Initial success has been achieved in Hong Kong in controlling primary air pollutants,but ambient ozone levels kept increasing during the past three decades.Volatile organic compounds(VOCs)are important for mitigating ...Initial success has been achieved in Hong Kong in controlling primary air pollutants,but ambient ozone levels kept increasing during the past three decades.Volatile organic compounds(VOCs)are important for mitigating ozone pollution as its major precursors.This study analyzed VOC characteristics of roadside,suburban,and rural sites in Hong Kong to investigate their compositions,concentrations,and source contributions.Herewe showthat the TVOC concentrations were 23.05±13.24,12.68±15.36,and 5.16±5.48 ppbv for roadside,suburban,and rural sites between May 2015 to June 2019,respectively.By using Positive Matrix Factorization(PMF)model,six sources were identified at the roadside site over five years:Liquefied petroleum gas(LPG)usage(33%–46%),gasoline evaporation(8%–31%),aged air mass(11%–28%),gasoline exhaust(5%–16%),diesel exhaust(2%–16%)and fuel filling(75–9%).Similarly,six sources were distinguished at the suburban site,including LPG usage(30%–33%),solvent usage(20%–26%),diesel exhaust(14%–26%),gasoline evaporation(8%–16%),aged air mass(4%–11%),and biogenic emissions(2%–5%).At the rural site,four sources were identified,including aged airmass(33%–51%),solvent usage(25%–30%),vehicular emissions(11%–28%),and biogenic emissions(6%–12%).The analysis further revealed that fuel filling and LPG usage were the primary contributors to OFP and OH reactivity at the roadside site,while solvent usage and biogenic emissions accounted for almost half of OFP and OH reactivity at the suburban and rural sites,respectively.These findings highlight the importance of identifying and characterizing VOC sources at different sites to help policymakers develop targeted measures for pollution mitigation in specific areas.展开更多
Furniture is identified as a vital volatile organic compound(VOC)emission source in the indoor environment.Leather has become the most common raw and auxiliary fabric material for upholstered furniture,particularly wi...Furniture is identified as a vital volatile organic compound(VOC)emission source in the indoor environment.Leather has become the most common raw and auxiliary fabric material for upholstered furniture,particularly with extensive consumption in sofas,due to its abundant resources and efficient functions.Despite being widely traded across the world,little research has been conducted on the VOCs released by leathermaterials and their health risk assessment in the indoor environment.Accordingly,this study investigated the VOC emissions of leather with different grades and the health risk of the inhalation exposure.Based on the ultra-fast gas phase electronic nose(EN)and GC-FID/Qtof,the substantial emissions of aliphatic aldehyde ketones(Aks),particularly hexanal,appear to be the cause of off-flavor in medium and low grade(MG and LG)sofa leathers.The health risk assessment indicated that leather materials barely pose non-carcinogenic and carcinogenic effects to residents.Given the abundance of VOC sources and the accumulation of health risks in the indoor environment,more stringent specifications concerning qualitative and quantitative content should be extended to provide VOC treatment basic for the manufacturing industry and obtain better indoor air quality.展开更多
VOCs(Volatile organic compounds)exert a vital role in ozone and secondary organic aerosol production,necessitating investigations into their concentration,chemical characteristics,and source apportionment for the effe...VOCs(Volatile organic compounds)exert a vital role in ozone and secondary organic aerosol production,necessitating investigations into their concentration,chemical characteristics,and source apportionment for the effective implementation of measures aimed at preventing and controlling atmospheric pollution.FromJuly to October 2020,onlinemonitoringwas conducted in the main urban area of Shijiazhuang to collect data on VOCs and analyze their concentrations and reactivity.Additionally,the PMF(positive matrix factorization)method was utilized to identify the VOCs sources.Results indicated that the TVOCs(total VOCs)concentration was(96.7±63.4μg/m^3),with alkanes exhibiting the highest concentration of(36.1±26.4μg/m^3),followed by OVOCs(16.4±14.4μg/m^3).The key active components were alkenes and aromatics,among which xylene,propylene,toluene,propionaldehyde,acetaldehyde,ethylene,and styrene played crucial roles as reactive species.The sources derived from PMF analysis encompassed vehicle emissions,solvent and coating sources,combustion sources,industrial emissions sources,as well as plant sources,the contribution of which were 37.80%,27.93%,16.57%,15.24%,and 2.46%,respectively.Hence,reducing vehicular exhaust emissions and encouraging neighboring industries to adopt low-volatile organic solvents and coatings should be prioritized to mitigate VOCs levels.展开更多
The organic compound composition ofwastewater,serves as a crucial indicator for the operational performance of activated sludge processes and has a major influence on the development of filamentous bulking in activate...The organic compound composition ofwastewater,serves as a crucial indicator for the operational performance of activated sludge processes and has a major influence on the development of filamentous bulking in activated sludge.This study focused on the impact of typical soluble and slowly-biodegradable organic compounds,investigating the pathways through which these substrates affect the occurrence of filamentous bulking in systems operated under both high-and low-oxygen conditions.Results showed that slowly-biodegradable organic compounds lead to a concentrated distribution of microorganisms within flocs,with inward growth of filamentous bacteria.Both Tween-80 and granular starch treated systems exhibited a significant increase in protein content.The glucose system,utilizing soluble substrates,exhibited a markedly higher total polysaccharide content.Microbial communities in the Tween-80 and granular starch treated systems were characterized by a higher abundance of bacteria known to enhance sludge flocculation and settling,such as Competibacter,Xanthomonadaceae and Zoogloea.These findings are of high significance for controlling the operational performance and stability of activated sludge systems,deepening our understanding and providing a novel perspective for the improvement of wastewater treatment processes.展开更多
