Previous studies suggest that dipolarization fronts (DFs) are 1 to 3RE (RE is the earth radius) wide in the dawn-dusk direction. Recent kinetic simulations have found that DFs may break up into small-scale structures ...Previous studies suggest that dipolarization fronts (DFs) are 1 to 3RE (RE is the earth radius) wide in the dawn-dusk direction. Recent kinetic simulations have found that DFs may break up into small-scale structures after they are produced by reconnection. Motivated by this simulation, we revisited the scale size of DFs in the dawn-dusk direction by using Cluster observations during the years when the inter-distance among Cluster spacecraft was between 1000 and 2000 km. We selected the DFs that were detected by more than one spacecraft and estimated the radii of these DFs by a simple geometrical analysis, which is based on comparison of DF normals observed by different spacecraft. We found a few DFs that were only a few ion inertial lengths in the dawn-dusk direction. These results point out the importance of multi-scale coupling during the evolution of DFs.展开更多
In this paper, the particle acceleration processes around magnetotail dipolarization fronts(DFs) were reviewed. We summarize the spacecraft observations(including Cluster, THEMIS, MMS) and numerical simulations(includ...In this paper, the particle acceleration processes around magnetotail dipolarization fronts(DFs) were reviewed. We summarize the spacecraft observations(including Cluster, THEMIS, MMS) and numerical simulations(including MHD, testparticle, hybrid, LSK, PIC) of these processes. Specifically, we(1) introduce the properties of DFs at MHD scale, ion scale, and electron scale,(2) review the properties of suprathermal electrons with particular focus on the pitch-angle distributions,(3)define the particle-acceleration process and distinguish it from the particle-heating process,(4) identify the particle-acceleration process from spacecraft measurements of energy fluxes, and(5) quantify the acceleration efficiency and compare it with other processes in the magnetosphere(e.g., magnetic reconnection and radiation-belt acceleration processes). We focus on both the acceleration of electrons and ions(including light ions and heavy ions). Regarding electron acceleration, we introduce Fermi,betatron, and non-adiabatic acceleration mechanisms;regarding ion acceleration, we present Fermi, betatron, reflection, resonance, and non-adiabatic acceleration mechanisms. We also discuss the unsolved problems and open questions relevant to this topic, and suggest directions for future studies.展开更多
In order to investigate the suprathermal electron flux(>30 ke V) around dipolarization fronts(DFs), we statistically studied the suprathermal electron flux variations and pitch angle distributions of hundreds of ea...In order to investigate the suprathermal electron flux(>30 ke V) around dipolarization fronts(DFs), we statistically studied the suprathermal electron flux variations and pitch angle distributions of hundreds of earthward propagating DFs observed by THEMIS spacecraft during its tail seasons in years 2008–2009. We focused on the electron flux variations across DFs and electron anisotropies behind DFs. We divided DF into three sectors in the equatorial plane: Dusk, central and dawn sectors. The sectors are defined according to the DF normals with respect to DF's meridian in the equatorial plane(the symmetric line of DF). We found that events with electron flux increases and decreases behind the fronts had no particular dependence on the observation locations. In addition, there was no obvious dependence of electron anisotropy behind DF on the different sectors of DF.展开更多
We report where and how ions are accelerated in the proximity of earthward propagating dipolarization fronts （DFs） in the magnetotail during a magnetospheric substorm on February 15, 2008. Two DFs were observed by m...We report where and how ions are accelerated in the proximity of earthward propagating dipolarization fronts （DFs） in the magnetotail during a magnetospheric substorm on February 15, 2008. Two DFs were observed by multiple THEMIS space- craft in the near-Earth magnetotail （-10 Re）. We studied the ion dynamics associated with these DFs by comparing observed results with large scale kinetic （LSK） simulation results. The LSK simulation reproduced the sudden ion energy flux enhance- ment concurrent with the arrival of the DF at the satellite locations. We found that ions can be accelerated to more than 100 keV energy at the DF. These ions were initially non-adiabatically accelerated near magnetic reconnection site and then still non-adiabatically accelerated at the DF structure.展开更多
It has been confirmed that dipolarization fronts(DFs)are the result of the interchange instability in the Earth's magnetotail.In this paper,we use a Hall MHD model to simulate the evolution of the interchange inst...It has been confirmed that dipolarization fronts(DFs)are the result of the interchange instability in the Earth's magnetotail.In this paper,we use a Hall MHD model to simulate the evolution of the interchange instability that produces DFs along the leading edge.A test particle simulation is performed to study the physical phenomenon of ion acceleration at the DF.The numerical simulation indicates that almost all particles move earthward and dawnward and then drift to the tail.The DF-reflected ion population at the duskside appears earlier as a consequence of the asymmetric Hall electric field.Ions that are distributed in a dawn-dusk asymmetric semicircle behind the DF tend to be accelerated to higher energies(>13.5 keV).These high-energy particles eventually concentrate in the dawnside.Ions experience effective acceleration by the dawnward electric field,while they drift through the dawn flank at the front,toward the tail.展开更多
