We present the first example of a silver double-tetranuclear cluster helicate[Ag_(4)L_(2)]_(2)obtained from a bisthiosemicarbazone ligand using electrochemical synthesis.This cluster helicate undergoes a rare desulfur...We present the first example of a silver double-tetranuclear cluster helicate[Ag_(4)L_(2)]_(2)obtained from a bisthiosemicarbazone ligand using electrochemical synthesis.This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate[Ag_(2)(H_(2)L)_(2)]SO_(4).This is the first silver mediated desulfurization reaction.展开更多
基金funding from the following FEDER cofunded-grants:from Consellería de Cultura,Educación e Ordenación Universitaria,Xunta de Galicia,2017 GRC GI-1682(ED431C 2017/01)2018 GRC GI-1584(ED431C 2018/13)+2 种基金MetalBIO Network(ED431D 2017/01)Ministerio de Ciencia,Innovación y Universidades,METALBIO(CTQ2017-90802-REDT)MultiMetDrugs(RED2018-102471-T).
文摘We present the first example of a silver double-tetranuclear cluster helicate[Ag_(4)L_(2)]_(2)obtained from a bisthiosemicarbazone ligand using electrochemical synthesis.This cluster helicate undergoes a rare desulfurization process in chloroform giving rise to a cationic silver dihelicate[Ag_(2)(H_(2)L)_(2)]SO_(4).This is the first silver mediated desulfurization reaction.