Ubiquitous contamination of the soil environment with volatile organic compounds(VOCs)has raised considerable concerns.However,there is still limited comprehensive surveying of soil VOCs on a national scale.Herein,65 ...Ubiquitous contamination of the soil environment with volatile organic compounds(VOCs)has raised considerable concerns.However,there is still limited comprehensive surveying of soil VOCs on a national scale.Herein,65 species of VOCswere simultaneously determined in surface soil samples collected from 63 chemical industrial parks(CIPs)across China.The results showed that the total VOC concentrations ranged from 7.15 to 1842 ng/g with a mean concentration of 326 ng/g(median:179 ng/g).Benzene homologs and halogenated hydrocarbons were identified as the dominant contaminant groups.Positive correlations between many VOC species indicated that these compounds probably originated from similar sources.Spatially,the hotspots of VOC pollution were located in eastern and southern China.Soils with higher clay content and a higher fraction of total organic carbon(TOC)content were significantly associated with higher soil VOC concentrations.Precipitation reduces the levels of highly water-soluble substances in surface soils.Both positive matrix factorization(PMF)and principal component analysis-multiple linear regression(PCA-MLR)identified a high proportion of industrial sources(PMF:59.2%and PCA-MLR:66.5%)and traffic emission sources(PMF:32.3%and PCA-MLR:33.5%).PMF,which had a higher R^(2) value(0.7892)than PCA-MLR(0.7683),was the preferred model for quantitative source analysis of soil VOCs.The health risk assessment indicated that the non-carcinogenic and carcinogenic risks of VOCs were at acceptable levels.Overall,this study provides valuable data on the occurrence of VOCs in soil from Chinese CIPs,which is essential for a comprehensive understanding of their environmental behavior.展开更多
To explore the potential utilization of Elaeagnus mollis,we conducted a comprehensive assessment of its phytochemical composition,antioxidant properties,cholinesterase inhibition,and anti-HepG2 cell proliferation acti...To explore the potential utilization of Elaeagnus mollis,we conducted a comprehensive assessment of its phytochemical composition,antioxidant properties,cholinesterase inhibition,and anti-HepG2 cell proliferation activity across different plant parts(branch wood,branch bark,and pericarp)using various solvents(water,methanol,ethanol,and n-hexane).Our findings revealed that water extracts displayed superior antioxidant activities in ABTS and RP assays,while methanol extracts exhibited better performance in DPPH and FRAP assays.Moreover,methanol extracts demonstrated the highest effectiveness against anti-HepG2 cell proliferation,whereas n-hexane extracts showed greater efficiency in cholinesterase inhibition.Notably,branch bark extracts exhibited the highest levels of phytochemical compounds,with both branch bark and pericarp extracts demonstrating significant effects in cholinesterase inhibition and anti-HepG2 cell proliferation.Correlation analysis indicated that phytochemical compounds were primarily responsible for the observed biological activities.Overall,extracts from the branch bark and pericarp of E.mollis showed promising potential for antioxidant and anticancer activities,suggesting their suitability for applications in the pharmaceutical industry as health-promoting products.展开更多
Peptic ulcer(PU)is characterized by inflammation,necrosis,and erosion of the gastrointestinal mucosa caused by various pathogenic factors,leading to ulcer formation.The stomach and duodenum are the most commonly affec...Peptic ulcer(PU)is characterized by inflammation,necrosis,and erosion of the gastrointestinal mucosa caused by various pathogenic factors,leading to ulcer formation.The stomach and duodenum are the most commonly affected sites.Bletilla striata,a traditional Chinese medicinal herb,contains diverse chemical constituents and exhibits multiple pharmacological effects.As a key component in various traditional Chinese medicine compound formulations,it has demonstrated notable clinical efficacy.Moreover,it has a solid research foundation and broad application prospects in the treatment of gastrointestinal diseases.This paper systematically elaborates on the clinical efficacy and mechanisms of action of Bletilla striata in the treatment of PUs,drawing from ancient medical literature and traditional formula applications to provide support for clinical use.展开更多
Due to its synergistic effects and reduced side effects,combination therapy has become an important strategy for treating complex diseases.In traditional Chinese medicine(TCM),the“monarch,minister,assistant,envoy”co...Due to its synergistic effects and reduced side effects,combination therapy has become an important strategy for treating complex diseases.In traditional Chinese medicine(TCM),the“monarch,minister,assistant,envoy”compatibilities theory provides a systematic framework for drug compatibility and has guided the formation of a large number of classic formulas.However,due to the complex compositions and diverse mechanisms of action of TCM,it is difficult to comprehensively reveal its potential synergistic patterns using traditional methods.Synergistic prediction based on molecular compatibility theory provides new ideas for identifying combinations of active compounds in TCM.Compared to resource-intensive traditional experimental methods,artificial intelligence possesses the ability to mine synergistic patterns from multi-omics and structural data,providing an efficient means for modeling and optimizing TCM combinations.This paper systematically reviews the application progress of AI in the synergistic prediction of TCM active compounds and explores the challenges and prospects of its application in modeling combination relationships,thereby contributing to the modernization of TCM theory and methodological innovation.展开更多
Emission characteristics of biogenic volatile organic compounds(BVOCs)from dominant tree species in the subtropical pristine forests of China are extremely limited.Here we conducted in situ field measurements of BVOCs...Emission characteristics of biogenic volatile organic compounds(BVOCs)from dominant tree species in the subtropical pristine forests of China are extremely limited.Here we conducted in situ field measurements of BVOCs emissions from representative mature evergreen trees by using dynamic branch enclosures at four altitude gradients(600-1690ma.s.l.)in the Nanling Mountains of southern China.Composition characteristics as well as seasonal and altitudinal variations were analyzed.Standardized emission rates and canopyscale emission factors were then calculated.Results showed that BVOCs emission intensities in the wet season were generally higher than those in the dry season.Monoterpenes were the dominant BVOCs emitted from most broad-leaved trees,accounting for over 70%of the total.Schima superba,Yushania basihirsuta and Altingia chinensis had relatively high emission intensities and secondary pollutant formation potentials.The localized emission factors of isoprene were comparable to the defaults in the Model of Emissions of Gases and Aerosols fromNature(MEGAN),while emission factors of monoterpenes and sesquiterpenes were 2 to 58 times of those in the model.Our results can be used to update the current BVOCs emission inventory in MEGAN,thereby reducing the uncertainties of BVOCs emission estimations in forested regions of southern China.展开更多