Many planets,including the Earth,possess a global dipolar magnetic field.To diagnose the interior source of the dipolar field,researchers usually adopt a dipole model consisting of six parameters to fit the observed d...Many planets,including the Earth,possess a global dipolar magnetic field.To diagnose the interior source of the dipolar field,researchers usually adopt a dipole model consisting of six parameters to fit the observed dataset of the magnetic field.However,the simultaneous fitting of these parameters often leads to multiple local optimal parameter sets.To address this fitting dilemma,Rong ZJ et al.(2021)recently developed a current loop model.This technique can successively separate and invert the loop parameters.Here,we further show how this technique can be reduced and modified to fit a dipole model.Applications of this reduced technique to the International Geomagnetic Reference Field model and the Martian crustal field model highlight its unique ability to diagnose both the planetary global dipolar field and the local crustal field anomaly,a capability that sets it apart from existing methods.The potential impact of this technique on geomagnetism and planetary magnetism is significant,given its unique ability to diagnose both the planetary global dipolar field and the local crustal field anomaly.展开更多
The multiple oligopeptides have been regarded as promising alignment media due to their structural diverseness and tendency for self-assembly in solution.Herein,an assembled amphiphilic peptide alignment medium,i.e.,C...The multiple oligopeptides have been regarded as promising alignment media due to their structural diverseness and tendency for self-assembly in solution.Herein,an assembled amphiphilic peptide alignment medium,i.e.,C15eCONH-Phg-Phg-IIIKK-CONH2 with un-natural amino acids for the determination of anisotropic parameters of NMR is introduced.The amphiphilic peptide can be self-assembled at low concentrations in DMSO and is stable and highly homogeneous.The NMR spectrum collected with the addition of the medium had fewer background signals.The utility of the acquired RDC data is demon-strated to determine relative configuration of three natural products,Helminthosporic acid,Estrone,and a-Santonin.展开更多
The characterization of kerogen nanopores is crucial for predicting the geostorage capacity and recoverability of natural gas in unconventional gas shale reservoirs.Towards this end,a powerful technique is presented w...The characterization of kerogen nanopores is crucial for predicting the geostorage capacity and recoverability of natural gas in unconventional gas shale reservoirs.Towards this end,a powerful technique is presented which integrates 2D NMR T_(1)-T_(2) relaxation measurements with molecular dynamics(MD)simulations of hydrocarbons confined in the nanopores of kerogen.The integrated NMR-MD technique is demonstrated using T_(1)-T_(2) measurements of kerogen isolates and organic-rich chalks saturated with heptane,together with MD simulations of heptane completely dissolved in a realistic kerogen model.The NMR-MD results are used to extract the swelling ratio and nanopore size distribution of kerogen as a function of depth in the reservoir.The effects of organic nanoconfinement on the T_(1) relaxation dispersion and T_(2) residual dipolar coupling of heptane are investigated,as well as the effect of downhole effective stress on the kerogen nanopore size as a function of depth and compaction.Potential applications in partially depleted gas shale reservoirs are discussed,including CO_(2) utilization/geostorage,geostorage of green H2,and integration of the NMR-MD technique with thermodynamic models for predicting the competitive sorption of gas mixtures in kerogen.展开更多
With conjunction observations of electromagnetic fields and plasma from Time History of Events and Macroscale Interactions during Substorm(THEMIS)in the near-Earth magnetotail,we investigate the spatial and temporal p...With conjunction observations of electromagnetic fields and plasma from Time History of Events and Macroscale Interactions during Substorm(THEMIS)in the near-Earth magnetotail,we investigate the spatial and temporal properties of substorm dipolarizations in the near-Earth plasma sheet(NEPS)during a substorm at 03:23 UT on 12 February 2008.Substorm dipolarizations with different features are detected by three near-Earth THEMIS probes(THA(P5),THD(P3)and THE(P4))in the magnetotail.In the current sheet with a large plasma beta value(β>2,whereβis the ratio of the plasma thermal pressure to the magnetic pressure),the dipolarization within the substorm onset region,(−10.4,2.8,−2.6)RE_gsm,has a large initial magnetic field elevation angle,θ>60°,θ=arctan(Bz/(Bx2+By2)1/2),and is accompanied by energetic ion(tens to hundred keV)dispersionless injection detected by THD(P3).This substorm onset dipolarization is characterized by Bx and By components around 0 nT with significant fluctuations.The Bz component increases sharply and its subsequent magnitude approaches the total magnetic field,Bt.The maximum value of the elevation angle approaches 85°during the later substorm expansion phase.In the NEPS withβ~1,the dipolarization outside the substorm onset region is characterized by a magnetic elevation angle with a small beginning value ofθ<45°and following multi-step enhancements during the substorm expansion phase.The maximum value of the elevation angle approaches to 70°during the later substorm expansion phase.Our observation results indicate that characteristics of dipolarization with a large beginning elevation angle within the substorm onset region provide a new indicator to identify substorm onset location.展开更多
The Space Plasma Environment Research Facility(SPERF)for ground simulation of the space plasma environment is a key component of the Space Environment Simulation Research Infrastructure(SESRI),a major national science...The Space Plasma Environment Research Facility(SPERF)for ground simulation of the space plasma environment is a key component of the Space Environment Simulation Research Infrastructure(SESRI),a major national science and technology infrastructure for fundamental research.It is designed to investigate outstanding issues in the space plasma environment,such as energetic particle acceleration,transport,and interaction with electromagnetic waves,as well as magnetic reconnection processes,in magnetospheric plasmas.The Tail-Research EXperiment(TREX)is part of the SPERF for laboratory studies of space physics relevant to magnetic reconnection,dipolarization and hydromagnetic wave excitation in the magnetotail.SPERFTREX is designed to carry out three types of experiments:the tail plasmoid for magnetic reconnection,dipolarization front formation,and magnetohydrodynamic waves excited by highspeed plasma jets.In this paper,the scientific goals and three scenarios of SPERF-TREX for typical processes in space plasmas are presented,and experimental plans for SPERF-TREX are also reviewed,together with the plasma sources applied to generate the plasma with the desired parameters and various magnetic configurations.展开更多
