipole interaction is greatly strong,the density decreases at the center of the trap and displays a sunken valley.As the attractive dipole interaction increases,the density displays more oscillations and sharp peaks appear in the strong attraction limit,which mainly originate from the atoms occupying the low single particle levels. 展开更多
关键词 Bose gas ONE-DIMENSIONAL dipole interaction
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Manipulation of nonreciprocal unconventional photon blockade in a cavity-driven system composed of an asymmetrical cavity and two atoms with weak dipole–dipole interaction
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作者 Xinqin Zhang Xiuwen Xia +3 位作者 Jingping Xu Haozhen Li Zeyun Fu Yaping Yang 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第7期302-308,共7页
We present a work of manipulating collective unconventional photon blockade(UCPB)and nonreciprocal UCPB(NUCPB)in a cavity-driven system composed of an asymmetrical single-mode cavity and two interacting identical twol... We present a work of manipulating collective unconventional photon blockade(UCPB)and nonreciprocal UCPB(NUCPB)in a cavity-driven system composed of an asymmetrical single-mode cavity and two interacting identical twolevel atoms(TLAs).When the atoms do not interact directly,the frequency and intensity restrictions of collective UCPB can be specified,and a giant NUCPB exists due to the splitting of optimal atom–cavity coupling strength in proper parameter regime.However,if a weak atom–atom interaction which provides a new and feeble quantum interference pathway to UCPB is taken into account,two restrictions of UCPB are combined complexly,which are rigorous to be matched simultaneously.Due to the push-and-pull effect induced by weak dipole–dipole interaction,the UCPB regime is compressed more or less.NUCPB is improved as a higher contrast is present when the two complex UCPB restrictions are matched,while it is suppressed when the restrictions are mismatched.In general,whether NUCPB is suppressed or promoted depends on its working parameters.Our findings show a prospective access to produce giant quantum nonreciprocity by a couple of weakly interacting atoms. 展开更多
关键词 unconventional photon blockade quantum nonreciprocity dipoledipole interaction
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The Role of the Dipole Interaction of Molecules with Charged Particles in the Polar Stratosphere
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作者 Yury Belikov Sergey Nikolayshvili 《Journal of Earth Science and Engineering》 2016年第3期115-149,共35页
Our analysis of published results of experiments in the Polar Regions substantiates and further develops our new approach to the photochemical processes in the polar stratosphere involving the charged particles. The d... Our analysis of published results of experiments in the Polar Regions substantiates and further develops our new approach to the photochemical processes in the polar stratosphere involving the charged particles. The dipole interaction of molecules with charged particles, primarily with ions, leads to the adhesion and disintegration of a number of molecules including ozone. Molecules acquire additional energy on the surface of the charged particles, enabling reactions that are not possible in space. Galactic cosmic rays are the main source of ions in the polar stratosphere, their equilibrium concentration at altitudes of 15 to 25 km can reach up ~ (1-5) ~ 103 ions/cm3. Estimations show that if the ozone destruction in the regime of"collision" with ions then the lifetime of ozone will vary from 10 days to 2 months. We suppose that alongside with the chlorine mechanism of ozone destruction there is a mechanism of ozone decay on a charged particle which can act also at those latitudes and altitudes where chlorine oxide CIO is absent, as well as in the night conditions. Here, we demonstrated the close connection of photochemical processes with the dynamic, electrical and condensational phenomena in the stratosphere, in particular, with the accumulation of unipolar charged particles on the upper and lower boundaries of the polar stratospheric clouds and aerosol layers as a result of the activity of the global electric circuit. 展开更多
关键词 Polar stratosphere OZONE charged particles dipole interaction global electric circuit photochemistry.