Visible-light-mediated O-H functionalization reactions of alcohols with diazo compounds have been fully developed in recent years.However,alkenyl and acetylenic alcohols were rarely examined in these reactions due to ...Visible-light-mediated O-H functionalization reactions of alcohols with diazo compounds have been fully developed in recent years.However,alkenyl and acetylenic alcohols were rarely examined in these reactions due to the inevitable side reactions involving cycloaddition.Herein,the visible-light-mediated O-H functionalization reactions of alkenyl alcohols with diazo compounds were developed.This process competed favorably with the cycloaddition reaction.A series of multifunctional ethers were provided in low to high yields with aryldiazoacetates or 3-diazooxindoles.Biologically relevant spirooxindole-fused oxacycle could be easily accessed from the O-H functionalization product of alkenyl alcohol and 3-diazooxindole.展开更多
The Rh(III)-catalyzed C—H functionalization of sulfoxonium ylides and successively annulation with two classes of cyclic diazo compounds has been realized,affording structurally diverse fused-ring or spirocyclic comp...The Rh(III)-catalyzed C—H functionalization of sulfoxonium ylides and successively annulation with two classes of cyclic diazo compounds has been realized,affording structurally diverse fused-ring or spirocyclic compounds under redoxneutral conditions.The reaction proceeds via successive chelation-assisted C—H activation,carbene insertion,and intramolecular[3+3]/[4+1]annulation processes.展开更多
Employing the principle of active moiety concatenation, a novel series of symmetrical triazine compounds were designed. A series of novel triazine compounds were synthesized using cyanuric chloride, amines, and chalco...Employing the principle of active moiety concatenation, a novel series of symmetrical triazine compounds were designed. A series of novel triazine compounds were synthesized using cyanuric chloride, amines, and chalcones as the initial reactants. The structures of these compounds were characterized through FT-IR, 1H-NMR, 13C-NMR, high-resolution mass spectrometry (HRMS) and high performance liquid chromatography (HPLC). 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetra- zolium bromide (MTT) assay was employed to evaluate the in vitro anti-proliferative activity of the new s-triazine compounds against human lung cancer cells (A549), human cervical cancer cells (HeLa), human breast cancer cells (MCF-7) and human colon cancer cells (SW620). The findings indicated that several compounds exhibited promising antitumor effects. Notably, (E)-1-(4-((4,6-dimorpholino-1,3,5-triazin-2-yl)oxy)phenyl)-3-(thiophen-2-yl)prop-2-en-1-one (3bg) demonstrated efficacy as a broad-spectrum anticancer agent, exhibiting significant activity against the A549, HeLa, and MCF-7 cell lines. Furthermore, (E)-1-(4-((4,6-dimorpholino-1,3,5-triazin-2-yl)oxy)phenyl)-3-phenylprop-2-en-1-one (3bb) displayed the most potent in vitro antitumor activity against the MCF-7 cell line with an IC_(50) value of 16.4 μmol/L, establishing it as the most active compound in assay.展开更多
Direct enantioselective allylic C—H functionalization has emerged as a powerful strategy for the asymmetric syn-thesis of highly valuable chiral products.Herein,a Rh(III)-catalyzed enantioselective allylic C—H alkyl...Direct enantioselective allylic C—H functionalization has emerged as a powerful strategy for the asymmetric syn-thesis of highly valuable chiral products.Herein,a Rh(III)-catalyzed enantioselective allylic C—H alkylation of unactivated alkenes withα-diazo carbonyl compounds is described,enabling direct access to chiral products with high efficiency(up to 77%yield,92%ee,and>10∶1 B/L(branched/linear)selectivity).This atom-and step-economical protocol directly converts simple,unactivated substrates into valuable enantioenriched products under mild conditions,providing an efficient catalytic system for asymmetric allylic C—H functionalization.展开更多
Nitrogen-containing organic compounds(NOCs)may potentially contribute to aqueous secondary organic aerosols,yet the different formation of NOCs in aerosol particles and cloud droplets remains unclear.With the in-situ ...Nitrogen-containing organic compounds(NOCs)may potentially contribute to aqueous secondary organic aerosols,yet the different formation of NOCs in aerosol particles and cloud droplets remains unclear.With the in-situ measurements performed at a mountain site(1690 m a.s.l.)in southern China,we investigated the formation of NOCs in the cloud droplets and the cloud-free particles,based on their mixing state information of NOCscontaining particles by single particle mass spectrometry.The relative abundance of NOCs in the cloud-free particles was significantly higher than those in cloud residual(cloud RES)particles.NOCs were highly correlated with carbonyl compounds(including glyoxalate and methylglyoxal)in the cloud-free particles,however,limited correlation was observed for cloud RES particles.Analysis of their mixing state and temporal variations highlights that NOCs was mainly formed from the carbonyl compounds and ammonium in the cloud-free particles,rather than in the cloud RES particles.The results support that the formation of NOCs from carbonyl compounds is facilitated in concentrated solutions in wet aerosols,rather than cloud droplets.In addition,we have identified the transport of biomass burning particles that facilitate the formation of NOCs,and that the observed NOCs is most likely contributed to the light absorption.These findings have implications for the evaluation of NOCs formation and their contribution to light absorption.展开更多
This research was carried out to identify the most effective plant species for air purification based on environmental factors. The existence of plants beside roadways can be considered a more efficient approach to im...This research was carried out to identify the most effective plant species for air purification based on environmental factors. The existence of plants beside roadways can be considered a more efficient approach to improving air quality and minimizing pollution exposure. The samples for this research were collected from various sites across the streets of Jeddah governorate. The primary sources of air pollution in the research area are vehicle traffic and emissions from cars. Eight species were gathered from various streets in Jeddah governorate, namely, Azadirachta indica, Senna sulfurea, Ziziphus spina-christi, Cordia sebestena, Tecoma stans, Bougainvillea spectabilis, Conocarpus lancifolius, and Ixora coccinea. The leaves of the studied plants were analyzed for secondary compounds using Gas chromatography-mass spectrometry (GC-MS) techniques. Gas-chromatographic analyses revealed that bis (2-ethylhexyl) phthalate was found in every plant. Bis-(2-ethylhexyl) phthalate, a widespread environmental pollutant. Moreover, Cordia sebestena was the sole plant that contained Phenol, 2,2’-methylenebis [6-(1,1-dimethylethyl)-4-methyl] which is part of the phenols category. Environmental conditions can affect the production of secondary metabolites. By tracking the concentrations of these substances, researchers can evaluate the well-being of ecosystems and identify pollution.展开更多
Selenium(Se),an essential micronutrient among the 15 vital elements required for human physiology,exerts its biological functions primarily through its incorporation into selenoproteins.To date,approximately 25 seleno...Selenium(Se),an essential micronutrient among the 15 vital elements required for human physiology,exerts its biological functions primarily through its incorporation into selenoproteins.To date,approximately 25 selenoproteins have been characterized in mammalian systems,including glutathione peroxidase(GPX),thioredoxin reductase(TrxR),and iodothyronine deiodinases(DIOs),all of which exhibit indispensable physiological functions.展开更多