Elastomer blends,among which natural rubber(NR)and butadiene rubber(BR),are involved in many components of the automotive/tire industry.A comprehensive understanding of their mechanical behavior requires,among other f...Elastomer blends,among which natural rubber(NR)and butadiene rubber(BR),are involved in many components of the automotive/tire industry.A comprehensive understanding of their mechanical behavior requires,among other features,a detailed description of the crosslink density in these mixtures.In the case of vulcanized immiscible blends,the distribution of the cross-link density within each of the NR-and BR-rich domains is key information,but difficult to determine using the conventional approaches used for one-component crosslinked elastomers.In this study,the vulcanization within NR/BR blends is investigated using a robust^(1)H double-quantum(DQ)MAS recoupling experiment,BaBa-xy16.Two kinds of cross-linked NR/BR blends were considered with two different microstructures for the BR component.The bulk organization of the resulting blends was first probed by analyzing the^(1)H spin-lattice relaxation behavior.In a second step,BaBa-xy16 was used to investigate,in a selective way,the cross-link heterogeneities within NR/BR blends.In particular,for immiscible NR/BR mixtures,the distribution of the cross-link density between both phases was compared and the observed differences were discussed.展开更多
Pyrolysis has the potential of transforming waste into recyclable products. Pyrolytic carbon black (PCB) is one of the most important products from the pyrolysis of used tires. Techniques for surface modifications of ...Pyrolysis has the potential of transforming waste into recyclable products. Pyrolytic carbon black (PCB) is one of the most important products from the pyrolysis of used tires. Techniques for surface modifications of PCB have been developed. One of the most significant applications for modified PCB is to reinforce the rubber matrix to obtain high added values. The transverse relaxation and the chain dynamics of vulcanized rubber networks with PCB and modified PCB were studied and compared with those of the commercial carbon blacks using selective 1H transverse relaxation (T2) experiments and dipolar correlation effect (DCE) experiments on the stimulated echo. Demineralization and coupling agent modification not only intensified the interactions between the modified PCB and the neighboring polyisoprene chains, but also increased the chemical cross-link density of the vulcanized rubber with modified PCB. The mechanical testing of the rubbers with different kinds of carbon blacks showed that the maximum strain of the rubber with modified PCB was improved greatly. The mechanical testing results confirmed the conclusion obtained by nuclear magnetic resonance (NMR). PCB modified by the demineralization and NDZ-105 titanate coupling agent could be used to replace the commercial semi-reinforcing carbon black.展开更多
The determination of natural products stereochemistry remains a formidable task.Residual dipolar couplings(RDCs)induced by anisotropic media are a powerful tool for determination of the stereochemistry of organic mole...The determination of natural products stereochemistry remains a formidable task.Residual dipolar couplings(RDCs)induced by anisotropic media are a powerful tool for determination of the stereochemistry of organic molecule in solution.This review will provide a short introduction on RDCs-based methodology for the structural elucidation of natural products.Special attention is given to the current availability of alignment media in organic solvents.The applications of RDCs for structural analysis of some examples of natural products were discussed and summarized.Graphical Abstract This review provides a short introduction on RDCs-based methodology for the structural elucidation of natural products.Special attention is given to the current availability of alignment media in organic solvents.The applications of RDCs for structural analysis of some examples of natural products were discussed and summarized.展开更多
We study the formation of vortices in a dipolar Bose-Einstein condensate in a synthetic magnetic field by numerically solving the Gross-Pitaevskii equation. The formation process depends on the dipole strength, the ro...We study the formation of vortices in a dipolar Bose-Einstein condensate in a synthetic magnetic field by numerically solving the Gross-Pitaevskii equation. The formation process depends on the dipole strength, the rotating frequency, the potential geometry, and the orientation of the dipoles. We make an extensive comparison with vortices created by a rotating trap, especially focusing on the issues of the critical rotating frequency and the vortex number as a function of the rotating frequency. We observe that a higher rotating frequency is needed to generate a large number of vortices and the anisotropic interaction manifests itself as a perceptible difference in the vortex formation. Furthermore, a large dipole strength or aspect ratio also can increase the number of vortices effectively. In particular, we discuss the validity of the Feynman rule.展开更多
A series of “H-shaped” organic dimers （azobenzene derivatives） exhibit linear absorption red shift compared with their corresponding monomers experimentally. Dipolar interaction model is not appropriate for the az...A series of “H-shaped” organic dimers （azobenzene derivatives） exhibit linear absorption red shift compared with their corresponding monomers experimentally. Dipolar interaction model is not appropriate for the azobenzene derivatives due to the small distance between two “D-π-A” chains. Energy transfer model is suggested for explanation of the absorption red shift. Two necessary conditions for energy transfer were verified. In addition, bi-exponential florescence-delay behavior of the dimer as well as Bella＇s quantum chemistry calculation shows evidence of energy transfer.展开更多