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Ab Initio Studies on the Structure and Binding Interaction of M^+CO_2(M=Sc,Ti…Zn) 被引量:1
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作者 FAN Hong-Jun ZHONG Shi-Jun LIU Chun-Wan 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1998年第2期80-85,共6页
The geometry and binding interaction of M+CO2 (M represents the firstrow transition metals) were studied using ab initio methods. In some cases the frequency calculations and basis set superposition error corrections ... The geometry and binding interaction of M+CO2 (M represents the firstrow transition metals) were studied using ab initio methods. In some cases the frequency calculations and basis set superposition error corrections were included. For all the complexes under the study, the linear structures were found to be the equilibrium structure. The distances of M+—O in R(M+—O) in which M has 4s electrons are obvious longer than those in which M has no 4s electrons, and from Sc to Zn the change trend is decreased, accompanied with some oscillation. The binding energy has an opposite change trend to that of the R(M+—O). Linear M+CO2 has the same spin as M+, while Tshape structures may have different spins. The static electronic interaction was found to be about 80% of the total binding energy. 展开更多
关键词 Chargeinduced dipole interaction Binding energy Equilibrium structure Ab initio
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Levitation and lateral forces between a point magnetic dipole and a superconducting sphere
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作者 H M Al-Khateeb M K Alqadi +3 位作者 F Y Alzoubi B Albiss M K Hasan (Qaseer) N Y Ayoub 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第5期453-456,共4页
The dipole–dipole interaction model is employed to investigate the angular dependence of the levitation and lateral forces acting on a small magnet in an anti-symmetric magnet/superconducting sphere system. Breaking ... The dipole–dipole interaction model is employed to investigate the angular dependence of the levitation and lateral forces acting on a small magnet in an anti-symmetric magnet/superconducting sphere system. Breaking the symmetry of the system enables us to study the lateral force which is important in the stability of the magnet above a superconducting sphere in the Meissner state. Under the assumption that the lateral displacement of the magnet is small compared to the physical dimensions of our proposed system, analytical expressions are obtained for the levitation and lateral forces as a function of the geometrical parameters of the superconductor as well as the height, the lateral displacement, and the orientation of the magnetic moment of the magnet. The dependence of the levitation force on the height of the levitating magnet is similar to that in the symmetric magnet/superconducting sphere system within the range of proposed lateral displacements. It is found that the levitation force is linearly dependent on the lateral displacement whereas the lateral force is independent of this displacement. A sinusoidal variation of both forces as a function of the polar and azimuthal angles specifying the orientation of the magnetic moment is observed. The relationship between the stability and the orientation of the magnetic moment is discussed for different orientations. 展开更多
关键词 lateral and levitation forces Meissner effect dipoledipole interaction model SUPERCONDUCTOR
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Photon bunching and anti-bunching with two dipole-coupled atoms in an optical cavity
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作者 郑雅梅 胡长生 +1 位作者 杨贞标 吴怀志 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第10期149-156,共8页
We investigate the effect of the dipole–dipole interaction(DDI) on the photon statistics with two atoms trapped in an optical cavity driven by a laser field and subjected to cooperative emission. By means of the quan... We investigate the effect of the dipole–dipole interaction(DDI) on the photon statistics with two atoms trapped in an optical cavity driven by a laser field and subjected to cooperative emission. By means of the quantum trajectory analysis and the second-order correlation functions, we show that the photon statistics of the cavity transmission can be flexibly modulated by the DDI while the incoming coherent laser selectively excites the atom–cavity system’s nonlinear Jaynes–Cummings ladder of excited states. Finally, we find that the effect of the cooperatively atomic emission can also be revealed by the numerical simulations and can be explained with a simplified picture. The DDI induced nonlinearity gives rise to highly nonclassical photon emission from the cavity that is significant for quantum information processing and quantum communication. 展开更多
关键词 photon bunching and anti-bunching dipoledipole interaction cooperative emission cavity QED
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LINKAGE BETWEEN INDIAN OCEAN DIPOLE AND TWO TYPES OF El NI?O AND ITS POSSIBLE MECHANISMS 被引量:2
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作者 董笛 何金海 李建平 《Journal of Tropical Meteorology》 SCIE 2016年第2期172-181,共10页