Chrysanthemum is rich in active compounds such as flavonoids and phenolic acids,and its dried head flowers are commonly used for tea and medicinal purposes.However,the genetic determinism underlying chrysanthemum acti...Chrysanthemum is rich in active compounds such as flavonoids and phenolic acids,and its dried head flowers are commonly used for tea and medicinal purposes.However,the genetic determinism underlying chrysanthemum active compounds remains elusive.In this study,we evaluated a panel of 137 chrysanthemum accessions for total flavonoids,chlorogenic acid,luteolin,and isochlorogenic acid A across two consecutive years.The four active compounds exhibited considerable variation,with a coefficient of variation ranging from 44.96%to 76.30%.Significant differences were observed in genotype and environments,and the broad-sense heritability was estimated at 0.5e0.63 for all examined traits.Significant pair-wise correlation was found between the four active compounds.Several accessions showing the highest active compounds were figured out for breeding use by integrating the membership function and hierarchical cluster analysis methods.Based on the 327042 high-quality SNPs,a genome-wide association study(GWAS)captured 59 significant SNPs for the four active compounds,of which 24 elite alleles exhibited pyramiding effects.A total of 18 potential candidate genes were mined,among which evm.model.scaffold_1149.273(QUA1)has one linkage disequilibrium(LD)block corresponding to Hap4 with the highest luteolin content.The findings are beneficial to understanding the genetic basis of the active compounds and provide parental materials and valuable markers for the genetic improvement of active compounds in chrysanthemums.展开更多
Bisphenol compounds(BPs)have various industrial uses and can enter the environment through various sources.To evaluate the ecotoxicity of BPs and identify potential gene candidates involved in the plant toxicity,Arabi...Bisphenol compounds(BPs)have various industrial uses and can enter the environment through various sources.To evaluate the ecotoxicity of BPs and identify potential gene candidates involved in the plant toxicity,Arabidopsis thaliana was exposed to bisphenol A(BPA),BPB,BPE,BPF,and BPS at 1,3,10 mg/L for a duration of 14 days,and their growth status were monitored.At day 14,roots and leaves were collected for internal BPs exposure concentration detection,RNA-seq(only roots),and morphological observations.As shown in the results,exposure to BPs significantly disturbed root elongation,exhibiting a trend of stimulation at low concentration and inhibition at high concentration.Additionally,BPs exhibited pronounced generation of reactive oxygen species,while none of the pollutants caused significant changes in root morphology.Internal exposure concentration analysis indicated that BPs tended to accumulate in the roots,with BPS exhibiting the highest level of accumulation.The results of RNA-seq indicated that the shared 211 differently expressed genes(DEGs)of these 5 exposure groups were enriched in defense response,generation of precursormetabolites,response to organic substance,response to oxygen-containing,response to hormone,oxidation-reduction process and so on.Regarding unique DEGs in each group,BPS wasmainly associated with the redox pathway,BPB primarily influenced seed germination,and BPA,BPE and BPF were primarily involved in metabolic signaling pathways.Our results provide newinsights for BPs induced adverse effects on Arabidopsis thaliana and suggest that the ecological risks associated with BPA alternatives cannot be ignored.展开更多
Atmospheric dimethyl sulfide(DMS,CH_(3)SCH_(3))and methanethiol(MeSH,CH_(3)SH)have been widely studied and recognized to significantly constrain the atmospheric sulfur budget.Nevertheless,while the role of DMS and MeS...Atmospheric dimethyl sulfide(DMS,CH_(3)SCH_(3))and methanethiol(MeSH,CH_(3)SH)have been widely studied and recognized to significantly constrain the atmospheric sulfur budget.Nevertheless,while the role of DMS and MeSH remains largely uncertain in inland regions,learning about dimethyl disulfide(DMDS,CH_(3)SSCH_(3))is also limited.In this study,we measured atmospheric DMS,MeSH and DMDS in winter,from 19 December 2022 to 30 January 2023,and spring,from 24 April to 2 June 2023 with a Vocus proton-transfer-reaction time-offlightmass spectrometer(Vocus PTR-TOF)at the Dianshan Lake(DSL)Air QualityMonitoring Supersite in a suburban area of Shanghai,China.The mixing ratios of DMS,MeSH and DMDS exhibited clear diurnal cycles,and were characterized by average and interquartile range values of 22.6(10.1-29.7),14.9(6.5-19.4)and 9.8(6.0-10.7)pptv,respectively,in the spring campaign,which are approximately twice as high as those in winter.MeSH and DMDS were found to be well correlated with DMS in the two campaigns.Wind analysis suggests that three reduced-sulfur compounds owned common sources from the DSL.Furthermore,the sulfur dioxide(SO_(2))production quantity fromthe three reduced-sulfur compounds over the DSL inMay 2023 was estimated to be 1.42±0.74 t with 84.8%originating fromDMDS,which was comparable to the monthly SO_(2) emissions fromships over the DSL.Our results highlight the prominent role of atmospheric DMDS in SO_(2) production when compared to DMS and MeSH in the suburban area of Shanghai,soliciting further investigation and consideration of DMDS in the sulfur budget.展开更多
Roasting is important for improving the content of bioactive compounds and enhancing the flavor of flaxseed oil.However,the effect of roasting time on germinated flaxseed oil(GFO)is unclear.Herein,the influence of roa...Roasting is important for improving the content of bioactive compounds and enhancing the flavor of flaxseed oil.However,the effect of roasting time on germinated flaxseed oil(GFO)is unclear.Herein,the influence of roasting time(0–50 min)at a specific temperature of 160?C on the physicochemical properties,bioactive compounds,antioxidant capacity,and volatile compounds of GFO from three flaxseed varieties was examined.An extension in roasting time increased the a^(*)value of GFO,while the L^(*)and b^(*)values of GFO decreased.Higher chlorophylls(1.63±0.01–2.18±0.01 mg/kg),carotenoids(2.25±0.00–2.69±0.02 mg/kg),total phenolic content(156.75±2.93–200.03±6.29 mg GAE/kg),phytosterol(1801.93±30.64–1965.23±13.71 mg GAE/kg)and DPPH(320.11±18.22–432.19±14.95μmol TE/kg)and ABTS radical scavenging activity(810.68±16.29–1119.01±14.25μmol TE/kg)were detected in GFO after roasting for 20–30 min.However,the total tocopherol and unsaturated fatty acid content declined,and the composition of fatty acids changed insignificantly(P>0.05).GC–MS recognized 68 volatile compounds in GFO,in which pyrazine imparted a nutty flavor to the GFO.This study provides important information for the development of high-quality GFO.展开更多
基金supported by Hong Kong Environment Protection Department(Quotation Ref.18-06532)Hong Kong Innovation and Technology Fund(ITS/193/20FP)Hong Kong Research Grants Council(No.26304921).