A modified correlated spectroscopy （COSY） revamped with asymmetric Z-gradient echo detection sequence was designed to investigate the influence of diffusion hehaviour on intermolecular double-quantum coherence signa...A modified correlated spectroscopy （COSY） revamped with asymmetric Z-gradient echo detection sequence was designed to investigate the influence of diffusion hehaviour on intermolecular double-quantum coherence signal attenuation during the pre-acquisition period. Theoretical formulas were deduced and experimental measurements and simulations were performed. It is found that the diffusion behaviour of intermolecular double-quantum coherence in the pre-acquisition period may be different from that of conventional single-quantum coherence, depending on the relative orientation of diffusion weighting gradients to coherence selection gradients. When the orientation of the diffusion weighting gradients is parallel or anti-parallel to the orientation of the coherence selection gradients, the diffusion is modulated by the distant dipolar field. This study is helpful for understanding the signal properties in intermolecular double-quantum coherence magnetic resonance imaging.展开更多
This paper analyses the heteronuclear Cosy Revamped by Asymmetric Z-gradient Echo Detection pulse sequence. General theoretical expressions of the pulse sequence with arbitrary flip angles were derived by using dipola...This paper analyses the heteronuclear Cosy Revamped by Asymmetric Z-gradient Echo Detection pulse sequence. General theoretical expressions of the pulse sequence with arbitrary flip angles were derived by using dipolar field treatment and signals originating from heteronuclear intermolecular single-quantum coherences （iSQCs） in highly-polarized two spin-1/2 systems were mainly discussed in order to find the optimal flip angles. The results show that signals from heteronuclear iSQCs decay slower than those from intermolecular double-quantum coherences or intermolecular zero-quantum coherences. Magical angle experiments validate that the signals are from heteronuclear iSQCs and insensitive to the imperfection of radio-frequency flip angles. All experimental observations are in excellent agreement with theoretical predictions. The quantum-mechanical treatment leads to similar predictions to the dipolar field treatment.展开更多
The main idea of this paper is to find an analytical formula for the input conductance of an elevated ferrite film circu-lator to match it systematically to the desired matching network. For solving the ferrite loaded...The main idea of this paper is to find an analytical formula for the input conductance of an elevated ferrite film circu-lator to match it systematically to the desired matching network. For solving the ferrite loaded dielectric resonator included in stripline elevated ferrite film circulator, the off diagonal components of the permeability tensor are taken as the perturbation. The electromagnetic fields computations are done for unperturbed structure. The dipolar resonant frequencies corresponding to harmonics of the resonant modes are then calculated using the perturbation integrals. The quality factor of the circulator is derived in terms of these dipolar resonant frequencies. Energy integrals are calculated to find the energy stored in the ferrite and dielectic layers. An analytical expression for the input conductance of the elevated ferrite film circulators is derived by using the quality factor and energy integrals. In this expression the ferrite and dielectric layers can have different permittivities. Some discussions about the effect of ferrite film thickness and permittivity mismatch on the bandwidth of the circulator are investigated by HFSS commercial software.展开更多
Tumor-targeted magnetic hyperthermia has recently attracted much attention.Magnetic nanoparticles(NPs) are heat mediator nanoprobes in magnetic hyperthermia for cancer treatment.In this paper,single cubic spinel struc...Tumor-targeted magnetic hyperthermia has recently attracted much attention.Magnetic nanoparticles(NPs) are heat mediator nanoprobes in magnetic hyperthermia for cancer treatment.In this paper,single cubic spinel structural Zn_(0.3)Fe_(2.7)O_(4) magnetic NPs with sizes of 14 nm-20 nm were synthesized,followed by coating with SiO_(2) shell.The SLP value of Zn_(0.3)Fe_(2.7)O_(4)/SiO_(2) NPs below 20 nm changes non-monotonically with the concentration of solution under the alternating current(AC) magnetic field of 430 kHz and 27 kA/m.SLP values of all Zn_(0.3)Fe_(2.7)O_(4)/SiO_(2) NPs appear a peak value with change of solution concentration.The solution concentrations with optimal SLP value decrease with increasing magnetic core size.This work can give guidance to the better prediction and control of the magnetic hyperthermia performance of materials in clinical applications.展开更多
We report a numerical study on the role of longrange dipolar interaction played on the creation and stabilization of skyrmion-(non)crystal structure in chiral ferromagnetic thin films without any anisotropies,based on...We report a numerical study on the role of longrange dipolar interaction played on the creation and stabilization of skyrmion-(non)crystal structure in chiral ferromagnetic thin films without any anisotropies,based on a Monte-Carlo simulation method.With the increase of external magnetic field,the microscopic spin configuration is transformed from a spin-spiral stripe or labyrinth structure,depending on the strength of dipolar interaction,into a skyrmion-(non)crystal structure,and then into a skyrmiongas structure,and finally into a ferromagnetic state.Interestingly,with the increase of dipolar interaction,the skyrmion-crystal structure evolves from a triangular arrangement into a square arrangement with the change of skyrmion shape from circle to square.For larger dipolar interactions,the skyrmion-crystal structure loses the regular arrangements and the skyrmions,remaining topological,exhibit different shapes and sizes and squeeze with each other,whose distributions are analogous to a non-crystal structure.Therefore,different skyrmion-(non)crystal structures are stabilized in different ranges of dipolar interactions,which further promotes the applications of skyrmions as non-volatile information carriers.展开更多