After compositing three representative ENSO indices,El Nio events have been divided into an eastern pattern(EP) and a central pattern(CP).By using EOF,correlation and composite analysis,the relationship and possible m... After compositing three representative ENSO indices,El Nio events have been divided into an eastern pattern(EP) and a central pattern(CP).By using EOF,correlation and composite analysis,the relationship and possible mechanisms between Indian Ocean Dipole(IOD) and two types of El Nio were investigated.IOD events,originating from Indo-Pacific scale air-sea interaction,are composed of two modes,which are associated with EP and CP El Ni o respectively.The IOD mode related to EP El Nio events(named as IOD1) is strongest at the depth of 50 to 150 m along the equatorial Indian Ocean.Besides,it shows a quasi-symmetric distribution,stronger in the south of the Equator.The IOD mode associated with CP El Nio(named as IOD2) has strongest signal in tropical southern Indian Ocean surface.In terms of mechanisms,before EP El Nio peaks,anomalous Walker circulation produces strong anomalous easterlies in equatorial Indian Ocean,resulting in upwelling in the east,decreasing sea temperature there;a couple of anomalous anticyclones(stronger in the south) form off the Equator where warm water accumulates,and thus the IOD1 occurs.When CP El Nio develops,anomalous Walker circulation is weaker and shifts its center to the west,therefore anomalous easterlies in equatorial Indian Ocean is less strong.Besides,the anticyclone south of Sumatra strengthens,and the southerlies east of it bring cold water from higher latitudes and northerlies west of it bring warm water from lower latitudes to the 15° to 25°S zone.Meanwhile,there exists strong divergence in the east and convergence in the west part of tropical southern Indian Ocean,making sea temperature fall and rise separately.Therefore,IOD2 lies farther south. 展开更多
关键词 Indian Ocean dipole two types of El Nio anomalous Walker circulation air-sea interaction sea temperature anomaly
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Entanglement transfer between atoms in two distant cavities via an optical fibre 被引量:2
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作者 肖兴 方卯发 《Chinese Physics B》 SCIE EI CAS CSCD 2009年第11期4695-4701,共7页
This paper presents a treatment of the entanglement transfer between atoms in two distant cavities coupled by an optical fibre. If the atoms resonantly and collectively interact with the local single-mode cavity field... This paper presents a treatment of the entanglement transfer between atoms in two distant cavities coupled by an optical fibre. If the atoms resonantly and collectively interact with the local single-mode cavity fields and the dipole-dipole interaction between the atoms is neglected, then it shows that a complete transfer of entanglement from one pair of atoms to another can be deterministically realized. Furthermore, it also investigates the effects of dipole-dipole interaction on entanglement transfer on the condition that the interaction between the atoms and the cavity is much weaker than the coupling between the cavity and the fibre. 展开更多
关键词 entanglement transfer dipole dipole interaction CONCURRENCE
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Exact solution of entanglement of the double Jaynes-Cummings model without rotating wave approximation 被引量:1
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作者 任学藻 姜道来 +1 位作者 丛红璐 黎雷 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第9期129-134,共6页
This paper investigates the influences of atom field coupling and dipole-dipole coupling for atoms on the entanglement between two atoms by means of concurrence, The results show that the sudden death occurs when the ... This paper investigates the influences of atom field coupling and dipole-dipole coupling for atoms on the entanglement between two atoms by means of concurrence, The results show that the sudden death occurs when the atom field coupling is strong enough, and the collapse and the revival appear when the dipole-dipole interaction is strong enough. 展开更多
关键词 CONCURRENCE sudden death atom-field coupling dipole dipole interaction
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Largely Improved Stretch Ductility and β-Form Room-temperature Durability of Poly(vinylidene fluoride) by Incorporating Aliphatic Polyketone 被引量:1
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作者 Shui-Qin Pu Shuo Guo +1 位作者 Ke Wang Qiang Fu 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2018年第11期1277-1285,共9页
In this study, we attempt to prepare a new blending system of poly(vinylidene fluoride) (PVDF) and aliphatic polyketone (POK) by melt compounding, The latter is a promising engineering plastic with comprehensive... In this study, we attempt to prepare a new blending system of poly(vinylidene fluoride) (PVDF) and aliphatic polyketone (POK) by melt compounding, The latter is a promising engineering plastic with comprehensive mechanical performances. When POK acted as minor phase to homogeneously disperse in and intimately contact with PVDF matrix, the brittle tensile behavior of neat PVDF transferred into a remarkably flexible manner (the elongation at break increased for 20 times), and more interestingly, the room- temperature durability of β-form PVDF in the uniaxially drawn blend film was obviously better than that in the neat PVDF film. Fourier transform infrared spectroscopy revealed that specific dipole interaction existed between CF2 group of PVDF and C=O group of POK. The intermolecular dipolar interaction induced good compatibility in the PVDF/POK blends, as evidently proved by fine two-phase morphology and decreased melting points of POK crystals. Therefore, the good compatibility and interracial enhancement are responsible for the improvement of the stretch ductility and β-form room-temperature durability of the PVDF/POK blends. 展开更多
关键词 BLEND Aliphatic polyketone dipole interaction Stretch ductility Uniaxially drawn β-PVDF
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Photoluminescence of green nanophosphors Sr_(2)MgSi_(2)O_(7)doped with Tb^(3+)under 374-nm excitation 被引量:1