文摘Initial success has been achieved in Hong Kong in controlling primary air pollutants,but ambient ozone levels kept increasing during the past three decades.Volatile organic compounds(VOCs)are important for mitigating ozone pollution as its major precursors.This study analyzed VOC characteristics of roadside,suburban,and rural sites in Hong Kong to investigate their compositions,concentrations,and source contributions.Herewe showthat the TVOC concentrations were 23.05±13.24,12.68±15.36,and 5.16±5.48 ppbv for roadside,suburban,and rural sites between May 2015 to June 2019,respectively.By using Positive Matrix Factorization(PMF)model,six sources were identified at the roadside site over five years:Liquefied petroleum gas(LPG)usage(33%–46%),gasoline evaporation(8%–31%),aged air mass(11%–28%),gasoline exhaust(5%–16%),diesel exhaust(2%–16%)and fuel filling(75–9%).Similarly,six sources were distinguished at the suburban site,including LPG usage(30%–33%),solvent usage(20%–26%),diesel exhaust(14%–26%),gasoline evaporation(8%–16%),aged air mass(4%–11%),and biogenic emissions(2%–5%).At the rural site,four sources were identified,including aged airmass(33%–51%),solvent usage(25%–30%),vehicular emissions(11%–28%),and biogenic emissions(6%–12%).The analysis further revealed that fuel filling and LPG usage were the primary contributors to OFP and OH reactivity at the roadside site,while solvent usage and biogenic emissions accounted for almost half of OFP and OH reactivity at the suburban and rural sites,respectively.These findings highlight the importance of identifying and characterizing VOC sources at different sites to help policymakers develop targeted measures for pollution mitigation in specific areas.
基金supported by the National Key Research and Development Program of China (No.2019YFC1904501).
文摘Furniture is identified as a vital volatile organic compound(VOC)emission source in the indoor environment.Leather has become the most common raw and auxiliary fabric material for upholstered furniture,particularly with extensive consumption in sofas,due to its abundant resources and efficient functions.Despite being widely traded across the world,little research has been conducted on the VOCs released by leathermaterials and their health risk assessment in the indoor environment.Accordingly,this study investigated the VOC emissions of leather with different grades and the health risk of the inhalation exposure.Based on the ultra-fast gas phase electronic nose(EN)and GC-FID/Qtof,the substantial emissions of aliphatic aldehyde ketones(Aks),particularly hexanal,appear to be the cause of off-flavor in medium and low grade(MG and LG)sofa leathers.The health risk assessment indicated that leather materials barely pose non-carcinogenic and carcinogenic effects to residents.Given the abundance of VOC sources and the accumulation of health risks in the indoor environment,more stringent specifications concerning qualitative and quantitative content should be extended to provide VOC treatment basic for the manufacturing industry and obtain better indoor air quality.
基金supported by the Natural Science Foundation of Hebei Province(Nos.D2019106042,D2020304038,and D2021106002)the National Natural Science Foundation of China(No.22276099)+1 种基金the State Environmental Protection Key Laboratory of Formation and Prevention of Urban Air Pollution Complex(No.2021080544)the Environmental Monitoring Research Foundation of Jiangsu Province(No.2211).
文摘VOCs(Volatile organic compounds)exert a vital role in ozone and secondary organic aerosol production,necessitating investigations into their concentration,chemical characteristics,and source apportionment for the effective implementation of measures aimed at preventing and controlling atmospheric pollution.FromJuly to October 2020,onlinemonitoringwas conducted in the main urban area of Shijiazhuang to collect data on VOCs and analyze their concentrations and reactivity.Additionally,the PMF(positive matrix factorization)method was utilized to identify the VOCs sources.Results indicated that the TVOCs(total VOCs)concentration was(96.7±63.4μg/m^3),with alkanes exhibiting the highest concentration of(36.1±26.4μg/m^3),followed by OVOCs(16.4±14.4μg/m^3).The key active components were alkenes and aromatics,among which xylene,propylene,toluene,propionaldehyde,acetaldehyde,ethylene,and styrene played crucial roles as reactive species.The sources derived from PMF analysis encompassed vehicle emissions,solvent and coating sources,combustion sources,industrial emissions sources,as well as plant sources,the contribution of which were 37.80%,27.93%,16.57%,15.24%,and 2.46%,respectively.Hence,reducing vehicular exhaust emissions and encouraging neighboring industries to adopt low-volatile organic solvents and coatings should be prioritized to mitigate VOCs levels.
基金supported by the Opening Project of National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology,and the National Natural Science Foundation of China(No.52270017).
文摘The organic compound composition ofwastewater,serves as a crucial indicator for the operational performance of activated sludge processes and has a major influence on the development of filamentous bulking in activated sludge.This study focused on the impact of typical soluble and slowly-biodegradable organic compounds,investigating the pathways through which these substrates affect the occurrence of filamentous bulking in systems operated under both high-and low-oxygen conditions.Results showed that slowly-biodegradable organic compounds lead to a concentrated distribution of microorganisms within flocs,with inward growth of filamentous bacteria.Both Tween-80 and granular starch treated systems exhibited a significant increase in protein content.The glucose system,utilizing soluble substrates,exhibited a markedly higher total polysaccharide content.Microbial communities in the Tween-80 and granular starch treated systems were characterized by a higher abundance of bacteria known to enhance sludge flocculation and settling,such as Competibacter,Xanthomonadaceae and Zoogloea.These findings are of high significance for controlling the operational performance and stability of activated sludge systems,deepening our understanding and providing a novel perspective for the improvement of wastewater treatment processes.
基金supported by the Medical and Health Projects in Zhejiang Province(No.2022PY049)the Basic Scientific Research Project of Hangzhou Medical College(No.YS2021006)Key Discipline of Zhejiang Province in Public Health and Preventive Medicine(First Class,Category A),Hangzhou Medical College.