基金supported by the National Natural Science Foundation of China (NSFC) under grant 41774154 and 41504123the Science Foundation of Jiangxi Province under grant 20122BAB21 2002+1 种基金the Nanchang University graduate innovation special fund project under grant CX2017106the Key Industry Innovation Chain of Shaanxi under grant 2018JQ4032
文摘Previous studies suggest that dipolarization fronts (DFs) are 1 to 3RE (RE is the earth radius) wide in the dawn-dusk direction. Recent kinetic simulations have found that DFs may break up into small-scale structures after they are produced by reconnection. Motivated by this simulation, we revisited the scale size of DFs in the dawn-dusk direction by using Cluster observations during the years when the inter-distance among Cluster spacecraft was between 1000 and 2000 km. We selected the DFs that were detected by more than one spacecraft and estimated the radii of these DFs by a simple geometrical analysis, which is based on comparison of DF normals observed by different spacecraft. We found a few DFs that were only a few ion inertial lengths in the dawn-dusk direction. These results point out the importance of multi-scale coupling during the evolution of DFs.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41404133, 41874188, 41574153, 40621003 & 41431071)supported by the project (Grant No. KP19-270)+1 种基金Christine GABRIELSE was supported by NASA (Grant No. NAS5-02099)the support by NASA’s MMS project at Sw RI and NSF (Grant Nos. AGS1602510, NASA NNX16AI39G/80NSSC18K1534, 80NSSC18K0570 & 80NSSC18K0693)
文摘In this paper, the particle acceleration processes around magnetotail dipolarization fronts(DFs) were reviewed. We summarize the spacecraft observations(including Cluster, THEMIS, MMS) and numerical simulations(including MHD, testparticle, hybrid, LSK, PIC) of these processes. Specifically, we(1) introduce the properties of DFs at MHD scale, ion scale, and electron scale,(2) review the properties of suprathermal electrons with particular focus on the pitch-angle distributions,(3)define the particle-acceleration process and distinguish it from the particle-heating process,(4) identify the particle-acceleration process from spacecraft measurements of energy fluxes, and(5) quantify the acceleration efficiency and compare it with other processes in the magnetosphere(e.g., magnetic reconnection and radiation-belt acceleration processes). We focus on both the acceleration of electrons and ions(including light ions and heavy ions). Regarding electron acceleration, we introduce Fermi,betatron, and non-adiabatic acceleration mechanisms;regarding ion acceleration, we present Fermi, betatron, reflection, resonance, and non-adiabatic acceleration mechanisms. We also discuss the unsolved problems and open questions relevant to this topic, and suggest directions for future studies.
基金supported by the National Natural Science Foundation of China(NSFC)(Grant Nos.41174147,41274170 and 41331070)Natural Science Foundation of Jiangxi Province(Grant No.20142BCB23006)
文摘In order to investigate the suprathermal electron flux(>30 ke V) around dipolarization fronts(DFs), we statistically studied the suprathermal electron flux variations and pitch angle distributions of hundreds of earthward propagating DFs observed by THEMIS spacecraft during its tail seasons in years 2008–2009. We focused on the electron flux variations across DFs and electron anisotropies behind DFs. We divided DF into three sectors in the equatorial plane: Dusk, central and dawn sectors. The sectors are defined according to the DF normals with respect to DF's meridian in the equatorial plane(the symmetric line of DF). We found that events with electron flux increases and decreases behind the fronts had no particular dependence on the observation locations. In addition, there was no obvious dependence of electron anisotropy behind DF on the different sectors of DF.
基金supported by National Natural Science Foundation of China(Grant Nos.41174147,41274170,41331070)China Postdoctoral Science Foundation Funded Project,and the Fundamental Research Fund for theCentral Universities(Grant No.2042014kf0017)
文摘We report where and how ions are accelerated in the proximity of earthward propagating dipolarization fronts （DFs） in the magnetotail during a magnetospheric substorm on February 15, 2008. Two DFs were observed by multiple THEMIS space- craft in the near-Earth magnetotail （-10 Re）. We studied the ion dynamics associated with these DFs by comparing observed results with large scale kinetic （LSK） simulation results. The LSK simulation reproduced the sudden ion energy flux enhance- ment concurrent with the arrival of the DF at the satellite locations. We found that ions can be accelerated to more than 100 keV energy at the DF. These ions were initially non-adiabatically accelerated near magnetic reconnection site and then still non-adiabatically accelerated at the DF structure.
基金This work was supported by the pre-research projects on Civil Aerospace Technologies funded by China’s National Space Administration(CNSA)(Grant No.D020103)and the National Natural Science Foundation of China(Grant Nos.41474144,41674176).
文摘It has been confirmed that dipolarization fronts(DFs)are the result of the interchange instability in the Earth's magnetotail.In this paper,we use a Hall MHD model to simulate the evolution of the interchange instability that produces DFs along the leading edge.A test particle simulation is performed to study the physical phenomenon of ion acceleration at the DF.The numerical simulation indicates that almost all particles move earthward and dawnward and then drift to the tail.The DF-reflected ion population at the duskside appears earlier as a consequence of the asymmetric Hall electric field.Ions that are distributed in a dawn-dusk asymmetric semicircle behind the DF tend to be accelerated to higher energies(>13.5 keV).These high-energy particles eventually concentrate in the dawnside.Ions experience effective acceleration by the dawnward electric field,while they drift through the dawn flank at the front,toward the tail.