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作者 Bo-Shi Mu Yi Zhang +5 位作者 Qing-Feng Bian Cheng-Ren Li Zhi-Chao Li Yun-Ting Chu Feng Zhao Jing-Chang Sun 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第12期343-347,共5页
A series of Sr_(2)MgSi_(2)O_(7):Tb^(3+)nanophosphors is prepared using a high-temperature solid-state reaction.The x-ray diffraction patterns show that the crystal structure of the sample is not significantly affected... A series of Sr_(2)MgSi_(2)O_(7):Tb^(3+)nanophosphors is prepared using a high-temperature solid-state reaction.The x-ray diffraction patterns show that the crystal structure of the sample is not significantly affected by Tb^(3+)ions.However,the images of the scanning electron microscope illustrate that the average size of nanoparticles becomes larger with the increase of Tb^(3+)concentration.Unlike earlier investigations on down-conversion emission of Tb^(3+)ion excited by deep ultraviolet light,in this work,the photoluminescence characteristics of Sr_(2)MgSi_(2)O_(7)nanophosphors doped with different Tb^(3+)concentrations are analyzed under 374-nm excitations.The intense green emission at 545 nm is observed at an optimal doping concentration of 1.6 mol%.The main reason for the concentration quenching is due to the electric dipole-electric dipole interaction among Tb^(3+)ions. 展开更多
关键词 Sr_(2)MgSi_(2)O_(7):Tb^(3+)nanophosphor green emission 374-nm excitation electric dipole-electric dipole interaction
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Quantum information processing with nuclear spins mediated by a weak-mechanically controlled electron spin
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作者 Wan-Jun Su Guang-Zheng Ye 《Communications in Theoretical Physics》 SCIE CAS CSCD 2022年第5期15-23,共9页
We propose a scheme to achieve nuclear–nuclear indirect interactions mediated by a mechanically driven nitrogen-vacancy(NV)center in a diamond.Here we demonstrate twoqubit entangling gates and quantum-state transfer ... We propose a scheme to achieve nuclear–nuclear indirect interactions mediated by a mechanically driven nitrogen-vacancy(NV)center in a diamond.Here we demonstrate twoqubit entangling gates and quantum-state transfer between two carbon nuclei.When the dipole–dipole interaction strength is much larger than the driving field strength,the scheme is robust against decoherence caused by coupling between the NV center(nuclear spins)and the environment.Conveniently,precise control of dipole coupling is not required so this scheme is insensitive to fluctuating positions of the nuclear spins and the NV center.Our scheme provides a general blueprint for multi-nuclear-spin gates and for multi-party communication. 展开更多
关键词 dipoledipole interaction mechanically control NV center quantum Zeno effect
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Dynamical stability of dipolar condensate in a parametrically modulated one-dimensional optical lattice
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作者 Ji-Li Ma Xiao-Xun Li +2 位作者 Rui-Jin Cheng Ai-Xia Zhang Ju-Kui Xue 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第6期143-148,共6页
We study the stabilization properties of dipolar Bose–Einstein condensate in a deep one-dimensional optical lattice with an additional external parametrically modulated harmonic trap potential. Through both analytica... We study the stabilization properties of dipolar Bose–Einstein condensate in a deep one-dimensional optical lattice with an additional external parametrically modulated harmonic trap potential. Through both analytical and numerical methods, we solve a dimensionless nonlocal nonlinear discrete Gross–Pitaevskii equation with both the short-range contact interaction and the long-range dipole–dipole interaction. It is shown that, the stability of dipolar condensate in modulated deep optical lattice can be controled by coupled effects of the contact interaction, the dipolar interaction and the external modulation. The system can be stabilized when the dipolar interaction, the contact interaction, the average strength of potential and the ratio of amplitude to frequency of the modulation satisfy a critical condition. In addition, the breather state, the diffused state and the attractive-interaction-induced-trapped state are predicted. The dipolar interaction and the external modulation of the lattice play important roles in stabilizing the condensate. 展开更多
关键词 Bose–Einstein condensate optical lattice dipoledipole interaction periodic modulation
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The dynamics of three coupled dipolar Bose Einstein condensates
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作者 武建华 许胜男 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第12期87-95,共9页
The dynamics of the three coupled dipolar Bose–Einstein condensates containing N bosons is investigated within a mean-field semiclassical picture based on the coherent-state method. Varieties of periodic solutions (... The dynamics of the three coupled dipolar Bose–Einstein condensates containing N bosons is investigated within a mean-field semiclassical picture based on the coherent-state method. Varieties of periodic solutions (configured as vortex, single depleted well, and dimerlike states) are obtained analytically when the fixed points are identified on the N=constant. The system dynamics are studied via numeric integration of trimer motion equations, thus revealing macroscopic effects of population inversion and self-trapping with different initial states. In particular, the trajectory of the oscillations of the populations in each well shows how the dynamics of the condensates are effected by the presence of dipole–dipole interaction and gauge field. 展开更多
关键词 Bose– Einstein condensate triple-well dipole dipole interaction dynamics
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