文摘Ubiquitous contamination of the soil environment with volatile organic compounds(VOCs)has raised considerable concerns.However,there is still limited comprehensive surveying of soil VOCs on a national scale.Herein,65 species of VOCswere simultaneously determined in surface soil samples collected from 63 chemical industrial parks(CIPs)across China.The results showed that the total VOC concentrations ranged from 7.15 to 1842 ng/g with a mean concentration of 326 ng/g(median:179 ng/g).Benzene homologs and halogenated hydrocarbons were identified as the dominant contaminant groups.Positive correlations between many VOC species indicated that these compounds probably originated from similar sources.Spatially,the hotspots of VOC pollution were located in eastern and southern China.Soils with higher clay content and a higher fraction of total organic carbon(TOC)content were significantly associated with higher soil VOC concentrations.Precipitation reduces the levels of highly water-soluble substances in surface soils.Both positive matrix factorization(PMF)and principal component analysis-multiple linear regression(PCA-MLR)identified a high proportion of industrial sources(PMF:59.2%and PCA-MLR:66.5%)and traffic emission sources(PMF:32.3%and PCA-MLR:33.5%).PMF,which had a higher R^(2) value(0.7892)than PCA-MLR(0.7683),was the preferred model for quantitative source analysis of soil VOCs.The health risk assessment indicated that the non-carcinogenic and carcinogenic risks of VOCs were at acceptable levels.Overall,this study provides valuable data on the occurrence of VOCs in soil from Chinese CIPs,which is essential for a comprehensive understanding of their environmental behavior.
基金National Natural Science Foundation of China(Grant No.31600549).
文摘To explore the potential utilization of Elaeagnus mollis,we conducted a comprehensive assessment of its phytochemical composition,antioxidant properties,cholinesterase inhibition,and anti-HepG2 cell proliferation activity across different plant parts(branch wood,branch bark,and pericarp)using various solvents(water,methanol,ethanol,and n-hexane).Our findings revealed that water extracts displayed superior antioxidant activities in ABTS and RP assays,while methanol extracts exhibited better performance in DPPH and FRAP assays.Moreover,methanol extracts demonstrated the highest effectiveness against anti-HepG2 cell proliferation,whereas n-hexane extracts showed greater efficiency in cholinesterase inhibition.Notably,branch bark extracts exhibited the highest levels of phytochemical compounds,with both branch bark and pericarp extracts demonstrating significant effects in cholinesterase inhibition and anti-HepG2 cell proliferation.Correlation analysis indicated that phytochemical compounds were primarily responsible for the observed biological activities.Overall,extracts from the branch bark and pericarp of E.mollis showed promising potential for antioxidant and anticancer activities,suggesting their suitability for applications in the pharmaceutical industry as health-promoting products.
基金Supported by National Science and Technology Major Project,No.2024ZD0521002The Innovation Team Project of Traditional Chinese Medicine of Liaoning Province,No.LNZYYCXTD-CCCX-003+1 种基金General Program of the National Natural Science Foundation of China,No.82074296Construction Project of Inheritance Studios of Famous Chinese Medicine Experts in China,No.[2022]No.75.
文摘Peptic ulcer(PU)is characterized by inflammation,necrosis,and erosion of the gastrointestinal mucosa caused by various pathogenic factors,leading to ulcer formation.The stomach and duodenum are the most commonly affected sites.Bletilla striata,a traditional Chinese medicinal herb,contains diverse chemical constituents and exhibits multiple pharmacological effects.As a key component in various traditional Chinese medicine compound formulations,it has demonstrated notable clinical efficacy.Moreover,it has a solid research foundation and broad application prospects in the treatment of gastrointestinal diseases.This paper systematically elaborates on the clinical efficacy and mechanisms of action of Bletilla striata in the treatment of PUs,drawing from ancient medical literature and traditional formula applications to provide support for clinical use.
基金supported by the National Key Research and Development Program of China(No.2024YFC3506900)Science and Technology Program of Tianjin(No.24ZXZSSS00460)Special Project for Technological Innovation in New Productive Forces of Modern Chinese Medicines(No.24ZXZKSY00010)。
文摘Due to its synergistic effects and reduced side effects,combination therapy has become an important strategy for treating complex diseases.In traditional Chinese medicine(TCM),the“monarch,minister,assistant,envoy”compatibilities theory provides a systematic framework for drug compatibility and has guided the formation of a large number of classic formulas.However,due to the complex compositions and diverse mechanisms of action of TCM,it is difficult to comprehensively reveal its potential synergistic patterns using traditional methods.Synergistic prediction based on molecular compatibility theory provides new ideas for identifying combinations of active compounds in TCM.Compared to resource-intensive traditional experimental methods,artificial intelligence possesses the ability to mine synergistic patterns from multi-omics and structural data,providing an efficient means for modeling and optimizing TCM combinations.This paper systematically reviews the application progress of AI in the synergistic prediction of TCM active compounds and explores the challenges and prospects of its application in modeling combination relationships,thereby contributing to the modernization of TCM theory and methodological innovation.
基金supported by the National Natural Science Foundation of China (NSFC)Projects (Nos.42205105,42121004,and 42077190)the Science and Technology Project of Shaoguan (No.210811164532141)+3 种基金the National Key R&D Program of China (2022YFC3700604)the Science and Technology Program of Guangzhou City (No.202201010400)the Fundamental Research Funds for the Central Universities (No.21622319)the Research Center of Low Carbon Economy for Guangzhou Region (No.22JNZS50).
文摘Emission characteristics of biogenic volatile organic compounds(BVOCs)from dominant tree species in the subtropical pristine forests of China are extremely limited.Here we conducted in situ field measurements of BVOCs emissions from representative mature evergreen trees by using dynamic branch enclosures at four altitude gradients(600-1690ma.s.l.)in the Nanling Mountains of southern China.Composition characteristics as well as seasonal and altitudinal variations were analyzed.Standardized emission rates and canopyscale emission factors were then calculated.Results showed that BVOCs emission intensities in the wet season were generally higher than those in the dry season.Monoterpenes were the dominant BVOCs emitted from most broad-leaved trees,accounting for over 70%of the total.Schima superba,Yushania basihirsuta and Altingia chinensis had relatively high emission intensities and secondary pollutant formation potentials.The localized emission factors of isoprene were comparable to the defaults in the Model of Emissions of Gases and Aerosols fromNature(MEGAN),while emission factors of monoterpenes and sesquiterpenes were 2 to 58 times of those in the model.Our results can be used to update the current BVOCs emission inventory in MEGAN,thereby reducing the uncertainties of BVOCs emission estimations in forested regions of southern China.