基金supported by the National Natural Science Foundation of China(Grant No.42388101)the Key Research Program of the Chinese Academy of Sciences(Grant No.ZDBS-SSW-TLC00103)the Key Research Program of the Institute of Geology and Geophysics,Chinese Academy of Sciences(IGGCAS-202102).
文摘Many planets,including the Earth,possess a global dipolar magnetic field.To diagnose the interior source of the dipolar field,researchers usually adopt a dipole model consisting of six parameters to fit the observed dataset of the magnetic field.However,the simultaneous fitting of these parameters often leads to multiple local optimal parameter sets.To address this fitting dilemma,Rong ZJ et al.(2021)recently developed a current loop model.This technique can successively separate and invert the loop parameters.Here,we further show how this technique can be reduced and modified to fit a dipole model.Applications of this reduced technique to the International Geomagnetic Reference Field model and the Martian crustal field model highlight its unique ability to diagnose both the planetary global dipolar field and the local crustal field anomaly,a capability that sets it apart from existing methods.The potential impact of this technique on geomagnetism and planetary magnetism is significant,given its unique ability to diagnose both the planetary global dipolar field and the local crustal field anomaly.
基金supported by the National Natural Science Foundation of China(21874158)the Science and Technology Major Program of Gansu Province of China(22ZD6FA006 and 23ZDFA015)+1 种基金We are also grateful for the financial support from the Science and Technology Program of Henan Province(232102311180)the foundation for the University Young Key Teacher of Henan Province(2024GGJS116).
文摘The multiple oligopeptides have been regarded as promising alignment media due to their structural diverseness and tendency for self-assembly in solution.Herein,an assembled amphiphilic peptide alignment medium,i.e.,C15eCONH-Phg-Phg-IIIKK-CONH2 with un-natural amino acids for the determination of anisotropic parameters of NMR is introduced.The amphiphilic peptide can be self-assembled at low concentrations in DMSO and is stable and highly homogeneous.The NMR spectrum collected with the addition of the medium had fewer background signals.The utility of the acquired RDC data is demon-strated to determine relative configuration of three natural products,Helminthosporic acid,Estrone,and a-Santonin.
基金Vinegar Technologies LLC,Chevron Energy Technology Company,Rice University Consortium for Processes in Porous Media,and the American Chemical Society Petroleum Research Fund(No.ACS PRF 58859-ND6)for their financial support。
文摘The characterization of kerogen nanopores is crucial for predicting the geostorage capacity and recoverability of natural gas in unconventional gas shale reservoirs.Towards this end,a powerful technique is presented which integrates 2D NMR T_(1)-T_(2) relaxation measurements with molecular dynamics(MD)simulations of hydrocarbons confined in the nanopores of kerogen.The integrated NMR-MD technique is demonstrated using T_(1)-T_(2) measurements of kerogen isolates and organic-rich chalks saturated with heptane,together with MD simulations of heptane completely dissolved in a realistic kerogen model.The NMR-MD results are used to extract the swelling ratio and nanopore size distribution of kerogen as a function of depth in the reservoir.The effects of organic nanoconfinement on the T_(1) relaxation dispersion and T_(2) residual dipolar coupling of heptane are investigated,as well as the effect of downhole effective stress on the kerogen nanopore size as a function of depth and compaction.Potential applications in partially depleted gas shale reservoirs are discussed,including CO_(2) utilization/geostorage,geostorage of green H2,and integration of the NMR-MD technique with thermodynamic models for predicting the competitive sorption of gas mixtures in kerogen.
基金supported by the National Natural Science Foundation of China(NSFC)under grants 41731070,41674167,41574161the Strategic Pioneer Program on Space Science,Chinese Academy of Sciences,grants XDA15052500,XDA15350201 and XDA15011401the Specialized Research Fund for State Key Laboratories of China.
文摘With conjunction observations of electromagnetic fields and plasma from Time History of Events and Macroscale Interactions during Substorm(THEMIS)in the near-Earth magnetotail,we investigate the spatial and temporal properties of substorm dipolarizations in the near-Earth plasma sheet(NEPS)during a substorm at 03:23 UT on 12 February 2008.Substorm dipolarizations with different features are detected by three near-Earth THEMIS probes(THA(P5),THD(P3)and THE(P4))in the magnetotail.In the current sheet with a large plasma beta value(β>2,whereβis the ratio of the plasma thermal pressure to the magnetic pressure),the dipolarization within the substorm onset region,(−10.4,2.8,−2.6)RE_gsm,has a large initial magnetic field elevation angle,θ>60°,θ=arctan(Bz/(Bx2+By2)1/2),and is accompanied by energetic ion(tens to hundred keV)dispersionless injection detected by THD(P3).This substorm onset dipolarization is characterized by Bx and By components around 0 nT with significant fluctuations.The Bz component increases sharply and its subsequent magnitude approaches the total magnetic field,Bt.The maximum value of the elevation angle approaches 85°during the later substorm expansion phase.In the NEPS withβ~1,the dipolarization outside the substorm onset region is characterized by a magnetic elevation angle with a small beginning value ofθ<45°and following multi-step enhancements during the substorm expansion phase.The maximum value of the elevation angle approaches to 70°during the later substorm expansion phase.Our observation results indicate that characteristics of dipolarization with a large beginning elevation angle within the substorm onset region provide a new indicator to identify substorm onset location.