文摘Visible-light-mediated O-H functionalization reactions of alcohols with diazo compounds have been fully developed in recent years.However,alkenyl and acetylenic alcohols were rarely examined in these reactions due to the inevitable side reactions involving cycloaddition.Herein,the visible-light-mediated O-H functionalization reactions of alkenyl alcohols with diazo compounds were developed.This process competed favorably with the cycloaddition reaction.A series of multifunctional ethers were provided in low to high yields with aryldiazoacetates or 3-diazooxindoles.Biologically relevant spirooxindole-fused oxacycle could be easily accessed from the O-H functionalization product of alkenyl alcohol and 3-diazooxindole.
文摘The Rh(III)-catalyzed C—H functionalization of sulfoxonium ylides and successively annulation with two classes of cyclic diazo compounds has been realized,affording structurally diverse fused-ring or spirocyclic compounds under redoxneutral conditions.The reaction proceeds via successive chelation-assisted C—H activation,carbene insertion,and intramolecular[3+3]/[4+1]annulation processes.
文摘Employing the principle of active moiety concatenation, a novel series of symmetrical triazine compounds were designed. A series of novel triazine compounds were synthesized using cyanuric chloride, amines, and chalcones as the initial reactants. The structures of these compounds were characterized through FT-IR, 1H-NMR, 13C-NMR, high-resolution mass spectrometry (HRMS) and high performance liquid chromatography (HPLC). 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetra- zolium bromide (MTT) assay was employed to evaluate the in vitro anti-proliferative activity of the new s-triazine compounds against human lung cancer cells (A549), human cervical cancer cells (HeLa), human breast cancer cells (MCF-7) and human colon cancer cells (SW620). The findings indicated that several compounds exhibited promising antitumor effects. Notably, (E)-1-(4-((4,6-dimorpholino-1,3,5-triazin-2-yl)oxy)phenyl)-3-(thiophen-2-yl)prop-2-en-1-one (3bg) demonstrated efficacy as a broad-spectrum anticancer agent, exhibiting significant activity against the A549, HeLa, and MCF-7 cell lines. Furthermore, (E)-1-(4-((4,6-dimorpholino-1,3,5-triazin-2-yl)oxy)phenyl)-3-phenylprop-2-en-1-one (3bb) displayed the most potent in vitro antitumor activity against the MCF-7 cell line with an IC_(50) value of 16.4 μmol/L, establishing it as the most active compound in assay.
文摘Direct enantioselective allylic C—H functionalization has emerged as a powerful strategy for the asymmetric syn-thesis of highly valuable chiral products.Herein,a Rh(III)-catalyzed enantioselective allylic C—H alkylation of unactivated alkenes withα-diazo carbonyl compounds is described,enabling direct access to chiral products with high efficiency(up to 77%yield,92%ee,and>10∶1 B/L(branched/linear)selectivity).This atom-and step-economical protocol directly converts simple,unactivated substrates into valuable enantioenriched products under mild conditions,providing an efficient catalytic system for asymmetric allylic C—H functionalization.
基金supported by the National Key Research and Development Program of China(No.2022YFC3701103)the National Natural Science Foundation of China(No.42222705)+1 种基金the Youth Innovation Promotion Association CAS(No.2021354)Guangdong Foundation for Program of Science and Technology Research(No.2023B1212060049).
文摘Nitrogen-containing organic compounds(NOCs)may potentially contribute to aqueous secondary organic aerosols,yet the different formation of NOCs in aerosol particles and cloud droplets remains unclear.With the in-situ measurements performed at a mountain site(1690 m a.s.l.)in southern China,we investigated the formation of NOCs in the cloud droplets and the cloud-free particles,based on their mixing state information of NOCscontaining particles by single particle mass spectrometry.The relative abundance of NOCs in the cloud-free particles was significantly higher than those in cloud residual(cloud RES)particles.NOCs were highly correlated with carbonyl compounds(including glyoxalate and methylglyoxal)in the cloud-free particles,however,limited correlation was observed for cloud RES particles.Analysis of their mixing state and temporal variations highlights that NOCs was mainly formed from the carbonyl compounds and ammonium in the cloud-free particles,rather than in the cloud RES particles.The results support that the formation of NOCs from carbonyl compounds is facilitated in concentrated solutions in wet aerosols,rather than cloud droplets.In addition,we have identified the transport of biomass burning particles that facilitate the formation of NOCs,and that the observed NOCs is most likely contributed to the light absorption.These findings have implications for the evaluation of NOCs formation and their contribution to light absorption.
文摘This research was carried out to identify the most effective plant species for air purification based on environmental factors. The existence of plants beside roadways can be considered a more efficient approach to improving air quality and minimizing pollution exposure. The samples for this research were collected from various sites across the streets of Jeddah governorate. The primary sources of air pollution in the research area are vehicle traffic and emissions from cars. Eight species were gathered from various streets in Jeddah governorate, namely, Azadirachta indica, Senna sulfurea, Ziziphus spina-christi, Cordia sebestena, Tecoma stans, Bougainvillea spectabilis, Conocarpus lancifolius, and Ixora coccinea. The leaves of the studied plants were analyzed for secondary compounds using Gas chromatography-mass spectrometry (GC-MS) techniques. Gas-chromatographic analyses revealed that bis (2-ethylhexyl) phthalate was found in every plant. Bis-(2-ethylhexyl) phthalate, a widespread environmental pollutant. Moreover, Cordia sebestena was the sole plant that contained Phenol, 2,2’-methylenebis [6-(1,1-dimethylethyl)-4-methyl] which is part of the phenols category. Environmental conditions can affect the production of secondary metabolites. By tracking the concentrations of these substances, researchers can evaluate the well-being of ecosystems and identify pollution.
基金Financial support from the Science and Technology Innovation Program of Hunan Province(No.2022RC4044)。
文摘Selenium(Se),an essential micronutrient among the 15 vital elements required for human physiology,exerts its biological functions primarily through its incorporation into selenoproteins.To date,approximately 25 selenoproteins have been characterized in mammalian systems,including glutathione peroxidase(GPX),thioredoxin reductase(TrxR),and iodothyronine deiodinases(DIOs),all of which exhibit indispensable physiological functions.
基金supported by the National Key Research and Development Program of China(2022YFD1200504)the National Natural Science Foundation of China(32171857)+2 种基金China Agriculture Research System(CARS-23-A18)The“JBGS”Project of Seed Industry Revitalization in Jiangsu Province(JBGS[2021]094)the Priority Academic Program Development of Jiangsu Higher Education Institutions.