基金supported by the State Commission of Development and Reform of ChinaNational Natural Science Foundation of China(Nos.42261134533,11261140326,11405038)。
文摘The Space Plasma Environment Research Facility(SPERF)for ground simulation of the space plasma environment is a key component of the Space Environment Simulation Research Infrastructure(SESRI),a major national science and technology infrastructure for fundamental research.It is designed to investigate outstanding issues in the space plasma environment,such as energetic particle acceleration,transport,and interaction with electromagnetic waves,as well as magnetic reconnection processes,in magnetospheric plasmas.The Tail-Research EXperiment(TREX)is part of the SPERF for laboratory studies of space physics relevant to magnetic reconnection,dipolarization and hydromagnetic wave excitation in the magnetotail.SPERFTREX is designed to carry out three types of experiments:the tail plasmoid for magnetic reconnection,dipolarization front formation,and magnetohydrodynamic waves excited by highspeed plasma jets.In this paper,the scientific goals and three scenarios of SPERF-TREX for typical processes in space plasmas are presented,and experimental plans for SPERF-TREX are also reviewed,together with the plasma sources applied to generate the plasma with the desired parameters and various magnetic configurations.
基金financial support from the French National Research Agency(ANR)[grant number ANR-22-CE06-0031]。
文摘Elastomer blends,among which natural rubber(NR)and butadiene rubber(BR),are involved in many components of the automotive/tire industry.A comprehensive understanding of their mechanical behavior requires,among other features,a detailed description of the crosslink density in these mixtures.In the case of vulcanized immiscible blends,the distribution of the cross-link density within each of the NR-and BR-rich domains is key information,but difficult to determine using the conventional approaches used for one-component crosslinked elastomers.In this study,the vulcanization within NR/BR blends is investigated using a robust^(1)H double-quantum(DQ)MAS recoupling experiment,BaBa-xy16.Two kinds of cross-linked NR/BR blends were considered with two different microstructures for the BR component.The bulk organization of the resulting blends was first probed by analyzing the^(1)H spin-lattice relaxation behavior.In a second step,BaBa-xy16 was used to investigate,in a selective way,the cross-link heterogeneities within NR/BR blends.In particular,for immiscible NR/BR mixtures,the distribution of the cross-link density between both phases was compared and the observed differences were discussed.
基金Project supported by the National Natural Science Foundation of China (Nos. 20490200 and 20176051), and the Project Based Per-sonnel Exchange Program with the China Scholarship Council and the German Academic Exchange Service
文摘Pyrolysis has the potential of transforming waste into recyclable products. Pyrolytic carbon black (PCB) is one of the most important products from the pyrolysis of used tires. Techniques for surface modifications of PCB have been developed. One of the most significant applications for modified PCB is to reinforce the rubber matrix to obtain high added values. The transverse relaxation and the chain dynamics of vulcanized rubber networks with PCB and modified PCB were studied and compared with those of the commercial carbon blacks using selective 1H transverse relaxation (T2) experiments and dipolar correlation effect (DCE) experiments on the stimulated echo. Demineralization and coupling agent modification not only intensified the interactions between the modified PCB and the neighboring polyisoprene chains, but also increased the chemical cross-link density of the vulcanized rubber with modified PCB. The mechanical testing of the rubbers with different kinds of carbon blacks showed that the maximum strain of the rubber with modified PCB was improved greatly. The mechanical testing results confirmed the conclusion obtained by nuclear magnetic resonance (NMR). PCB modified by the demineralization and NDZ-105 titanate coupling agent could be used to replace the commercial semi-reinforcing carbon black.
基金co-supported by National Natural Science Foundation of China(21572164,U1504207)the Sino-German Center for Research Promotion(GZ1289).
文摘The determination of natural products stereochemistry remains a formidable task.Residual dipolar couplings(RDCs)induced by anisotropic media are a powerful tool for determination of the stereochemistry of organic molecule in solution.This review will provide a short introduction on RDCs-based methodology for the structural elucidation of natural products.Special attention is given to the current availability of alignment media in organic solvents.The applications of RDCs for structural analysis of some examples of natural products were discussed and summarized.Graphical Abstract This review provides a short introduction on RDCs-based methodology for the structural elucidation of natural products.Special attention is given to the current availability of alignment media in organic solvents.The applications of RDCs for structural analysis of some examples of natural products were discussed and summarized.
基金supported by the National Natural Science Foundation of China(Grant No.11274039)the National Basic Research Program of China(Grant No.2013CB922002)the Fundamental Research Funds for the Central Universities of China
文摘We study the formation of vortices in a dipolar Bose-Einstein condensate in a synthetic magnetic field by numerically solving the Gross-Pitaevskii equation. The formation process depends on the dipole strength, the rotating frequency, the potential geometry, and the orientation of the dipoles. We make an extensive comparison with vortices created by a rotating trap, especially focusing on the issues of the critical rotating frequency and the vortex number as a function of the rotating frequency. We observe that a higher rotating frequency is needed to generate a large number of vortices and the anisotropic interaction manifests itself as a perceptible difference in the vortex formation. Furthermore, a large dipole strength or aspect ratio also can increase the number of vortices effectively. In particular, we discuss the validity of the Feynman rule.