文摘Chrysanthemum is rich in active compounds such as flavonoids and phenolic acids,and its dried head flowers are commonly used for tea and medicinal purposes.However,the genetic determinism underlying chrysanthemum active compounds remains elusive.In this study,we evaluated a panel of 137 chrysanthemum accessions for total flavonoids,chlorogenic acid,luteolin,and isochlorogenic acid A across two consecutive years.The four active compounds exhibited considerable variation,with a coefficient of variation ranging from 44.96%to 76.30%.Significant differences were observed in genotype and environments,and the broad-sense heritability was estimated at 0.5e0.63 for all examined traits.Significant pair-wise correlation was found between the four active compounds.Several accessions showing the highest active compounds were figured out for breeding use by integrating the membership function and hierarchical cluster analysis methods.Based on the 327042 high-quality SNPs,a genome-wide association study(GWAS)captured 59 significant SNPs for the four active compounds,of which 24 elite alleles exhibited pyramiding effects.A total of 18 potential candidate genes were mined,among which evm.model.scaffold_1149.273(QUA1)has one linkage disequilibrium(LD)block corresponding to Hap4 with the highest luteolin content.The findings are beneficial to understanding the genetic basis of the active compounds and provide parental materials and valuable markers for the genetic improvement of active compounds in chrysanthemums.
基金supported by the National Science Foundation of China (No.22106098)the Youth Science and Technology Research Foundation of Shanxi Province (No.20210302124298)+2 种基金the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (Nos.2020L0174,and 2020L0025)the Startup Foundation for Doctors of Shanxi Province (No.SD1917)the Startup Foundation for Doctors of Shanxi Medical University (No.XD1917).
文摘Bisphenol compounds(BPs)have various industrial uses and can enter the environment through various sources.To evaluate the ecotoxicity of BPs and identify potential gene candidates involved in the plant toxicity,Arabidopsis thaliana was exposed to bisphenol A(BPA),BPB,BPE,BPF,and BPS at 1,3,10 mg/L for a duration of 14 days,and their growth status were monitored.At day 14,roots and leaves were collected for internal BPs exposure concentration detection,RNA-seq(only roots),and morphological observations.As shown in the results,exposure to BPs significantly disturbed root elongation,exhibiting a trend of stimulation at low concentration and inhibition at high concentration.Additionally,BPs exhibited pronounced generation of reactive oxygen species,while none of the pollutants caused significant changes in root morphology.Internal exposure concentration analysis indicated that BPs tended to accumulate in the roots,with BPS exhibiting the highest level of accumulation.The results of RNA-seq indicated that the shared 211 differently expressed genes(DEGs)of these 5 exposure groups were enriched in defense response,generation of precursormetabolites,response to organic substance,response to oxygen-containing,response to hormone,oxidation-reduction process and so on.Regarding unique DEGs in each group,BPS wasmainly associated with the redox pathway,BPB primarily influenced seed germination,and BPA,BPE and BPF were primarily involved in metabolic signaling pathways.Our results provide newinsights for BPs induced adverse effects on Arabidopsis thaliana and suggest that the ecological risks associated with BPA alternatives cannot be ignored.
基金supported by the National Natural Science Foundation of China(Nos.21925601 and 22127811).
文摘Atmospheric dimethyl sulfide(DMS,CH_(3)SCH_(3))and methanethiol(MeSH,CH_(3)SH)have been widely studied and recognized to significantly constrain the atmospheric sulfur budget.Nevertheless,while the role of DMS and MeSH remains largely uncertain in inland regions,learning about dimethyl disulfide(DMDS,CH_(3)SSCH_(3))is also limited.In this study,we measured atmospheric DMS,MeSH and DMDS in winter,from 19 December 2022 to 30 January 2023,and spring,from 24 April to 2 June 2023 with a Vocus proton-transfer-reaction time-offlightmass spectrometer(Vocus PTR-TOF)at the Dianshan Lake(DSL)Air QualityMonitoring Supersite in a suburban area of Shanghai,China.The mixing ratios of DMS,MeSH and DMDS exhibited clear diurnal cycles,and were characterized by average and interquartile range values of 22.6(10.1-29.7),14.9(6.5-19.4)and 9.8(6.0-10.7)pptv,respectively,in the spring campaign,which are approximately twice as high as those in winter.MeSH and DMDS were found to be well correlated with DMS in the two campaigns.Wind analysis suggests that three reduced-sulfur compounds owned common sources from the DSL.Furthermore,the sulfur dioxide(SO_(2))production quantity fromthe three reduced-sulfur compounds over the DSL inMay 2023 was estimated to be 1.42±0.74 t with 84.8%originating fromDMDS,which was comparable to the monthly SO_(2) emissions fromships over the DSL.Our results highlight the prominent role of atmospheric DMDS in SO_(2) production when compared to DMS and MeSH in the suburban area of Shanghai,soliciting further investigation and consideration of DMDS in the sulfur budget.
基金supported by Shaanxi Province Qin Chuangyuan“Scientist+Engineer”team construction project(2024QCY-KXJ-079)Shaanxi Science and Technology Innovation Team Project(2024RSCXTD-70)for the financial support。
文摘Roasting is important for improving the content of bioactive compounds and enhancing the flavor of flaxseed oil.However,the effect of roasting time on germinated flaxseed oil(GFO)is unclear.Herein,the influence of roasting time(0–50 min)at a specific temperature of 160?C on the physicochemical properties,bioactive compounds,antioxidant capacity,and volatile compounds of GFO from three flaxseed varieties was examined.An extension in roasting time increased the a^(*)value of GFO,while the L^(*)and b^(*)values of GFO decreased.Higher chlorophylls(1.63±0.01–2.18±0.01 mg/kg),carotenoids(2.25±0.00–2.69±0.02 mg/kg),total phenolic content(156.75±2.93–200.03±6.29 mg GAE/kg),phytosterol(1801.93±30.64–1965.23±13.71 mg GAE/kg)and DPPH(320.11±18.22–432.19±14.95μmol TE/kg)and ABTS radical scavenging activity(810.68±16.29–1119.01±14.25μmol TE/kg)were detected in GFO after roasting for 20–30 min.However,the total tocopherol and unsaturated fatty acid content declined,and the composition of fatty acids changed insignificantly(P>0.05).GC–MS recognized 68 volatile compounds in GFO,in which pyrazine imparted a nutty flavor to the GFO.This study provides important information for the development of high-quality GFO.