文摘A series of “H-shaped” organic dimers （azobenzene derivatives） exhibit linear absorption red shift compared with their corresponding monomers experimentally. Dipolar interaction model is not appropriate for the azobenzene derivatives due to the small distance between two “D-π-A” chains. Energy transfer model is suggested for explanation of the absorption red shift. Two necessary conditions for energy transfer were verified. In addition, bi-exponential florescence-delay behavior of the dimer as well as Bella＇s quantum chemistry calculation shows evidence of energy transfer.
基金Project supported by the National Natural Science Foundation of China (Grant No 10875101)the Natural Science Foundation of Fujian Province, China (Grant No 2008J0028)
文摘A modified correlated spectroscopy （COSY） revamped with asymmetric Z-gradient echo detection sequence was designed to investigate the influence of diffusion hehaviour on intermolecular double-quantum coherence signal attenuation during the pre-acquisition period. Theoretical formulas were deduced and experimental measurements and simulations were performed. It is found that the diffusion behaviour of intermolecular double-quantum coherence in the pre-acquisition period may be different from that of conventional single-quantum coherence, depending on the relative orientation of diffusion weighting gradients to coherence selection gradients. When the orientation of the diffusion weighting gradients is parallel or anti-parallel to the orientation of the coherence selection gradients, the diffusion is modulated by the distant dipolar field. This study is helpful for understanding the signal properties in intermolecular double-quantum coherence magnetic resonance imaging.
基金Project supported by the National Natural Science Foundation of China(Grant Nos 20573084 and 10575085)the Nation Science Foundation of Fujian,China(Grant No A0610005)the Program for New Century Excellent Talents in University of Ministry of Education of China
文摘This paper analyses the heteronuclear Cosy Revamped by Asymmetric Z-gradient Echo Detection pulse sequence. General theoretical expressions of the pulse sequence with arbitrary flip angles were derived by using dipolar field treatment and signals originating from heteronuclear intermolecular single-quantum coherences （iSQCs） in highly-polarized two spin-1/2 systems were mainly discussed in order to find the optimal flip angles. The results show that signals from heteronuclear iSQCs decay slower than those from intermolecular double-quantum coherences or intermolecular zero-quantum coherences. Magical angle experiments validate that the signals are from heteronuclear iSQCs and insensitive to the imperfection of radio-frequency flip angles. All experimental observations are in excellent agreement with theoretical predictions. The quantum-mechanical treatment leads to similar predictions to the dipolar field treatment.
文摘The main idea of this paper is to find an analytical formula for the input conductance of an elevated ferrite film circu-lator to match it systematically to the desired matching network. For solving the ferrite loaded dielectric resonator included in stripline elevated ferrite film circulator, the off diagonal components of the permeability tensor are taken as the perturbation. The electromagnetic fields computations are done for unperturbed structure. The dipolar resonant frequencies corresponding to harmonics of the resonant modes are then calculated using the perturbation integrals. The quality factor of the circulator is derived in terms of these dipolar resonant frequencies. Energy integrals are calculated to find the energy stored in the ferrite and dielectic layers. An analytical expression for the input conductance of the elevated ferrite film circulators is derived by using the quality factor and energy integrals. In this expression the ferrite and dielectric layers can have different permittivities. Some discussions about the effect of ferrite film thickness and permittivity mismatch on the bandwidth of the circulator are investigated by HFSS commercial software.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51771124,51571146,and 51701130)。
文摘Tumor-targeted magnetic hyperthermia has recently attracted much attention.Magnetic nanoparticles(NPs) are heat mediator nanoprobes in magnetic hyperthermia for cancer treatment.In this paper,single cubic spinel structural Zn_(0.3)Fe_(2.7)O_(4) magnetic NPs with sizes of 14 nm-20 nm were synthesized,followed by coating with SiO_(2) shell.The SLP value of Zn_(0.3)Fe_(2.7)O_(4)/SiO_(2) NPs below 20 nm changes non-monotonically with the concentration of solution under the alternating current(AC) magnetic field of 430 kHz and 27 kA/m.SLP values of all Zn_(0.3)Fe_(2.7)O_(4)/SiO_(2) NPs appear a peak value with change of solution concentration.The solution concentrations with optimal SLP value decrease with increasing magnetic core size.This work can give guidance to the better prediction and control of the magnetic hyperthermia performance of materials in clinical applications.
基金financially supported by the National Natural Science Foundation of China(No.11774045)the Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science(No.20180510008)。
文摘We report a numerical study on the role of longrange dipolar interaction played on the creation and stabilization of skyrmion-(non)crystal structure in chiral ferromagnetic thin films without any anisotropies,based on a Monte-Carlo simulation method.With the increase of external magnetic field,the microscopic spin configuration is transformed from a spin-spiral stripe or labyrinth structure,depending on the strength of dipolar interaction,into a skyrmion-(non)crystal structure,and then into a skyrmiongas structure,and finally into a ferromagnetic state.Interestingly,with the increase of dipolar interaction,the skyrmion-crystal structure evolves from a triangular arrangement into a square arrangement with the change of skyrmion shape from circle to square.For larger dipolar interactions,the skyrmion-crystal structure loses the regular arrangements and the skyrmions,remaining topological,exhibit different shapes and sizes and squeeze with each other,whose distributions are analogous to a non-crystal structure.Therefore,different skyrmion-(non)crystal structures are stabilized in different ranges of dipolar interactions,which further promotes the applications of skyrmions as non-volatile information carriers.
